#------------------------------------------------------------------------------
#$Date: 2022-09-28 18:08:17 +0300 (Wed, 28 Sep 2022) $
#$Revision: 278247 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/01/58/2015854.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2015854
loop_
_publ_author_name
'Menezes Vicenti, Juliano R. de'
'Burrow, Robert A.'
_publ_section_title
;catena-Poly[[(N,N-dimethylformamide-κO)(nitrato-κO)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ²P:P']
 at 100 and 293K: temperature effects on the volume of the solvent pocket
;
_journal_coeditor_code           GD3080
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m88
_journal_page_last               m90
_journal_paper_doi               10.1107/S010827010700306X
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag (N O3) (C3 H7 N O) (C26 H24 P2)]'
_chemical_formula_moiety         'C29 H31 Ag N2 O4 P2'
_chemical_formula_sum            'C29 H31 Ag N2 O4 P2'
_chemical_formula_weight         641.37
_chemical_name_systematic
;
catena-Poly[[(N,N-dimethylformamide-\kO)(nitrato-κ²O:O')silver(I)]-
μ-1,2-bis(diphenylphosphino)ethane-κ²P:P']
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                112.2010(10)
_cell_angle_beta                 102.2000(10)
_cell_angle_gamma                106.8560(10)
_cell_formula_units_Z            2
_cell_length_a                   11.1758(3)
_cell_length_b                   12.1731(3)
_cell_length_c                   13.0499(3)
_cell_measurement_reflns_used    5132
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      22.58
_cell_measurement_theta_min      2.72
_cell_volume                     1466.34(7)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEX2, BIS and COSMO (Bruker, 2006)'
_computing_data_reduction        'SAINT and SADABS (Bruker, 2006)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXTL (Bruker, 2006)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0528
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            35945
_diffrn_reflns_theta_full        29.98
_diffrn_reflns_theta_max         29.98
_diffrn_reflns_theta_min         2.96
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.832
_exptl_absorpt_correction_T_max  0.95064
_exptl_absorpt_correction_T_min  0.89766
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
Bruker APEX2 routines (using XPREP and SADABS) were used to perform
the Gaussian face-indexed numerical absorption correction.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.453
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             656
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.08
_refine_diff_density_max         0.661
_refine_diff_density_min         -0.534
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     345
_refine_ls_number_reflns         8523
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0785
_refine_ls_R_factor_gt           0.0444
