#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/81/2018148.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2018148
loop_
_publ_author_name
'Bigun, Inna'
'Smetana, Volodymyr'
'Kalychak, Yaroslav'
_publ_section_title
;
 A new rhombohedral modification of EuNi₅In
;
_journal_coeditor_code           KU3048
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              i42
_journal_page_last               i44
_journal_paper_doi               10.1107/S0108270111022359
_journal_volume                  67
_journal_year                    2011
_chemical_formula_iupac          'Eu Ni5 In'
_chemical_formula_sum            'Eu In Ni5'
_chemical_formula_weight         560.33
_chemical_name_common            'europium nickel indide'
_chemical_name_systematic
;
europium pentanickel indide
;
_space_group_IT_number           166
_symmetry_cell_setting           trigonal
_symmetry_space_group_name_Hall  '-R 3 2"'
_symmetry_space_group_name_H-M   'R -3 m :H'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            6
_cell_length_a                   4.8956(7)
_cell_length_b                   4.8956(7)
_cell_length_c                   29.751(6)
_cell_measurement_reflns_used    1820
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.3
_cell_measurement_theta_min      2.1
_cell_volume                     617.51(18)
_computing_cell_refinement       'SAINT (Bruker, 1996)'
_computing_data_collection       'SMART (Bruker, 1996)'
_computing_data_reduction        'SAINT (Bruker,1996)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.962
_diffrn_measured_fraction_theta_max 0.962
_diffrn_measurement_device_type  'Bruker CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0353
_diffrn_reflns_av_sigmaI/netI    0.0219
_diffrn_reflns_limit_h_max       6
_diffrn_reflns_limit_h_min       -6
_diffrn_reflns_limit_k_max       6
_diffrn_reflns_limit_k_min       -6
_diffrn_reflns_limit_l_max       39
_diffrn_reflns_limit_l_min       -39
_diffrn_reflns_number            1820
_diffrn_reflns_theta_full        28.29
_diffrn_reflns_theta_max         28.29
_diffrn_reflns_theta_min         2.05
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    42.635
_exptl_absorpt_correction_T_max  0.100
_exptl_absorpt_correction_T_min  0.003
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '(Blessing, 1995)'
_exptl_crystal_colour            metallic-grey
_exptl_crystal_density_diffrn    9.041
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'xenomorphic fragment'
_exptl_crystal_F_000             1512
_exptl_crystal_size_max          0.15
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.05
_refine_diff_density_max         2.548
_refine_diff_density_min         -1.313
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.080
_refine_ls_matrix_type           full
_refine_ls_number_parameters     20
_refine_ls_number_reflns         229
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.080
_refine_ls_R_factor_all          0.0249
_refine_ls_R_factor_gt           0.0219
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0246P)²+10.2303P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0492
_refine_ls_wR_factor_ref         0.0508
_reflns_number_gt                209
_reflns_number_total             229
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ku3048.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      R-3m
_cod_database_code               2018148
_cod_database_fobs_code          2018148
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'y, x, -z'
'x-y, -y, -z'
'-x, -x+y, -z'
'x+2/3, y+1/3, z+1/3'
'-y+2/3, x-y+1/3, z+1/3'
'-x+y+2/3, -x+1/3, z+1/3'
'y+2/3, x+1/3, -z+1/3'
'x-y+2/3, -y+1/3, -z+1/3'
'-x+2/3, -x+y+1/3, -z+1/3'
'x+1/3, y+2/3, z+2/3'
'-y+1/3, x-y+2/3, z+2/3'
'-x+y+1/3, -x+2/3, z+2/3'
'y+1/3, x+2/3, -z+2/3'
'x-y+1/3, -y+2/3, -z+2/3'
'-x+1/3, -x+y+2/3, -z+2/3'
'-x, -y, -z'
'y, -x+y, -z'
'x-y, x, -z'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'-x+2/3, -y+1/3, -z+1/3'
'y+2/3, -x+y+1/3, -z+1/3'
'x-y+2/3, x+1/3, -z+1/3'
'-y+2/3, -x+1/3, z+1/3'
'-x+y+2/3, y+1/3, z+1/3'
'x+2/3, x-y+1/3, z+1/3'
'-x+1/3, -y+2/3, -z+2/3'
'y+1/3, -x+y+2/3, -z+2/3'
'x-y+1/3, x+2/3, -z+2/3'
'-y+1/3, -x+2/3, z+2/3'
'-x+y+1/3, y+2/3, z+2/3'
'x+1/3, x-y+2/3, z+2/3'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_disorder_assembly
_atom_site_disorder_group
Eu Eu1 0.0000 0.0000 0.0000 0.0098(2) Uani d S 1 12 . .
