#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/64/2016410.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2016410
loop_
_publ_author_name
'Wang, Xin-Qiang'
'Yu, Wen-Tao'
'Xu, Dong'
'Fan, Jian-Dong'
'Zhang, Guang-Hui'
'Ren, Quan'
_publ_section_title
;
 Tetraphenylphosphonium
 bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III) acetone solvate
 and ethyltriphenylphosphonium
 bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III)
;
_journal_coeditor_code           SK3168
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m46
_journal_page_last               m49
_journal_paper_doi               10.1107/S010827010706074X
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '(C24 H20 P) [Au (C3 S5)2] , C3 H6 O'
_chemical_formula_moiety         'C24 H20 P + , C6 Au S10 - , C3 H6 O'
_chemical_formula_sum            'C33 H26 Au O P S10'
_chemical_formula_weight         987.07
_chemical_name_systematic
;
Tetraphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate(III)
acetone solvate
;
_space_group_IT_number           13
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yc'
_symmetry_space_group_name_H-M   'P 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 115.7720(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.4198(7)
_cell_length_b                   7.4511(2)
_cell_length_c                   23.1654(6)
_cell_measurement_reflns_used    6858
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.50
_cell_volume                     3795.78(18)
_computing_cell_refinement       'APEX2 (Bruker, 2005)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'APEX2 (Bruker, 2005)'
_computing_molecular_graphics    'SHELXTL (Bruker, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR97 (Altomare et al.,  1999)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0241
_diffrn_reflns_av_sigmaI/netI    0.0231
_diffrn_reflns_limit_h_max       27
_diffrn_reflns_limit_h_min       -31
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       30
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            33785
_diffrn_reflns_theta_full        27.51
_diffrn_reflns_theta_max         27.51
_diffrn_reflns_theta_min         0.93
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    4.495
_exptl_absorpt_correction_T_max  0.508
_exptl_absorpt_correction_T_min  0.379
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(APEX2; Bruker, 2005)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.727
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1944
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.623
_refine_diff_density_min         -0.438
_refine_ls_extinction_coef       0.00015(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 1997)'
_refine_ls_goodness_of_fit_ref   1.026
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     419
_refine_ls_number_reflns         8724
_refine_ls_number_restraints     14
_refine_ls_restrained_S_all      1.056
_refine_ls_R_factor_all          0.0304
