#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/96/2019661.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2019661
loop_
_publ_author_name
'Hoos, James'
'Suen, Nian-Tzu'
'Bobev, Svilen'
_publ_section_title
;
 Synthesis and crystal structures of
 RE₇Zn₂₁₊ₓSi~2{--~x} [RE = Ce, Pr, and Nd;
 0.09(1) < x < 0.95(1)]
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              945
_journal_page_last               948
_journal_paper_doi               10.1107/S2053229614019822
_journal_volume                  70
_journal_year                    2014
_chemical_formula_iupac          'Pr7 Zn21.09 Si1.91'
_chemical_formula_sum            'Pr7 Si1.91 Zn21.09'
_chemical_formula_weight         2418.86
_chemical_name_systematic
;
Heptapraseodymium henicosazinc disilicon
;
_space_group_crystal_system      orthorhombic
_space_group_IT_number           55
_space_group_name_Hall           '-P 2 2ab'
_space_group_name_H-M_alt        'P b a m'
_symmetry_space_group_name_Hall  '-P 2 2ab'
_symmetry_space_group_name_H-M   'P b a m'
_audit_creation_method           SHELXL
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   15.361(2)
_cell_length_b                   16.984(2)
_cell_length_c                   4.4555(6)
_cell_measurement_reflns_used    1395
_cell_measurement_temperature    200(2)
_cell_measurement_theta_max      29.16
_cell_measurement_theta_min      2.65
_cell_volume                     1162.4(3)
_computing_cell_refinement       'SAINT (Bruker, 2007)'
_computing_data_collection       'APEX2 (Bruker, 2007)'
_computing_data_reduction        'SAINT (Bruker, 2007)'
_computing_molecular_graphics    'CrystalMaker (Palmer, 2007)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      200(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0750
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       5
_diffrn_reflns_limit_l_min       -5
_diffrn_reflns_number            14240
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         28.362
_diffrn_reflns_theta_min         1.788
_exptl_absorpt_coefficient_mu    35.704
_exptl_absorpt_correction_T_max  0.7461
_exptl_absorpt_correction_T_min  0.5790
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2008)'
_exptl_crystal_colour            silver-grey
_exptl_crystal_density_diffrn    6.911
_exptl_crystal_description       irregular
_exptl_crystal_F_000             2145
_exptl_crystal_size_max          0.035
_exptl_crystal_size_mid          0.029
_exptl_crystal_size_min          0.022
_refine_diff_density_max         1.771
_refine_diff_density_min         -1.820
_refine_ls_extinction_coef       0.000201(19)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     95
_refine_ls_number_reflns         1630
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0446
_refine_ls_R_factor_gt           0.0275
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0140P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0446
_refine_ls_wR_factor_ref         0.0495
_reflns_number_gt                1284
_reflns_number_total             1630
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            fn3179sup1.cif
_cod_data_source_block           II
_cod_depositor_comments
'Adding full bibliography for 2019660--2019662.cif.'
_cod_database_code               2019661
_cod_database_fobs_code          2019661
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.368
_shelx_estimated_absorpt_t_max   0.507
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'-x+1/2, y+1/2, -z'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x, y, -z'
'x-1/2, -y-1/2, z'
'-x-1/2, y-1/2, z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Pr Pr1 0.16438(4) 0.17980(3) 0.5000 0.00676(13) Uani d 1
Pr Pr2 0.41922(4) 0.26158(3) 0.5000 0.00981(13) Uani d 1
Pr Pr3 0.16574(4) 0.45419(3) 0.0000 0.00719(13) Uani d 1
Pr Pr4 0.0000 0.0000 0.5000 0.00884(17) Uani d 1
Si Si1 0.02049(18) 0.14167(14) 0.0000 0.0075(8) Uani d 0.957(7)
Zn Zn1 0.02049(18) 0.14167(14) 0.0000 0.0075(8) Uani d 0.043(7)
Zn Zn2 0.07295(8) 0.35903(7) 0.5000 0.0109(3) Uani d 1
Zn Zn3 0.24847(9) 0.35265(6) 0.5000 0.0113(3) Uani d 1
Zn Zn4 0.29998(8) 0.49384(7) 0.5000 0.0106(3) Uani d 1
Zn Zn5 0.35265(8) 0.08105(7) 0.5000 0.0114(3) Uani d 1
