#------------------------------------------------------------------------------
#$Date: 2019-05-03 22:25:03 +0300 (Fri, 03 May 2019) $
#$Revision: 214914 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/02/15/2021540.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2021540
loop_
_publ_author_name
'Bai, Chao'
'Liu, Bin'
'Hu, Huai-Ming'
'Li, Jin-Dian'
'Wang, Xiaofang'
'Xue, Ganglin'
_publ_section_title
;
 Structural investigation of one- and three-dimensional lanthanide(III)
 coordination polymers based on functionalized terpyridine carboxylate and
 aromatic dicarboxylate ligands
;
_journal_coeditor_code           QP3023
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              422
_journal_page_last               432
_journal_paper_doi               10.1107/S2053229619003437
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac          '[Dy (C8 H4 O4) (C22 H14 N3 O3)], H2 O'
_chemical_formula_moiety         'C30 H18 Dy N3 O6, H2 O'
_chemical_formula_sum            'C30 H20 Dy N3 O7'
_chemical_formula_weight         694.97
_chemical_name_systematic
'catena-Poly[[dysprosium(III)-μ₂-(benzene-1,2-dicarboxylato)-μ₂-[2-(2,2':6',2''-terpyridin-4'-yl)benzoato]] monohydrate]'
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.051(2)
_cell_angle_beta                 110.504(2)
_cell_angle_gamma                106.834(2)
_cell_formula_units_Z            2
_cell_length_a                   10.7276(13)
_cell_length_b                   11.6173(14)
_cell_length_c                   12.524(2)
_cell_measurement_reflns_used    4860
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      26.15
_cell_measurement_theta_min      2.17
_cell_volume                     1302.7(3)
_computing_cell_refinement
;
SMART (Bruker, 2008)
;
_computing_data_collection
;
SMART (Bruker, 2008)
;
_computing_data_reduction
;
SAINT (Bruker, 2008)
;
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008)
;
_computing_publication_material
;
SHELXTL (Sheldrick, 2008)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.986
_diffrn_measured_fraction_theta_max 0.986
_diffrn_measurement_device_type  'Bruker SMART APEXII CCD area detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0184
_diffrn_reflns_av_sigmaI/netI    0.0355
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            6466
_diffrn_reflns_theta_full        25.05
_diffrn_reflns_theta_max         25.05
_diffrn_reflns_theta_min         1.97
_exptl_absorpt_coefficient_mu    2.923
_exptl_absorpt_correction_T_max  0.643
_exptl_absorpt_correction_T_min  0.598
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Sheldrick, 1996)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.772
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             682
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.16
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.433
_refine_diff_density_min         -1.190
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.071
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     370
_refine_ls_number_reflns         4542
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.071
_refine_ls_R_factor_all          0.0308
_refine_ls_R_factor_gt           0.0289
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0592P)²+0.0000P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0830
_refine_ls_wR_factor_ref         0.0843
_reflns_number_gt                4258
_reflns_number_total             4542
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            qp3023sup1.cif
_cod_data_source_block           nw2201
_cod_depositor_comments
'Adding full bibliography for 2021540--2021549.cif.'