Eu Eu2 0.0000 0.0000 0.5000 0.0095(2) Uani d S 1 12 . .
In In1 0.0000 0.0000 0.11026(3) 0.0091(2) Uani d S 1 6 . .
Ni Ni1 0.0000 0.0000 0.33355(5) 0.0099(4) Uani d S 1 6 . .
Ni Ni2 0.0000 0.0000 0.19824(5) 0.0130(4) Uani d S 1 6 . .
Ni Ni3 0.49899(10) 0.50101(10) 0.06802(3) 0.0089(2) Uani d S 1 2 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
Ni1 Eu1 Ni1 25 25_445 120.0 ?
Ni1 Eu1 Ni1 25 13_554 60.0 ?
Ni1 Eu1 Ni1 25_445 13_554 180.0 ?
Ni1 Eu1 Ni1 25 13_444 180.0 ?
Ni1 Eu1 Ni1 25_445 13_444 60.0 ?
Ni1 Eu1 Ni1 13_554 13_444 120.0 ?
Ni1 Eu1 Ni1 25 25_455 120.0 ?
Ni1 Eu1 Ni1 25_445 25_455 120.0 ?
Ni1 Eu1 Ni1 13_554 25_455 60.0 ?
Ni1 Eu1 Ni1 13_444 25_455 60.0 ?
Ni1 Eu1 Ni1 25 13_544 60.0 ?
Ni1 Eu1 Ni1 25_445 13_544 60.0 ?
Ni1 Eu1 Ni1 13_554 13_544 120.0 ?
Ni1 Eu1 Ni1 13_444 13_544 120.0 ?
Ni1 Eu1 Ni1 25_455 13_544 180.0 ?
Ni1 Eu1 Ni3 25 . 48.34(3) ?
Ni1 Eu1 Ni3 25_445 . 132.09(3) ?
Ni1 Eu1 Ni3 13_554 . 47.91(3) ?
Ni1 Eu1 Ni3 13_444 . 131.66(3) ?
Ni1 Eu1 Ni3 25_455 . 89.93(2) ?
Ni1 Eu1 Ni3 13_544 . 90.07(2) ?
Ni1 Eu1 Ni3 25 19 131.66(3) ?
Ni1 Eu1 Ni3 25_445 19 47.91(3) ?
Ni1 Eu1 Ni3 13_554 19 132.09(3) ?
Ni1 Eu1 Ni3 13_444 19 48.34(3) ?
Ni1 Eu1 Ni3 25_455 19 90.07(2) ?
Ni1 Eu1 Ni3 13_544 19 89.93(2) ?
Ni3 Eu1 Ni3 . 19 180.00(3) ?
Ni1 Eu1 Ni3 25 21_545 90.07(2) ?
Ni1 Eu1 Ni3 25_445 21_545 47.91(3) ?
Ni1 Eu1 Ni3 13_554 21_545 132.09(3) ?
Ni1 Eu1 Ni3 13_444 21_545 89.93(2) ?
Ni1 Eu1 Ni3 25_455 21_545 131.66(3) ?
Ni1 Eu1 Ni3 13_544 21_545 48.34(3) ?
Ni3 Eu1 Ni3 . 21_545 134.96(3) ?
Ni3 Eu1 Ni3 19 21_545 45.04(3) ?
Ni1 Eu1 Ni3 25 3_565 89.93(2) ?
Ni1 Eu1 Ni3 25_445 3_565 132.09(3) ?
Ni1 Eu1 Ni3 13_554 3_565 47.91(3) ?
Ni1 Eu1 Ni3 13_444 3_565 90.07(2) ?
Ni1 Eu1 Ni3 25_455 3_565 48.34(3) ?
Ni1 Eu1 Ni3 13_544 3_565 131.66(3) ?
Ni3 Eu1 Ni3 . 3_565 45.04(3) ?
Ni3 Eu1 Ni3 19 3_565 134.96(3) ?
Ni3 Eu1 Ni3 21_545 3_565 180.00(5) ?
Ni1 Eu1 Ni3 25 2_655 48.34(3) ?
Ni1 Eu1 Ni3 25_445 2_655 89.93(2) ?
Ni1 Eu1 Ni3 13_554 2_655 90.07(2) ?
Ni1 Eu1 Ni3 13_444 2_655 131.66(3) ?
Ni1 Eu1 Ni3 25_455 2_655 132.09(3) ?
Ni1 Eu1 Ni3 13_544 2_655 47.91(3) ?
Ni3 Eu1 Ni3 . 2_655 45.62(3) ?
Ni3 Eu1 Ni3 19 2_655 134.38(3) ?
