#------------------------------------------------------------------------------
#$Date: 2016-11-06 05:42:21 +0200 (Sun, 06 Nov 2016) $
#$Revision: 187987 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/02/05/2020584.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2020584
loop_
_publ_author_name
'Hasi, Qi-Meige'
'Fan, Yan'
'Hou, Chen'
'Yao, Xiao-Qiang'
'Liu, Jia-Cheng'
_publ_section_title
;
 Two new two-dimensional coordination polymers based on isophthalate and a
 flexible N-donor ligand containing benzimidazole and pyridine
 rings: synthesis, crystal structures and a solid-state UV--Vis study
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              724
_journal_page_last               729
_journal_paper_doi               10.1107/S2053229616012912
_journal_volume                  72
_journal_year                    2016
_chemical_formula_iupac          '[Co (C34 H28 N6 O2)0.5 (C8 H4 O4) (H2 O)]'
_chemical_formula_moiety         'C25 H20 Co N3 O6'
_chemical_formula_sum            'C25 H20 Co N3 O6'
_chemical_formula_weight         517.37
_chemical_name_systematic
Poly[diaqua(μ₄-1,4-bis{[1-(pyridin-3-ylmethyl)-1H-benz[d]imidazol-2-yl]methoxy}benzene)bis(μ₂-isophthalato)dicobalt(II)]
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                108.73(3)
_cell_angle_beta                 99.81(3)
_cell_angle_gamma                94.99(3)
_cell_formula_units_Z            2
_cell_length_a                   9.995(2)
_cell_length_b                   10.294(2)
_cell_length_c                   10.796(2)
_cell_measurement_reflns_used    2529
_cell_measurement_temperature    150(2)
_cell_measurement_theta_max      27.800
_cell_measurement_theta_min      3.8820
_cell_volume                     1024.6(4)
_computing_cell_refinement
;
CrysAlis PRO (Agilent, 2013)
;
_computing_data_collection
;
CrysAlis PRO (Agilent, 2013)
;
_computing_data_reduction
;
CrysAlis PRO (Agilent, 2013)
;
_computing_molecular_graphics    'DIAMOND (Brandenburg & Putz, 2005)'
_computing_publication_material
;
SHELXL97 (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL97 (Sheldrick, 2008)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      150(2)
_diffrn_measured_fraction_theta_full 0.984
_diffrn_measured_fraction_theta_max 0.984
_diffrn_measurement_device_type
'Agilent SuperNova Dual Source diffractometer with an Eos detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0410
_diffrn_reflns_av_sigmaI/netI    0.0716
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       12
_diffrn_reflns_limit_l_min       -12
_diffrn_reflns_number            6021
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         3.10
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.891
_exptl_absorpt_correction_T_max  0.8780
_exptl_absorpt_correction_T_min  0.8419
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Agilent, 2013)
;
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.677
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             532
_exptl_crystal_size_max          0.20
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.15
_refine_diff_density_max         0.414
_refine_diff_density_min         -0.431
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.036
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     316
_refine_ls_number_reflns         3546
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.036
_refine_ls_R_factor_all          0.0558
_refine_ls_R_factor_gt           0.0444
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0338P)²+0.3444P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0941
_refine_ls_wR_factor_ref         0.1037
_reflns_number_gt                2943
_reflns_number_total             3546
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            lf3037sup1.cif
_cod_data_source_block           1
_cod_depositor_comments
'Adding full bibliography for 2020584--2020585.cif.'
