#------------------------------------------------------------------------------
#$Date: 2022-09-28 18:08:17 +0300 (Wed, 28 Sep 2022) $
#$Revision: 278247 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/01/58/2015855.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2015855
loop_
_publ_author_name
'Menezes Vicenti, Juliano R. de'
'Burrow, Robert A.'
_publ_section_title
;catena-Poly[[(N,N-dimethylformamide-κO)(nitrato-κO)silver(I)]-μ-1,2-bis(diphenylphosphino)ethane-κ²P:P']
 at 100 and 293K: temperature effects on the volume of the solvent pocket
;
_journal_coeditor_code           GD3080
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m88
_journal_page_last               m90
_journal_paper_doi               10.1107/S010827010700306X
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag (N O3) (C3 H7 N O) (C26 H24 P2)]'
_chemical_formula_moiety         'C29 H31 Ag N2 O4 P2'
_chemical_formula_sum            'C29 H31 Ag N2 O4 P2'
_chemical_formula_weight         641.37
_chemical_name_systematic
;
catena-Poly[[(N,N-dimethylformamide-\kO)(nitrato-κ²O:O')silver(I)]-
μ-1,2-bis(diphenylphosphino)ethane-κ²P:P']
;
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                112.322(2)
_cell_angle_beta                 102.410(2)
_cell_angle_gamma                106.216(2)
_cell_formula_units_Z            2
_cell_length_a                   11.0869(3)
_cell_length_b                   11.9653(4)
_cell_length_c                   12.9618(4)
_cell_measurement_reflns_used    9993
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      29.69
_cell_measurement_theta_min      2.75
_cell_volume                     1424.15(9)
_computing_cell_refinement       'SAINT (Bruker, 2006)'
_computing_data_collection       'APEX2, BIS and COSMO (Bruker, 2006)'
_computing_data_reduction        'SAINT and SADABS (Bruker, 2006)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXTL (Bruker, 2006)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0421
_diffrn_reflns_limit_h_max       15
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            36255
_diffrn_reflns_theta_full        29.95
_diffrn_reflns_theta_max         29.95
_diffrn_reflns_theta_min         2.95
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.857
_exptl_absorpt_correction_T_max  0.958
_exptl_absorpt_correction_T_min  0.900
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
Bruker APEX2 routines (using XPREP and SADABS) were used to perform
the Gaussian face-indexed numerical absorption correction.
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.496
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             656
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.06
_refine_diff_density_max         1.604
_refine_diff_density_min         -0.626
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.041
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     345
_refine_ls_number_reflns         8237