Ni3 Eu1 Ni3 21_545 2_655 96.26(2) ?
Ni3 Eu1 Ni3 3_565 2_655 83.74(2) ?
Ni1 Eu1 Ni3 25 20_455 131.66(3) ?
Ni1 Eu1 Ni3 25_445 20_455 90.07(2) ?
Ni1 Eu1 Ni3 13_554 20_455 89.93(2) ?
Ni1 Eu1 Ni3 13_444 20_455 48.34(3) ?
Ni1 Eu1 Ni3 25_455 20_455 47.91(3) ?
Ni1 Eu1 Ni3 13_544 20_455 132.09(3) ?
Ni3 Eu1 Ni3 . 20_455 134.38(3) ?
Ni3 Eu1 Ni3 19 20_455 45.62(3) ?
Ni3 Eu1 Ni3 21_545 20_455 83.74(2) ?
Ni3 Eu1 Ni3 3_565 20_455 96.26(2) ?
Ni3 Eu1 Ni3 2_655 20_455 180.00(2) ?
Ni2 Eu2 Ni2 31_445 7 180.00(6) ?
Ni2 Eu2 Ni2 31_445 31 110.53(3) ?
Ni2 Eu2 Ni2 7 31 69.47(3) ?
Ni2 Eu2 Ni2 31_445 7_445 69.47(3) ?
Ni2 Eu2 Ni2 7 7_445 110.53(3) ?
Ni2 Eu2 Ni2 31 7_445 180.0 ?
Ni2 Eu2 Ni2 31_445 31_545 110.53(3) ?
Ni2 Eu2 Ni2 7 31_545 69.47(3) ?
Ni2 Eu2 Ni2 31 31_545 110.53(3) ?
Ni2 Eu2 Ni2 7_445 31_545 69.47(3) ?
Ni2 Eu2 Ni2 31_445 7_455 69.47(3) ?
Ni2 Eu2 Ni2 7 7_455 110.53(3) ?
Ni2 Eu2 Ni2 31 7_455 69.47(3) ?
Ni2 Eu2 Ni2 7_445 7_455 110.53(3) ?
Ni2 Eu2 Ni2 31_545 7_455 180.00(6) ?
Ni2 Eu2 Ni3 31_445 31 94.57(3) ?
Ni2 Eu2 Ni3 7 31 85.43(3) ?
Ni2 Eu2 Ni3 31 31 94.57(3) ?
Ni2 Eu2 Ni3 7_445 31 85.43(3) ?
Ni2 Eu2 Ni3 31_545 31 133.96(3) ?
Ni2 Eu2 Ni3 7_455 31 46.04(3) ?
Ni2 Eu2 Ni3 31_445 7_445 85.43(3) ?
Ni2 Eu2 Ni3 7 7_445 94.57(3) ?
Ni2 Eu2 Ni3 31 7_445 85.43(3) ?
Ni2 Eu2 Ni3 7_445 7_445 94.57(3) ?
Ni2 Eu2 Ni3 31_545 7_445 46.04(3) ?
Ni2 Eu2 Ni3 7_455 7_445 133.96(3) ?
Ni3 Eu2 Ni3 31 7_445 180.000(13) ?
Ni2 Eu2 Ni3 31_445 33_545 133.96(3) ?
Ni2 Eu2 Ni3 7 33_545 46.04(3) ?
Ni2 Eu2 Ni3 31 33_545 94.57(3) ?
Ni2 Eu2 Ni3 7_445 33_545 85.43(3) ?
Ni2 Eu2 Ni3 31_545 33_545 94.57(3) ?
Ni2 Eu2 Ni3 7_455 33_545 85.43(3) ?
Ni3 Eu2 Ni3 31 33_545 43.91(3) ?
Ni3 Eu2 Ni3 7_445 33_545 136.09(3) ?
Ni2 Eu2 Ni3 31_445 9_455 46.04(3) ?
Ni2 Eu2 Ni3 7 9_455 133.96(3) ?
Ni2 Eu2 Ni3 31 9_455 85.43(3) ?
Ni2 Eu2 Ni3 7_445 9_455 94.57(3) ?
Ni2 Eu2 Ni3 31_545 9_455 85.43(3) ?
Ni2 Eu2 Ni3 7_455 9_455 94.57(3) ?
Ni3 Eu2 Ni3 31 9_455 136.09(3) ?
Ni3 Eu2 Ni3 7_445 9_455 43.91(3) ?
Ni3 Eu2 Ni3 33_545 9_455 180.0 ?
Ni2 Eu2 Ni3 31_445 32_445 94.57(3) ?
Ni2 Eu2 Ni3 7 32_445 85.43(3) ?