_cod_original_cell_volume        1024.6(3)
_cod_database_code               2020584
_cod_database_fobs_code          2020584
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
C C1 0.7144(4) 0.2012(3) 0.1951(3) 0.0188(8) Uani d . 1 1
C C2 0.7998(3) 0.1083(3) 0.2455(3) 0.0158(7) Uani d . 1 1
C C3 0.9340(4) 0.1590(4) 0.3174(3) 0.0210(8) Uani d . 1 1
H H3 0.9706 0.2531 0.3359 0.025 Uiso calc R 1 1
C C4 1.0147(4) 0.0741(4) 0.3623(3) 0.0246(8) Uani d . 1 1
H H4 1.1056 0.1101 0.4126 0.030 Uiso calc R 1 1
C C5 0.9620(3) -0.0646(4) 0.3333(3) 0.0214(8) Uani d . 1 1
H H5 1.0181 -0.1236 0.3623 0.026 Uiso calc R 1 1
C C6 0.8276(3) -0.1175(3) 0.2619(3) 0.0163(7) Uani d . 1 1
C C7 0.7472(3) -0.0296(3) 0.2197(3) 0.0169(7) Uani d . 1 1
H H7 0.6550 -0.0643 0.1724 0.020 Uiso calc R 1 1
C C8 0.7784(3) -0.2679(3) 0.2234(3) 0.0175(7) Uani d . 1 1
C C9 0.7013(3) 0.3025(3) -0.1494(3) 0.0155(7) Uani d . 1 1
C C10 0.6270(3) 0.1802(3) -0.1536(3) 0.0196(7) Uani d . 1 1
H H10 0.5959 0.1734 -0.0772 0.024 Uiso calc R 1 1
C C11 0.5996(3) 0.0689(4) -0.2717(3) 0.0226(8) Uani d . 1 1
H H11 0.5496 -0.0157 -0.2758 0.027 Uiso calc R 1 1
C C12 0.6434(3) 0.0772(3) -0.3859(3) 0.0223(8) Uani d . 1 1
H H12 0.6238 -0.0022 -0.4650 0.027 Uiso calc R 1 1
C C13 0.7145(3) 0.1987(4) -0.3857(3) 0.0206(8) Uani d . 1 1
H H13 0.7429 0.2059 -0.4632 0.025 Uiso calc R 1 1
C C14 0.7421(3) 0.3094(3) -0.2660(3) 0.0152(7) Uani d . 1 1
C C15 0.8259(3) 0.5041(3) -0.0954(3) 0.0159(7) Uani d . 1 1
C C16 0.9170(3) 0.6393(3) -0.0225(3) 0.0176(7) Uani d . 1 1
H H16A 0.9390 0.6547 0.0745 0.021 Uiso calc R 1 1
H H16B 1.0039 0.6393 -0.0548 0.021 Uiso calc R 1 1
C C17 0.9272(3) 0.8717(3) -0.0209(3) 0.0167(7) Uani d . 1 1
C C18 0.8641(3) 0.9665(3) -0.0673(3) 0.0194(7) Uani d . 1 1
H H18 0.7708 0.9433 -0.1137 0.023 Uiso calc R 1 1
C C19 1.0636(3) 0.9056(3) 0.0462(3) 0.0203(8) Uani d . 1 1
H H19 1.1072 0.8404 0.0777 0.024 Uiso calc R 1 1
C C20 0.8796(3) 0.4939(4) -0.3194(3) 0.0191(8) Uani d . 1 1
H H20A 0.9227 0.4212 -0.3768 0.023 Uiso calc R 1 1
H H20B 0.9525 0.5733 -0.2663 0.023 Uiso calc R 1 1
C C21 0.7726(3) 0.5416(3) -0.4082(3) 0.0163(7) Uani d . 1 1
