#------------------------------------------------------------------------------
#$Date: 2020-08-29 07:51:37 +0300 (Sat, 29 Aug 2020) $
#$Revision: 255738 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/02/22/2022243.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2022243
loop_
_publ_author_name
'Songkerdthong, Jetnipat'
'Harding, Phimphaka'
'Harding, David J.'
_publ_section_title
;
 Conformational polymorphism in a cobalt(II) dithiocarbamate complex
;
_journal_coeditor_code           YP3208
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section C'
_journal_page_first
;
;
_journal_paper_doi               10.1107/S205322962001164X
_journal_volume                  76
_journal_year                    2020
_chemical_formula_iupac          '[Co (C45 H34 B N6) (C9 H18 N S2)]'
_chemical_formula_moiety         'C54 H52 B Co N7 S2'
_chemical_formula_sum            'C54 H52 B Co N7 S2'
_chemical_formula_weight         932.88
_chemical_name_systematic
(N,N-Dibutyldithiocarbamato-κ²S,S')[tris(3,5-diphenylpyrazol-1-yl-κN²)hydroborato]cobalt(II)
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_atom_sites_solution_hydrogens   mixed
_audit_creation_method
;
Olex2 1.3
(compiled 2020.02.04 svn.rd84adfe8 for OlexSys, GUI svn.r6032)
;
_cell_angle_alpha                117.4408(9)
_cell_angle_beta                 100.7910(8)
_cell_angle_gamma                94.2199(7)
_cell_formula_units_Z            2
_cell_length_a                   11.69503(10)
_cell_length_b                   15.27162(13)
_cell_length_c                   15.43643(16)
_cell_measurement_reflns_used    22677
_cell_measurement_temperature    150.01(10)
_cell_measurement_theta_max      68.4310
_cell_measurement_theta_min      3.3090
_cell_volume                     2362.76(4)
_computing_cell_refinement
;
CrysAlis PRO (Rigaku OD, 2020)
;
_computing_data_collection
;
CrysAlis PRO (Rigaku OD, 2020)
;
_computing_data_reduction
;
CrysAlis PRO (Rigaku OD, 2020)
;
_computing_molecular_graphics
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_publication_material
;
OLEX2 (Dolomanov et al.,  2009)
;
_computing_structure_refinement
;
SHELXL2018 (Sheldrick, 2015b)
;
_computing_structure_solution
;
SHELXT (Sheldrick, 2015a)
;
_diffrn_ambient_temperature      150.01(10)
_diffrn_detector                 'Hybrid Pixel Array Detector'
_diffrn_detector_area_resol_mean 10.0000
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device       'four-circle diffractometer'
_diffrn_measurement_device_type
'Rigaku SuperNova (Single source at offset/far, HyPix3000)'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  mirror
_diffrn_radiation_probe          x-ray
_diffrn_radiation_type           'Cu K\a'
_diffrn_radiation_wavelength     1.54184
_diffrn_reflns_av_R_equivalents  0.0478
_diffrn_reflns_av_unetI/netI     0.0341
_diffrn_reflns_limit_h_max       12
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       18
_diffrn_reflns_limit_k_min       -18
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            31970
_diffrn_reflns_theta_full        67.684
_diffrn_reflns_theta_max         68.492
_diffrn_reflns_theta_min         3.317
_diffrn_source                   'micro-focus sealed X-ray tube'
_exptl_absorpt_coefficient_mu    4.019
_exptl_absorpt_correction_T_max  1.00000
_exptl_absorpt_correction_T_min  0.63103
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
(CrysAlis PRO; Rigaku OD, 2020)
;
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.311
_exptl_crystal_description       block
_exptl_crystal_F_000             978
_exptl_crystal_size_max          0.258
_exptl_crystal_size_mid          0.219
_exptl_crystal_size_min          0.178
_refine_diff_density_max         0.464
_refine_diff_density_min         -0.308
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.047
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     630
_refine_ls_number_reflns         8636
_refine_ls_number_restraints     37
_refine_ls_restrained_S_all      1.049
_refine_ls_R_factor_all          0.0364
_refine_ls_R_factor_gt           0.0348
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.0504P)²+0.7689P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0918
_refine_ls_wR_factor_ref         0.0928
_reflns_number_gt                8250
_reflns_number_total             8636
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            yp3208sup1.cif
_cod_data_source_block           1b
_cod_database_code               2022243
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Co Co1 0.67469(2) 0.41937(2) 0.70877(2) 0.01895(8) Uani d 1 . .
S S1 0.63988(4) 0.58822(3) 0.76749(3) 0.02751(11) Uani d 1 . .
S S2 0.76723(4) 0.50606(3) 0.88528(3) 0.03307(11) Uani d 1 . .
N N1 0.54286(11) 0.34115(10) 0.56900(10) 0.0191(3) Uani d 1 . .
N N2 0.57705(11) 0.26241(10) 0.49498(10) 0.0191(3) Uani d 1 . .
N N3 0.80540(12) 0.39736(10) 0.62988(10) 0.0197(3) Uani d 1 . .
N N4 0.79945(11) 0.30288(10) 0.55204(10) 0.0188(3) Uani d 1 . .
N N5 0.66200(12) 0.27225(10) 0.69499(10) 0.0204(3) Uani d 1 . .
N N6 0.68462(12) 0.20111(10) 0.60836(10) 0.0195(3) Uani d 1 . .
N N7 0.75119(16) 0.70004(12) 0.96305(12) 0.0385(4) Uani d 1 . .
C C1 0.44845(14) 0.36209(12) 0.52235(12) 0.0212(3) Uani d 1 . .
C C2 0.42374(15) 0.29942(13) 0.41809(13) 0.0250(3) Uani d 1 . .
H H2 0.364047 0.299509 0.368980 0.030 Uiso calc 1 . .
C C3 0.50662(14) 0.23735(12) 0.40335(12) 0.0216(3) Uani d 1 . .
