#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/97/2019788.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2019788
loop_
_publ_author_name
'Liu, Yan-Fei'
'Liu, Ya-Ping'
'Zhang, Ke-Ke'
'Ren, Qing-Ling'
'Qin, Jie'
_publ_section_title
;
 Mononuclear and three-dimensional metal complexes based on a multidentate
 hydrazone ligand
;
_journal_coeditor_code           KU3143
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229615000698
_journal_volume                  71
_journal_year                    2015
_chemical_formula_iupac          '[Cd (C12 H10 N5 O) (C2 H3 O2)], 2C H Cl3'
_chemical_formula_moiety         'C16 H15 Cd Cl6 N5 O3'
_chemical_formula_sum            'C16 H15 Cd Cl6 N5 O3'
_chemical_formula_weight         650.43
_chemical_name_systematic
'Poly[[(acetato-κ²O,O'){μ₃-N'-[1-(pyrazin-2-yl-κ²N¹:N⁴)ethylidene]nicotinohydrazidato-κ³N',O:N¹}cadmium(II)] chloroform disolvate]'
_space_group_IT_number           19
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  'P 2ac 2ab'
_symmetry_space_group_name_H-M   'P 21 21 21'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   10.4215(4)
_cell_length_b                   10.5323(4)
_cell_length_c                   22.2477(10)
_cell_measurement_reflns_used    9979
_cell_measurement_temperature    273(2)
_cell_measurement_theta_max      30.11
_cell_measurement_theta_min      2.68
_cell_volume                     2441.96(17)
_computing_cell_refinement
;
SMART (Bruker, 2002)
;
_computing_data_collection
;
SMART (Bruker, 2002)
;
_computing_data_reduction
;
SAINT (Bruker, 2002)
;
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008)
;
_computing_publication_material
;
SHELXTL (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL97 (Sheldrick, 2008)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      273(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0291
_diffrn_reflns_av_sigmaI/netI    0.0229
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            24532
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.16
_exptl_absorpt_coefficient_mu    1.579
_exptl_absorpt_correction_T_max  0.6937
_exptl_absorpt_correction_T_min  0.6843
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2002)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.769
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1280
_exptl_crystal_size_max          0.26
_exptl_crystal_size_mid          0.25