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0474P)²+0.249P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0971
_refine_ls_wR_factor_ref         0.1109
_reflns_number_gt                5657
_reflns_number_total             8523
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            gd3080.cif
_cod_data_source_block           I_293K
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               2015854
_cod_database_fobs_code          2015854
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Ag Ag1 0.20328(2) 0.48532(2) 0.32426(2) 0.04324(9) Uani d . 1
C C1 0.4526(3) 0.4340(3) 0.4903(2) 0.0398(6) Uani d . 1
H H1A 0.4137 0.4472 0.5513 0.048 Uiso calc R 1
H H1B 0.5028 0.3822 0.4960 0.048 Uiso calc R 1
C C2 0.0473(3) 0.5716(3) 0.5326(2) 0.0360(6) Uani d . 1
H H2A 0.1229 0.5861 0.5963 0.043 Uiso calc R 1
H H2B 0.0008 0.6226 0.5680 0.043 Uiso calc R 1
C C11 -0.0824(6) 0.2728(5) 0.0573(6) 0.1110(19) Uani d . 1
H H11 -0.0543 0.3374 0.0354 0.133 Uiso calc R 1
C C12 -0.2331(6) 0.0654(6) 0.0094(6) 0.138(3) Uani d . 1
H H12A -0.2027 -0.0001 -0.0282 0.207 Uiso calc R 1
H H12B -0.3293 0.0282 -0.0188 0.207 Uiso calc R 1
H H12C -0.1979 0.0982 0.0939 0.207 Uiso calc R 1
C C13 -0.2639(7) 0.1504(8) -0.1316(5) 0.168(4) Uani d . 1
H H13A -0.3563 0.1279 -0.1397 0.251 Uiso calc R 1
H H13B -0.2565 0.0818 -0.1939 0.251 Uiso calc R 1
H H13C -0.2297 0.2295 -0.1366 0.251 Uiso calc R 1
C C111 0.4067(3) 0.3073(3) 0.2404(3) 0.0399(6) Uani d . 1
C C112 0.3728(4) 0.3189(4) 0.1386(3) 0.0614(10) Uani d . 1
H H112 0.3033 0.3439 0.1209 0.074 Uiso calc R 1
C C113 0.4423(6) 0.2931(5) 0.0619(4) 0.0887(15) Uani d . 1
H H113 0.4184 0.3001 -0.0074 0.106 Uiso calc R 1
C C114 0.5439(6) 0.2583(5) 0.0875(5) 0.0958(16) Uani d . 1
H H114 0.5911 0.2437 0.0365 0.115 Uiso calc R 1
C C115 0.5790(5) 0.2440(5) 0.1868(4) 0.0946(16) Uani d . 1
H H115 0.6482 0.2179 0.2026 0.113 Uiso calc R 1
C C116 0.5101(4) 0.2689(4) 0.2640(3) 0.0672(11) Uani d . 1
H H116 0.5336 0.2597 0.3321 0.081 Uiso calc R 1
C C121 0.2222(3) 0.1916(3) 0.3316(3) 0.0394(6) Uani d . 1
C C122 0.1049(3) 0.1090(3) 0.2327(3) 0.0564(9) Uani d . 1
H H122 0.0792 0.1342 0.1757 0.068 Uiso calc R 1
C C123 0.0265(4) -0.0101(4) 0.2188(4) 0.0699(11) Uani d . 1
H H123 -0.0508 -0.0653 0.1516 0.084 Uiso calc R 1
C C124 0.0612(4) -0.0479(4) 0.3029(4) 0.0739(12) Uani d . 1
H H124 0.0062 -0.1275 0.2935 0.089 Uiso calc R 1
C C125 0.1758(4) 0.0306(4) 0.4003(4) 0.0697(11) Uani d . 1
H H125 0.1993 0.0044 0.4570 0.084 Uiso calc R 1
C C126 0.2575(4) 0.1500(3) 0.4148(3) 0.0558(9) Uani d . 1
H H126 0.3365 0.2027 0.4808 0.067 Uiso calc R 1
C C212 -0.0386(3) 0.6225(3) 0.3368(3) 0.0377(6) Uani d . 1
C C213 -0.0492(3) 0.5888(3) 0.2212(3) 0.0488(8) Uani d . 1
H H213 0.0185 0.5716 0.1964 0.059 Uiso calc R 1
C C214 -0.1599(4) 0.5802(4) 0.1405(3) 0.0619(10) Uani d . 1
H H214 -0.1660 0.5580 0.0626 0.074 Uiso calc R 1