C C4 0.38095(13) 0.43744(12) 0.57805(12) 0.0214(3) Uani d 1 . .
C C5 0.35199(15) 0.44405(13) 0.66423(13) 0.0258(4) Uani d 1 . .
H H5 0.377866 0.401470 0.688451 0.031 Uiso calc 1 . .
C C6 0.28516(15) 0.51327(14) 0.71422(14) 0.0285(4) Uani d 1 . .
H H6 0.265917 0.516545 0.771307 0.034 Uiso calc 1 . .
C C7 0.24691(15) 0.57769(13) 0.67920(14) 0.0291(4) Uani d 1 . .
H H7 0.202601 0.624596 0.712958 0.035 Uiso calc 1 . .
C C8 0.27512(16) 0.57172(14) 0.59367(15) 0.0300(4) Uani d 1 . .
H H8 0.249518 0.614791 0.570024 0.036 Uiso calc 1 . .
C C9 0.34123(15) 0.50203(13) 0.54297(13) 0.0261(4) Uani d 1 . .
H H9 0.359182 0.498320 0.485306 0.031 Uiso calc 1 . .
C C10 0.52455(14) 0.15942(13) 0.30711(12) 0.0236(3) Uani d 1 . .
C C11 0.54449(16) 0.18677(14) 0.23586(13) 0.0284(4) Uani d 1 . .
H H11 0.543177 0.252242 0.248102 0.034 Uiso calc 1 . .
C C12 0.56630(17) 0.11619(16) 0.14658(14) 0.0352(4) Uani d 1 . .
H H12 0.581331 0.134994 0.099842 0.042 Uiso calc 1 . .
C C13 0.56582(17) 0.01842(15) 0.12684(14) 0.0350(4) Uani d 1 . .
H H13 0.580073 -0.028494 0.066725 0.042 Uiso calc 1 . .
C C14 0.54415(17) -0.01018(14) 0.19626(14) 0.0331(4) Uani d 1 . .
H H14 0.542693 -0.076356 0.182485 0.040 Uiso calc 1 . .
C C15 0.52464(15) 0.06054(13) 0.28652(13) 0.0279(4) Uani d 1 . .
H H15 0.511505 0.041683 0.333681 0.034 Uiso calc 1 . .
C C16 0.90739(14) 0.45271(12) 0.64211(12) 0.0217(3) Uani d 1 . .
C C17 0.96854(14) 0.39394(13) 0.57334(13) 0.0249(3) Uani d 1 . .
H H17 1.041811 0.414250 0.566639 0.030 Uiso calc 1 . .
C C18 0.89862(14) 0.29956(12) 0.51717(12) 0.0212(3) Uani d 1 . .
C C19 0.94663(14) 0.56111(13) 0.71491(13) 0.0234(3) Uani d 1 . .
C C20 1.01150(17) 0.59454(14) 0.81253(14) 0.0323(4) Uani d 1 . .
H H20 1.022399 0.549470 0.836884 0.039 Uiso calc 1 . .
C C21 1.06063(18) 0.69637(16) 0.87447(15) 0.0397(5) Uani d 1 . .
H H21 1.104713 0.718790 0.939959 0.048 Uiso calc 1 . .
C C22 1.04434(18) 0.76321(14) 0.83945(16) 0.0389(5) Uani d 1 . .
H H22 1.078448 0.830624 0.880795 0.047 Uiso calc 1 . .
C C23 0.97755(18) 0.73102(14) 0.74309(16) 0.0368(4) Uani d 1 . .
H H23 0.964889 0.776881 0.720016 0.044 Uiso calc 1 . .
C C24 0.92939(16) 0.63035(13) 0.68077(14) 0.0297(4) Uani d 1 . .
H H24 0.885108 0.608672 0.615498 0.036 Uiso calc 1 . .
C C25 0.92623(15) 0.20986(12) 0.43611(13) 0.0228(3) Uani d 1 . .
C C26 0.84642(16) 0.14686(13) 0.34368(13) 0.0269(4) Uani d 1 . .
H H26 0.770836 0.160434 0.330366 0.032 Uiso calc 1 . .
C C27 0.87903(18) 0.06390(14) 0.27129(15) 0.0341(4) Uani d 1 . .
H H27 0.824801 0.021435 0.210141 0.041 Uiso calc 1 . .
C C28 0.99230(19) 0.04410(14) 0.28988(16) 0.0360(4) Uani d 1 . .
H H28 1.013714 -0.011894 0.241471 0.043 Uiso calc 1 . .
C C29 1.07299(18) 0.10740(16) 0.38003(16) 0.0368(4) Uani d 1 . .
H H29 1.149360 0.094809 0.391971 0.044 Uiso calc 1 . .
C C30 1.04056(16) 0.18993(15) 0.45309(14) 0.0304(4) Uani d 1 . .
H H30 1.095406 0.232352 0.513886 0.037 Uiso calc 1 . .
C C31 0.65223(14) 0.22883(12) 0.75218(12) 0.0213(3) Uani d 1 . .
C C32 0.67073(14) 0.12991(12) 0.70315(13) 0.0229(3) Uani d 1 . .
H H32 0.669807 0.083958 0.726918 0.028 Uiso calc 1 . .
C C33 0.69067(13) 0.11451(12) 0.61213(12) 0.0205(3) Uani d 1 . .
C C34 0.61664(15) 0.27707(12) 0.84809(13) 0.0239(3) Uani d 1 . .
C C35 0.66535(18) 0.25881(15) 0.92593(14) 0.0335(4) Uani d 1 . .
H H35 0.723739 0.219586 0.918823 0.040 Uiso calc 1 . .
C C36 0.6277(2) 0.29863(17) 1.01456(15) 0.0429(5) Uani d 1 . .
H H36 0.661463 0.286389 1.066526 0.051 Uiso calc 1 . .