Zn Zn6 0.07440(8) 0.28275(6) 0.0000 0.0089(3) Uani d 1
Zn Zn7 0.14987(8) 0.05204(6) 0.0000 0.0087(3) Uani d 1
Zn Zn8 0.25701(8) 0.28109(6) 0.0000 0.0085(3) Uani d 1
Zn Zn9 0.30302(8) 0.14075(7) 0.0000 0.0095(3) Uani d 1
Zn Zn10 0.36526(8) 0.40034(7) 0.0000 0.0101(3) Uani d 1
Zn Zn11 0.46548(8) 0.09805(7) 0.0000 0.0112(3) Uani d 1
Zn Zn12 0.0000 0.5000 0.5000 0.0117(4) Uani d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Si Si 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pr Pr -0.2180 2.8214 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
Zn7 Pr1 Zn7 . 1_556 91.21(3)
Zn7 Pr1 Zn6 . . 81.35(3)
Zn7 Pr1 Zn6 1_556 . 149.31(4)
Zn7 Pr1 Zn6 . 1_556 149.31(4)
Zn7 Pr1 Zn6 1_556 1_556 81.35(3)
Zn6 Pr1 Zn6 . 1_556 89.97(3)
Zn7 Pr1 Zn9 . 1_556 114.00(3)
Zn7 Pr1 Zn9 1_556 1_556 52.91(3)
Zn6 Pr1 Zn9 . 1_556 155.87(3)
Zn6 Pr1 Zn9 1_556 1_556 85.04(2)
Zn7 Pr1 Zn9 . . 52.91(3)
Zn7 Pr1 Zn9 1_556 . 114.00(3)
Zn6 Pr1 Zn9 . . 85.04(2)
Zn6 Pr1 Zn9 1_556 . 155.87(3)
Zn9 Pr1 Zn9 1_556 . 89.93(4)
Zn7 Pr1 Zn8 . . 84.67(2)
Zn7 Pr1 Zn8 1_556 . 156.43(4)
Zn6 Pr1 Zn8 . . 52.83(3)
Zn6 Pr1 Zn8 1_556 . 113.24(3)
Zn9 Pr1 Zn8 1_556 . 108.01(3)
Zn9 Pr1 Zn8 . . 46.44(3)
Zn7 Pr1 Zn8 . 1_556 156.43(4)
Zn7 Pr1 Zn8 1_556 1_556 84.67(2)
Zn6 Pr1 Zn8 . 1_556 113.24(3)
Zn6 Pr1 Zn8 1_556 1_556 52.83(3)
Zn9 Pr1 Zn8 1_556 1_556 46.44(3)
Zn9 Pr1 Zn8 . 1_556 108.01(3)
Zn8 Pr1 Zn8 . 1_556 89.88(3)
Zn7 Pr1 Zn1 . 1_556 107.87(5)
Zn7 Pr1 Zn1 1_556 1_556 46.63(5)
Zn6 Pr1 Zn1 . 1_556 107.52(5)
Zn6 Pr1 Zn1 1_556 1_556 47.01(5)
Zn9 Pr1 Zn1 1_556 1_556 86.11(4)
Zn9 Pr1 Zn1 . 1_556 156.17(5)
Zn8 Pr1 Zn1 . 1_556 155.85(5)
Zn8 Pr1 Zn1 1_556 1_556 86.00(4)
Zn7 Pr1 Si1 . 1_556 107.87(5)
Zn7 Pr1 Si1 1_556 1_556 46.63(5)
Zn6 Pr1 Si1 . 1_556 107.52(5)
Zn6 Pr1 Si1 1_556 1_556 47.01(5)
Zn9 Pr1 Si1 1_556 1_556 86.11(4)
Zn9 Pr1 Si1 . 1_556 156.17(5)
Zn8 Pr1 Si1 . 1_556 155.85(5)
Zn8 Pr1 Si1 1_556 1_556 86.00(4)
Zn1 Pr1 Si1 1_556 1_556 0.00(11)
Zn7 Pr1 Si1 . . 46.63(5)
Zn7 Pr1 Si1 1_556 . 107.87(5)
Zn6 Pr1 Si1 . . 47.01(5)
Zn6 Pr1 Si1 1_556 . 107.52(5)
Zn9 Pr1 Si1 1_556 . 156.17(5)
Zn9 Pr1 Si1 . . 86.11(4)
Zn8 Pr1 Si1 . . 86.00(4)
Zn8 Pr1 Si1 1_556 . 155.85(5)
Zn1 Pr1 Si1 1_556 . 88.10(7)
Si1 Pr1 Si1 1_556 . 88.10(7)
Zn3 Pr2 Zn2 . 7_665 169.59(4)
Zn3 Pr2 Zn1 . 7_666 99.16(5)
Zn2 Pr2 Zn1 7_665 7_666 88.22(5)
Zn3 Pr2 Si1 . 7_666 99.16(5)
Zn2 Pr2 Si1 7_665 7_666 88.22(5)
Zn1 Pr2 Si1 7_666 7_666 0.00(8)
Zn3 Pr2 Zn1 . 7_665 99.16(5)
Zn2 Pr2 Zn1 7_665 7_665 88.22(5)
Zn1 Pr2 Zn1 7_666 7_665 89.11(7)
Si1 Pr2 Zn1 7_666 7_665 89.11(7)
Zn3 Pr2 Si1 . 7_665 99.16(5)
Zn2 Pr2 Si1 7_665 7_665 88.22(5)
Zn1 Pr2 Si1 7_666 7_665 89.11(7)
Si1 Pr2 Si1 7_666 7_665 89.11(7)
Zn1 Pr2 Si1 7_665 7_665 0.00(8)
Zn3 Pr2 Zn5 . . 102.09(4)
Zn2 Pr2 Zn5 7_665 . 67.50(3)
Zn1 Pr2 Zn5 7_666 . 130.23(4)
Si1 Pr2 Zn5 7_666 . 130.23(4)
Zn1 Pr2 Zn5 7_665 . 130.23(4)
Si1 Pr2 Zn5 7_665 . 130.23(4)
Zn3 Pr2 Zn10 . 1_556 55.18(2)
Zn2 Pr2 Zn10 7_665 1_556 130.42(2)
Zn1 Pr2 Zn10 7_666 1_556 44.77(5)
Si1 Pr2 Zn10 7_666 1_556 44.77(5)
Zn1 Pr2 Zn10 7_665 1_556 102.94(4)
Si1 Pr2 Zn10 7_665 1_556 102.94(4)
Zn5 Pr2 Zn10 . 1_556 126.13(3)
Zn3 Pr2 Zn10 . . 55.18(2)
Zn2 Pr2 Zn10 7_665 . 130.42(2)
Zn1 Pr2 Zn10 7_666 . 102.94(4)
Si1 Pr2 Zn10 7_666 . 102.94(4)
Zn1 Pr2 Zn10 7_665 . 44.77(5)
Si1 Pr2 Zn10 7_665 . 44.77(5)
Zn5 Pr2 Zn10 . . 126.13(3)
Zn10 Pr2 Zn10 1_556 . 83.45(3)
Zn3 Pr2 Zn6 . 7_666 136.672(17)
Zn2 Pr2 Zn6 7_665 7_666 46.76(2)
Zn1 Pr2 Zn6 7_666 7_666 45.64(5)
Si1 Pr2 Zn6 7_666 7_666 45.64(5)
Zn1 Pr2 Zn6 7_665 7_666 103.55(5)
Si1 Pr2 Zn6 7_665 7_666 103.55(5)
Zn5 Pr2 Zn6 . 7_666 90.68(3)
Zn10 Pr2 Zn6 1_556 7_666 83.79(2)
Zn10 Pr2 Zn6 . 7_666 141.02(3)
Zn3 Pr2 Zn6 . 7_665 136.672(17)
Zn2 Pr2 Zn6 7_665 7_665 46.76(2)
Zn1 Pr2 Zn6 7_666 7_665 103.55(5)
Si1 Pr2 Zn6 7_666 7_665 103.55(5)
Zn1 Pr2 Zn6 7_665 7_665 45.64(5)
Si1 Pr2 Zn6 7_665 7_665 45.64(5)
Zn5 Pr2 Zn6 . 7_665 90.68(3)
Zn10 Pr2 Zn6 1_556 7_665 141.02(3)
Zn10 Pr2 Zn6 . 7_665 83.79(2)
Zn6 Pr2 Zn6 7_666 7_665 83.41(3)
Zn3 Pr2 Zn8 . . 46.44(2)
Zn2 Pr2 Zn8 7_665 . 128.68(2)
Zn1 Pr2 Zn8 7_666 . 141.06(5)
Si1 Pr2 Zn8 7_666 . 141.06(5)
Zn1 Pr2 Zn8 7_665 . 81.20(4)
Si1 Pr2 Zn8 7_665 . 81.20(4)
Zn5 Pr2 Zn8 . . 81.89(3)