C C22 0.6805(3) 0.6286(4) -0.3597(3) 0.0210(8) Uani d . 1 1
H H22 0.6794 0.6609 -0.2670 0.025 Uiso calc R 1 1
C C23 0.5907(4) 0.6670(4) -0.4488(3) 0.0240(8) Uani d . 1 1
H H23 0.5276 0.7275 -0.4179 0.029 Uiso calc R 1 1
C C24 0.7673(3) 0.4956(3) 0.4549(3) 0.0186(7) Uani d . 1 1
H H24 0.8298 0.4355 0.4216 0.022 Uiso calc R 1 1
C C25 0.5930(3) 0.6169(4) 0.4161(3) 0.0218(8) Uani d . 1 1
H H25 0.5309 0.6447 0.3560 0.026 Uiso calc R 1 1
Co Co1 0.70319(4) 0.47561(4) 0.15670(4) 0.01500(15) Uani d . 1 1
N N1 0.6793(3) 0.5307(3) 0.3668(2) 0.0179(6) Uani d . 1 1
N N2 0.7541(3) 0.4274(3) -0.0431(2) 0.0146(6) Uani d . 1 1
N N3 0.8197(3) 0.4392(3) -0.2287(2) 0.0157(6) Uani d . 1 1
O O1 0.5865(2) 0.1724(2) 0.1703(2) 0.0249(6) Uani d . 1 1
O O2 0.7807(2) 0.3067(2) 0.18253(19) 0.0161(5) Uani d . 1 1
O O3 0.6574(2) -0.3225(2) 0.1564(2) 0.0168(5) Uani d . 1 1
O O4 0.8602(2) -0.3462(2) 0.2546(2) 0.0191(5) Uani d . 1 1
O O5 0.5007(2) 0.3793(2) 0.09958(19) 0.0183(5) Uani d . 1 1
H H5B 0.4742 0.3600 0.0187 0.027 Uiso d R 1 1
H H5A 0.5119 0.3021 0.1132 0.022 Uiso d R 1 1
O O6 0.8466(2) 0.7463(2) -0.0465(2) 0.0198(5) Uani d . 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co 0.3494 0.9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O1 C1 O2 . . 124.9(3)
O1 C1 C2 . . 119.0(3)
O2 C1 C2 . . 116.1(3)
C7 C2 C3 . . 119.0(3)
C7 C2 C1 . . 120.9(3)
C3 C2 C1 . . 120.2(3)
C4 C3 C2 . . 120.9(3)
C4 C3 H3 . . 119.6
C2 C3 H3 . . 119.6
C3 C4 C5 . . 119.6(3)
C3 C4 H4 . . 120.2
C5 C4 H4 . . 120.2
C4 C5 C6 . . 120.5(3)
C4 C5 H5 . . 119.8
C6 C5 H5 . . 119.8
C7 C6 C5 . . 118.9(3)
C7 C6 C8 . . 121.8(3)
C5 C6 C8 . . 119.1(3)
C2 C7 C6 . . 121.1(3)
C2 C7 H7 . . 119.5
C6 C7 H7 . . 119.5
O3 C8 O4 . . 118.7(3)
O3 C8 C6 . . 121.9(3)
O4 C8 C6 . . 119.4(3)
O3 C8 Co1 . 1_545 59.68(16)
O4 C8 Co1 . 1_545 59.01(16)
C6 C8 Co1 . 1_545 178.0(2)
C10 C9 N2 . . 131.4(3)
C10 C9 C14 . . 119.0(3)
N2 C9 C14 . . 109.5(3)
C11 C10 C9 . . 118.2(3)
C11 C10 H10 . . 120.9
C9 C10 H10 . . 120.9
C10 C11 C12 . . 121.8(3)
C10 C11 H11 . . 119.1
C12 C11 H11 . . 119.1
C13 C12 C11 . . 121.3(3)
C13 C12 H12 . . 119.3
