#------------------------------------------------------------------------------
#$Date: 2023-03-26 11:09:57 +0300 (Sun, 26 Mar 2023) $
#$Revision: 282068 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/10/52/2105250.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2105250
loop_
_publ_author_name
'Moëlo, Yves'
'Guillot-Deudon, Catherine'
'Evain, Michel'
'Orlandi, Paolo'
'Biagioni, Cristian'
_publ_section_title
;
 Comparative modular analysis of two complex sulfosalt structures:
 sterryite, Cu(Ag,Cu)₃Pb₁₉(Sb,As)₂₂(As--As)S₅₆, and parasterryite,
 Ag₄Pb₂₀(Sb,As)₂₄S₅₈
;
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              480
_journal_page_last               492
_journal_paper_doi               10.1107/S0108768112034027
_journal_volume                  68
_journal_year                    2012
_chemical_compound_source        'Pollone mine, Tuscany, Italy'
_chemical_formula_moiety         'Ag4 As10.23 Pb20.21 S58 Sb13.56'
_chemical_formula_structural     'Ag4 As10.23 Pb20.21 S58 Sb13.56'
_chemical_formula_sum            'Ag4 As10.23 Pb20.21 S58 Sb13.56'
_chemical_formula_weight         8896.54
_chemical_name_mineral           Parasterryite
_chemical_name_systematic        Parasterryite
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_cell_angle_alpha                90
_cell_angle_beta                 90.061(12)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   8.3965(5)
_cell_length_b                   27.954(7)
_cell_length_c                   43.884(13)
_cell_measurement_temperature    293
_cell_measurement_theta_max      35
_cell_measurement_theta_min      6.43
_cell_volume                     10300(4)
_computing_cell_refinement       unknown
_computing_data_collection       unknown
_computing_data_reduction        unknown
_computing_molecular_graphics    unknown
_computing_publication_material
'Jana2006 (Petricek, Dusek & Palatinus, 2006)'
_computing_structure_refinement
'Jana2006 (Petricek, Dusek & Palatinus, 2006)'
_computing_structure_solution    unknown
_database_code_amcsd             0019483
_diffrn_ambient_temperature      293
_diffrn_measured_fraction_theta_full 0.98
_diffrn_measured_fraction_theta_max 0.98
_diffrn_measurement_device       'four-cycle diffractometer'
_diffrn_measurement_device_type  'Nonius CCD'
_diffrn_measurement_method       'phi and omega scans method'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'X-ray tube'
_diffrn_radiation_type           'Mo K\a'
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.1784
_diffrn_reflns_av_sigmaI/netI    0.1115
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       45
_diffrn_reflns_limit_k_min       -43
_diffrn_reflns_limit_l_max       69