Zn10 Pr2 Zn8 1_556 . 100.85(3)
Zn10 Pr2 Zn8 . . 46.00(3)
Zn6 Pr2 Zn8 7_666 . 172.56(3)
Zn6 Pr2 Zn8 7_665 . 96.26(2)
Zn3 Pr3 Zn3 . 1_554 92.25(4)
Zn3 Pr3 Zn2 . . 51.69(3)
Zn3 Pr3 Zn2 1_554 . 114.60(3)
Zn3 Pr3 Zn2 . 1_554 114.60(3)
Zn3 Pr3 Zn2 1_554 1_554 51.69(3)
Zn2 Pr3 Zn2 . 1_554 91.90(4)
Zn3 Pr3 Zn4 . . 48.07(3)
Zn3 Pr3 Zn4 1_554 . 111.38(4)
Zn2 Pr3 Zn4 . . 84.43(3)
Zn2 Pr3 Zn4 1_554 . 158.89(4)
Zn3 Pr3 Zn4 . 1_554 111.38(4)
Zn3 Pr3 Zn4 1_554 1_554 48.07(3)
Zn2 Pr3 Zn4 . 1_554 158.89(4)
Zn2 Pr3 Zn4 1_554 1_554 84.43(3)
Zn4 Pr3 Zn4 . 1_554 91.53(4)
Zn3 Pr3 Zn5 . 3_556 84.70(3)
Zn3 Pr3 Zn5 1_554 3_556 159.99(4)
Zn2 Pr3 Zn5 . 3_556 78.74(3)
Zn2 Pr3 Zn5 1_554 3_556 146.49(4)
Zn4 Pr3 Zn5 . 3_556 52.94(3)
Zn4 Pr3 Zn5 1_554 3_556 115.03(3)
Zn3 Pr3 Zn5 . 3 159.99(4)
Zn3 Pr3 Zn5 1_554 3 84.70(3)
Zn2 Pr3 Zn5 . 3 146.49(4)
Zn2 Pr3 Zn5 1_554 3 78.74(3)
Zn4 Pr3 Zn5 . 3 115.03(3)
Zn4 Pr3 Zn5 1_554 3 52.94(3)
Zn5 Pr3 Zn5 3_556 3 91.42(3)
Zn3 Pr3 Zn11 . 3 133.795(19)
Zn3 Pr3 Zn11 1_554 3 133.795(18)
Zn2 Pr3 Zn11 . 3 96.29(3)
Zn2 Pr3 Zn11 1_554 3 96.29(3)
Zn4 Pr3 Zn11 . 3 104.77(3)
Zn4 Pr3 Zn11 1_554 3 104.77(3)
Zn5 Pr3 Zn11 3_556 3 53.71(2)
Zn5 Pr3 Zn11 3 3 53.71(2)
Zn3 Pr3 Zn10 . . 56.39(3)
Zn3 Pr3 Zn10 1_554 . 56.39(3)
Zn2 Pr3 Zn10 . . 106.95(3)
Zn2 Pr3 Zn10 1_554 . 106.95(3)
Zn4 Pr3 Zn10 . . 55.00(2)
Zn4 Pr3 Zn10 1_554 . 55.00(2)
Zn5 Pr3 Zn10 3_556 . 106.55(3)
Zn5 Pr3 Zn10 3 . 106.55(3)
Zn11 Pr3 Zn10 3 . 146.14(4)
Zn3 Pr3 Zn11 . 7_565 103.91(3)
Zn3 Pr3 Zn11 1_554 7_565 103.91(3)
Zn2 Pr3 Zn11 . 7_565 54.10(2)
Zn2 Pr3 Zn11 1_554 7_565 54.10(2)
Zn4 Pr3 Zn11 . 7_565 134.203(19)
Zn4 Pr3 Zn11 1_554 7_565 134.203(19)
Zn5 Pr3 Zn11 3_556 7_565 96.01(3)
Zn5 Pr3 Zn11 3 7_565 96.01(3)
Zn11 Pr3 Zn11 3 7_565 66.57(4)
Zn10 Pr3 Zn11 . 7_565 147.30(3)
Zn3 Pr3 Zn9 . 3 119.35(3)
Zn3 Pr3 Zn9 1_554 3 119.35(3)
Zn2 Pr3 Zn9 . 3 125.76(2)
Zn2 Pr3 Zn9 1_554 3 125.76(2)
Zn4 Pr3 Zn9 . 3 71.73(3)
Zn4 Pr3 Zn9 1_554 3 71.73(3)
Zn5 Pr3 Zn9 3_556 3 47.860(19)
Zn5 Pr3 Zn9 3 3 47.860(19)
Zn11 Pr3 Zn9 3 3 48.13(3)
Zn10 Pr3 Zn9 . 3 98.00(3)
Zn11 Pr3 Zn9 7_565 3 114.70(3)
Zn4 Pr4 Zn4 7_565 3_546 180.0
Zn4 Pr4 Si1 7_565 . 94.05(5)
Zn4 Pr4 Si1 3_546 . 85.95(5)
Zn4 Pr4 Zn1 7_565 5 85.95(5)
Zn4 Pr4 Zn1 3_546 5 94.05(5)
Si1 Pr4 Zn1 . 5 94.89(6)
Zn4 Pr4 Zn1 7_565 1_556 94.05(5)
Zn4 Pr4 Zn1 3_546 1_556 85.95(5)
Si1 Pr4 Zn1 . 1_556 85.11(6)
Zn1 Pr4 Zn1 5 1_556 180.00(9)
Zn4 Pr4 Si1 7_565 1_556 94.05(5)
Zn4 Pr4 Si1 3_546 1_556 85.95(5)
Si1 Pr4 Si1 . 1_556 85.11(6)
Zn1 Pr4 Si1 5 1_556 180.00(9)
Zn1 Pr4 Si1 1_556 1_556 0.00(9)
Zn4 Pr4 Si1 7_565 5 85.95(5)
Zn4 Pr4 Si1 3_546 5 94.05(5)
Si1 Pr4 Si1 . 5 94.89(6)
Zn1 Pr4 Si1 5 5 0.00(6)
Zn1 Pr4 Si1 1_556 5 180.0
Si1 Pr4 Si1 1_556 5 180.0
Zn4 Pr4 Zn1 7_565 5_556 85.95(5)
Zn4 Pr4 Zn1 3_546 5_556 94.05(5)
Si1 Pr4 Zn1 . 5_556 180.0
Zn1 Pr4 Zn1 5 5_556 85.10(6)
Zn1 Pr4 Zn1 1_556 5_556 94.90(6)
Si1 Pr4 Zn1 1_556 5_556 94.90(6)
Si1 Pr4 Zn1 5 5_556 85.10(6)
Zn4 Pr4 Si1 7_565 5_556 85.95(5)
Zn4 Pr4 Si1 3_546 5_556 94.05(5)
Si1 Pr4 Si1 . 5_556 180.0
Zn1 Pr4 Si1 5 5_556 85.10(6)
Zn1 Pr4 Si1 1_556 5_556 94.90(6)
Si1 Pr4 Si1 1_556 5_556 94.90(6)
Si1 Pr4 Si1 5 5_556 85.10(6)
Zn1 Pr4 Si1 5_556 5_556 0.00(11)
Zn4 Pr4 Zn7 7_565 5 46.898(19)
Zn4 Pr4 Zn7 3_546 5 133.102(19)
Si1 Pr4 Zn7 . 5 78.88(4)
Zn1 Pr4 Zn7 5 5 44.45(5)
Zn1 Pr4 Zn7 1_556 5 135.55(5)
Si1 Pr4 Zn7 1_556 5 135.55(5)
Si1 Pr4 Zn7 5 5 44.45(5)
Zn1 Pr4 Zn7 5_556 5 101.12(4)
Si1 Pr4 Zn7 5_556 5 101.12(4)
Zn4 Pr4 Zn7 7_565 1_556 133.102(19)
Zn4 Pr4 Zn7 3_546 1_556 46.898(19)
Si1 Pr4 Zn7 . 1_556 101.12(4)
Zn1 Pr4 Zn7 5 1_556 135.55(5)
Zn1 Pr4 Zn7 1_556 1_556 44.45(5)
Si1 Pr4 Zn7 1_556 1_556 44.45(5)
Si1 Pr4 Zn7 5 1_556 135.55(5)
Zn1 Pr4 Zn7 5_556 1_556 78.88(4)
Si1 Pr4 Zn7 5_556 1_556 78.88(4)
Zn7 Pr4 Zn7 5 1_556 180.0
Zn10 Si1 Zn7 7_565 . 125.89(11)
Zn10 Si1 Zn6 7_565 . 125.72(11)
Zn7 Si1 Zn6 . . 108.39(10)
Zn10 Si1 Pr2 7_565 7_565 71.27(6)
Zn7 Si1 Pr2 . 7_565 134.72(4)
Zn6 Si1 Pr2 . 7_565 70.79(5)
Zn10 Si1 Pr2 7_565 7_564 71.27(6)
Zn7 Si1 Pr2 . 7_564 134.72(4)
Zn6 Si1 Pr2 . 7_564 70.79(5)
Pr2 Si1 Pr2 7_565 7_564 89.11(7)
Zn10 Si1 Pr1 7_565 1_554 135.95(3)
Zn7 Si1 Pr1 . 1_554 64.87(5)
Zn6 Si1 Pr1 . 1_554 65.40(5)
Pr2 Si1 Pr1 7_565 1_554 136.15(8)
Pr2 Si1 Pr1 7_564 1_554 75.26(3)