C C37 0.54081(19) 0.35591(17) 1.02570(16) 0.0437(5) Uani d 1 . .
H H37 0.515951 0.382627 1.085130 0.052 Uiso calc 1 . .
C C38 0.49040(18) 0.37374(17) 0.94817(16) 0.0411(5) Uani d 1 . .
H H38 0.430854 0.411833 0.955196 0.049 Uiso calc 1 . .
C C39 0.52843(16) 0.33496(15) 0.85999(14) 0.0325(4) Uani d 1 . .
H H39 0.494681 0.347752 0.808414 0.039 Uiso calc 1 . .
C C40 0.71008(14) 0.02183(12) 0.52925(12) 0.0215(3) Uani d 1 . .
C C41 0.80796(16) 0.02057(13) 0.48917(14) 0.0282(4) Uani d 1 . .
H H41 0.863171 0.079082 0.514959 0.034 Uiso calc 1 . .
C C42 0.82282(18) -0.06777(15) 0.41106(16) 0.0356(4) Uani d 1 . .
H H42 0.887780 -0.068127 0.384231 0.043 Uiso calc 1 . .
C C43 0.74192(19) -0.15539(14) 0.37264(15) 0.0357(4) Uani d 1 . .
H H43 0.752122 -0.214278 0.319768 0.043 Uiso calc 1 . .
C C44 0.64565(17) -0.15545(13) 0.41295(14) 0.0318(4) Uani d 1 . .
H H44 0.591688 -0.214528 0.387831 0.038 Uiso calc 1 . .
C C45 0.62990(15) -0.06706(13) 0.49095(13) 0.0249(3) Uani d 1 . .
H H45 0.565147 -0.067247 0.517876 0.030 Uiso calc 1 . .
C C46 0.72412(15) 0.60980(13) 0.88158(13) 0.0261(4) Uani d 1 . .
C C47 0.71402(18) 0.78904(13) 0.96084(14) 0.0327(4) Uani d 1 . .
H H47A 0.710383 0.837213 1.028228 0.039 Uiso calc 1 . .
H H47B 0.634720 0.769319 0.917345 0.039 Uiso calc 1 . .
C C48 0.79424(18) 0.84017(15) 0.92440(17) 0.0391(5) Uani d 1 . .
H H48A 0.875485 0.851436 0.961416 0.047 Uiso calc 1 . .
H H48B 0.788788 0.795731 0.853690 0.047 Uiso calc 1 . .
C C49 0.76408(18) 0.93956(15) 0.93704(17) 0.0379(4) Uani d 1 . .
H H49A 0.680430 0.929725 0.906709 0.046 Uiso calc 1 . .
H H49B 0.778453 0.986576 1.008390 0.046 Uiso calc 1 . .
C C50 0.8345(2) 0.98442(19) 0.8902(2) 0.0557(6) Uani d 1 . .
H H50A 0.814986 0.941276 0.818504 0.084 Uiso calc 1 . .
H H50B 0.917508 0.991398 0.917436 0.084 Uiso calc 1 . .
H H50C 0.815853 1.049183 0.904695 0.084 Uiso calc 1 . .
B B1 0.68992(16) 0.22226(13) 0.52053(14) 0.0193(4) Uani d 1 . .
H H1 0.6949(15) 0.1543(13) 0.4577(14) 0.017(4) Uiso d 1 . .
C C51 0.8044(2) 0.71341(19) 1.06424(19) 0.0301(8) Uani d 0.725(6) A 1
H H51A 0.785243 0.650913 1.064993 0.036 Uiso calc 0.725(6) A 1
H H51B 0.771582 0.764110 1.113914 0.036 Uiso calc 0.725(6) A 1
C C52 0.9373(3) 0.7450(3) 1.0912(3) 0.0438(9) Uani d 0.725(6) A 1
H H52A 0.955889 0.805879 1.087411 0.053 Uiso calc 0.725(6) A 1
H H52B 0.969852 0.693026 1.042486 0.053 Uiso calc 0.725(6) A 1
C C53 0.9952(4) 0.7634(3) 1.1968(3) 0.0491(10) Uani d 0.725(6) A 1
H H53A 1.078141 0.792458 1.213824 0.059 Uiso calc 0.725(6) A 1
H H53B 0.958532 0.812299 1.244393 0.059 Uiso calc 0.725(6) A 1
C C54 0.9868(6) 0.6717(5) 1.2094(5) 0.0789(17) Uani d 0.725(6) A 1
H H54C 1.024562 0.689890 1.277717 0.118 Uiso calc 0.725(6) A 1
H H54A 1.025437 0.623599 1.164481 0.118 Uiso calc 0.725(6) A 1
H H54B 0.905027 0.642915 1.194132 0.118 Uiso calc 0.725(6) A 1
C C51A 0.8768(6) 0.7233(6) 1.0377(6) 0.036(2) Uani d 0.275(6) A 2
H H51C 0.921826 0.670807 1.008539 0.043 Uiso calc 0.275(6) A 2
H H51D 0.922117 0.787064 1.053865 0.043 Uiso calc 0.275(6) A 2
C C52A 0.8460(9) 0.7269(9) 1.1315(8) 0.066(3) Uani d 0.275(6) A 2
H H52C 0.799634 0.662574 1.112365 0.079 Uiso calc 0.275(6) A 2
H H52D 0.797227 0.777398 1.156261 0.079 Uiso calc 0.275(6) A 2
C C53A 0.9559(11) 0.7510(10) 1.2176(9) 0.063(4) Uani d 0.275(6) A 2
H H53C 1.002095 0.816191 1.239169 0.076 Uiso calc 0.275(6) A 2
H H53D 0.931356 0.752636 1.274857 0.076 Uiso calc 0.275(6) A 2
C C54A 1.0273(11) 0.6730(10) 1.1800(12) 0.067(4) Uani d 0.275(6) A 2
H H54F 1.085175 0.677509 1.235664 0.100 Uiso calc 0.275(6) A 2
H H54D 1.066765 0.682162 1.134732 0.100 Uiso calc 0.275(6) A 2
H H54E 0.976901 0.608177 1.144949 0.100 Uiso calc 0.275(6) A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0090 0.0039 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co -2.3653 3.6143 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.3331 0.5567 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_exptl_crystal_face_index_h
_exptl_crystal_face_index_k
_exptl_crystal_face_index_l
_exptl_crystal_face_perp_dist
0 -5 3 0.1066
-5 1 2 0.1311
0 5 -3 0.1107
5 -3 -1 0.1121
0 0 1 0.0892
0 0 -1 0.0892
-5 4 0 0.1390
-5 4 -3 0.1234
1 5 -1 0.0809
0 -5 1 0.1036
-5 -4 2 0.1317
5 0 -1 0.1153
1 3 -5 0.1204
0 -4 5 0.1222
1 5 -3 0.0979
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
S2 Co1 S1 . . 74.746(16) ?
