#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/79/2017994.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2017994
loop_
_publ_author_name
'Fang, Chao'
'Ma, Jian-Ping'
'Wei, Sui'
'Dong, Yu-Bin'
_publ_section_title
;
 1,1'-[(Ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-2,3-dione)
 (L) and a novel [Ag₂L₂]²⁺ metallocycle based on
 coordination-driven Ag---O and Ag---π bonds
;
_journal_coeditor_code           SQ3280
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              m35
_journal_page_last               m38
_journal_paper_doi               10.1107/S0108270110054697
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          '[Ag2 (C32 H24 N2 O6)2] [Sb F6]2'
_chemical_formula_moiety         'C64 H48 Ag2 N4 O12 2+, 2(F6 Sb -)'
_chemical_formula_sum            'C64 H48 Ag2 F12 N4 O12 Sb2'
_chemical_formula_weight         1752.30
_chemical_name_systematic
;
bis{μ-1,1'-[(ethane-1,2-diyldioxy)di-o-phenylene]bis(indoline-
2,3-dione)}disilver(I) bis(hexafluoridoantimonate)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                111.121(3)
_cell_angle_beta                 91.073(3)
_cell_angle_gamma                100.819(3)
_cell_formula_units_Z            1
_cell_length_a                   10.193(2)
_cell_length_b                   11.594(3)
_cell_length_c                   14.220(3)
_cell_measurement_reflns_used    2230
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      21.959
_cell_measurement_theta_min      2.498
_cell_volume                     1532.9(6)
_computing_cell_refinement       'SMART (Bruker, 2003)'
_computing_data_collection       'SMART (Bruker, 2003)'
_computing_data_reduction        'SAINT (Bruker, 2003)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.981
_diffrn_measured_fraction_theta_max 0.981
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0236
_diffrn_reflns_av_sigmaI/netI    0.0549
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            8087
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         1.54
_exptl_absorpt_coefficient_mu    1.606
_exptl_absorpt_correction_T_max  0.8559
_exptl_absorpt_correction_T_min  0.6445
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2003)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.898
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             860
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.065
_refine_diff_density_min         -1.019
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     481
_refine_ls_number_reflns         5593
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0699
_refine_ls_R_factor_gt           0.0525
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0582P)²+1.8707P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1238
_refine_ls_wR_factor_ref         0.1342
_reflns_number_gt                4279
_reflns_number_total             5593
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            sq3280.cif
_cod_data_source_block           II
_cod_original_cell_volume        1533.0(6)
_cod_database_code               2017994
_cod_database_fobs_code          2017994
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag1 -0.20269(7) 0.35357(5) 0.42128(4) 0.0796(2) Uani d . 1 . .
C C1 0.3205(6) 0.4053(6) 0.4483(4) 0.0485(13) Uani d . 1 . .
C C2 0.3631(5) 0.2907(5) 0.3880(4) 0.0462(13) Uani d . 1 . .
C C3 0.4572(6) 0.2677(6) 0.3178(5) 0.0564(15) Uani d . 1 . .
H H3 0.5081 0.3334 0.3029 0.068 Uiso calc R 1 . .
C C4 0.4733(6) 0.1456(7) 0.2707(5) 0.0652(18) Uani d . 1 . .
H H4 0.5343 0.1279 0.2223 0.078 Uiso calc R 1 . .
C C5 0.3994(7) 0.0490(7) 0.2948(6) 0.072(2) Uani d . 1 . .
H H5 0.4129 -0.0328 0.2628 0.086 Uiso calc R 1 . .
C C6 0.3050(6) 0.0708(6) 0.3658(5) 0.0637(17) Uani d . 1 . .
H H6 0.2558 0.0054 0.3818 0.076 Uiso calc R 1 . .
C C7 0.2882(6) 0.1932(5) 0.4109(4) 0.0490(13) Uani d . 1 . .
C C8 0.2091(6) 0.3630(5) 0.5067(4) 0.0474(13) Uani d . 1 . .
C C9 0.1080(6) 0.1641(6) 0.5282(4) 0.0538(15) Uani d . 1 . .
H H9A 0.1402 0.1903 0.5989 0.065 Uiso calc R 1 . .
H H9B 0.1114 0.0757 0.4950 0.065 Uiso calc R 1 . .