Zn10 Si1 Pr1 7_565 . 135.95(3)
Zn7 Si1 Pr1 . . 64.87(5)
Zn6 Si1 Pr1 . . 65.40(5)
Pr2 Si1 Pr1 7_565 . 75.26(3)
Pr2 Si1 Pr1 7_564 . 136.15(8)
Pr1 Si1 Pr1 1_554 . 88.09(7)
Zn10 Si1 Pr4 7_565 1_554 72.49(6)
Zn7 Si1 Pr4 . 1_554 68.39(5)
Zn6 Si1 Pr4 . 1_554 136.18(4)
Pr2 Si1 Pr4 7_565 1_554 143.67(9)
Pr2 Si1 Pr4 7_564 1_554 81.76(3)
Pr1 Si1 Pr4 1_554 1_554 75.13(3)
Pr1 Si1 Pr4 . 1_554 133.13(8)
Zn10 Si1 Pr4 7_565 . 72.49(6)
Zn7 Si1 Pr4 . . 68.39(5)
Zn6 Si1 Pr4 . . 136.18(4)
Pr2 Si1 Pr4 7_565 . 81.76(3)
Pr2 Si1 Pr4 7_564 . 143.67(9)
Pr1 Si1 Pr4 1_554 . 133.13(8)
Pr1 Si1 Pr4 . . 75.13(3)
Pr4 Si1 Pr4 1_554 . 85.11(6)
Zn6 Zn2 Zn6 1_556 . 119.63(6)
Zn6 Zn2 Zn12 1_556 . 117.32(3)
Zn6 Zn2 Zn12 . . 117.32(3)
Zn6 Zn2 Zn3 1_556 . 88.35(4)
Zn6 Zn2 Zn3 . . 88.35(4)
Zn12 Zn2 Zn3 . . 117.38(5)
Zn6 Zn2 Zn11 1_556 7_565 143.56(6)
Zn6 Zn2 Zn11 . 7_565 57.39(3)
Zn12 Zn2 Zn11 . 7_565 61.68(3)
Zn3 Zn2 Zn11 . 7_565 125.84(3)
Zn6 Zn2 Zn11 1_556 7_566 57.39(3)
Zn6 Zn2 Zn11 . 7_566 143.56(6)
Zn12 Zn2 Zn11 . 7_566 61.68(3)
Zn3 Zn2 Zn11 . 7_566 125.84(3)
Zn11 Zn2 Zn11 7_565 7_566 101.98(6)
Zn6 Zn2 Pr3 1_556 1_556 68.70(3)
Zn6 Zn2 Pr3 . 1_556 151.58(6)
Zn12 Zn2 Pr3 . 1_556 73.90(3)
Zn3 Zn2 Pr3 . 1_556 63.99(3)
Zn11 Zn2 Pr3 7_565 1_556 133.69(5)
Zn11 Zn2 Pr3 7_566 1_556 64.77(3)
Zn6 Zn2 Pr3 1_556 . 151.58(6)
Zn6 Zn2 Pr3 . . 68.70(3)
Zn12 Zn2 Pr3 . . 73.90(3)
Zn3 Zn2 Pr3 . . 63.99(3)
Zn11 Zn2 Pr3 7_565 . 64.77(3)
Zn11 Zn2 Pr3 7_566 . 133.69(5)
Pr3 Zn2 Pr3 1_556 . 91.91(4)
Zn6 Zn2 Pr2 1_556 7_565 71.16(4)
Zn6 Zn2 Pr2 . 7_565 71.16(4)
Zn12 Zn2 Pr2 . 7_565 105.86(4)
Zn3 Zn2 Pr2 . 7_565 136.76(5)
Zn11 Zn2 Pr2 7_565 7_565 74.43(4)
Zn11 Zn2 Pr2 7_566 7_565 74.43(4)
Pr3 Zn2 Pr2 1_556 7_565 133.556(19)
Pr3 Zn2 Pr2 . 7_565 133.556(19)
Zn6 Zn2 Pr1 1_556 . 62.61(3)
Zn6 Zn2 Pr1 . . 62.61(3)
Zn12 Zn2 Pr1 . . 179.69(5)
Zn3 Zn2 Pr1 . . 62.93(4)
Zn11 Zn2 Pr1 7_565 . 118.17(3)
Zn11 Zn2 Pr1 7_566 . 118.17(3)
Pr3 Zn2 Pr1 1_556 . 106.31(3)
Pr3 Zn2 Pr1 . . 106.31(3)
Pr2 Zn2 Pr1 7_565 . 73.83(3)
Zn4 Zn3 Zn8 . 1_556 115.98(4)
Zn4 Zn3 Zn8 . . 115.98(4)
Zn8 Zn3 Zn8 1_556 . 122.49(6)
Zn4 Zn3 Zn2 . . 105.96(5)
Zn8 Zn3 Zn2 1_556 . 94.06(4)
Zn8 Zn3 Zn2 . . 94.06(4)
Zn4 Zn3 Zn10 . 1_556 63.40(3)
Zn8 Zn3 Zn10 1_556 1_556 56.09(3)
Zn8 Zn3 Zn10 . 1_556 139.12(6)
Zn2 Zn3 Zn10 . 1_556 126.30(3)
Zn4 Zn3 Zn10 . . 63.40(3)
Zn8 Zn3 Zn10 1_556 . 139.12(6)
Zn8 Zn3 Zn10 . . 56.09(3)
Zn2 Zn3 Zn10 . . 126.30(3)
Zn10 Zn3 Zn10 1_556 . 97.08(5)
Zn4 Zn3 Pr2 . . 102.27(5)
Zn8 Zn3 Pr2 1_556 . 73.30(4)
Zn8 Zn3 Pr2 . . 73.30(4)
Zn2 Zn3 Pr2 . . 151.77(5)
Zn10 Zn3 Pr2 1_556 . 67.58(3)
Zn10 Zn3 Pr2 . . 67.58(3)
Zn4 Zn3 Pr3 . 1_556 66.36(3)
Zn8 Zn3 Pr3 1_556 1_556 69.89(3)
Zn8 Zn3 Pr3 . 1_556 156.93(6)
Zn2 Zn3 Pr3 . 1_556 64.33(3)
Zn10 Zn3 Pr3 1_556 1_556 63.64(3)
Zn10 Zn3 Pr3 . 1_556 129.52(5)
Pr2 Zn3 Pr3 . 1_556 129.61(3)
Zn4 Zn3 Pr3 . . 66.36(3)
Zn8 Zn3 Pr3 1_556 . 156.93(6)
Zn8 Zn3 Pr3 . . 69.89(3)
Zn2 Zn3 Pr3 . . 64.33(3)
Zn10 Zn3 Pr3 1_556 . 129.52(5)
Zn10 Zn3 Pr3 . . 63.64(3)
Pr2 Zn3 Pr3 . . 129.61(3)
Pr3 Zn3 Pr3 1_556 . 92.25(4)
Zn4 Zn3 Pr1 . . 174.51(6)
Zn8 Zn3 Pr1 1_556 . 65.36(3)
Zn8 Zn3 Pr1 . . 65.35(3)
Zn2 Zn3 Pr1 . . 68.55(4)
Zn10 Zn3 Pr1 1_556 . 119.50(3)
Zn10 Zn3 Pr1 . . 119.50(3)
Pr2 Zn3 Pr1 . . 83.22(3)
Pr3 Zn3 Pr1 1_556 . 110.19(3)
Pr3 Zn3 Pr1 . . 110.19(3)
Zn3 Zn4 Zn7 . 3_556 117.49(3)
Zn3 Zn4 Zn7 . 3 117.49(3)
Zn7 Zn4 Zn7 3_556 3 121.28(6)
Zn3 Zn4 Zn5 . 3_556 104.02(6)
Zn7 Zn4 Zn5 3_556 3_556 92.77(4)
Zn7 Zn4 Zn5 3 3_556 92.77(4)
Zn3 Zn4 Zn10 . . 65.81(4)
Zn7 Zn4 Zn10 3_556 . 140.66(6)
Zn7 Zn4 Zn10 3 . 55.99(3)
Zn5 Zn4 Zn10 3_556 . 125.59(3)
Zn3 Zn4 Zn10 . 1_556 65.81(4)
Zn7 Zn4 Zn10 3_556 1_556 55.99(3)
Zn7 Zn4 Zn10 3 1_556 140.66(6)
Zn5 Zn4 Zn10 3_556 1_556 125.59(3)
Zn10 Zn4 Zn10 . 1_556 99.73(5)
Zn3 Zn4 Pr4 . 3_556 110.21(5)
Zn7 Zn4 Pr4 3_556 3_556 71.68(4)
Zn7 Zn4 Pr4 3 3_556 71.68(4)
Zn5 Zn4 Pr4 3_556 3_556 145.77(5)
Zn10 Zn4 Pr4 . 3_556 71.01(3)
Zn10 Zn4 Pr4 1_556 3_556 71.01(3)
Zn3 Zn4 Pr3 . 1_556 65.57(3)
Zn7 Zn4 Pr3 3_556 1_556 70.07(3)
Zn7 Zn4 Pr3 3 1_556 155.24(6)
Zn5 Zn4 Pr3 3_556 1_556 63.58(3)
Zn10 Zn4 Pr3 . 1_556 131.14(5)
Zn10 Zn4 Pr3 1_556 1_556 64.05(3)
Pr4 Zn4 Pr3 3_556 1_556 132.08(2)
Zn3 Zn4 Pr3 . . 65.58(3)
Zn7 Zn4 Pr3 3_556 . 155.24(6)
Zn7 Zn4 Pr3 3 . 70.07(3)