N1 Co1 S1 . . 101.13(4) ?
N1 Co1 S2 . . 161.55(4) ?
N1 Co1 N5 . . 82.10(5) ?
N3 Co1 S1 . . 109.37(4) ?
N3 Co1 S2 . . 108.76(4) ?
N3 Co1 N1 . . 89.62(5) ?
N3 Co1 N5 . . 92.96(5) ?
N5 Co1 S1 . . 157.38(4) ?
N5 Co1 S2 . . 95.05(4) ?
C46 S1 Co1 . . 84.51(6) ?
C46 S2 Co1 . . 84.88(6) ?
N2 N1 Co1 . . 113.93(9) ?
C1 N1 Co1 . . 136.42(11) ?
C1 N1 N2 . . 106.47(13) ?
N1 N2 B1 . . 120.91(12) ?
C3 N2 N1 . . 109.72(12) ?
C3 N2 B1 . . 129.02(13) ?
N4 N3 Co1 . . 117.84(10) ?
C16 N3 Co1 . . 134.87(11) ?
C16 N3 N4 . . 106.88(13) ?
N3 N4 B1 . . 118.44(12) ?
C18 N4 N3 . . 109.68(13) ?
C18 N4 B1 . . 131.87(13) ?
N6 N5 Co1 . . 114.09(10) ?
C31 N5 Co1 . . 138.64(11) ?
C31 N5 N6 . . 106.64(12) ?
N5 N6 B1 . . 120.78(12) ?
C33 N6 N5 . . 110.09(13) ?
C33 N6 B1 . . 128.94(13) ?
C46 N7 C47 . . 122.22(16) ?
C46 N7 C51 . . 121.38(17) ?
C46 N7 C51A . . 115.0(3) ?
C47 N7 C51 . . 115.75(17) ?
C47 N7 C51A . . 113.8(3) ?
N1 C1 C2 . . 110.20(14) ?
N1 C1 C4 . . 122.40(14) ?
C2 C1 C4 . . 127.33(15) ?
C1 C2 H2 . . 127.2 ?
C3 C2 C1 . . 105.55(14) ?
C3 C2 H2 . . 127.2 ?
N2 C3 C2 . . 108.02(14) ?
N2 C3 C10 . . 123.39(14) ?
C2 C3 C10 . . 128.52(15) ?
C5 C4 C1 . . 121.37(15) ?
C5 C4 C9 . . 118.67(15) ?
C9 C4 C1 . . 119.93(15) ?
C4 C5 H5 . . 119.6 ?
C6 C5 C4 . . 120.82(16) ?
C6 C5 H5 . . 119.6 ?
C5 C6 H6 . . 120.0 ?
C5 C6 C7 . . 120.06(17) ?
C7 C6 H6 . . 120.0 ?
C6 C7 H7 . . 120.2 ?
C8 C7 C6 . . 119.58(16) ?
C8 C7 H7 . . 120.2 ?
C7 C8 H8 . . 119.7 ?
C7 C8 C9 . . 120.54(17) ?
C9 C8 H8 . . 119.7 ?
C4 C9 H9 . . 119.8 ?
C8 C9 C4 . . 120.33(17) ?
C8 C9 H9 . . 119.8 ?
C11 C10 C3 . . 118.69(15) ?
C15 C10 C3 . . 122.17(16) ?
C15 C10 C11 . . 119.13(16) ?
C10 C11 H11 . . 120.0 ?
C12 C11 C10 . . 119.97(17) ?
C12 C11 H11 . . 120.0 ?
C11 C12 H12 . . 119.8 ?
C13 C12 C11 . . 120.39(18) ?
C13 C12 H12 . . 119.8 ?
C12 C13 H13 . . 119.9 ?
C12 C13 C14 . . 120.22(17) ?
C14 C13 H13 . . 119.9 ?
C13 C14 H14 . . 120.2 ?
C13 C14 C15 . . 119.62(18) ?
C15 C14 H14 . . 120.2 ?
C10 C15 H15 . . 119.7 ?
C14 C15 C10 . . 120.63(17) ?
C14 C15 H15 . . 119.7 ?
N3 C16 C17 . . 109.77(14) ?
N3 C16 C19 . . 124.93(14) ?
C17 C16 C19 . . 125.25(15) ?
C16 C17 H17 . . 126.8 ?
C18 C17 C16 . . 106.32(14) ?
C18 C17 H17 . . 126.8 ?
N4 C18 C17 . . 107.34(14) ?
N4 C18 C25 . . 125.59(15) ?
C17 C18 C25 . . 127.05(15) ?
C20 C19 C16 . . 121.62(16) ?
C20 C19 C24 . . 119.10(17) ?
C24 C19 C16 . . 118.87(16) ?
C19 C20 H20 . . 120.1 ?
C19 C20 C21 . . 119.75(19) ?
C21 C20 H20 . . 120.1 ?
C20 C21 H21 . . 119.8 ?