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.041
_refine_ls_R_factor_all          0.0433
_refine_ls_R_factor_gt           0.034
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0342P)²+1.2423P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0761
_refine_ls_wR_factor_ref         0.0805
_reflns_number_gt                7005
_reflns_number_total             8237
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            gd3080.cif
_cod_data_source_block           I_100K
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               2015855
_cod_database_fobs_code          2015855
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Ag Ag1 0.201247(16) 0.484687(16) 0.321223(14) 0.01572(5) Uani d . 1
C C1 0.4526(2) 0.4334(2) 0.49036(18) 0.0147(4) Uani d . 1
H H1A 0.4119 0.4476 0.5527 0.018 Uiso calc R 1
H H1B 0.5043 0.3794 0.497 0.018 Uiso calc R 1
C C2 0.0477(2) 0.5729(2) 0.53449(18) 0.0143(4) Uani d . 1
H H2A 0.1253 0.5862 0.5991 0.017 Uiso calc R 1
H H2B 0 0.6259 0.5717 0.017 Uiso calc R 1
C C11 -0.0818(3) 0.2733(3) 0.0535(3) 0.0327(6) Uani d . 1
H H11 -0.0555 0.3384 0.0285 0.039 Uiso calc R 1
C C12 -0.2360(3) 0.0593(3) 0.0105(3) 0.0360(6) Uani d . 1
H H12A -0.2214 -0.0169 -0.0399 0.054 Uiso calc R 1
H H12B -0.3321 0.0337 -0.0021 0.054 Uiso calc R 1
H H12C -0.1846 0.0906 0.0947 0.054 Uiso calc R 1
C C13 -0.2687(3) 0.1429(3) -0.1375(2) 0.0445(8) Uani d . 1
H H13A -0.2274 0.2197 -0.1481 0.067 Uiso calc R 1
H H13B -0.3614 0.1307 -0.1428 0.067 Uiso calc R 1
H H13C -0.2691 0.0643 -0.2002 0.067 Uiso calc R 1
C C111 0.4105(2) 0.3049(2) 0.24057(19) 0.0150(4) Uani d . 1
C C112 0.3802(3) 0.3203(2) 0.1384(2) 0.0217(5) Uani d . 1
H H112 0.3097 0.348 0.1198 0.026 Uiso calc R 1
C C113 0.4532(3) 0.2950(3) 0.0630(2) 0.0314(6) Uani d . 1
H H113 0.4319 0.3049 -0.0072 0.038 Uiso calc R 1
C C114 0.5560(3) 0.2557(3) 0.0902(3) 0.0347(6) Uani d . 1
H H114 0.607 0.2411 0.04 0.042 Uiso calc R 1
C C115 0.5851(3) 0.2372(3) 0.1902(2) 0.0331(6) Uani d . 1
H H115 0.6549 0.2083 0.2076 0.04 Uiso calc R 1
C C116 0.5124(2) 0.2611(3) 0.2653(2) 0.0255(5) Uani d . 1
H H116 0.532 0.2476 0.3336 0.031 Uiso calc R 1
C C121 0.2216(2) 0.1881(2) 0.32879(19) 0.0150(4) Uani d . 1
C C122 0.1042(2) 0.1043(2) 0.2264(2) 0.0190(4) Uani d . 1
H H122 0.0799 0.1308 0.1674 0.023 Uiso calc R 1
C C123 0.0236(2) -0.0169(2) 0.2112(2) 0.0247(5) Uani d . 1
H H123 -0.0543 -0.0739 0.1408 0.03 Uiso calc R 1
C C124 0.0562(2) -0.0553(2) 0.2985(2) 0.0247(5) Uani d . 1
H H124 -0.0002 -0.1377 0.2884 0.03 Uiso calc R 1
C C125 0.1707(2) 0.0264(2) 0.3998(2) 0.0235(5) Uani d . 1
H H125 0.1924 0.0003 0.4597 0.028 Uiso calc R 1
C C126 0.2548(2) 0.1471(2) 0.4149(2) 0.0193(4) Uani d . 1
H H126 0.3348 0.2015 0.4837 0.023 Uiso calc R 1
C C211 -0.0406(2) 0.6240(2) 0.33620(19) 0.0144(4) Uani d . 1
C C212 -0.0508(2) 0.5891(2) 0.21807(19) 0.0175(4) Uani d . 1
H H212 0.0198 0.5727 0.193 0.021 Uiso calc R 1
C C213 -0.1638(2) 0.5782(2) 0.1368(2) 0.0216(5) Uani d . 1
