#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/74/2017409.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2017409
loop_
_publ_author_name
'Dols, Thomas S.'
'Spaniol, Thomas P.'
'Okuda, Jun'
_publ_section_title
;
 Titanium complexes with sulfur-linked bis(phenolate) ligands
;
_journal_coeditor_code           SK3350
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m443
_journal_page_last               m446
_journal_paper_doi               10.1107/S0108270109042280
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Ti (C18 H18 O2 S2) Cl2]'
_chemical_formula_moiety         'C18 H18 Cl2 O2 S2 Ti'
_chemical_formula_sum            'C18 H18 Cl2 O2 S2 Ti'
_chemical_formula_weight         449.24
_chemical_name_systematic
dichlorido{2,2'-[cyclohexane-1,2-diylbis(sulfanediyl)]diphenolato}titanium(IV)
_space_group_IT_number           14
_space_group_name_Hall           '-P 2yn'
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 104.195(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.4627(7)
_cell_length_b                   16.8985(4)
_cell_length_c                   12.0810(11)
_cell_measurement_reflns_used    82760
_cell_measurement_temperature    100(2)
_cell_measurement_theta_max      36.32
_cell_measurement_theta_min      2.91
_cell_volume                     1872.8(2)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2003)'
_computing_data_reduction        'SAINT (Bruker, 2001)'
_computing_molecular_graphics    'ORTEP3 (Farrugia, 1997)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      100(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0532
_diffrn_reflns_av_sigmaI/netI    0.0262
_diffrn_reflns_limit_h_max       22
_diffrn_reflns_limit_h_min       -22
_diffrn_reflns_limit_k_max       41
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       29
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            257682
_diffrn_reflns_theta_full        60.00
_diffrn_reflns_theta_max         60.00
_diffrn_reflns_theta_min         2.74
_exptl_absorpt_coefficient_mu    0.975
_exptl_absorpt_correction_T_max  0.8441
_exptl_absorpt_correction_T_min  0.7586
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(MULABS in PLATON; Spek, 2009)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.593
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       fragment
_exptl_crystal_F_000             920
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.841
_refine_diff_density_min         -0.727
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.239
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         28176
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.239
_refine_ls_R_factor_all          0.0686
_refine_ls_R_factor_gt           0.0490
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
;calc w=1/[σ\^2\^(Fo\^2\^)+(0.0269P)\^2\^+0.5527P] where
 P=(Fo\^2\^+2Fc\^2\^)/3
;
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0916
_refine_ls_wR_factor_ref         0.0979
_reflns_number_gt                22536
_reflns_number_total             28176
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            sk3350.cif
_cod_data_source_block           IIa
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2017409
_cod_database_fobs_code          2017409
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ti Ti1 0.391941(11) 0.404359(6) 0.177709(8) 0.010050(10) Uani d . 1 . .
Cl Cl1 0.45087(2) 0.337295(10) 0.033394(14) 0.01702(3) Uani d . 1 . .
Cl Cl2 0.216452(18) 0.330863(10) 0.224790(16) 0.01741(3) Uani d . 1 . .
S S1 0.362857(16) 0.507412(9) 0.333419(12) 0.01013(2) Uani d . 1 . .
S S2 0.603073(17) 0.501657(8) 0.167314(12) 0.01033(2) Uani d . 1 . .
O O1 0.26987(5) 0.48047(3) 0.09177(4) 0.01341(6) Uani d . 1 . .
O O2 0.54628(5) 0.36568(3) 0.29468(4) 0.01151(6) Uani d . 1 . .
C C1 0.19830(6) 0.54178(3) 0.12310(5) 0.01175(7) Uani d . 1 . .
C C2 0.22848(6) 0.56395(3) 0.23886(5) 0.01125(7) Uani d . 1 . .
C C3 0.15042(7) 0.62488(4) 0.27487(6) 0.01427(8) Uani d . 1 . .
H H3 0.1707 0.6390 0.3533 0.017 Uiso calc R 1 . .