_cod_original_sg_symbol_H-M      'P-1   '
_cod_database_code               2021540
_cod_database_fobs_code          2021540
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Dy Dy1 0.283755(18) 0.300773(15) 0.490897(15) 0.02170(9) Uani d . 1 1
N N1 0.3891(4) 0.1726(3) 0.6053(3) 0.0275(8) Uani d . 1 1
N N2 0.1515(4) 0.2056(3) 0.6046(3) 0.0243(7) Uani d . 1 1
N N3 0.0397(4) 0.3210(3) 0.4530(3) 0.0263(7) Uani d . 1 1
O O1 -0.3169(3) -0.1630(3) 0.6673(3) 0.0372(7) Uani d . 1 1
O O2 -0.1026(3) -0.1039(3) 0.6679(3) 0.0405(8) Uani d . 1 1
O O3 0.5292(3) 0.3979(3) 0.5403(2) 0.0283(6) Uani d . 1 1
O O4 0.7306(3) 0.5787(3) 0.6320(3) 0.0318(7) Uani d . 1 1
O O5 0.3719(3) 0.4642(3) 0.6682(3) 0.0332(7) Uani d . 1 1
O O6 0.4653(5) 0.6041(4) 0.8567(3) 0.0580(11) Uani d . 1 1
O O7 0.4858(7) 0.1341(5) 0.0478(6) 0.109(2) Uani d . 1 1
C C1 0.5004(5) 0.1470(4) 0.5952(4) 0.0346(10) Uani d . 1 1
H H1 0.5371 0.1782 0.5455 0.042 Uiso calc R 1 1
C C2 0.5620(5) 0.0774(5) 0.6544(5) 0.0414(12) Uani d . 1 1
H H2 0.6398 0.0635 0.6461 0.050 Uiso calc R 1 1
C C3 0.5069(6) 0.0286(5) 0.7263(5) 0.0495(13) Uani d . 1 1
H H3 0.5446 -0.0211 0.7657 0.059 Uiso calc R 1 1
C C4 0.3941(6) 0.0553(5) 0.7384(5) 0.0455(13) Uani d . 1 1
H H4 0.3557 0.0242 0.7872 0.055 Uiso calc R 1 1
C C5 0.3383(5) 0.1282(4) 0.6779(4) 0.0295(9) Uani d . 1 1
C C6 0.2181(4) 0.1608(4) 0.6885(4) 0.0267(9) Uani d . 1 1
C C7 0.1756(5) 0.1435(4) 0.7780(4) 0.0315(10) Uani d . 1 1
H H7 0.2294 0.1199 0.8388 0.038 Uiso calc R 1 1
C C8 0.0536(5) 0.1611(4) 0.7774(4) 0.0268(9) Uani d . 1 1
C C9 -0.0163(5) 0.2047(4) 0.6891(4) 0.0289(9) Uani d . 1 1
H H9 -0.0981 0.2190 0.6862 0.035 Uiso calc R 1 1
C C10 0.0349(4) 0.2270(4) 0.6057(4) 0.0258(9) Uani d . 1 1
C C11 -0.0357(4) 0.2763(4) 0.5110(4) 0.0268(9) Uani d . 1 1
C C12 -0.1714(5) 0.2760(5) 0.4875(5) 0.0393(11) Uani d . 1 1
H H12 -0.2205 0.2444 0.5298 0.047 Uiso calc R 1 1
C C13 -0.2341(5) 0.3233(5) 0.3998(4) 0.0421(11) Uani d . 1 1
H H13 -0.3256 0.3239 0.3823 0.050 Uiso calc R 1 1
C C14 -0.1579(5) 0.3693(5) 0.3394(4) 0.0389(11) Uani d . 1 1
H H14 -0.1962 0.4025 0.2807 0.047 Uiso calc R 1 1
C C15 -0.0235(5) 0.3653(4) 0.3678(4) 0.0350(10) Uani d . 1 1