Zn5 Zn4 Pr3 3_556 . 63.58(3)
Zn10 Zn4 Pr3 . . 64.05(3)
Zn10 Zn4 Pr3 1_556 . 131.14(5)
Pr4 Zn4 Pr3 3_556 . 132.08(2)
Pr3 Zn4 Pr3 1_556 . 91.53(4)
Zn3 Zn4 Pr1 . 3_556 171.58(6)
Zn7 Zn4 Pr1 3_556 3_556 64.37(3)
Zn7 Zn4 Pr1 3 3_556 64.37(3)
Zn5 Zn4 Pr1 3_556 3_556 67.55(4)
Zn10 Zn4 Pr1 . 3_556 118.57(3)
Zn10 Zn4 Pr1 1_556 3_556 118.57(3)
Pr4 Zn4 Pr1 3_556 3_556 78.22(3)
Pr3 Zn4 Pr1 1_556 3_556 109.07(3)
Pr3 Zn4 Pr1 . 3_556 109.07(3)
Zn9 Zn5 Zn9 . 1_556 120.69(6)
Zn9 Zn5 Zn12 . 3_546 117.36(4)
Zn9 Zn5 Zn12 1_556 3_546 117.36(4)
Zn9 Zn5 Zn4 . 3_546 87.70(4)
Zn9 Zn5 Zn4 1_556 3_546 87.70(4)
Zn12 Zn5 Zn4 3_546 3_546 116.41(5)
Zn9 Zn5 Zn11 . . 57.25(3)
Zn9 Zn5 Zn11 1_556 . 145.46(6)
Zn12 Zn5 Zn11 3_546 . 62.03(3)
Zn4 Zn5 Zn11 3_546 . 124.80(3)
Zn9 Zn5 Zn11 . 1_556 145.46(6)
Zn9 Zn5 Zn11 1_556 1_556 57.26(3)
Zn12 Zn5 Zn11 3_546 1_556 62.03(3)
Zn4 Zn5 Zn11 3_546 1_556 124.80(3)
Zn11 Zn5 Zn11 . 1_556 103.47(6)
Zn9 Zn5 Pr3 . 3_545 67.96(3)
Zn9 Zn5 Pr3 1_556 3_545 150.33(5)
Zn12 Zn5 Pr3 3_546 3_545 73.61(3)
Zn4 Zn5 Pr3 3_546 3_545 63.48(3)
Zn11 Zn5 Pr3 . 3_545 64.14(3)
Zn11 Zn5 Pr3 1_556 3_545 133.47(5)
Zn9 Zn5 Pr3 . 3_546 150.33(5)
Zn9 Zn5 Pr3 1_556 3_546 67.96(3)
Zn12 Zn5 Pr3 3_546 3_546 73.61(3)
Zn4 Zn5 Pr3 3_546 3_546 63.48(3)
Zn11 Zn5 Pr3 . 3_546 133.47(5)
Zn11 Zn5 Pr3 1_556 3_546 64.14(3)
Pr3 Zn5 Pr3 3_545 3_546 91.42(3)
Zn9 Zn5 Pr2 . . 73.67(4)
Zn9 Zn5 Pr2 1_556 . 73.68(4)
Zn12 Zn5 Pr2 3_546 . 102.86(4)
Zn4 Zn5 Pr2 3_546 . 140.73(5)
Zn11 Zn5 Pr2 . . 73.16(3)
Zn11 Zn5 Pr2 1_556 . 73.16(3)
Pr3 Zn5 Pr2 3_545 . 133.28(2)
Pr3 Zn5 Pr2 3_546 . 133.28(2)
Zn9 Zn5 Pr1 . . 62.89(3)
Zn9 Zn5 Pr1 1_556 . 62.89(3)
Zn12 Zn5 Pr1 3_546 . 178.80(5)
Zn4 Zn5 Pr1 3_546 . 62.39(4)
Zn11 Zn5 Pr1 . . 118.52(3)
Zn11 Zn5 Pr1 1_556 . 118.52(3)
Pr3 Zn5 Pr1 3_545 . 105.59(3)
Pr3 Zn5 Pr1 3_546 . 105.59(3)
Pr2 Zn5 Pr1 . . 78.33(3)
Si1 Zn6 Zn2 . 1_554 118.18(4)
Si1 Zn6 Zn2 . . 118.18(4)
Zn2 Zn6 Zn2 1_554 . 119.63(6)
Si1 Zn6 Zn11 . 7_565 121.36(8)
Zn2 Zn6 Zn11 1_554 7_565 66.86(4)
Zn2 Zn6 Zn11 . 7_565 66.86(4)
Si1 Zn6 Zn8 . . 108.49(7)
Zn2 Zn6 Zn8 1_554 . 90.79(4)
Zn2 Zn6 Zn8 . . 90.79(4)
Zn11 Zn6 Zn8 7_565 . 130.15(6)
Si1 Zn6 Pr1 . . 67.59(5)
Zn2 Zn6 Pr1 1_554 . 153.36(5)
Zn2 Zn6 Pr1 . . 70.83(3)
Zn11 Zn6 Pr1 7_565 . 135.000(17)
Zn8 Zn6 Pr1 . . 63.63(3)
Si1 Zn6 Pr1 . 1_554 67.59(5)
Zn2 Zn6 Pr1 1_554 1_554 70.83(3)
Zn2 Zn6 Pr1 . 1_554 153.36(5)
Zn11 Zn6 Pr1 7_565 1_554 135.000(17)
Zn8 Zn6 Pr1 . 1_554 63.63(3)
Pr1 Zn6 Pr1 . 1_554 89.97(3)
Si1 Zn6 Pr3 . . 173.34(8)
Zn2 Zn6 Pr3 1_554 . 63.31(3)
Zn2 Zn6 Pr3 . . 63.31(3)
Zn11 Zn6 Pr3 7_565 . 65.30(4)
Zn8 Zn6 Pr3 . . 64.85(3)
Pr1 Zn6 Pr3 . . 108.03(3)
Pr1 Zn6 Pr3 1_554 . 108.03(3)
Si1 Zn6 Pr2 . 7_564 63.57(5)
Zn2 Zn6 Pr2 1_554 7_564 62.08(3)
Zn2 Zn6 Pr2 . 7_564 133.00(5)
Zn11 Zn6 Pr2 7_565 7_564 73.73(3)
Zn8 Zn6 Pr2 . 7_564 135.20(2)
Pr1 Zn6 Pr2 . 7_564 131.13(4)
Pr1 Zn6 Pr2 1_554 7_564 73.57(2)
Pr3 Zn6 Pr2 . 7_564 120.77(3)
Si1 Zn6 Pr2 . 7_565 63.57(5)
Zn2 Zn6 Pr2 1_554 7_565 133.00(5)
Zn2 Zn6 Pr2 . 7_565 62.08(3)
Zn11 Zn6 Pr2 7_565 7_565 73.73(3)
Zn8 Zn6 Pr2 . 7_565 135.20(2)
Pr1 Zn6 Pr2 . 7_565 73.57(2)
Pr1 Zn6 Pr2 1_554 7_565 131.13(4)
Pr3 Zn6 Pr2 . 7_565 120.77(3)
Pr2 Zn6 Pr2 7_564 7_565 83.41(3)
Si1 Zn7 Zn4 . 3_545 118.32(4)
Si1 Zn7 Zn4 . 3_546 118.32(4)
Zn4 Zn7 Zn4 3_545 3_546 121.28(6)
Si1 Zn7 Zn10 . 3_545 122.30(8)
Zn4 Zn7 Zn10 3_545 3_545 69.02(4)
Zn4 Zn7 Zn10 3_546 3_545 69.02(4)
Si1 Zn7 Zn9 . . 109.91(7)
Zn4 Zn7 Zn9 3_545 . 87.40(4)
Zn4 Zn7 Zn9 3_546 . 87.40(4)
Zn10 Zn7 Zn9 3_545 . 127.79(6)
Si1 Zn7 Pr1 . 1_554 68.50(4)
Zn4 Zn7 Pr1 3_545 1_554 67.96(3)
Zn4 Zn7 Pr1 3_546 1_554 150.50(5)
Zn10 Zn7 Pr1 3_545 1_554 134.390(17)
Zn9 Zn7 Pr1 . 1_554 64.18(3)
Si1 Zn7 Pr1 . . 68.50(4)
Zn4 Zn7 Pr1 3_545 . 150.50(5)
Zn4 Zn7 Pr1 3_546 . 67.96(3)
Zn10 Zn7 Pr1 3_545 . 134.391(17)
Zn9 Zn7 Pr1 . . 64.18(3)
Pr1 Zn7 Pr1 1_554 . 91.21(3)
Si1 Zn7 Pr3 . 3_545 172.95(7)
Zn4 Zn7 Pr3 3_545 3_545 62.89(3)
Zn4 Zn7 Pr3 3_546 3_545 62.89(3)
Zn10 Zn7 Pr3 3_545 3_545 64.75(4)
Zn9 Zn7 Pr3 . 3_545 63.04(4)
Pr1 Zn7 Pr3 1_554 3_545 106.89(3)
Pr1 Zn7 Pr3 . 3_545 106.89(3)
Si1 Zn7 Pr4 . 1_554 67.16(5)
Zn4 Zn7 Pr4 3_545 1_554 61.43(3)
Zn4 Zn7 Pr4 3_546 1_554 133.65(5)
Zn10 Zn7 Pr4 3_545 1_554 70.91(3)
