#------------------------------------------------------------------------------
#$Date: 2018-05-24 18:31:32 +0300 (Thu, 24 May 2018) $
#$Revision: 207961 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/02/11/2021136.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2021136
loop_
_publ_author_name
'Nisar, Madiha'
'Wong, Lawrence W.-Y.'
'Sung, Herman H.-Y.'
'Haynes, Richard K.'
'Williams, Ian D.'
_publ_section_title
;
 Cocrystals of the antimalarial drug 11-azaartemisinin with three alkenoic
 acids of 1:1 or 2:1 stoichiometry
;
_journal_coeditor_code           LF3073
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S2053229618006320
_journal_volume                  74
_journal_year                    2018
_chemical_formula_iupac          '2C15 H23 N O4, C4 H4 O4'
_chemical_formula_moiety         '2(C15 H23 N O4), C4 H4 O4'
_chemical_formula_sum            'C34 H50 N2 O12'
_chemical_formula_weight         678.76
_chemical_name_common
;
11-Azaartemisinin--fumaric acid (1/1)
;
_chemical_name_systematic
'1,5,9-Trimethyl-14,15,16-trioxa-11-azatetracyclo[10.3.1.0^4,13^.0^8,13^]hexadecan-10-one--(2E)-but-2-enedioic acid (1/1)'
_space_group_crystal_system      monoclinic
_space_group_IT_number           4
_space_group_name_Hall           'P 2yb'
_space_group_name_H-M_alt        'P 1 21 1'
_symmetry_space_group_name_Hall  'P 2yb'
_symmetry_space_group_name_H-M   'P 1 21 1'
_atom_sites_solution_hydrogens   mixed
_atom_sites_solution_primary     direct
_audit_creation_method
;
Olex2 1.2-beta
(compiled 2018.02.02 svn.r3481 for OlexSys, GUI svn.r5470)
;
_cell_angle_alpha                90
_cell_angle_beta                 96.4731(11)
_cell_angle_gamma                90
_cell_formula_units_Z            2
_cell_length_a                   9.57929(11)
_cell_length_b                   10.05214(16)
_cell_length_c                   17.7765(2)
_cell_measurement_reflns_used    10873
_cell_measurement_temperature    99.96(13)
_cell_measurement_theta_max      75.5340
_cell_measurement_theta_min      4.6330
_cell_volume                     1700.83(4)
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      99.96(13)
_diffrn_detector_area_resol_mean 10.3577
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type
'Rigaku SuperNova Dual Source diffractometer with an Atlas detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_type           CuK\a
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0241
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       20
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            15361
_diffrn_reflns_theta_full        66.500
_diffrn_reflns_theta_max         67.497