_refine_ls_R_factor_gt           0.0226
_refine_ls_shift/su_max          0.004
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0246P)²+1.8915P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0496
_refine_ls_wR_factor_ref         0.0536
_reflns_number_gt                7545
_reflns_number_total             8724
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            sk3168.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      P2/c
_cod_database_code               2016410
_cod_database_fobs_code          2016410
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Au Au1 0.743045(4) 0.072091(14) 0.744125(4) 0.03323(4) Uani d . 1
C C1 0.61106(18) 0.5443(5) 0.54607(16) 0.0647(10) Uani d . 1
C C2 0.67440(12) 0.3955(4) 0.65743(13) 0.0381(6) Uani d . 1
C C3 0.67318(12) 0.2724(4) 0.61440(12) 0.0408(6) Uani d . 1
C C4 0.81844(13) -0.1314(4) 0.87232(13) 0.0436(7) Uani d . 1
C C5 0.81351(13) -0.2546(4) 0.82822(13) 0.0420(7) Uani d . 1
C C6 0.8809(2) -0.4073(5) 0.93658(17) 0.0773(13) Uani d . 1
C C7 0.50051(12) 0.1656(4) 0.68865(12) 0.0371(6) Uani d . 1
C C8 0.45587(15) 0.0332(4) 0.66528(15) 0.0501(8) Uani d . 1
H H8 0.4262 0.0264 0.6802 0.060 Uiso calc R 1
C C9 0.45560(16) -0.0872(4) 0.62025(15) 0.0557(8) Uani d . 1
H H9 0.4256 -0.1749 0.6046 0.067 Uiso calc R 1
C C10 0.49958(16) -0.0784(4) 0.59830(15) 0.0531(8) Uani d . 1
H H10 0.4991 -0.1597 0.5676 0.064 Uiso calc R 1
C C11 0.54409(15) 0.0500(5) 0.62151(16) 0.0545(8) Uani d . 1
H H11 0.5740 0.0545 0.6068 0.065 Uiso calc R 1
C C12 0.54496(13) 0.1734(4) 0.66678(14) 0.0453(7) Uani d . 1
H H12 0.5752 0.2606 0.6823 0.054 Uiso calc R 1
C C13 0.56529(12) 0.4570(4) 0.78121(13) 0.0377(6) Uani d . 1
C C14 0.60901(14) 0.4460(4) 0.84412(14) 0.0519(8) Uani d . 1
H H14 0.6069 0.3566 0.8711 0.062 Uiso calc R 1
C C15 0.65604(16) 0.5705(5) 0.86636(17) 0.0647(10) Uani d . 1
H H15 0.6853 0.5649 0.9087 0.078 Uiso calc R 1
C C16 0.65990(15) 0.7007(5) 0.82693(17) 0.0580(9) Uani d . 1
H H16 0.6921 0.7818 0.8423 0.070 Uiso calc R 1
C C17 0.61632(14) 0.7126(4) 0.76451(16) 0.0513(8) Uani d . 1
H H17 0.6190 0.8020 0.7378 0.062 Uiso calc R 1
C C18 0.56901(14) 0.5928(4) 0.74156(14) 0.0457(7) Uani d . 1
H H18 0.5394 0.6020 0.6995 0.055 Uiso calc R 1
C C19 0.93779(12) 0.5504(4) 0.70427(13) 0.0393(6) Uani d . 1
C C20 0.88291(14) 0.5617(5) 0.70767(17) 0.0561(9) Uani d . 1
H H20 0.8765 0.6514 0.7320 0.067 Uiso calc R 1
C C21 0.83756(17) 0.4391(6) 0.6748(2) 0.0745(12) Uani d . 1
H H21 0.8006 0.4461 0.6772 0.089 Uiso calc R 1
C C22 0.84676(17) 0.3076(5) 0.63892(18) 0.0700(11) Uani d . 1
H H22 0.8160 0.2254 0.6171 0.084 Uiso calc R 1
C C23 0.90077(16) 0.2956(5) 0.63477(16) 0.0587(9) Uani d . 1
H H23 0.9065 0.2067 0.6097 0.070 Uiso calc R 1
C C24 0.94674(15) 0.4154(4) 0.66771(15) 0.0510(8) Uani d . 1
H H24 0.9838 0.4062 0.6656 0.061 Uiso calc R 1
C C25 0.98150(12) 0.8390(4) 0.80145(12) 0.0384(6) Uani d . 1
C C26 0.93880(14) 0.9737(4) 0.77422(15) 0.0513(8) Uani d . 1
H H26 0.9198 0.9876 0.7299 0.062 Uiso calc R 1
