#------------------------------------------------------------------------------
#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/93/2019301.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2019301
loop_
_publ_author_name
'Schäfer, Marion C.'
'Bobev, Svilen'
_publ_section_title
;
 On the possibility for Rb- and Eu-cation ordering in type-I clathrates:
 synthesis and homogeneity range of the novel compounds
 Rb~8{--~x}Euₓ(In,Ge)₄₆ (0.6 {łeq} x {łeq}
 1.8)
;
_journal_coeditor_code           FN3157
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              1457
_journal_page_last               1461
_journal_paper_doi               10.1107/S0108270113030011
_journal_volume                  69
_journal_year                    2013
_chemical_formula_iupac          'Rb6.30 Eu1.70 In9.76 Ge36.24'
_chemical_formula_moiety         'Rb6.30(3) Eu1.70(3) In9.76(4) Ge36.24(4)'
_chemical_formula_sum            'Eu1.7 Ge36.24 In9.76 Rb6.3'
_chemical_formula_weight         4548.10
_chemical_name_systematic
;
Hexarubidium dieuropium decaindium hexatriacontagermanide
;
_space_group_IT_number           223
_symmetry_cell_setting           cubic
_symmetry_space_group_name_Hall  '-P 4n 2 3'
_symmetry_space_group_name_H-M   'P m -3 n'
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            1
_cell_length_a                   11.0592(3)
_cell_length_b                   11.0592(3)
_cell_length_c                   11.0592(3)
_cell_measurement_reflns_used    1018
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      26.88
_cell_measurement_theta_min      2.60
_cell_volume                     1352.61(6)
_computing_cell_refinement       'SMART (Bruker, 2002)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        'SAINT (Bruker, 2002)'
_computing_molecular_graphics    'CrystalMaker (CrystalMaker, 2007)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'ω and φ'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0646
_diffrn_reflns_av_sigmaI/netI    0.0123
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            16518
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.04
_diffrn_reflns_theta_min         2.60
_exptl_absorpt_coefficient_mu    31.407
_exptl_absorpt_correction_T_max  0.2770
_exptl_absorpt_correction_T_min  0.1988
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2008)'