H H15 0.0266 0.3949 0.3254 0.042 Uiso calc R 1 1
C C16 -0.0019(5) 0.1363(4) 0.8673(4) 0.0255(9) Uani d . 1 1
C C17 0.0634(5) 0.2290(4) 0.9836(4) 0.0325(10) Uani d . 1 1
H H17 0.1447 0.3031 1.0060 0.039 Uiso calc R 1 1
C C18 0.0092(5) 0.2127(4) 1.0674(4) 0.0368(11) Uani d . 1 1
H H18 0.0545 0.2752 1.1457 0.044 Uiso calc R 1 1
C C19 -0.1125(5) 0.1030(5) 1.0338(4) 0.0370(11) Uani d . 1 1
H H19 -0.1509 0.0932 1.0888 0.044 Uiso calc R 1 1
C C20 -0.1775(5) 0.0073(4) 0.9182(4) 0.0299(9) Uani d . 1 1
H H20 -0.2580 -0.0671 0.8967 0.036 Uiso calc R 1 1
C C21 -0.1223(5) 0.0226(4) 0.8349(4) 0.0260(9) Uani d . 1 1
C C22 -0.1842(5) -0.0863(4) 0.7169(4) 0.0257(9) Uani d . 1 1
C C23 0.6387(4) 0.4817(4) 0.6332(4) 0.0231(8) Uani d . 1 1
C C24 0.6723(4) 0.4645(4) 0.7535(4) 0.0254(9) Uani d . 1 1
C C25 0.7877(5) 0.4302(4) 0.7995(4) 0.0350(10) Uani d . 1 1
H H25 0.8457 0.4268 0.7594 0.042 Uiso calc R 1 1
C C26 0.8179(6) 0.4011(5) 0.9038(5) 0.0464(12) Uani d . 1 1
H H26 0.8950 0.3768 0.9323 0.056 Uiso calc R 1 1
C C27 0.7369(6) 0.4073(5) 0.9656(5) 0.0521(14) Uani d . 1 1
H H27 0.7555 0.3844 1.0342 0.062 Uiso calc R 1 1
C C28 0.6266(6) 0.4482(5) 0.9250(4) 0.0439(12) Uani d . 1 1
H H28 0.5748 0.4578 0.9699 0.053 Uiso calc R 1 1
C C29 0.5909(5) 0.4756(4) 0.8182(4) 0.0291(9) Uani d . 1 1
C C30 0.4689(5) 0.5197(4) 0.7797(4) 0.0302(10) Uani d . 1 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Dy Dy -0.1892 4.4098 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O5 Dy1 O4 . 2_666 96.87(11)
O5 Dy1 O3 . . 77.08(10)
O4 Dy1 O3 2_666 . 80.79(10)
O5 Dy1 O2 . 2_556 152.98(12)
O4 Dy1 O2 2_666 2_556 95.00(11)
O3 Dy1 O2 . 2_556 128.92(10)
O5 Dy1 O1 . 2_556 151.61(11)
O4 Dy1 O1 2_666 2_556 82.91(11)
O3 Dy1 O1 . 2_556 74.86(10)
O2 Dy1 O1 2_556 2_556 54.18(10)
O5 Dy1 N1 . . 90.14(11)
O4 Dy1 N1 2_666 . 155.52(12)
O3 Dy1 N1 . . 77.97(11)
O2 Dy1 N1 2_556 . 89.00(12)
O1 Dy1 N1 2_556 . 79.92(11)
O5 Dy1 N2 . . 76.00(11)
O4 Dy1 N2 2_666 . 140.54(11)
O3 Dy1 N2 . . 132.63(10)
O2 Dy1 N2 2_556 . 79.40(11)
O1 Dy1 N2 2_556 . 121.32(11)
N1 Dy1 N2 . . 63.93(11)
O5 Dy1 N3 . . 84.33(11)
O4 Dy1 N3 2_666 . 77.08(11)
O3 Dy1 N3 . . 149.04(11)
O2 Dy1 N3 2_556 . 74.80(11)
