#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/87/2018764.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2018764
loop_
_publ_author_name
'Cai, Hua'
'Guo, Ying'
'Li, Jian-Gang'
_publ_section_title
;
 Controllable assembly of a three-dimensional metal--organic
 supramolecular framework including π--π stacking interactions
;
_journal_coeditor_code           SK3461
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              8
_journal_page_last               10
_journal_paper_doi               10.1107/S0108270112048937
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          '[Cu2 (C8 H4 O4) (C8 H6 N3)2]'
_chemical_formula_moiety         'C24 H16 Cu2 N6 O4'
_chemical_formula_sum            'C24 H16 Cu2 N6 O4'
_chemical_formula_weight         579.51
_chemical_name_systematic
;
poly[(μ₃-phthalato)[μ₂-3-(pyridin-2-yl)-1H-pyrazol-1-
ido]dicopper(II)]
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.639(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.752(2)
_cell_length_b                   20.566(7)
_cell_length_c                   14.141(4)
_cell_measurement_reflns_used    4370
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      28.41
_cell_measurement_theta_min      2.46
_cell_volume                     2222.6(11)
_computing_cell_refinement       'APEX2 (Bruker, 2003)'
_computing_data_collection       'APEX2 (Bruker, 2003)'
_computing_data_reduction        'SAINT (Bruker, 2003)'
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg et al.,
2005)
;
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.991
_diffrn_measured_fraction_theta_max 0.991
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0244
_diffrn_reflns_av_sigmaI/netI    0.0332
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       25
_diffrn_reflns_limit_k_min       -26
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -13
_diffrn_reflns_number            12705
_diffrn_reflns_theta_full        27.03
_diffrn_reflns_theta_max         27.03
_diffrn_reflns_theta_min         1.76
_exptl_absorpt_coefficient_mu    1.960
_exptl_absorpt_correction_T_max  0.6952
_exptl_absorpt_correction_T_min  0.6098
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2003)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.732
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1168
_exptl_crystal_size_max          0.28
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.20
_refine_diff_density_max         0.383
_refine_diff_density_min         -0.361
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         4813
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.0591
_refine_ls_R_factor_gt           0.0297
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0287P)²+1.8398P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0648
_refine_ls_wR_factor_ref         0.0791
_reflns_number_gt                3469
_reflns_number_total             4813
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            sk3461.cif
_cod_data_source_block           I
_cod_original_cell_volume        2222.7(12)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2018764
_cod_database_fobs_code          2018764
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Cu Cu1 0.76108(4) 0.759298(16) 0.57840(2) 0.02923(10) Uani d . 1 1
Cu Cu2 1.05463(4) 0.805560(16) 0.82856(2) 0.02947(10) Uani d . 1 1
O O1 0.6334(2) 0.68530(9) 0.51198(14) 0.0315(4) Uani d . 1 1