C11 C12 H12 . . 119.3
C12 C13 C14 . . 116.2(3)
C12 C13 H13 . . 121.9
C14 C13 H13 . . 121.9
N3 C14 C13 . . 130.9(3)
N3 C14 C9 . . 105.5(3)
C13 C14 C9 . . 123.4(3)
N2 C15 N3 . . 112.6(3)
N2 C15 C16 . . 127.2(3)
N3 C15 C16 . . 119.9(3)
O6 C16 C15 . . 108.1(2)
O6 C16 H16A . . 110.1
C15 C16 H16A . . 110.1
O6 C16 H16B . . 110.1
C15 C16 H16B . . 110.1
H16A C16 H16B . . 108.4
O6 C17 C18 . . 115.9(3)
O6 C17 C19 . . 124.2(3)
C18 C17 C19 . . 119.9(3)
C19 C18 C17 2_775 . 120.0(3)
C19 C18 H18 2_775 . 120.0
C17 C18 H18 . . 120.0
C18 C19 C17 2_775 . 120.1(3)
C18 C19 H19 2_775 . 119.9
C17 C19 H19 . . 119.9
N3 C20 C21 . . 112.3(3)
N3 C20 H20A . . 109.1
C21 C20 H20A . . 109.1
N3 C20 H20B . . 109.1
C21 C20 H20B . . 109.1
H20A C20 H20B . . 107.9
C22 C21 C24 . 1_554 118.0(3)
C22 C21 C20 . . 123.8(3)
C24 C21 C20 1_554 . 118.3(3)
C23 C22 C21 . . 118.7(3)
C23 C22 H22 . . 120.7
C21 C22 H22 . . 120.7
C22 C23 C25 . 1_554 119.5(3)
C22 C23 H23 . . 120.2
C25 C23 H23 1_554 . 120.2
N1 C24 C21 . 1_556 124.0(3)
N1 C24 H24 . . 118.0
C21 C24 H24 1_556 . 118.0
N1 C25 C23 . 1_556 122.8(3)
N1 C25 H25 . . 118.6
C23 C25 H25 1_556 . 118.6
O2 Co1 O5 . . 94.52(9)
O2 Co1 O4 . 1_565 107.91(9)
O5 Co1 O4 . 1_565 152.60(9)
O2 Co1 O3 . 1_565 168.82(8)
O5 Co1 O3 . 1_565 95.69(9)
O4 Co1 O3 1_565 1_565 61.03(8)
O2 Co1 N2 . . 91.67(9)
O5 Co1 N2 . . 99.13(9)
O4 Co1 N2 1_565 . 95.81(9)
O3 Co1 N2 1_565 . 91.19(9)
O2 Co1 N1 . . 86.02(10)
O5 Co1 N1 . . 87.58(10)
O4 Co1 N1 1_565 . 78.73(9)
O3 Co1 N1 1_565 . 89.87(9)
N2 Co1 N1 . . 173.07(10)
O2 Co1 C8 . 1_565 138.41(9)
O5 Co1 C8 . 1_565 124.88(10)
O4 Co1 C8 1_565 1_565 30.53(9)
O3 Co1 C8 1_565 1_565 30.50(9)
N2 Co1 C8 . 1_565 94.21(10)
N1 Co1 C8 . 1_565 83.27(10)
C25 N1 C24 . . 117.0(3)
C25 N1 Co1 . . 122.4(2)
C24 N1 Co1 . . 119.9(2)
C15 N2 C9 . . 104.9(2)
C15 N2 Co1 . . 131.5(2)
C9 N2 Co1 . . 123.4(2)
C15 N3 C14 . . 107.5(2)
C15 N3 C20 . . 127.7(3)
C14 N3 C20 . . 124.7(3)
C1 O2 Co1 . . 127.0(2)
C8 O3 Co1 . 1_545 89.83(19)
C8 O4 Co1 . 1_545 90.46(18)
Co1 O5 H5B . . 109.5
Co1 O5 H5A . . 99.3
H5B O5 H5A . . 106.9
C17 O6 C16 . . 116.0(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