_exptl_crystal_colour            silver--grey
_exptl_crystal_density_diffrn    5.584
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       irregular
_exptl_crystal_F_000             1978
_exptl_crystal_size_max          0.08
_exptl_crystal_size_mid          0.06
_exptl_crystal_size_min          0.05
_refine_diff_density_max         0.429
_refine_diff_density_min         -0.705
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.147
_refine_ls_matrix_type           full
_refine_ls_number_parameters     20
_refine_ls_number_reflns         324
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.147
_refine_ls_R_factor_all          0.0196
_refine_ls_R_factor_gt           0.0161
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0080P)²+6.2731P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0296
_refine_ls_wR_factor_ref         0.0307
_reflns_number_gt                295
_reflns_number_total             324
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            fn3157.cif
_cod_data_source_block           II
_cod_original_formula_sum        'Eu1.70 Ge36.24 In9.76 Rb6.30'
_cod_database_code               2019301
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, z'
'-x, y, -z'
'x, -y, -z'
'z, x, y'
'z, -x, -y'
'-z, -x, y'
'-z, x, -y'
'y, z, x'
'-y, z, -x'
'y, -z, -x'
'-y, -z, x'
'y+1/2, x+1/2, -z+1/2'
'-y+1/2, -x+1/2, -z+1/2'
'y+1/2, -x+1/2, z+1/2'
'-y+1/2, x+1/2, z+1/2'
'x+1/2, z+1/2, -y+1/2'
'-x+1/2, z+1/2, y+1/2'
'-x+1/2, -z+1/2, -y+1/2'
'x+1/2, -z+1/2, y+1/2'
'z+1/2, y+1/2, -x+1/2'
'z+1/2, -y+1/2, x+1/2'
'-z+1/2, y+1/2, x+1/2'
'-z+1/2, -y+1/2, -x+1/2'
'-x, -y, -z'
'x, y, -z'
'x, -y, z'
'-x, y, z'
'-z, -x, -y'
'-z, x, y'
'z, x, -y'
'z, -x, y'
'-y, -z, -x'
'y, -z, x'
'-y, z, x'
'y, z, -x'
'-y-1/2, -x-1/2, z-1/2'
'y-1/2, x-1/2, z-1/2'
'-y-1/2, x-1/2, -z-1/2'
'y-1/2, -x-1/2, -z-1/2'
'-x-1/2, -z-1/2, y-1/2'
'x-1/2, -z-1/2, -y-1/2'
'x-1/2, z-1/2, y-1/2'
'-x-1/2, z-1/2, -y-1/2'
'-z-1/2, -y-1/2, x-1/2'
'-z-1/2, y-1/2, -x-1/2'
'z-1/2, -y-1/2, -x-1/2'
'z-1/2, y-1/2, x-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Ge Ge1 0.0000 0.30045(5) 0.11392(5) 0.00995(12) Uani d SP 0.97 2
In In1 0.0000 0.30045(5) 0.11392(5) 0.00995(12) Uani d SP 0.03 2
Ge Ge2 0.18311(3) 0.18311(3) 0.18311(3) 0.00920(13) Uani d SP 0.81 3
In In2 0.18311(3) 0.18311(3) 0.18311(3) 0.00920(13) Uani d SP 0.19 3
