#------------------------------------------------------------------------------
#$Date: 2016-02-20 02:53:41 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176768 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/57/2105768.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2105768
loop_
_publ_author_name
'Hau, Sam C. K.'
'Tam, Dennis Y. S.'
'Mak, Thomas C. W.'
_publ_section_title
;
 Organosilver(I) framework assembly with trifluoroacetate and
 enediyne-functionalized alicycles
;
_journal_coeditor_code           BI5014
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              37
_journal_page_last               46
_journal_paper_doi               10.1107/S2052520614000171
_journal_volume                  70
_journal_year                    2014
_chemical_formula_moiety
;
 7(Ag +), (C13 H14 2-), 5(C2 F3 O2 -), 4(C2 H6 S O)
;
_chemical_formula_sum            'C31 H38 Ag7 F15 O14 S4'
_chemical_formula_weight         1802.94
_space_group_crystal_system      triclinic
_space_group_IT_number           1
_space_group_name_Hall           'P 1'
_space_group_name_H-M_alt        'P 1'
_symmetry_space_group_name_Hall  'P 1'
_symmetry_space_group_name_H-M   'P 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-2013
_cell_angle_alpha                110.194(2)
_cell_angle_beta                 106.492(2)
_cell_angle_gamma                104.003(2)
_cell_formula_units_Z            2
_cell_length_a                   13.4350(15)
_cell_length_b                   13.8806(15)
_cell_length_c                   16.3609(18)
_cell_measurement_temperature    173(2)
_cell_volume                     2542.2(5)
_computing_cell_refinement       'SAINT (Bruker, 2003)'
_computing_data_collection       'APEX2 (Bruker, 2003)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2009)'
_computing_publication_material  SHELXL-2013
_computing_structure_refinement  'SHELXL-2013 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.990
_diffrn_measured_fraction_theta_max 0.990
_diffrn_measurement_device_type  'Bruker APEX-II CCD diffractometer'
_diffrn_measurement_method       'φ and ω scan'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0753
_diffrn_reflns_limit_h_max       16
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -16
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            31854
_diffrn_reflns_theta_full        25.242
_diffrn_reflns_theta_max         25.246
_diffrn_reflns_theta_min         1.449
_exptl_absorpt_coefficient_mu    2.915
_exptl_absorpt_correction_T_max  0.3885
_exptl_absorpt_correction_T_min  0.3235
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'SADABS (Bruker, 2003)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.355
_exptl_crystal_description       block
_exptl_crystal_F_000             1728
_exptl_crystal_size_max          0.500
_exptl_crystal_size_mid          0.400
_exptl_crystal_size_min          0.400
_refine_diff_density_max         3.888
_refine_diff_density_min         -1.655
_refine_ls_abs_structure_details
;
 Refined as an inversion twin.
