#------------------------------------------------------------------------------
#$Date: 2019-06-03 22:34:33 +0300 (Mon, 03 Jun 2019) $
#$Revision: 215662 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/02/15/2021564.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2021564
loop_
_publ_author_name
'Chen, Hui-Ru'
_publ_section_title
;
 A fourfold interpenetrating diamond-like three-dimensional zinc(II)
 coordination polymer: synthesis, crystal structure and physical
 properties
;
_journal_coeditor_code           YO3061
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first              504
_journal_page_last               507
_journal_paper_doi               10.1107/S2053229619004303
_journal_volume                  75
_journal_year                    2019
_chemical_formula_iupac          '[Zn (C6 H2 O5) (C20 H18 N4 O)], 1.76H2 O'
_chemical_formula_moiety         'C26 H20 N4 O6 Zn, 1.76(H2 O)'
_chemical_formula_sum            'C26 H23.52 N4 O7.76 Zn'
_chemical_formula_weight         581.56
_chemical_name_systematic
;Poly[[{μ₂-bis[4-(2-methyl-1H-imidazol-1-yl)phenyl]
ether-κ²N³:N^3'^}(μ₂-furan-2,5-dicarboxylato-κ²O²:O⁵)zinc(II)] 1.76-hydrate]
;
_space_group_crystal_system      monoclinic
_space_group_IT_number           14
_space_group_name_Hall           '-P 2ybc'
_space_group_name_H-M_alt        'P 1 21/c 1'
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method           SHELXL-2014
_cell_angle_alpha                90
_cell_angle_beta                 92.13(3)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   11.622(5)
_cell_length_b                   12.346(6)
_cell_length_c                   18.669(9)
_cell_measurement_reflns_used    9602
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.43
_cell_measurement_theta_min      2.85
_cell_volume                     2677(2)
_computing_cell_refinement
;
SAINT (Bruker, 2016)
;
_computing_data_collection
;
APEX3 (Bruker, 2016)
;
_computing_data_reduction
;
SAINT (Bruker, 2016)
;
_computing_molecular_graphics
;
DIAMOND (Brandenburg & Putz, 2005)
;
_computing_publication_material
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_refinement
;
SHELXL2014 (Sheldrick, 2015)
;
_computing_structure_solution
;
SHELXS97 (Sheldrick, 2008)
;
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEXII CCD'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0296
_diffrn_reflns_av_unetI/netI     0.0128
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            75815
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.998
_diffrn_reflns_theta_min         2.750
_exptl_absorpt_coefficient_mu    0.972
_exptl_absorpt_correction_T_max  0.831
_exptl_absorpt_correction_T_min  0.815
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(SADABS; Bruker, 2008)
;
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.443
_exptl_crystal_description       block
_exptl_crystal_F_000             1198
_exptl_crystal_size_max          0.210
_exptl_crystal_size_mid          0.200
_exptl_crystal_size_min          0.190
_refine_diff_density_max         0.488
_refine_diff_density_min         -0.358
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     354
_refine_ls_number_reflns         5259
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.053
_refine_ls_R_factor_all          0.0337
_refine_ls_R_factor_gt           0.0285
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0432P)²+1.3019P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0768
_refine_ls_wR_factor_ref         0.0790
_reflns_number_gt                4694
_reflns_number_total             5259
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            yo3061sup1.cif
_cod_data_source_block           I
_cod_depositor_comments          'Adding full bibliography for 2021564.cif.'
