#------------------------------------------------------------------------------
#$Date: 2019-02-03 22:57:48 +0200 (Sun, 03 Feb 2019) $
#$Revision: 213464 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/02/14/2021417.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2021417
loop_
_publ_author_name
'Xiang, Zheng'
'Shan, Yue-Bin'
'Li, Tao'
'Huang, Chang-Cang'
'Huang, Xi-He'
'Lin, Mei-Jin'
_publ_section_title
;
 Four isostructural lanthanide(III) coordination compounds based on a new
 N-oxydic pyridyl naphthalenediimide ligand: synthesis and
 characterization
;
_journal_coeditor_code           QF3018
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              38
_journal_page_last               45
_journal_paper_doi               10.1107/S2053229618017357
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac          '[Eu (C26 H16 N4 O4)1.5 (N O3)3], C H4 O'
_chemical_formula_moiety         'C39 H24 Eu N9 O18, C H4 O'
_chemical_formula_sum            'C40 H28 Eu N9 O19'
_chemical_formula_weight         1090.67
_chemical_name_systematic
'catena-Poly[[[tris(nitrato-κ²O,O')europium(III)]-bis{μ-N,N'-bis[(1-oxidopyridin-1-ium-3-yl)methyl]-1,8:4,5-naphthalenetetracarboxdiimide-κ²O:O'}-[tris(nitrato-κ²O,O')europium(III)]-μ-N,N'-bis[(1-oxidopyridin-1-ium-3-yl)methyl]-1,8:4,5-naphthalenetetracarboxdiimide-κ²O:O'] methanol disolvate]'
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_audit_creation_method           SHELXL-2014/7
_cell_angle_alpha                109.498(2)
_cell_angle_beta                 103.761(2)
_cell_angle_gamma                106.110(2)
_cell_formula_units_Z            2
_cell_length_a                   9.8247(2)
_cell_length_b                   15.2829(4)
_cell_length_c                   15.9914(4)
_cell_measurement_reflns_used    18481
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      29.3730
_cell_measurement_theta_min      2.4170
_cell_volume                     2024.57(10)
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2015)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015b)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Rigaku Enhance (Mo) X-ray Source'
_diffrn_measurement_method       'Omiga scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0318
_diffrn_reflns_av_unetI/netI     0.0318
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       19
_diffrn_reflns_limit_k_min       -19
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            29383
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         26.372
_diffrn_reflns_theta_min         2.758
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.647
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.79686
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2015)
;
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.789
_exptl_crystal_description       block
_exptl_crystal_F_000             1092
_exptl_crystal_size_max          0.150
_exptl_crystal_size_mid          0.130
_exptl_crystal_size_min          0.110
_refine_diff_density_max         0.637
_refine_diff_density_min         -0.547
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.058
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     624
_refine_ls_number_reflns         8248
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.058
_refine_ls_R_factor_all          0.0266
_refine_ls_R_factor_gt           0.0232
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0290P)²+0.5700P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0552
_refine_ls_wR_factor_ref         0.0565
_reflns_number_gt                7596
_reflns_number_total             8248
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            qf3018sup1.cif
_cod_data_source_block           Eu
_cod_depositor_comments
'Adding full bibliography for 2021417--2021420.cif.'