C C4 0.04283(7) 0.66467(4) 0.19517(7) 0.01665(10) Uani d . 1 . .
H H4 -0.0100 0.7066 0.2188 0.020 Uiso calc R 1 . .
C C5 0.01283(7) 0.64277(4) 0.08041(7) 0.01740(10) Uani d . 1 . .
H H5 -0.0619 0.6695 0.0265 0.021 Uiso calc R 1 . .
C C6 0.09026(7) 0.58249(4) 0.04333(6) 0.01548(9) Uani d . 1 . .
H H6 0.0701 0.5691 -0.0353 0.019 Uiso calc R 1 . .
C C7 0.52787(6) 0.56925(3) 0.35809(4) 0.00966(6) Uani d . 1 . .
H H7 0.6094 0.5376 0.4063 0.012 Uiso calc R 1 . .
C C8 0.57159(6) 0.58972(3) 0.24800(4) 0.00953(6) Uani d . 1 . .
H H8 0.4889 0.6198 0.1984 0.011 Uiso calc R 1 . .
C C9 0.70609(6) 0.64374(4) 0.27085(5) 0.01288(7) Uani d . 1 . .
H H9A 0.7921 0.6139 0.3141 0.015 Uiso calc R 1 . .
H H9B 0.7253 0.6600 0.1972 0.015 Uiso calc R 1 . .
C C10 0.68506(7) 0.71749(4) 0.33840(6) 0.01612(9) Uani d . 1 . .
H H10A 0.7750 0.7498 0.3545 0.019 Uiso calc R 1 . .
H H10B 0.6045 0.7499 0.2927 0.019 Uiso calc R 1 . .
C C11 0.64989(7) 0.69342(4) 0.45034(6) 0.01599(9) Uani d . 1 . .
H H11A 0.6368 0.7414 0.4939 0.019 Uiso calc R 1 . .
H H11B 0.7320 0.6625 0.4971 0.019 Uiso calc R 1 . .
C C12 0.51054(7) 0.64357(4) 0.42650(5) 0.01285(7) Uani d . 1 . .
H H12A 0.4276 0.6754 0.3829 0.015 Uiso calc R 1 . .
H H12B 0.4891 0.6279 0.4997 0.015 Uiso calc R 1 . .
C C13 0.73737(6) 0.44920(3) 0.26808(5) 0.01115(7) Uani d . 1 . .
C C14 0.68789(6) 0.38515(3) 0.32288(5) 0.01003(6) Uani d . 1 . .
C C15 0.78821(6) 0.34152(4) 0.40452(5) 0.01281(7) Uani d . 1 . .
H H15 0.7562 0.2983 0.4423 0.015 Uiso calc R 1 . .
C C16 0.93511(7) 0.36186(4) 0.43007(7) 0.01683(10) Uani d . 1 . .
H H16 1.0029 0.3326 0.4863 0.020 Uiso calc R 1 . .
C C17 0.98442(7) 0.42461(5) 0.37431(8) 0.01889(11) Uani d . 1 . .
H H17 1.0851 0.4379 0.3926 0.023 Uiso calc R 1 . .
C C18 0.88586(7) 0.46771(4) 0.29187(7) 0.01576(9) Uani d . 1 . .
H H18 0.9192 0.5094 0.2520 0.019 Uiso calc R 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ti Ti 0.2776 0.4457 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O1 Ti1 O2 . . 156.60(2) ?
O1 Ti1 Cl2 . . 97.257(18) ?
O2 Ti1 Cl2 . . 95.919(16) ?
O1 Ti1 Cl1 . . 98.778(17) ?
O2 Ti1 Cl1 . . 96.440(17) ?
Cl2 Ti1 Cl1 . . 104.745(9) ?
O1 Ti1 S2 . . 85.172(18) ?
O2 Ti1 S2 . . 78.060(15) ?
Cl2 Ti1 S2 . . 167.716(8) ?
Cl1 Ti1 S2 . . 86.693(8) ?
O1 Ti1 S1 . . 77.416(16) ?
O2 Ti1 S1 . . 83.735(16) ?