_diffrn_reflns_theta_min         4.646
_exptl_absorpt_coefficient_mu    0.833
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.54561
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2015)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.325
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             728
_exptl_crystal_size_max          0.4
_exptl_crystal_size_mid          0.15
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.152
_refine_diff_density_min         -0.162
_refine_ls_abs_structure_details
;
Flack x determined using 2330 quotients [(I+)-(I-)]/[(I+)+(I-)]
(Parsons et al.,  2013)
;
_refine_ls_abs_structure_Flack   0.11(6)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.018
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     455
_refine_ls_number_reflns         5657
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.018
_refine_ls_R_factor_all          0.0259
_refine_ls_R_factor_gt           0.0254
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0392P)²+0.2051P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0654
_refine_ls_wR_factor_ref         0.0657
_reflns_number_gt                5564
_reflns_number_total             5657
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            lf3073sup1.cif
_cod_data_source_block           madiha46cult
_cod_original_cell_volume        1700.82(4)
_cod_database_code               2021136
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.732
_shelx_estimated_absorpt_t_max   0.907
_shelxl_version_number           2.014
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
O O1 -0.14705(13) 0.01930(15) 0.43814(7) 0.0210(3) Uani d 1
O O2 -0.16249(13) 0.00003(15) 0.51896(7) 0.0223(3) Uani d 1
O O3 -0.14576(13) 0.22260(14) 0.55118(7) 0.0203(3) Uani d 1
O O10 0.30392(13) 0.09722(15) 0.52817(7) 0.0229(3) Uani d 1
N N11 0.08612(15) 0.17835(18) 0.53053(9) 0.0185(3) Uani d 1
H H11 0.112(2) 0.205(3) 0.5749(14) 0.026(6) Uiso d 1
C C1 -0.10110(18) 0.1537(2) 0.42303(10) 0.0181(4) Uani d 1
C C2 -0.04967(17) 0.2267(2) 0.49631(10) 0.0177(4) Uani d 1
H H2 -0.0373 0.3223 0.4830 0.021 Uiso calc 1
C C3 -0.23863(18) 0.1106(2) 0.54311(11) 0.0218(4) Uani d 1
C C4 -0.36889(18) 0.1414(2) 0.48717(12) 0.0263(5) Uani d 1
H H4A -0.3982 0.0591 0.4591 0.032 Uiso calc 1
H H4B -0.4466 0.1682 0.5162 0.032 Uiso calc 1
C C5 -0.34649(19) 0.2507(2) 0.43025(11) 0.0255(4) Uani d 1
H H5A -0.3277 0.3350 0.4584 0.031 Uiso calc 1
H H5B -0.4352 0.2624 0.3965 0.031 Uiso calc 1
C C6 -0.1824(2) 0.3593(2) 0.34533(11) 0.0246(4) Uani d 1
H H6 -0.1477 0.4208 0.3876 0.029 Uiso calc 1
C C7 -0.0624(2) 0.3357(2) 0.29766(11) 0.0282(5) Uani d 1
H H7A -0.0311 0.4223 0.2791 0.034 Uiso calc 1