C C215 -0.2595(4) 0.6047(4) 0.1773(4) 0.0658(10) Uani d . 1
H H215 -0.3350 0.5966 0.1234 0.079 Uiso calc R 1
C C216 -0.2491(4) 0.6410(4) 0.2923(4) 0.0675(11) Uani d . 1
H H216 -0.3157 0.6606 0.3173 0.081 Uiso calc R 1
C C217 -0.1400(3) 0.6486(4) 0.3713(3) 0.0580(9) Uani d . 1
H H217 -0.1345 0.6718 0.4493 0.070 Uiso calc R 1
C C221 0.2169(3) 0.7977(3) 0.5331(3) 0.0385(6) Uani d . 1
C C222 0.1783(4) 0.8781(3) 0.6147(3) 0.0592(9) Uani d . 1
H H222 0.0942 0.8450 0.6186 0.071 Uiso calc R 1
C C223 0.2640(4) 1.0068(4) 0.6900(4) 0.0730(11) Uani d . 1
H H223 0.2366 1.0601 0.7435 0.088 Uiso calc R 1
C C224 0.3880(4) 1.0561(4) 0.6868(4) 0.0703(11) Uani d . 1
H H224 0.4455 1.1427 0.7382 0.084 Uiso calc R 1
C C225 0.4281(4) 0.9776(4) 0.6072(4) 0.0648(10) Uani d . 1
H H225 0.5129 1.0113 0.6047 0.078 Uiso calc R 1
C C226 0.3429(3) 0.8483(3) 0.5307(3) 0.0495(8) Uani d . 1
H H226 0.3710 0.7955 0.4775 0.059 Uiso calc R 1
N N1 0.3609(3) 0.6073(3) 0.2012(2) 0.0482(6) Uani d . 1
N N11 -0.1875(4) 0.1686(4) -0.0182(3) 0.0810(11) Uani d . 1
O O1 0.2362(2) 0.5401(3) 0.1655(2) 0.0607(6) Uani d . 1
O O2 0.4305(3) 0.6486(3) 0.3063(2) 0.0673(7) Uani d . 1
O O3 0.4117(3) 0.6270(3) 0.1312(2) 0.0755(8) Uani d . 1
O O11 -0.0171(4) 0.2934(3) 0.1551(4) 0.1368(18) Uani d . 1
P P1 0.31895(7) 0.34780(7) 0.34372(6) 0.03427(16) Uani d . 1
P P2 0.10879(7) 0.62630(7) 0.43386(6) 0.03282(16) Uani d . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 0 -1 0.04
0 0 1 0.064
0 -1 0 0.038
0 1 0 0.034
-1 1 0 0.102
1 -1 0 0.057
-1 0 0 0.097
1 0 0 0.056
0 1 1 0.044
0 -1 -1 0.037
0 -1 1 0.063
0 1 -1 0.053
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle
_geom_angle_publ_flag
P2 Ag1 P1 . 140.92(2) y
P2 Ag1 O1 . 107.16(6) y
P1 Ag1 O1 . 110.04(6) y
P2 Ag1 O11 . 100.02(11) y
P1 Ag1 O11 . 95.27(8) y
O1 Ag1 O11 . 84.19(12) y
P2 Ag1 O2 . 106.76(6) ?
P1 Ag1 O2 . 90.21(6) ?
O1 Ag1 O2 . 47.17(7) ?
O11 Ag1 O2 . 129.27(12) ?
N1 O2 Ag1 . 87.55(19) y
C1 C1 P1 2_666 110.1(2) ?
C1 C1 H1A 2_666 109.6 ?
P1 C1 H1A . 109.6 ?
C1 C1 H1B 2_666 109.6 ?
P1 C1 H1B . 109.6 ?
H1A C1 H1B . 108.2 ?
C2 C2 P2 2_566 111.9(3) ?
C2 C2 H2A 2_566 109.2 ?
P2 C2 H2A . 109.2 ?
C2 C2 H2B 2_566 109.2 ?
P2 C2 H2B . 109.2 ?
H2A C2 H2B . 107.9 ?
O11 C11 N11 . 125.3(6) ?
O11 C11 H11 . 117.4 ?
N11 C11 H11 . 117.4 ?
N11 C12 H12A . 109.5 ?
N11 C12 H12B . 109.5 ?
H12A C12 H12B . 109.5 ?
N11 C12 H12C . 109.5 ?
H12A C12 H12C . 109.5 ?
H12B C12 H12C . 109.5 ?
N11 C13 H13A . 109.5 ?
N11 C13 H13B . 109.5 ?
H13A C13 H13B . 109.5 ?
N11 C13 H13C . 109.5 ?
H13A C13 H13C . 109.5 ?
H13B C13 H13C . 109.5 ?
C112 C111 C116 . 118.6(3) ?
C112 C111 P1 . 119.7(2) ?
C116 C111 P1 . 121.6(2) ?
C111 C112 C113 . 120.1(4) ?
C111 C112 H112 . 119.9 ?
C113 C112 H112 . 119.9 ?
C114 C113 C112 . 120.3(4) ?
C114 C113 H113 . 119.9 ?
C112 C113 H113 . 119.9 ?
C113 C114 C115 . 121.2(4) ?
C113 C114 H114 . 119.4 ?
C115 C114 H114 . 119.4 ?
C114 C115 C116 . 119.1(4) ?
C114 C115 H115 . 120.4 ?