Ni2 Eu2 Ni3 31 32_445 133.96(3) ?
Ni2 Eu2 Ni3 7_445 32_445 46.04(3) ?
Ni2 Eu2 Ni3 31_545 32_445 94.57(3) ?
Ni2 Eu2 Ni3 7_455 32_445 85.43(3) ?
Ni3 Eu2 Ni3 31 32_445 43.91(3) ?
Ni3 Eu2 Ni3 7_445 32_445 136.09(3) ?
Ni3 Eu2 Ni3 33_545 32_445 43.91(3) ?
Ni3 Eu2 Ni3 9_455 32_445 136.09(3) ?
Ni2 Eu2 Ni3 31_445 8 85.43(3) ?
Ni2 Eu2 Ni3 7 8 94.57(3) ?
Ni2 Eu2 Ni3 31 8 46.04(3) ?
Ni2 Eu2 Ni3 7_445 8 133.96(3) ?
Ni2 Eu2 Ni3 31_545 8 85.43(3) ?
Ni2 Eu2 Ni3 7_455 8 94.57(3) ?
Ni3 Eu2 Ni3 31 8 136.09(3) ?
Ni3 Eu2 Ni3 7_445 8 43.91(3) ?
Ni3 Eu2 Ni3 33_545 8 136.09(3) ?
Ni3 Eu2 Ni3 9_455 8 43.91(3) ?
Ni3 Eu2 Ni3 32_445 8 180.0 ?
Ni2 In1 Ni3 . 1_445 117.18(2) ?
Ni2 In1 Ni3 . 2 117.18(2) ?
Ni3 In1 Ni3 1_445 2 52.48(4) ?
Ni2 In1 Ni3 . 3 117.18(2) ?
Ni3 In1 Ni3 1_445 3 53.17(4) ?
Ni3 In1 Ni3 2 3 100.78(3) ?
Ni2 In1 Ni3 . . 117.18(2) ?
Ni3 In1 Ni3 1_445 . 125.64(5) ?
Ni3 In1 Ni3 2 . 100.78(3) ?
Ni3 In1 Ni3 3 . 100.78(3) ?
Ni2 In1 Ni3 . 2_655 117.18(2) ?
Ni3 In1 Ni3 1_445 2_655 100.78(3) ?
Ni3 In1 Ni3 2 2_655 125.64(5) ?
Ni3 In1 Ni3 3 2_655 52.48(4) ?
Ni3 In1 Ni3 . 2_655 53.17(4) ?
Ni2 In1 Ni3 . 3_565 117.18(2) ?
Ni3 In1 Ni3 1_445 3_565 100.78(3) ?
Ni3 In1 Ni3 2 3_565 53.17(4) ?
Ni3 In1 Ni3 3 3_565 125.64(5) ?
Ni3 In1 Ni3 . 3_565 52.48(4) ?
Ni3 In1 Ni3 2_655 3_565 100.78(3) ?
Ni2 In1 Ni2 . 25 75.35(3) ?
Ni3 In1 Ni2 1_445 25 149.58(3) ?
Ni3 In1 Ni2 2 25 149.58(3) ?
Ni3 In1 Ni2 3 25 96.46(2) ?
Ni3 In1 Ni2 . 25 51.07(3) ?
Ni3 In1 Ni2 2_655 25 51.07(3) ?
Ni3 In1 Ni2 3_565 25 96.46(2) ?
Ni2 In1 Ni2 . 25_445 75.35(3) ?
Ni3 In1 Ni2 1_445 25_445 51.07(3) ?
Ni3 In1 Ni2 2 25_445 96.46(2) ?
Ni3 In1 Ni2 3 25_445 51.07(3) ?
Ni3 In1 Ni2 . 25_445 149.58(3) ?
Ni3 In1 Ni2 2_655 25_445 96.46(2) ?
Ni3 In1 Ni2 3_565 25_445 149.58(3) ?
Ni2 In1 Ni2 25 25_445 113.83(3) ?
Ni2 In1 Ni2 . 25_455 75.35(3) ?
Ni3 In1 Ni2 1_445 25_455 96.46(2) ?
Ni3 In1 Ni2 2 25_455 51.07(3) ?
Ni3 In1 Ni2 3 25_455 149.58(3) ?
Ni3 In1 Ni2 . 25_455 96.46(2) ?
Ni3 In1 Ni2 2_655 25_455 149.58(3) ?
Ni3 In1 Ni2 3_565 25_455 51.07(3) ?
Ni2 In1 Ni2 25 25_455 113.83(3) ?
Ni2 In1 Ni2 25_445 25_455 113.83(3) ?