C1 O1 . 1.249(4)
C1 O2 . 1.279(4)
C1 C2 . 1.503(4)
C2 C7 . 1.390(4)
C2 C3 . 1.392(4)
C3 C4 . 1.382(5)
C3 H3 . 0.9500
C4 C5 . 1.393(5)
C4 H4 . 0.9500
C5 C6 . 1.395(4)
C5 H5 . 0.9500
C6 C7 . 1.393(4)
C6 C8 . 1.481(4)
C7 H7 . 0.9500
C8 O3 . 1.274(4)
C8 O4 . 1.276(4)
C8 Co1 1_545 2.511(3)
C9 C10 . 1.388(4)
C9 N2 . 1.405(4)
C9 C14 . 1.409(4)
C10 C11 . 1.379(5)
C10 H10 . 0.9500
C11 C12 . 1.401(5)
C11 H11 . 0.9500
C12 C13 . 1.383(5)
C12 H12 . 0.9500
C13 C14 . 1.387(4)
C13 H13 . 0.9500
C14 N3 . 1.385(4)
C15 N2 . 1.335(4)
C15 N3 . 1.366(4)
C15 C16 . 1.489(4)
C16 O6 . 1.425(4)
C16 H16A . 0.9900
C16 H16B . 0.9900
C17 O6 . 1.381(4)
C17 C18 . 1.383(5)
C17 C19 . 1.387(4)
C18 C19 2_775 1.376(4)
C18 H18 . 0.9500
C19 C18 2_775 1.376(4)
C19 H19 . 0.9500
C20 N3 . 1.459(4)
C20 C21 . 1.532(4)
C20 H20A . 0.9900
C20 H20B . 0.9900
C21 C22 . 1.389(5)
C21 C24 1_554 1.390(4)
C22 C23 . 1.378(4)
C22 H22 . 0.9500
C23 C25 1_554 1.387(4)
C23 H23 . 0.9500
C24 N1 . 1.342(4)
C24 C21 1_556 1.390(4)
C24 H24 . 0.9500
C25 N1 . 1.341(4)
C25 C23 1_556 1.387(4)
C25 H25 . 0.9500
Co1 O2 . 2.044(2)
Co1 O5 . 2.072(2)
Co1 O4 1_565 2.153(2)
Co1 O3 1_565 2.168(2)
Co1 N2 . 2.211(2)
Co1 N1 . 2.215(3)
Co1 C8 1_565 2.511(3)
O3 Co1 1_545 2.168(2)
O4 Co1 1_545 2.153(2)
O5 H5B . 0.8200
O5 H5A . 0.8665
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
O1 C1 C2 C7 . . 23.7(5)
O2 C1 C2 C7 . . -157.1(3)
O1 C1 C2 C3 . . -157.2(3)
O2 C1 C2 C3 . . 22.0(4)
C7 C2 C3 C4 . . 0.3(5)
C1 C2 C3 C4 . . -178.8(3)
C2 C3 C4 C5 . . 1.1(5)
C3 C4 C5 C6 . . -1.4(5)
C4 C5 C6 C7 . . 0.3(5)
C4 C5 C6 C8 . . 175.1(3)
C3 C2 C7 C6 . . -1.5(5)
C1 C2 C7 C6 . . 177.6(3)
C5 C6 C7 C2 . . 1.1(5)
C8 C6 C7 C2 . . -173.5(3)
C7 C6 C8 O3 . . -4.3(5)
C5 C6 C8 O3 . . -178.9(3)
C7 C6 C8 O4 . . 173.8(3)
C5 C6 C8 O4 . . -0.8(4)
C7 C6 C8 Co1 . 1_545 138(6)
C5 C6 C8 Co1 . 1_545 -36(6)
N2 C9 C10 C11 . . -174.1(3)
C14 C9 C10 C11 . . 1.8(5)
C9 C10 C11 C12 . . -0.6(5)
C10 C11 C12 C13 . . -1.0(5)
C11 C12 C13 C14 . . 1.4(5)
C12 C13 C14 N3 . . 173.7(3)
C12 C13 C14 C9 . . -0.2(5)
C10 C9 C14 N3 . . -176.7(3)
N2 C9 C14 N3 . . 0.0(3)
C10 C9 C14 C13 . . -1.4(5)