_diffrn_reflns_limit_l_min       -70
_diffrn_reflns_number            246165
_diffrn_reflns_theta_full        35
_diffrn_reflns_theta_max         35
_diffrn_reflns_theta_min         6.43
_exptl_absorpt_coefficient_mu    41.858
_exptl_absorpt_correction_T_max  0.0777
_exptl_absorpt_correction_T_min  0.023
_exptl_absorpt_correction_type   gaussian
_exptl_absorpt_process_details
'Jana2006  (Petricek, Dusek & Palatinus, 2000)'
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    5.7533
_exptl_crystal_description       paralleliped
_exptl_crystal_F_000             15209
_exptl_crystal_size_max          0.090
_exptl_crystal_size_mid          0.040
_exptl_crystal_size_min          0.040
_refine_diff_density_max         3.68
_refine_diff_density_min         -2.48
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.35
_refine_ls_number_constraints    135
_refine_ls_number_parameters     965
_refine_ls_number_reflns         36071
_refine_ls_number_restraints     0
_refine_ls_R_factor_all          0.1566
_refine_ls_R_factor_gt           0.0661
_refine_ls_shift/su_max          1.2848
_refine_ls_shift/su_mean         0.0212
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details     w=1/(σ²(F)+0.000484F²)
_refine_ls_weighting_scheme      sigma
_refine_ls_wR_factor_gt          0.1239
_refine_ls_wR_factor_ref         0.1643
_reflns_number_gt                18992
_reflns_number_total             36071
_reflns_threshold_expression     I>3σ(I)
_cod_data_source_file            bp5041.cif
_cod_data_source_block           parasterryite
_cod_original_cell_volume        10300(3)
_cod_database_code               2105250
_cod_database_fobs_code          2105250
loop_
_symmetry_equiv_pos_site_id
_space_group_symop_operation_xyz
1 x,y,z
2 -x,y+1/2,-z+1/2
3 -x,-y,-z
4 x,-y+1/2,z+1/2
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Pb Pb1 0.36763(14) 0.36216(3) 0.18873(2) 0.0223(3) Uani d 1 4
Pb Pb2 0.87463(14) 0.36391(4) 0.18918(2) 0.0242(3) Uani d 1 4
Pb Pb3 0.36370(14) 0.29977(3) 0.09552(2) 0.0239(3) Uani d 1 4
Pb Pb4 0.86185(14) 0.29243(3) 0.10178(2) 0.0243(3) Uani d 1 4
Pb Pb5 0.35693(14) 0.45226(3) 0.10872(2) 0.0250(3) Uani d 1 4
Pb Pb6 0.85479(14) 0.45238(3) 0.10944(2) 0.0256(3) Uani d 1 4
Ag Ag7 0.3362(4) 0.58389(10) 0.10610(8) 0.0555(10) Uani d 1 4
Pb Pb8 0.81865(15) 0.59875(4) 0.11581(3) 0.0323(3) Uani d 1 4
As As9 0.6226(3) 0.49315(8) 0.18644(5) 0.0159(6) Uani d 1 4
Sb Sb10 0.1312(2) 0.49109(6) 0.19319(4) 0.0210(4) Uani d 1 4
Sb Sb11 0.3725(3) 0.90657(8) 0.23240(5) 0.0173(6) Uani d 0.12 4
As As11 0.3725(3) 0.90657(8) 0.23240(5) 0.0173(6) Uani d 0.88 4
Sb Sb12 0.8665(3) 0.91492(6) 0.23679(4) 0.0203(4) Uani d 0.87 4