O O2 0.8618(3) 0.68147(11) 0.43756(18) 0.0504(6) Uani d . 1 1
O O3 0.3944(3) 0.67498(10) 0.30964(14) 0.0379(5) Uani d . 1 1
O O4 0.2065(2) 0.62158(9) 0.38407(15) 0.0353(5) Uani d . 1 1
N N1 0.6539(3) 0.82191(11) 0.47260(17) 0.0340(6) Uani d . 1 1
N N2 0.8424(3) 0.84219(11) 0.64051(17) 0.0316(5) Uani d . 1 1
N N3 0.9415(3) 0.86178(11) 0.72439(17) 0.0338(6) Uani d . 1 1
N N4 1.1584(3) 0.74380(11) 0.93560(17) 0.0299(5) Uani d . 1 1
N N5 0.9626(3) 0.72221(11) 0.76932(16) 0.0299(5) Uani d . 1 1
N N6 0.8685(3) 0.70246(11) 0.68402(17) 0.0336(6) Uani d . 1 1
C C1 0.5582(4) 0.80677(16) 0.3870(2) 0.0415(8) Uani d . 1 1
H H1 0.5422 0.7632 0.3701 0.050 Uiso calc R 1 1
C C2 0.4833(5) 0.85353(17) 0.3237(2) 0.0485(9) Uani d . 1 1
H H2 0.4170 0.8415 0.2653 0.058 Uiso calc R 1 1
C C3 0.5071(5) 0.91833(17) 0.3474(2) 0.0501(9) Uani d . 1 1
H H3 0.4570 0.9505 0.3054 0.060 Uiso calc R 1 1
C C4 0.6069(5) 0.93459(16) 0.4347(2) 0.0450(8) Uani d . 1 1
H H4 0.6257 0.9779 0.4521 0.054 Uiso calc R 1 1
C C5 0.6783(4) 0.88528(14) 0.4958(2) 0.0349(7) Uani d . 1 1
C C6 0.7846(4) 0.89583(14) 0.5904(2) 0.0352(7) Uani d . 1 1
C C7 0.8445(5) 0.95050(15) 0.6410(2) 0.0475(9) Uani d . 1 1
H H7 0.8239 0.9937 0.6231 0.057 Uiso calc R 1 1
C C8 0.9427(4) 0.92699(14) 0.7249(2) 0.0441(8) Uani d . 1 1
H H8 1.0010 0.9526 0.7743 0.053 Uiso calc R 1 1
C C9 1.2500(4) 0.76037(16) 1.0207(2) 0.0384(7) Uani d . 1 1
H H9 1.2807 0.8038 1.0319 0.046 Uiso calc R 1 1
C C10 1.3011(4) 0.71566(17) 1.0928(2) 0.0464(8) Uani d . 1 1
H H10 1.3664 0.7285 1.1511 0.056 Uiso calc R 1 1
C C11 1.2530(4) 0.65144(17) 1.0764(2) 0.0468(8) Uani d . 1 1
H H11 1.2849 0.6203 1.1238 0.056 Uiso calc R 1 1
C C12 1.1568(4) 0.63395(15) 0.9889(2) 0.0417(8) Uani d . 1 1
H H12 1.1231 0.5909 0.9768 0.050 Uiso calc R 1 1
C C13 1.1113(4) 0.68106(14) 0.9196(2) 0.0322(7) Uani d . 1 1
C C14 1.0087(4) 0.66960(14) 0.8242(2) 0.0323(7) Uani d . 1 1
C C15 0.9430(5) 0.61432(15) 0.7750(2) 0.0481(9) Uani d . 1 1
H H15 0.9545 0.5714 0.7959 0.058 Uiso calc R 1 1
C C16 0.8565(5) 0.63704(14) 0.6877(2) 0.0461(8) Uani d . 1 1
H H16 0.7985 0.6110 0.6387 0.055 Uiso calc R 1 1
C C17 0.6653(4) 0.59072(13) 0.42102(19) 0.0278(6) Uani d . 1 1
C C18 0.7891(4) 0.54115(16) 0.4341(2) 0.0395(7) Uani d . 1 1
H H18 0.9065 0.5512 0.4538 0.047 Uiso calc R 1 1
C C19 0.7391(4) 0.47669(15) 0.4179(2) 0.0414(8) Uani d . 1 1
H H19 0.8224 0.4438 0.4273 0.050 Uiso calc R 1 1
C C20 0.5647(4) 0.46185(14) 0.3878(2) 0.0380(7) Uani d . 1 1
H H20 0.5300 0.4187 0.3788 0.046 Uiso calc R 1 1
C C21 0.4416(4) 0.51109(14) 0.3710(2) 0.0333(7) Uani d . 1 1
H H21 0.3250 0.5007 0.3491 0.040 Uiso calc R 1 1
C C22 0.4901(3) 0.57597(13) 0.38658(18) 0.0264(6) Uani d . 1 1
C C23 0.7249(4) 0.65767(14) 0.4558(2) 0.0301(6) Uani d . 1 1
C C24 0.3562(4) 0.62900(13) 0.35832(19) 0.0283(6) Uani d . 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O1 Cu1 N6 . . 91.03(9) yes
O1 Cu1 N2 . . 168.38(9) yes
N6 Cu1 N2 . . 96.45(10) yes
O1 Cu1 N1 . . 91.58(9) yes
N6 Cu1 N1 . . 177.34(10) yes
N2 Cu1 N1 . . 80.89(10) yes
N3 Cu2 O4 . 4_676 90.75(9) yes
N3 Cu2 N5 . . 96.21(10) yes
O4 Cu2 N5 4_676 . 164.89(9) yes
N3 Cu2 N4 . . 176.46(10) yes
O4 Cu2 N4 4_676 . 92.44(9) yes
N5 Cu2 N4 . . 81.05(10) yes
N3 Cu2 O2 . 4_576 99.98(10) yes
O4 Cu2 O2 4_676 4_576 93.18(9) yes
N5 Cu2 O2 . 4_576 98.78(9) yes
N4 Cu2 O2 . 4_576 78.31(9) yes
C23 O1 Cu1 . . 110.63(17) ?
C23 O2 Cu2 . 4_575 148.3(2) ?
C24 O4 Cu2 . 4_475 107.64(17) ?