C C27 0.92444(16) 1.0866(5) 0.81239(18) 0.0595(9) Uani d . 1
H H27 0.8955 1.1762 0.7938 0.071 Uiso calc R 1
C C28 0.95230(19) 1.0684(5) 0.87763(19) 0.0657(10) Uani d . 1
H H28 0.9421 1.1448 0.9032 0.079 Uiso calc R 1
C C29 0.9952(2) 0.9371(6) 0.90531(18) 0.0738(12) Uani d . 1
H H29 1.0145 0.9256 0.9497 0.089 Uiso calc R 1
C C30 1.00990(16) 0.8216(5) 0.86709(15) 0.0572(9) Uani d . 1
H H30 1.0389 0.7325 0.8859 0.069 Uiso calc R 1
P P1 0.5000 0.31188(14) 0.7500 0.0353(2) Uani d S 1
P P2 1.0000 0.69624(14) 0.7500 0.0360(2) Uani d S 1
S S1 0.56884(7) 0.6801(2) 0.48764(5) 0.1163(6) Uani d U 1
S S2 0.63706(4) 0.59766(11) 0.62603(4) 0.0564(2) Uani d . 1
S S3 0.63422(4) 0.33387(14) 0.53405(4) 0.0623(2) Uani d . 1
S S4 0.70838(4) 0.36335(10) 0.74012(3) 0.04252(17) Uani d . 1
S S5 0.70504(4) 0.05928(10) 0.63341(3) 0.04545(17) Uani d . 1
S S6 0.78624(4) 0.08266(10) 0.85538(3) 0.04876(19) Uani d . 1
S S7 0.77268(4) -0.22242(10) 0.74579(3) 0.04580(17) Uani d . 1
S S8 0.86143(5) -0.19546(14) 0.95187(4) 0.0709(3) Uani d . 1
S S9 0.84996(5) -0.45844(12) 0.85599(4) 0.0633(3) Uani d . 1
S S10 0.92384(9) -0.5475(2) 0.99244(6) 0.1455(8) Uani d U 1
O O1 0.8261(3) 0.0873(8) 1.0601(4) 0.218(3) Uani d . 1
C C31 0.7672(6) 0.3303(12) 1.0190(5) 0.369(11) Uani d D 1
H H31A 0.7706 0.3740 1.0594 0.553 Uiso calc R 1
H H31B 0.7271 0.3549 0.9862 0.553 Uiso calc R 1
H H31C 0.7968 0.3892 1.0086 0.553 Uiso calc R 1
C C32 0.7782(4) 0.1340(11) 1.0232(3) 0.160(4) Uani d D 1
C C33 0.7244(4) 0.0304(16) 0.9827(4) 0.274(8) Uani d D 1
H H33A 0.7335 -0.0954 0.9892 0.410 Uiso calc R 1
H H33B 0.7126 0.0599 0.9385 0.410 Uiso calc R 1
H H33C 0.6917 0.0586 0.9936 0.410 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
S7 Au1 S4 . . 177.20(3) y
S7 Au1 S5 . . 87.20(3) y
S4 Au1 S5 . . 91.76(3) y
S7 Au1 S6 . . 91.48(3) y
S4 Au1 S6 . . 89.68(3) y
S5 Au1 S6 . . 176.97(3) y
S1 C1 S2 . . 123.3(2) ?
S1 C1 S3 . . 123.8(2) ?
S2 C1 S3 . . 112.88(18) ?
C3 C2 S4 . . 124.6(2) ?
C3 C2 S2 . . 116.1(2) ?
S4 C2 S2 . . 119.30(16) ?
C2 C3 S5 . . 124.9(2) ?
C2 C3 S3 . . 116.0(2) ?
S5 C3 S3 . . 119.13(17) ?
C5 C4 S8 . . 115.5(2) ?
C5 C4 S6 . . 124.9(2) ?
S8 C4 S6 . . 119.53(18) ?
C4 C5 S9 . . 117.1(2) ?
C4 C5 S7 . . 124.0(2) ?
S9 C5 S7 . . 118.88(17) ?
S10 C6 S9 . . 122.9(2) ?
S10 C6 S8 . . 124.0(2) ?
S9 C6 S8 . . 113.16(19) ?
C12 C7 C8 . . 119.5(3) ?
C12 C7 P1 . . 122.7(2) ?
C8 C7 P1 . . 117.6(2) ?
C9 C8 C7 . . 120.1(3) ?
C9 C8 H8 . . 119.9 ?
C7 C8 H8 . . 119.9 ?
C8 C9 C10 . . 120.2(3) ?
C8 C9 H9 . . 119.9 ?
C10 C9 H9 . . 119.9 ?
C11 C10 C9 . . 120.1(3) ?
C11 C10 H10 . . 119.9 ?
C9 C10 H10 . . 119.9 ?
C10 C11 C12 . . 120.5(3) ?
C10 C11 H11 . . 119.7 ?
C12 C11 H11 . . 119.7 ?
C7 C12 C11 . . 119.5(3) ?
C7 C12 H12 . . 120.3 ?
C11 C12 H12 . . 120.3 ?
C14 C13 C18 . . 119.6(3) ?
C14 C13 P1 . . 122.1(2) ?
C18 C13 P1 . . 118.1(2) ?
C13 C14 C15 . . 119.1(3) ?
C13 C14 H14 . . 120.5 ?
C15 C14 H14 . . 120.5 ?
C16 C15 C14 . . 120.9(3) ?
C16 C15 H15 . . 119.6 ?
C14 C15 H15 . . 119.6 ?
C15 C16 C17 . . 120.2(3) ?