_cod_original_cell_volume        2024.56(9)
_cod_database_code               2021417
_cod_database_fobs_code          2021417
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.790
_shelx_estimated_absorpt_t_max   0.840
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Eu Eu1 0.23304(2) 0.17623(2) 0.36540(2) 0.01755(4) Uani d 1
O O1 0.99602(17) 0.84648(12) 0.74558(10) 0.0240(3) Uani d 1
O O2 1.0610(2) 0.57604(15) 0.92946(16) 0.0476(5) Uani d 1
O O3 0.82530(18) 0.78049(11) 1.03917(11) 0.0255(3) Uani d 1
O O4 0.12489(18) 0.36038(12) 0.82417(13) 0.0338(4) Uani d 1
O O5 0.36525(19) 0.15321(11) 0.72898(12) 0.0307(4) Uani d 1
O O6 0.06151(18) 0.07713(11) 0.40637(10) 0.0239(3) Uani d 1
O O7 -0.36415(18) 0.12907(12) 0.29828(11) 0.0285(4) Uani d 1
O O8 -0.30671(19) 0.31525(12) 0.13132(12) 0.0293(4) Uani d 1
O O9 0.17730(17) 0.30952(11) 0.45667(11) 0.0246(3) Uani d 1
O O10 0.38370(17) 0.22572(12) 0.53458(11) 0.0274(4) Uani d 1
O O11 0.50562(19) 0.28887(12) 0.45849(11) 0.0303(4) Uani d 1
O O12 0.6311(2) 0.29761(15) 0.59542(13) 0.0424(5) Uani d 1
O O13 0.31826(18) 0.16358(11) 0.22915(11) 0.0248(3) Uani d 1
O O14 0.30191(19) 0.30595(12) 0.29937(12) 0.0293(4) Uani d 1
O O15 0.35490(19) 0.27359(13) 0.17011(12) 0.0309(4) Uani d 1
O O16 0.37282(19) 0.06388(12) 0.37038(12) 0.0306(4) Uani d 1
O O17 0.15888(18) -0.00257(11) 0.25278(11) 0.0251(3) Uani d 1
O O18 0.3045(2) -0.08657(13) 0.25866(13) 0.0394(4) Uani d 1
N N1 1.04557(19) 0.87889(13) 0.83965(12) 0.0184(4) Uani d 1
N N2 0.9379(2) 0.67891(14) 0.97398(13) 0.0220(4) Uani d 1
N N3 0.2454(2) 0.25788(13) 0.77498(13) 0.0220(4) Uani d 1
N N4 -0.0024(2) 0.10166(13) 0.47121(13) 0.0203(4) Uani d 1
N N5 -0.3514(2) 0.22176(14) 0.21306(14) 0.0222(4) Uani d 1
N N6 0.1046(2) 0.35926(14) 0.42156(13) 0.0230(4) Uani d 1
N N7 0.3266(2) 0.24910(14) 0.23121(13) 0.0221(4) Uani d 1
N N8 0.5110(2) 0.27178(14) 0.53234(14) 0.0270(4) Uani d 1
N N9 0.2801(2) -0.01049(14) 0.29337(14) 0.0252(4) Uani d 1
C C1 1.1122(2) 0.97884(16) 0.89547(16) 0.0196(4) Uani d 1
H H1 1.1201 1.0252 0.8677 0.023 Uiso calc 1
C C2 1.1687(2) 1.01338(17) 0.99281(16) 0.0221(5) Uani d 1
H H2 1.2165 1.0838 1.0325 0.026 Uiso calc 1
C C3 1.1557(2) 0.94517(16) 1.03318(15) 0.0208(5) Uani d 1
H H3 1.1940 0.9689 1.1005 0.025 Uiso calc 1
C C4 1.0867(2) 0.84240(16) 0.97508(15) 0.0196(4) Uani d 1
C C5 1.0325(2) 0.81071(16) 0.87765(15) 0.0196(4) Uani d 1