Ni2 In1 Eu1 . . 180.0 ?
Ni3 In1 Eu1 1_445 . 62.82(2) ?
Ni3 In1 Eu1 2 . 62.82(2) ?
Ni3 In1 Eu1 3 . 62.82(2) ?
Ni3 In1 Eu1 . . 62.82(2) ?
Ni3 In1 Eu1 2_655 . 62.82(2) ?
Ni3 In1 Eu1 3_565 . 62.82(2) ?
Ni2 In1 Eu1 25 . 104.65(3) ?
Ni2 In1 Eu1 25_445 . 104.65(3) ?
Ni2 In1 Eu1 25_455 . 104.65(3) ?
Ni2 In1 Eu2 . 13_554 59.304(14) ?
Ni3 In1 Eu2 1_445 13_554 153.418(18) ?
Ni3 In1 Eu2 2 13_554 103.642(18) ?
Ni3 In1 Eu2 3 13_554 153.417(18) ?
Ni3 In1 Eu2 . 13_554 64.49(2) ?
Ni3 In1 Eu2 2_655 13_554 103.641(18) ?
Ni3 In1 Eu2 3_565 13_554 64.49(2) ?
Ni2 In1 Eu2 25 13_554 56.971(15) ?
Ni2 In1 Eu2 25_445 13_554 134.66(4) ?
Ni2 In1 Eu2 25_455 13_554 56.972(15) ?
Eu1 In1 Eu2 . 13_554 120.696(14) ?
Ni3 Ni1 Ni3 7_445 8 59.32(5) ?
Ni3 Ni1 Ni3 7_445 9_455 59.32(5) ?
Ni3 Ni1 Ni3 8 9_455 59.32(5) ?
Ni3 Ni1 Ni3 7_445 25 110.14(3) ?
Ni3 Ni1 Ni3 8 25 146.730(12) ?
Ni3 Ni1 Ni3 9_455 25 146.730(11) ?
Ni3 Ni1 Ni3 7_445 27_445 146.730(11) ?
Ni3 Ni1 Ni3 8 27_445 146.728(11) ?
Ni3 Ni1 Ni3 9_455 27_445 110.14(3) ?
Ni3 Ni1 Ni3 25 27_445 59.58(5) ?
Ni3 Ni1 Ni3 7_445 26_455 146.730(12) ?
Ni3 Ni1 Ni3 8 26_455 110.14(3) ?
Ni3 Ni1 Ni3 9_455 26_455 146.728(11) ?
Ni3 Ni1 Ni3 25 26_455 59.58(5) ?
Ni3 Ni1 Ni3 27_445 26_455 59.58(5) ?
Ni3 Ni1 Eu1 7_445 7 73.51(2) ?
Ni3 Ni1 Eu1 8 7 73.51(2) ?
Ni3 Ni1 Eu1 9_455 7 124.98(5) ?
Ni3 Ni1 Eu1 25 7 73.221(19) ?
Ni3 Ni1 Eu1 27_445 7 124.88(6) ?
Ni3 Ni1 Eu1 26_455 7 73.221(19) ?
Ni3 Ni1 Eu1 7_445 7_445 73.51(2) ?
Ni3 Ni1 Eu1 8 7_445 124.98(5) ?
Ni3 Ni1 Eu1 9_455 7_445 73.51(2) ?
Ni3 Ni1 Eu1 25 7_445 73.221(19) ?
Ni3 Ni1 Eu1 27_445 7_445 73.221(19) ?
Ni3 Ni1 Eu1 26_455 7_445 124.88(6) ?
Eu1 Ni1 Eu1 7 7_445 120.0 ?
Ni3 Ni1 Ni1 7_445 31_445 106.83(6) ?
Ni3 Ni1 Ni1 8 31_445 106.83(6) ?
Ni3 Ni1 Ni1 9_455 31_445 55.41(5) ?
Ni3 Ni1 Ni1 25 31_445 106.44(6) ?
Ni3 Ni1 Ni1 27_445 31_445 54.73(5) ?
Ni3 Ni1 Ni1 26_455 31_445 106.44(6) ?
Eu1 Ni1 Ni1 7 31_445 179.61(9) ?
Eu1 Ni1 Ni1 7_445 31_445 60.0 ?
Ni3 Ni1 Ni1 7_445 31 106.83(6) ?
Ni3 Ni1 Ni1 8 31 55.41(5) ?
Ni3 Ni1 Ni1 9_455 31 106.83(6) ?
Ni3 Ni1 Ni1 25 31 106.44(6) ?
Ni3 Ni1 Ni1 27_445 31 106.44(6) ?
Ni3 Ni1 Ni1 26_455 31 54.73(5) ?