H H7B -0.0973 0.2814 0.2530 0.034 Uiso calc 1
C C8 0.0629(2) 0.2655(2) 0.34086(11) 0.0241(4) Uani d 1
H H8A 0.1045 0.3235 0.3825 0.029 Uiso calc 1
H H8B 0.1353 0.2490 0.3064 0.029 Uiso calc 1
C C9 0.14019(19) 0.0564(2) 0.41805(10) 0.0197(4) Uani d 1
H H9 0.1029 -0.0345 0.4270 0.024 Uiso calc 1
C C10 0.18336(18) 0.1151(2) 0.49567(10) 0.0193(4) Uani d 1
C C11 -0.22729(19) 0.2280(2) 0.38059(11) 0.0218(4) Uani d 1
H H11A -0.2659 0.1695 0.3377 0.026 Uiso calc 1
C C12 0.01905(18) 0.1331(2) 0.37367(10) 0.0197(4) Uani d 1
H H12 -0.0184 0.0758 0.3300 0.024 Uiso calc 1
C C13 -0.2729(2) 0.0746(2) 0.62168(12) 0.0300(5) Uani d 1
H H13A -0.1869 0.0468 0.6528 0.045 Uiso calc 1
H H13B -0.3411 0.0016 0.6182 0.045 Uiso calc 1
H H13C -0.3129 0.1523 0.6448 0.045 Uiso calc 1
C C14 -0.3053(2) 0.4275(3) 0.29779(13) 0.0332(5) Uani d 1
H H14A -0.2709 0.5058 0.2727 0.050 Uiso calc 1
H H14B -0.3755 0.4551 0.3307 0.050 Uiso calc 1
H H14C -0.3482 0.3653 0.2595 0.050 Uiso calc 1
C C15 0.2678(2) 0.0359(2) 0.37455(12) 0.0291(5) Uani d 1
H H15A 0.3157 0.1211 0.3699 0.044 Uiso calc 1
H H15B 0.2366 0.0009 0.3240 0.044 Uiso calc 1
H H15C 0.3326 -0.0275 0.4019 0.044 Uiso calc 1
O O1A 0.81813(12) 0.99691(14) 0.98122(6) 0.0179(3) Uani d 1
O O2A 0.83624(13) 0.85557(14) 0.96239(7) 0.0189(3) Uani d 1
O O3A 0.81395(12) 0.88511(13) 0.83245(7) 0.0164(3) Uani d 1
O O10A 0.38942(12) 0.88100(14) 0.91775(7) 0.0208(3) Uani d 1
N N11A 0.58533(15) 0.91491(18) 0.86173(9) 0.0170(3) Uani d 1
H H11B 0.569(2) 0.839(3) 0.8393(13) 0.025(6) Uiso d 1
C C1A 0.76808(17) 1.07386(19) 0.91388(9) 0.0149(4) Uani d 1
C C2A 0.71516(17) 0.98276(19) 0.84849(10) 0.0153(4) Uani d 1
H H2A 0.6944 1.0393 0.8023 0.018 Uiso calc 1
C C3A 0.90985(18) 0.8486(2) 0.89763(10) 0.0184(4) Uani d 1
C C4A 1.03800(18) 0.9410(2) 0.90419(11) 0.0216(4) Uani d 1
H H4AA 1.0711 0.9538 0.9585 0.026 Uiso calc 1
H H4AB 1.1144 0.8967 0.8805 0.026 Uiso calc 1
C C5A 1.01141(18) 1.0771(2) 0.86762(11) 0.0206(4) Uani d 1
H H5AA 0.9911 1.0641 0.8123 0.025 Uiso calc 1
H H5AB 1.0993 1.1294 0.8765 0.025 Uiso calc 1
C C6A 0.84479(19) 1.2720(2) 0.83779(10) 0.0199(4) Uani d 1
H H6A 0.8106 1.2293 0.7883 0.024 Uiso calc 1
C C7A 0.7233(2) 1.3519(2) 0.86383(11) 0.0236(4) Uani d 1
H H7AA 0.6907 1.4181 0.8244 0.028 Uiso calc 1
H H7AB 0.7570 1.4010 0.9107 0.028 Uiso calc 1
C C8A 0.59940(19) 1.2629(2) 0.87903(11) 0.0215(4) Uani d 1
H H8AA 0.5242 1.3181 0.8969 0.026 Uiso calc 1
H H8AB 0.5607 1.2185 0.8315 0.026 Uiso calc 1
C C9A 0.53028(18) 1.0664(2) 0.96248(10) 0.0184(4) Uani d 1
H H9A 0.5681 1.0283 1.0126 0.022 Uiso calc 1
C C10A 0.49670(17) 0.9490(2) 0.91108(10) 0.0174(4) Uani d 1
