#------------------------------------------------------------------------------
#$Date: 2016-02-20 00:18:51 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176760 $
#$URL: svn://www.crystallography.net/cod/cif/2/01/99/2019922.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2019922
loop_
_publ_author_name
'Mohri, Saki'
'Ohisa, Shinji'
'Isozaki, Katsuhiro'
'Yonezawa, Noriyuki'
'Okamoto, Akiko'
_publ_section_title
;
 Hydrogen bonding between aromatic H and F groups leading to a stripe
 structure withR- andS-columns: the crystal structure of
 (2,7-dimethoxynaphthalen-1-yl)(3-fluorophenyl)methanone and comparison
 with its 1-aroylnaphthalene analogues
;
_journal_coeditor_code           YF3082
_journal_issue                   5
_journal_name_full
'Acta Crystallographica Section C Structural Chemistry'
_journal_paper_doi               10.1107/S2053229615005720
_journal_volume                  71
_journal_year                    2015
_chemical_formula_iupac          'C19 H15 F O3'
_chemical_formula_moiety         'C19 H15 F O3'
_chemical_formula_sum            'C19 H15 F O3'
_chemical_formula_weight         310.31
_chemical_name_systematic
;
(2,7-Dimethoxynaphthalen-1-yl)(3-fluorophenyl)methanone
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.6710(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   11.0057(2)
_cell_length_b                   7.64555(14)
_cell_length_c                   18.6746(3)
_cell_measurement_reflns_used    20127
_cell_measurement_temperature    193(2)
_cell_measurement_theta_max      68.22
_cell_measurement_theta_min      4.13
_cell_volume                     1526.85(5)
_computing_cell_refinement
;
PROCESS-AUTO (Rigaku, 1998)
;
_computing_data_collection
;
PROCESS-AUTO (Rigaku, 1998)
;
_computing_data_reduction
;
CrystalStructure (Rigaku, 2010)
;
_computing_molecular_graphics
;
ORTEPIII (Burnett & Johnson, 1996)
;
_computing_publication_material
;
SHELXL97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL97 (Sheldrick, 2008)
;
_computing_structure_solution
;
SIR2004 (Burla et al.,  2007)
;
_diffrn_ambient_temperature      193(2)
_diffrn_detector_area_resol_mean 10.000
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.997
_diffrn_measurement_device_type  'Rigaku R-AXIS RAPID'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54187
_diffrn_reflns_av_R_equivalents  0.0425
_diffrn_reflns_av_sigmaI/netI    0.0220
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -22
_diffrn_reflns_number            23103
_diffrn_reflns_theta_full        68.22
_diffrn_reflns_theta_max         68.22
_diffrn_reflns_theta_min         4.13
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.819
_exptl_absorpt_correction_T_max  0.7624
_exptl_absorpt_correction_T_min  0.5601
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details
;
(NUMABS; Higashi, 1999)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.350
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             648
_exptl_crystal_size_max          0.80
_exptl_crystal_size_mid          0.60
_exptl_crystal_size_min          0.35
_refine_diff_density_max         0.193
_refine_diff_density_min         -0.136
_refine_ls_extinction_coef       0.0090(6)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method
;
SHELXL97 (Sheldrick, 2008)
;