C1 N1 C5 . . 118.4(3) ?
C1 N1 Cu1 . . 127.5(2) ?
C5 N1 Cu1 . . 114.1(2) ?
C6 N2 N3 . . 107.8(2) ?
C6 N2 Cu1 . . 114.85(19) ?
N3 N2 Cu1 . . 137.33(18) ?
C8 N3 N2 . . 107.6(2) ?
C8 N3 Cu2 . . 125.7(2) ?
N2 N3 Cu2 . . 126.60(17) ?
C9 N4 C13 . . 118.9(3) ?
C9 N4 Cu2 . . 126.5(2) ?
C13 N4 Cu2 . . 114.18(19) ?
C14 N5 N6 . . 108.8(2) ?
C14 N5 Cu2 . . 114.13(19) ?
N6 N5 Cu2 . . 137.00(18) ?
C16 N6 N5 . . 107.0(2) ?
C16 N6 Cu1 . . 126.7(2) ?
N5 N6 Cu1 . . 126.18(18) ?
N1 C1 C2 . . 122.2(3) ?
N1 C1 H1 . . 118.9 ?
C2 C1 H1 . . 118.9 ?
C1 C2 C3 . . 119.6(3) ?
C1 C2 H2 . . 120.2 ?
C3 C2 H2 . . 120.2 ?
C2 C3 C4 . . 118.8(3) ?
C2 C3 H3 . . 120.6 ?
C4 C3 H3 . . 120.6 ?
C3 C4 C5 . . 119.0(3) ?
C3 C4 H4 . . 120.5 ?
C5 C4 H4 . . 120.5 ?
N1 C5 C4 . . 122.0(3) ?
N1 C5 C6 . . 113.5(3) ?
C4 C5 C6 . . 124.5(3) ?
N2 C6 C7 . . 110.0(3) ?
N2 C6 C5 . . 116.5(3) ?
C7 C6 C5 . . 133.5(3) ?
C6 C7 C8 . . 104.5(3) ?
C6 C7 H7 . . 127.7 ?
C8 C7 H7 . . 127.7 ?
N3 C8 C7 . . 110.0(3) ?
N3 C8 H8 . . 125.0 ?
C7 C8 H8 . . 125.0 ?
N4 C9 C10 . . 122.6(3) ?
N4 C9 H9 . . 118.7 ?
C10 C9 H9 . . 118.7 ?
C9 C10 C11 . . 118.5(3) ?
C9 C10 H10 . . 120.8 ?
C11 C10 H10 . . 120.8 ?
C12 C11 C10 . . 119.3(3) ?
C12 C11 H11 . . 120.4 ?
C10 C11 H11 . . 120.4 ?
C11 C12 C13 . . 119.2(3) ?
C11 C12 H12 . . 120.4 ?
C13 C12 H12 . . 120.4 ?
N4 C13 C12 . . 121.5(3) ?
N4 C13 C14 . . 113.5(2) ?
C12 C13 C14 . . 125.1(3) ?
N5 C14 C15 . . 109.3(3) ?
N5 C14 C13 . . 116.9(3) ?
C15 C14 C13 . . 133.8(3) ?
C16 C15 C14 . . 104.7(3) ?
C16 C15 H15 . . 127.6 ?
C14 C15 H15 . . 127.6 ?
N6 C16 C15 . . 110.2(3) ?
N6 C16 H16 . . 124.9 ?
C15 C16 H16 . . 124.9 ?
C18 C17 C22 . . 119.7(3) ?
C18 C17 C23 . . 117.3(3) ?
C22 C17 C23 . . 122.6(2) ?
C19 C18 C17 . . 120.7(3) ?
C19 C18 H18 . . 119.7 ?
C17 C18 H18 . . 119.7 ?
C20 C19 C18 . . 119.6(3) ?
C20 C19 H19 . . 120.2 ?
C18 C19 H19 . . 120.2 ?
C19 C20 C21 . . 120.1(3) ?
C19 C20 H20 . . 119.9 ?
C21 C20 H20 . . 119.9 ?
C20 C21 C22 . . 120.9(3) ?
C20 C21 H21 . . 119.6 ?
C22 C21 H21 . . 119.6 ?
C21 C22 C17 . . 118.9(3) ?
C21 C22 C24 . . 119.6(2) ?
C17 C22 C24 . . 121.3(2) ?
O2 C23 O1 . . 122.5(3) ?
O2 C23 C17 . . 121.4(3) ?
O1 C23 C17 . . 115.8(2) ?
O3 C24 O4 . . 124.2(3) ?
O3 C24 C22 . . 118.8(3) ?