;
_refine_ls_abs_structure_Flack   0.71(8)
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.050
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     1276
_refine_ls_number_reflns         16780
_refine_ls_number_restraints     615
_refine_ls_restrained_S_all      1.043
_refine_ls_R_factor_all          0.0902
_refine_ls_R_factor_gt           0.0865
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1443P)²+44.0080P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2315
_refine_ls_wR_factor_ref         0.2351
_reflns_number_gt                15708
_reflns_number_total             16780
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            bi5014sup1.cif
_cod_data_source_block           IV
_cod_database_code               2105768
#BEGIN Tags that were not found in dictionaries:
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_shelx_estimated_absorpt_t_min   0.323
_shelx_estimated_absorpt_t_max   0.388
#END Tags that were not found in dictionaries
loop_
_space_group_symop_operation_xyz
'x, y, z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_occupancy
Ag Ag1 -0.38356(18) -1.04880(17) -0.29993(16) 0.0296(5) Uani d 1
Ag Ag2 -0.39957(15) -0.95877(15) -0.43389(14) 0.0227(4) Uani d 1
Ag Ag3 -0.18377(17) -0.97454(18) -0.33388(18) 0.0345(5) Uani d 1
Ag Ag4 -0.2679(3) -0.8511(2) -0.11866(19) 0.0525(8) Uani d 1
Ag Ag5 0.01505(17) -0.74041(16) 0.06564(14) 0.0246(4) Uani d 1
Ag Ag6 0.09451(18) -0.73854(17) -0.09833(15) 0.0295(5) Uani d 1
Ag Ag7 0.17573(17) -0.53556(16) 0.09545(14) 0.0251(4) Uani d 1
Ag Ag8 -0.05579(19) -0.55442(18) 0.10487(15) 0.0308(5) Uani d 1
Ag Ag9 0.09364(17) -0.34284(16) 0.30561(15) 0.0267(4) Uani d 1
Ag Ag10 0.16204(17) -0.53232(16) 0.26833(14) 0.0243(4) Uani d 1
Ag Ag11 0.39091(17) -0.42528(19) 0.27721(16) 0.0332(5) Uani d 1
Ag Ag12 0.38647(17) -0.06238(17) 0.58175(15) 0.0270(5) Uani d 1
Ag Ag13 0.4225(2) -0.26637(17) 0.53787(16) 0.0313(5) Uani d 1
Ag Ag14 0.61891(17) -0.18002(17) 0.50427(15) 0.0272(5) Uani d 1
C C1 -0.282(2) -0.882(2) -0.2728(19) 0.023(5) Uani d 1
C C2 -0.213(2) -0.782(2) -0.2325(16) 0.017(5) Uani d 1
C C3 -0.135(2) -0.6717(19) -0.1801(17) 0.018(5) Uani d 1
C C4 -0.061(2) -0.652(2) -0.092(2) 0.023(5) Uani d 1
C C5 0.001(2) -0.636(2) -0.003(2) 0.026(5) Uani d 1
C C6 -0.134(2) -0.587(2) -0.212(2) 0.027(6) Uani d 1
C C7 -0.053(2) -0.470(2) -0.143(2) 0.030(6) Uani d 1
H H7A -0.0947 -0.4300 -0.1140 0.035 Uiso calc 1
H H7B 0.0041 -0.4740 -0.0918 0.035 Uiso calc 1
C C8 0.007(3) -0.404(3) -0.180(2) 0.042(7) Uani d 1
H H8A 0.0449 -0.3258 -0.1305 0.050 Uiso calc 1
H H8B -0.0485 -0.4058 -0.2361 0.050 Uiso calc 1
C C9 0.095(4) -0.447(4) -0.209(4) 0.071(12) Uani d 1
H H9A 0.1327 -0.3977 -0.2316 0.085 Uiso calc 1
H H9B 0.1533 -0.4371 -0.1499 0.085 Uiso calc 1
C C10 0.058(4) -0.566(4) -0.283(3) 0.058(10) Uani d 1
H H10A 0.0407 -0.6170 -0.2547 0.070 Uiso calc 1
H H10B 0.1194 -0.5747 -0.3027 0.070 Uiso calc 1
C C11 -0.050(4) -0.595(4) -0.373(3) 0.064(11) Uani d 1
H H11A -0.0561 -0.5247 -0.3713 0.077 Uiso calc 1