H H5 0.9855 0.7406 0.8366 0.023 Uiso calc 1
C C6 1.0820(3) 0.76817(18) 1.01879(17) 0.0279(5) Uani d 1
H H6A 1.1661 0.7454 1.0144 0.033 Uiso calc 1
H H6B 1.1001 0.8034 1.0872 0.033 Uiso calc 1
C C7 0.9423(3) 0.58344(18) 0.93153(17) 0.0272(5) Uani d 1
C C8 0.7970(2) 0.49520(17) 0.89054(16) 0.0220(5) Uani d 1
C C9 0.7899(3) 0.39900(18) 0.84329(17) 0.0280(5) Uani d 1
H H9 0.8792 0.3895 0.8372 0.034 Uiso calc 1
C C10 0.6520(3) 0.31566(17) 0.80437(17) 0.0267(5) Uani d 1
H H10 0.6488 0.2499 0.7727 0.032 Uiso calc 1
C C11 0.5211(3) 0.32785(16) 0.81139(15) 0.0206(5) Uani d 1
C C12 0.3749(3) 0.23915(16) 0.76836(15) 0.0229(5) Uani d 1
C C13 0.8118(2) 0.69581(16) 0.99117(15) 0.0189(4) Uani d 1
C C14 0.6679(2) 0.60659(15) 0.94800(14) 0.0168(4) Uani d 1
C C15 0.5364(2) 0.61852(16) 0.95508(15) 0.0188(4) Uani d 1
H H15 0.5402 0.6840 0.9887 0.023 Uiso calc 1
C C16 0.3968(2) 0.53516(16) 0.91321(15) 0.0190(4) Uani d 1
H H16 0.3069 0.5445 0.9179 0.023 Uiso calc 1
C C17 0.3908(2) 0.44030(16) 0.86557(15) 0.0180(4) Uani d 1
C C18 0.2434(3) 0.35281(16) 0.82058(16) 0.0224(5) Uani d 1
C C19 0.6637(2) 0.50944(16) 0.89910(15) 0.0179(4) Uani d 1
C C20 0.5243(2) 0.42534(15) 0.85853(14) 0.0175(4) Uani d 1
C C21 -0.1467(3) 0.09464(17) 0.44159(17) 0.0269(5) Uani d 1
H H21 -0.2013 0.0732 0.3759 0.032 Uiso calc 1
C C22 -0.2142(3) 0.1186(2) 0.50675(19) 0.0350(6) Uani d 1
H H22 -0.3154 0.1152 0.4866 0.042 Uiso calc 1
C C23 -0.1350(3) 0.14790(18) 0.60231(18) 0.0300(5) Uani d 1
H H23 -0.1806 0.1663 0.6480 0.036 Uiso calc 1
C C24 0.0114(3) 0.15015(16) 0.63061(16) 0.0224(5) Uani d 1
C C25 0.0765(2) 0.12768(15) 0.56287(15) 0.0204(5) Uani d 1
H H25 0.1776 0.1306 0.5811 0.024 Uiso calc 1
C C26 0.0984(3) 0.17107(16) 0.73155(16) 0.0252(5) Uani d 1
H H26A 0.0358 0.1843 0.7707 0.030 Uiso calc 1
H H26B 0.1168 0.1106 0.7315 0.030 Uiso calc 1
C C27 0.1847(3) 0.44786(19) 0.42465(19) 0.0342(6) Uani d 1
H H27 0.2927 0.4756 0.4521 0.041 Uiso calc 1
C C28 0.1103(3) 0.4983(2) 0.3881(2) 0.0429(7) Uani d 1
H H28 0.1670 0.5613 0.3909 0.052 Uiso calc 1
C C29 -0.0482(3) 0.45749(19) 0.3469(2) 0.0380(6) Uani d 1
H H29 -0.1003 0.4915 0.3204 0.046 Uiso calc 1
C C30 -0.1280(3) 0.36611(17) 0.34537(16) 0.0258(5) Uani d 1
C C31 -0.0485(3) 0.31901(16) 0.38454(15) 0.0228(5) Uani d 1
H H31 -0.1024 0.2574 0.3854 0.027 Uiso calc 1
C C32 -0.2995(3) 0.31546(18) 0.30058(17) 0.0268(5) Uani d 1
H H32A -0.3401 0.2994 0.3471 0.032 Uiso calc 1