As As12 0.8665(3) 0.91492(6) 0.23679(4) 0.0203(4) Uani d 0.13 4
Pb Pb13 0.61281(15) 0.78747(4) 0.22624(2) 0.0293(3) Uani d 1 4
Pb Pb14 0.13196(15) 0.78428(4) 0.22712(2) 0.0250(3) Uani d 1 4
Sb Sb15 0.5937(2) 0.22519(6) 0.16976(4) 0.0191(4) Uani d 0.91 4
As As15 0.5937(2) 0.22519(6) 0.16976(4) 0.0191(4) Uani d 0.09 4
As As16 0.1231(3) 0.23186(8) 0.17065(5) 0.0163(6) Uani d 1 4
Sb Sb17 0.6199(3) 0.16758(7) 0.09448(5) 0.0210(5) Uani d 0.43 4
As As17 0.6199(3) 0.16758(7) 0.09448(5) 0.0210(5) Uani d 0.57 4
Sb Sb18 0.1139(2) 0.15868(6) 0.08751(4) 0.0215(4) Uani d 1 4
Sb Sb19 0.6161(2) 0.07517(6) 0.00797(4) 0.0168(4) Uani d 0.8 4
As As19 0.6161(2) 0.07517(6) 0.00797(4) 0.0168(4) Uani d 0.2 4
Pb Pb20 0.1146(2) 0.08099(6) 0.01537(3) 0.0319(4) Uani d 0.46 4
Sb Sb20 0.1146(2) 0.08099(6) 0.01537(3) 0.0319(4) Uani d 0.54 4
Pb Pb21 0.38579(14) 0.00515(3) 0.06394(2) 0.0222(2) Uani d 1 4
Sb Sb22 0.8772(2) 0.00802(6) 0.07129(4) 0.0177(4) Uani d 0.78 4
As As22 0.8772(2) 0.00802(6) 0.07129(4) 0.0177(4) Uani d 0.22 4
Sb Sb23 0.3700(2) 0.07949(6) 0.15271(4) 0.0186(4) Uani d 0.82 4
As As23 0.3700(2) 0.07949(6) 0.15271(4) 0.0186(4) Uani d 0.18 4
Pb Pb24 0.88296(14) 0.08179(3) 0.14700(2) 0.0230(3) Uani d 1 4
Ag Ag25 0.3523(3) 0.16014(8) 0.23146(5) 0.0351(7) Uani d 1 4
Sb Sb26 0.8696(3) 0.16689(7) 0.22674(4) 0.0208(5) Uani d 0.7 4
As As26 0.8696(3) 0.16689(7) 0.22674(4) 0.0208(5) Uani d 0.3 4
Pb Pb27 0.39721(14) 0.61845(4) 0.19934(2) 0.0276(3) Uani d 1 4
Sb Sb28 0.8947(3) 0.61462(7) 0.20042(4) 0.0210(5) Uani d 0.6 4
As As28 0.8947(3) 0.61462(7) 0.20042(4) 0.0210(5) Uani d 0.4 4
Sb Sb29 0.6118(2) 0.03729(6) 0.22421(4) 0.0211(4) Uani d 1 4
Pb Pb30 0.11604(14) 0.02959(4) 0.22269(2) 0.0251(3) Uani d 1 4
Pb Pb31 0.62627(14) 0.94878(3) 0.14183(2) 0.0233(3) Uani d 1 4
Pb Pb32 0.11873(14) 0.95038(3) 0.14272(2) 0.0227(3) Uani d 1 4
Pb Pb33a 0.62472(14) 0.86693(4) 0.06450(2) 0.0248(3) Uani d 1 4
Pb Pb34a 0.14489(13) 0.87105(4) 0.06308(2) 0.0233(3) Uani d 1 4
Pb Pb35 0.35797(15) 0.21290(4) 0.01550(2) 0.0273(3) Uani d 1 4
Pb Pb36 0.86164(14) 0.21330(4) 0.01791(2) 0.0237(3) Uani d 1 4
As As37 0.5987(3) 0.38671(8) 0.03818(5) 0.0162(6) Uani d 0.95 4
Sb Sb37 0.5987(3) 0.38671(8) 0.03818(5) 0.0162(6) Uani d 0.05 4
Sb Sb38 0.1380(2) 0.39220(6) 0.03406(4) 0.0207(5) Uani d 0.9 4
As As38 0.1380(2) 0.39220(6) 0.03406(4) 0.0207(5) Uani d 0.1 4
Sb Sb39 0.6318(3) 0.52810(7) 0.03770(5) 0.0220(5) Uani d 0.57 4
As As39 0.6318(3) 0.52810(7) 0.03770(5) 0.0220(5) Uani d 0.43 4
Sb Sb40 0.0989(2) 0.52584(6) 0.04232(4) 0.0201(5) Uani d 0.87 4
As As40 0.0989(2) 0.52584(6) 0.04232(4) 0.0201(5) Uani d 0.13 4
Sb Sb41 0.5784(2) 0.66010(6) 0.04420(4) 0.0215(5) Uani d 1 4
As As42 0.1522(3) 0.66143(8) 0.02030(5) 0.0173(6) Uani d 1 4
