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#$Date: 2017-12-03 18:43:28 +0200 (Sun, 03 Dec 2017) $
#$Revision: 203902 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/10/12/2101226.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2101226
loop_
_publ_author_name
'Ojala, W. H.'
'Lu, L. K.'
'Albers, K. E.'
'Gleason, W. B.'
'Richardson, T. I.'
'Lovrien, R. E.'
'Sudbeck, E. A.'
_publ_section_title
;
 Intermolecular interactions of sulfonated azo dyes: crystal structures
 of the diammonium, dilithium, magnesium and calcium salts of
 7-hydroxy-8-(phenylazo)-1,3-naphthalenedisulfonic acid(Orange G)
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              684
_journal_page_last               694
_journal_paper_doi               10.1107/S0108768194005203
_journal_volume                  50
_journal_year                    1994
_chemical_formula_sum            'C16 H26 Mg N2 O15 S2'
_chemical_formula_weight         574.81
_space_group_crystal_system      triclinic
_space_group_IT_number           2
_space_group_name_Hall           '-P 1'
_space_group_name_H-M_alt        'P -1'
_cell_angle_alpha                79.180(10)
_cell_angle_beta                 79.490(10)
_cell_angle_gamma                79.490(10)
_cell_formula_units_Z            2
_cell_length_a                   8.8440(10)
_cell_length_b                   10.1790(10)
_cell_length_c                   13.9010(10)
_cell_volume                     1194.2(2)
_diffrn_radiation_type           Cu
_diffrn_radiation_wavelength     1.54178
_exptl_absorpt_coefficient_mu    2.946
_exptl_crystal_density_diffrn    1.598
_exptl_crystal_F_000             600
_cod_data_source_file            gr0362.cif
_cod_data_source_block           gr0362c
_cod_original_cell_volume        1194.2(5)
_cod_database_code               2101226
loop_
_space_group_symop_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,-y,-z
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
S(1) .53042(5) .19071(4) .27538(3)
S(2) .00603(5) .54971(4) .30859(3)
Mg(1) .5 .5 .5
Mg(2) .0 1 .5
O(1) .6651(2) .25150(10) .28050(10)
O(2) .5687(2) .07300(10) .22490(10)
O(3) .4418(2) .16040(10) .37430(10)
O(4) -.1286(2) .60300(10) .25780(10)
O(5) .0763(2) .65690(10) .32990(10)
O(6) -.0280(2) .44810(10) .39540(10)
O(7) .6270(2) .2535(2) -.13440(10)
O(8) .4874(2) .29590(10) .52810(10)
O(9) .2846(2) .5335(2) .45750(10)
O(10) .6042(2) .49250(10) .35550(10)
O(11) -.1977(2) .8798(2) .31090(10)
O(12) .4077(2) .8482(2) .29960(10)
O(13) -.1973(2) .9293(2) .49440(10)
O(14) .0996(2) .9144(2) .37770(10)
O(15) .0768(2) .8233(2) .59600(10)
N(1) .6776(2) .2547(2) .06170(10)
N(2) .7979(2) .2144(2) -.00110(10)
C(1) .3991(2) .3143(2) .20760(10)
C(2) .2731(2) .3754(2) .26750(10)
C(3) .1520(2) .4639(2) .22740(10)
C(4) .1515(2) .4874(2) .12680(10)
C(4A) .2775(2) .4257(2) .06470(10)
C(5) .2689(3) .4466(2) -.04020(10)
C(6) .3809(3) .3864(2) -.10440(10)
C(7) .5202(3) .3072(2) -.07300(10)
C(8) .5396(2) .2956(2) .03050(10)
C(8A) .4082(2) .3437(2) .10220(10)
C(9) .9479(2) .1777(2) .02500(10)
C(10) .9751(3) .1704(2) .1212(2)
C(11) 1.1249(3) .1252(2) .1428(2)
C(12) 1.2470(3) .0895(2) .0687(2)
C(13) 1.2189(3) .1001(2) -.0274(2)
C(14) 1.0695(3) .1446(2) -.0504(2)
H(2) .273(3) .355(3) .331(2)
H(2N) .770(3) .213(3) -.059(2)
H(4) .060(3) .553(3) .096(2)
H(5) .179(3) .509(3) -.063(2)
H(6) .379(3) .394(3) -.171(2)
H(8W) .518(3) .248(3) .586(2)
H(8A) .480(4) .246(3) .486(2)
H(9W) .208(4) .528(3) .501(2)
H(9A) .251(3) .585(3) .413(2)
H(10W) .615(3) .420(3) .333(2)