H H213 -0.1702 0.5544 0.0564 0.026 Uiso calc R 1
C C214 -0.2671(2) 0.6019(2) 0.1729(2) 0.0219(5) Uani d . 1
H H214 -0.345 0.5927 0.1169 0.026 Uiso calc R 1
C C215 -0.2567(2) 0.6390(2) 0.2903(2) 0.0234(5) Uani d . 1
H H215 -0.3266 0.6573 0.3153 0.028 Uiso calc R 1
C C216 -0.1444(2) 0.6496(2) 0.3718(2) 0.0200(4) Uani d . 1
H H216 -0.1381 0.6743 0.4523 0.024 Uiso calc R 1
C C221 0.2144(2) 0.8015(2) 0.53434(19) 0.0146(4) Uani d . 1
C C222 0.1735(2) 0.8831(2) 0.6167(2) 0.0208(4) Uani d . 1
H H222 0.0871 0.8484 0.6202 0.025 Uiso calc R 1
C C223 0.2585(3) 1.0147(2) 0.6932(2) 0.0248(5) Uani d . 1
H H223 0.23 1.0695 0.7486 0.03 Uiso calc R 1
C C224 0.3849(2) 1.0660(2) 0.6890(2) 0.0247(5) Uani d . 1
H H224 0.4428 1.1559 0.7413 0.03 Uiso calc R 1
C C225 0.4267(2) 0.9859(2) 0.6083(2) 0.0232(5) Uani d . 1
H H225 0.5136 1.0212 0.606 0.028 Uiso calc R 1
C C226 0.3424(2) 0.8545(2) 0.5306(2) 0.0188(4) Uani d . 1
H H226 0.3714 0.8005 0.4751 0.023 Uiso calc R 1
N N1 0.35962(19) 0.60651(18) 0.19860(17) 0.0172(4) Uani d . 1
N N11 -0.1915(2) 0.1639(2) -0.02095(19) 0.0278(5) Uani d . 1
O O1 0.23316(16) 0.54134(17) 0.16375(14) 0.0220(3) Uani d . 1
O O2 0.43074(17) 0.65141(17) 0.30621(14) 0.0233(3) Uani d . 1
O O3 0.41026(18) 0.62281(17) 0.12625(15) 0.0258(4) Uani d . 1
O O11 -0.0126(2) 0.29565(19) 0.15202(19) 0.0446(6) Uani d . 1
P P1 0.31958(5) 0.34638(5) 0.34195(5) 0.01304(10) Uani d . 1
P P2 0.10820(5) 0.62830(5) 0.43420(5) 0.01235(10) Uani d . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.006 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 0 -1 0.04
0 0 1 0.064
0 -1 0 0.038
0 1 0 0.034
-1 1 0 0.102
1 -1 0 0.057
-1 0 0 0.097
1 0 0 0.056
0 1 1 0.044
0 -1 -1 0.037
0 -1 1 0.063
0 1 -1 0.053
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle
_geom_angle_publ_flag
P2 Ag1 P1 . 139.863(18) y
P2 Ag1 O1 . 107.38(4) y
P1 Ag1 O1 . 110.53(4) y
P2 Ag1 O11 . 101.31(6) y
P1 Ag1 O11 . 95.67(5) y
O1 Ag1 O11 . 83.44(7) y
P2 Ag1 O2 . 106.37(4) ?
P1 Ag1 O2 . 89.91(4) ?
O1 Ag1 O2 . 47.74(5) ?
O11 Ag1 O2 . 128.93(7) ?
C1 C1 P1 2_666 109.73(17) ?
C1 C1 H1A 2_666 109.7 ?
P1 C1 H1A . 109.7 ?
C1 C1 H1B 2_666 109.7 ?
P1 C1 H1B . 109.7 ?
H1A C1 H1B . 108.2 ?
C2 C2 P2 2_566 110.53(18) ?
C2 C2 H2A 2_566 109.5 ?
P2 C2 H2A . 109.5 ?
C2 C2 H2B 2_566 109.5 ?
P2 C2 H2B . 109.5 ?
H2A C2 H2B . 108.1 ?
O11 C11 N11 . 124.4(3) ?
O11 C11 H11 . 117.8 ?
N11 C11 H11 . 117.8 ?
N11 C12 H12A . 109.5 ?
N11 C12 H12B . 109.5 ?
H12A C12 H12B . 109.5 ?
N11 C12 H12C . 109.5 ?
H12A C12 H12C . 109.5 ?
H12B C12 H12C . 109.5 ?
N11 C13 H13A . 109.5 ?
N11 C13 H13B . 109.5 ?
H13A C13 H13B . 109.5 ?
N11 C13 H13C . 109.5 ?
H13A C13 H13C . 109.5 ?
H13B C13 H13C . 109.5 ?
C112 C111 C116 . 119.3(2) ?
C112 C111 P1 . 119.33(16) ?
C116 C111 P1 . 121.36(17) ?
C111 C112 C113 . 120.0(2) ?
C111 C112 H112 . 120 ?
C113 C112 H112 . 120 ?
C114 C113 C112 . 120.1(2) ?
C114 C113 H113 . 119.9 ?
C112 C113 H113 . 119.9 ?
C113 C114 C115 . 120.4(2) ?
C113 C114 H114 . 119.8 ?