C22 C21 C20 . . 120.48(19) ?
C22 C21 H21 . . 119.8 ?
C21 C22 H22 . . 119.9 ?
C21 C22 C23 . . 120.20(18) ?
C23 C22 H22 . . 119.9 ?
C22 C23 H23 . . 120.1 ?
C22 C23 C24 . . 119.86(19) ?
C24 C23 H23 . . 120.1 ?
C19 C24 H24 . . 119.7 ?
C23 C24 C19 . . 120.58(18) ?
C23 C24 H24 . . 119.7 ?
C26 C25 C18 . . 123.76(15) ?
C26 C25 C30 . . 118.79(16) ?
C30 C25 C18 . . 117.41(16) ?
C25 C26 H26 . . 119.8 ?
C27 C26 C25 . . 120.35(17) ?
C27 C26 H26 . . 119.8 ?
C26 C27 H27 . . 119.9 ?
C26 C27 C28 . . 120.19(19) ?
C28 C27 H27 . . 119.9 ?
C27 C28 H28 . . 120.0 ?
C29 C28 C27 . . 119.96(17) ?
C29 C28 H28 . . 120.0 ?
C28 C29 H29 . . 119.9 ?
C28 C29 C30 . . 120.11(18) ?
C30 C29 H29 . . 119.9 ?
C25 C30 H30 . . 119.7 ?
C29 C30 C25 . . 120.56(18) ?
C29 C30 H30 . . 119.7 ?
N5 C31 C32 . . 109.88(14) ?
N5 C31 C34 . . 123.94(15) ?
C32 C31 C34 . . 125.97(15) ?
C31 C32 H32 . . 127.1 ?
C33 C32 C31 . . 105.87(14) ?
C33 C32 H32 . . 127.1 ?
N6 C33 C32 . . 107.52(14) ?
N6 C33 C40 . . 123.86(14) ?
C32 C33 C40 . . 128.57(15) ?
C35 C34 C31 . . 119.74(16) ?
C35 C34 C39 . . 118.66(17) ?
C39 C34 C31 . . 121.43(16) ?
C34 C35 H35 . . 119.7 ?
C34 C35 C36 . . 120.59(19) ?
C36 C35 H35 . . 119.7 ?
C35 C36 H36 . . 119.8 ?
C37 C36 C35 . . 120.3(2) ?
C37 C36 H36 . . 119.8 ?
C36 C37 H37 . . 120.1 ?
C36 C37 C38 . . 119.74(18) ?
C38 C37 H37 . . 120.1 ?
C37 C38 H38 . . 119.9 ?
C37 C38 C39 . . 120.2(2) ?
C39 C38 H38 . . 119.9 ?
C34 C39 H39 . . 119.7 ?
C38 C39 C34 . . 120.52(19) ?
C38 C39 H39 . . 119.7 ?
C41 C40 C33 . . 121.71(15) ?
C45 C40 C33 . . 119.27(15) ?
C45 C40 C41 . . 119.01(16) ?
C40 C41 H41 . . 120.0 ?
C42 C41 C40 . . 120.03(17) ?
C42 C41 H41 . . 120.0 ?
C41 C42 H42 . . 119.7 ?
C43 C42 C41 . . 120.54(17) ?
C43 C42 H42 . . 119.7 ?
C42 C43 H43 . . 120.0 ?
C42 C43 C44 . . 119.95(17) ?
C44 C43 H43 . . 120.0 ?
C43 C44 H44 . . 120.1 ?
C43 C44 C45 . . 119.82(18) ?
C45 C44 H44 . . 120.1 ?
C40 C45 H45 . . 119.7 ?
C44 C45 C40 . . 120.64(16) ?
C44 C45 H45 . . 119.7 ?
S1 C46 S2 . . 115.64(10) ?
N7 C46 S1 . . 122.51(14) ?
N7 C46 S2 . . 121.81(14) ?
N7 C47 H47A . . 108.6 ?
N7 C47 H47B . . 108.6 ?
N7 C47 C48 . . 114.60(16) ?
H47A C47 H47B . . 107.6 ?
C48 C47 H47A . . 108.6 ?
C48 C47 H47B . . 108.6 ?
C47 C48 H48A . . 108.9 ?
C47 C48 H48B . . 108.9 ?
H48A C48 H48B . . 107.7 ?
C49 C48 C47 . . 113.36(16) ?
C49 C48 H48A . . 108.9 ?
C49 C48 H48B . . 108.9 ?
C48 C49 H49A . . 108.9 ?
C48 C49 H49B . . 108.9 ?
H49A C49 H49B . . 107.7 ?
C50 C49 C48 . . 113.24(18) ?
C50 C49 H49A . . 108.9 ?
C50 C49 H49B . . 108.9 ?
C49 C50 H50A . . 109.5 ?
C49 C50 H50B . . 109.5 ?
C49 C50 H50C . . 109.5 ?
H50A C50 H50B . . 109.5 ?
H50A C50 H50C . . 109.5 ?
H50B C50 H50C . . 109.5 ?
N2 B1 H1 . . 110.8(10) ?
N4 B1 N2 . . 108.59(13) ?
N4 B1 N6 . . 109.61(13) ?
N4 B1 H1 . . 110.5(10) ?
N6 B1 N2 . . 109.24(13) ?
N6 B1 H1 . . 108.1(10) ?
N7 C51 H51A . . 109.6 ?
N7 C51 H51B . . 109.6 ?
N7 C51 C52 . . 110.4(2) ?
H51A C51 H51B . . 108.1 ?
C52 C51 H51A . . 109.6 ?
C52 C51 H51B . . 109.6 ?
C51 C52 H52A . . 109.2 ?
C51 C52 H52B . . 109.2 ?
C51 C52 C53 . . 112.0(3) ?
H52A C52 H52B . . 107.9 ?
C53 C52 H52A . . 109.2 ?
C53 C52 H52B . . 109.2 ?