In In3 0.2500 0.0000 0.5000 0.00946(15) Uani d S 1 8
Rb Rb1 0.2500 0.5000 0.0000 0.0203(2) Uani d S 1 8
Eu Eu2 0.0000 0.0000 0.0000 0.0146(2) Uani d SP 0.85 24
Rb Rb2 0.0000 0.0000 0.0000 0.0146(2) Uani d SP 0.15 24
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Ge Ge 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
In In -0.7276 1.3100 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
In1 Ge1 In2 26 28 107.647(13)
Ge1 Ge1 In2 26 28 107.647(13)
In1 Ge1 Ge2 26 28 107.647(13)
Ge1 Ge1 Ge2 26 28 107.647(13)
In1 Ge1 Ge2 26 . 107.648(13)
Ge1 Ge1 Ge2 26 . 107.648(13)
In2 Ge1 Ge2 28 . 106.71(2)
Ge2 Ge1 Ge2 28 . 106.71(2)
In1 Ge1 In3 26 9 124.291(11)
Ge1 Ge1 In3 26 9 124.291(11)
In2 Ge1 In3 28 9 104.715(18)
Ge2 Ge1 In3 28 9 104.715(18)
Ge2 Ge1 In3 . 9 104.714(18)
In1 Ge1 Eu2 26 . 69.236(8)
Ge1 Ge1 Eu2 26 . 69.236(8)
In2 Ge1 Eu2 28 . 68.081(17)
Ge2 Ge1 Eu2 28 . 68.081(17)
Ge2 Ge1 Eu2 . . 68.081(17)
In3 Ge1 Eu2 9 . 166.474(19)
In1 Ge1 Rb1 26 . 70.397(8)
Ge1 Ge1 Rb1 26 . 70.397(8)
In2 Ge1 Rb1 28 . 174.039(17)
Ge2 Ge1 Rb1 28 . 174.039(17)
Ge2 Ge1 Rb1 . . 79.231(8)
In3 Ge1 Rb1 9 . 72.752(9)
Eu2 Ge1 Rb1 . . 115.503(10)
In1 Ge1 Rb1 26 25_565 70.397(8)
Ge1 Ge1 Rb1 26 25_565 70.397(8)
In2 Ge1 Rb1 28 25_565 79.232(8)
Ge2 Ge1 Rb1 28 25_565 79.232(8)
Ge2 Ge1 Rb1 . 25_565 174.039(17)
In3 Ge1 Rb1 9 25_565 72.752(9)
Eu2 Ge1 Rb1 . 25_565 115.503(10)
Rb1 Ge1 Rb1 . 25_565 94.827(11)
Ge1 Ge2 In1 . 9 108.976(17)
Ge1 Ge2 In1 . 5 108.977(17)
In1 Ge2 In1 9 5 108.977(17)
Ge1 Ge2 Ge1 . 9 108.976(17)
In1 Ge2 Ge1 5 9 108.977(17)
Ge1 Ge2 Ge1 . 5 108.977(17)
In1 Ge2 Ge1 9 5 108.977(17)
Ge1 Ge2 Ge1 9 5 108.977(17)
Ge1 Ge2 In2 . 14 109.962(17)
In1 Ge2 In2 9 14 109.961(16)
In1 Ge2 In2 5 14 109.961(17)
Ge1 Ge2 In2 9 14 109.961(16)
Ge1 Ge2 In2 5 14 109.961(17)
Ge1 Ge2 Ge2 . 14 109.962(17)
In1 Ge2 Ge2 9 14 109.961(16)
In1 Ge2 Ge2 5 14 109.961(17)
Ge1 Ge2 Ge2 9 14 109.961(16)
Ge1 Ge2 Ge2 5 14 109.961(17)
Ge1 Ge2 Eu2 . . 70.038(17)
In1 Ge2 Eu2 9 . 70.039(17)
In1 Ge2 Eu2 5 . 70.039(17)
Ge1 Ge2 Eu2 9 . 70.039(17)
Ge1 Ge2 Eu2 5 . 70.039(17)
In2 Ge2 Eu2 14 . 180.00(4)
Ge2 Ge2 Eu2 14 . 180.00(4)
Ge1 Ge2 Rb1 . 9 172.276(11)
In1 Ge2 Rb1 9 9 63.712(10)
In1 Ge2 Rb1 5 9 76.755(11)
Ge1 Ge2 Rb1 9 9 63.712(10)
Ge1 Ge2 Rb1 5 9 76.755(11)
In2 Ge2 Rb1 14 9 71.856(7)
Ge2 Ge2 Rb1 14 9 71.856(7)
Eu2 Ge2 Rb1 . 9 108.144(7)
Ge1 Ge2 Rb1 . . 63.712(10)