H H11B -0.0390 -0.6331 -0.4308 0.077 Uiso calc 1
C C12 -0.152(4) -0.662(4) -0.379(3) 0.064(11) Uani d 1
H H12A -0.1422 -0.7286 -0.3743 0.077 Uiso calc 1
H H12B -0.2095 -0.6876 -0.4434 0.077 Uiso calc 1
C C13 -0.202(3) -0.614(3) -0.307(3) 0.050(9) Uani d 1
H H13A -0.2115 -0.5467 -0.3095 0.060 Uiso calc 1
H H13B -0.2766 -0.6691 -0.3258 0.060 Uiso calc 1
C C14 0.224(2) -0.395(2) 0.2382(18) 0.021(5) Uani d 1
C C15 0.265(2) -0.292(2) 0.270(2) 0.025(5) Uani d 1
C C16 0.326(2) -0.1780(18) 0.3168(16) 0.014(4) Uani d 1
C C17 0.408(3) -0.143(2) 0.411(2) 0.032(6) Uani d 1
C C18 0.465(2) -0.146(2) 0.4811(19) 0.021(5) Uani d 1
C C19 0.316(3) -0.104(3) 0.280(2) 0.032(6) Uani d 1
C C20 0.373(3) 0.015(3) 0.331(2) 0.039(7) Uani d 1
H H20A 0.4403 0.0311 0.3864 0.046 Uiso calc 1
H H20B 0.3231 0.0450 0.3561 0.046 Uiso calc 1
C C21 0.413(3) 0.081(3) 0.279(3) 0.045(8) Uani d 1
H H21A 0.4552 0.1602 0.3257 0.053 Uiso calc 1
H H21B 0.3465 0.0763 0.2297 0.053 Uiso calc 1
C C22 0.490(4) 0.035(4) 0.232(4) 0.072(12) Uani d 1
H H22A 0.5093 0.0810 0.1999 0.086 Uiso calc 1
H H22B 0.5603 0.0549 0.2858 0.086 Uiso calc 1
C C23 0.464(5) -0.080(5) 0.164(4) 0.076(13) Uani d 1
H H23A 0.4721 -0.1258 0.1985 0.091 Uiso calc 1
H H23B 0.5174 -0.0804 0.1329 0.091 Uiso calc 1
C C24 0.347(4) -0.130(4) 0.090(3) 0.065(11) Uani d 1
H H24A 0.3501 -0.1700 0.0278 0.078 Uiso calc 1
H H24B 0.3255 -0.0673 0.0864 0.078 Uiso calc 1
C C25 0.246(4) -0.212(4) 0.096(3) 0.067(11) Uani d 1
H H25A 0.1786 -0.2436 0.0362 0.080 Uiso calc 1
H H25B 0.2665 -0.2738 0.1022 0.080 Uiso calc 1
C C26 0.221(3) -0.155(3) 0.177(2) 0.042(7) Uani d 1
H H26A 0.1547 -0.2086 0.1734 0.050 Uiso calc 1
H H26B 0.2004 -0.0946 0.1682 0.050 Uiso calc 1
S S1 0.0743(5) -0.9081(5) -0.3241(5) 0.0257(13) Uani d 1
O O21 0.0129(14) -0.8547(16) -0.2695(13) 0.027(4) Uani d 1
C C47 0.163(3) -0.801(3) -0.338(3) 0.040(7) Uani d 1
H H47A 0.1169 -0.7801 -0.3821 0.061 Uiso calc 1
H H47B 0.2138 -0.8279 -0.3641 0.061 Uiso calc 1
H H47C 0.2073 -0.7359 -0.2763 0.061 Uiso calc 1
C C48 0.172(3) -0.935(4) -0.243(3) 0.046(8) Uani d 1
H H48A 0.1316 -0.9935 -0.2309 0.069 Uiso calc 1
H H48B 0.2164 -0.8673 -0.1834 0.069 Uiso calc 1
H H48C 0.2226 -0.9592 -0.2715 0.069 Uiso calc 1
S S2 -0.2231(7) -0.8851(7) 0.0884(6) 0.0360(17) Uani d 1
O O22 -0.1846(19) -0.875(2) 0.0112(14) 0.038(5) Uani d 1
C C49 -0.337(3) -0.841(3) 0.076(3) 0.042(8) Uani d 1
H H49A -0.3099 -0.7610 0.0979 0.062 Uiso calc 1
H H49B -0.3763 -0.8609 0.1135 0.062 Uiso calc 1
H H49C -0.3895 -0.8784 0.0085 0.062 Uiso calc 1
C C50 -0.298(5) -1.030(4) 0.044(4) 0.073(13) Uani d 1
H H50A -0.2448 -1.0677 0.0466 0.110 Uiso calc 1
H H50B -0.3509 -1.0601 -0.0224 0.110 Uiso calc 1
H H50C -0.3388 -1.0422 0.0825 0.110 Uiso calc 1
S S3 -0.3680(7) -0.6334(7) -0.0477(6) 0.0367(17) Uani d 1
O O23 -0.2800(17) -0.6826(19) -0.0259(15) 0.036(5) Uani d 1
C C51 -0.507(3) -0.758(3) -0.130(2) 0.047(8) Uani d 1
H H51A -0.5314 -0.7945 -0.0940 0.070 Uiso calc 1
H H51B -0.4963 -0.8103 -0.1820 0.070 Uiso calc 1
H H51C -0.5641 -0.7320 -0.1572 0.070 Uiso calc 1