O1 Dy1 N3 2_556 . 122.81(11)
N1 Dy1 N3 . . 127.10(11)
N2 Dy1 N3 . . 63.70(10)
O5 Dy1 C22 . 2_556 174.98(11)
O4 Dy1 C22 2_666 2_556 87.81(11)
O3 Dy1 C22 . 2_556 101.99(11)
O2 Dy1 C22 2_556 2_556 27.09(12)
O1 Dy1 C22 2_556 2_556 27.13(11)
N1 Dy1 C22 . 2_556 84.85(11)
N2 Dy1 C22 . 2_556 101.51(11)
N3 Dy1 C22 . 2_556 98.54(12)
C5 N1 C1 . . 117.7(4)
C5 N1 Dy1 . . 121.8(3)
C1 N1 Dy1 . . 120.5(3)
C10 N2 C6 . . 117.8(3)
C10 N2 Dy1 . . 121.2(3)
C6 N2 Dy1 . . 119.1(3)
C11 N3 C15 . . 117.0(4)
C11 N3 Dy1 . . 120.4(3)
C15 N3 Dy1 . . 122.3(3)
C22 O1 Dy1 . 2_556 90.9(2)
C22 O2 Dy1 . 2_556 94.5(3)
C23 O3 Dy1 . . 134.3(3)
C23 O4 Dy1 . 2_666 133.9(3)
C30 O5 Dy1 . . 145.7(3)
N1 C1 C2 . . 123.4(4)
N1 C1 H1 . . 118.3
C2 C1 H1 . . 118.3
C1 C2 C3 . . 118.9(5)
C1 C2 H2 . . 120.5
C3 C2 H2 . . 120.5
C2 C3 C4 . . 118.3(5)
C2 C3 H3 . . 120.9
C4 C3 H3 . . 120.9
C3 C4 C5 . . 120.1(5)
C3 C4 H4 . . 120.0
C5 C4 H4 . . 120.0
N1 C5 C4 . . 121.7(4)
N1 C5 C6 . . 116.0(4)
C4 C5 C6 . . 122.4(4)
N2 C6 C7 . . 122.3(4)
N2 C6 C5 . . 116.2(4)
C7 C6 C5 . . 121.5(4)
C8 C7 C6 . . 120.2(4)
C8 C7 H7 . . 119.9
C6 C7 H7 . . 119.9
C7 C8 C9 . . 117.0(4)
C7 C8 C16 . . 122.4(4)
C9 C8 C16 . . 120.6(4)
C10 C9 C8 . . 120.5(4)
C10 C9 H9 . . 119.7
C8 C9 H9 . . 119.7
N2 C10 C9 . . 122.0(4)
N2 C10 C11 . . 116.0(3)
C9 C10 C11 . . 121.9(4)
N3 C11 C12 . . 122.8(4)
N3 C11 C10 . . 116.8(4)
C12 C11 C10 . . 120.5(4)
C11 C12 C13 . . 119.3(4)
C11 C12 H12 . . 120.3
C13 C12 H12 . . 120.3
C14 C13 C12 . . 118.5(5)
C14 C13 H13 . . 120.8
C12 C13 H13 . . 120.8
C13 C14 C15 . . 118.5(4)
C13 C14 H14 . . 120.8
C15 C14 H14 . . 120.8
N3 C15 C14 . . 124.0(4)
N3 C15 H15 . . 118.0
C14 C15 H15 . . 118.0
C17 C16 C21 . . 119.4(4)
C17 C16 C8 . . 119.2(4)
C21 C16 C8 . . 121.4(4)
C16 C17 C18 . . 120.8(4)
C16 C17 H17 . . 119.6
C18 C17 H17 . . 119.6
C19 C18 C17 . . 119.7(4)
C19 C18 H18 . . 120.2
C17 C18 H18 . . 120.2
C18 C19 C20 . . 120.3(4)
C18 C19 H19 . . 119.8
C20 C19 H19 . . 119.8
C21 C20 C19 . . 120.1(4)
C21 C20 H20 . . 120.0
C19 C20 H20 . . 120.0
C20 C21 C16 . . 119.7(4)
C20 C21 C22 . . 119.0(4)
C16 C21 C22 . . 121.1(4)
O1 C22 O2 . . 120.3(4)
O1 C22 C21 . . 120.0(4)
O2 C22 C21 . . 119.7(4)
O1 C22 Dy1 . 2_556 62.0(2)