C52 C53 H53A . . 108.6 ?
C52 C53 H53B . . 108.6 ?
H53A C53 H53B . . 107.5 ?
C54 C53 C52 . . 114.8(4) ?
C54 C53 H53A . . 108.6 ?
C54 C53 H53B . . 108.6 ?
C53 C54 H54C . . 109.5 ?
C53 C54 H54A . . 109.5 ?
C53 C54 H54B . . 109.5 ?
H54C C54 H54A . . 109.5 ?
H54C C54 H54B . . 109.5 ?
H54A C54 H54B . . 109.5 ?
N7 C51A H51C . . 111.0 ?
N7 C51A H51D . . 111.0 ?
H51C C51A H51D . . 109.0 ?
C52A C51A N7 . . 103.6(6) ?
C52A C51A H51C . . 111.0 ?
C52A C51A H51D . . 111.0 ?
C51A C52A H52C . . 108.9 ?
C51A C52A H52D . . 108.9 ?
C51A C52A C53A . . 113.5(9) ?
H52C C52A H52D . . 107.7 ?
C53A C52A H52C . . 108.9 ?
C53A C52A H52D . . 108.9 ?
C52A C53A H53C . . 110.0 ?
C52A C53A H53D . . 110.0 ?
H53C C53A H53D . . 108.4 ?
C54A C53A C52A . . 108.4(10) ?
C54A C53A H53C . . 110.0 ?
C54A C53A H53D . . 110.0 ?
C53A C54A H54F . . 109.5 ?
C53A C54A H54D . . 109.5 ?
C53A C54A H54E . . 109.5 ?
H54F C54A H54D . . 109.5 ?
H54F C54A H54E . . 109.5 ?
H54D C54A H54E . . 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Co1 S1 . 2.4030(5) ?
Co1 S2 . 2.3892(5) ?
Co1 N1 . 2.1371(14) ?
Co1 N3 . 2.0804(13) ?
Co1 N5 . 2.1480(13) ?
S1 C46 . 1.7169(18) ?
S2 C46 . 1.7199(18) ?
N1 N2 . 1.3737(18) ?
N1 C1 . 1.344(2) ?
N2 C3 . 1.358(2) ?
N2 B1 . 1.556(2) ?
N3 N4 . 1.3735(18) ?
N3 C16 . 1.339(2) ?
N4 C18 . 1.362(2) ?
N4 B1 . 1.541(2) ?
N5 N6 . 1.3691(18) ?
N5 C31 . 1.341(2) ?
N6 C33 . 1.357(2) ?
N6 B1 . 1.542(2) ?
N7 C46 . 1.331(2) ?
N7 C47 . 1.470(2) ?
N7 C51 . 1.481(3) ?
N7 C51A . 1.588(8) ?
C1 C2 . 1.398(2) ?
C1 C4 . 1.470(2) ?
C2 H2 . 0.9300 ?
C2 C3 . 1.382(2) ?
C3 C10 . 1.480(2) ?
C4 C5 . 1.395(2) ?
C4 C9 . 1.396(2) ?
C5 H5 . 0.9300 ?
C5 C6 . 1.385(2) ?
C6 H6 . 0.9300 ?
C6 C7 . 1.387(3) ?
C7 H7 . 0.9300 ?
C7 C8 . 1.384(3) ?
C8 H8 . 0.9300 ?
C8 C9 . 1.387(3) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.394(2) ?
C10 C15 . 1.393(3) ?
C11 H11 . 0.9300 ?
C11 C12 . 1.389(3) ?
C12 H12 . 0.9300 ?
C12 C13 . 1.379(3) ?
C13 H13 . 0.9300 ?
C13 C14 . 1.386(3) ?
C14 H14 . 0.9300 ?
C14 C15 . 1.389(3) ?
C15 H15 . 0.9300 ?
C16 C17 . 1.394(2) ?
C16 C19 . 1.481(2) ?
C17 H17 . 0.9300 ?
C17 C18 . 1.381(2) ?
C18 C25 . 1.478(2) ?
C19 C20 . 1.383(3) ?
C19 C24 . 1.393(3) ?
C20 H20 . 0.9300 ?
C20 C21 . 1.398(3) ?
C21 H21 . 0.9300 ?
C21 C22 . 1.367(3) ?
C22 H22 . 0.9300 ?
C22 C23 . 1.378(3) ?
C23 H23 . 0.9300 ?
C23 C24 . 1.383(3) ?
C24 H24 . 0.9300 ?
C25 C26 . 1.392(2) ?
C25 C30 . 1.397(2) ?
C26 H26 . 0.9300 ?
C26 C27 . 1.387(3) ?
C27 H27 . 0.9300 ?
C27 C28 . 1.388(3) ?
C28 H28 . 0.9300 ?
C28 C29 . 1.377(3) ?
C29 H29 . 0.9300 ?
C29 C30 . 1.387(3) ?
C30 H30 . 0.9300 ?
C31 C32 . 1.399(2) ?
C31 C34 . 1.476(2) ?
C32 H32 . 0.9300 ?
C32 C33 . 1.382(2) ?
C33 C40 . 1.476(2) ?
C34 C35 . 1.386(2) ?
C34 C39 . 1.391(3) ?
C35 H35 . 0.9300 ?
C35 C36 . 1.391(3) ?
C36 H36 . 0.9300 ?
C36 C37 . 1.373(3) ?
C37 H37 . 0.9300 ?
C37 C38 . 1.383(3) ?
C38 H38 . 0.9300 ?
C38 C39 . 1.387(3) ?
C39 H39 . 0.9300 ?
C40 C41 . 1.397(2) ?
C40 C45 . 1.392(2) ?
C41 H41 . 0.9300 ?
C41 C42 . 1.385(3) ?
C42 H42 . 0.9300 ?
C42 C43 . 1.382(3) ?
C43 H43 . 0.9300 ?
C43 C44 . 1.385(3) ?