C C10 -0.0341(6) 0.1780(5) 0.5215(4) 0.0489(13) Uani d . 1 . .
C C11 -0.1097(6) 0.1270(5) 0.4280(4) 0.0457(13) Uani d . 1 . .
C C12 -0.2450(6) 0.1377(6) 0.4212(5) 0.0545(15) Uani d . 1 . .
H H12 -0.3059 0.0717 0.3659 0.065 Uiso calc R 1 . .
C C13 -0.3004(7) 0.2012(6) 0.5085(6) 0.0663(18) Uani d . 1 . .
H H13 -0.3981 0.1807 0.5084 0.080 Uiso calc R 1 . .
C C14 -0.2259(8) 0.2535(7) 0.6004(6) 0.079(2) Uani d . 1 . .
H H14 -0.2633 0.2979 0.6582 0.095 Uiso calc R 1 . .
C C15 -0.0950(7) 0.2398(6) 0.6064(5) 0.0670(18) Uani d . 1 . .
H H15 -0.0458 0.2729 0.6694 0.080 Uiso calc R 1 . .
C C16 -0.1128(6) 0.0250(6) 0.2483(4) 0.0520(14) Uani d . 1 . .
H H16A -0.1530 0.0908 0.2403 0.062 Uiso calc R 1 . .
H H16B -0.1831 -0.0491 0.2367 0.062 Uiso calc R 1 . .
C C17 -0.0094(6) -0.0064(5) 0.1752(4) 0.0512(14) Uani d . 1 . .
H H17A 0.0473 -0.0537 0.1952 0.061 Uiso calc R 1 . .
H H17B -0.0525 -0.0576 0.1078 0.061 Uiso calc R 1 . .
C C18 0.1676(5) 0.1032(5) 0.1116(4) 0.0424(12) Uani d . 1 . .
C C19 0.1988(6) -0.0095(5) 0.0491(4) 0.0516(14) Uani d . 1 . .
H H19 0.1500 -0.0863 0.0481 0.062 Uiso calc R 1 . .
C C20 0.3029(7) -0.0071(6) -0.0117(5) 0.0622(17) Uani d . 1 . .
H H20 0.3266 -0.0822 -0.0513 0.075 Uiso calc R 1 . .
C C21 0.3712(7) 0.1053(7) -0.0139(5) 0.0643(17) Uani d . 1 . .
H H21 0.4388 0.1064 -0.0567 0.077 Uiso calc R 1 . .
C C22 0.3393(6) 0.2162(6) 0.0475(5) 0.0540(15) Uani d . 1 . .
H H22 0.3871 0.2924 0.0465 0.065 Uiso calc R 1 . .
C C23 0.2377(5) 0.2176(5) 0.1108(4) 0.0429(12) Uani d . 1 . .
C C24 0.2107(6) 0.3421(5) 0.1799(4) 0.0499(14) Uani d . 1 . .
H H24A 0.2366 0.3539 0.2493 0.060 Uiso calc R 1 . .
H H24B 0.2666 0.4095 0.1648 0.060 Uiso calc R 1 . .
C C25 -0.0144(6) 0.3522(5) 0.2435(4) 0.0460(13) Uani d . 1 . .
C C26 -0.1544(6) 0.3407(5) 0.1955(4) 0.0483(13) Uani d . 1 . .
C C27 -0.1344(5) 0.3430(5) 0.0945(4) 0.0458(13) Uani d . 1 . .
C C28 0.0010(5) 0.3467(4) 0.0833(4) 0.0407(12) Uani d . 1 . .
C C29 0.0543(6) 0.3441(5) -0.0062(4) 0.0500(14) Uani d . 1 . .
H H29 0.1450 0.3466 -0.0141 0.060 Uiso calc R 1 . .
C C30 -0.0357(7) 0.3376(6) -0.0835(5) 0.0612(17) Uani d . 1 . .
H H30 -0.0037 0.3350 -0.1449 0.073 Uiso calc R 1 . .
C C31 -0.1695(8) 0.3348(6) -0.0733(5) 0.0680(19) Uani d . 1 . .
H H31 -0.2259 0.3308 -0.1271 0.082 Uiso calc R 1 . .