Cl2 Ti1 S1 . . 88.369(8) ?
Cl1 Ti1 S1 . . 166.765(8) ?
S2 Ti1 S1 . . 80.384(7) ?
C13 S2 C8 . . 102.88(3) ?
C13 S2 Ti1 . . 94.61(2) ?
C8 S2 Ti1 . . 104.946(18) ?
C2 S1 C7 . . 104.18(3) ?
C2 S1 Ti1 . . 94.63(2) ?
C7 S1 Ti1 . . 104.983(18) ?
C14 O2 Ti1 . . 130.45(4) ?
C1 O1 Ti1 . . 131.45(4) ?
O2 C14 C15 . . 120.87(5) ?
O2 C14 C13 . . 119.76(5) ?
C15 C14 C13 . . 119.36(5) ?
C18 C13 C14 . . 120.57(5) ?
C18 C13 S2 . . 123.07(5) ?
C14 C13 S2 . . 116.34(4) ?
C17 C18 C13 . . 119.55(6) ?
C17 C18 H18 . . 120.2 ?
C13 C18 H18 . . 120.2 ?
C18 C17 C16 . . 119.87(6) ?
C18 C17 H17 . . 120.1 ?
C16 C17 H17 . . 120.1 ?
C15 C16 C17 . . 120.96(6) ?
C15 C16 H16 . . 119.5 ?
C17 C16 H16 . . 119.5 ?
C16 C15 C14 . . 119.63(6) ?
C16 C15 H15 . . 120.2 ?
C14 C15 H15 . . 120.2 ?
C7 C8 C9 . . 111.59(4) ?
C7 C8 S2 . . 113.04(4) ?
C9 C8 S2 . . 109.93(4) ?
C7 C8 H8 . . 107.3 ?
C9 C8 H8 . . 107.3 ?
S2 C8 H8 . . 107.3 ?
C8 C7 C12 . . 111.80(5) ?
C8 C7 S1 . . 112.82(4) ?
C12 C7 S1 . . 110.70(4) ?
C8 C7 H7 . . 107.1 ?
C12 C7 H7 . . 107.1 ?
S1 C7 H7 . . 107.1 ?
C11 C12 C7 . . 110.54(5) ?
C11 C12 H12A . . 109.5 ?
C7 C12 H12A . . 109.5 ?
C11 C12 H12B . . 109.5 ?
C7 C12 H12B . . 109.5 ?
H12A C12 H12B . . 108.1 ?
C10 C11 C12 . . 110.18(5) ?
C10 C11 H11A . . 109.6 ?
C12 C11 H11A . . 109.6 ?
C10 C11 H11B . . 109.6 ?
C12 C11 H11B . . 109.6 ?
H11A C11 H11B . . 108.1 ?
C11 C10 C9 . . 109.95(5) ?
C11 C10 H10A . . 109.7 ?
C9 C10 H10A . . 109.7 ?
C11 C10 H10B . . 109.7 ?
C9 C10 H10B . . 109.7 ?
H10A C10 H10B . . 108.2 ?
C10 C9 C8 . . 111.71(5) ?
C10 C9 H9A . . 109.3 ?
C8 C9 H9A . . 109.3 ?
C10 C9 H9B . . 109.3 ?
C8 C9 H9B . . 109.3 ?
H9A C9 H9B . . 107.9 ?
C3 C2 C1 . . 120.76(5) ?
C3 C2 S1 . . 123.28(5) ?
C1 C2 S1 . . 115.90(4) ?
O1 C1 C6 . . 121.24(6) ?
O1 C1 C2 . . 119.48(5) ?
C6 C1 C2 . . 119.24(6) ?
C5 C6 C1 . . 119.40(6) ?
C5 C6 H6 . . 120.3 ?
C1 C6 H6 . . 120.3 ?
C6 C5 C4 . . 121.28(6) ?
C6 C5 H5 . . 119.4 ?
C4 C5 H5 . . 119.4 ?
C3 C4 C5 . . 119.71(6) ?
C3 C4 H4 . . 120.1 ?