C44 H44 . 0.9300 ?
C44 C45 . 1.388(2) ?
C45 H45 . 0.9300 ?
C47 H47A . 0.9700 ?
C47 H47B . 0.9700 ?
C47 C48 . 1.517(3) ?
C48 H48A . 0.9700 ?
C48 H48B . 0.9700 ?
C48 C49 . 1.516(3) ?
C49 H49A . 0.9700 ?
C49 H49B . 0.9700 ?
C49 C50 . 1.506(3) ?
C50 H50A . 0.9600 ?
C50 H50B . 0.9600 ?
C50 H50C . 0.9600 ?
B1 H1 . 1.060(18) ?
C51 H51A . 0.9700 ?
C51 H51B . 0.9700 ?
C51 C52 . 1.512(4) ?
C52 H52A . 0.9700 ?
C52 H52B . 0.9700 ?
C52 C53 . 1.527(5) ?
C53 H53A . 0.9700 ?
C53 H53B . 0.9700 ?
C53 C54 . 1.499(7) ?
C54 H54C . 0.9600 ?
C54 H54A . 0.9600 ?
C54 H54B . 0.9600 ?
C51A H51C . 0.9700 ?
C51A H51D . 0.9700 ?
C51A C52A . 1.535(14) ?
C52A H52C . 0.9700 ?
C52A H52D . 0.9700 ?
C52A C53A . 1.548(13) ?
C53A H53C . 0.9700 ?
C53A H53D . 0.9700 ?
C53A C54A . 1.465(14) ?
C54A H54F . 0.9600 ?
C54A H54D . 0.9600 ?
C54A H54E . 0.9600 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
Co1 S1 C46 S2 . . . . -4.36(9) ?
Co1 S1 C46 N7 . . . . 177.89(17) ?
Co1 S2 C46 S1 . . . . 4.38(9) ?
Co1 S2 C46 N7 . . . . -177.85(16) ?
Co1 N1 N2 C3 . . . . -161.33(10) ?
Co1 N1 N2 B1 . . . . 12.51(17) ?
Co1 N1 C1 C2 . . . . 155.63(13) ?
Co1 N1 C1 C4 . . . . -27.3(2) ?
Co1 N3 N4 C18 . . . . -172.90(10) ?
Co1 N3 N4 B1 . . . . 6.48(17) ?
Co1 N3 C16 C17 . . . . 171.32(12) ?
Co1 N3 C16 C19 . . . . -11.0(3) ?
Co1 N5 N6 C33 . . . . 171.69(10) ?
Co1 N5 N6 B1 . . . . -13.01(17) ?
Co1 N5 C31 C32 . . . . -168.66(12) ?
Co1 N5 C31 C34 . . . . 16.3(3) ?
N1 N2 C3 C2 . . . . -1.21(18) ?
N1 N2 C3 C10 . . . . 176.13(14) ?
N1 N2 B1 N4 . . . . -68.23(17) ?
N1 N2 B1 N6 . . . . 51.27(18) ?
N1 C1 C2 C3 . . . . 1.24(19) ?
N1 C1 C4 C5 . . . . -42.8(2) ?
N1 C1 C4 C9 . . . . 139.30(17) ?
N2 N1 C1 C2 . . . . -1.96(18) ?
N2 N1 C1 C4 . . . . 175.07(14) ?
N2 C3 C10 C11 . . . . -120.61(18) ?
N2 C3 C10 C15 . . . . 58.0(2) ?
N3 N4 C18 C17 . . . . -0.50(18) ?
N3 N4 C18 C25 . . . . 177.84(14) ?
N3 N4 B1 N2 . . . . 55.64(17) ?
N3 N4 B1 N6 . . . . -63.63(17) ?
N3 C16 C17 C18 . . . . 0.59(19) ?
N3 C16 C19 C20 . . . . 89.0(2) ?
N3 C16 C19 C24 . . . . -98.4(2) ?
N4 N3 C16 C17 . . . . -0.89(18) ?
N4 N3 C16 C19 . . . . 176.74(15) ?
N4 C18 C25 C26 . . . . 48.1(2) ?
N4 C18 C25 C30 . . . . -134.06(18) ?
N5 N6 C33 C32 . . . . 0.38(17) ?
N5 N6 C33 C40 . . . . 177.95(14) ?
N5 N6 B1 N2 . . . . -50.68(18) ?
N5 N6 B1 N4 . . . . 68.19(17) ?
N5 C31 C32 C33 . . . . -0.86(18) ?
N5 C31 C34 C35 . . . . -145.47(17) ?
N5 C31 C34 C39 . . . . 39.4(2) ?
N6 N5 C31 C32 . . . . 1.08(17) ?
N6 N5 C31 C34 . . . . -173.94(14) ?
N6 C33 C40 C41 . . . . 55.7(2) ?
N6 C33 C40 C45 . . . . -125.29(17) ?
N7 C47 C48 C49 . . . . -171.71(17) ?
N7 C51 C52 C53 . . . . 177.9(3) ?
N7 C51A C52A C53A . . . . -178.9(8) ?
C1 N1 N2 C3 . . . . 1.96(17) ?
C1 N1 N2 B1 . . . . 175.80(14) ?
C1 C2 C3 N2 . . . . 0.00(19) ?
C1 C2 C3 C10 . . . . -177.16(16) ?
C1 C4 C5 C6 . . . . -177.94(15) ?
C1 C4 C9 C8 . . . . 178.46(16) ?
C2 C1 C4 C5 . . . . 133.69(19) ?
C2 C1 C4 C9 . . . . -44.2(2) ?
C2 C3 C10 C11 . . . . 56.2(2) ?
C2 C3 C10 C15 . . . . -125.2(2) ?
C3 N2 B1 N4 . . . . 104.30(18) ?
C3 N2 B1 N6 . . . . -136.19(16) ?
C3 C10 C11 C12 . . . . 177.43(16) ?