C C52 -0.341(2) -0.581(3) -0.126(2) 0.032(6) Uani d 1
H H52A -0.2707 -0.5159 -0.0910 0.048 Uiso calc 1
H H52B -0.4026 -0.5596 -0.1519 0.048 Uiso calc 1
H H52C -0.3350 -0.6380 -0.1774 0.048 Uiso calc 1
S S4 0.0300(7) -1.0024(6) -0.0916(5) 0.0335(15) Uani d 1
O O24 0.015(2) -0.8956(18) -0.0740(15) 0.040(5) Uani d 1
C C53 0.117(4) -0.989(4) 0.017(3) 0.061(11) Uani d 1
H H53A 0.1929 -0.9371 0.0368 0.092 Uiso calc 1
H H53B 0.1192 -1.0618 0.0094 0.092 Uiso calc 1
H H53C 0.0879 -0.9617 0.0649 0.092 Uiso calc 1
C C54 -0.094(3) -1.099(3) -0.107(3) 0.052(9) Uani d 1
H H54A -0.1544 -1.1168 -0.1669 0.078 Uiso calc 1
H H54B -0.1148 -1.0671 -0.0539 0.078 Uiso calc 1
H H54C -0.0825 -1.1665 -0.1091 0.078 Uiso calc 1
S S5 0.1171(5) -0.0987(5) 0.4906(4) 0.0219(12) Uani d 1
O O25 0.1783(16) -0.1792(15) 0.4562(13) 0.025(4) Uani d 1
C C55 0.109(3) -0.032(3) 0.417(3) 0.044(8) Uani d 1
H H55A 0.1842 0.0188 0.4334 0.066 Uiso calc 1
H H55B 0.0606 0.0098 0.4258 0.066 Uiso calc 1
H H55C 0.0777 -0.0875 0.3503 0.066 Uiso calc 1
C C56 -0.030(2) -0.181(2) 0.441(2) 0.026(6) Uani d 1
H H56A -0.0435 -0.2269 0.4741 0.039 Uiso calc 1
H H56B -0.0554 -0.2289 0.3733 0.039 Uiso calc 1
H H56C -0.0721 -0.1320 0.4496 0.039 Uiso calc 1
S S6 0.1621(6) -0.4651(6) 0.4917(5) 0.0286(14) Uani d 1
O O26 0.2445(18) -0.4207(17) 0.4514(14) 0.035(5) Uani d 1
C C57 0.172(4) -0.345(4) 0.586(3) 0.056(10) Uani d 1
H H57A 0.1363 -0.3030 0.5590 0.084 Uiso calc 1
H H57B 0.2514 -0.2990 0.6267 0.084 Uiso calc 1
H H57C 0.1346 -0.3677 0.6231 0.084 Uiso calc 1
C C58 0.232(3) -0.521(3) 0.561(2) 0.040(7) Uani d 1
H H58A 0.2337 -0.5898 0.5196 0.060 Uiso calc 1
H H58B 0.1919 -0.5353 0.6001 0.060 Uiso calc 1
H H58C 0.3087 -0.4673 0.6032 0.060 Uiso calc 1
S S7 0.5048(7) -0.4923(7) 0.4683(6) 0.0392(18) Uani d 1
O O27 0.4769(18) -0.4092(16) 0.4351(16) 0.035(5) Uani d 1
C C59 0.605(4) -0.530(4) 0.424(4) 0.067(12) Uani d 1
H H59A 0.6776 -0.4676 0.4594 0.100 Uiso calc 1
H H59B 0.5789 -0.5476 0.3563 0.100 Uiso calc 1
H H59C 0.6127 -0.5946 0.4323 0.100 Uiso calc 1
C C60 0.392(3) -0.617(3) 0.391(3) 0.056(10) Uani d 1
H H60A 0.3262 -0.6149 0.4046 0.084 Uiso calc 1
H H60B 0.4112 -0.6780 0.4001 0.084 Uiso calc 1
H H60C 0.3764 -0.6297 0.3253 0.084 Uiso calc 1
S S8 0.6568(8) -0.2760(7) 0.2900(7) 0.045(2) Uani d 1
O O28 0.569(2) -0.282(2) 0.3294(19) 0.053(7) Uani d 1
C C61 0.702(4) -0.394(4) 0.283(4) 0.067(12) Uani d 1
H H61A 0.7491 -0.3807 0.3466 0.101 Uiso calc 1
H H61B 0.7452 -0.4019 0.2429 0.101 Uiso calc 1
H H61C 0.6360 -0.4628 0.2542 0.101 Uiso calc 1
C C62 0.572(4) -0.327(4) 0.161(3) 0.067(12) Uani d 1
H H62A 0.5412 -0.2722 0.1522 0.100 Uiso calc 1
H H62B 0.5100 -0.3974 0.1379 0.100 Uiso calc 1
H H62C 0.6191 -0.3380 0.1259 0.100 Uiso calc 1
O O1 -0.3524(17) -1.1860(17) -0.2667(15) 0.032(4) Uiso d 1
O O2 -0.5322(18) -1.313(2) -0.3373(16) 0.041(6) Uani d 1
C C27 -0.437(2) -1.268(2) -0.2820(19) 0.024(5) Uani d 1
C C28 -0.4005(18) -1.3323(17) -0.2239(17) 0.042(8) Uani d 1
F F1 -0.4853(19) -1.4177(19) -0.243(2) 0.090(10) Uani d 1
F F2 -0.325(2) -1.368(3) -0.243(3) 0.110(12) Uani d 1