H H32B -0.3408 0.3626 0.2849 0.032 Uiso calc 1
C C33 -0.3856(2) 0.13046(17) 0.22113(16) 0.0223(5) Uani d 1
C C34 -0.4467(2) 0.03778(16) 0.13106(16) 0.0200(4) Uani d 1
C C35 -0.4694(2) 0.04442(16) 0.04290(16) 0.0192(4) Uani d 1
C C36 -0.4304(2) 0.13889(16) 0.03896(16) 0.0205(5) Uani d 1
C C37 -0.3587(2) 0.23226(17) 0.12893(17) 0.0228(5) Uani d 1
C C38 -0.4829(2) -0.05518(17) 0.13293(16) 0.0224(5) Uani d 1
H H38 -0.4661 -0.0595 0.1922 0.027 Uiso calc 1
C C39 -0.4561(2) 0.14298(17) -0.04837(16) 0.0220(5) Uani d 1
H H39 -0.4318 0.2066 -0.0507 0.026 Uiso calc 1
O O19 0.2938(2) 0.41874(16) 0.65577(13) 0.0478(5) Uani d 1
H H19 0.2483 0.3763 0.5986 0.072 Uiso calc 1
C C40 0.4438(3) 0.4749(2) 0.66977(19) 0.0414(7) Uani d 1
H H40A 0.4434 0.4976 0.6192 0.062 Uiso calc 1
H H40B 0.5032 0.4327 0.6681 0.062 Uiso calc 1
H H40C 0.4897 0.5336 0.7318 0.062 Uiso calc 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O1 Eu1 O9 2_666 . 78.86(5)
O1 Eu1 O10 2_666 . 147.22(5)
O1 Eu1 O11 2_666 . 144.94(6)
O1 Eu1 O13 2_666 . 81.87(5)
O1 Eu1 O14 2_666 . 73.23(5)
O1 Eu1 O16 2_666 . 132.34(5)
O1 Eu1 O17 2_666 . 81.14(5)
O1 Eu1 N7 2_666 . 75.11(5)
O1 Eu1 N8 2_666 . 160.18(5)
O1 Eu1 N9 2_666 . 106.79(6)
O6 Eu1 O1 . 2_666 80.88(5)
O6 Eu1 O9 . . 84.97(5)
O6 Eu1 O10 . . 78.31(5)
O6 Eu1 O11 . . 129.57(5)
O6 Eu1 O13 . . 139.31(5)
O6 Eu1 O14 . . 150.42(6)
O6 Eu1 O16 . . 86.55(6)
O6 Eu1 O17 . . 73.04(5)
O6 Eu1 N7 . . 153.23(5)
O6 Eu1 N8 . . 103.45(5)
O6 Eu1 N9 . . 80.10(5)
O9 Eu1 O10 . . 74.35(5)
O9 Eu1 O11 . . 86.35(5)
O9 Eu1 O13 . . 127.00(5)
O9 Eu1 O14 . . 76.32(5)
O9 Eu1 O16 . . 145.60(5)
O9 Eu1 O17 . . 152.29(5)
O9 Eu1 N7 . . 101.60(5)
O9 Eu1 N8 . . 82.24(5)
O9 Eu1 N9 . . 162.86(5)
O10 Eu1 O14 . . 117.21(5)
O10 Eu1 O17 . . 115.96(5)
O10 Eu1 N7 . . 128.45(5)
O10 Eu1 N8 . . 25.77(5)
O10 Eu1 N9 . . 94.28(5)
O11 Eu1 O10 . . 51.57(5)
O11 Eu1 O14 . . 72.45(5)
O11 Eu1 O16 . . 73.76(6)
O11 Eu1 O17 . . 120.61(5)
O11 Eu1 N7 . . 77.05(5)
O11 Eu1 N8 . . 26.13(5)
O11 Eu1 N9 . . 96.66(6)
O13 Eu1 O10 . . 129.70(5)
O13 Eu1 O11 . . 82.09(5)
O13 Eu1 O14 . . 50.85(5)
O13 Eu1 O16 . . 78.48(5)
O13 Eu1 O17 . . 68.05(5)
O13 Eu1 N7 . . 25.43(5)
O13 Eu1 N8 . . 105.18(5)
O13 Eu1 N9 . . 70.13(5)
O14 Eu1 N7 . . 25.47(5)
O14 Eu1 N8 . . 96.58(5)
O14 Eu1 N9 . . 120.70(5)
O16 Eu1 O10 . . 71.29(5)
O16 Eu1 O14 . . 121.55(5)
O16 Eu1 O17 . . 51.26(5)
O16 Eu1 N7 . . 100.89(5)
O16 Eu1 N8 . . 67.48(5)
O16 Eu1 N9 . . 25.55(5)