In1 Ge2 Rb1 9 . 76.755(11)
In1 Ge2 Rb1 5 . 172.277(11)
Ge1 Ge2 Rb1 9 . 76.755(11)
Ge1 Ge2 Rb1 5 . 172.277(11)
In2 Ge2 Rb1 14 . 71.856(7)
Ge2 Ge2 Rb1 14 . 71.856(7)
Eu2 Ge2 Rb1 . . 108.144(7)
Rb1 Ge2 Rb1 9 . 110.765(7)
In1 In3 Ge1 45_666 5 108.507(11)
In1 In3 In1 45_666 5 108.507(11)
Ge1 In3 Ge1 5 45_666 108.507(11)
In1 In3 Ge1 5 45_666 108.507(11)
In1 In3 In1 45_666 46_656 111.42(2)
Ge1 In3 In1 5 46_656 108.507(11)
In1 In3 In1 5 46_656 108.507(11)
Ge1 In3 In1 45_666 46_656 111.42(2)
In1 In3 Ge1 45_666 46_656 111.42(2)
Ge1 In3 Ge1 5 46_656 108.507(11)
In1 In3 Ge1 5 46_656 108.507(11)
Ge1 In3 Ge1 45_666 46_656 111.42(2)
In1 In3 In1 45_666 6_556 108.507(11)
Ge1 In3 In1 5 6_556 111.42(2)
In1 In3 In1 5 6_556 111.42(2)
Ge1 In3 In1 45_666 6_556 108.507(11)
In1 In3 In1 46_656 6_556 108.507(11)
Ge1 In3 In1 46_656 6_556 108.507(11)
In1 In3 Ge1 45_666 6_556 108.507(11)
Ge1 In3 Ge1 5 6_556 111.42(2)
In1 In3 Ge1 5 6_556 111.42(2)
Ge1 In3 Ge1 45_666 6_556 108.507(11)
In1 In3 Ge1 46_656 6_556 108.507(11)
Ge1 In3 Ge1 46_656 6_556 108.507(11)
In1 In3 Rb1 45_666 33_656 66.523(7)
Ge1 In3 Rb1 5 33_656 169.291(11)
In1 In3 Rb1 5 33_656 169.291(11)
Ge1 In3 Rb1 45_666 33_656 66.523(7)
In1 In3 Rb1 46_656 33_656 66.523(7)
Ge1 In3 Rb1 46_656 33_656 66.523(7)
In1 In3 Rb1 6_556 33_656 79.291(11)
Ge1 In3 Rb1 6_556 33_656 79.291(11)
In1 In3 Rb1 45_666 29_556 169.291(11)
Ge1 In3 Rb1 5 29_556 66.523(7)
In1 In3 Rb1 5 29_556 66.523(7)
Ge1 In3 Rb1 45_666 29_556 169.291(11)
In1 In3 Rb1 46_656 29_556 79.291(11)
Ge1 In3 Rb1 46_656 29_556 79.291(11)
In1 In3 Rb1 6_556 29_556 66.523(7)
Ge1 In3 Rb1 6_556 29_556 66.523(7)
Rb1 In3 Rb1 33_656 29_556 120.0
In1 In3 Rb1 45_666 5 79.291(11)
Ge1 In3 Rb1 5 5 66.523(7)
In1 In3 Rb1 5 5 66.523(7)
Ge1 In3 Rb1 45_666 5 79.291(11)
In1 In3 Rb1 46_656 5 169.291(11)
Ge1 In3 Rb1 46_656 5 169.291(11)
In1 In3 Rb1 6_556 5 66.523(7)
Ge1 In3 Rb1 6_556 5 66.523(7)
Rb1 In3 Rb1 33_656 5 120.0
Rb1 In3 Rb1 29_556 5 90.0
In1 In3 Rb1 45_666 9 66.523(7)
Ge1 In3 Rb1 5 9 79.291(11)
In1 In3 Rb1 5 9 79.291(11)
Ge1 In3 Rb1 45_666 9 66.523(7)
In1 In3 Rb1 46_656 9 66.523(7)
Ge1 In3 Rb1 46_656 9 66.523(7)
In1 In3 Rb1 6_556 9 169.291(11)
Ge1 In3 Rb1 6_556 9 169.291(11)
Rb1 In3 Rb1 33_656 9 90.0
Rb1 In3 Rb1 29_556 9 120.0
Rb1 In3 Rb1 5 9 120.0
In1 Rb1 In1 17 26 159.458(16)
In1 Rb1 Ge1 26 17 159.458(16)
In1 Rb1 Ge1 17 26 159.458(16)