F F3 -0.359(3) -1.267(2) -0.1334(17) 0.141(16) Uani d 1
O O3 -0.482(2) -1.022(3) -0.1882(19) 0.070(11) Uani d 1
O O4 -0.6593(19) -1.077(2) -0.2961(17) 0.045(6) Uani d 1
C C29 -0.585(3) -1.063(2) -0.222(2) 0.031(6) Uani d 1
C C30 -0.6359(18) -1.0936(18) -0.1531(16) 0.042(8) Uani d 1
F F4 -0.594(3) -1.159(3) -0.128(3) 0.127(14) Uani d 1
F F5 -0.7440(17) -1.142(2) -0.1946(18) 0.089(9) Uani d 1
F F6 -0.608(2) -1.003(2) -0.0784(18) 0.112(13) Uani d 1
O O5 -0.4731(17) -0.8220(16) -0.4242(15) 0.030(4) Uani d 1
O O6 -0.6226(18) -0.8911(16) -0.3978(16) 0.033(5) Uani d 1
C C31 -0.560(2) -0.820(2) -0.4064(19) 0.022(5) Uani d 1
C C32 -0.5856(13) -0.7147(15) -0.3985(11) 0.029(6) Uani d 1
F F7 -0.5087(14) -0.6424(15) -0.4044(14) 0.050(5) Uani d 1
F F8 -0.6817(14) -0.7421(15) -0.4661(13) 0.058(6) Uani d 1
F F9 -0.5909(17) -0.6673(15) -0.3166(11) 0.053(5) Uani d 1
O O7 -0.3209(17) -0.9409(19) -0.5395(16) 0.035(5) Uani d 1
O O8 -0.203(3) -1.023(3) -0.4960(18) 0.066(9) Uani d 1
C C33 -0.243(3) -0.973(3) -0.541(2) 0.037(7) Uani d 1
C C34 -0.167(2) -0.934(2) -0.588(2) 0.081(14) Uani d 1
F F10 -0.206(3) -0.881(3) -0.632(3) 0.113(12) Uani d 1
F F11 -0.068(3) -0.867(3) -0.522(2) 0.137(15) Uani d 1
F F12 -0.155(3) -1.016(2) -0.648(2) 0.115(12) Uani d 1
O O9 -0.1194(18) -1.109(2) -0.326(2) 0.048(6) Uani d 1
O O10 -0.2549(18) -1.2516(16) -0.4568(15) 0.037(5) Uani d 1
C C35 -0.165(2) -1.206(2) -0.385(2) 0.029(6) Uani d 1
C C36 -0.1062(18) -1.2819(18) -0.3635(15) 0.040(7) Uani d 1
F F13 -0.008(2) -1.231(2) -0.2935(18) 0.109(12) Uani d 1
F F14 -0.097(2) -1.344(2) -0.4391(15) 0.090(10) Uani d 1
F F15 -0.171(3) -1.347(3) -0.342(3) 0.150(18) Uani d 1
O O11 -0.1077(19) -0.6042(17) 0.2100(14) 0.034(5) Uani d 1
O O12 -0.0333(19) -0.4442(18) 0.3394(15) 0.036(5) Uani d 1
C C37 -0.095(2) -0.545(3) 0.289(2) 0.031(6) Uani d 1
C C38 -0.1617(16) -0.6031(17) 0.3361(14) 0.046(8) Uani d 1
F F16 -0.2671(14) -0.625(2) 0.2905(16) 0.076(8) Uani d 1
F F17 -0.148(2) -0.6953(16) 0.3254(18) 0.076(8) Uani d 1
F F18 -0.133(2) -0.5418(18) 0.4256(12) 0.077(8) Uani d 1
O O13 -0.104(2) -0.4182(18) 0.0773(17) 0.049(7) Uani d 1
O O14 -0.025(2) -0.275(2) 0.2222(16) 0.046(6) Uani d 1
C C39 -0.080(3) -0.322(2) 0.137(2) 0.032(6) Uani d 1
C C40 -0.1383(19) -0.2506(19) 0.0960(16) 0.043(8) Uani d 1
F F19 -0.238(2) -0.313(2) 0.0287(17) 0.098(10) Uani d 1
F F20 -0.150(3) -0.173(2) 0.1616(17) 0.112(12) Uani d 1
F F21 -0.077(2) -0.204(3) 0.062(3) 0.129(14) Uani d 1
O O15 0.0417(19) -0.8175(15) 0.1631(15) 0.034(5) Uani d 1
O O16 0.124(2) -0.6664(17) 0.3067(16) 0.042(6) Uani d 1
C C41 0.077(2) -0.769(2) 0.250(2) 0.027(6) Uani d 1
C C42 0.0758(16) -0.8481(16) 0.2994(13) 0.036(7) Uani d 1
F F22 0.094(2) -0.7988(16) 0.3891(12) 0.066(7) Uani d 1
F F23 0.154(2) -0.887(2) 0.295(2) 0.096(10) Uani d 1
F F24 -0.0196(18) -0.9311(17) 0.2564(16) 0.087(9) Uani d 1
O O17 0.256(2) -0.634(2) -0.0957(19) 0.054(7) Uani d 1
O O18 0.2842(17) -0.4720(16) 0.0230(16) 0.035(5) Uani d 1
C C43 0.298(2) -0.536(3) -0.048(2) 0.028(6) Uani d 1
C C44 0.3802(17) -0.4695(16) -0.0800(13) 0.042(8) Uani d 1