C15 C16 H16 . . 119.9 ?
C17 C16 H16 . . 119.9 ?
C18 C17 C16 . . 120.1(3) ?
C18 C17 H17 . . 119.9 ?
C16 C17 H17 . . 119.9 ?
C17 C18 C13 . . 120.1(3) ?
C17 C18 H18 . . 119.9 ?
C13 C18 H18 . . 119.9 ?
C20 C19 C24 . . 119.5(3) ?
C20 C19 P2 . . 121.6(2) ?
C24 C19 P2 . . 118.7(2) ?
C19 C20 C21 . . 119.7(3) ?
C19 C20 H20 . . 120.2 ?
C21 C20 H20 . . 120.2 ?
C22 C21 C20 . . 120.3(3) ?
C22 C21 H21 . . 119.8 ?
C20 C21 H21 . . 119.8 ?
C21 C22 C23 . . 120.6(3) ?
C21 C22 H22 . . 119.7 ?
C23 C22 H22 . . 119.7 ?
C22 C23 C24 . . 119.9(3) ?
C22 C23 H23 . . 120.1 ?
C24 C23 H23 . . 120.1 ?
C23 C24 C19 . . 120.0(3) ?
C23 C24 H24 . . 120.0 ?
C19 C24 H24 . . 120.0 ?
C30 C25 C26 . . 119.3(3) ?
C30 C25 P2 . . 121.8(2) ?
C26 C25 P2 . . 118.9(2) ?
C27 C26 C25 . . 120.2(3) ?
C27 C26 H26 . . 119.9 ?
C25 C26 H26 . . 119.9 ?
C28 C27 C26 . . 120.5(3) ?
C28 C27 H27 . . 119.8 ?
C26 C27 H27 . . 119.8 ?
C27 C28 C29 . . 119.9(3) ?
C27 C28 H28 . . 120.0 ?
C29 C28 H28 . . 120.0 ?
C28 C29 C30 . . 120.0(3) ?
C28 C29 H29 . . 120.0 ?
C30 C29 H29 . . 120.0 ?
C25 C30 C29 . . 120.0(3) ?
C25 C30 H30 . . 120.0 ?
C29 C30 H30 . . 120.0 ?
C7 P1 C7 . 2_656 105.24(18) ?
C7 P1 C13 . . 111.92(12) ?
C7 P1 C13 2_656 . 110.91(12) ?
C7 P1 C13 . 2_656 110.91(12) ?
C7 P1 C13 2_656 2_656 111.92(12) ?
C13 P1 C13 . 2_656 106.06(18) ?
C19 P2 C19 . 2_756 105.36(19) ?
C19 P2 C25 . . 110.98(13) ?
C19 P2 C25 2_756 . 111.10(12) ?
C19 P2 C25 . 2_756 111.10(12) ?
C19 P2 C25 2_756 2_756 110.98(13) ?
C25 P2 C25 . 2_756 107.36(19) ?
C1 S2 C2 . . 97.48(15) ?
C1 S3 C3 . . 97.53(15) ?
C2 S4 Au1 . . 99.44(10) ?
C3 S5 Au1 . . 99.35(9) ?
C4 S6 Au1 . . 99.27(10) ?
C5 S7 Au1 . . 100.09(10) ?
C6 S8 C4 . . 97.25(16) ?
C6 S9 C5 . . 96.93(16) ?
C32 C31 H31A . . 109.5 ?
C32 C31 H31B . . 109.5 ?
H31A C31 H31B . . 109.5 ?
C32 C31 H31C . . 109.5 ?
H31A C31 H31C . . 109.5 ?
H31B C31 H31C . . 109.5 ?
O1 C32 C33 . . 130.7(9) ?
O1 C32 C31 . . 116.1(10) ?
C33 C32 C31 . . 113.1(9) ?
C32 C33 H33A . . 109.5 ?
C32 C33 H33B . . 109.5 ?
H33A C33 H33B . . 109.5 ?
C32 C33 H33C . . 109.5 ?
H33A C33 H33C . . 109.5 ?