As As43 0.9503(3) 0.75165(9) 0.06151(6) 0.0176(6) Uani d 1 4
Pb Pb44a 0.6387(4) 0.74091(15) 0.12709(9) 0.0228(7) Uani d 0.75 4
Sb Sb44b 0.650(3) 0.7466(8) 0.1205(5) 0.034(4) Uani d 0.25 4
Ag Ag45 0.2654(3) 0.70516(13) 0.09631(8) 0.0543(10) Uani d 1 4
Ag Ag46 0.0835(5) 0.71966(9) 0.15450(7) 0.0559(11) Uani d 1 4
Sb Sb47 0.3303(3) 0.83235(8) 0.14525(6) 0.0260(6) Uani d 0.35 4
As As47 0.3303(3) 0.83235(8) 0.14525(6) 0.0260(6) Uani d 0.65 4
As As48 0.8846(3) 0.84764(8) 0.16134(5) 0.0169(6) Uani d 1 4
S S1 0.6128(8) 0.30470(19) 0.14902(13) 0.0185(15) Uani d 1 4
S S2 0.1178(9) 0.3032(2) 0.14703(12) 0.0178(15) Uani d 1 4
S S3 0.6084(8) 0.3777(2) 0.08942(12) 0.0156(14) Uani d 1 4
S S4 0.1212(8) 0.37573(19) 0.08806(12) 0.0159(14) Uani d 1 4
S S5 0.6167(8) 0.4229(2) 0.15998(13) 0.0174(15) Uani d 1 4
S S6 0.1232(9) 0.42371(19) 0.15807(12) 0.0172(15) Uani d 1 4
S S7 0.6268(8) 0.3412(2) 0.23469(12) 0.0174(14) Uani d 1 4
S S8 0.1314(8) 0.3382(2) 0.23789(13) 0.0177(15) Uani d 1 4
S S9 0.6118(8) 0.23581(19) 0.06312(13) 0.0172(15) Uani d 1 4
S S10 0.1119(7) 0.2392(2) 0.06355(13) 0.0170(15) Uani d 1 4
S S11 0.6102(8) 0.5196(2) 0.09193(12) 0.0164(14) Uani d 1 4
S S12 0.1065(8) 0.5302(2) 0.09812(13) 0.0176(15) Uani d 1 4
S S13 0.4124(8) 0.5310(2) 0.16301(14) 0.0203(17) Uani d 1 4
S S14 0.8350(8) 0.5246(2) 0.16117(14) 0.0184(16) Uani d 1 4
S S15 0.3397(8) 0.4508(2) 0.22736(15) 0.0179(16) Uani d 1 4
S S16 0.9195(7) 0.4492(2) 0.22794(13) 0.0164(15) Uani d 1 4
S S17 0.5801(8) 0.8792(2) 0.20257(14) 0.0201(17) Uani d 1 4
S S18 0.1613(8) 0.8827(2) 0.20223(13) 0.0179(16) Uani d 1 4
S S19 0.3391(7) 0.2442(2) 0.20238(13) 0.0188(16) Uani d 1 4
S S20 0.9211(8) 0.2497(2) 0.20391(14) 0.0198(16) Uani d 1 4
S S21 0.4117(8) 0.1926(2) 0.12933(14) 0.0201(17) Uani d 1 4
S S22 0.8298(8) 0.1955(2) 0.12646(14) 0.0204(17) Uani d 1 4
S S23 0.3354(7) 0.1299(2) 0.05158(14) 0.0184(16) Uani d 1 4
S S24 0.8962(8) 0.1267(2) 0.05336(13) 0.0174(15) Uani d 1 4
S S25 0.6067(8) 0.9543(2) 0.02238(13) 0.0210(16) Uani d 1 4
S S26 0.1601(8) 0.9522(2) 0.02319(14) 0.0204(17) Uani d 1 4
S S27 0.6556(8) 0.0338(2) 0.10331(15) 0.0230(18) Uani d 1 4
S S28 0.1024(9) 0.0356(2) 0.10293(14) 0.0207(17) Uani d 1 4
S S29 0.5970(8) 0.1057(2) 0.18492(14) 0.0204(16) Uani d 1 4
S S30 0.1581(8) 0.1115(2) 0.18398(15) 0.0217(17) Uani d 1 4
S S31 0.3492(9) 0.6990(2) 0.24609(15) 0.0242(18) Uani d 1 4
S S32 0.9218(8) 0.6860(2) 0.23571(14) 0.0208(17) Uani d 1 4
S S33 0.6860(9) 0.6526(2) 0.17319(17) 0.029(2) Uani d 1 4
S S34 0.0939(9) 0.6303(3) 0.16317(16) 0.030(2) Uani d 1 4
S S35 0.5988(9) 0.5746(3) 0.24488(15) 0.0267(19) Uani d 1 4
S S36 0.1625(8) 0.5719(2) 0.24762(14) 0.0204(17) Uani d 1 4
S S37 0.6358(8) 0.4985(2) 0.32563(14) 0.0190(15) Uani d 1 4