O2 C22 Dy1 . 2_556 58.4(2)
C21 C22 Dy1 . 2_556 174.4(3)
O3 C23 O4 . . 124.1(4)
O3 C23 C24 . . 119.0(3)
O4 C23 C24 . . 116.7(4)
C25 C24 C29 . . 118.9(4)
C25 C24 C23 . . 117.1(4)
C29 C24 C23 . . 124.0(4)
C26 C25 C24 . . 120.9(5)
C26 C25 H25 . . 119.6
C24 C25 H25 . . 119.6
C27 C26 C25 . . 121.0(5)
C27 C26 H26 . . 119.5
C25 C26 H26 . . 119.5
C26 C27 C28 . . 118.9(5)
C26 C27 H27 . . 120.5
C28 C27 H27 . . 120.5
C27 C28 C29 . . 121.6(5)
C27 C28 H28 . . 119.2
C29 C28 H28 . . 119.2
C28 C29 C24 . . 118.6(4)
C28 C29 C30 . . 118.4(4)
C24 C29 C30 . . 122.9(4)
O6 C30 O5 . . 123.5(5)
O6 C30 C29 . . 118.9(4)
O5 C30 C29 . . 117.6(4)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Dy1 O5 . 2.240(3)
Dy1 O4 2_666 2.299(3)
Dy1 O3 . 2.327(3)
Dy1 O2 2_556 2.372(3)
Dy1 O1 2_556 2.450(3)
Dy1 N1 . 2.520(4)
Dy1 N2 . 2.546(3)
Dy1 N3 . 2.583(3)
Dy1 C22 2_556 2.776(4)
N1 C5 . 1.336(5)
N1 C1 . 1.351(6)
N2 C10 . 1.348(5)
N2 C6 . 1.349(5)
N3 C11 . 1.337(5)
N3 C15 . 1.344(5)
O1 C22 . 1.266(5)
O1 Dy1 2_556 2.450(3)
O2 C22 . 1.268(5)
O2 Dy1 2_556 2.372(3)
O3 C23 . 1.245(5)
O4 C23 . 1.272(5)
O4 Dy1 2_666 2.299(3)
O5 C30 . 1.279(5)
O6 C30 . 1.230(6)
C1 C2 . 1.370(7)
C1 H1 . 0.9300
C2 C3 . 1.375(7)
C2 H2 . 0.9300
C3 C4 . 1.381(7)
C3 H3 . 0.9300
C4 C5 . 1.384(6)
C4 H4 . 0.9300
C5 C6 . 1.485(6)
C6 C7 . 1.383(6)
C7 C8 . 1.380(6)
C7 H7 . 0.9300
C8 C9 . 1.391(6)
C8 C16 . 1.490(6)
C9 C10 . 1.378(6)
C9 H9 . 0.9300
C10 C11 . 1.496(5)
C11 C12 . 1.379(6)
C12 C13 . 1.390(7)
C12 H12 . 0.9300
C13 C14 . 1.374(7)
C13 H13 . 0.9300
C14 C15 . 1.376(7)
C14 H14 . 0.9300
C15 H15 . 0.9300
C16 C17 . 1.382(6)
C16 C21 . 1.407(6)
C17 C18 . 1.389(6)
C17 H17 . 0.9300
C18 C19 . 1.384(7)
C18 H18 . 0.9300
C19 C20 . 1.391(6)
C19 H19 . 0.9300
C20 C21 . 1.387(6)
C20 H20 . 0.9300
C21 C22 . 1.486(6)
C22 Dy1 2_556 2.776(4)
C23 C24 . 1.496(5)
C24 C25 . 1.383(6)
C24 C29 . 1.396(6)
C25 C26 . 1.375(7)
C25 H25 . 0.9300
C26 C27 . 1.358(8)
C26 H26 . 0.9300
C27 C28 . 1.377(8)
C27 H27 . 0.9300
C28 C29 . 1.393(6)
C28 H28 . 0.9300
C29 C30 . 1.505(6)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
O5 Dy1 N1 C5 . . 67.8(3)
O4 Dy1 N1 C5 2_666 . 174.9(3)
O3 Dy1 N1 C5 . . 144.6(3)
O2 Dy1 N1 C5 2_556 . -85.2(3)