Eu1 Ni1 Ni1 7 31 60.0 ?
Eu1 Ni1 Ni1 7_445 31 179.61(9) ?
Ni1 Ni1 Ni1 31_445 31 119.9990(10) ?
Ni3 Ni1 Eu1 7_445 7_455 124.98(5) ?
Ni3 Ni1 Eu1 8 7_455 73.51(2) ?
Ni3 Ni1 Eu1 9_455 7_455 73.51(2) ?
Ni3 Ni1 Eu1 25 7_455 124.88(6) ?
Ni3 Ni1 Eu1 27_445 7_455 73.220(19) ?
Ni3 Ni1 Eu1 26_455 7_455 73.220(19) ?
Eu1 Ni1 Eu1 7 7_455 120.0 ?
Eu1 Ni1 Eu1 7_445 7_455 120.0 ?
Ni1 Ni1 Eu1 31_445 7_455 60.0 ?
Ni1 Ni1 Eu1 31 7_455 60.0 ?
Ni3 Ni1 Ni1 7_445 31_545 55.41(5) ?
Ni3 Ni1 Ni1 8 31_545 106.83(6) ?
Ni3 Ni1 Ni1 9_455 31_545 106.83(6) ?
Ni3 Ni1 Ni1 25 31_545 54.73(5) ?
Ni3 Ni1 Ni1 27_445 31_545 106.44(6) ?
Ni3 Ni1 Ni1 26_455 31_545 106.44(6) ?
Eu1 Ni1 Ni1 7 31_545 60.0 ?
Eu1 Ni1 Ni1 7_445 31_545 60.0 ?
Ni1 Ni1 Ni1 31_445 31_545 119.9980(10) ?
Ni1 Ni1 Ni1 31 31_545 119.9980(10) ?
Eu1 Ni1 Ni1 7_455 31_545 179.61(9) ?
Ni3 Ni2 Ni3 25 26_455 60.33(5) ?
Ni3 Ni2 Ni3 25 27_445 60.33(5) ?
Ni3 Ni2 Ni3 26_455 27_445 60.33(5) ?
Ni3 Ni2 In1 25 . 144.53(3) ?
Ni3 Ni2 In1 26_455 . 144.53(3) ?
Ni3 Ni2 In1 27_445 . 144.53(3) ?
Ni3 Ni2 In1 25 25 60.88(2) ?
Ni3 Ni2 In1 26_455 25 60.88(2) ?
Ni3 Ni2 In1 27_445 25 110.82(6) ?
In1 Ni2 In1 . 25 104.65(3) ?
Ni3 Ni2 In1 25 25_445 60.88(2) ?
Ni3 Ni2 In1 26_455 25_445 110.82(6) ?
Ni3 Ni2 In1 27_445 25_445 60.88(2) ?
In1 Ni2 In1 . 25_445 104.65(3) ?
In1 Ni2 In1 25 25_445 113.83(3) ?
Ni3 Ni2 In1 25 25_455 110.82(6) ?
Ni3 Ni2 In1 26_455 25_455 60.88(2) ?
Ni3 Ni2 In1 27_445 25_455 60.88(2) ?
In1 Ni2 In1 . 25_455 104.65(3) ?
In1 Ni2 In1 25 25_455 113.83(3) ?
In1 Ni2 In1 25_445 25_455 113.83(3) ?
Ni3 Ni2 Eu2 25 13_444 122.15(3) ?
Ni3 Ni2 Eu2 26_455 13_444 122.15(3) ?
Ni3 Ni2 Eu2 27_445 13_444 72.92(2) ?
In1 Ni2 Eu2 . 13_444 71.61(3) ?
In1 Ni2 Eu2 25 13_444 176.26(6) ?
In1 Ni2 Eu2 25_445 13_444 67.709(8) ?
In1 Ni2 Eu2 25_455 13_444 67.710(8) ?
Ni3 Ni2 Eu2 25 13_554 122.15(3) ?
Ni3 Ni2 Eu2 26_455 13_554 72.92(2) ?
Ni3 Ni2 Eu2 27_445 13_554 122.15(3) ?
In1 Ni2 Eu2 . 13_554 71.61(3) ?
In1 Ni2 Eu2 25 13_554 67.709(8) ?
In1 Ni2 Eu2 25_445 13_554 176.26(6) ?
In1 Ni2 Eu2 25_455 13_554 67.710(8) ?
Eu2 Ni2 Eu2 13_444 13_554 110.53(3) ?
Ni3 Ni2 Eu2 25 13_544 72.92(2) ?
Ni3 Ni2 Eu2 26_455 13_544 122.16(3) ?