_cod_database_code               2021564
_cod_database_fobs_code          2021564
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.822
_shelx_estimated_absorpt_t_max   0.837
_shelxl_version_number           2.014
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
C C1 0.5367(2) 0.43499(18) 0.18771(16) 0.0573(6) Uani d 1
H H1A 0.5066 0.4148 0.2330 0.086 Uiso calc 1
H H1B 0.6126 0.4056 0.1839 0.086 Uiso calc 1
H H1C 0.4874 0.4071 0.1496 0.086 Uiso calc 1
C C2 0.54176(15) 0.55437(16) 0.18253(10) 0.0327(4) Uani d 1
C C3 0.50141(17) 0.72303(15) 0.15807(11) 0.0385(4) Uani d 1
H H3 0.4623 0.7843 0.1414 0.046 Uiso calc 1
C C4 0.60567(18) 0.72289(16) 0.19173(12) 0.0429(5) Uani d 1
H H4 0.6518 0.7828 0.2021 0.051 Uiso calc 1
C C5 0.73578(15) 0.57888(15) 0.24232(10) 0.0336(4) Uani d 1
C C6 0.73480(16) 0.52289(17) 0.30642(11) 0.0401(4) Uani d 1
H H6 0.6653 0.5089 0.3278 0.048 Uiso calc 1
C C7 0.83724(17) 0.48756(17) 0.33894(10) 0.0401(4) Uani d 1
H H7 0.8370 0.4498 0.3820 0.048 Uiso calc 1
C C8 0.93949(16) 0.50927(16) 0.30648(10) 0.0362(4) Uani d 1
C C9 0.94087(16) 0.56777(16) 0.24316(10) 0.0360(4) Uani d 1
H H9 1.0104 0.5838 0.2225 0.043 Uiso calc 1
C C10 0.83870(16) 0.60197(15) 0.21097(10) 0.0348(4) Uani d 1
H H10 0.8390 0.6406 0.1682 0.042 Uiso calc 1
C C11 1.06815(17) 0.41327(17) 0.39102(12) 0.0422(5) Uani d 1
C C12 1.01238(17) 0.31617(17) 0.39990(11) 0.0435(5) Uani d 1
H H12 0.9527 0.2953 0.3683 0.052 Uiso calc 1
C C13 1.04657(17) 0.24982(16) 0.45686(11) 0.0406(4) Uani d 1
H H13 1.0087 0.1846 0.4642 0.049 Uiso calc 1
C C14 1.13636(16) 0.28044(15) 0.50243(10) 0.0351(4) Uani d 1
C C15 1.19299(19) 0.37706(19) 0.49313(13) 0.0505(6) Uani d 1
H H15 1.2540 0.3969 0.5240 0.061 Uiso calc 1
C C16 1.1576(2) 0.4444(2) 0.43701(14) 0.0562(6) Uani d 1
H H16 1.1942 0.5104 0.4304 0.067 Uiso calc 1
C C17 1.3120(2) 0.1004(2) 0.49227(12) 0.0553(6) Uani d 1
H H17A 1.3663 0.0438 0.5036 0.083 Uiso calc 1
H H17B 1.3525 0.1641 0.4777 0.083 Uiso calc 1
H H17C 1.2604 0.0772 0.4540 0.083 Uiso calc 1
C C18 1.24530(16) 0.12550(15) 0.55636(10) 0.0325(4) Uani d 1
C C19 1.18000(18) 0.12671(16) 0.66359(10) 0.0383(4) Uani d 1
H H19 1.1676 0.1077 0.7109 0.046 Uiso calc 1
C C20 1.13161(19) 0.21130(17) 0.62874(11) 0.0438(5) Uani d 1
H H20 1.0805 0.2611 0.6472 0.053 Uiso calc 1
C C21 0.25083(15) 0.63055(16) 0.26829(9) 0.0325(4) Uani d 1