O1 Dy1 N1 C5 2_556 . -138.9(3)
N2 Dy1 N1 C5 . . -6.5(3)
N3 Dy1 N1 C5 . . -15.2(4)
C22 Dy1 N1 C5 2_556 . -112.0(3)
O5 Dy1 N1 C1 . . -111.9(3)
O4 Dy1 N1 C1 2_666 . -4.8(5)
O3 Dy1 N1 C1 . . -35.1(3)
O2 Dy1 N1 C1 2_556 . 95.1(3)
O1 Dy1 N1 C1 2_556 . 41.4(3)
N2 Dy1 N1 C1 . . 173.8(4)
N3 Dy1 N1 C1 . . 165.1(3)
C22 Dy1 N1 C1 2_556 . 68.3(3)
O5 Dy1 N2 C10 . . 80.8(3)
O4 Dy1 N2 C10 2_666 . -2.9(4)
O3 Dy1 N2 C10 . . 138.0(3)
O2 Dy1 N2 C10 2_556 . -87.9(3)
O1 Dy1 N2 C10 2_556 . -123.7(3)
N1 Dy1 N2 C10 . . 178.0(3)
N3 Dy1 N2 C10 . . -9.7(3)
C22 Dy1 N2 C10 2_556 . -103.6(3)
O5 Dy1 N2 C6 . . -82.8(3)
O4 Dy1 N2 C6 2_666 . -166.5(3)
O3 Dy1 N2 C6 . . -25.7(3)
O2 Dy1 N2 C6 2_556 . 108.5(3)
O1 Dy1 N2 C6 2_556 . 72.7(3)
N1 Dy1 N2 C6 . . 14.4(3)
N3 Dy1 N2 C6 . . -173.3(3)
C22 Dy1 N2 C6 2_556 . 92.7(3)
O5 Dy1 N3 C11 . . -75.6(3)
O4 Dy1 N3 C11 2_666 . -174.1(3)
O3 Dy1 N3 C11 . . -128.6(3)
O2 Dy1 N3 C11 2_556 . 87.0(3)
O1 Dy1 N3 C11 2_556 . 113.3(3)
N1 Dy1 N3 C11 . . 10.2(4)
N2 Dy1 N3 C11 . . 1.5(3)
C22 Dy1 N3 C11 2_556 . 100.2(3)
O5 Dy1 N3 C15 . . 110.4(3)
O4 Dy1 N3 C15 2_666 . 12.0(3)
O3 Dy1 N3 C15 . . 57.4(4)
O2 Dy1 N3 C15 2_556 . -86.9(3)
O1 Dy1 N3 C15 2_556 . -60.7(4)
N1 Dy1 N3 C15 . . -163.8(3)
N2 Dy1 N3 C15 . . -172.5(4)
C22 Dy1 N3 C15 2_556 . -73.8(3)
O5 Dy1 O3 C23 . . 10.9(4)
O4 Dy1 O3 C23 2_666 . 110.2(4)
O2 Dy1 O3 C23 2_556 . -160.8(3)
O1 Dy1 O3 C23 2_556 . -164.7(4)
N1 Dy1 O3 C23 . . -82.1(4)
N2 Dy1 O3 C23 . . -45.9(4)
N3 Dy1 O3 C23 . . 65.5(4)
C22 Dy1 O3 C23 2_556 . -164.1(4)
O4 Dy1 O5 C30 2_666 . -131.6(5)
O3 Dy1 O5 C30 . . -52.7(5)
O2 Dy1 O5 C30 2_556 . 113.0(5)
O1 Dy1 O5 C30 2_556 . -43.7(6)
N1 Dy1 O5 C30 . . 24.9(5)
N2 Dy1 O5 C30 . . 88.0(5)
N3 Dy1 O5 C30 . . 152.2(5)
C22 Dy1 O5 C30 2_556 . 27.2(16)
C5 N1 C1 C2 . . 0.6(7)
Dy1 N1 C1 C2 . . -179.7(4)
N1 C1 C2 C3 . . 1.2(8)
C1 C2 C3 C4 . . -1.9(8)
C2 C3 C4 C5 . . 0.7(9)
C1 N1 C5 C4 . . -1.8(7)
Dy1 N1 C5 C4 . . 178.5(4)
C1 N1 C5 C6 . . 178.7(4)
Dy1 N1 C5 C6 . . -1.0(5)
C3 C4 C5 N1 . . 1.1(8)
C3 C4 C5 C6 . . -179.4(5)
C10 N2 C6 C7 . . -3.6(6)
Dy1 N2 C6 C7 . . 160.6(3)
C10 N2 C6 C5 . . 175.1(4)
Dy1 N2 C6 C5 . . -20.7(5)
N1 C5 C6 N2 . . 14.3(6)
C4 C5 C6 N2 . . -165.2(4)
N1 C5 C6 C7 . . -167.0(4)