F F25 0.4730(15) -0.4860(17) -0.0541(16) 0.067(7) Uani d 1
F F26 0.3384(18) -0.5054(19) -0.1719(11) 0.065(6) Uani d 1
F F27 0.4050(18) -0.3626(14) -0.0412(14) 0.057(6) Uani d 1
O O19 0.260(2) -0.6802(19) 0.098(2) 0.058(8) Uani d 1
O O20 0.4398(17) -0.5637(18) 0.1967(18) 0.045(6) Uani d 1
C C45 0.3612(19) -0.651(2) 0.1285(16) 0.015(5) Uani d 1
C C46 0.4076(16) -0.7424(17) 0.0827(13) 0.038(7) Uani d 1
F F28 0.3365(19) -0.811(2) -0.0039(13) 0.083(8) Uani d 1
F F29 0.5039(17) -0.6974(19) 0.0825(18) 0.076(8) Uani d 1
F F30 0.419(2) -0.799(2) 0.1321(18) 0.088(9) Uani d 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
C1 Ag1 O1 . . 136.7(9)
C1 Ag1 O3 . . 106.5(11)
O1 Ag1 O3 . . 88.1(10)
C1 Ag1 Ag2 . . 53.1(7)
O1 Ag1 Ag2 . . 145.0(6)
O3 Ag1 Ag2 . . 124.1(8)
C1 Ag1 Ag4 . . 52.7(7)
O1 Ag1 Ag4 . . 104.9(5)
O3 Ag1 Ag4 . . 63.1(6)
Ag2 Ag1 Ag4 . . 102.42(9)
C1 Ag1 Ag3 . . 49.8(8)
O1 Ag1 Ag3 . . 98.0(6)
O3 Ag1 Ag3 . . 148.6(6)
Ag2 Ag1 Ag3 . . 62.62(7)
Ag4 Ag1 Ag3 . . 85.68(10)
C1 Ag1 Ag12 . 1_444 98.6(7)
O1 Ag1 Ag12 . 1_444 124.6(5)
O3 Ag1 Ag12 . 1_444 75.4(6)
Ag2 Ag1 Ag12 . 1_444 60.99(7)
Ag4 Ag1 Ag12 . 1_444 112.80(11)
Ag3 Ag1 Ag12 . 1_444 123.12(9)
C1 Ag1 Ag14 . 1_444 97.8(7)
O1 Ag1 Ag14 . 1_444 85.5(6)
O3 Ag1 Ag14 . 1_444 150.5(6)
Ag2 Ag1 Ag14 . 1_444 59.81(7)
Ag4 Ag1 Ag14 . 1_444 146.24(11)
Ag3 Ag1 Ag14 . 1_444 60.86(7)
Ag12 Ag1 Ag14 1_444 1_444 84.79(8)
C1 Ag1 Ag13 . 1_444 141.1(7)
O1 Ag1 Ag13 . 1_444 74.6(5)
O3 Ag1 Ag13 . 1_444 94.8(6)
Ag2 Ag1 Ag13 . 1_444 88.00(8)
Ag4 Ag1 Ag13 . 1_444 157.77(11)
Ag3 Ag1 Ag13 . 1_444 116.52(10)
Ag12 Ag1 Ag13 1_444 1_444 55.31(7)
Ag14 Ag1 Ag13 1_444 1_444 55.76(7)
O7 Ag2 O5 . . 97.3(7)
O7 Ag2 C1 . . 118.5(9)
O5 Ag2 C1 . . 97.5(9)
O7 Ag2 C18 . 1_444 103.5(9)
O5 Ag2 C18 . 1_444 115.3(8)
C1 Ag2 C18 . 1_444 122.3(9)
O7 Ag2 Ag1 . . 139.7(5)
O5 Ag2 Ag1 . . 120.8(5)
C1 Ag2 Ag1 . . 49.0(6)
C18 Ag2 Ag1 1_444 . 73.3(6)
O7 Ag2 Ag14 . 1_444 84.2(6)
O5 Ag2 Ag14 . 1_444 161.1(5)
C1 Ag2 Ag14 . 1_444 98.3(6)
C18 Ag2 Ag14 1_444 1_444 46.6(6)
Ag1 Ag2 Ag14 . 1_444 64.23(7)
O7 Ag2 Ag3 . . 84.0(5)
O5 Ag2 Ag3 . . 137.5(5)
C1 Ag2 Ag3 . . 47.9(7)
C18 Ag2 Ag3 1_444 . 105.4(6)
Ag1 Ag2 Ag3 . . 59.57(7)
Ag14 Ag2 Ag3 1_444 . 61.39(7)
O7 Ag2 Ag12 . 1_444 144.2(5)
O5 Ag2 Ag12 . 1_444 79.8(5)
C1 Ag2 Ag12 . 1_444 97.2(7)
C18 Ag2 Ag12 1_444 1_444 49.3(6)
Ag1 Ag2 Ag12 . 1_444 62.92(7)
Ag14 Ag2 Ag12 1_444 1_444 87.96(7)
Ag3 Ag2 Ag12 . 1_444 122.02(9)
C1 Ag3 O9 . . 139.8(10)
C1 Ag3 O8 . . 121.1(8)
O9 Ag3 O8 . . 93.2(10)
C1 Ag3 O21 . . 111.0(8)
O9 Ag3 O21 . . 85.8(8)
O8 Ag3 O21 . . 92.2(10)
C1 Ag3 Ag1 . . 48.5(6)
O9 Ag3 Ag1 . . 98.4(7)
O8 Ag3 Ag1 . . 118.7(9)
O21 Ag3 Ag1 . . 148.3(5)
C1 Ag3 Ag2 . . 50.5(7)
O9 Ag3 Ag2 . . 137.8(6)
O8 Ag3 Ag2 . . 73.9(6)
O21 Ag3 Ag2 . . 133.6(5)
Ag1 Ag3 Ag2 . . 57.80(7)
C1 Ag3 Ag14 . 1_444 98.3(7)
O9 Ag3 Ag14 . 1_444 79.5(6)
O8 Ag3 Ag14 . 1_444 60.9(9)
O21 Ag3 Ag14 . 1_444 148.0(5)
Ag1 Ag3 Ag14 . 1_444 62.70(7)
Ag2 Ag3 Ag14 . 1_444 59.01(7)
O22 Ag4 C1 . . 144.9(9)
O22 Ag4 O23 . . 93.2(8)
C1 Ag4 O23 . . 116.3(8)
O22 Ag4 C2 . . 139.0(8)