_refine_ls_goodness_of_fit_ref   1.037
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     211
_refine_ls_number_reflns         2785
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.037
_refine_ls_R_factor_all          0.0433
_refine_ls_R_factor_gt           0.0363
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0576P)²+0.1828P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0969
_refine_ls_wR_factor_ref         0.1005
_reflns_number_gt                2335
_reflns_number_total             2785
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            yf3082sup1.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2019922
_cod_database_fobs_code          2019922
loop_
_symmetry_equiv_pos_site_id
_symmetry_equiv_pos_as_xyz
1 +X,+Y,+Z
2 -X,1/2+Y,1/2-Z
3 -X,-Y,-Z
4 +X,1/2-Y,1/2+Z
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
F F1 0.45548(8) 0.03160(13) 0.12994(4) 0.0599(3) Uani d . 1 1
O O1 0.01902(9) -0.12098(15) -0.09759(6) 0.0544(3) Uani d . 1 1
O O2 0.41064(10) -0.11752(14) -0.35964(5) 0.0537(3) Uani d . 1 1
O O3 0.30109(8) -0.30703(13) -0.10728(5) 0.0462(3) Uani d . 1 1
C C1 0.14582(11) -0.12474(17) -0.18076(7) 0.0364(3) Uani d . 1 1
C C2 0.02776(12) -0.10296(18) -0.16903(8) 0.0431(3) Uani d . 1 1
C C3 -0.07532(12) -0.0672(2) -0.22790(9) 0.0509(4) Uani d . 1 1
H H3 -0.1561 -0.0506 -0.2191 0.061 Uiso calc R 1 1
C C4 -0.05808(13) -0.05659(19) -0.29775(9) 0.0509(4) Uani d . 1 1
H H4 -0.1278 -0.0323 -0.3374 0.061 Uiso calc R 1 1
C C5 0.07923(16) -0.0708(2) -0.38521(8) 0.0552(4) Uani d . 1 1
H H5 0.0093 -0.0527 -0.4255 0.066 Uiso calc R 1 1
C C6 0.19403(16) -0.0865(2) -0.39830(8) 0.0558(4) Uani d . 1 1
H H6 0.2042 -0.0803 -0.4474 0.067 Uiso calc R 1 1
C C7 0.29944(14) -0.11226(18) -0.33908(8) 0.0449(3) Uani d . 1 1
C C8 0.28575(12) -0.12826(17) -0.26824(7) 0.0387(3) Uani d . 1 1
H H8 0.3569 -0.1491 -0.2291 0.046 Uiso calc R 1 1
C C9 0.16555(12) -0.11380(16) -0.25330(7) 0.0369(3) Uani d . 1 1
C C10 0.06016(13) -0.08062(18) -0.31260(8) 0.0444(3) Uani d . 1 1
C C11 0.25103(11) -0.16428(17) -0.11525(6) 0.0342(3) Uani d . 1 1
C C12 0.29267(10) -0.02169(17) -0.06054(6) 0.0329(3) Uani d . 1 1
C C13 0.35546(11) -0.06424(18) 0.01137(7) 0.0365(3) Uani d . 1 1
H H13 0.3691 -0.1826 0.0266 0.044 Uiso calc R 1 1
C C14 0.39675(11) 0.0711(2) 0.05924(7) 0.0403(3) Uani d . 1 1
C C15 0.38375(12) 0.2443(2) 0.03965(7) 0.0447(3) Uani d . 1 1
H H15 0.4159 0.3338 0.0743 0.054 Uiso calc R 1 1
C C16 0.32245(13) 0.28471(19) -0.03199(8) 0.0460(3) Uani d . 1 1
H H16 0.3128 0.4034 -0.0473 0.055 Uiso calc R 1 1
C C17 0.27496(12) 0.15229(18) -0.08157(7) 0.0397(3) Uani d . 1 1
H H17 0.2301 0.1809 -0.1301 0.048 Uiso calc R 1 1
C C18 -0.10079(14) -0.0980(3) -0.08165(11) 0.0645(5) Uani d . 1 1
H H18A -0.1309 0.0209 -0.0951 0.077 Uiso calc R 1 1
H H18B -0.0937 -0.1165 -0.0289 0.077 Uiso calc R 1 1
H H18C -0.1599 -0.1828 -0.1100 0.077 Uiso calc R 1 1
C C19 0.52317(14) -0.1292(2) -0.30333(8) 0.0548(4) Uani d . 1 1
H H19A 0.5265 -0.0328 -0.2684 0.066 Uiso calc R 1 1
H H19B 0.5953 -0.1219 -0.3255 0.066 Uiso calc R 1 1
H H19C 0.5251 -0.2409 -0.2774 0.066 Uiso calc R 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0727 0.0534 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C2 O1 C18 118.16(12)
C7 O2 C19 118.29(10)
C2 C1 C9 120.37(12)