C C22 0.21898(15) 0.70943(15) 0.32380(9) 0.0301(4) Uani d 1
C C23 0.15612(19) 0.80050(17) 0.32017(10) 0.0421(5) Uani d 1
H H23 0.1187 0.8291 0.2795 0.051 Uiso calc 1
C C24 0.1578(2) 0.84465(17) 0.39009(10) 0.0433(5) Uani d 1
H H24 0.1217 0.9078 0.4045 0.052 Uiso calc 1
C C25 0.22218(16) 0.77716(15) 0.43180(9) 0.0314(4) Uani d 1
C C26 0.25729(16) 0.78125(16) 0.50914(10) 0.0362(4) Uani d 1
N N1 0.46154(12) 0.61806(12) 0.15208(8) 0.0309(3) Uani d 1
N N2 0.63084(13) 0.61590(13) 0.20782(9) 0.0346(3) Uani d 1
N N3 1.17226(13) 0.20987(12) 0.56069(8) 0.0344(3) Uani d 1
N N4 1.25081(13) 0.07256(12) 0.61824(8) 0.0305(3) Uani d 1
O O1 1.04794(12) 0.48206(15) 0.33317(9) 0.0612(5) Uani d 1
O O2 0.21115(11) 0.65552(11) 0.20532(6) 0.0371(3) Uani d 1
O O3 0.31001(13) 0.55100(13) 0.28280(7) 0.0475(4) Uani d 1
O O4 0.26064(11) 0.69279(10) 0.39230(6) 0.0327(3) Uani d 1
O O5 0.22551(12) 0.86727(11) 0.53981(7) 0.0407(3) Uani d 1
O O6 0.30911(17) 0.70551(15) 0.53787(8) 0.0664(5) Uani d 1
O O7 0.47612(19) 0.48887(19) 0.38610(12) 0.0777(6) Uani d 0.91
H H7B 0.4251 0.5106 0.3556 0.116 Uiso d 0.91
H H7A 0.4892 0.5392 0.4164 0.116 Uiso d 0.91
O O8 0.5279(2) 0.6499(2) 0.48896(14) 0.0891(8) Uani d 0.85
H H8B 0.4615 0.6764 0.4952 0.134 Uiso d 0.85
H H8A 0.5423 0.6046 0.5224 0.134 Uiso d 0.85
Zn Zn1 0.29611(2) 0.58356(2) 0.13066(2) 0.02567(8) Uani d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
C2 C1 H1A . . 109.5
C2 C1 H1B . . 109.5
H1A C1 H1B . . 109.5
C2 C1 H1C . . 109.5
H1A C1 H1C . . 109.5
H1B C1 H1C . . 109.5
N1 C2 N2 . . 109.37(17)
N1 C2 C1 . . 126.00(18)
N2 C2 C1 . . 124.62(17)
C4 C3 N1 . . 109.32(17)
C4 C3 H3 . . 125.3
N1 C3 H3 . . 125.3
C3 C4 N2 . . 106.41(17)
C3 C4 H4 . . 126.8
N2 C4 H4 . . 126.8
C10 C5 C6 . . 120.35(17)
C10 C5 N2 . . 118.68(17)
C6 C5 N2 . . 120.96(17)
C5 C6 C7 . . 120.11(18)
C5 C6 H6 . . 119.9
C7 C6 H6 . . 119.9
C8 C7 C6 . . 119.08(18)
C8 C7 H7 . . 120.5
C6 C7 H7 . . 120.5
O1 C8 C7 . . 125.75(17)
O1 C8 C9 . . 113.30(17)
C7 C8 C9 . . 120.87(17)
C10 C9 C8 . . 119.66(18)
C10 C9 H9 . . 120.2
C8 C9 H9 . . 120.2
C9 C10 C5 . . 119.89(17)
C9 C10 H10 . . 120.1
C5 C10 H10 . . 120.1
C12 C11 C16 . . 121.04(18)
C12 C11 O1 . . 124.09(19)
C16 C11 O1 . . 114.61(18)
C11 C12 C13 . . 118.92(19)
C11 C12 H12 . . 120.5
C13 C12 H12 . . 120.5
C14 C13 C12 . . 120.05(19)
C14 C13 H13 . . 120.0