Zn9 Zn7 Pr4 . 1_554 136.619(17)
Pr1 Zn7 Pr4 1_554 1_554 75.855(17)
Pr1 Zn7 Pr4 . 1_554 135.53(4)
Pr3 Zn7 Pr4 3_545 1_554 117.57(3)
Si1 Zn7 Pr4 . . 67.16(5)
Zn4 Zn7 Pr4 3_545 . 133.65(5)
Zn4 Zn7 Pr4 3_546 . 61.43(3)
Zn10 Zn7 Pr4 3_545 . 70.91(3)
Zn9 Zn7 Pr4 . . 136.619(17)
Pr1 Zn7 Pr4 1_554 . 135.53(4)
Pr1 Zn7 Pr4 . . 75.855(17)
Pr3 Zn7 Pr4 3_545 . 117.57(3)
Pr4 Zn7 Pr4 1_554 . 84.19(3)
Zn9 Zn8 Zn3 . 1_554 118.24(3)
Zn9 Zn8 Zn3 . . 118.25(3)
Zn3 Zn8 Zn3 1_554 . 122.49(6)
Zn9 Zn8 Zn10 . . 124.10(6)
Zn3 Zn8 Zn10 1_554 . 70.31(4)
Zn3 Zn8 Zn10 . . 70.31(4)
Zn9 Zn8 Zn6 . . 107.09(5)
Zn3 Zn8 Zn6 1_554 . 86.77(4)
Zn3 Zn8 Zn6 . . 86.76(4)
Zn10 Zn8 Zn6 . . 128.81(5)
Zn9 Zn8 Pr1 . . 66.75(3)
Zn3 Zn8 Pr1 1_554 . 148.96(6)
Zn3 Zn8 Pr1 . . 67.56(3)
Zn10 Zn8 Pr1 . . 135.060(17)
Zn6 Zn8 Pr1 . . 63.54(3)
Zn9 Zn8 Pr1 . 1_554 66.75(3)
Zn3 Zn8 Pr1 1_554 1_554 67.57(3)
Zn3 Zn8 Pr1 . 1_554 148.96(6)
Zn10 Zn8 Pr1 . 1_554 135.061(17)
Zn6 Zn8 Pr1 . 1_554 63.54(3)
Pr1 Zn8 Pr1 . 1_554 89.88(3)
Zn9 Zn8 Pr3 . . 171.02(6)
Zn3 Zn8 Pr3 1_554 . 63.00(3)
Zn3 Zn8 Pr3 . . 63.00(3)
Zn10 Zn8 Pr3 . . 64.88(4)
Zn6 Zn8 Pr3 . . 63.93(3)
Pr1 Zn8 Pr3 . . 107.35(3)
Pr1 Zn8 Pr3 1_554 . 107.35(3)
Zn9 Zn8 Pr2 . . 72.21(3)
Zn3 Zn8 Pr2 1_554 . 131.83(5)
Zn3 Zn8 Pr2 . . 60.27(3)
Zn10 Zn8 Pr2 . . 66.77(3)
Zn6 Zn8 Pr2 . . 137.971(17)
Pr1 Zn8 Pr2 . . 79.186(19)
Pr1 Zn8 Pr2 1_554 . 138.54(4)
Pr3 Zn8 Pr2 . . 114.10(3)
Zn9 Zn8 Pr2 . 1_554 72.21(3)
Zn3 Zn8 Pr2 1_554 1_554 60.26(3)
Zn3 Zn8 Pr2 . 1_554 131.83(5)
Zn10 Zn8 Pr2 . 1_554 66.77(3)
Zn6 Zn8 Pr2 . 1_554 137.971(17)
Pr1 Zn8 Pr2 . 1_554 138.54(4)
Pr1 Zn8 Pr2 1_554 1_554 79.186(18)
Pr3 Zn8 Pr2 . 1_554 114.10(3)
Pr2 Zn8 Pr2 . 1_554 83.10(3)
Zn8 Zn9 Zn5 . . 117.63(3)
Zn8 Zn9 Zn5 . 1_554 117.63(3)
Zn5 Zn9 Zn5 . 1_554 120.69(6)
Zn8 Zn9 Zn11 . . 122.72(6)
Zn5 Zn9 Zn11 . . 66.68(4)
Zn5 Zn9 Zn11 1_554 . 66.68(4)
Zn8 Zn9 Zn7 . . 106.12(5)
Zn5 Zn9 Zn7 . . 92.13(4)
Zn5 Zn9 Zn7 1_554 . 92.13(4)
Zn11 Zn9 Zn7 . . 131.16(6)
Zn8 Zn9 Pr1 . 1_554 66.81(3)
Zn5 Zn9 Pr1 . 1_554 153.92(5)
Zn5 Zn9 Pr1 1_554 1_554 70.73(3)
Zn11 Zn9 Pr1 . 1_554 135.026(18)
Zn7 Zn9 Pr1 . 1_554 62.91(3)
Zn8 Zn9 Pr1 . . 66.81(3)
Zn5 Zn9 Pr1 . . 70.73(3)
Zn5 Zn9 Pr1 1_554 . 153.92(5)
Zn11 Zn9 Pr1 . . 135.026(18)
Zn7 Zn9 Pr1 . . 62.91(3)
Pr1 Zn9 Pr1 1_554 . 89.93(4)
Zn8 Zn9 Pr3 . 3_545 172.09(6)
Zn5 Zn9 Pr3 . 3_545 64.18(3)
Zn5 Zn9 Pr3 1_554 3_545 64.18(3)
Zn11 Zn9 Pr3 . 3_545 65.18(4)
Zn7 Zn9 Pr3 . 3_545 65.98(4)
Pr1 Zn9 Pr3 1_554 3_545 108.01(3)
Pr1 Zn9 Pr3 . 3_545 108.01(3)
Zn8 Zn9 Pr2 . 1_554 65.46(3)
Zn5 Zn9 Pr2 . 1_554 129.09(5)
Zn5 Zn9 Pr2 1_554 1_554 61.92(3)
Zn11 Zn9 Pr2 . 1_554 71.06(3)
Zn7 Zn9 Pr2 . 1_554 137.93(2)
Pr1 Zn9 Pr2 1_554 1_554 76.844(19)
Pr1 Zn9 Pr2 . 1_554 131.91(4)
Pr3 Zn9 Pr2 3_545 1_554 120.07(3)
Zn8 Zn9 Pr2 . . 65.46(3)
Zn5 Zn9 Pr2 . . 61.92(3)
Zn5 Zn9 Pr2 1_554 . 129.09(5)
Zn11 Zn9 Pr2 . . 71.06(3)
Zn7 Zn9 Pr2 . . 137.93(2)
Pr1 Zn9 Pr2 1_554 . 131.91(4)
Pr1 Zn9 Pr2 . . 76.842(19)
Pr3 Zn9 Pr2 3_545 . 120.08(3)
Pr2 Zn9 Pr2 1_554 . 78.64(3)
Zn1 Zn10 Si1 7_665 7_665 0.00(11)
Zn1 Zn10 Zn7 7_665 3 111.81(8)
Si1 Zn10 Zn7 7_665 3 111.81(8)
Zn1 Zn10 Zn8 7_665 . 112.73(8)
Si1 Zn10 Zn8 7_665 . 112.73(8)
Zn7 Zn10 Zn8 3 . 135.46(6)
Zn1 Zn10 Zn4 7_665 . 119.07(5)
Si1 Zn10 Zn4 7_665 . 119.07(5)
Zn7 Zn10 Zn4 3 . 54.99(3)
Zn8 Zn10 Zn4 . . 101.70(4)
Zn1 Zn10 Zn4 7_665 1_554 119.07(5)
Si1 Zn10 Zn4 7_665 1_554 119.07(5)
Zn7 Zn10 Zn4 3 1_554 54.99(3)
Zn8 Zn10 Zn4 . 1_554 101.70(4)
Zn4 Zn10 Zn4 . 1_554 99.73(5)
Zn1 Zn10 Zn3 7_665 1_554 120.00(4)
Si1 Zn10 Zn3 7_665 1_554 120.00(4)
Zn7 Zn10 Zn3 3 1_554 102.54(4)
Zn8 Zn10 Zn3 . 1_554 53.59(3)
Zn4 Zn10 Zn3 . 1_554 120.91(5)
Zn4 Zn10 Zn3 1_554 1_554 50.79(3)
Zn1 Zn10 Zn3 7_665 . 120.00(4)
Si1 Zn10 Zn3 7_665 . 120.00(4)
Zn7 Zn10 Zn3 3 . 102.54(4)
Zn8 Zn10 Zn3 . . 53.59(3)
Zn4 Zn10 Zn3 . . 50.79(3)
Zn4 Zn10 Zn3 1_554 . 120.91(5)
Zn3 Zn10 Zn3 1_554 . 97.08(5)
Zn1 Zn10 Pr3 7_665 . 179.96(7)
Si1 Zn10 Pr3 7_665 . 179.96(7)
Zn7 Zn10 Pr3 3 . 68.23(4)
Zn8 Zn10 Pr3 . . 67.23(4)
Zn4 Zn10 Pr3 . . 60.95(3)
Zn4 Zn10 Pr3 1_554 . 60.95(3)
Zn3 Zn10 Pr3 1_554 . 59.98(3)
Zn3 Zn10 Pr3 . . 59.98(3)
Zn1 Zn10 Pr2 7_665 . 63.95(4)
Si1 Zn10 Pr2 7_665 . 63.95(4)
Zn7 Zn10 Pr2 3 . 136.34(2)
Zn8 Zn10 Pr2 . . 67.23(3)
Zn4 Zn10 Pr2 . . 87.71(2)