S S38 0.1140(9) 0.4981(2) 0.32276(14) 0.0199(16) Uani d 1 4
S S39 0.3796(8) 0.9258(2) 0.09634(13) 0.0171(14) Uani d 1 4
S S40 0.8829(9) 0.9279(2) 0.09136(13) 0.0200(16) Uani d 1 4
S S41 0.3884(8) 0.8440(2) 0.01412(13) 0.0190(15) Uani d 1 4
S S42 0.8890(8) 0.84341(19) 0.01686(13) 0.0162(14) Uani d 1 4
S S43 0.3975(8) 0.3338(2) 0.02800(13) 0.0176(15) Uani d 1 4
S S44 0.8137(8) 0.3337(2) 0.03128(14) 0.0202(17) Uani d 1 4
S S45 0.3230(8) 0.4604(2) 0.03968(15) 0.0202(17) Uani d 1 4
S S46 0.9069(8) 0.4616(2) 0.03874(15) 0.0190(16) Uani d 1 4
S S47 0.4112(8) 0.5896(2) 0.03314(15) 0.0231(18) Uani d 1 4
S S48 0.8246(8) 0.5900(2) 0.04252(15) 0.0216(17) Uani d 1 4
S S49 0.3297(7) 0.7174(2) 0.03390(13) 0.0188(16) Uani d 1 4
S S50 0.9310(7) 0.7104(2) 0.01616(14) 0.0180(15) Uani d 1 4
S S51 0.6874(8) 0.7623(2) 0.06275(14) 0.0198(16) Uani d 1 4
S S52 0.3758(9) 0.7929(2) 0.09786(12) 0.0218(16) Uani d 1 4
S S53 0.6749(8) 0.8420(2) 0.13026(13) 0.0186(16) Uani d 1 4
S S54 1.0593(8) 0.8227(3) 0.12564(15) 0.0236(18) Uani d 1 4
S S55 0.3550(9) 0.7631(2) 0.17457(15) 0.0255(18) Uani d 1 4
S S56 0.8673(8) 0.7755(2) 0.18359(12) 0.0187(15) Uani d 1 4
S S57 0.5126(8) 0.6530(2) 0.10049(14) 0.0219(17) Uani d 1 4
S S58 0.9728(9) 0.6938(3) 0.09658(17) 0.030(2) Uani d 1 4
loop_
_atom_type_symbol
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Pb -3.394 10.111 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Sb -0.587 1.546 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
As 0.050 2.006 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Ag -0.897 1.102 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
Cu 0.320 1.265 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
S 0.125 0.123 'International Tables Vol C tables 4.2.6.8 and 6.1.1.1'
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Pb1 S1 . 3.138(6)
Pb1 S2 . 3.236(6)
Pb1 S5 . 2.974(6)
Pb1 S6 . 2.998(6)
Pb1 S7 . 3.026(6)
Pb1 S8 . 3.005(6)
Pb1 S15 . 3.012(6)
Pb1 S19 . 3.359(7)
Pb2 S1 . 3.269(6)
Pb2 S2 1_655 3.234(6)
Pb2 S5 . 3.009(6)
Pb2 S6 1_655 3.002(6)
Pb2 S7 . 2.952(6)
Pb2 S8 1_655 3.122(6)
Pb2 S16 . 2.953(6)
Pb2 S20 . 3.282(7)
Pb3 S1 . 3.149(7)
Pb3 S2 . 3.061(6)
Pb3 S3 . 3.006(6)
Pb3 S4 . 2.960(6)
Pb3 S9 . 3.091(6)
Pb3 S10 . 3.051(6)
Pb3 S21 . 3.367(6)
Pb3 S43 . 3.124(6)
Pb4 S1 . 2.963(7)
Pb4 S2 1_655 2.943(7)
Pb4 S3 . 3.241(6)
Pb4 S4 1_655 3.244(6)
Pb4 S9 . 3.130(6)
Pb4 S10 1_655 3.070(6)
Pb4 S22 . 2.931(6)
Pb4 S44 . 3.327(7)
Pb5 S3 . 3.085(6)
Pb5 S4 . 3.053(6)
Pb5 S5 . 3.241(6)
Pb5 S6 . 3.028(6)
Pb5 S11 . 2.933(6)
Pb5 S12 . 3.064(6)
Pb5 S13 . 3.277(7)
Pb5 S45 . 3.052(7)
Pb6 S3 . 3.069(6)
Pb6 S4 1_655 3.236(6)
Pb6 S5 . 3.096(6)
Pb6 S6 1_655 3.208(6)
Pb6 S11 . 2.887(6)