C12 C13 H13 . . 120.0
C13 C14 C15 . . 121.05(18)
C13 C14 N3 . . 119.47(17)
C15 C14 N3 . . 119.47(17)
C14 C15 C16 . . 119.0(2)
C14 C15 H15 . . 120.5
C16 C15 H15 . . 120.5
C11 C16 C15 . . 119.9(2)
C11 C16 H16 . . 120.0
C15 C16 H16 . . 120.0
C18 C17 H17A . . 109.5
C18 C17 H17B . . 109.5
H17A C17 H17B . . 109.5
C18 C17 H17C . . 109.5
H17A C17 H17C . . 109.5
H17B C17 H17C . . 109.5
N4 C18 N3 . . 109.79(16)
N4 C18 C17 . . 126.17(17)
N3 C18 C17 . . 123.99(17)
C20 C19 N4 . . 109.21(17)
C20 C19 H19 . . 125.4
N4 C19 H19 . . 125.4
C19 C20 N3 . . 106.63(17)
C19 C20 H20 . . 126.7
N3 C20 H20 . . 126.7
O3 C21 O2 . . 125.10(17)
O3 C21 C22 . . 121.77(16)
O2 C21 C22 . . 113.12(17)
C23 C22 O4 . . 110.29(15)
C23 C22 C21 . . 131.80(17)
O4 C22 C21 . . 117.88(16)
C22 C23 C24 . . 106.72(17)
C22 C23 H23 . . 126.6
C24 C23 H23 . . 126.6
C25 C24 C23 . . 106.46(18)
C25 C24 H24 . . 126.8
C23 C24 H24 . . 126.8
C24 C25 O4 . . 110.27(16)
C24 C25 C26 . . 131.80(17)
O4 C25 C26 . . 117.92(16)
O6 C26 O5 . . 126.03(18)
O6 C26 C25 . . 120.80(18)
O5 C26 C25 . . 113.14(17)
C2 N1 C3 . . 107.01(15)
C2 N1 Zn1 . . 127.89(13)
C3 N1 Zn1 . . 122.35(12)
C2 N2 C4 . . 107.88(15)
C2 N2 C5 . . 127.19(16)
C4 N2 C5 . . 124.88(16)
C18 N3 C20 . . 107.74(15)
C18 N3 C14 . . 125.90(16)
C20 N3 C14 . . 126.18(16)
C18 N4 C19 . . 106.61(15)
C18 N4 Zn1 . 4_666 125.24(13)
C19 N4 Zn1 . 4_666 123.73(12)
C8 O1 C11 . . 123.80(16)
C21 O2 Zn1 . . 111.75(12)
C25 O4 C22 . . 106.26(14)
C26 O5 Zn1 . 4_576 122.17(12)
H7B O7 H7A . . 108.5
H8B O8 H8A . . 107.9
O2 Zn1 O5 . 4_575 105.75(7)
O2 Zn1 N1 . . 105.60(6)
O5 Zn1 N1 4_575 . 118.58(6)
O2 Zn1 N4 . 4_465 112.45(6)
O5 Zn1 N4 4_575 4_465 95.63(6)
N1 Zn1 N4 . 4_465 118.32(6)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 C2 . 1.478(3) ?
C1 H1A . 0.9600 ?
C1 H1B . 0.9600 ?
C1 H1C . 0.9600 ?
C2 N1 . 1.331(2) ?
C2 N2 . 1.355(2) ?
C3 C4 . 1.344(3) ?
C3 N1 . 1.379(3) ?
C3 H3 . 0.9300 ?
C4 N2 . 1.383(3) ?
C4 H4 . 0.9300 ?
C5 C10 . 1.381(3) ?
C5 C6 . 1.382(3) ?
C5 N2 . 1.433(2) ?
C6 C7 . 1.386(3) ?
C6 H6 . 0.9300 ?
C7 C8 . 1.380(3) ?
C7 H7 . 0.9300 ?
C8 O1 . 1.380(2) ?
C8 C9 . 1.386(3) ?
C9 C10 . 1.377(3) ?
C9 H9 . 0.9300 ?
C10 H10 . 0.9300 ?
C11 C12 . 1.376(3) ?
C11 C16 . 1.378(3) ?
C11 O1 . 1.387(2) ?
C12 C13 . 1.389(3) ?
C12 H12 . 0.9300 ?
C13 C14 . 1.375(3) ?
C13 H13 . 0.9300 ?
C14 C15 . 1.376(3) ?
C14 N3 . 1.443(2) ?