_exptl_crystal_size_min          0.25
_refine_diff_density_max         0.528
_refine_diff_density_min         -0.396
_refine_ls_abs_structure_details
;
Flack (1983), with 2061 Friedel pairs
;
_refine_ls_abs_structure_Flack   -0.028(19)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.065
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     282
_refine_ls_number_reflns         4778
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.070
_refine_ls_R_factor_all          0.0239
_refine_ls_R_factor_gt           0.0221
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0236P)²+1.4602P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0524
_refine_ls_wR_factor_ref         0.0534
_reflns_number_gt                4608
_reflns_number_total             4778
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ku3143sup1.cif
_cod_data_source_block           III
_cod_database_code               2019788
_cod_database_fobs_code          2019788
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
N N5 0.6290(2) 0.4362(2) 0.65754(10) 0.0300(5) Uani d . 1 1
C C12 0.5718(3) 0.3934(3) 0.70722(12) 0.0286(6) Uani d . 1 1
C C8 0.6216(3) 0.2956(3) 0.74188(11) 0.0253(5) Uani d . 1 1
Cd Cd1 0.479411(17) 0.080513(17) 0.903263(7) 0.02443(6) Uani d U 1 1
C C1 0.2489(3) 0.1118(3) 1.01124(13) 0.0337(7) Uani d . 1 1
H H1 0.2780 0.0329 1.0241 0.040 Uiso calc R 1 1
C C2 0.1614(3) 0.1765(3) 1.04589(14) 0.0368(7) Uani d . 1 1
H H2 0.1338 0.1409 1.0819 0.044 Uiso calc R 1 1
C C3 0.1579(3) 0.3350(3) 0.97698(13) 0.0336(6) Uani d . 1 1
H H3 0.1255 0.4121 0.9633 0.040 Uiso calc R 1 1
C C4 0.2492(3) 0.2723(3) 0.94224(12) 0.0276(6) Uani d . 1 1
C C5 0.3022(3) 0.3281(3) 0.88675(12) 0.0336(6) Uani d . 1 1
C C6 0.2483(4) 0.4483(4) 0.86119(18) 0.0665(13) Uani d . 1 1
H H6A 0.2820 0.5197 0.8829 0.100 Uiso calc R 1 1
H H6B 0.1565 0.4472 0.8647 0.100 Uiso calc R 1 1
H H6C 0.2719 0.4551 0.8196 0.100 Uiso calc R 1 1
C C7 0.5562(2) 0.2495(3) 0.79749(11) 0.0263(5) Uani d . 1 1
C C9 0.7365(3) 0.2407(3) 0.72331(13) 0.0353(7) Uani d . 1 1
H H9 0.7725 0.1740 0.7449 0.042 Uiso calc R 1 1
C C10 0.7958(3) 0.2869(3) 0.67247(15) 0.0432(8) Uani d . 1 1
H H10 0.8731 0.2524 0.6595 0.052 Uiso calc R 1 1
C C11 0.7399(3) 0.3837(3) 0.64131(14) 0.0381(7) Uani d . 1 1
H H11 0.7811 0.4145 0.6072 0.046 Uiso calc R 1 1
H H12 0.4950 0.4308 0.7191 0.046 Uiso d R 1 1
C C13 0.6311(6) -0.2391(5) 0.9937(2) 0.0890(18) Uani d . 1 1