C C32 -0.2207(6) 0.3381(5) 0.0165(5) 0.0574(15) Uani d . 1 . .
H H32 -0.3113 0.3370 0.0244 0.069 Uiso calc R 1 . .
N N1 0.1959(4) 0.2378(4) 0.4823(3) 0.0442(10) Uani d . 1 . .
N N2 0.0707(4) 0.3528(4) 0.1717(3) 0.0439(10) Uani d . 1 . .
O O1 0.3549(5) 0.5140(4) 0.4556(3) 0.0641(11) Uani d . 1 . .
O O2 0.1461(5) 0.4326(4) 0.5649(3) 0.0619(11) Uani d . 1 . .
O O3 -0.0450(4) 0.0677(4) 0.3484(3) 0.0510(9) Uani d . 1 . .
O O4 0.0687(4) 0.1091(3) 0.1757(3) 0.0493(9) Uani d . 1 . .
O O5 0.0114(4) 0.3543(4) 0.3278(3) 0.0572(11) Uani d . 1 . .
O O6 -0.2563(4) 0.3242(4) 0.2363(3) 0.0633(11) Uani d . 1 . .
Sb Sb1 0.58932(4) 0.65652(4) 0.22306(3) 0.05775(17) Uani d D 1 . .
F F1 0.5908(17) 0.557(2) 0.0941(13) 0.173(9) Uani d P 0.50 A 1
F F2 0.553(3) 0.773(3) 0.1718(17) 0.213(8) Uani d P 0.50 A 1
F F3 0.7705(10) 0.7206(18) 0.225(2) 0.141(8) Uani d PD 0.50 A 1
F F4 0.5995(16) 0.777(2) 0.3467(10) 0.154(8) Uani d PD 0.50 A 1
F F5 0.625(2) 0.551(3) 0.273(3) 0.224(10) Uani d P 0.50 A 1
F F6 0.4088(10) 0.645(3) 0.212(3) 0.170(12) Uani d PD 0.50 A 1
F F3' 0.7694(8) 0.6482(18) 0.2339(17) 0.132(8) Uani d PD 0.50 A 2
F F4' 0.606(3) 0.8212(9) 0.258(3) 0.267(16) Uani d PD 0.50 A 2
F F1' 0.5596(15) 0.4808(10) 0.176(2) 0.154(7) Uani d P 0.50 A 2
F F5' 0.5852(15) 0.656(4) 0.3504(12) 0.191(12) Uani d P 0.50 A 2
F F2' 0.601(3) 0.642(3) 0.0948(17) 0.213(8) Uani d P 0.50 A 2
F F6' 0.4072(7) 0.615(2) 0.219(2) 0.112(7) Uani d PD 0.50 A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O2 Ag1 C12 2_566 . 174.39(18) ?
O2 Ag1 O6 2_566 . 80.32(14) ?
C12 Ag1 O6 . . 104.62(18) ?
O2 Ag1 C13 2_566 . 145.85(19) ?
C12 Ag1 C13 . . 31.9(2) ?
O6 Ag1 C13 . . 126.5(2) ?
O2 Ag1 O5 2_566 . 78.73(14) ?
C12 Ag1 O5 . . 100.40(16) ?
O6 Ag1 O5 . . 68.87(13) ?
C13 Ag1 O5 . . 127.52(17) ?
O1 C1 C2 . . 132.5(6) ?
O1 C1 C8 . . 122.4(5) ?
C2 C1 C8 . . 105.1(5) ?
C7 C2 C3 . . 120.9(5) ?
C7 C2 C1 . . 106.9(5) ?
C3 C2 C1 . . 132.2(5) ?
C4 C3 C2 . . 118.4(6) ?
C4 C3 H3 . . 120.8 ?
C2 C3 H3 . . 120.8 ?
C3 C4 C5 . . 120.4(6) ?
C3 C4 H4 . . 119.8 ?
C5 C4 H4 . . 119.8 ?
C4 C5 C6 . . 121.8(6) ?
C4 C5 H5 . . 119.1 ?
C6 C5 H5 . . 119.1 ?
C7 C6 C5 . . 117.1(6) ?
C7 C6 H6 . . 121.5 ?
C5 C6 H6 . . 121.5 ?
C6 C7 C2 . . 121.3(6) ?
C6 C7 N1 . . 127.4(6) ?