H(10) .885(3) .190(3) .173(2)
H(10A) .685(3) .531(3) .331(2)
H(11) 1.143(3) .115(3) .212(2)
H(11W) -.202(4) .801(3) .289(2)
H(11A) -.266(4) .932(3) .280(2)
H(12) 1.348(4) .060(3) .080(2)
H(12W) .454(3) .921(3) .281(2)
H(12A) .401(3) .816(3) .251(2)
H(13W) -.268(4) .911(3) .541(2)
H(13) 1.307(3) .070(3) -.080(2)
H(13A) -.206(4) .905(3) .443(2)
H(14) 1.048(3) .147(3) -.114(2)
H(14W) .059(4) .880(3) .356(2)
H(14A) .194(4) .892(3) .354(2)
H(15W) .153(4) .811(3) .626(2)
H(15A) .050(4) .748(4) .597(2)
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
O(1) S(1) O(2) 113.78(8)
O(1) S(1) O(3) 110.26(8)
O(1) S(1) C(1) 108.71(8)
O(2) S(1) O(3) 111.84(8)
O(2) S(1) C(1) 107.11(8)
O(3) S(1) C(1) 104.63(9)
O(4) S(2) O(5) 111.96(9)
O(4) S(2) O(6) 112.67(9)
O(4) S(2) C(3) 108.41(9)
O(5) S(2) O(6) 112.95(9)
O(5) S(2) C(3) 105.04(9)
O(6) S(2) C(3) 105.18(8)
N(2) N(1) C(8) 118.9(2)
N(1) N(2) C(9) 121.9(2)
S(1) C(1) C(2) 113.80(10)
S(1) C(1) C(8A) 126.10(10)
C(2) C(1) C(8A) 119.9(2)
C(1) C(2) C(3) 121.5(2)
S(2) C(3) C(2) 118.20(10)
S(2) C(3) C(4) 121.5(2)
C(2) C(3) C(4) 120.2(2)
C(3) C(4) C(4A) 119.2(2)
C(4) C(4A) C(5) 117.6(2)
C(4) C(4A) C(8A) 122.0(2)
C(5) C(4A) C(8A) 120.3(2)
C(4A) C(5) C(6) 121.6(2)
C(5) C(6) C(7) 121.3(2)
O(7) C(7) C(6) 121.0(2)
O(7) C(7) C(8) 120.7(2)
C(6) C(7) C(8) 118.2(2)
N(1) C(8) C(7) 122.7(2)
N(1) C(8) C(8A) 117.4(2)
C(7) C(8) C(8A) 119.6(2)
C(1) C(8A) C(4A) 116.8(2)
C(1) C(8A) C(8) 125.7(2)
C(4A) C(8A) C(8) 117.5(2)
N(2) C(9) C(10) 122.2(2)
N(2) C(9) C(14) 116.8(2)
O(8) Mg(1) O(9) 88.37(7)
O(8) Mg(1) O(9) 91.63(7)
O(8) Mg(1) O(10) 92.60(6)
O(8) Mg(1) O(10) 87.40(6)
O(9) Mg(1) O(10) 90.43(6)
O(9) Mg(1) O(10) 89.57(6)
O(13) Mg(2) O(14) 87.85(7)
O(13) Mg(2) O(14) 92.15(7)
O(13) Mg(2) O(15) 91.33(8)
O(13) Mg(2) O(15) 88.67(8)
O(14) Mg(2) O(15) 91.89(8)
O(14) Mg(2) O(15) 88.11(8)
O(8) Mg(1) O(8) 180.00
O(9) Mg(1) O(9) 180.00
O(10) Mg(1) O(10) 180.00
O(13) Mg(2) O(13) 180.00
O(14) Mg(2) O(14) 180.00
O(15) Mg(2) O(15) 180.00
C(10) C(9) C(14) 121.0(2)
C(9) C(10) C(11) 118.9(2)
C(10) C(11) C(12) 120.7(2)
C(11) C(12) C(13) 119.8(2)
C(12) C(13) C(14) 120.4(2)
C(9) C(14) C(13) 119.2(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
S(1) O(1) 1.4570(10)
S(1) O(2) 1.4570(10)
S(1) O(3) 1.4620(10)
S(1) C(1) 1.800(2)
S(2) O(4) 1.462(2)
S(2) O(5) 1.4490(10)
S(2) O(6) 1.4590(10)
S(2) C(3) 1.770(2)
O(7) C(7) 1.269(3)
N(1) N(2) 1.303(2)
N(1) C(8) 1.339(3)
N(2) C(9) 1.405(3)
C(1) C(2) 1.387(3)
C(1) C(8A) 1.429(2)
C(2) C(3) 1.395(3)
C(3) C(4) 1.374(3)
C(4) C(4A) 1.407(3)
C(4A) C(5) 1.447(3)
C(4A) C(8A) 1.417(3)
C(5) C(6) 1.347(3)
C(6) C(7) 1.435(3)
C(7) C(8) 1.460(3)
C(8) C(8A) 1.462(3)
Mg(1) O(8) 2.061(2)
Mg(1) O(8) 2.061(2)
Mg(1) O(9) 2.047(2)
Mg(1) O(9) 2.047(2)
Mg(1) O(10) 2.0600(10)
Mg(1) O(10) 2.0600(10)
Mg(2) O(13) 2.024(2)
Mg(2) O(13) 2.024(2)
Mg(2) O(14) 2.038(2)
Mg(2) O(14) 2.038(2)
Mg(2) O(15) 2.112(2)
Mg(2) O(15) 2.112(2)
O(8) H(8W) .92(3)
O(8) H(8A) .87(3)
O(9) H(9W) .82(3)
O(9) H(9A) .80(3)
O(10) H(10W) .84(3)
O(10) H(10A) .86(3)
O(11) H(11W) .92(3)
O(11) H(11A) .85(3)
O(12) H(12W) .89(3)
O(12) H(12A) .81(3)
O(13) H(13W) .84(3)
O(13) H(13A) .82(3)
O(14) H(14W) .68(3)
O(14) H(14A) .84(3)
O(15) H(15W) .83(4)
O(15) H(15A) .84(3)
N(2) H(2N) .88(3)
C(2) H(2) .86(3)
C(4) H(4) 1.06(3)
C(5) H(5) .99(3)
C(6) H(6) .92(3)
C(9) C(10) 1.388(3)
C(9) C(14) 1.398(3)
C(10) C(11) 1.389(3)
C(10) H(10) .99(3)
C(11) C(12) 1.396(3)
C(11) H(11) .99(3)
C(12) C(13) 1.383(3)
C(12) H(12) .92(3)
C(13) C(14) 1.391(3)
C(13) H(13) 1.01(3)
C(14) H(14) .93(3)