C3 C10 C15 C14 . . . . -178.67(16) ?
C4 C1 C2 C3 . . . . -175.60(16) ?
C4 C5 C6 C7 . . . . -0.5(3) ?
C5 C4 C9 C8 . . . . 0.5(2) ?
C5 C6 C7 C8 . . . . 0.5(3) ?
C6 C7 C8 C9 . . . . -0.1(3) ?
C7 C8 C9 C4 . . . . -0.5(3) ?
C9 C4 C5 C6 . . . . 0.0(3) ?
C10 C11 C12 C13 . . . . 1.4(3) ?
C11 C10 C15 C14 . . . . -0.1(3) ?
C11 C12 C13 C14 . . . . -0.4(3) ?
C12 C13 C14 C15 . . . . -0.9(3) ?
C13 C14 C15 C10 . . . . 1.1(3) ?
C15 C10 C11 C12 . . . . -1.2(3) ?
C16 N3 N4 C18 . . . . 0.86(17) ?
C16 N3 N4 B1 . . . . -179.75(13) ?
C16 C17 C18 N4 . . . . -0.05(19) ?
C16 C17 C18 C25 . . . . -178.35(16) ?
C16 C19 C20 C21 . . . . 171.21(17) ?
C16 C19 C24 C23 . . . . -172.00(16) ?
C17 C16 C19 C20 . . . . -93.7(2) ?
C17 C16 C19 C24 . . . . 78.9(2) ?
C17 C18 C25 C26 . . . . -133.92(19) ?
C17 C18 C25 C30 . . . . 44.0(2) ?
C18 N4 B1 N2 . . . . -125.13(17) ?
C18 N4 B1 N6 . . . . 115.60(18) ?
C18 C25 C26 C27 . . . . -179.97(16) ?
C18 C25 C30 C29 . . . . -179.55(17) ?
C19 C16 C17 C18 . . . . -177.03(16) ?
C19 C20 C21 C22 . . . . 0.4(3) ?
C20 C19 C24 C23 . . . . 0.8(3) ?
C20 C21 C22 C23 . . . . 1.1(3) ?
C21 C22 C23 C24 . . . . -1.7(3) ?
C22 C23 C24 C19 . . . . 0.7(3) ?
C24 C19 C20 C21 . . . . -1.3(3) ?
C25 C26 C27 C28 . . . . -1.1(3) ?
C26 C25 C30 C29 . . . . -1.6(3) ?
C26 C27 C28 C29 . . . . -0.6(3) ?
C27 C28 C29 C30 . . . . 1.2(3) ?
C28 C29 C30 C25 . . . . -0.1(3) ?
C30 C25 C26 C27 . . . . 2.2(3) ?
C31 N5 N6 C33 . . . . -0.91(17) ?
C31 N5 N6 B1 . . . . 174.40(13) ?
C31 C32 C33 N6 . . . . 0.28(18) ?
C31 C32 C33 C40 . . . . -177.15(16) ?
C31 C34 C35 C36 . . . . -176.06(18) ?
C31 C34 C39 C38 . . . . 175.39(17) ?
C32 C31 C34 C35 . . . . 40.3(2) ?
C32 C31 C34 C39 . . . . -134.85(19) ?
C32 C33 C40 C41 . . . . -127.23(19) ?
C32 C33 C40 C45 . . . . 51.8(2) ?
C33 N6 B1 N2 . . . . 123.65(16) ?
C33 N6 B1 N4 . . . . -117.48(16) ?
C33 C40 C41 C42 . . . . -179.67(16) ?
C33 C40 C45 C44 . . . . 179.93(16) ?
C34 C31 C32 C33 . . . . 174.04(15) ?
C34 C35 C36 C37 . . . . 0.6(3) ?
C35 C34 C39 C38 . . . . 0.2(3) ?
C35 C36 C37 C38 . . . . 0.2(3) ?
C36 C37 C38 C39 . . . . -0.8(3) ?
C37 C38 C39 C34 . . . . 0.6(3) ?
C39 C34 C35 C36 . . . . -0.8(3) ?
C40 C41 C42 C43 . . . . -0.5(3) ?
C41 C40 C45 C44 . . . . -1.1(3) ?
C41 C42 C43 C44 . . . . -0.6(3) ?
C42 C43 C44 C45 . . . . 0.9(3) ?
C43 C44 C45 C40 . . . . -0.1(3) ?
C45 C40 C41 C42 . . . . 1.3(3) ?
C46 N7 C47 C48 . . . . -83.4(2) ?
C46 N7 C51 C52 . . . . 97.5(3) ?
C46 N7 C51A C52A . . . . -111.6(6) ?
C47 N7 C46 S1 . . . . -1.9(3) ?
C47 N7 C46 S2 . . . . -179.54(14) ?
C47 N7 C51 C52 . . . . -91.5(3) ?
C47 N7 C51A C52A . . . . 100.2(6) ?
C47 C48 C49 C50 . . . . -173.42(19) ?
B1 N2 C3 C2 . . . . -174.41(15) ?
B1 N2 C3 C10 . . . . 2.9(3) ?
B1 N4 C18 C17 . . . . -179.77(16) ?
B1 N4 C18 C25 . . . . -1.4(3) ?
B1 N6 C33 C32 . . . . -174.43(15) ?
B1 N6 C33 C40 . . . . 3.1(2) ?
C51 N7 C46 S1 . . . . 168.49(17) ?
C51 N7 C46 S2 . . . . -9.1(3) ?
C51 N7 C47 C48 . . . . 105.7(2) ?
C51 C52 C53 C54 . . . . 66.4(5) ?
C51A N7 C46 S1 . . . . -147.1(4) ?
C51A N7 C46 S2 . . . . 35.2(4) ?
C51A N7 C47 C48 . . . . 62.2(4) ?
C51A C52A C53A C54A . . . . -59.9(16) ?

_cod_database_fobs_code 2022243