C116 C115 H115 . 120.4 ?
C111 C116 C115 . 120.6(4) ?
C111 C116 H116 . 119.7 ?
C115 C116 H116 . 119.7 ?
C122 C121 C126 . 118.1(3) ?
C122 C121 P1 . 117.5(2) ?
C126 C121 P1 . 124.4(3) ?
C123 C122 C121 . 120.4(3) ?
C123 C122 H122 . 119.8 ?
C121 C122 H122 . 119.8 ?
C124 C123 C122 . 120.7(4) ?
C124 C123 H123 . 119.7 ?
C122 C123 H123 . 119.7 ?
C125 C124 C123 . 120.2(4) ?
C125 C124 H124 . 119.9 ?
C123 C124 H124 . 119.9 ?
C124 C125 C126 . 120.0(4) ?
C124 C125 H125 . 120.0 ?
C126 C125 H125 . 120.0 ?
C125 C126 C121 . 120.6(3) ?
C125 C126 H126 . 119.7 ?
C121 C126 H126 . 119.7 ?
C213 C212 C217 . 118.3(3) ?
C213 C212 P2 . 117.2(2) ?
C217 C212 P2 . 124.5(2) ?
C212 C213 C214 . 121.0(3) ?
C212 C213 H213 . 119.5 ?
C214 C213 H213 . 119.5 ?
C215 C214 C213 . 119.2(3) ?
C215 C214 H214 . 120.4 ?
C213 C214 H214 . 120.4 ?
C216 C215 C214 . 120.5(3) ?
C216 C215 H215 . 119.7 ?
C214 C215 H215 . 119.7 ?
C215 C216 C217 . 120.0(3) ?
C215 C216 H216 . 120.0 ?
C217 C216 H216 . 120.0 ?
C216 C217 C212 . 121.0(3) ?
C216 C217 H217 . 119.5 ?
C212 C217 H217 . 119.5 ?
C226 C221 C222 . 118.7(3) ?
C226 C221 P2 . 119.2(2) ?
C222 C221 P2 . 122.1(2) ?
C223 C222 C221 . 120.4(3) ?
C223 C222 H222 . 119.8 ?
C221 C222 H222 . 119.8 ?
C224 C223 C222 . 120.6(4) ?
C224 C223 H223 . 119.7 ?
C222 C223 H223 . 119.7 ?
C223 C224 C225 . 119.7(4) ?
C223 C224 H224 . 120.1 ?
C225 C224 H224 . 120.1 ?
C224 C225 C226 . 120.3(3) ?
C224 C225 H225 . 119.8 ?
C226 C225 H225 . 119.8 ?
C221 C226 C225 . 120.3(3) ?
C221 C226 H226 . 119.9 ?
C225 C226 H226 . 119.9 ?
O3 N1 O2 . 121.2(3) ?
O3 N1 O1 . 120.1(3) ?
O2 N1 O1 . 118.6(3) ?
C11 N11 C12 . 119.7(5) ?
C11 N11 C13 . 123.2(6) ?
C12 N11 C13 . 117.1(5) ?
N1 O1 Ag1 . 105.46(18) y
C11 O11 Ag1 . 133.3(4) ?
C121 P1 C1 . 104.52(13) ?
C121 P1 C111 . 103.83(13) ?
C1 P1 C111 . 103.70(14) ?
C121 P1 Ag1 . 118.39(9) ?
C1 P1 Ag1 . 109.55(10) ?
C111 P1 Ag1 . 115.39(10) ?
C221 P2 C2 . 102.71(13) ?
C221 P2 C212 . 105.98(13) ?
C2 P2 C212 . 104.35(13) ?
C221 P2 Ag1 . 118.94(10) ?
C2 P2 Ag1 . 110.86(9) ?
C212 P2 Ag1 . 112.63(10) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 O1 . 2.469(2) y
Ag1 O2 . 2.851(3) y
Ag1 O11 . 2.620(3) y
Ag1 P1 . 2.4445(7) y
Ag1 P2 . 2.4372(7) y
C1 C1 2_666 1.536(6) ?
C1 P1 . 1.832(3) ?