O4 C24 C22 . . 116.9(2) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 O1 . 1.9663(19) yes
Cu1 N6 . 1.968(2) yes
Cu1 N2 . 1.972(2) yes
Cu1 N1 . 2.042(2) yes
Cu2 N3 . 1.960(2) yes
Cu2 O4 4_676 1.984(2) yes
Cu2 N5 . 1.987(2) yes
Cu2 N4 . 2.036(2) yes
Cu2 O2 4_576 2.335(2) yes
O1 C23 . 1.283(3) ?
O2 C23 . 1.234(3) ?
O2 Cu2 4_575 2.335(2) ?
O3 C24 . 1.235(3) ?
O4 C24 . 1.283(3) ?
O4 Cu2 4_475 1.984(2) ?
N1 C1 . 1.346(4) ?
N1 C5 . 1.350(4) ?
N2 C6 . 1.347(4) ?
N2 N3 . 1.362(3) ?
N3 C8 . 1.341(4) ?
N4 C9 . 1.335(4) ?
N4 C13 . 1.350(4) ?
N5 C14 . 1.345(3) ?
N5 N6 . 1.363(3) ?
N6 C16 . 1.350(4) ?
C1 C2 . 1.374(4) ?
C1 H1 . 0.9300 ?
C2 C3 . 1.379(5) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.384(5) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.386(4) ?
C4 H4 . 0.9300 ?
C5 C6 . 1.465(4) ?
C6 C7 . 1.372(4) ?
C7 C8 . 1.385(4) ?
C7 H7 . 0.9300 ?
C8 H8 . 0.9300 ?
C9 C10 . 1.381(4) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.381(5) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.381(5) ?
C11 H11 . 0.9300 ?
C12 C13 . 1.381(4) ?
C12 H12 . 0.9300 ?
C13 C14 . 1.466(4) ?
C14 C15 . 1.385(4) ?
C15 C16 . 1.383(4) ?
C15 H15 . 0.9300 ?
C16 H16 . 0.9300 ?
C17 C18 . 1.391(4) ?
C17 C22 . 1.397(4) ?
C17 C23 . 1.508(4) ?
C18 C19 . 1.389(4) ?
C18 H18 . 0.9300 ?
C19 C20 . 1.381(4) ?
C19 H19 . 0.9300 ?
C20 C21 . 1.385(4) ?
C20 H20 . 0.9300 ?
C21 C22 . 1.394(4) ?
C21 H21 . 0.9300 ?
C22 C24 . 1.512(4) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
N6 Cu1 O1 C23 . -89.56(19)
N2 Cu1 O1 C23 . 140.2(4)
N1 Cu1 O1 C23 . 90.93(19)
O1 Cu1 N1 C1 . -9.3(3)
N2 Cu1 N1 C1 . 179.6(3)
O1 Cu1 N1 C5 . 167.5(2)
N2 Cu1 N1 C5 . -3.6(2)
O1 Cu1 N2 C6 . -46.6(6)
N6 Cu1 N2 C6 . -176.4(2)
N1 Cu1 N2 C6 . 3.6(2)
O1 Cu1 N2 N3 . 131.4(4)
N6 Cu1 N2 N3 . 1.6(3)
N1 Cu1 N2 N3 . -178.5(3)
C6 N2 N3 C8 . 0.3(3)
Cu1 N2 N3 C8 . -177.8(2)
C6 N2 N3 Cu2 . 177.9(2)
Cu1 N2 N3 Cu2 . -0.1(4)
O4 Cu2 N3 C8 4_676 -18.9(3)
N5 Cu2 N3 C8 . 174.5(3)
O2 Cu2 N3 C8 4_576 74.5(3)
O4 Cu2 N3 N2 4_676 163.8(2)
N5 Cu2 N3 N2 . -2.7(2)
O2 Cu2 N3 N2 4_576 -102.8(2)
O4 Cu2 N4 C9 4_676 17.5(2)
N5 Cu2 N4 C9 . -176.2(3)
O2 Cu2 N4 C9 4_576 -75.2(2)
O4 Cu2 N4 C13 4_676 -169.7(2)
N5 Cu2 N4 C13 . -3.4(2)
O2 Cu2 N4 C13 4_576 97.6(2)