N2 C9 C14 C13 . . 175.3(3)
N2 C15 C16 O6 . . -104.6(4)
N3 C15 C16 O6 . . 82.0(4)
O6 C17 C18 C19 . 2_775 179.9(3)
C19 C17 C18 C19 . 2_775 -0.3(6)
O6 C17 C19 C18 . 2_775 -179.9(3)
C18 C17 C19 C18 . 2_775 0.3(6)
N3 C20 C21 C22 . . 49.7(4)
N3 C20 C21 C24 . 1_554 -130.4(3)
C24 C21 C22 C23 1_554 . -1.3(5)
C20 C21 C22 C23 . . 178.6(3)
C21 C22 C23 C25 . 1_554 0.9(5)
C23 C25 N1 C24 1_556 . -1.2(5)
C23 C25 N1 Co1 1_556 . -170.9(2)
C21 C24 N1 C25 1_556 . 0.8(4)
C21 C24 N1 Co1 1_556 . 170.8(2)
O2 Co1 N1 C25 . . -159.6(3)
O5 Co1 N1 C25 . . -64.9(2)
O4 Co1 N1 C25 1_565 . 91.2(3)
O3 Co1 N1 C25 1_565 . 30.8(2)
N2 Co1 N1 C25 . . 129.6(8)
C8 Co1 N1 C25 1_565 . 60.6(3)
O2 Co1 N1 C24 . . 30.9(2)
O5 Co1 N1 C24 . . 125.6(2)
O4 Co1 N1 C24 1_565 . -78.3(2)
O3 Co1 N1 C24 1_565 . -138.7(2)
N2 Co1 N1 C24 . . -39.9(9)
C8 Co1 N1 C24 1_565 . -108.8(2)
N3 C15 N2 C9 . . 1.8(3)
C16 C15 N2 C9 . . -172.0(3)
N3 C15 N2 Co1 . . -173.0(2)
C16 C15 N2 Co1 . . 13.2(5)
C10 C9 N2 C15 . . 175.1(4)
C14 C9 N2 C15 . . -1.1(3)
C10 C9 N2 Co1 . . -9.7(5)
C14 C9 N2 Co1 . . 174.2(2)
O2 Co1 N2 C15 . . -126.4(3)
O5 Co1 N2 C15 . . 138.7(3)
O4 Co1 N2 C15 1_565 . -18.2(3)
O3 Co1 N2 C15 1_565 . 42.8(3)
N1 Co1 N2 C15 . . -56.0(9)
C8 Co1 N2 C15 1_565 . 12.4(3)
O2 Co1 N2 C9 . . 59.7(2)
O5 Co1 N2 C9 . . -35.2(2)
O4 Co1 N2 C9 1_565 . 167.9(2)
O3 Co1 N2 C9 1_565 . -131.1(2)
N1 Co1 N2 C9 . . 130.1(8)
C8 Co1 N2 C9 1_565 . -161.5(2)
N2 C15 N3 C14 . . -1.8(4)
C16 C15 N3 C14 . . 172.5(3)
N2 C15 N3 C20 . . 176.8(3)
C16 C15 N3 C20 . . -8.9(5)
C13 C14 N3 C15 . . -173.7(3)
C9 C14 N3 C15 . . 1.0(3)
C13 C14 N3 C20 . . 7.6(5)
C9 C14 N3 C20 . . -177.6(3)
C21 C20 N3 C15 . . -102.0(4)
C21 C20 N3 C14 . . 76.4(4)
O1 C1 O2 Co1 . . 13.3(4)
C2 C1 O2 Co1 . . -165.79(19)
O5 Co1 O2 C1 . . -17.2(2)
O4 Co1 O2 C1 1_565 . 146.9(2)
O3 Co1 O2 C1 1_565 . 138.7(4)
N2 Co1 O2 C1 . . -116.5(2)
N1 Co1 O2 C1 . . 70.1(2)
C8 Co1 O2 C1 1_565 . 145.3(2)
O4 C8 O3 Co1 . 1_545 0.5(3)
C6 C8 O3 Co1 . 1_545 178.6(3)
O3 C8 O4 Co1 . 1_545 -0.5(3)
C6 C8 O4 Co1 . 1_545 -178.7(2)
C18 C17 O6 C16 . . 168.3(3)
C19 C17 O6 C16 . . -11.4(4)
C15 C16 O6 C17 . . -161.7(2)