C C11A 0.89160(17) 1.1607(2) 0.89452(10) 0.0172(4) Uani d 1
H H11C 0.9309 1.2052 0.9426 0.021 Uiso calc 1
C C12A 0.64707(17) 1.1581(2) 0.93868(10) 0.0168(4) Uani d 1
H H12A 0.6862 1.2075 0.9852 0.020 Uiso calc 1
C C13A 0.9415(2) 0.7027(2) 0.88912(11) 0.0230(4) Uani d 1
H H13D 0.8566 0.6505 0.8941 0.035 Uiso calc 1
H H13E 1.0160 0.6760 0.9286 0.035 Uiso calc 1
H H13F 0.9724 0.6869 0.8392 0.035 Uiso calc 1
C C14A 0.9675(2) 1.3635(2) 0.82478(12) 0.0271(4) Uani d 1
H H14D 1.0121 1.3962 0.8736 0.041 Uiso calc 1
H H14E 0.9326 1.4390 0.7932 0.041 Uiso calc 1
H H14F 1.0365 1.3138 0.7992 0.041 Uiso calc 1
C C15A 0.39547(19) 1.1407(2) 0.97620(13) 0.0294(5) Uani d 1
H H15D 0.3515 1.1778 0.9283 0.044 Uiso calc 1
H H15E 0.4186 1.2130 1.0125 0.044 Uiso calc 1
H H15F 0.3302 1.0789 0.9966 0.044 Uiso calc 1
O O21 0.41238(14) 0.26565(17) 0.62699(8) 0.0286(3) Uani d 1
H H21 0.368(4) 0.205(4) 0.595(2) 0.084(12) Uiso d 1
O O22 0.21229(13) 0.27193(16) 0.68154(8) 0.0249(3) Uani d 1
O O23 0.31017(14) 0.65994(15) 0.85688(8) 0.0237(3) Uani d 1
H H23 0.352(3) 0.742(4) 0.8795(19) 0.067(10) Uiso d 1
O O24 0.51070(13) 0.64800(15) 0.80351(8) 0.0290(3) Uani d 1
C C21 0.32987(18) 0.3129(2) 0.67523(11) 0.0210(4) Uani d 1
C C22 0.39656(19) 0.4253(2) 0.72062(11) 0.0215(4) Uani d 1
H H22 0.4866 0.4556 0.7107 0.026 Uiso calc 1
C C23 0.33419(19) 0.4837(2) 0.77402(10) 0.0201(4) Uani d 1
H H23A 0.2487 0.4482 0.7878 0.024 Uiso calc 1
C C24 0.39572(18) 0.6052(2) 0.81339(10) 0.0201(4) Uani d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
C1 O1 O2 111.57(13)
C3 O2 O1 107.64(13)
C2 O3 C3 113.52(14)
C2 N11 H11 116.2(16)
C10 N11 H11 115.8(16)
C10 N11 C2 126.99(16)
O1 C1 C2 111.33(15)
O1 C1 C11 107.62(14)
O1 C1 C12 103.95(15)
C2 C1 C11 110.12(16)
C2 C1 C12 111.19(14)
C12 C1 C11 112.44(15)
O3 C2 N11 108.79(14)
O3 C2 C1 113.66(14)
O3 C2 H2 107.2
N11 C2 C1 112.51(15)
N11 C2 H2 107.2
C1 C2 H2 107.2
O2 C3 O3 108.10(13)
O2 C3 C4 111.66(16)
O2 C3 C13 105.32(16)
O3 C3 C4 110.84(16)
O3 C3 C13 106.97(17)
C13 C3 C4 113.61(16)
C3 C4 H4A 108.7
C3 C4 H4B 108.7
H4A C4 H4B 107.6
C5 C4 C3 114.21(15)
C5 C4 H4A 108.7
C5 C4 H4B 108.7
C4 C5 H5A 108.2
C4 C5 H5B 108.2
C4 C5 C11 116.33(18)
H5A C5 H5B 107.4
C11 C5 H5A 108.2
C11 C5 H5B 108.2
C7 C6 H6 107.9
C7 C6 C11 110.80(18)
C7 C6 C14 110.16(17)
C11 C6 H6 107.9
C14 C6 H6 107.9
C14 C6 C11 112.00(17)
C6 C7 H7A 108.9
C6 C7 H7B 108.9
C6 C7 C8 113.15(16)
H7A C7 H7B 107.8
C8 C7 H7A 108.9
C8 C7 H7B 108.9
C7 C8 H8A 109.4
C7 C8 H8B 109.4
C7 C8 C12 111.15(16)
H8A C8 H8B 108.0
C12 C8 H8A 109.4
C12 C8 H8B 109.4
C10 C9 H9 106.1
C10 C9 C12 112.67(16)
C10 C9 C15 111.14(15)
C12 C9 H9 106.1
C15 C9 H9 106.1
C15 C9 C12 114.07(16)
O10 C10 N11 120.80(17)
O10 C10 C9 120.69(16)