Ni3 Ni2 Eu2 27_445 13_544 122.16(3) ?
In1 Ni2 Eu2 . 13_544 71.61(3) ?
In1 Ni2 Eu2 25 13_544 67.710(8) ?
In1 Ni2 Eu2 25_445 13_544 67.710(8) ?
In1 Ni2 Eu2 25_455 13_544 176.26(6) ?
Eu2 Ni2 Eu2 13_444 13_544 110.53(3) ?
Eu2 Ni2 Eu2 13_554 13_544 110.53(3) ?
Ni3 Ni3 Ni3 3_565 2_665 60.0 ?
Ni3 Ni3 Ni2 3_565 25 120.17(2) ?
Ni3 Ni3 Ni2 2_665 25 120.17(2) ?
Ni3 Ni3 Ni1 3_565 13_554 60.34(2) ?
Ni3 Ni3 Ni1 2_665 13_554 60.34(2) ?
Ni2 Ni3 Ni1 25 13_554 179.38(5) ?
Ni3 Ni3 Ni3 3_565 3_665 180.00(9) ?
Ni3 Ni3 Ni3 2_665 3_665 120.0 ?
Ni2 Ni3 Ni3 25 3_665 59.83(2) ?
Ni1 Ni3 Ni3 13_554 3_665 119.66(2) ?
Ni3 Ni3 Ni3 3_565 2_655 120.0 ?
Ni3 Ni3 Ni3 2_665 2_655 180.00(8) ?
Ni2 Ni3 Ni3 25 2_655 59.83(2) ?
Ni1 Ni3 Ni3 13_554 2_655 119.66(2) ?
Ni3 Ni3 Ni3 3_665 2_655 60.0 ?
Ni3 Ni3 Ni1 3_565 25 119.79(2) ?
Ni3 Ni3 Ni1 2_665 25 119.79(2) ?
Ni2 Ni3 Ni1 25 25 109.52(5) ?
Ni1 Ni3 Ni1 13_554 25 69.86(3) ?
Ni3 Ni3 Ni1 3_665 25 60.21(2) ?
Ni3 Ni3 Ni1 2_655 25 60.21(2) ?
Ni3 Ni3 In1 3_565 1_665 116.583(18) ?
Ni3 Ni3 In1 2_665 1_665 63.762(18) ?
Ni2 Ni3 In1 25 1_665 68.05(2) ?
Ni1 Ni3 In1 13_554 1_665 112.12(2) ?
Ni3 Ni3 In1 3_665 1_665 63.417(18) ?
Ni3 Ni3 In1 2_655 1_665 116.238(18) ?
Ni1 Ni3 In1 25 1_665 111.86(2) ?
Ni3 Ni3 In1 3_565 . 63.762(18) ?
Ni3 Ni3 In1 2_665 . 116.583(18) ?
Ni2 Ni3 In1 25 . 68.05(2) ?
Ni1 Ni3 In1 13_554 . 112.12(2) ?
Ni3 Ni3 In1 3_665 . 116.238(18) ?
Ni3 Ni3 In1 2_655 . 63.417(18) ?
Ni1 Ni3 In1 25 . 111.86(2) ?
In1 Ni3 In1 1_665 . 125.64(5) ?
Ni3 Ni3 Eu1 3_565 . 67.479(15) ?
Ni3 Ni3 Eu1 2_665 . 112.811(15) ?
Ni2 Ni3 Eu1 25 . 121.16(2) ?
Ni1 Ni3 Eu1 13_554 . 58.577(18) ?
Ni3 Ni3 Eu1 3_665 . 112.521(15) ?
Ni3 Ni3 Eu1 2_655 . 67.189(15) ?
Ni1 Ni3 Eu1 25 . 58.437(19) ?
In1 Ni3 Eu1 1_665 . 167.59(3) ?
In1 Ni3 Eu1 . . 66.76(2) ?
Ni3 Ni3 Eu1 3_565 1_665 112.811(15) ?
Ni3 Ni3 Eu1 2_665 1_665 67.479(15) ?
Ni2 Ni3 Eu1 25 1_665 121.16(2) ?
Ni1 Ni3 Eu1 13_554 1_665 58.577(18) ?
Ni3 Ni3 Eu1 3_665 1_665 67.189(15) ?
Ni3 Ni3 Eu1 2_655 1_665 112.521(15) ?
Ni1 Ni3 Eu1 25 1_665 58.437(19) ?
In1 Ni3 Eu1 1_665 1_665 66.76(2) ?
In1 Ni3 Eu1 . 1_665 167.59(3) ?
Eu1 Ni3 Eu1 . 1_665 100.84(3) ?