Pb6 S12 1_655 3.073(6)
Pb6 S14 . 3.043(6)
Pb6 S46 . 3.144(7)
Ag7 S11 . 2.985(7)
Ag7 S12 . 2.469(7)
Ag7 S13 . 2.973(7)
Ag7 S34 . 3.477(8)
Ag7 S47 . 3.267(8)
Ag7 S57 . 2.447(7)
Pb8 S11 . 3.010(6)
Pb8 S12 1_655 3.180(6)
Pb8 S14 . 2.877(6)
Pb8 S33 . 3.137(8)
Pb8 S34 1_655 3.233(8)
Pb8 S48 . 3.226(7)
Pb8 S57 . 3.059(7)
Pb8 S58 . 3.072(8)
As9 S5 . 2.282(6)
As9 S13 . 2.301(7)
As9 S14 . 2.277(7)
As9 S15 . 3.202(7)
As9 S16 . 3.324(7)
As9 S35 . 3.434(8)
Sb10 S6 . 2.435(6)
Sb10 S13 . 2.927(7)
Sb10 S14 1_455 3.008(7)
Sb10 S15 . 2.566(7)
Sb10 S16 1_455 2.618(6)
Sb10 S36 . 3.298(7)
Sb11 S7 2_655 2.328(6)
Sb11 S15 2_655 3.240(7)
Sb11 S16 2_655 3.232(6)
Sb11 S17 . 2.310(7)
Sb11 S18 . 2.312(7)
Sb11 S37 2_655 3.619(6)
As11 S7 2_655 2.328(6)
As11 S15 2_655 3.240(7)
As11 S16 2_655 3.232(6)
As11 S17 . 2.310(7)
As11 S18 . 2.312(7)
As11 S37 2_655 3.619(6)
Sb12 S8 2_655 2.415(6)
Sb12 S15 2_655 2.544(7)
Sb12 S16 2_755 2.559(6)
Sb12 S17 . 3.008(7)
Sb12 S18 1_655 3.038(7)
Sb12 S38 2_655 3.501(6)
As12 S8 2_655 2.415(6)
As12 S15 2_655 2.544(7)
As12 S16 2_755 2.559(6)
As12 S17 . 3.008(7)
As12 S18 1_655 3.038(7)
As12 S38 2_655 3.501(6)
Pb13 S7 2_655 3.040(6)
Pb13 S8 2_655 3.018(6)
Pb13 S17 . 2.779(7)
Pb13 S19 2_655 3.382(6)
Pb13 S31 . 3.431(7)
Pb13 S55 . 3.210(7)
Pb13 S56 . 2.859(6)
Pb14 S7 2_655 3.075(6)
Pb14 S8 2_555 3.084(6)
Pb14 S18 . 2.971(6)
Pb14 S20 2_655 3.208(6)
Pb14 S31 . 3.116(7)
Pb14 S32 1_455 3.286(6)
Pb14 S55 . 3.027(7)
Pb14 S56 1_455 2.942(6)
Sb15 S1 . 2.407(6)
Sb15 S19 . 2.626(6)
Sb15 S20 . 3.206(7)
Sb15 S21 . 2.514(7)
Sb15 S22 . 2.868(7)
Sb15 S29 . 3.406(6)
Sb15 S31 2_645 3.796(7)
As15 S1 . 2.407(6)
As15 S19 . 2.626(6)
As15 S20 . 3.206(7)
As15 S21 . 2.514(7)
As15 S22 . 2.868(7)
As15 S29 . 3.406(6)
As15 S31 2_645 3.796(7)
As16 S2 . 2.249(6)
As16 S19 . 2.314(7)
As16 S20 1_455 2.291(7)
As16 S21 . 3.218(7)
As16 S22 1_455 3.297(7)
As16 S30 . 3.427(7)
Sb17 S9 . 2.353(6)
Sb17 S21 . 2.424(7)
Sb17 S22 . 2.385(7)
Sb17 S23 . 3.220(7)
Sb17 S24 . 3.153(7)
Sb17 S27 . 3.771(7)
As17 S9 . 2.353(6)
As17 S21 . 2.424(7)
As17 S22 . 2.385(7)
As17 S23 . 3.220(7)
As17 S24 . 3.153(7)
As17 S27 . 3.771(7)
Sb18 S10 . 2.485(6)
Sb18 S21 . 3.245(7)
Sb18 S22 1_455 3.108(7)
Sb18 S23 . 2.567(6)
Sb18 S24 1_455 2.528(6)
Sb18 S28 . 3.509(6)
Sb19 S23 . 3.398(6)
Sb19 S24 . 3.404(6)
Sb19 S25 1_545 3.437(6)
Sb19 S25 3_665 2.441(6)
Sb19 S26 3_665 2.446(7)
Sb19 S41 3_665 2.458(6)
As19 S23 . 3.398(6)
As19 S24 . 3.404(6)
As19 S25 1_545 3.437(6)
As19 S25 3_665 2.441(6)
As19 S26 3_665 2.446(7)
As19 S41 3_665 2.458(6)
Pb20 S23 . 2.799(6)
Pb20 S24 1_455 2.787(6)
Pb20 S25 3_665 3.031(6)
Pb20 S26 1_545 3.637(7)
Pb20 S26 3_565 3.009(7)
Pb20 S42 3_665 2.543(6)
Sb20 S23 . 2.799(6)
Sb20 S24 1_455 2.787(6)