C4 C5 C6 C7 . . 13.6(7)
N2 C6 C7 C8 . . 5.8(7)
C5 C6 C7 C8 . . -172.9(4)
C6 C7 C8 C9 . . -4.2(6)
C6 C7 C8 C16 . . 176.4(4)
C7 C8 C9 C10 . . 0.9(6)
C16 C8 C9 C10 . . -179.7(4)
C6 N2 C10 C9 . . 0.1(6)
Dy1 N2 C10 C9 . . -163.7(3)
C6 N2 C10 C11 . . -179.9(4)
Dy1 N2 C10 C11 . . 16.3(5)
C8 C9 C10 N2 . . 1.2(6)
C8 C9 C10 C11 . . -178.8(4)
C15 N3 C11 C12 . . -0.8(6)
Dy1 N3 C11 C12 . . -175.1(3)
C15 N3 C11 C10 . . 179.9(4)
Dy1 N3 C11 C10 . . 5.6(5)
N2 C10 C11 N3 . . -14.2(5)
C9 C10 C11 N3 . . 165.8(4)
N2 C10 C11 C12 . . 166.5(4)
C9 C10 C11 C12 . . -13.5(7)
N3 C11 C12 C13 . . 0.2(7)
C10 C11 C12 C13 . . 179.5(4)
C11 C12 C13 C14 . . -0.1(8)
C12 C13 C14 C15 . . 0.6(8)
C11 N3 C15 C14 . . 1.3(7)
Dy1 N3 C15 C14 . . 175.5(4)
C13 C14 C15 N3 . . -1.3(7)
C7 C8 C16 C17 . . 80.3(6)
C9 C8 C16 C17 . . -99.0(5)
C7 C8 C16 C21 . . -101.8(5)
C9 C8 C16 C21 . . 78.9(5)
C21 C16 C17 C18 . . -1.8(7)
C8 C16 C17 C18 . . 176.1(4)
C16 C17 C18 C19 . . -0.6(7)
C17 C18 C19 C20 . . 2.2(7)
C18 C19 C20 C21 . . -1.3(7)
C19 C20 C21 C16 . . -1.1(6)
C19 C20 C21 C22 . . 173.9(4)
C17 C16 C21 C20 . . 2.6(6)
C8 C16 C21 C20 . . -175.3(4)
C17 C16 C21 C22 . . -172.3(4)
C8 C16 C21 C22 . . 9.8(6)
Dy1 O1 C22 O2 2_556 . 4.1(4)
Dy1 O1 C22 C21 2_556 . -174.0(3)
Dy1 O2 C22 O1 2_556 . -4.3(4)
Dy1 O2 C22 C21 2_556 . 173.8(3)
C20 C21 C22 O1 . . 31.8(6)
C16 C21 C22 O1 . . -153.3(4)
C20 C21 C22 O2 . . -146.3(4)
C16 C21 C22 O2 . . 28.6(6)
C20 C21 C22 Dy1 . 2_556 -78(3)
C16 C21 C22 Dy1 . 2_556 97(3)
Dy1 O3 C23 O4 . . -131.7(3)
Dy1 O3 C23 C24 . . 52.9(5)
Dy1 O4 C23 O3 2_666 . 29.3(6)
Dy1 O4 C23 C24 2_666 . -155.1(3)
O3 C23 C24 C25 . . 106.4(4)
O4 C23 C24 C25 . . -69.3(5)
O3 C23 C24 C29 . . -70.8(5)
O4 C23 C24 C29 . . 113.4(5)
C29 C24 C25 C26 . . 3.3(7)
C23 C24 C25 C26 . . -174.1(4)
C24 C25 C26 C27 . . -1.1(8)
C25 C26 C27 C28 . . -2.5(9)
C26 C27 C28 C29 . . 4.0(8)
C27 C28 C29 C24 . . -1.8(8)
C27 C28 C29 C30 . . 180.0(5)
C25 C24 C29 C28 . . -1.8(6)
C23 C24 C29 C28 . . 175.4(4)
C25 C24 C29 C30 . . 176.4(4)
C23 C24 C29 C30 . . -6.5(6)
Dy1 O5 C30 O6 . . -168.6(4)
Dy1 O5 C30 C29 . . 9.6(8)
C28 C29 C30 O6 . . 46.6(6)
C24 C29 C30 O6 . . -131.6(5)
C28 C29 C30 O5 . . -131.7(5)
C24 C29 C30 O5 . . 50.2(6)