C5 C4 H4 . . 120.1 ?
C4 C3 C2 . . 119.58(6) ?
C4 C3 H3 . . 120.2 ?
C2 C3 H3 . . 120.2 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ti1 O1 . 1.8649(5) ?
Ti1 O2 . 1.8828(5) ?
Ti1 Cl2 . 2.2554(2) ?
Ti1 Cl1 . 2.2609(2) ?
Ti1 S2 . 2.6141(2) ?
Ti1 S1 . 2.6270(2) ?
S2 C13 . 1.7675(6) ?
S2 C8 . 1.8428(5) ?
S1 C2 . 1.7670(6) ?
S1 C7 . 1.8413(6) ?
O2 C14 . 1.3401(7) ?
O1 C1 . 1.3421(8) ?
C14 C15 . 1.3993(8) ?
C14 C13 . 1.4076(8) ?
C13 C18 . 1.3988(8) ?
C18 C17 . 1.3916(10) ?
C18 H18 . 0.9500 ?
C17 C16 . 1.3965(10) ?
C17 H17 . 0.9500 ?
C16 C15 . 1.3912(9) ?
C16 H16 . 0.9500 ?
C15 H15 . 0.9500 ?
C8 C7 . 1.5264(7) ?
C8 C9 . 1.5352(8) ?
C8 H8 . 1.0000 ?
C7 C12 . 1.5341(8) ?
C7 H7 . 1.0000 ?
C12 C11 . 1.5314(9) ?
C12 H12A . 0.9900 ?
C12 H12B . 0.9900 ?
C11 C10 . 1.5249(11) ?
C11 H11A . 0.9900 ?
C11 H11B . 0.9900 ?
C10 C9 . 1.5293(9) ?
C10 H10A . 0.9900 ?
C10 H10B . 0.9900 ?
C9 H9A . 0.9900 ?
C9 H9B . 0.9900 ?
C2 C3 . 1.3973(8) ?
C2 C1 . 1.4078(8) ?
C1 C6 . 1.4014(8) ?
C6 C5 . 1.3914(10) ?
C6 H6 . 0.9500 ?
C5 C4 . 1.3952(12) ?
C5 H5 . 0.9500 ?
C4 C3 . 1.3911(10) ?
C4 H4 . 0.9500 ?
C3 H3 . 0.9500 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
O1 Ti1 S2 C13 . . . . 170.16(2) ?
O2 Ti1 S2 C13 . . . . 6.57(2) ?
Cl2 Ti1 S2 C13 . . . . 68.16(4) ?
Cl1 Ti1 S2 C13 . . . . -90.73(2) ?
S1 Ti1 S2 C13 . . . . 92.13(2) ?
O1 Ti1 S2 C8 . . . . 65.51(2) ?
O2 Ti1 S2 C8 . . . . -98.09(2) ?
Cl2 Ti1 S2 C8 . . . . -36.49(4) ?
Cl1 Ti1 S2 C8 . . . . 164.615(18) ?
S1 Ti1 S2 C8 . . . . -12.519(18) ?
O1 Ti1 S1 C2 . . . . 7.49(3) ?
O2 Ti1 S1 C2 . . . . 173.55(2) ?
Cl2 Ti1 S1 C2 . . . . -90.32(2) ?
Cl1 Ti1 S1 C2 . . . . 82.05(4) ?
S2 Ti1 S1 C2 . . . . 94.65(2) ?
O1 Ti1 S1 C7 . . . . -98.54(2) ?
O2 Ti1 S1 C7 . . . . 67.52(2) ?
Cl2 Ti1 S1 C7 . . . . 163.655(18) ?
Cl1 Ti1 S1 C7 . . . . -23.98(4) ?
S2 Ti1 S1 C7 . . . . -11.383(18) ?
O1 Ti1 O2 C14 . . . . -53.67(9) ?
Cl2 Ti1 O2 C14 . . . . -177.69(5) ?
Cl1 Ti1 O2 C14 . . . . 76.70(5) ?