H33B C33 H33C . . 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Au1 S7 . 2.3057(8) y
Au1 S4 . 2.3166(7) y
Au1 S5 . 2.3191(7) y
Au1 S6 . 2.3233(7) y
C1 S1 . 1.645(3) y
C1 S2 . 1.723(4) y
C1 S3 . 1.730(4) y
C2 C3 . 1.345(4) y
C2 S4 . 1.742(3) y
C2 S2 . 1.747(3) y
C3 S5 . 1.739(3) y
C3 S3 . 1.743(3) y
C4 C5 . 1.340(4) y
C4 S8 . 1.745(3) y
C4 S6 . 1.746(3) y
C5 S9 . 1.736(3) y
C5 S7 . 1.744(3) y
C6 S10 . 1.639(4) y
C6 S9 . 1.725(4) y
C6 S8 . 1.729(4) y
C7 C12 . 1.384(4) ?
C7 C8 . 1.393(4) ?
C7 P1 . 1.795(3) ?
C8 C9 . 1.374(4) ?
C8 H8 . 0.9300 ?
C9 C10 . 1.375(5) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.370(5) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.388(4) ?
C11 H11 . 0.9300 ?
C12 H12 . 0.9300 ?
C13 C14 . 1.385(4) ?
C13 C18 . 1.396(4) ?
C13 P1 . 1.797(3) ?
C14 C15 . 1.389(4) ?
C14 H14 . 0.9300 ?
C15 C16 . 1.364(5) ?
C15 H15 . 0.9300 ?
C16 C17 . 1.376(5) ?
C16 H16 . 0.9300 ?
C17 C18 . 1.371(4) ?
C17 H17 . 0.9300 ?
C18 H18 . 0.9300 ?
C19 C20 . 1.379(4) ?
C19 C24 . 1.392(4) ?
C19 P2 . 1.792(3) ?
C20 C21 . 1.381(5) ?
C20 H20 . 0.9300 ?
C21 C22 . 1.366(5) ?
C21 H21 . 0.9300 ?
C22 C23 . 1.366(5) ?
C22 H22 . 0.9300 ?
C23 C24 . 1.376(4) ?
C23 H23 . 0.9300 ?
C24 H24 . 0.9300 ?
C25 C30 . 1.376(4) ?
C25 C26 . 1.386(4) ?
C25 P2 . 1.796(3) ?
C26 C27 . 1.372(4) ?
C26 H26 . 0.9300 ?
C27 C28 . 1.368(5) ?
C27 H27 . 0.9300 ?
C28 C29 . 1.372(5) ?
C28 H28 . 0.9300 ?
C29 C30 . 1.389(5) ?
C29 H29 . 0.9300 ?
C30 H30 . 0.9300 ?
P1 C7 2_656 1.795(3) ?
P1 C13 2_656 1.797(3) ?
P2 C19 2_756 1.792(3) ?
P2 C25 2_756 1.796(3) ?
O1 C32 . 1.162(8) ?
C31 C32 . 1.483(8) ?
C31 H31A . 0.9600 ?
C31 H31B . 0.9600 ?
C31 H31C . 0.9600 ?
C32 C33 . 1.460(8) ?
C33 H33A . 0.9600 ?
C33 H33B . 0.9600 ?