N11 C10 C9 118.35(16)
C1 C11 H11A 106.9
C5 C11 C1 112.49(16)
C5 C11 C6 111.45(17)
C5 C11 H11A 106.9
C6 C11 C1 111.93(15)
C6 C11 H11A 106.9
C1 C12 H12 107.1
C8 C12 C1 110.77(16)
C8 C12 C9 114.12(15)
C8 C12 H12 107.1
C9 C12 C1 110.22(15)
C9 C12 H12 107.1
C3 C13 H13A 109.5
C3 C13 H13B 109.5
C3 C13 H13C 109.5
H13A C13 H13B 109.5
H13A C13 H13C 109.5
H13B C13 H13C 109.5
C6 C14 H14A 109.5
C6 C14 H14B 109.5
C6 C14 H14C 109.5
H14A C14 H14B 109.5
H14A C14 H14C 109.5
H14B C14 H14C 109.5
C9 C15 H15A 109.5
C9 C15 H15B 109.5
C9 C15 H15C 109.5
H15A C15 H15B 109.5
H15A C15 H15C 109.5
H15B C15 H15C 109.5
C1A O1A O2A 111.13(12)
C3A O2A O1A 108.31(13)
C2A O3A C3A 113.24(13)
C2A N11A H11B 116.6(15)
C10A N11A H11B 115.8(15)
C10A N11A C2A 127.12(17)
O1A C1A C2A 110.98(15)
O1A C1A C11A 107.08(13)
O1A C1A C12A 104.18(13)
C2A C1A C11A 111.62(14)
C2A C1A C12A 110.68(13)
C12A C1A C11A 112.00(15)
O3A C2A N11A 108.03(15)
O3A C2A C1A 113.51(13)
O3A C2A H2A 107.7
N11A C2A C1A 111.98(14)
N11A C2A H2A 107.7
C1A C2A H2A 107.7
O2A C3A O3A 108.03(13)
O2A C3A C4A 112.05(15)
O2A C3A C13A 104.69(15)
O3A C3A C4A 109.80(15)
O3A C3A C13A 106.48(16)
C13A C3A C4A 115.37(15)
C3A C4A H4AA 108.6
C3A C4A H4AB 108.6
H4AA C4A H4AB 107.6
C5A C4A C3A 114.69(14)
C5A C4A H4AA 108.6
C5A C4A H4AB 108.6
C4A C5A H5AA 108.1
C4A C5A H5AB 108.1
C4A C5A C11A 116.83(15)
H5AA C5A H5AB 107.3
C11A C5A H5AA 108.1
C11A C5A H5AB 108.1
C7A C6A H6A 107.8
C7A C6A C11A 111.06(15)
C7A C6A C14A 110.75(17)
C11A C6A H6A 107.8
C14A C6A H6A 107.8
C14A C6A C11A 111.34(15)
C6A C7A H7AA 109.2
C6A C7A H7AB 109.2
C6A C7A C8A 112.18(17)
H7AA C7A H7AB 107.9
C8A C7A H7AA 109.2
C8A C7A H7AB 109.2
C7A C8A H8AA 109.6
C7A C8A H8AB 109.6
H8AA C8A H8AB 108.1
C12A C8A C7A 110.35(15)
C12A C8A H8AA 109.6
C12A C8A H8AB 109.6
C10A C9A H9A 105.8
C10A C9A C12A 114.43(15)
C10A C9A C15A 110.62(15)
C12A C9A H9A 105.8
C15A C9A H9A 105.8
C15A C9A C12A 113.64(16)
O10A C10A N11A 120.89(18)
O10A C10A C9A 119.50(16)
N11A C10A C9A 119.52(16)
C1A C11A C5A 112.24(16)
C1A C11A H11C 106.7
C5A C11A H11C 106.7
C6A C11A C1A 112.58(15)
C6A C11A C5A 111.42(15)
C6A C11A H11C 106.7
C1A C12A C9A 109.99(15)
C1A C12A H12A 106.6
C8A C12A C1A 110.88(15)
C8A C12A C9A 115.63(15)
C8A C12A H12A 106.6
C9A C12A H12A 106.6
C3A C13A H13D 109.5
C3A C13A H13E 109.5
C3A C13A H13F 109.5
H13D C13A H13E 109.5
H13D C13A H13F 109.5
H13E C13A H13F 109.5
C6A C14A H14D 109.5
C6A C14A H14E 109.5
C6A C14A H14F 109.5
H14D C14A H14E 109.5
H14D C14A H14F 109.5
H14E C14A H14F 109.5
C9A C15A H15D 109.5
C9A C15A H15E 109.5
C9A C15A H15F 109.5
H15D C15A H15E 109.5
H15D C15A H15F 109.5
H15E C15A H15F 109.5
C21 O21 H21 112(2)
C24 O23 H23 109.9(19)