Zn4 Zn10 Pr2 1_554 . 167.90(4)
Zn3 Zn10 Pr2 1_554 . 117.15(4)
Zn3 Zn10 Pr2 . . 57.24(3)
Pr3 Zn10 Pr2 . . 116.02(3)
Zn1 Zn10 Pr2 7_665 1_554 63.95(4)
Si1 Zn10 Pr2 7_665 1_554 63.95(4)
Zn7 Zn10 Pr2 3 1_554 136.34(2)
Zn8 Zn10 Pr2 . 1_554 67.23(3)
Zn4 Zn10 Pr2 . 1_554 167.90(4)
Zn4 Zn10 Pr2 1_554 1_554 87.71(2)
Zn3 Zn10 Pr2 1_554 1_554 57.24(3)
Zn3 Zn10 Pr2 . 1_554 117.15(4)
Pr3 Zn10 Pr2 . 1_554 116.02(3)
Pr2 Zn10 Pr2 . 1_554 83.45(3)
Zn1 Zn10 Pr4 7_665 3_556 64.51(5)
Si1 Zn10 Pr4 7_665 3_556 64.51(5)
Zn7 Zn10 Pr4 3 3_556 64.47(3)
Zn8 Zn10 Pr4 . 3_556 138.875(17)
Zn4 Zn10 Pr4 . 3_556 56.65(3)
Zn4 Zn10 Pr4 1_554 3_556 115.40(4)
Zn3 Zn10 Pr4 1_554 3_556 166.20(4)
Zn3 Zn10 Pr4 . 3_556 90.67(2)
Pr3 Zn10 Pr4 . 3_556 115.52(3)
Pr2 Zn10 Pr4 . 3_556 76.651(18)
Pr2 Zn10 Pr4 1_554 3_556 128.40(4)
Zn9 Zn11 Zn6 . 7_665 113.37(6)
Zn9 Zn11 Zn12 . 3_545 110.12(3)
Zn6 Zn11 Zn12 7_665 3_545 109.51(3)
Zn9 Zn11 Zn12 . 3_546 110.12(3)
Zn6 Zn11 Zn12 7_665 3_546 109.51(3)
Zn12 Zn11 Zn12 3_545 3_546 103.77(4)
Zn9 Zn11 Zn5 . . 56.07(3)
Zn6 Zn11 Zn5 7_665 . 117.88(4)
Zn12 Zn11 Zn5 3_545 . 132.25(5)
Zn12 Zn11 Zn5 3_546 . 55.72(3)
Zn9 Zn11 Zn5 . 1_554 56.07(3)
Zn6 Zn11 Zn5 7_665 1_554 117.88(4)
Zn12 Zn11 Zn5 3_545 1_554 55.72(3)
Zn12 Zn11 Zn5 3_546 1_554 132.25(5)
Zn5 Zn11 Zn5 . 1_554 103.47(6)
Zn9 Zn11 Zn2 . 7_665 118.81(4)
Zn6 Zn11 Zn2 7_665 7_665 55.75(3)
Zn12 Zn11 Zn2 3_545 7_665 130.77(5)
Zn12 Zn11 Zn2 3_546 7_665 55.27(2)
Zn5 Zn11 Zn2 . 7_665 76.56(3)
Zn5 Zn11 Zn2 1_554 7_665 171.01(6)
Zn9 Zn11 Zn2 . 7_664 118.81(4)
Zn6 Zn11 Zn2 7_665 7_664 55.75(3)
Zn12 Zn11 Zn2 3_545 7_664 55.27(2)
Zn12 Zn11 Zn2 3_546 7_664 130.77(5)
Zn5 Zn11 Zn2 . 7_664 171.01(6)
Zn5 Zn11 Zn2 1_554 7_664 76.56(3)
Zn2 Zn11 Zn2 7_665 7_664 101.98(6)
Zn9 Zn11 Pr3 . 3_545 66.68(4)
Zn6 Zn11 Pr3 7_665 3_545 179.95(6)
Zn12 Zn11 Pr3 3_545 3_545 70.46(2)
Zn12 Zn11 Pr3 3_546 3_545 70.46(2)
Zn5 Zn11 Pr3 . 3_545 62.15(3)
Zn5 Zn11 Pr3 1_554 3_545 62.15(3)
Zn2 Zn11 Pr3 7_665 3_545 124.23(3)
Zn2 Zn11 Pr3 7_664 3_545 124.23(3)
Zn9 Zn11 Pr3 . 7_665 179.88(5)
Zn6 Zn11 Pr3 7_665 7_665 66.51(4)
Zn12 Zn11 Pr3 3_545 7_665 69.95(2)
Zn12 Zn11 Pr3 3_546 7_665 69.95(3)
Zn5 Zn11 Pr3 . 7_665 123.97(3)
Zn5 Zn11 Pr3 1_554 7_665 123.97(3)
Zn2 Zn11 Pr3 7_665 7_665 61.13(3)
Zn2 Zn11 Pr3 7_664 7_665 61.13(3)
Pr3 Zn11 Pr3 3_545 7_665 113.43(4)
Zn9 Zn11 Pr2 . 1_554 66.33(3)
Zn6 Zn11 Pr2 7_665 1_554 62.29(3)
Zn12 Zn11 Pr2 3_545 1_554 90.217(13)
Zn12 Zn11 Pr2 3_546 1_554 165.77(3)
Zn5 Zn11 Pr2 . 1_554 116.11(4)
Zn5 Zn11 Pr2 1_554 1_554 58.43(3)
Zn2 Zn11 Pr2 7_665 1_554 113.26(4)
Zn2 Zn11 Pr2 7_664 1_554 56.04(3)
Pr3 Zn11 Pr2 3_545 1_554 117.75(3)
Pr3 Zn11 Pr2 7_665 1_554 113.58(3)
Zn9 Zn11 Pr2 . . 66.33(3)
Zn6 Zn11 Pr2 7_665 . 62.29(3)
Zn12 Zn11 Pr2 3_545 . 165.77(3)
Zn12 Zn11 Pr2 3_546 . 90.217(13)
Zn5 Zn11 Pr2 . . 58.43(3)
Zn5 Zn11 Pr2 1_554 . 116.11(4)
Zn2 Zn11 Pr2 7_665 . 56.04(3)
Zn2 Zn11 Pr2 7_664 . 113.26(4)
Pr3 Zn11 Pr2 3_545 . 117.75(3)
Pr3 Zn11 Pr2 7_665 . 113.58(3)
Pr2 Zn11 Pr2 1_554 . 75.70(3)
Zn2 Zn12 Zn2 . 5_566 180.0
Zn2 Zn12 Zn5 . 7_565 83.78(4)
Zn2 Zn12 Zn5 5_566 7_565 96.23(4)
Zn2 Zn12 Zn5 . 3_556 96.22(4)
Zn2 Zn12 Zn5 5_566 3_556 83.77(4)
Zn5 Zn12 Zn5 7_565 3_556 180.00(4)
Zn2 Zn12 Zn11 . 7_565 63.05(3)
Zn2 Zn12 Zn11 5_566 7_565 116.95(3)
Zn5 Zn12 Zn11 7_565 7_565 62.25(3)
Zn5 Zn12 Zn11 3_556 7_565 117.75(3)
Zn2 Zn12 Zn11 . 3_556 116.95(3)
Zn2 Zn12 Zn11 5_566 3_556 63.05(3)
Zn5 Zn12 Zn11 7_565 3_556 117.75(3)
Zn5 Zn12 Zn11 3_556 3_556 62.25(3)
Zn11 Zn12 Zn11 7_565 3_556 180.00(4)
Zn2 Zn12 Zn11 . 7_566 63.05(3)
Zn2 Zn12 Zn11 5_566 7_566 116.95(3)
Zn5 Zn12 Zn11 7_565 7_566 62.25(3)
Zn5 Zn12 Zn11 3_556 7_566 117.75(3)
Zn11 Zn12 Zn11 7_565 7_566 103.77(4)
Zn11 Zn12 Zn11 3_556 7_566 76.23(4)
Zn2 Zn12 Zn11 . 3 116.95(3)
Zn2 Zn12 Zn11 5_566 3 63.05(3)
Zn5 Zn12 Zn11 7_565 3 117.75(3)
Zn5 Zn12 Zn11 3_556 3 62.25(3)
Zn11 Zn12 Zn11 7_565 3 76.23(4)
Zn11 Zn12 Zn11 3_556 3 103.77(4)
Zn11 Zn12 Zn11 7_566 3 180.00(4)
Zn2 Zn12 Pr3 . . 59.08(2)
Zn2 Zn12 Pr3 5_566 . 120.92(2)
Zn5 Zn12 Pr3 7_565 . 120.68(2)
Zn5 Zn12 Pr3 3_556 . 59.32(2)
Zn11 Zn12 Pr3 7_565 . 60.04(3)
Zn11 Zn12 Pr3 3_556 . 119.96(3)
Zn11 Zn12 Pr3 7_566 . 120.70(3)
Zn11 Zn12 Pr3 3 . 59.30(3)
Zn2 Zn12 Pr3 . 5_565 120.93(2)