H H13A 0.5925 -0.2434 1.0328 0.133 Uiso calc R 1 1
H H13B 0.7225 -0.2318 0.9978 0.133 Uiso calc R 1 1
H H13C 0.6109 -0.3147 0.9716 0.133 Uiso calc R 1 1
C C14 0.5801(4) -0.1247(3) 0.96050(14) 0.0407(8) Uani d . 1 1
C C15 0.8780(3) 0.0884(5) 0.87745(17) 0.0574(9) Uani d . 1 1
H H15 0.7843 0.0877 0.8810 0.069 Uiso calc R 1 1
C C16 0.2599(4) 0.8177(4) 0.16924(17) 0.0539(9) Uani d . 1 1
H H16 0.2339 0.7303 0.1602 0.065 Uiso calc R 1 1
Cl Cl1 0.94263(13) 0.03738(17) 0.94528(6) 0.1023(5) Uani d . 1 1
Cl Cl2 0.92171(13) -0.01349(12) 0.81879(6) 0.0805(3) Uani d . 1 1
Cl Cl3 0.92675(14) 0.24334(13) 0.86164(7) 0.0891(4) Uani d . 1 1
Cl Cl4 0.32655(18) 0.81988(17) 0.24117(6) 0.1074(5) Uani d . 1 1
Cl Cl5 0.37276(11) 0.86462(13) 0.11562(6) 0.0811(4) Uani d . 1 1
Cl Cl6 0.12367(11) 0.91405(13) 0.16595(6) 0.0791(3) Uani d . 1 1
N N1 0.2931(2) 0.1595(2) 0.95971(10) 0.0293(5) Uani d . 1 1
N N2 0.1151(2) 0.2889(2) 1.02908(10) 0.0322(5) Uani d . 1 1
N N3 0.3990(2) 0.2693(2) 0.86398(9) 0.0270(5) Uani d . 1 1
N N4 0.4550(2) 0.3183(2) 0.81351(10) 0.0324(5) Uani d . 1 1
O O1 0.60245(19) 0.15310(19) 0.82352(9) 0.0331(5) Uani d . 1 1
O O2 0.6364(2) -0.0872(2) 0.91424(10) 0.0469(5) Uani d . 1 1
O O3 0.4845(2) -0.0690(2) 0.98151(9) 0.0426(5) Uani d U 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cd Cd -0.8075 1.2024 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
C11 N5 C12 . . 118.2(3)
C11 N5 Cd1 . 3_656 122.33(19)
C12 N5 Cd1 . 3_656 119.02(18)
N5 C12 C8 . . 123.0(2)
N5 C12 H12 . . 118.5
C8 C12 H12 . . 118.5
C12 C8 C9 . . 117.7(2)
C12 C8 C7 . . 122.1(2)
C9 C8 C7 . . 120.2(2)
O1 Cd1 N5 . 3_646 92.24(8)
O1 Cd1 N3 . . 68.30(7)
N5 Cd1 N3 3_646 . 99.50(9)
O1 Cd1 O3 . . 140.90(7)
N5 Cd1 O3 3_646 . 90.22(8)
N3 Cd1 O3 . . 149.22(7)
O1 Cd1 O2 . . 86.79(7)
N5 Cd1 O2 3_646 . 84.84(8)
N3 Cd1 O2 . . 154.79(8)
O3 Cd1 O2 . . 54.58(7)
O1 Cd1 N1 . . 135.76(7)
N5 Cd1 N1 3_646 . 97.73(8)
N3 Cd1 N1 . . 67.56(7)
O3 Cd1 N1 . . 82.29(7)
O2 Cd1 N1 . . 136.85(7)
O1 Cd1 N2 . 4_557 88.06(8)
N5 Cd1 N2 3_646 4_557 172.41(9)
N3 Cd1 N2 . 4_557 87.67(8)
O3 Cd1 N2 . 4_557 84.80(8)
O2 Cd1 N2 . 4_557 87.61(8)
N1 Cd1 N2 . 4_557 87.29(8)
N1 C1 C2 . . 121.7(3)
N1 C1 H1 . . 119.2
C2 C1 H1 . . 119.2
N2 C2 C1 . . 121.5(3)
N2 C2 H2 . . 119.2
C1 C2 H2 . . 119.2
N2 C3 C4 . . 122.5(3)
N2 C3 H3 . . 118.7
C4 C3 H3 . . 118.7
N1 C4 C3 . . 119.8(2)
N1 C4 C5 . . 118.1(2)
C3 C4 C5 . . 122.1(3)