C115 C114 H114 . 119.8 ?
C114 C115 C116 . 120.0(2) ?
C114 C115 H115 . 120 ?
C116 C115 H115 . 120 ?
C115 C116 C111 . 120.2(2) ?
C115 C116 H116 . 119.9 ?
C111 C116 H116 . 119.9 ?
C126 C121 C122 . 118.8(2) ?
C126 C121 P1 . 124.05(17) ?
C122 C121 P1 . 117.15(16) ?
C123 C122 C121 . 120.3(2) ?
C123 C122 H122 . 119.8 ?
C121 C122 H122 . 119.8 ?
C122 C123 C124 . 120.3(2) ?
C122 C123 H123 . 119.8 ?
C124 C123 H123 . 119.8 ?
C125 C124 C123 . 119.9(2) ?
C125 C124 H124 . 120 ?
C123 C124 H124 . 120 ?
C124 C125 C126 . 120.4(2) ?
C124 C125 H125 . 119.8 ?
C126 C125 H125 . 119.8 ?
C125 C126 C121 . 120.2(2) ?
C125 C126 H126 . 119.9 ?
C121 C126 H126 . 119.9 ?
C212 C211 C216 . 119.07(19) ?
C212 C211 P2 . 116.91(16) ?
C216 C211 P2 . 123.99(16) ?
C213 C212 C211 . 120.3(2) ?
C213 C212 H212 . 119.8 ?
C211 C212 H212 . 119.8 ?
C214 C213 C212 . 120.0(2) ?
C214 C213 H213 . 120 ?
C212 C213 H213 . 120 ?
C215 C214 C213 . 120.1(2) ?
C215 C214 H214 . 120 ?
C213 C214 H214 . 120 ?
C214 C215 C216 . 120.2(2) ?
C214 C215 H215 . 119.9 ?
C216 C215 H215 . 119.9 ?
C215 C216 C211 . 120.3(2) ?
C215 C216 H216 . 119.8 ?
C211 C216 H216 . 119.8 ?
C222 C221 C226 . 119.0(2) ?
C222 C221 P2 . 122.03(16) ?
C226 C221 P2 . 118.94(17) ?
C223 C222 C221 . 120.3(2) ?
C223 C222 H222 . 119.8 ?
C221 C222 H222 . 119.8 ?
C224 C223 C222 . 120.2(2) ?
C224 C223 H223 . 119.9 ?
C222 C223 H223 . 119.9 ?
C225 C224 C223 . 119.9(2) ?
C225 C224 H224 . 120 ?
C223 C224 H224 . 120 ?
C224 C225 C226 . 120.5(2) ?
C224 C225 H225 . 119.7 ?
C226 C225 H225 . 119.7 ?
C225 C226 C221 . 120.0(2) ?
C225 C226 H226 . 120 ?
C221 C226 H226 . 120 ?
O3 N1 O2 . 121.31(19) ?
O3 N1 O1 . 119.94(18) ?
O2 N1 O1 . 118.74(18) ?
N1 O2 Ag1 . 86.18(12) y
C11 N11 C12 . 120.7(2) ?
C11 N11 C13 . 121.6(3) ?
C12 N11 C13 . 117.6(2) ?
N1 O1 Ag1 . 105.41(12) y
C11 O11 Ag1 . 135.48(19) ?
C121 P1 C111 . 103.80(9) ?
C121 P1 C1 . 104.77(9) ?
C111 P1 C1 . 103.17(10) ?
C121 P1 Ag1 . 117.53(7) ?
C111 P1 Ag1 . 116.35(7) ?
C1 P1 Ag1 . 109.70(7) ?
C221 P2 C211 . 106.06(9) ?
C221 P2 C2 . 102.30(9) ?
C211 P2 C2 . 104.56(10) ?
C221 P2 Ag1 . 119.87(7) ?
C211 P2 Ag1 . 111.50(7) ?
C2 P2 Ag1 . 111.17(7) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 O1 . 2.4451(16) y
Ag1 O2 . 2.8573(17) y
Ag1 O11 . 2.5588(19) y
Ag1 P1 . 2.4354(5) y
Ag1 P2 . 2.4268(6) y
C1 C1 2_666 1.535(4) ?