O17 Eu1 O14 . . 115.71(5)
O17 Eu1 N7 . . 91.50(5)
O17 Eu1 N8 . . 118.68(5)
O17 Eu1 N9 . . 25.78(5)
N8 Eu1 N7 . . 103.15(5)
N8 Eu1 N9 . . 93.02(6)
N9 Eu1 N7 . . 95.52(5)
N1 O1 Eu1 . 2_666 132.01(12)
N4 O6 Eu1 . . 131.22(12)
N6 O9 Eu1 . . 125.14(12)
N8 O10 Eu1 . . 95.75(12)
N8 O11 Eu1 . . 95.36(12)
N7 O13 Eu1 . . 97.88(12)
N7 O14 Eu1 . . 94.86(12)
N9 O16 Eu1 . . 96.31(12)
N9 O17 Eu1 . . 95.69(12)
O1 N1 C1 . . 119.06(18)
O1 N1 C5 . . 119.52(17)
C1 N1 C5 . . 121.39(18)
C7 N2 C6 . . 118.20(18)
C13 N2 C6 . . 115.96(19)
C13 N2 C7 . . 124.99(18)
C12 N3 C26 . . 118.05(18)
C18 N3 C12 . . 125.35(18)
C18 N3 C26 . . 116.60(18)
O6 N4 C21 . . 118.66(18)
O6 N4 C25 . . 119.22(18)
C25 N4 C21 . . 122.04(19)
C33 N5 C32 . . 118.00(19)
C37 N5 C32 . . 116.77(18)
C37 N5 C33 . . 125.21(19)
O9 N6 C27 . . 119.87(19)
O9 N6 C31 . . 118.75(18)
C27 N6 C31 . . 121.4(2)
O13 N7 Eu1 . . 56.70(10)
O14 N7 Eu1 . . 59.68(10)
O14 N7 O13 . . 116.21(17)
O15 N7 Eu1 . . 174.94(14)
O15 N7 O13 . . 121.36(19)
O15 N7 O14 . . 122.42(19)
O10 N8 Eu1 . . 58.48(10)
O10 N8 O11 . . 115.88(18)
O11 N8 Eu1 . . 58.51(10)
O12 N8 Eu1 . . 169.35(16)
O12 N8 O10 . . 122.5(2)
O12 N8 O11 . . 121.6(2)
O16 N9 Eu1 . . 58.14(10)
O16 N9 O17 . . 116.44(18)
O17 N9 Eu1 . . 58.53(10)
O18 N9 Eu1 . . 175.15(14)
O18 N9 O16 . . 122.4(2)
O18 N9 O17 . . 121.2(2)
N1 C1 H1 . . 120.2
N1 C1 C2 . . 119.7(2)
C2 C1 H1 . . 120.2
C1 C2 H2 . . 120.0
C1 C2 C3 . . 119.9(2)
C3 C2 H2 . . 120.0
C2 C3 H3 . . 120.0
C4 C3 C2 . . 120.0(2)
C4 C3 H3 . . 120.0
C3 C4 C6 . . 119.9(2)
C5 C4 C3 . . 118.4(2)
C5 C4 C6 . . 121.6(2)
N1 C5 C4 . . 120.67(19)
N1 C5 H5 . . 119.7
C4 C5 H5 . . 119.7
N2 C6 C4 . . 114.45(18)
N2 C6 H6A . . 108.6
N2 C6 H6B . . 108.6
C4 C6 H6A . . 108.6
C4 C6 H6B . . 108.6
H6A C6 H6B . . 107.6
O2 C7 N2 . . 120.3(2)
O2 C7 C8 . . 122.8(2)
N2 C7 C8 . . 116.93(19)
C9 C8 C7 . . 120.6(2)
C9 C8 C19 . . 119.8(2)
C19 C8 C7 . . 119.6(2)
C8 C9 H9 . . 119.8
C8 C9 C10 . . 120.4(2)
C10 C9 H9 . . 119.8
C9 C10 H10 . . 119.6
C11 C10 C9 . . 120.7(2)
C11 C10 H10 . . 119.6
C10 C11 C12 . . 120.3(2)
C10 C11 C20 . . 120.2(2)
C20 C11 C12 . . 119.43(19)
O5 C12 N3 . . 120.3(2)
O5 C12 C11 . . 122.6(2)
N3 C12 C11 . . 117.06(19)
O3 C13 N2 . . 119.90(19)
O3 C13 C14 . . 123.81(19)
N2 C13 C14 . . 116.29(19)
C15 C14 C13 . . 119.55(19)
C15 C14 C19 . . 119.95(19)
C19 C14 C13 . . 120.50(19)
C14 C15 H15 . . 119.5
C14 C15 C16 . . 120.9(2)
C16 C15 H15 . . 119.5