N3 C5 C4 . . 115.6(3)
N3 C5 C6 . . 123.5(3)
C4 C5 C6 . . 120.9(3)
C5 C6 H6A . . 109.5
C5 C6 H6B . . 109.5
H6A C6 H6B . . 109.5
C5 C6 H6C . . 109.5
H6A C6 H6C . . 109.5
H6B C6 H6C . . 109.5
O1 C7 N4 . . 128.2(2)
O1 C7 C8 . . 117.8(2)
N4 C7 C8 . . 114.0(2)
C10 C9 C8 . . 118.8(3)
C10 C9 H9 . . 120.6
C8 C9 H9 . . 120.6
C11 C10 C9 . . 119.4(3)
C11 C10 H10 . . 120.3
C9 C10 H10 . . 120.3
N5 C11 C10 . . 122.9(3)
N5 C11 H11 . . 118.6
C10 C11 H11 . . 118.6
C14 C13 H13A . . 109.5
C14 C13 H13B . . 109.5
H13A C13 H13B . . 109.5
C14 C13 H13C . . 109.5
H13A C13 H13C . . 109.5
H13B C13 H13C . . 109.5
O3 C14 O2 . . 122.4(3)
O3 C14 C13 . . 118.3(3)
O2 C14 C13 . . 119.3(3)
Cl1 C15 Cl3 . . 110.6(2)
Cl1 C15 Cl2 . . 110.9(2)
Cl3 C15 Cl2 . . 110.3(2)
Cl1 C15 H15 . . 108.3
Cl3 C15 H15 . . 108.3
Cl2 C15 H15 . . 108.3
Cl4 C16 Cl5 . . 110.8(2)
Cl4 C16 Cl6 . . 110.7(2)
Cl5 C16 Cl6 . . 110.7(2)
Cl4 C16 H16 . . 108.2
Cl5 C16 H16 . . 108.2
Cl6 C16 H16 . . 108.2
C4 N1 C1 . . 117.9(2)
C4 N1 Cd1 . . 115.12(18)
C1 N1 Cd1 . . 125.80(19)
C2 N2 C3 . . 116.6(3)
C2 N2 Cd1 . 4_457 121.91(19)
C3 N2 Cd1 . 4_457 121.0(2)
C5 N3 N4 . . 118.4(2)
C5 N3 Cd1 . . 123.04(18)
N4 N3 Cd1 . . 118.51(16)
C7 N4 N3 . . 110.7(2)
C7 O1 Cd1 . . 113.86(16)
C14 O2 Cd1 . . 89.77(19)
C14 O3 Cd1 . . 93.18(18)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
N5 C11 . 1.331(4)
N5 C12 . 1.334(3)
N5 Cd1 3_656 2.328(2)
C12 C8 . 1.387(4)
C12 H12 . 0.9304
C8 C9 . 1.392(4)
C8 C7 . 1.494(3)
Cd1 O1 . 2.3186(19)
Cd1 N5 3_646 2.328(2)
Cd1 N3 . 2.328(2)
Cd1 O3 . 2.348(2)
Cd1 O2 . 2.420(2)
Cd1 N1 . 2.457(2)
Cd1 N2 4_557 2.482(2)
C1 N1 . 1.334(3)
C1 C2 . 1.375(4)
C1 H1 . 0.9300
C2 N2 . 1.331(4)
C2 H2 . 0.9300
C3 N2 . 1.334(4)
C3 C4 . 1.392(4)
C3 H3 . 0.9300
C4 N1 . 1.332(4)
C4 C5 . 1.475(4)
C5 N3 . 1.287(4)
C5 C6 . 1.497(4)
C6 H6A . 0.9600
C6 H6B . 0.9600
C6 H6C . 0.9600
C7 O1 . 1.264(3)
C7 N4 . 1.329(3)
C9 C10 . 1.378(4)
C9 H9 . 0.9300
C10 C11 . 1.364(4)
C10 H10 . 0.9300
C11 H11 . 0.9300
C13 C14 . 1.510(5)
C13 H13A . 0.9600
C13 H13B . 0.9600
C13 H13C . 0.9600
C14 O3 . 1.247(4)
C14 O2 . 1.249(4)
C15 Cl1 . 1.738(4)
C15 Cl3 . 1.745(5)
C15 Cl2 . 1.750(4)
C15 H15 . 0.9800
C16 Cl4 . 1.745(4)
C16 Cl5 . 1.747(4)
C16 Cl6 . 1.747(4)
C16 H16 . 0.9800
N2 Cd1 4_457 2.482(2)
N3 N4 . 1.367(3)
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C15 H15 O2 . 0.98 2.51 3.230(5) 129.9
C15 H15 O1 . 0.98 2.39 3.186(4) 138.2
C16 H16 O2 4_456 0.98 2.46 3.316(5) 145.9