C33 H33C . 0.9600 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_4
_geom_torsion
S4 C2 C3 S5 . 0.2(4)
S2 C2 C3 S5 . -178.12(17)
S4 C2 C3 S3 . 178.02(16)
S2 C2 C3 S3 . -0.3(3)
S8 C4 C5 S9 . 0.1(4)
S6 C4 C5 S9 . 179.40(18)
S8 C4 C5 S7 . 179.68(17)
S6 C4 C5 S7 . -1.0(4)
C12 C7 C8 C9 . -0.8(5)
P1 C7 C8 C9 . -177.3(3)
C7 C8 C9 C10 . 0.4(5)
C8 C9 C10 C11 . 0.4(5)
C9 C10 C11 C12 . -0.7(5)
C8 C7 C12 C11 . 0.5(4)
P1 C7 C12 C11 . 176.8(2)
C10 C11 C12 C7 . 0.2(5)
C18 C13 C14 C15 . -0.4(5)
P1 C13 C14 C15 . -175.5(3)
C13 C14 C15 C16 . -0.8(5)
C14 C15 C16 C17 . 1.2(5)
C15 C16 C17 C18 . -0.4(5)
C16 C17 C18 C13 . -0.8(5)
C14 C13 C18 C17 . 1.2(4)
P1 C13 C18 C17 . 176.5(2)
C24 C19 C20 C21 . 0.0(5)
P2 C19 C20 C21 . -175.8(3)
C19 C20 C21 C22 . -0.3(6)
C20 C21 C22 C23 . -0.2(7)
C21 C22 C23 C24 . 0.9(6)
C22 C23 C24 C19 . -1.1(5)
C20 C19 C24 C23 . 0.7(5)
P2 C19 C24 C23 . 176.6(3)
C30 C25 C26 C27 . -1.0(5)
P2 C25 C26 C27 . -179.0(3)
C25 C26 C27 C28 . 0.4(5)
C26 C27 C28 C29 . 0.4(6)
C27 C28 C29 C30 . -0.7(6)
C26 C25 C30 C29 . 0.7(5)
P2 C25 C30 C29 . 178.6(3)
C28 C29 C30 C25 . 0.2(6)
C12 C7 P1 C7 2_656 -123.6(3)
C8 C7 P1 C7 2_656 52.7(2)
C12 C7 P1 C13 . -3.1(3)
C8 C7 P1 C13 . 173.3(2)
C12 C7 P1 C13 2_656 115.2(2)
C8 C7 P1 C13 2_656 -68.5(3)
C14 C13 P1 C7 . -115.0(3)
C18 C13 P1 C7 . 69.9(3)
C14 C13 P1 C7 2_656 2.3(3)
C18 C13 P1 C7 2_656 -172.9(2)
C14 C13 P1 C13 2_656 124.0(3)
C18 C13 P1 C13 2_656 -51.2(2)
C20 C19 P2 C19 2_756 124.0(3)
C24 C19 P2 C19 2_756 -51.8(2)
C20 C19 P2 C25 . 3.7(3)
C24 C19 P2 C25 . -172.2(2)
C20 C19 P2 C25 2_756 -115.7(3)
C24 C19 P2 C25 2_756 68.5(3)
C30 C25 P2 C19 . 112.1(3)
C26 C25 P2 C19 . -70.0(3)
C30 C25 P2 C19 2_756 -4.8(3)
C26 C25 P2 C19 2_756 173.1(2)
C30 C25 P2 C25 2_756 -126.3(3)
C26 C25 P2 C25 2_756 51.6(2)
S1 C1 S2 C2 . 178.1(3)
S3 C1 S2 C2 . -2.0(3)
C3 C2 S2 C1 . 1.4(3)
S4 C2 S2 C1 . -177.0(2)
S1 C1 S3 C3 . -178.2(3)
S2 C1 S3 C3 . 1.9(3)
C2 C3 S3 C1 . -1.0(3)
S5 C3 S3 C1 . 177.0(2)
C3 C2 S4 Au1 . -0.6(3)
S2 C2 S4 Au1 . 177.61(15)
S5 Au1 S4 C2 . 0.63(10)
S6 Au1 S4 C2 . 177.97(10)
C2 C3 S5 Au1 . 0.4(3)
S3 C3 S5 Au1 . -177.39(15)
S7 Au1 S5 C3 . 176.82(10)
S4 Au1 S5 C3 . -0.58(10)
C5 C4 S6 Au1 . -2.3(3)
S8 C4 S6 Au1 . 176.91(16)
S7 Au1 S6 C4 . 3.42(11)
S4 Au1 S6 C4 . -179.13(11)
C4 C5 S7 Au1 . 3.8(3)
S9 C5 S7 Au1 . -176.69(15)
S5 Au1 S7 C5 . 173.48(11)
S6 Au1 S7 C5 . -3.80(11)
S10 C6 S8 C4 . 179.1(3)
S9 C6 S8 C4 . -1.5(3)
C5 C4 S8 C6 . 0.8(3)
S6 C4 S8 C6 . -178.5(2)
S10 C6 S9 C5 . -179.1(3)
S8 C6 S9 C5 . 1.5(3)
C4 C5 S9 C6 . -1.0(3)
S7 C5 S9 C6 . 179.4(2)