Zn2 Zn12 Pr3 5_566 5_565 59.08(2)
Zn5 Zn12 Pr3 7_565 5_565 59.33(2)
Zn5 Zn12 Pr3 3_556 5_565 120.67(2)
Zn11 Zn12 Pr3 7_565 5_565 59.31(3)
Zn11 Zn12 Pr3 3_556 5_565 120.69(2)
Zn11 Zn12 Pr3 7_566 5_565 119.96(3)
Zn11 Zn12 Pr3 3 5_565 60.04(3)
Pr3 Zn12 Pr3 . 5_565 100.153(16)
Zn2 Zn12 Pr3 . 1_556 59.07(2)
Zn2 Zn12 Pr3 5_566 1_556 120.92(2)
Zn5 Zn12 Pr3 7_565 1_556 120.67(2)
Zn5 Zn12 Pr3 3_556 1_556 59.33(2)
Zn11 Zn12 Pr3 7_565 1_556 120.69(3)
Zn11 Zn12 Pr3 3_556 1_556 59.31(3)
Zn11 Zn12 Pr3 7_566 1_556 60.04(3)
Zn11 Zn12 Pr3 3 1_556 119.96(3)
Pr3 Zn12 Pr3 . 1_556 79.847(16)
Pr3 Zn12 Pr3 5_565 1_556 180.000(16)
Zn2 Zn12 Pr3 . 5_566 120.93(2)
Zn2 Zn12 Pr3 5_566 5_566 59.08(2)
Zn5 Zn12 Pr3 7_565 5_566 59.33(2)
Zn5 Zn12 Pr3 3_556 5_566 120.67(2)
Zn11 Zn12 Pr3 7_565 5_566 119.96(3)
Zn11 Zn12 Pr3 3_556 5_566 60.04(3)
Zn11 Zn12 Pr3 7_566 5_566 59.31(2)
Zn11 Zn12 Pr3 3 5_566 120.69(2)
Pr3 Zn12 Pr3 . 5_566 179.999(13)
Pr3 Zn12 Pr3 5_565 5_566 79.846(16)
Pr3 Zn12 Pr3 1_556 5_566 100.154(16)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Pr1 Zn7 . 3.1178(9)
Pr1 Zn7 1_556 3.1178(9)
Pr1 Zn6 . 3.1512(9)
Pr1 Zn6 1_556 3.1513(9)
Pr1 Zn9 1_556 3.1525(10)
Pr1 Zn9 . 3.1525(10)
Pr1 Zn8 . 3.1539(9)
Pr1 Zn8 1_556 3.1539(9)
Pr1 Zn1 1_556 3.204(2)
Pr1 Si1 1_556 3.204(2)
Pr1 Si1 . 3.204(2)
Pr2 Zn3 . 3.0450(14)
Pr2 Zn2 7_665 3.1261(14)
Pr2 Zn1 7_666 3.1754(19)
Pr2 Si1 7_666 3.1754(19)
Pr2 Zn1 7_665 3.1754(19)
Pr2 Si1 7_665 3.1754(19)
Pr2 Zn5 . 3.2321(13)
Pr2 Zn10 1_556 3.3472(10)
Pr2 Zn10 . 3.3472(10)
Pr2 Zn6 7_666 3.3485(10)
Pr2 Zn6 7_665 3.3485(10)
Pr2 Zn8 . 3.3587(11)
Pr3 Zn3 . 3.0905(9)
Pr3 Zn3 1_554 3.0906(9)
Pr3 Zn2 . 3.0994(9)
Pr3 Zn2 1_554 3.0994(9)
Pr3 Zn4 . 3.1094(10)
Pr3 Zn4 1_554 3.1094(10)
Pr3 Zn5 3_556 3.1121(9)
Pr3 Zn5 3 3.1121(9)
Pr3 Zn11 3 3.1674(13)
Pr3 Zn10 . 3.1983(14)
Pr3 Zn11 7_565 3.2015(14)
Pr3 Zn9 3 3.2046(13)
Pr4 Zn4 7_565 3.0743(13)
Pr4 Zn4 3_546 3.0743(13)
Pr4 Si1 . 3.2942(18)
Pr4 Zn1 5 3.2942(18)
Pr4 Zn1 1_556 3.2942(18)
Pr4 Si1 1_556 3.2942(18)
Pr4 Si1 5 3.2942(18)
Pr4 Zn1 5_556 3.2942(18)
Pr4 Si1 5_556 3.2942(18)
Pr4 Zn7 5 3.3232(10)
Pr4 Zn7 1_556 3.3232(10)
Si1 Zn10 7_565 2.489(3)
Si1 Zn7 . 2.503(3)
Si1 Zn6 . 2.535(3)
Si1 Pr2 7_565 3.1754(19)
Si1 Pr2 7_564 3.1754(19)
Si1 Pr1 1_554 3.204(2)
Si1 Pr4 1_554 3.2942(18)
Zn2 Zn6 1_556 2.5772(8)
Zn2 Zn6 . 2.5772(8)
Zn2 Zn12 . 2.6434(12)
Zn2 Zn3 . 2.6983(18)
Zn2 Zn11 7_565 2.8670(11)
Zn2 Zn11 7_566 2.8670(11)
Zn2 Pr3 1_556 3.0994(9)
Zn2 Pr2 7_565 3.1261(14)
Zn3 Zn4 . 2.5251(16)
Zn3 Zn8 1_556 2.5411(8)
Zn3 Zn8 . 2.5411(8)
Zn3 Zn10 1_556 2.9727(12)
Zn3 Zn10 . 2.9727(12)
Zn3 Pr3 1_556 3.0905(9)
Zn4 Zn7 3_556 2.5560(8)
Zn4 Zn7 3 2.5560(8)
Zn4 Zn5 3_556 2.7731(18)
Zn4 Zn10 . 2.9138(11)
Zn4 Zn10 1_556 2.9138(11)
Zn4 Pr4 3_556 3.0743(13)
Zn4 Pr3 1_556 3.1094(10)
Zn4 Pr1 3_556 3.2053(13)
Zn5 Zn9 . 2.5636(8)
Zn5 Zn9 1_556 2.5636(8)
Zn5 Zn12 3_546 2.6492(13)
Zn5 Zn4 3_546 2.7731(18)
Zn5 Zn11 . 2.8372(11)
Zn5 Zn11 1_556 2.8373(11)
Zn5 Pr3 3_545 3.1121(9)
Zn5 Pr3 3_546 3.1121(9)
Zn6 Zn2 1_554 2.5772(8)
Zn6 Zn11 7_565 2.6265(17)
Zn6 Zn8 . 2.8051(17)
Zn6 Pr1 1_554 3.1513(9)
Zn6 Pr2 7_564 3.3485(10)
Zn6 Pr2 7_565 3.3485(10)
Zn7 Zn4 3_545 2.5560(8)
Zn7 Zn4 3_546 2.5560(8)
Zn7 Zn10 3_545 2.5869(16)
Zn7 Zn9 . 2.7936(17)
Zn7 Pr1 1_554 3.1177(9)
Zn7 Pr3 3_545 3.2840(14)
Zn7 Pr4 1_554 3.3233(10)
Zn8 Zn9 . 2.4861(16)
Zn8 Zn3 1_554 2.5411(8)
Zn8 Zn10 . 2.6205(16)
Zn8 Pr1 1_554 3.1539(9)
Zn8 Pr2 1_554 3.3587(10)
Zn9 Zn5 1_554 2.5636(8)
Zn9 Zn11 . 2.5987(17)
Zn9 Pr1 1_554 3.1525(10)
Zn9 Pr3 3_545 3.2046(13)
Zn9 Pr2 1_554 3.5157(10)
Zn10 Zn1 7_665 2.489(3)
Zn10 Si1 7_665 2.489(3)
Zn10 Zn7 3 2.5869(16)
Zn10 Zn4 1_554 2.9138(11)
Zn10 Zn3 1_554 2.9727(12)
Zn10 Pr2 1_554 3.3472(10)
Zn10 Pr4 3_556 3.4802(9)
Zn11 Zn6 7_665 2.6264(17)
Zn11 Zn12 3_545 2.8314(8)
Zn11 Zn12 3_546 2.8314(8)
Zn11 Zn5 1_554 2.8373(11)
Zn11 Zn2 7_665 2.8670(11)
Zn11 Zn2 7_664 2.8670(11)
Zn11 Pr3 3_545 3.1674(13)
Zn11 Pr3 7_665 3.2016(14)
Zn11 Pr2 1_554 3.6307(11)
Zn12 Zn2 5_566 2.6435(12)
Zn12 Zn5 7_565 2.6492(13)
Zn12 Zn5 3_556 2.6492(13)
Zn12 Zn11 7_565 2.8314(8)
Zn12 Zn11 3_556 2.8314(8)
Zn12 Zn11 7_566 2.8314(8)
Zn12 Zn11 3 2.8314(8)
Zn12 Pr3 5_565 3.4713(6)
Zn12 Pr3 1_556 3.4713(6)
Zn12 Pr3 5_566 3.4713(6)