C2 C7 N1 . . 111.2(5) ?
O2 C8 N1 . . 127.4(5) ?
O2 C8 C1 . . 125.0(5) ?
N1 C8 C1 . . 107.6(5) ?
N1 C9 C10 . . 113.0(5) ?
N1 C9 H9A . . 109.0 ?
C10 C9 H9A . . 109.0 ?
N1 C9 H9B . . 109.0 ?
C10 C9 H9B . . 109.0 ?
H9A C9 H9B . . 107.8 ?
C15 C10 C11 . . 118.2(6) ?
C15 C10 C9 . . 122.0(6) ?
C11 C10 C9 . . 119.7(5) ?
O3 C11 C10 . . 115.4(5) ?
O3 C11 C12 . . 124.5(5) ?
C10 C11 C12 . . 120.1(5) ?
C13 C12 C11 . . 119.2(6) ?
C13 C12 Ag1 . . 78.6(4) ?
C11 C12 Ag1 . . 97.3(4) ?
C13 C12 H12 . . 117.5 ?
C11 C12 H12 . . 117.5 ?
Ag1 C12 H12 . . 117.5 ?
C14 C13 C12 . . 121.0(6) ?
C14 C13 Ag1 . . 101.9(5) ?
C12 C13 Ag1 . . 69.5(4) ?
C14 C13 H13 . . 117.5 ?
C12 C13 H13 . . 117.5 ?
Ag1 C13 H13 . . 117.5 ?
C13 C14 C15 . . 119.2(6) ?
C13 C14 H14 . . 120.4 ?
C15 C14 H14 . . 120.4 ?
C14 C15 C10 . . 122.2(7) ?
C14 C15 H15 . . 118.9 ?
C10 C15 H15 . . 118.9 ?
O3 C16 C17 . . 106.8(5) ?
O3 C16 H16A . . 110.4 ?
C17 C16 H16A . . 110.4 ?
O3 C16 H16B . . 110.4 ?
C17 C16 H16B . . 110.4 ?
H16A C16 H16B . . 108.6 ?
O4 C17 C16 . . 107.9(4) ?
O4 C17 H17A . . 110.1 ?
C16 C17 H17A . . 110.1 ?
O4 C17 H17B . . 110.1 ?
C16 C17 H17B . . 110.1 ?
H17A C17 H17B . . 108.4 ?
O4 C18 C23 . . 116.5(5) ?
O4 C18 C19 . . 123.3(5) ?
C23 C18 C19 . . 120.2(5) ?
C20 C19 C18 . . 119.7(6) ?
C20 C19 H19 . . 120.2 ?
C18 C19 H19 . . 120.2 ?
C21 C20 C19 . . 120.3(6) ?
C21 C20 H20 . . 119.8 ?
C19 C20 H20 . . 119.8 ?
C20 C21 C22 . . 119.6(6) ?
C20 C21 H21 . . 120.2 ?
C22 C21 H21 . . 120.2 ?
C21 C22 C23 . . 121.6(6) ?
C21 C22 H22 . . 119.2 ?
C23 C22 H22 . . 119.2 ?
C22 C23 C18 . . 118.5(5) ?
C22 C23 C24 . . 119.5(5) ?
C18 C23 C24 . . 122.0(5) ?
N2 C24 C23 . . 114.0(4) ?
N2 C24 H24A . . 108.8 ?
C23 C24 H24A . . 108.8 ?
N2 C24 H24B . . 108.8 ?
C23 C24 H24B . . 108.8 ?
H24A C24 H24B . . 107.7 ?
O5 C25 N2 . . 127.9(6) ?
O5 C25 C26 . . 125.7(5) ?
N2 C25 C26 . . 106.3(5) ?
O6 C26 C27 . . 131.2(6) ?
O6 C26 C25 . . 123.1(5) ?
C27 C26 C25 . . 105.5(5) ?
C32 C27 C28 . . 120.8(5) ?
C32 C27 C26 . . 133.1(6) ?
C28 C27 C26 . . 106.1(5) ?
C29 C28 C27 . . 121.6(5) ?
C29 C28 N2 . . 126.9(5) ?
C27 C28 N2 . . 111.5(5) ?
C28 C29 C30 . . 116.1(6) ?