Ge1 Rb1 Ge1 17 26 159.458(16)
In1 Rb1 In1 17 42_666 39.207(15)
In1 Rb1 In1 26 42_666 122.825(7)
Ge1 Rb1 In1 17 42_666 39.207(15)
Ge1 Rb1 In1 26 42_666 122.825(7)
In1 Rb1 Ge1 17 42_666 39.207(15)
In1 Rb1 Ge1 26 42_666 122.825(7)
Ge1 Rb1 Ge1 17 42_666 39.207(15)
Ge1 Rb1 Ge1 26 42_666 122.825(7)
In1 Rb1 Ge1 17 25_565 122.825(7)
In1 Rb1 Ge1 26 25_565 71.984(13)
Ge1 Rb1 Ge1 17 25_565 122.825(7)
Ge1 Rb1 Ge1 26 25_565 71.984(13)
In1 Rb1 Ge1 42_666 25_565 159.457(16)
Ge1 Rb1 Ge1 42_666 25_565 159.457(16)
In1 Rb1 In1 17 18_554 71.984(13)
In1 Rb1 In1 26 18_554 122.825(7)
Ge1 Rb1 In1 17 18_554 71.984(13)
Ge1 Rb1 In1 26 18_554 122.825(7)
In1 Rb1 In1 42_666 18_554 85.173(11)
Ge1 Rb1 In1 42_666 18_554 85.173(11)
Ge1 Rb1 In1 25_565 18_554 98.496(12)
In1 Rb1 In1 17 25_565 122.825(7)
In1 Rb1 In1 26 25_565 71.984(13)
Ge1 Rb1 In1 17 25_565 122.825(7)
Ge1 Rb1 In1 26 25_565 71.984(13)
In1 Rb1 In1 42_666 25_565 159.457(16)
Ge1 Rb1 In1 42_666 25_565 159.457(16)
In1 Rb1 In1 18_554 25_565 98.496(12)
In1 Rb1 Ge1 17 18_554 71.984(13)
In1 Rb1 Ge1 26 18_554 122.825(7)
Ge1 Rb1 Ge1 17 18_554 71.984(13)
Ge1 Rb1 Ge1 26 18_554 122.825(7)
In1 Rb1 Ge1 42_666 18_554 85.173(11)
Ge1 Rb1 Ge1 42_666 18_554 85.173(11)
Ge1 Rb1 Ge1 25_565 18_554 98.496(12)
In1 Rb1 Ge1 25_565 18_554 98.496(12)
In1 Rb1 In1 17 41_665 85.173(11)
In1 Rb1 In1 26 41_665 98.496(12)
Ge1 Rb1 In1 17 41_665 85.173(11)
Ge1 Rb1 In1 26 41_665 98.496(12)
In1 Rb1 In1 42_666 41_665 71.984(13)
Ge1 Rb1 In1 42_666 41_665 71.984(13)
Ge1 Rb1 In1 25_565 41_665 122.825(7)
In1 Rb1 In1 18_554 41_665 39.207(15)
In1 Rb1 In1 25_565 41_665 122.825(7)
Ge1 Rb1 In1 18_554 41_665 39.207(15)
In1 Rb1 Ge1 17 2_565 98.496(12)
In1 Rb1 Ge1 26 2_565 85.173(11)
Ge1 Rb1 Ge1 17 2_565 98.496(12)
Ge1 Rb1 Ge1 26 2_565 85.173(11)
In1 Rb1 Ge1 42_666 2_565 122.825(7)
Ge1 Rb1 Ge1 42_666 2_565 122.825(7)
Ge1 Rb1 Ge1 25_565 2_565 39.207(15)
In1 Rb1 Ge1 18_554 2_565 122.825(7)
In1 Rb1 Ge1 25_565 2_565 39.207(15)
Ge1 Rb1 Ge1 18_554 2_565 122.825(7)
In1 Rb1 Ge1 41_665 2_565 159.458(16)
In2 Eu2 In2 25 28 109.5
Ge2 Eu2 In2 25 28 109.5
In2 Eu2 In2 25 4 70.5
Ge2 Eu2 In2 25 4 70.5
In2 Eu2 In2 28 4 180.0
In2 Eu2 In2 25 27 109.5
Ge2 Eu2 In2 25 27 109.5
In2 Eu2 In2 28 27 109.5
In2 Eu2 In2 4 27 70.5
In2 Eu2 In2 25 3 70.5290(10)
Ge2 Eu2 In2 25 3 70.5290(10)
In2 Eu2 In2 28 3 70.5
In2 Eu2 In2 4 3 109.5
In2 Eu2 In2 27 3 180.0