Ni3 Ni3 Eu2 3_565 13_554 68.045(13) ?
Ni3 Ni3 Eu2 2_665 13_554 68.045(13) ?
Ni2 Ni3 Eu2 25 13_554 61.05(3) ?
Ni1 Ni3 Eu2 13_554 13_554 119.57(4) ?
Ni3 Ni3 Eu2 3_665 13_554 111.955(13) ?
Ni3 Ni3 Eu2 2_655 13_554 111.955(13) ?
Ni1 Ni3 Eu2 25 13_554 170.57(4) ?
In1 Ni3 Eu2 1_665 13_554 65.75(2) ?
In1 Ni3 Eu2 . 13_554 65.75(2) ?
Eu1 Ni3 Eu2 . 13_554 125.162(17) ?
Eu1 Ni3 Eu2 1_665 13_554 125.162(17) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Eu1 Ni1 25 2.8265(4) ?
Eu1 Ni1 25_445 2.8265(4) ?
Eu1 Ni1 13_554 2.8265(4) ?
Eu1 Ni1 13_444 2.8265(4) ?
Eu1 Ni1 25_455 2.8265(4) ?
Eu1 Ni1 13_544 2.8265(4) ?
Eu1 Ni3 . 3.1760(7) ?
Eu1 Ni3 19 3.1760(7) ?
Eu1 Ni3 21_545 3.1760(7) ?
Eu1 Ni3 3_565 3.1760(7) ?
Eu1 Ni3 2_655 3.1760(7) ?
Eu1 Ni3 20_455 3.1760(7) ?
Eu2 Ni2 31_445 2.9785(6) ?
Eu2 Ni2 7 2.9785(6) ?
Eu2 Ni2 31 2.9785(6) ?
Eu2 Ni2 7_445 2.9785(6) ?
Eu2 Ni2 31_545 2.9785(6) ?
Eu2 Ni2 7_455 2.9785(6) ?
Eu2 Ni3 31 3.2536(10) ?
Eu2 Ni3 7_445 3.2536(10) ?
Eu2 Ni3 33_545 3.2537(10) ?
Eu2 Ni3 9_455 3.2537(10) ?
Eu2 Ni3 32_445 3.2537(10) ?
Eu2 Ni3 8 3.2537(10) ?
In1 Ni2 . 2.6175(19) ?
In1 Ni3 1_445 2.7516(7) ?
In1 Ni3 2 2.7516(7) ?
In1 Ni3 3 2.7516(7) ?
In1 Ni3 . 2.7516(7) ?
In1 Ni3 2_655 2.7516(7) ?
In1 Ni3 3_565 2.7516(7) ?
In1 Ni2 25 2.9214(6) ?
In1 Ni2 25_445 2.9214(6) ?
In1 Ni2 25_455 2.9214(6) ?
In1 Eu2 13_554 3.2870(6) ?
Ni1 Ni3 7_445 2.4581(15) ?
Ni1 Ni3 8 2.4581(15) ?
Ni1 Ni3 9_455 2.4581(15) ?
Ni1 Ni3 25 2.4784(16) ?
Ni1 Ni3 27_445 2.4784(16) ?
Ni1 Ni3 26_455 2.4784(16) ?
Ni1 Eu1 7 2.8265(4) ?
Ni1 Eu1 7_445 2.8265(4) ?
Ni1 Ni1 31_445 2.8265(4) ?
Ni1 Ni1 31 2.8265(4) ?
Ni1 Eu1 7_455 2.8265(4) ?
Ni1 Ni1 31_545 2.8265(4) ?
Ni2 Ni3 25 2.4502(16) ?
Ni2 Ni3 26_455 2.4503(16) ?
Ni2 Ni3 27_445 2.4503(16) ?
Ni2 In1 25 2.9214(6) ?
Ni2 In1 25_445 2.9214(6) ?
Ni2 In1 25_455 2.9214(6) ?
Ni2 Eu2 13_444 2.9785(6) ?
Ni2 Eu2 13_554 2.9785(6) ?
Ni2 Eu2 13_544 2.9785(6) ?
Ni3 Ni3 3_565 2.4330(15) ?
Ni3 Ni3 2_665 2.4330(15) ?
Ni3 Ni2 25 2.4502(16) ?
Ni3 Ni1 13_554 2.4581(15) ?
Ni3 Ni3 3_665 2.4626(15) ?
Ni3 Ni3 2_655 2.4626(15) ?
Ni3 Ni1 25 2.4784(16) ?
Ni3 In1 1_665 2.7516(7) ?
Ni3 Eu1 1_665 3.1760(7) ?
Ni3 Eu2 13_554 3.2536(10) ?