C15 C16 H16 . . 120.1
C17 C16 C15 . . 119.86(19)
C17 C16 H16 . . 120.1
C16 C17 C18 . . 119.74(19)
C16 C17 C20 . . 120.57(19)
C20 C17 C18 . . 119.69(19)
O4 C18 N3 . . 120.0(2)
O4 C18 C17 . . 123.0(2)
N3 C18 C17 . . 116.98(19)
C14 C19 C8 . . 121.1(2)
C20 C19 C8 . . 119.66(19)
C20 C19 C14 . . 119.29(19)
C11 C20 C17 . . 121.46(19)
C19 C20 C11 . . 119.16(19)
C19 C20 C17 . . 119.38(19)
N4 C21 H21 . . 120.3
N4 C21 C22 . . 119.5(2)
C22 C21 H21 . . 120.3
C21 C22 H22 . . 120.0
C21 C22 C23 . . 120.0(2)
C23 C22 H22 . . 120.0
C22 C23 H23 . . 120.2
C22 C23 C24 . . 119.5(2)
C24 C23 H23 . . 120.2
C23 C24 C26 . . 122.4(2)
C25 C24 C23 . . 118.5(2)
C25 C24 C26 . . 119.0(2)
N4 C25 C24 . . 120.4(2)
N4 C25 H25 . . 119.8
C24 C25 H25 . . 119.8
N3 C26 C24 . . 112.48(18)
N3 C26 H26A . . 109.1
N3 C26 H26B . . 109.1
C24 C26 H26A . . 109.1
C24 C26 H26B . . 109.1
H26A C26 H26B . . 107.8
N6 C27 H27 . . 120.1
N6 C27 C28 . . 119.8(2)
C28 C27 H27 . . 120.1
C27 C28 H28 . . 119.8
C27 C28 C29 . . 120.4(2)
C29 C28 H28 . . 119.8
C28 C29 H29 . . 120.8
C30 C29 C28 . . 118.5(2)
C30 C29 H29 . . 120.8
C29 C30 C32 . . 122.1(2)
C31 C30 C29 . . 119.1(2)
C31 C30 C32 . . 118.8(2)
N6 C31 C30 . . 120.8(2)
N6 C31 H31 . . 119.6
C30 C31 H31 . . 119.6
N5 C32 C30 . . 112.02(18)
N5 C32 H32A . . 109.2
N5 C32 H32B . . 109.2
C30 C32 H32A . . 109.2
C30 C32 H32B . . 109.2
H32A C32 H32B . . 107.9
O7 C33 N5 . . 120.8(2)
O7 C33 C34 . . 122.9(2)
N5 C33 C34 . . 116.38(19)
C35 C34 C33 . . 120.16(19)
C38 C34 C33 . . 120.0(2)
C38 C34 C35 . . 119.9(2)
C35 C35 C34 2_455 . 119.9(2)
C35 C35 C36 2_455 . 119.0(2)
C36 C35 C34 . . 121.1(2)
C35 C36 C37 . . 119.2(2)
C39 C36 C35 . . 119.8(2)
C39 C36 C37 . . 121.0(2)
O8 C37 N5 . . 120.2(2)
O8 C37 C36 . . 122.6(2)
N5 C37 C36 . . 117.28(19)
C34 C38 H38 . . 119.8
C34 C38 C39 . 2_455 120.4(2)
C39 C38 H38 2_455 . 119.8
C36 C39 C38 . 2_455 121.0(2)
C36 C39 H39 . . 119.5
C38 C39 H39 2_455 . 119.5
C40 O19 H19 . . 109.5
O19 C40 H40A . . 109.5
O19 C40 H40B . . 109.5
O19 C40 H40C . . 109.5
H40A C40 H40B . . 109.5
H40A C40 H40C . . 109.5
H40B C40 H40C . . 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Eu1 O1 2_666 2.3644(15) y
Eu1 O6 . 2.3094(15) y
Eu1 O9 . 2.3653(15) y
Eu1 O10 . 2.4879(16) y
Eu1 O11 . 2.4871(16) y
Eu1 O13 . 2.4825(15) y
Eu1 O14 . 2.5488(16) y
Eu1 O16 . 2.4877(16) y
Eu1 O17 . 2.4953(15) y
Eu1 N7 . 2.9422(18) ?
Eu1 N8 . 2.9038(19) ?
Eu1 N9 . 2.9112(19) ?
O1 Eu1 2_666 2.3644(15) ?