S2 Ti1 O2 C14 . . . . -8.53(5) ?
S1 Ti1 O2 C14 . . . . -89.99(5) ?
O2 Ti1 O1 C1 . . . . -48.06(9) ?
Cl2 Ti1 O1 C1 . . . . 75.73(6) ?
Cl1 Ti1 O1 C1 . . . . -178.05(5) ?
S2 Ti1 O1 C1 . . . . -92.16(6) ?
S1 Ti1 O1 C1 . . . . -10.95(5) ?
Ti1 O2 C14 C15 . . . . -171.68(4) ?
Ti1 O2 C14 C13 . . . . 6.91(8) ?
O2 C14 C13 C18 . . . . -176.49(6) ?
C15 C14 C13 C18 . . . . 2.12(9) ?
O2 C14 C13 S2 . . . . 2.04(7) ?
C15 C14 C13 S2 . . . . -179.35(5) ?
C8 S2 C13 C18 . . . . -81.11(6) ?
Ti1 S2 C13 C18 . . . . 172.40(5) ?
C8 S2 C13 C14 . . . . 100.40(5) ?
Ti1 S2 C13 C14 . . . . -6.09(4) ?
C14 C13 C18 C17 . . . . -2.99(10) ?
S2 C13 C18 C17 . . . . 178.58(6) ?
C13 C18 C17 C16 . . . . 1.93(12) ?
C18 C17 C16 C15 . . . . -0.02(12) ?
C17 C16 C15 C14 . . . . -0.85(11) ?
O2 C14 C15 C16 . . . . 178.40(6) ?
C13 C14 C15 C16 . . . . -0.19(9) ?
C13 S2 C8 C7 . . . . -56.25(4) ?
Ti1 S2 C8 C7 . . . . 42.16(4) ?
C13 S2 C8 C9 . . . . 69.17(4) ?
Ti1 S2 C8 C9 . . . . 167.58(3) ?
C9 C8 C7 C12 . . . . 52.39(6) ?
S2 C8 C7 C12 . . . . 176.90(4) ?
C9 C8 C7 S1 . . . . 177.93(4) ?
S2 C8 C7 S1 . . . . -57.55(4) ?
C2 S1 C7 C8 . . . . -57.88(4) ?
Ti1 S1 C7 C8 . . . . 40.96(4) ?
C2 S1 C7 C12 . . . . 68.26(4) ?
Ti1 S1 C7 C12 . . . . 167.10(3) ?
C8 C7 C12 C11 . . . . -55.21(6) ?
S1 C7 C12 C11 . . . . 178.08(4) ?
C7 C12 C11 C10 . . . . 58.77(7) ?
C12 C11 C10 C9 . . . . -59.51(7) ?
C11 C10 C9 C8 . . . . 56.91(7) ?
C7 C8 C9 C10 . . . . -53.41(7) ?
S2 C8 C9 C10 . . . . -179.65(4) ?
C7 S1 C2 C3 . . . . -82.14(5) ?
Ti1 S1 C2 C3 . . . . 171.13(5) ?
C7 S1 C2 C1 . . . . 100.72(5) ?
Ti1 S1 C2 C1 . . . . -6.02(4) ?
Ti1 O1 C1 C6 . . . . -167.58(5) ?
Ti1 O1 C1 C2 . . . . 10.15(9) ?
C3 C2 C1 O1 . . . . -176.67(6) ?
S1 C2 C1 O1 . . . . 0.55(7) ?
C3 C2 C1 C6 . . . . 1.10(9) ?
S1 C2 C1 C6 . . . . 178.32(5) ?
O1 C1 C6 C5 . . . . 176.31(6) ?
C2 C1 C6 C5 . . . . -1.42(9) ?
C1 C6 C5 C4 . . . . 1.43(10) ?
C6 C5 C4 C3 . . . . -1.08(10) ?
C5 C4 C3 C2 . . . . 0.73(10) ?
C1 C2 C3 C4 . . . . -0.76(9) ?
S1 C2 C3 C4 . . . . -177.77(5) ?