C2 C1 C11 117.96(12)
C9 C1 C11 121.65(11)
O1 C2 C1 115.43(12)
O1 C2 C3 123.52(13)
C1 C2 C3 121.04(13)
C4 C3 C2 119.33(13)
C4 C3 H3 120.3
C2 C3 H3 120.3
C3 C4 C10 121.70(13)
C3 C4 H4 119.1
C10 C4 H4 119.1
C6 C5 C10 121.60(13)
C6 C5 H5 119.2
C10 C5 H5 119.2
C5 C6 C7 120.09(14)
C5 C6 H6 120.0
C7 C6 H6 120.0
O2 C7 C8 125.30(13)
O2 C7 C6 114.06(12)
C8 C7 C6 120.64(14)
C7 C8 C9 120.16(12)
C7 C8 H8 119.9
C9 C8 H8 119.9
C8 C9 C1 122.75(11)
C8 C9 C10 119.12(12)
C1 C9 C10 118.09(12)
C4 C10 C5 122.23(13)
C4 C10 C9 119.46(13)
C5 C10 C9 118.30(13)
O3 C11 C12 121.05(11)
O3 C11 C1 121.32(11)
C12 C11 C1 117.63(11)
C17 C12 C13 120.01(12)
C17 C12 C11 120.49(11)
C13 C12 C11 119.42(11)
C14 C13 C12 117.60(13)
C14 C13 H13 121.2
C12 C13 H13 121.2
F1 C14 C15 117.95(12)
F1 C14 C13 118.24(13)
C15 C14 C13 123.80(12)
C14 C15 C16 117.99(13)
C14 C15 H15 121.0
C16 C15 H15 121.0
C15 C16 C17 120.20(13)
C15 C16 H16 119.9
C17 C16 H16 119.9
C12 C17 C16 120.32(12)
C12 C17 H17 119.8
C16 C17 H17 119.8
O1 C18 H18A 109.5
O1 C18 H18B 109.5
H18A C18 H18B 109.5
O1 C18 H18C 109.5
H18A C18 H18C 109.5
H18B C18 H18C 109.5
O2 C19 H19A 109.5
O2 C19 H19B 109.5
H19A C19 H19B 109.5
O2 C19 H19C 109.5
H19A C19 H19C 109.5
H19B C19 H19C 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
F1 C14 1.3597(14)
O1 C2 1.3670(17)
O1 C18 1.4296(16)
O2 C7 1.3671(17)
O2 C19 1.4254(18)
O3 C11 1.2158(15)
C1 C2 1.3779(18)
C1 C9 1.4242(18)
C1 C11 1.5031(17)
C2 C3 1.408(2)
C3 C4 1.364(2)
C3 H3 0.9500
C4 C10 1.405(2)
C4 H4 0.9500
C5 C6 1.348(2)
C5 C10 1.422(2)
C5 H5 0.9500
C6 C7 1.415(2)
C6 H6 0.9500
C7 C8 1.3720(19)
C8 C9 1.4193(18)
C8 H8 0.9500
C9 C10 1.4243(18)
C11 C12 1.4902(17)
C12 C17 1.3876(18)
C12 C13 1.3957(17)
C13 C14 1.3726(19)
C13 H13 0.9500
C14 C15 1.373(2)
C15 C16 1.3834(19)
C15 H15 0.9500
C16 C17 1.3881(19)
C16 H16 0.9500
C17 H17 0.9500
C18 H18A 0.9800
C18 H18B 0.9800
C18 H18C 0.9800
C19 H19A 0.9800
C19 H19B 0.9800
C19 H19C 0.9800
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
C19 H19A F1 3_655 0.98 2.55 3.2767(16) 131 y
C15 H15 O2 4_555 0.95 2.50 3.3917(18) 156 y
C16 H16 O3 1_565 0.95 2.47 3.4086(18) 169 y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C18 O1 C2 C1 179.33(13)
C18 O1 C2 C3 -1.6(2)
C9 C1 C2 O1 178.24(11)
C11 C1 C2 O1 -0.32(18)
C9 C1 C2 C3 -0.9(2)
C11 C1 C2 C3 -179.45(12)
O1 C2 C3 C4 -178.06(13)
C1 C2 C3 C4 1.0(2)
C2 C3 C4 C10 0.0(2)
C10 C5 C6 C7 -0.5(2)
C19 O2 C7 C8 -4.3(2)
C19 O2 C7 C6 175.16(13)
C5 C6 C7 O2 -176.97(14)
C5 C6 C7 C8 2.5(2)
O2 C7 C8 C9 177.52(12)
C6 C7 C8 C9 -1.9(2)
C7 C8 C9 C1 -178.35(12)
C7 C8 C9 C10 -0.71(19)
C2 C1 C9 C8 177.44(12)
C11 C1 C9 C8 -4.06(19)
C2 C1 C9 C10 -0.23(19)
C11 C1 C9 C10 178.28(12)
C3 C4 C10 C5 179.68(14)
C3 C4 C10 C9 -1.2(2)
C6 C5 C10 C4 177.05(14)
C6 C5 C10 C9 -2.1(2)
C8 C9 C10 C4 -176.53(12)
C1 C9 C10 C4 1.23(19)
C8 C9 C10 C5 2.67(19)
C1 C9 C10 C5 -179.57(12)
C2 C1 C11 O3 110.35(14)
C9 C1 C11 O3 -68.19(17)
C2 C1 C11 C12 -70.12(15)
C9 C1 C11 C12 111.34(13)
O3 C11 C12 C17 153.87(12)
C1 C11 C12 C17 -25.67(16)
O3 C11 C12 C13 -22.92(17)
C1 C11 C12 C13 157.54(11)
C17 C12 C13 C14 0.58(17)
C11 C12 C13 C14 177.39(10)
C12 C13 C14 F1 178.48(10)
C12 C13 C14 C15 -2.44(18)
F1 C14 C15 C16 -179.10(11)
C13 C14 C15 C16 1.82(19)
C14 C15 C16 C17 0.69(19)
C13 C12 C17 C16 1.79(18)
C11 C12 C17 C16 -174.97(11)
C15 C16 C17 C12 -2.5(2)