O1 N1 . 1.329(2) ?
O2 C7 . 1.210(3) ?
O3 C13 . 1.214(3) ?
O4 C18 . 1.214(3) ?
O5 C12 . 1.217(3) ?
O6 N4 . 1.338(2) ?
O7 C33 . 1.210(3) ?
O8 C37 . 1.212(3) ?
O9 N6 . 1.341(2) ?
O10 N8 . 1.269(2) ?
O11 N8 . 1.284(3) ?
O12 N8 . 1.215(3) ?
O13 N7 . 1.275(2) ?
O14 N7 . 1.270(2) ?
O15 N7 . 1.220(2) ?
O16 N9 . 1.263(2) ?
O17 N9 . 1.272(2) ?
O18 N9 . 1.227(2) ?
N1 C1 . 1.347(3) ?
N1 C5 . 1.363(3) ?
N2 C6 . 1.474(3) ?
N2 C7 . 1.407(3) ?
N2 C13 . 1.403(3) ?
N3 C12 . 1.399(3) ?
N3 C18 . 1.398(3) ?
N3 C26 . 1.474(3) ?
N4 C21 . 1.345(3) ?
N4 C25 . 1.344(3) ?
N5 C32 . 1.479(3) ?
N5 C33 . 1.399(3) ?
N5 C37 . 1.395(3) ?
N6 C27 . 1.342(3) ?
N6 C31 . 1.345(3) ?
C1 H1 . 0.9500 ?
C1 C2 . 1.374(3) ?
C2 H2 . 0.9500 ?
C2 C3 . 1.391(3) ?
C3 H3 . 0.9500 ?
C3 C4 . 1.387(3) ?
C4 C5 . 1.380(3) ?
C4 C6 . 1.514(3) ?
C5 H5 . 0.9500 ?
C6 H6A . 0.9900 ?
C6 H6B . 0.9900 ?
C7 C8 . 1.477(3) ?
C8 C9 . 1.383(3) ?
C8 C19 . 1.416(3) ?
C9 H9 . 0.9500 ?
C9 C10 . 1.399(3) ?
C10 H10 . 0.9500 ?
C10 C11 . 1.374(3) ?
C11 C12 . 1.484(3) ?
C11 C20 . 1.415(3) ?
C13 C14 . 1.474(3) ?
C14 C15 . 1.379(3) ?
C14 C19 . 1.412(3) ?
C15 H15 . 0.9500 ?
C15 C16 . 1.406(3) ?
C16 H16 . 0.9500 ?
C16 C17 . 1.371(3) ?
C17 C18 . 1.480(3) ?
C17 C20 . 1.416(3) ?
C19 C20 . 1.412(3) ?
C21 H21 . 0.9500 ?
C21 C22 . 1.367(4) ?
C22 H22 . 0.9500 ?
C22 C23 . 1.388(4) ?
C23 H23 . 0.9500 ?
C23 C24 . 1.388(3) ?
C24 C25 . 1.380(3) ?
C24 C26 . 1.512(3) ?
C25 H25 . 0.9500 ?
C26 H26A . 0.9900 ?
C26 H26B . 0.9900 ?
C27 H27 . 0.9500 ?
C27 C28 . 1.371(4) ?
C28 H28 . 0.9500 ?
C28 C29 . 1.395(4) ?
C29 H29 . 0.9500 ?
C29 C30 . 1.388(3) ?
C30 C31 . 1.379(3) ?
C30 C32 . 1.511(3) ?
C31 H31 . 0.9500 ?
C32 H32A . 0.9900 ?
C32 H32B . 0.9900 ?
C33 C34 . 1.482(3) ?
C34 C35 . 1.416(3) ?
C34 C38 . 1.378(3) ?
C35 C35 2_455 1.414(4) ?
C35 C36 . 1.414(3) ?
C36 C37 . 1.481(3) ?
C36 C39 . 1.385(3) ?
C38 H38 . 0.9500 ?
C38 C39 2_455 1.395(3) ?
C39 C38 2_455 1.395(3) ?
C39 H39 . 0.9500 ?
O19 H19 . 0.8400 ?
O19 C40 . 1.405(3) ?
C40 H40A . 0.9800 ?
C40 H40B . 0.9800 ?
C40 H40C . 0.9800 ?