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
C11 N5 C12 C8 . . -1.2(4)
Cd1 N5 C12 C8 3_656 . 171.4(2)
N5 C12 C8 C9 . . 0.0(4)
N5 C12 C8 C7 . . 179.8(3)
N1 C1 C2 N2 . . 1.1(5)
N2 C3 C4 N1 . . 2.6(5)
N2 C3 C4 C5 . . -175.8(3)
N1 C4 C5 N3 . . -8.5(4)
C3 C4 C5 N3 . . 170.0(3)
N1 C4 C5 C6 . . 173.9(3)
C3 C4 C5 C6 . . -7.6(5)
C12 C8 C7 O1 . . 174.2(3)
C9 C8 C7 O1 . . -6.0(4)
C12 C8 C7 N4 . . -6.4(4)
C9 C8 C7 N4 . . 173.4(3)
C12 C8 C9 C10 . . 1.0(4)
C7 C8 C9 C10 . . -178.8(3)
C8 C9 C10 C11 . . -0.8(5)
C12 N5 C11 C10 . . 1.4(5)
Cd1 N5 C11 C10 3_656 . -171.0(3)
C9 C10 C11 N5 . . -0.4(5)
C3 C4 N1 C1 . . -1.3(4)
C5 C4 N1 C1 . . 177.2(3)
C3 C4 N1 Cd1 . . -169.7(2)
C5 C4 N1 Cd1 . . 8.8(3)
C2 C1 N1 C4 . . -0.4(5)
C2 C1 N1 Cd1 . . 166.6(2)
O1 Cd1 N1 C4 . . -0.9(2)
N5 Cd1 N1 C4 3_646 . -102.2(2)
N3 Cd1 N1 C4 . . -5.05(19)
O3 Cd1 N1 C4 . . 168.7(2)
O2 Cd1 N1 C4 . . 167.13(18)
N2 Cd1 N1 C4 4_557 . 83.5(2)
O1 Cd1 N1 C1 . . -168.2(2)
N5 Cd1 N1 C1 3_646 . 90.5(2)
N3 Cd1 N1 C1 . . -172.3(3)
O3 Cd1 N1 C1 . . 1.4(2)
O2 Cd1 N1 C1 . . -0.2(3)
N2 Cd1 N1 C1 4_557 . -83.7(2)
C1 C2 N2 C3 . . 0.1(5)
C1 C2 N2 Cd1 . 4_457 -171.9(2)
C4 C3 N2 C2 . . -1.9(5)
C4 C3 N2 Cd1 . 4_457 170.2(2)
C4 C5 N3 N4 . . -178.1(2)
C6 C5 N3 N4 . . -0.6(5)
C4 C5 N3 Cd1 . . 3.6(4)
C6 C5 N3 Cd1 . . -178.9(3)
O1 Cd1 N3 C5 . . -176.3(3)
N5 Cd1 N3 C5 3_646 . 95.0(2)
O3 Cd1 N3 C5 . . -11.7(3)
O2 Cd1 N3 C5 . . -166.8(2)
N1 Cd1 N3 C5 . . 0.5(2)
N2 Cd1 N3 C5 4_557 . -87.5(2)
O1 Cd1 N3 N4 . . 5.41(18)
N5 Cd1 N3 N4 3_646 . -83.22(19)
O3 Cd1 N3 N4 . . 170.02(17)
O2 Cd1 N3 N4 . . 14.9(3)
N1 Cd1 N3 N4 . . -177.7(2)
N2 Cd1 N3 N4 4_557 . 94.25(19)
O1 C7 N4 N3 . . -1.7(4)
C8 C7 N4 N3 . . 179.0(2)
C5 N3 N4 C7 . . 177.4(3)
Cd1 N3 N4 C7 . . -4.3(3)
N4 C7 O1 Cd1 . . 6.6(4)
C8 C7 O1 Cd1 . . -174.11(18)
N5 Cd1 O1 C7 3_646 . 93.6(2)
N3 Cd1 O1 C7 . . -5.74(18)
O3 Cd1 O1 C7 . . -173.31(17)
O2 Cd1 O1 C7 . . 178.3(2)
N1 Cd1 O1 C7 . . -9.9(2)
N2 Cd1 O1 C7 4_557 . -94.00(19)
O3 C14 O2 Cd1 . . -2.6(3)
C13 C14 O2 Cd1 . . 179.4(4)
O1 Cd1 O2 C14 . . 174.9(2)
N5 Cd1 O2 C14 3_646 . -92.5(2)
N3 Cd1 O2 C14 . . 166.1(2)
O3 Cd1 O2 C14 . . 1.41(19)
N1 Cd1 O2 C14 . . 3.3(2)
N2 Cd1 O2 C14 4_557 . 86.7(2)
O2 C14 O3 Cd1 . . 2.7(4)
C13 C14 O3 Cd1 . . -179.3(4)
O1 Cd1 O3 C14 . . -11.7(3)
N5 Cd1 O3 C14 3_646 . 82.1(2)
N3 Cd1 O3 C14 . . -168.7(2)
O2 Cd1 O3 C14 . . -1.42(19)
N1 Cd1 O3 C14 . . 179.9(2)
N2 Cd1 O3 C14 4_557 . -92.2(2)