C1 Ag4 C2 . . 29.3(8)
O23 Ag4 C2 . . 94.6(8)
O22 Ag4 Ag1 . . 116.6(6)
C1 Ag4 Ag1 . . 48.2(6)
O23 Ag4 Ag1 . . 143.1(5)
C2 Ag4 Ag1 . . 77.5(5)
C5 Ag5 O15 . . 168.4(10)
C5 Ag5 O24 . . 95.0(9)
O15 Ag5 O24 . . 95.9(7)
C5 Ag5 O22 . . 106.3(9)
O15 Ag5 O22 . . 78.9(7)
O24 Ag5 O22 . . 83.1(8)
C5 Ag5 Ag8 . . 48.8(7)
O15 Ag5 Ag8 . . 121.9(6)
O24 Ag5 Ag8 . . 139.9(5)
O22 Ag5 Ag8 . . 91.0(5)
C5 Ag5 Ag7 . . 48.3(8)
O15 Ag5 Ag7 . . 124.1(6)
O24 Ag5 Ag7 . . 106.6(5)
O22 Ag5 Ag7 . . 152.6(5)
Ag8 Ag5 Ag7 . . 64.83(7)
C5 Ag5 Ag6 . . 53.3(7)
O15 Ag5 Ag6 . . 134.3(6)
O24 Ag5 Ag6 . . 48.3(5)
O22 Ag5 Ag6 . . 115.7(5)
Ag8 Ag5 Ag6 . . 101.77(8)
Ag7 Ag5 Ag6 . . 61.08(7)
C5 Ag5 Ag10 . . 91.7(8)
O15 Ag5 Ag10 . . 77.1(5)
O24 Ag5 Ag10 . . 146.4(6)
O22 Ag5 Ag10 . . 126.3(5)
Ag8 Ag5 Ag10 . . 63.75(7)
Ag7 Ag5 Ag10 . . 56.01(6)
Ag6 Ag5 Ag10 . . 115.45(8)
O17 Ag6 O24 . . 142.5(10)
O17 Ag6 O21 . . 94.6(8)
O24 Ag6 O21 . . 90.3(7)
O17 Ag6 C5 . . 117.1(9)
O24 Ag6 C5 . . 88.6(8)
O21 Ag6 C5 . . 126.3(8)
O17 Ag6 C4 . . 117.5(9)
O24 Ag6 C4 . . 98.6(8)
O21 Ag6 C4 . . 97.6(8)
C5 Ag6 C4 . . 30.2(9)
O17 Ag6 Ag7 . . 80.8(6)
O24 Ag6 Ag7 . . 104.9(5)
O21 Ag6 Ag7 . . 160.6(5)
C5 Ag6 Ag7 . . 44.2(7)
C4 Ag6 Ag7 . . 68.7(6)
O17 Ag6 Ag5 . . 132.1(7)
O24 Ag6 Ag5 . . 52.3(6)
O21 Ag6 Ag5 . . 133.2(5)
C5 Ag6 Ag5 . . 42.1(6)
C4 Ag6 Ag5 . . 66.9(6)
Ag7 Ag6 Ag5 . . 55.40(6)
C5 Ag7 C14 . . 122.3(10)
C5 Ag7 O18 . . 112.7(9)
C14 Ag7 O18 . . 107.7(8)
C5 Ag7 O19 . . 102.9(9)
C14 Ag7 O19 . . 115.6(9)
O18 Ag7 O19 . . 91.6(10)
C5 Ag7 Ag10 . . 99.5(7)
C14 Ag7 Ag10 . . 48.1(7)
O18 Ag7 Ag10 . . 147.7(5)
O19 Ag7 Ag10 . . 84.0(7)
C5 Ag7 Ag5 . . 46.8(7)
C14 Ag7 Ag5 . . 112.3(7)
O18 Ag7 Ag5 . . 139.8(4)
O19 Ag7 Ag5 . . 67.3(7)
Ag10 Ag7 Ag5 . . 66.89(7)
C5 Ag7 Ag11 . . 159.9(7)
C14 Ag7 Ag11 . . 49.1(6)
O18 Ag7 Ag11 . . 87.2(5)
O19 Ag7 Ag11 . . 72.4(6)
Ag10 Ag7 Ag11 . . 60.89(7)
Ag5 Ag7 Ag11 . . 115.66(9)
C5 Ag7 Ag6 . . 54.5(7)
C14 Ag7 Ag6 . . 175.7(7)
O18 Ag7 Ag6 . . 76.6(4)
O19 Ag7 Ag6 . . 64.2(6)
Ag10 Ag7 Ag6 . . 128.24(9)
Ag5 Ag7 Ag6 . . 63.51(7)
Ag11 Ag7 Ag6 . . 132.76(9)
C5 Ag7 Ag8 . . 44.7(7)
C14 Ag7 Ag8 . . 77.9(7)
O18 Ag7 Ag8 . . 139.1(6)
O19 Ag7 Ag8 . . 123.3(8)
Ag10 Ag7 Ag8 . . 64.99(7)
Ag5 Ag7 Ag8 . . 57.37(7)
Ag11 Ag7 Ag8 . . 121.05(9)
Ag6 Ag7 Ag8 . . 98.58(8)
C5 Ag8 O11 . . 131.8(9)
C5 Ag8 O13 . . 108.9(10)
O11 Ag8 O13 . . 117.8(10)
C5 Ag8 Ag5 . . 47.0(7)
O11 Ag8 Ag5 . . 85.4(6)
O13 Ag8 Ag5 . . 155.8(7)
C5 Ag8 Ag7 . . 44.5(8)
O11 Ag8 Ag7 . . 122.4(6)
O13 Ag8 Ag7 . . 109.0(8)
Ag5 Ag8 Ag7 . . 57.81(7)
C5 Ag8 Ag9 . . 127.1(8)
O11 Ag8 Ag9 . . 76.0(5)
O13 Ag8 Ag9 . . 78.2(6)
Ag5 Ag8 Ag9 . . 116.67(9)
Ag7 Ag8 Ag9 . . 82.96(8)
C5 Ag8 Ag10 . . 89.7(8)
O11 Ag8 Ag10 . . 70.5(6)
O13 Ag8 Ag10 . . 129.2(6)
Ag5 Ag8 Ag10 . . 62.54(7)
Ag7 Ag8 Ag10 . . 53.93(6)
Ag9 Ag8 Ag10 . . 54.15(6)
O12 Ag9 O14 . . 98.2(9)
O12 Ag9 O25 . . 97.1(7)
O14 Ag9 O25 . . 96.0(7)
O12 Ag9 C14 . . 129.1(9)
O14 Ag9 C14 . . 115.0(9)
O25 Ag9 C14 . . 115.4(8)
O12 Ag9 C15 . . 156.0(9)
O14 Ag9 C15 . . 102.8(9)
O25 Ag9 C15 . . 92.2(8)
C14 Ag9 C15 . . 29.0(9)
O12 Ag9 Ag10 . . 83.1(6)