O21 C21 C22 111.93(16)
O22 C21 O21 124.56(19)
O22 C21 C22 123.49(17)
C21 C22 H22 119.1
C23 C22 C21 121.83(17)
C23 C22 H22 119.1
C22 C23 H23A 119.5
C22 C23 C24 121.02(17)
C24 C23 H23A 119.5
O23 C24 C23 112.32(16)
O24 C24 O23 125.09(19)
O24 C24 C23 122.57(17)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
O1 O2 1.4735(18)
O1 C1 1.456(2)
O2 C3 1.422(2)
O3 C2 1.415(2)
O3 C3 1.432(2)
O10 C10 1.245(2)
N11 H11 0.84(3)
N11 C2 1.456(2)
N11 C10 1.337(2)
C1 C2 1.527(2)
C1 C11 1.543(3)
C1 C12 1.538(2)
C2 H2 1.0000
C3 C4 1.537(3)
C3 C13 1.514(3)
C4 H4A 0.9900
C4 H4B 0.9900
C4 C5 1.525(3)
C5 H5A 0.9900
C5 H5B 0.9900
C5 C11 1.537(3)
C6 H6 1.0000
C6 C7 1.522(3)
C6 C11 1.543(3)
C6 C14 1.532(3)
C7 H7A 0.9900
C7 H7B 0.9900
C7 C8 1.523(3)
C8 H8A 0.9900
C8 H8B 0.9900
C8 C12 1.531(3)
C9 H9 1.0000
C9 C10 1.515(3)
C9 C12 1.535(3)
C9 C15 1.532(2)
C11 H11A 1.0000
C12 H12 1.0000
C13 H13A 0.9800
C13 H13B 0.9800
C13 H13C 0.9800
C14 H14A 0.9800
C14 H14B 0.9800
C14 H14C 0.9800
C15 H15A 0.9800
C15 H15B 0.9800
C15 H15C 0.9800
O1A O2A 1.4744(19)
O1A C1A 1.460(2)
O2A C3A 1.418(2)
O3A C2A 1.415(2)
O3A C3A 1.443(2)
O10A C10A 1.251(2)
N11A H11B 0.87(3)
N11A C2A 1.461(2)
N11A C10A 1.332(2)
C1A C2A 1.521(2)
C1A C11A 1.540(2)
C1A C12A 1.540(2)
C2A H2A 1.0000
C3A C4A 1.533(3)
C3A C13A 1.508(3)
C4A H4AA 0.9900
C4A H4AB 0.9900
C4A C5A 1.524(3)
C5A H5AA 0.9900
C5A H5AB 0.9900
C5A C11A 1.541(2)
C6A H6A 1.0000
C6A C7A 1.529(3)
C6A C11A 1.539(3)
C6A C14A 1.531(3)
C7A H7AA 0.9900
C7A H7AB 0.9900
C7A C8A 1.534(3)
C8A H8AA 0.9900
C8A H8AB 0.9900
C8A C12A 1.528(3)
C9A H9A 1.0000
C9A C10A 1.505(3)
C9A C12A 1.545(2)
C9A C15A 1.535(2)
C11A H11C 1.0000
C12A H12A 1.0000
C13A H13D 0.9800
C13A H13E 0.9800
C13A H13F 0.9800
C14A H14D 0.9800
C14A H14E 0.9800
C14A H14F 0.9800
C15A H15D 0.9800
C15A H15E 0.9800
C15A H15F 0.9800
O21 H21 0.91(4)
O21 C21 1.319(2)
O22 C21 1.216(2)
O23 H23 0.98(4)
O23 C24 1.310(2)
O24 C24 1.214(2)
C21 C22 1.490(3)
C22 H22 0.9500
C22 C23 1.316(3)
C23 H23A 0.9500
C23 C24 1.495(3)
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N11 H11 O22 0.84(3) 2.14(3) 2.970(2) 170(2)
N11A H11B O24 0.87(3) 2.08(3) 2.935(2) 169(2)
O21 H21 O10 0.91(4) 1.67(4) 2.573(2) 172(4)
O23 H23 O10A 0.98(4) 1.58(4) 2.550(2) 169(3)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O1 O2 C3 O3 -75.33(16)
O1 O2 C3 C4 46.84(18)
O1 O2 C3 C13 170.59(14)
O1 C1 C2 O3 -51.2(2)
O1 C1 C2 N11 72.98(18)
O1 C1 C11 C5 67.0(2)
O1 C1 C11 C6 -166.59(14)
O1 C1 C12 C8 170.02(14)
O1 C1 C12 C9 -62.71(17)
O2 O1 C1 C2 13.05(18)
O2 O1 C1 C11 -107.72(14)
O2 O1 C1 C12 132.84(13)
O2 C3 C4 C5 -96.5(2)
O3 C3 C4 C5 24.1(2)
C1 O1 O2 C3 46.95(16)
C2 O3 C3 O2 36.03(19)
C2 O3 C3 C4 -86.64(18)