C28 C29 H29 . . 122.0 ?
C30 C29 H29 . . 122.0 ?
C31 C30 C29 . . 123.0(6) ?
C31 C30 H30 . . 118.5 ?
C29 C30 H30 . . 118.5 ?
C30 C31 C32 . . 120.2(6) ?
C30 C31 H31 . . 119.9 ?
C32 C31 H31 . . 119.9 ?
C31 C32 C27 . . 118.4(6) ?
C31 C32 H32 . . 120.8 ?
C27 C32 H32 . . 120.8 ?
C8 N1 C7 . . 109.2(5) ?
C8 N1 C9 . . 124.4(5) ?
C7 N1 C9 . . 126.3(5) ?
C25 N2 C28 . . 110.4(5) ?
C25 N2 C24 . . 124.3(5) ?
C28 N2 C24 . . 124.6(5) ?
C8 O2 Ag1 . 2_566 114.6(4) ?
C11 O3 C16 . . 118.0(4) ?
C18 O4 C17 . . 118.1(4) ?
C25 O5 Ag1 . . 109.9(4) ?
C26 O6 Ag1 . . 111.3(4) ?
F5 Sb1 F4' . . 139.3(16) ?
F5 Sb1 F2' . . 125.2(12) ?
F4' Sb1 F2' . . 89.5(14) ?
F5 Sb1 F1 . . 95.7(12) ?
F4' Sb1 F1 . . 121.0(15) ?
F2' Sb1 F1 . . 31.5(8) ?
F5 Sb1 F4 . . 91.6(12) ?
F4' Sb1 F4 . . 50.5(10) ?
F2' Sb1 F4 . . 139.9(12) ?
F1 Sb1 F4 . . 171.0(13) ?
F5 Sb1 F5' . . 48.3(11) ?
F4' Sb1 F5' . . 96.3(14) ?
F2' Sb1 F5' . . 173.5(13) ?
F1 Sb1 F5' . . 142.6(14) ?
F4 Sb1 F5' . . 45.8(9) ?
F5 Sb1 F6 . . 109.5(14) ?
F4' Sb1 F6 . . 86.9(14) ?
F2' Sb1 F6 . . 92.1(14) ?
F1 Sb1 F6 . . 93.5(12) ?
F4 Sb1 F6 . . 89.1(11) ?
F5' Sb1 F6 . . 91.1(12) ?
F5 Sb1 F6' . . 97.0(11) ?
F4' Sb1 F6' . . 97.8(11) ?
F2' Sb1 F6' . . 98.4(12) ?
F1 Sb1 F6' . . 93.2(11) ?
F4 Sb1 F6' . . 91.2(11) ?
F5' Sb1 F6' . . 83.7(10) ?
F6 Sb1 F6' . . 12.6(17) ?
F5 Sb1 F2 . . 178.8(14) ?
F4' Sb1 F2 . . 39.5(12) ?
F2' Sb1 F2 . . 55.7(9) ?
F1 Sb1 F2 . . 85.4(10) ?
F4 Sb1 F2 . . 87.3(10) ?
F5' Sb1 F2 . . 130.8(13) ?
F6 Sb1 F2 . . 71.0(13) ?
F6' Sb1 F2 . . 83.5(11) ?
F5 Sb1 F3 . . 91.1(11) ?
F4' Sb1 F3 . . 74.3(10) ?
F2' Sb1 F3 . . 78.7(12) ?
F1 Sb1 F3 . . 88.4(11) ?
F4 Sb1 F3 . . 86.1(10) ?
F5' Sb1 F3 . . 100.0(10) ?
F6 Sb1 F3 . . 159.1(12) ?
F6' Sb1 F3 . . 171.6(10) ?
F2 Sb1 F3 . . 88.4(11) ?
F5 Sb1 F1' . . 46.0(9) ?
F4' Sb1 F1' . . 174.4(15) ?
F2' Sb1 F1' . . 86.7(10) ?
F1 Sb1 F1' . . 55.3(8) ?
F4 Sb1 F1' . . 133.4(12) ?
F5' Sb1 F1' . . 87.7(12) ?
F6 Sb1 F1' . . 89.0(12) ?
F6' Sb1 F1' . . 78.6(9) ?
F2 Sb1 F1' . . 135.2(11) ?