Sb20 S25 3_665 3.031(6)
Sb20 S26 1_545 3.637(7)
Sb20 S26 3_565 3.009(7)
Sb20 S42 3_665 2.543(6)
Pb21 S23 . 3.554(6)
Pb21 S25 1_545 2.963(6)
Pb21 S26 1_545 2.998(7)
Pb21 S27 . 2.961(7)
Pb21 S28 . 3.050(7)
Pb21 S39 1_545 2.636(6)
Sb22 S24 . 3.412(6)
Sb22 S25 1_545 3.468(6)
Sb22 S26 1_645 3.539(7)
Sb22 S27 . 2.440(7)
Sb22 S28 1_655 2.471(7)
Sb22 S40 1_545 2.407(6)
As22 S24 . 3.412(6)
As22 S25 1_545 3.468(6)
As22 S26 1_645 3.539(7)
As22 S27 . 2.440(7)
As22 S28 1_655 2.471(7)
As22 S40 1_545 2.407(6)
Sb23 S21 . 3.343(7)
Sb23 S27 . 3.474(7)
Sb23 S28 . 3.367(7)
Sb23 S29 . 2.484(7)
Sb23 S30 . 2.418(7)
Sb23 S37 2_645 2.456(6)
As23 S21 . 3.343(7)
As23 S27 . 3.474(7)
As23 S28 . 3.367(7)
As23 S29 . 2.484(7)
As23 S30 . 2.418(7)
As23 S37 2_645 2.456(6)
Pb24 S22 . 3.333(6)
Pb24 S27 . 3.021(7)
Pb24 S28 1_655 2.966(7)
Pb24 S29 . 2.995(7)
Pb24 S30 1_655 2.944(7)
Pb24 S38 2_645 2.690(6)
Ag25 S19 . 2.677(7)
Ag25 S29 . 3.271(7)
Ag25 S30 . 2.976(7)
Ag25 S31 2_645 2.905(8)
Ag25 S32 2_645 2.809(7)
Ag25 S35 2_645 2.640(8)
Sb26 S20 . 2.558(7)
Sb26 S29 . 3.397(7)
Sb26 S30 1_655 3.432(7)
Sb26 S31 2_645 2.366(7)
Sb26 S32 2_745 2.465(7)
Sb26 S36 2_645 2.897(7)
As26 S20 . 2.558(7)
As26 S29 . 3.397(7)
As26 S30 1_655 3.432(7)
As26 S31 2_645 2.366(7)
As26 S32 2_745 2.465(7)
As26 S36 2_645 2.897(7)
Pb27 S13 . 2.921(7)
Pb27 S31 . 3.072(7)
Pb27 S33 . 2.846(8)
Pb27 S34 . 3.021(8)
Pb27 S35 . 2.893(7)
Pb27 S36 . 3.171(7)
Sb28 S14 . 3.090(6)
Sb28 S32 . 2.537(7)
Sb28 S33 . 2.373(8)
Sb28 S34 1_655 2.378(8)
Sb28 S35 . 3.350(7)
Sb28 S36 1_655 3.284(7)
As28 S14 . 3.090(6)
As28 S32 . 2.537(7)
As28 S33 . 2.373(8)
As28 S34 1_655 2.378(8)
As28 S35 . 3.350(7)
As28 S36 1_655 3.284(7)
Sb29 S15 2_645 3.244(6)
Sb29 S29 . 2.578(6)
Sb29 S35 2_645 2.459(7)
Sb29 S36 2_645 2.462(7)
Sb29 S37 2_645 3.208(7)
Sb29 S38 2_645 3.277(7)
Pb30 S16 2_645 3.136(6)
Pb30 S30 . 2.873(6)
Pb30 S35 2_645 3.057(7)
Pb30 S36 2_545 2.925(7)
Pb30 S37 2_645 3.096(7)
Pb30 S38 2_545 2.915(7)
Pb31 S17 . 3.323(6)
Pb31 S27 1_565 2.928(7)
Pb31 S37 2_655 2.967(6)
Pb31 S38 2_655 3.013(7)
Pb31 S39 . 2.949(6)
Pb31 S40 . 3.143(7)
Pb31 S53 . 3.055(6)
Pb32 S18 . 3.245(6)
Pb32 S28 1_565 2.956(6)
Pb32 S37 2_655 2.827(6)
Pb32 S38 2_555 2.808(7)
Pb32 S39 . 3.066(6)
Pb32 S40 1_455 3.067(7)
Pb32 S54 1_455 3.681(7)
Pb33a S25 . 3.068(6)
Pb33a S39 . 2.981(6)
Pb33a S40 . 3.000(7)
Pb33a S41 . 3.040(6)
Pb33a S42 . 3.117(6)
Pb33a S51 . 2.973(6)
Pb33a S52 . 3.283(7)
Pb33a S53 . 2.999(6)
Pb34a S26 . 2.868(6)
Pb34a S39 . 2.891(6)
Pb34a S40 1_455 2.983(7)
Pb34a S41 . 3.060(6)
Pb34a S42 1_455 3.056(6)
Pb34a S52 . 3.296(6)
Pb34a S54 1_455 3.142(7)
Pb35 S9 . 3.055(6)
Pb35 S10 . 3.041(6)
Pb35 S23 . 2.815(6)
Pb35 S41 3_665 2.958(7)
Pb35 S42 3_665 2.967(6)
Pb35 S43 . 3.439(6)