C2 O3 C3 C13 149.01(16)
C2 N11 C10 O10 168.54(19)
C2 N11 C10 C9 -16.1(3)
C2 C1 C11 C5 -54.5(2)
C2 C1 C11 C6 71.88(19)
C2 C1 C12 C8 -70.09(19)
C2 C1 C12 C9 57.2(2)
C3 O3 C2 N11 -101.04(17)
C3 O3 C2 C1 25.2(2)
C3 C4 C5 C11 57.3(2)
C4 C5 C11 C1 -34.6(2)
C4 C5 C11 C6 -161.27(16)
C6 C7 C8 C12 56.4(2)
C7 C6 C11 C1 51.9(2)
C7 C6 C11 C5 178.85(16)
C7 C8 C12 C1 -55.0(2)
C7 C8 C12 C9 179.94(16)
C10 N11 C2 O3 149.75(18)
C10 N11 C2 C1 22.9(3)
C10 C9 C12 C1 -49.7(2)
C10 C9 C12 C8 75.73(19)
C11 C1 C2 O3 68.1(2)
C11 C1 C2 N11 -167.73(14)
C11 C1 C12 C8 53.9(2)
C11 C1 C12 C9 -178.82(16)
C11 C6 C7 C8 -54.4(2)
C12 C1 C2 O3 -166.63(16)
C12 C1 C2 N11 -42.4(2)
C12 C1 C11 C5 -179.11(16)
C12 C1 C11 C6 -52.7(2)
C12 C9 C10 O10 -155.53(18)
C12 C9 C10 N11 29.1(2)
C13 C3 C4 C5 144.58(19)
C14 C6 C7 C8 -178.86(18)
C14 C6 C11 C1 175.34(16)
C14 C6 C11 C5 -57.7(2)
C15 C9 C10 O10 -26.1(3)
C15 C9 C10 N11 158.55(18)
C15 C9 C12 C1 -177.59(16)
C15 C9 C12 C8 -52.2(2)
O1A O2A C3A O3A -74.54(16)
O1A O2A C3A C4A 46.53(17)
O1A O2A C3A C13A 172.27(13)
O1A C1A C2A O3A -53.41(18)
O1A C1A C2A N11A 69.25(17)
O1A C1A C11A C5A 67.91(18)
O1A C1A C11A C6A -165.41(14)
O1A C1A C12A C8A 169.96(15)
O1A C1A C12A C9A -60.88(17)
O2A O1A C1A C2A 14.00(17)
O2A O1A C1A C11A -108.05(14)
O2A O1A C1A C12A 133.15(13)
O2A C3A C4A C5A -94.82(19)
O3A C3A C4A C5A 25.2(2)
C1A O1A O2A C3A 46.89(16)
C2A O3A C3A O2A 33.9(2)
C2A O3A C3A C4A -88.58(17)
C2A O3A C3A C13A 145.87(15)
C2A N11A C10A O10A -178.97(16)
C2A N11A C10A C9A -2.4(3)
C2A C1A C11A C5A -53.7(2)
C2A C1A C11A C6A 72.94(19)
C2A C1A C12A C8A -70.70(19)
C2A C1A C12A C9A 58.46(19)
C3A O3A C2A N11A -96.98(16)
C3A O3A C2A C1A 27.8(2)
C3A C4A C5A C11A 56.1(2)
C4A C5A C11A C1A -34.7(2)
C4A C5A C11A C6A -161.99(15)
C6A C7A C8A C12A 57.9(2)
C7A C6A C11A C1A 51.3(2)
C7A C6A C11A C5A 178.43(15)
C7A C8A C12A C1A -57.1(2)
C7A C8A C12A C9A 176.83(16)
C10A N11A C2A O3A 144.14(17)
C10A N11A C2A C1A 18.4(2)
C10A C9A C12A C1A -42.5(2)
C10A C9A C12A C8A 84.0(2)
C11A C1A C2A O3A 65.96(19)
C11A C1A C2A N11A -171.38(14)
C11A C1A C12A C8A 54.57(19)
C11A C1A C12A C9A -176.28(14)
C11A C6A C7A C8A -54.6(2)
C12A C1A C2A O3A -168.57(14)
C12A C1A C2A N11A -45.9(2)
C12A C1A C11A C5A -178.48(14)
C12A C1A C11A C6A -51.8(2)
C12A C9A C10A O10A -168.40(16)
C12A C9A C10A N11A 14.9(2)
C13A C3A C4A C5A 145.53(16)
C14A C6A C7A C8A -178.81(16)
C14A C6A C11A C1A 175.24(15)
C14A C6A C11A C5A -57.7(2)
C15A C9A C10A O10A -38.5(2)
C15A C9A C10A N11A 144.86(18)
C15A C9A C12A C1A -170.95(15)
C15A C9A C12A C8A -44.4(2)
O21 C21 C22 C23 -177.50(19)
O22 C21 C22 C23 3.6(3)
C21 C22 C23 C24 -173.53(17)
C22 C23 C24 O23 171.06(18)
C22 C23 C24 O24 -7.1(3)

_cod_database_fobs_code 2021136