C1 P1 . 1.834(2) ?
C1 H1A . 0.99 ?
C1 H1B . 0.99 ?
C2 C2 2_566 1.529(4) ?
C2 P2 . 1.834(2) ?
C2 H2A . 0.99 ?
C2 H2B . 0.99 ?
C11 O11 . 1.223(3) ?
C11 N11 . 1.331(3) ?
C11 H11 . 0.95 ?
C12 N11 . 1.451(4) ?
C12 H12A . 0.98 ?
C12 H12B . 0.98 ?
C12 H12C . 0.98 ?
C13 N11 . 1.454(3) ?
C13 H13A . 0.98 ?
C13 H13B . 0.98 ?
C13 H13C . 0.98 ?
C111 C112 . 1.389(3) ?
C111 C116 . 1.398(3) ?
C111 P1 . 1.829(2) ?
C112 C113 . 1.398(3) ?
C112 H112 . 0.95 ?
C113 C114 . 1.377(4) ?
C113 H113 . 0.95 ?
C114 C115 . 1.382(4) ?
C114 H114 . 0.95 ?
C115 C116 . 1.391(3) ?
C115 H115 . 0.95 ?
C116 H116 . 0.95 ?
C121 C126 . 1.401(3) ?
C121 C122 . 1.407(3) ?
C121 P1 . 1.823(2) ?
C122 C123 . 1.387(3) ?
C122 H122 . 0.95 ?
C123 C124 . 1.390(3) ?
C123 H123 . 0.95 ?
C124 C125 . 1.381(3) ?
C124 H124 . 0.95 ?
C125 C126 . 1.396(3) ?
C125 H125 . 0.95 ?
C126 H126 . 0.95 ?
C211 C212 . 1.395(3) ?
C211 C216 . 1.396(3) ?
C211 P2 . 1.828(2) ?
C212 C213 . 1.390(3) ?
C212 H212 . 0.95 ?
C213 C214 . 1.387(3) ?
C213 H213 . 0.95 ?
C214 C215 . 1.381(3) ?
C214 H214 . 0.95 ?
C215 C216 . 1.389(3) ?
C215 H215 . 0.95 ?
C216 H216 . 0.95 ?
C221 C222 . 1.401(3) ?
C221 C226 . 1.402(3) ?
C221 P2 . 1.818(2) ?
C222 C223 . 1.391(3) ?
C222 H222 . 0.95 ?
C223 C224 . 1.386(4) ?
C223 H223 . 0.95 ?
C224 C225 . 1.386(4) ?
C224 H224 . 0.95 ?
C225 C226 . 1.390(3) ?
C225 H225 . 0.95 ?
C226 H226 . 0.95 ?
N1 O3 . 1.240(2) ?
N1 O2 . 1.256(2) ?
N1 O1 . 1.276(2) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
C116 C111 C112 C113 . -1.4(4)
P1 C111 C112 C113 . 176.95(19)
C111 C112 C113 C114 . -0.5(4)
C112 C113 C114 C115 . 1.9(4)
C113 C114 C115 C116 . -1.3(4)
C114 C115 C116 C111 . -0.6(4)
C112 C111 C116 C115 . 2.0(4)
P1 C111 C116 C115 . -176.4(2)
C126 C121 C122 C123 . -0.3(3)
P1 C121 C122 C123 . -179.09(18)
C121 C122 C123 C124 . 1.7(4)
C122 C123 C124 C125 . -1.2(4)
C123 C124 C125 C126 . -0.6(4)
C124 C125 C126 C121 . 1.9(4)
C122 C121 C126 C125 . -1.4(3)
P1 C121 C126 C125 . 177.23(18)
C216 C211 C212 C213 . -0.9(3)
P2 C211 C212 C213 . 177.25(17)
C211 C212 C213 C214 . 0.0(3)
C212 C213 C214 C215 . 1.3(4)
C213 C214 C215 C216 . -1.5(4)
C214 C215 C216 C211 . 0.6(4)