N3 Cu2 N5 C14 . -177.4(2)
O4 Cu2 N5 C14 4_676 65.7(4)
N4 Cu2 N5 C14 . 0.4(2)
O2 Cu2 N5 C14 4_576 -76.2(2)
N3 Cu2 N5 N6 . 6.1(3)
O4 Cu2 N5 N6 4_676 -110.9(4)
N4 Cu2 N5 N6 . -176.2(3)
O2 Cu2 N5 N6 4_576 107.2(3)
C14 N5 N6 C16 . 0.4(3)
Cu2 N5 N6 C16 . 177.1(2)
C14 N5 N6 Cu1 . 177.7(2)
Cu2 N5 N6 Cu1 . -5.7(4)
O1 Cu1 N6 C16 . 6.7(3)
N2 Cu1 N6 C16 . 177.8(3)
O1 Cu1 N6 N5 . -170.0(2)
N2 Cu1 N6 N5 . 1.1(2)
C5 N1 C1 C2 . -0.9(5)
Cu1 N1 C1 C2 . 175.8(3)
N1 C1 C2 C3 . 0.5(5)
C1 C2 C3 C4 . 0.2(6)
C2 C3 C4 C5 . -0.5(5)
C1 N1 C5 C4 . 0.5(5)
Cu1 N1 C5 C4 . -176.6(3)
C1 N1 C5 C6 . -179.9(3)
Cu1 N1 C5 C6 . 3.0(3)
C3 C4 C5 N1 . 0.2(5)
C3 C4 C5 C6 . -179.3(3)
N3 N2 C6 C7 . -0.3(4)
Cu1 N2 C6 C7 . 178.3(2)
N3 N2 C6 C5 . 178.4(3)
Cu1 N2 C6 C5 . -3.0(4)
N1 C5 C6 N2 . -0.1(4)
C4 C5 C6 N2 . 179.5(3)
N1 C5 C6 C7 . 178.2(4)
C4 C5 C6 C7 . -2.2(6)
N2 C6 C7 C8 . 0.2(4)
C5 C6 C7 C8 . -178.2(4)
N2 N3 C8 C7 . -0.1(4)
Cu2 N3 C8 C7 . -177.9(2)
C6 C7 C8 N3 . 0.0(4)
C13 N4 C9 C10 . 1.0(5)
Cu2 N4 C9 C10 . 173.5(2)
N4 C9 C10 C11 . -1.0(5)
C9 C10 C11 C12 . 0.4(5)
C10 C11 C12 C13 . 0.1(5)
C9 N4 C13 C12 . -0.5(4)
Cu2 N4 C13 C12 . -173.8(2)
C9 N4 C13 C14 . 178.9(3)
Cu2 N4 C13 C14 . 5.6(3)
C11 C12 C13 N4 . -0.1(5)
C11 C12 C13 C14 . -179.4(3)
N6 N5 C14 C15 . -0.5(3)
Cu2 N5 C14 C15 . -178.0(2)
N6 N5 C14 C13 . -179.9(2)
Cu2 N5 C14 C13 . 2.6(3)
N4 C13 C14 N5 . -5.5(4)
C12 C13 C14 N5 . 173.9(3)
N4 C13 C14 C15 . 175.3(3)
C12 C13 C14 C15 . -5.4(6)
N5 C14 C15 C16 . 0.3(4)
C13 C14 C15 C16 . 179.7(3)
N5 N6 C16 C15 . -0.2(4)
Cu1 N6 C16 C15 . -177.4(2)
C14 C15 C16 N6 . -0.1(4)
C22 C17 C18 C19 . -3.3(5)
C23 C17 C18 C19 . 169.9(3)
C17 C18 C19 C20 . 0.5(5)
C18 C19 C20 C21 . 2.0(5)
C19 C20 C21 C22 . -1.7(5)
C20 C21 C22 C17 . -1.0(4)
C20 C21 C22 C24 . 173.9(3)
C18 C17 C22 C21 . 3.5(4)
C23 C17 C22 C21 . -169.3(3)
C18 C17 C22 C24 . -171.4(3)
C23 C17 C22 C24 . 15.8(4)
Cu2 O2 C23 O1 4_575 -149.6(3)
Cu2 O2 C23 C17 4_575 36.8(6)
Cu1 O1 C23 O2 . -9.6(3)
Cu1 O1 C23 C17 . 164.29(18)
C18 C17 C23 O2 . 46.8(4)
C22 C17 C23 O2 . -140.2(3)
C18 C17 C23 O1 . -127.2(3)
C22 C17 C23 O1 . 45.8(4)
Cu2 O4 C24 O3 4_475 1.6(3)
Cu2 O4 C24 C22 4_475 -175.63(18)
C21 C22 C24 O3 . -130.1(3)
C17 C22 C24 O3 . 44.7(4)
C21 C22 C24 O4 . 47.3(4)
C17 C22 C24 O4 . -137.9(3)