C1 H1A . 0.9700 ?
C1 H1B . 0.9700 ?
C2 C2 2_566 1.520(5) ?
C2 P2 . 1.826(3) ?
C2 H2A . 0.9700 ?
C2 H2B . 0.9700 ?
C11 O11 . 1.218(6) ?
C11 N11 . 1.289(6) ?
C11 H11 . 0.9300 ?
C12 N11 . 1.421(7) ?
C12 H12A . 0.9600 ?
C12 H12B . 0.9600 ?
C12 H12C . 0.9600 ?
C13 N11 . 1.440(6) ?
C13 H13A . 0.9600 ?
C13 H13B . 0.9600 ?
C13 H13C . 0.9600 ?
C111 C112 . 1.374(4) ?
C111 C116 . 1.387(4) ?
C111 P1 . 1.833(3) ?
C112 C113 . 1.391(5) ?
C112 H112 . 0.9300 ?
C113 C114 . 1.343(7) ?
C113 H113 . 0.9300 ?
C114 C115 . 1.364(7) ?
C114 H114 . 0.9300 ?
C115 C116 . 1.390(5) ?
C115 H115 . 0.9300 ?
C116 H116 . 0.9300 ?
C121 C122 . 1.391(4) ?
C121 C126 . 1.393(4) ?
C121 P1 . 1.821(3) ?
C122 C123 . 1.378(5) ?
C122 H122 . 0.9300 ?
C123 C124 . 1.368(6) ?
C123 H123 . 0.9300 ?
C124 C125 . 1.361(6) ?
C124 H124 . 0.9300 ?
C125 C126 . 1.390(5) ?
C125 H125 . 0.9300 ?
C126 H126 . 0.9300 ?
C212 C213 . 1.374(4) ?
C212 C217 . 1.381(4) ?
C212 P2 . 1.830(3) ?
C213 C214 . 1.392(4) ?
C213 H213 . 0.9300 ?
C214 C215 . 1.368(5) ?
C214 H214 . 0.9300 ?
C215 C216 . 1.362(5) ?
C215 H215 . 0.9300 ?
C216 C217 . 1.374(5) ?
C216 H216 . 0.9300 ?
C217 H217 . 0.9300 ?
C221 C226 . 1.376(4) ?
C221 C222 . 1.388(5) ?
C221 P2 . 1.824(3) ?
C222 C223 . 1.381(5) ?
C222 H222 . 0.9300 ?
C223 C224 . 1.357(6) ?
C223 H223 . 0.9300 ?
C224 C225 . 1.375(6) ?
C224 H224 . 0.9300 ?
C225 C226 . 1.387(5) ?
C225 H225 . 0.9300 ?
C226 H226 . 0.9300 ?
N1 O3 . 1.232(3) ?
N1 O2 . 1.242(3) ?
N1 O1 . 1.267(4) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
C116 C111 C112 C113 . -0.5(6)
P1 C111 C112 C113 . 177.6(3)
C111 C112 C113 C114 . -0.8(7)
C112 C113 C114 C115 . 1.8(8)
C113 C114 C115 C116 . -1.5(8)
C112 C111 C116 C115 . 0.7(6)
P1 C111 C116 C115 . -177.3(3)
C114 C115 C116 C111 . 0.2(7)
C126 C121 C122 C123 . 0.2(5)
P1 C121 C122 C123 . -179.4(3)
C121 C122 C123 C124 . 1.3(6)
C122 C123 C124 C125 . -1.7(7)
C123 C124 C125 C126 . 0.4(7)
C124 C125 C126 C121 . 1.1(6)
C122 C121 C126 C125 . -1.4(5)
P1 C121 C126 C125 . 178.2(3)
C217 C212 C213 C214 . -0.5(5)
P2 C212 C213 C214 . 178.3(3)
C212 C213 C214 C215 . -0.5(6)
C213 C214 C215 C216 . 1.9(6)
C214 C215 C216 C217 . -2.3(7)