C15 C16 . 1.388(3) ?
C15 H15 . 0.9300 ?
C16 H16 . 0.9300 ?
C17 C18 . 1.482(3) ?
C17 H17A . 0.9600 ?
C17 H17B . 0.9600 ?
C17 H17C . 0.9600 ?
C18 N4 . 1.327(2) ?
C18 N3 . 1.348(2) ?
C19 C20 . 1.343(3) ?
C19 N4 . 1.376(2) ?
C19 H19 . 0.9300 ?
C20 N3 . 1.372(3) ?
C20 H20 . 0.9300 ?
C21 O3 . 1.224(2) ?
C21 O2 . 1.284(2) ?
C21 C22 . 1.479(2) ?
C22 C23 . 1.341(3) ?
C22 O4 . 1.366(2) ?
C23 C24 . 1.414(3) ?
C23 H23 . 0.9300 ?
C24 C25 . 1.348(3) ?
C24 H24 . 0.9300 ?
C25 O4 . 1.361(2) ?
C25 C26 . 1.487(2) ?
C26 O6 . 1.225(3) ?
C26 O5 . 1.268(2) ?
Zn1 N1 . 1.9951(17) y
N4 Zn1 4_666 2.0092(17) y
Zn1 O2 . 1.9516(14) y
O5 Zn1 4_576 1.9532(15) y
O7 H7B . 0.8500 ?
O7 H7A . 0.8499 ?
O8 H8B . 0.8500 ?
O8 H8A . 0.8501 ?
Zn1 O5 4_575 1.9532(15) y
Zn1 N4 4_465 2.0093(17) y
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O8 H8A O7 3_666 0.85 2.08 2.896(4) 161.0
O8 H8B O6 . 0.85 2.00 2.818(3) 160.9
O7 H7A O8 . 0.85 1.96 2.813(4) 176.2
O7 H7B O3 . 0.85 1.94 2.785(3) 176.2
C16 H16 O4 1_655 0.93 2.49 3.407(3) 167.9
C15 H15 O8 3_766 0.93 2.62 3.266(4) 127.1
C9 H9 O2 1_655 0.93 2.53 3.421(3) 161.5
C6 H6 O7 . 0.93 2.50 3.429(3) 175.0
C3 H3 O6 4_575 0.93 2.58 3.230(3) 127.2
O8 H8B O6 . 0.85 2.00 2.818(3) 160.9
O7 H7A O8 . 0.85 1.96 2.813(4) 176.2
O7 H7B O3 . 0.85 1.94 2.785(3) 176.2
C6 H6 O7 . 0.93 2.50 3.429(3) 175.0
C3 H3 O6 4_575 0.93 2.58 3.230(3) 127.2
C9 H9 O2 1_655 0.93 2.53 3.421(3) 161.5
C16 H16 O4 1_655 0.93 2.49 3.407(3) 167.9
C15 H15 O8 3_766 0.93 2.62 3.266(4) 127.1
O8 H8A O7 3_666 0.85 2.08 2.896(4) 161.0
C3 H3 O6 4_575 0.93 2.58 3.230(3) 127.2
C6 H6 O7 . 0.93 2.50 3.429(3) 175.0
C9 H9 O2 1_655 0.93 2.53 3.421(3) 161.5
C15 H15 O8 3_766 0.93 2.62 3.266(4) 127.1
C16 H16 O4 1_655 0.93 2.49 3.407(3) 167.9
O7 H7B O3 . 0.85 1.94 2.785(3) 176.2
O7 H7A O8 . 0.85 1.96 2.813(4) 176.2
O8 H8B O6 . 0.85 2.00 2.818(3) 160.9
O8 H8A O7 3_666 0.85 2.08 2.896(4) 161.0
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_4
_geom_torsion
N1 C3 C4 N2 . -0.7(2)