C212 C211 C216 C215 . 0.6(3)
P2 C211 C216 C215 . -177.38(18)
C226 C221 C222 C223 . 0.2(3)
P2 C221 C222 C223 . 178.90(18)
C221 C222 C223 C224 . -0.3(4)
C222 C223 C224 C225 . 0.0(4)
C223 C224 C225 C226 . 0.5(4)
C224 C225 C226 C221 . -0.6(3)
C222 C221 C226 C225 . 0.2(3)
P2 C221 C226 C225 . -178.50(17)
O11 C11 N11 C12 . -1.2(4)
O11 C11 N11 C13 . -179.3(3)
O3 N1 O1 Ag1 . 163.48(16)
O2 N1 O1 Ag1 . -15.5(2)
P2 Ag1 O1 N1 . 104.58(12)
P1 Ag1 O1 N1 . -61.97(13)
O11 Ag1 O1 N1 . -155.58(14)
N11 C11 O11 Ag1 . 179.59(19)
P2 Ag1 O11 C11 . 86.9(3)
P1 Ag1 O11 C11 . -129.6(3)
O1 Ag1 O11 C11 . -19.6(3)
C126 C121 P1 C111 . 103.80(19)
C122 C121 P1 C111 . -77.53(18)
C126 C121 P1 C1 . -4.1(2)
C122 C121 P1 C1 . 174.57(17)
C126 C121 P1 Ag1 . -126.14(17)
C122 C121 P1 Ag1 . 52.53(18)
C112 C111 P1 C121 . 113.25(19)
C116 C111 P1 C121 . -68.4(2)
C112 C111 P1 C1 . -137.66(18)
C116 C111 P1 C1 . 40.7(2)
C112 C111 P1 Ag1 . -17.5(2)
C116 C111 P1 Ag1 . 160.84(17)
C1 C1 P1 C121 2_666 177.02(19)
C1 C1 P1 C111 2_666 68.7(2)
C1 C1 P1 Ag1 2_666 -56.0(2)
P2 Ag1 P1 C121 . 75.71(8)
O1 Ag1 P1 C121 . -124.43(9)
O11 Ag1 P1 C121 . -39.34(10)
P2 Ag1 P1 C111 . -160.34(8)
O1 Ag1 P1 C111 . -0.48(9)
O11 Ag1 P1 C111 . 84.61(10)
P2 Ag1 P1 C1 . -43.76(8)
O1 Ag1 P1 C1 . 116.09(8)
O11 Ag1 P1 C1 . -158.81(9)
C222 C221 P2 C211 . 64.2(2)
C226 C221 P2 C211 . -117.10(17)
C222 C221 P2 C2 . -45.1(2)
C226 C221 P2 C2 . 133.60(17)
C222 C221 P2 Ag1 . -168.57(15)
C226 C221 P2 Ag1 . 10.14(19)
C212 C211 P2 C221 . 107.02(17)
C216 C211 P2 C221 . -74.9(2)
C212 C211 P2 C2 . -145.30(16)
C216 C211 P2 C2 . 32.8(2)
C212 C211 P2 Ag1 . -25.08(18)
C216 C211 P2 Ag1 . 152.98(17)
C2 C2 P2 C221 2_566 178.81(19)
C2 C2 P2 C211 2_566 68.4(2)
C2 C2 P2 Ag1 2_566 -52.1(2)
P1 Ag1 P2 C221 . 87.60(8)
O1 Ag1 P2 C221 . -72.65(9)
O11 Ag1 P2 C221 . -159.24(9)
P1 Ag1 P2 C211 . -147.72(7)
O1 Ag1 P2 C211 . 52.03(8)
O11 Ag1 P2 C211 . -34.55(9)
P1 Ag1 P2 C2 . -31.47(8)
O1 Ag1 P2 C2 . 168.29(8)
O11 Ag1 P2 C2 . 81.70(9)
O3 N1 O2 Ag1 . -166.20(18)
O1 N1 O2 Ag1 . 12.76(18)
P2 Ag1 O2 N1 . -106.69(11)
P1 Ag1 O2 N1 . 110.53(11)
O1 Ag1 O2 N1 . -7.85(11)
O11 Ag1 O2 N1 . 13.32(15)