C215 C216 C217 C212 . 1.3(6)
C213 C212 C217 C216 . 0.1(5)
P2 C212 C217 C216 . -178.6(3)
C226 C221 C222 C223 . 1.3(5)
P2 C221 C222 C223 . 178.7(3)
C221 C222 C223 C224 . -1.0(7)
C222 C223 C224 C225 . 0.5(7)
C223 C224 C225 C226 . -0.2(6)
C222 C221 C226 C225 . -1.0(5)
P2 C221 C226 C225 . -178.5(3)
C224 C225 C226 C221 . 0.5(5)
O11 C11 N11 C12 . -1.5(9)
O11 C11 N11 C13 . 178.0(6)
O3 N1 O1 Ag1 . 165.4(2)
O2 N1 O1 Ag1 . -12.1(3)
P2 Ag1 O1 N1 . 103.49(19)
P1 Ag1 O1 N1 . -64.3(2)
O11 Ag1 O1 N1 . -157.8(2)
N11 C11 O11 Ag1 . 176.8(4)
P2 Ag1 O11 C11 . 88.5(6)
P1 Ag1 O11 C11 . -127.6(6)
O1 Ag1 O11 C11 . -17.9(6)
C122 C121 P1 C1 . 174.0(3)
C126 C121 P1 C1 . -5.6(3)
C122 C121 P1 C111 . -77.6(3)
C126 C121 P1 C111 . 102.8(3)
C122 C121 P1 Ag1 . 51.8(3)
C126 C121 P1 Ag1 . -127.8(3)
C1 C1 P1 C121 2_666 177.0(3)
C1 C1 P1 C111 2_666 68.5(3)
C1 C1 P1 Ag1 2_666 -55.2(3)
C112 C111 P1 C121 . 111.6(3)
C116 C111 P1 C121 . -70.4(3)
C112 C111 P1 C1 . -139.3(3)
C116 C111 P1 C1 . 38.6(3)
C112 C111 P1 Ag1 . -19.6(3)
C116 C111 P1 Ag1 . 158.4(3)
P2 Ag1 P1 C121 . 74.25(12)
O1 Ag1 P1 C121 . -124.47(13)
O11 Ag1 P1 C121 . -38.74(16)
P2 Ag1 P1 C1 . -45.37(11)
O1 Ag1 P1 C1 . 115.91(12)
O11 Ag1 P1 C1 . -158.36(15)
P2 Ag1 P1 C111 . -161.89(11)
O1 Ag1 P1 C111 . -0.61(13)
O11 Ag1 P1 C111 . 85.11(16)
C226 C221 P2 C2 . 132.7(2)
C222 C221 P2 C2 . -44.7(3)
C226 C221 P2 C212 . -118.1(2)
C222 C221 P2 C212 . 64.5(3)
C226 C221 P2 Ag1 . 9.9(3)
C222 C221 P2 Ag1 . -167.5(2)
C2 C2 P2 C221 2_566 179.8(3)
C2 C2 P2 C212 2_566 69.3(3)
C2 C2 P2 Ag1 2_566 -52.2(3)
C213 C212 P2 C221 . 106.7(3)
C217 C212 P2 C221 . -74.6(3)
C213 C212 P2 C2 . -145.3(2)
C217 C212 P2 C2 . 33.4(3)
C213 C212 P2 Ag1 . -25.0(3)
C217 C212 P2 Ag1 . 153.7(3)
P1 Ag1 P2 C221 . 88.20(11)
O1 Ag1 P2 C221 . -73.40(12)
O11 Ag1 P2 C221 . -160.37(14)
P1 Ag1 P2 C2 . -30.47(11)
O1 Ag1 P2 C2 . 167.93(11)
O11 Ag1 P2 C2 . 80.96(13)
P1 Ag1 P2 C212 . -146.96(10)
O1 Ag1 P2 C212 . 51.44(12)
O11 Ag1 P2 C212 . -35.53(14)
O3 N1 O2 Ag1 . -167.4(3)
O1 N1 O2 Ag1 . 10.1(3)
P2 Ag1 O2 N1 . -104.29(18)
P1 Ag1 O2 N1 . 111.44(18)
O1 Ag1 O2 N1 . -6.19(17)
O11 Ag1 O2 N1 . 14.5(2)