F3 Sb1 F1' . . 108.9(8) ?
F5 Sb1 F3' . . 64.2(10) ?
F4' Sb1 F3' . . 99.9(11) ?
F2' Sb1 F3' . . 89.6(11) ?
F1 Sb1 F3' . . 84.5(8) ?
F4 Sb1 F3' . . 93.9(8) ?
F5' Sb1 F3' . . 86.5(10) ?
F6 Sb1 F3' . . 173.0(12) ?
F6' Sb1 F3' . . 160.6(10) ?
F2 Sb1 F3' . . 115.5(11) ?
F3 Sb1 F3' . . 27.8(8) ?
F1' Sb1 F3' . . 84.3(7) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 O2 2_566 2.372(4) ?
Ag1 C12 . 2.458(6) ?
Ag1 O6 . 2.562(5) ?
Ag1 C13 . 2.572(6) ?
Ag1 O5 . 2.577(4) ?
C1 O1 . 1.209(7) ?
C1 C2 . 1.448(8) ?
C1 C8 . 1.529(8) ?
C2 C7 . 1.385(8) ?
C2 C3 . 1.389(8) ?
C3 C4 . 1.374(9) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.382(10) ?
C4 H4 . 0.9300 ?
C5 C6 . 1.398(9) ?
C5 H5 . 0.9300 ?
C6 C7 . 1.378(8) ?
C6 H6 . 0.9300 ?
C7 N1 . 1.422(7) ?
C8 O2 . 1.217(7) ?
C8 N1 . 1.344(7) ?
C9 N1 . 1.448(7) ?
C9 C10 . 1.492(8) ?
C9 H9A . 0.9700 ?
C9 H9B . 0.9700 ?
C10 C15 . 1.389(8) ?
C10 C11 . 1.391(8) ?
C11 O3 . 1.351(6) ?
C11 C12 . 1.412(8) ?
C12 C13 . 1.387(9) ?
C12 H12 . 0.9800 ?
C13 C14 . 1.368(10) ?
C13 H13 . 0.9800 ?
C14 C15 . 1.378(10) ?
C14 H14 . 0.9300 ?
C15 H15 . 0.9300 ?
C16 O3 . 1.441(7) ?
C16 C17 . 1.496(8) ?
C16 H16A . 0.9700 ?
C16 H16B . 0.9700 ?
C17 O4 . 1.421(6) ?
C17 H17A . 0.9700 ?
C17 H17B . 0.9700 ?
C18 O4 . 1.367(6) ?
C18 C23 . 1.387(7) ?
C18 C19 . 1.389(7) ?
C19 C20 . 1.384(8) ?
C19 H19 . 0.9300 ?
C20 C21 . 1.368(9) ?
C20 H20 . 0.9300 ?
C21 C22 . 1.372(9) ?
C21 H21 . 0.9300 ?
C22 C23 . 1.384(7) ?
C22 H22 . 0.9300 ?
C23 C24 . 1.504(7) ?
C24 N2 . 1.462(7) ?
C24 H24A . 0.9700 ?
C24 H24B . 0.9700 ?
C25 O5 . 1.213(7) ?
C25 N2 . 1.353(7) ?
C25 C26 . 1.532(8) ?
C26 O6 . 1.217(7) ?
C26 C27 . 1.464(8) ?
C27 C32 . 1.381(8) ?
C27 C28 . 1.386(7) ?
C28 C29 . 1.386(7) ?
C28 N2 . 1.406(7) ?
C29 C30 . 1.390(9) ?
C29 H29 . 0.9300 ?
C30 C31 . 1.369(9) ?
C30 H30 . 0.9300 ?
C31 C32 . 1.380(9) ?
C31 H31 . 0.9300 ?
C32 H32 . 0.9300 ?
O2 Ag1 2_566 2.372(4) ?
Sb1 F5 . 1.702(15) ?
Sb1 F4' . 1.765(9) ?
Sb1 F2' . 1.777(18) ?
Sb1 F1 . 1.784(12) ?
Sb1 F4 . 1.793(9) ?
Sb1 F5' . 1.816(12) ?
Sb1 F6 . 1.819(9) ?
Sb1 F6' . 1.824(6) ?
Sb1 F2 . 1.84(2) ?