In2 Eu2 In2 25 26 109.5
Ge2 Eu2 In2 25 26 109.5
In2 Eu2 In2 28 26 109.5
In2 Eu2 In2 4 26 70.5
In2 Eu2 In2 27 26 109.5
In2 Eu2 In2 3 26 70.5
In2 Eu2 In2 25 2 70.5
Ge2 Eu2 In2 25 2 70.5
In2 Eu2 In2 28 2 70.5
In2 Eu2 In2 4 2 109.5
In2 Eu2 In2 27 2 70.5
In2 Eu2 In2 3 2 109.5
In2 Eu2 In2 26 2 180.000(9)
In2 Eu2 Ge2 25 28 109.5
Ge2 Eu2 Ge2 25 28 109.5
In2 Eu2 Ge2 4 28 180.0
In2 Eu2 Ge2 27 28 109.5
In2 Eu2 Ge2 3 28 70.5
In2 Eu2 Ge2 26 28 109.5
In2 Eu2 Ge2 2 28 70.5
In2 Eu2 Ge2 25 4 70.5
Ge2 Eu2 Ge2 25 4 70.5
In2 Eu2 Ge2 28 4 180.0
In2 Eu2 Ge2 27 4 70.5
In2 Eu2 Ge2 3 4 109.5
In2 Eu2 Ge2 26 4 70.5
In2 Eu2 Ge2 2 4 109.5
Ge2 Eu2 Ge2 28 4 180.0
In2 Eu2 Ge2 25 27 109.5
Ge2 Eu2 Ge2 25 27 109.5
In2 Eu2 Ge2 28 27 109.5
In2 Eu2 Ge2 4 27 70.5
In2 Eu2 Ge2 3 27 180.000(9)
In2 Eu2 Ge2 26 27 109.5
In2 Eu2 Ge2 2 27 70.5
Ge2 Eu2 Ge2 28 27 109.5
Ge2 Eu2 Ge2 4 27 70.5
In2 Eu2 Ge2 25 3 70.5290(10)
Ge2 Eu2 Ge2 25 3 70.5290(10)
In2 Eu2 Ge2 28 3 70.5
In2 Eu2 Ge2 4 3 109.5
In2 Eu2 Ge2 27 3 180.0
In2 Eu2 Ge2 26 3 70.5
In2 Eu2 Ge2 2 3 109.5
Ge2 Eu2 Ge2 28 3 70.5
Ge2 Eu2 Ge2 4 3 109.5
Ge2 Eu2 Ge2 27 3 180.0
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ge1 In1 26 2.5198(10)
Ge1 Ge1 26 2.5198(10)
Ge1 In2 28 2.5239(4)
Ge1 Ge2 28 2.5239(4)
Ge1 Ge2 . 2.5239(4)
Ge1 In3 9 2.6712(5)
Ge1 Eu2 . 3.5536(5)
Ge1 Rb1 . 3.7552(4)
Ge1 Rb1 25_565 3.7552(4)
Ge2 In1 9 2.5239(4)
Ge2 In1 5 2.5239(4)
Ge2 Ge1 9 2.5239(4)
Ge2 Ge1 5 2.5239(4)
Ge2 In2 14 2.5627(11)
Ge2 Ge2 14 2.5627(11)
Ge2 Eu2 . 3.5074(6)
Ge2 Rb1 9 4.1146(2)
Ge2 Rb1 . 4.1146(2)
In3 In1 45_666 2.6711(5)
In3 Ge1 5 2.6711(5)
In3 In1 5 2.6711(5)
In3 Ge1 45_666 2.6711(5)
In3 In1 46_656 2.6711(5)
In3 Ge1 46_656 2.6711(5)
In3 In1 6_556 2.6711(5)
In3 Ge1 6_556 2.6711(5)
In3 Rb1 33_656 3.91002(11)
In3 Rb1 29_556 3.91002(11)
In3 Rb1 5 3.91002(11)
In3 Rb1 9 3.91002(11)
Rb1 In1 17 3.7552(4)
Rb1 In1 26 3.7552(4)
Rb1 Ge1 17 3.7552(4)
Rb1 Ge1 26 3.7552(4)
Rb1 In1 42_666 3.7552(4)
Rb1 Ge1 42_666 3.7552(4)
Rb1 Ge1 25_565 3.7552(4)
Rb1 In1 18_554 3.7552(4)
Rb1 In1 25_565 3.7552(4)
Rb1 Ge1 18_554 3.7552(4)
Rb1 In1 41_665 3.7552(4)
Rb1 Ge1 2_565 3.7552(4)
Eu2 In2 25 3.5074(6)
Eu2 Ge2 25 3.5074(6)
Eu2 In2 28 3.5074(6)
Eu2 In2 4 3.5074(6)
Eu2 In2 27 3.5074(6)
Eu2 In2 3 3.5074(6)
Eu2 In2 26 3.5074(6)
Eu2 In2 2 3.5074(6)
Eu2 Ge2 28 3.5074(6)
Eu2 Ge2 4 3.5074(6)
Eu2 Ge2 27 3.5074(6)
Eu2 Ge2 3 3.5074(6)