Pb35 S50 3_665 3.524(6)
Pb35 S51 3_665 3.524(7)
Pb36 S9 . 2.954(6)
Pb36 S10 1_655 2.994(6)
Pb36 S24 . 2.894(6)
Pb36 S41 3_665 2.993(7)
Pb36 S42 3_765 3.036(6)
Pb36 S44 . 3.440(7)
Pb36 S49 3_665 3.392(6)
Pb36 S50 3_765 3.132(6)
As37 S3 . 2.264(6)
As37 S43 . 2.291(7)
As37 S44 . 2.354(7)
As37 S45 . 3.100(7)
As37 S46 . 3.329(7)
As37 S47 3_665 3.200(7)
Sb37 S3 . 2.264(6)
Sb37 S43 . 2.291(7)
Sb37 S44 . 2.354(7)
Sb37 S45 . 3.100(7)
Sb37 S46 . 3.329(7)
Sb37 S47 3_665 3.200(7)
Sb38 S4 . 2.418(6)
Sb38 S43 . 2.736(6)
Sb38 S44 1_455 3.179(7)
Sb38 S45 . 2.472(7)
Sb38 S46 1_455 2.752(6)
Sb38 S48 3_665 3.411(7)
Sb38 S50 3_665 3.664(6)
As38 S4 . 2.418(6)
As38 S43 . 2.736(6)
As38 S44 1_455 3.179(7)
As38 S45 . 2.472(7)
As38 S46 1_455 2.752(6)
As38 S48 3_665 3.411(7)
As38 S50 3_665 3.664(6)
Sb39 S11 . 2.399(6)
Sb39 S45 . 3.210(7)
Sb39 S45 3_665 3.431(7)
Sb39 S46 . 2.965(7)
Sb39 S47 . 2.535(7)
Sb39 S48 . 2.379(7)
As39 S11 . 2.399(6)
As39 S45 . 3.210(7)
As39 S45 3_665 3.431(7)
As39 S46 . 2.965(7)
As39 S47 . 2.535(7)
As39 S48 . 2.379(7)
Sb40 S12 . 2.452(6)
Sb40 S45 . 2.626(7)
Sb40 S46 1_455 2.418(6)
Sb40 S46 3_665 3.575(7)
Sb40 S47 . 3.196(7)
Sb40 S48 1_455 2.919(7)
As40 S12 . 2.452(6)
As40 S45 . 2.626(7)
As40 S46 1_455 2.418(6)
As40 S46 3_665 3.575(7)
As40 S47 . 3.196(7)
As40 S48 1_455 2.919(7)
Sb41 S43 3_665 3.179(6)
Sb41 S47 . 2.468(7)
Sb41 S48 . 2.849(7)
Sb41 S49 . 2.671(6)
Sb41 S50 . 3.500(6)
Sb41 S51 . 3.109(6)
Sb41 S57 . 2.538(7)
As42 S44 3_665 2.286(7)
As42 S47 . 3.014(7)
As42 S48 1_455 3.535(7)
As42 S49 . 2.242(7)
As42 S50 1_455 2.315(7)
As42 S58 1_455 3.779(8)
As43 S42 . 3.269(6)
As43 S49 1_655 3.539(7)
As43 S50 . 2.306(7)
As43 S51 . 2.228(7)
As43 S54 . 3.565(7)
As43 S58 . 2.241(8)
Pb44a S33 . 3.216(8)
Pb44a S51 . 2.915(7)
Pb44a S52 . 2.939(8)
Pb44a S53 . 2.845(7)
Pb44a S55 . 3.224(8)
Pb44a S56 . 3.283(7)
Pb44a S57 . 2.920(8)
Pb44a S58 . 3.374(9)
Sb44b S33 . 3.51(2)
Sb44b S51 . 2.59(2)
Sb44b S52 . 2.82(3)
Sb44b S53 . 2.71(2)
Sb44b S55 . 3.46(2)
Sb44b S56 . 3.42(2)
Sb44b S57 . 2.99(2)
Sb44b S58 . 3.26(3)
Ag45 S49 . 2.812(7)
Ag45 S52 . 2.624(7)
Ag45 S57 . 2.543(7)
Ag45 S58 1_455 2.478(8)
Ag46 S34 . 2.527(8)
Ag46 S54 1_455 3.154(8)
Ag46 S55 . 2.729(8)
Ag46 S56 1_455 2.713(7)
Ag46 S58 1_455 2.802(8)
Sb47 S17 . 3.528(7)
Sb47 S18 . 3.200(7)
Sb47 S39 . 3.405(6)
Sb47 S52 . 2.384(6)
Sb47 S53 . 2.979(7)
Sb47 S54 1_455 2.449(7)
Sb47 S55 . 2.333(7)
As47 S17 . 3.528(7)
As47 S18 . 3.200(7)
As47 S39 . 3.405(6)
As47 S52 . 2.384(6)
As47 S53 . 2.979(7)
As47 S54 1_455 2.449(7)
As47 S55 . 2.333(7)
As48 S17 . 3.253(7)
As48 S18 1_655 3.096(7)
As48 S53 . 2.234(7)
As48 S54 . 2.255(7)
As48 S56 . 2.245(6)
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 AMCSD 0019483