Sb1 F3 . 1.854(8) ?
Sb1 F1' . 1.862(11) ?
Sb1 F3' . 1.863(8) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
O1 C1 C2 C7 . . . . -180.0(6) ?
C8 C1 C2 C7 . . . . -1.7(6) ?
O1 C1 C2 C3 . . . . -0.6(11) ?
C8 C1 C2 C3 . . . . 177.7(6) ?
C7 C2 C3 C4 . . . . 0.6(9) ?
C1 C2 C3 C4 . . . . -178.7(6) ?
C2 C3 C4 C5 . . . . -1.4(9) ?
C3 C4 C5 C6 . . . . 1.0(10) ?
C4 C5 C6 C7 . . . . 0.2(10) ?
C5 C6 C7 C2 . . . . -1.0(9) ?
C5 C6 C7 N1 . . . . 177.8(6) ?
C3 C2 C7 C6 . . . . 0.6(9) ?
C1 C2 C7 C6 . . . . -179.9(5) ?
C3 C2 C7 N1 . . . . -178.3(5) ?
C1 C2 C7 N1 . . . . 1.1(6) ?
O1 C1 C8 O2 . . . . -0.4(9) ?
C2 C1 C8 O2 . . . . -178.9(5) ?
O1 C1 C8 N1 . . . . -179.8(5) ?
C2 C1 C8 N1 . . . . 1.7(6) ?
N1 C9 C10 C15 . . . . -111.3(6) ?
N1 C9 C10 C11 . . . . 69.4(7) ?
C15 C10 C11 O3 . . . . -179.8(5) ?
C9 C10 C11 O3 . . . . -0.4(7) ?
C15 C10 C11 C12 . . . . -0.5(8) ?
C9 C10 C11 C12 . . . . 178.9(5) ?
O3 C11 C12 C13 . . . . -179.9(5) ?
C10 C11 C12 C13 . . . . 1.0(8) ?
O3 C11 C12 Ag1 . . . . -98.9(5) ?
C10 C11 C12 Ag1 . . . . 81.9(5) ?
O2 Ag1 C12 C13 2_566 . . . 70.6(18) ?
O6 Ag1 C12 C13 . . . . -138.1(4) ?
O5 Ag1 C12 C13 . . . . 151.2(4) ?
O2 Ag1 C12 C11 2_566 . . . -47.8(19) ?
O6 Ag1 C12 C11 . . . . 103.5(4) ?
C13 Ag1 C12 C11 . . . . -118.4(6) ?
O5 Ag1 C12 C11 . . . . 32.8(4) ?
C11 C12 C13 C14 . . . . 0.2(10) ?
Ag1 C12 C13 C14 . . . . -91.9(7) ?
C11 C12 C13 Ag1 . . . . 92.1(5) ?
O2 Ag1 C13 C14 2_566 . . . -51.6(6) ?
C12 Ag1 C13 C14 . . . . 118.9(6) ?
O6 Ag1 C13 C14 . . . . 172.4(4) ?
O5 Ag1 C13 C14 . . . . 82.2(5) ?
O2 Ag1 C13 C12 2_566 . . . -170.5(3) ?
O6 Ag1 C13 C12 . . . . 53.5(5) ?
O5 Ag1 C13 C12 . . . . -36.7(5) ?
C12 C13 C14 C15 . . . . -1.7(11) ?
Ag1 C13 C14 C15 . . . . -74.9(7) ?
C13 C14 C15 C10 . . . . 2.2(11) ?
C11 C10 C15 C14 . . . . -1.1(10) ?
C9 C10 C15 C14 . . . . 179.5(6) ?
O3 C16 C17 O4 . . . . -76.1(6) ?
O4 C18 C19 C20 . . . . -178.3(5) ?
C23 C18 C19 C20 . . . . 1.9(9) ?
C18 C19 C20 C21 . . . . -2.9(10) ?
C19 C20 C21 C22 . . . . 2.4(10) ?
C20 C21 C22 C23 . . . . -1.1(10) ?
C21 C22 C23 C18 . . . . 0.2(9) ?
C21 C22 C23 C24 . . . . 177.3(6) ?
O4 C18 C23 C22 . . . . 179.6(5) ?
C19 C18 C23 C22 . . . . -0.6(8) ?