C10 C5 C6 C7 . -1.3(3)
N2 C5 C6 C7 . 179.90(19)
C5 C6 C7 C8 . 0.1(3)
C6 C7 C8 O1 . 178.1(2)
C6 C7 C8 C9 . 1.5(3)
O1 C8 C9 C10 . -178.96(19)
C7 C8 C9 C10 . -2.0(3)
C8 C9 C10 C5 . 0.7(3)
C6 C5 C10 C9 . 0.9(3)
N2 C5 C10 C9 . 179.71(18)
C16 C11 C12 C13 . 0.8(3)
O1 C11 C12 C13 . 174.7(2)
C11 C12 C13 C14 . -1.3(3)
C12 C13 C14 C15 . 0.7(3)
C12 C13 C14 N3 . -178.96(18)
C13 C14 C15 C16 . 0.5(4)
N3 C14 C15 C16 . -179.9(2)
C12 C11 C16 C15 . 0.3(4)
O1 C11 C16 C15 . -174.1(2)
C14 C15 C16 C11 . -1.0(4)
N4 C19 C20 N3 . 0.2(2)
O3 C21 C22 C23 . -179.9(2)
O2 C21 C22 C23 . 0.7(3)
O3 C21 C22 O4 . 1.9(3)
O2 C21 C22 O4 . -177.48(15)
O4 C22 C23 C24 . 0.1(2)
C21 C22 C23 C24 . -178.14(19)
C22 C23 C24 C25 . 0.1(3)
C23 C24 C25 O4 . -0.3(2)
C23 C24 C25 C26 . 178.5(2)
C24 C25 C26 O6 . 173.9(2)
O4 C25 C26 O6 . -7.4(3)
C24 C25 C26 O5 . -4.4(3)
O4 C25 C26 O5 . 174.30(16)
N2 C2 N1 C3 . 0.2(2)
C1 C2 N1 C3 . -179.1(2)
N2 C2 N1 Zn1 . -161.01(13)
C1 C2 N1 Zn1 . 19.7(3)
C4 C3 N1 C2 . 0.3(2)
C4 C3 N1 Zn1 . 162.82(14)
N1 C2 N2 C4 . -0.7(2)
C1 C2 N2 C4 . 178.7(2)
N1 C2 N2 C5 . -178.03(17)
C1 C2 N2 C5 . 1.3(3)
C3 C4 N2 C2 . 0.8(2)
C3 C4 N2 C5 . 178.27(18)
C10 C5 N2 C2 . 119.2(2)
C6 C5 N2 C2 . -62.0(3)
C10 C5 N2 C4 . -57.7(3)
C6 C5 N2 C4 . 121.0(2)
N4 C18 N3 C20 . 1.1(2)
C17 C18 N3 C20 . -176.5(2)
N4 C18 N3 C14 . -174.28(17)
C17 C18 N3 C14 . 8.1(3)
C19 C20 N3 C18 . -0.8(2)
C19 C20 N3 C14 . 174.59(18)
C13 C14 N3 C18 . 84.1(2)
C15 C14 N3 C18 . -95.6(3)
C13 C14 N3 C20 . -90.5(3)
C15 C14 N3 C20 . 89.8(3)
N3 C18 N4 C19 . -1.0(2)
C17 C18 N4 C19 . 176.6(2)
N3 C18 N4 Zn1 4_666 155.97(13)
C17 C18 N4 Zn1 4_666 -26.4(3)
C20 C19 N4 C18 . 0.5(2)
C20 C19 N4 Zn1 4_666 -156.93(15)
C7 C8 O1 C11 . 11.0(4)
C9 C8 O1 C11 . -172.2(2)
C12 C11 O1 C8 . 45.3(3)
C16 C11 O1 C8 . -140.5(2)
O3 C21 O2 Zn1 . -19.7(2)
C22 C21 O2 Zn1 . 159.66(12)
C24 C25 O4 C22 . 0.4(2)
C26 C25 O4 C22 . -178.61(16)
C23 C22 O4 C25 . -0.3(2)
C21 C22 O4 C25 . 178.23(15)
O6 C26 O5 Zn1 4_576 20.8(3)
C25 C26 O5 Zn1 4_576 -161.01(12)