O4 C18 C23 C24 . . . . 2.5(8) ?
C19 C18 C23 C24 . . . . -177.7(5) ?
C22 C23 C24 N2 . . . . 127.6(6) ?
C18 C23 C24 N2 . . . . -55.4(7) ?
O5 C25 C26 O6 . . . . -4.8(9) ?
N2 C25 C26 O6 . . . . 172.1(5) ?
O5 C25 C26 C27 . . . . 179.7(5) ?
N2 C25 C26 C27 . . . . -3.3(6) ?
O6 C26 C27 C32 . . . . 6.1(11) ?
C25 C26 C27 C32 . . . . -178.9(6) ?
O6 C26 C27 C28 . . . . -171.3(6) ?
C25 C26 C27 C28 . . . . 3.6(6) ?
C32 C27 C28 C29 . . . . -0.7(8) ?
C26 C27 C28 C29 . . . . 177.1(5) ?
C32 C27 C28 N2 . . . . 179.4(5) ?
C26 C27 C28 N2 . . . . -2.8(6) ?
C27 C28 C29 C30 . . . . 0.0(8) ?
N2 C28 C29 C30 . . . . 179.9(5) ?
C28 C29 C30 C31 . . . . 0.5(9) ?
C29 C30 C31 C32 . . . . -0.2(10) ?
C30 C31 C32 C27 . . . . -0.5(9) ?
C28 C27 C32 C31 . . . . 1.0(9) ?
C26 C27 C32 C31 . . . . -176.2(6) ?
O2 C8 N1 C7 . . . . 179.6(6) ?
C1 C8 N1 C7 . . . . -1.1(6) ?
O2 C8 N1 C9 . . . . -4.6(9) ?
C1 C8 N1 C9 . . . . 174.8(5) ?
C6 C7 N1 C8 . . . . -178.9(6) ?
C2 C7 N1 C8 . . . . 0.0(6) ?
C6 C7 N1 C9 . . . . 5.4(9) ?
C2 C7 N1 C9 . . . . -175.8(5) ?
C10 C9 N1 C8 . . . . 54.9(7) ?
C10 C9 N1 C7 . . . . -130.0(6) ?
O5 C25 N2 C28 . . . . 178.6(5) ?
C26 C25 N2 C28 . . . . 1.7(5) ?
O5 C25 N2 C24 . . . . 7.2(9) ?
C26 C25 N2 C24 . . . . -169.7(4) ?
C29 C28 N2 C25 . . . . -179.3(5) ?
C27 C28 N2 C25 . . . . 0.6(6) ?
C29 C28 N2 C24 . . . . -7.9(8) ?
C27 C28 N2 C24 . . . . 172.0(5) ?
C23 C24 N2 C25 . . . . 108.7(6) ?
C23 C24 N2 C28 . . . . -61.5(7) ?
N1 C8 O2 Ag1 . . . 2_566 -178.3(4) ?
C1 C8 O2 Ag1 . . . 2_566 2.4(7) ?
C10 C11 O3 C16 . . . . -173.4(5) ?
C12 C11 O3 C16 . . . . 7.4(8) ?
C17 C16 O3 C11 . . . . 166.1(4) ?
C23 C18 O4 C17 . . . . 177.1(5) ?
C19 C18 O4 C17 . . . . -2.7(8) ?
C16 C17 O4 C18 . . . . -178.0(5) ?
N2 C25 O5 Ag1 . . . . 179.4(4) ?
C26 C25 O5 Ag1 . . . . -4.3(6) ?
O2 Ag1 O5 C25 2_566 . . . -77.5(4) ?
C12 Ag1 O5 C25 . . . . 108.1(4) ?
O6 Ag1 O5 C25 . . . . 6.4(3) ?
C13 Ag1 O5 C25 . . . . 126.9(4) ?
C27 C26 O6 Ag1 . . . . -175.1(5) ?
C25 C26 O6 Ag1 . . . . 10.7(6) ?
O2 Ag1 O6 C26 2_566 . . . 72.8(4) ?
C12 Ag1 O6 C26 . . . . -104.5(4) ?
C13 Ag1 O6 C26 . . . . -130.5(4) ?
O5 Ag1 O6 C26 . . . . -8.8(4) ?