O14 Ag9 Ag10 . . 139.6(6)
O25 Ag9 Ag10 . . 124.1(5)
C14 Ag9 Ag10 . . 46.5(6)
C15 Ag9 Ag10 . . 73.4(6)
O12 Ag9 Ag8 . . 77.7(6)
O14 Ag9 Ag8 . . 77.3(6)
O25 Ag9 Ag8 . . 170.7(5)
C14 Ag9 Ag8 . . 73.7(6)
C15 Ag9 Ag8 . . 95.6(6)
Ag10 Ag9 Ag8 . . 63.42(7)
O16 Ag10 C14 . . 172.1(10)
O16 Ag10 O26 . . 80.2(8)
C14 Ag10 O26 . . 97.1(8)
O16 Ag10 Ag7 . . 129.8(6)
C14 Ag10 Ag7 . . 50.7(7)
O26 Ag10 Ag7 . . 145.3(5)
O16 Ag10 Ag9 . . 130.1(7)
C14 Ag10 Ag9 . . 55.2(7)
O26 Ag10 Ag9 . . 74.1(5)
Ag7 Ag10 Ag9 . . 92.26(8)
O16 Ag10 Ag11 . . 122.0(7)
C14 Ag10 Ag11 . . 50.2(7)
O26 Ag10 Ag11 . . 87.7(5)
Ag7 Ag10 Ag11 . . 62.68(7)
Ag9 Ag10 Ag11 . . 99.13(8)
O16 Ag10 Ag5 . . 78.0(6)
C14 Ag10 Ag5 . . 105.3(7)
O26 Ag10 Ag5 . . 157.3(5)
Ag7 Ag10 Ag5 . . 57.10(6)
Ag9 Ag10 Ag5 . . 116.13(8)
Ag11 Ag10 Ag5 . . 109.26(8)
O16 Ag10 Ag8 . . 111.0(7)
C14 Ag10 Ag8 . . 76.5(7)
O26 Ag10 Ag8 . . 131.1(5)
Ag7 Ag10 Ag8 . . 61.09(7)
Ag9 Ag10 Ag8 . . 62.43(7)
Ag11 Ag10 Ag8 . . 119.13(8)
Ag5 Ag10 Ag8 . . 53.71(6)
O20 Ag11 C14 . . 131.0(8)
O20 Ag11 O28 . . 93.8(9)
C14 Ag11 O28 . . 121.9(10)
O20 Ag11 O27 . . 98.4(9)
C14 Ag11 O27 . . 117.6(8)
O28 Ag11 O27 . . 81.5(9)
O20 Ag11 Ag10 . . 107.4(6)
C14 Ag11 Ag10 . . 45.6(6)
O28 Ag11 Ag10 . . 158.2(7)
O27 Ag11 Ag10 . . 90.3(5)
O20 Ag11 Ag7 . . 84.5(6)
C14 Ag11 Ag7 . . 46.9(6)
O28 Ag11 Ag7 . . 132.9(7)
O27 Ag11 Ag7 . . 145.4(5)
Ag10 Ag11 Ag7 . . 56.43(7)
O4 Ag12 O6 1_666 1_666 99.4(9)
O4 Ag12 C18 1_666 . 138.5(9)
O6 Ag12 C18 1_666 . 120.5(8)
O4 Ag12 Ag13 1_666 . 90.5(7)
O6 Ag12 Ag13 1_666 . 169.5(5)
C18 Ag12 Ag13 . . 49.1(6)
O4 Ag12 Ag2 1_666 1_666 134.8(6)
O6 Ag12 Ag2 1_666 1_666 80.7(5)
C18 Ag12 Ag2 . 1_666 51.6(6)
Ag13 Ag12 Ag2 . 1_666 89.80(8)
O4 Ag12 Ag1 1_666 1_666 84.3(6)
O6 Ag12 Ag1 1_666 1_666 114.0(5)
C18 Ag12 Ag1 . 1_666 70.3(6)
Ag13 Ag12 Ag1 . 1_666 63.17(7)
Ag2 Ag12 Ag1 1_666 1_666 56.09(6)
C18 Ag13 O2 . 1_666 148.1(9)
C18 Ag13 O26 . . 119.6(8)
O2 Ag13 O26 1_666 . 91.9(7)
C18 Ag13 O27 . . 95.8(9)
O2 Ag13 O27 1_666 . 94.0(8)
O26 Ag13 O27 . . 80.1(7)
C18 Ag13 Ag12 . . 52.6(7)
O2 Ag13 Ag12 1_666 . 115.3(7)
O26 Ag13 Ag12 . . 109.7(6)
O27 Ag13 Ag12 . . 148.1(5)
C18 Ag13 Ag14 . . 48.5(7)
O2 Ag13 Ag14 1_666 . 111.4(6)
O26 Ag13 Ag14 . . 137.6(5)
O27 Ag13 Ag14 . . 64.0(5)
Ag12 Ag13 Ag14 . . 92.19(8)
C18 Ag13 Ag1 . 1_666 70.6(7)
O2 Ag13 Ag1 1_666 1_666 77.9(6)
O26 Ag13 Ag1 . 1_666 160.4(5)
O27 Ag13 Ag1 . 1_666 117.0(5)
Ag12 Ag13 Ag1 . 1_666 61.53(7)
Ag14 Ag13 Ag1 . 1_666 62.00(7)
C18 Ag14 O10 . 1_666 161.0(9)
C18 Ag14 O28 . . 93.3(10)
O10 Ag14 O28 1_666 . 93.0(9)
C18 Ag14 Ag13 . . 49.0(6)
O10 Ag14 Ag13 1_666 . 112.0(7)
O28 Ag14 Ag13 . . 107.3(5)
C18 Ag14 Ag2 . 1_666 52.7(6)
O10 Ag14 Ag2 1_666 1_666 138.2(5)
O28 Ag14 Ag2 . 1_666 114.9(7)
Ag13 Ag14 Ag2 . 1_666 89.65(8)
C18 Ag14 Ag3 . 1_666 109.5(7)
O10 Ag14 Ag3 1_666 1_666 78.6(5)
O28 Ag14 Ag3 . 1_666 133.2(5)
Ag13 Ag14 Ag3 . 1_666 118.58(10)
Ag2 Ag14 Ag3 1_666 1_666 59.60(7)
C18 Ag14 Ag1 . 1_666 70.9(7)
O10 Ag14 Ag1 1_666 1_666 101.9(6)
O28 Ag14 Ag1 . 1_666 164.2(6)
Ag13 Ag14 Ag1 . 1_666 62.24(7)
Ag2 Ag14 Ag1 1_666 1_666 55.96(6)
Ag3 Ag14 Ag1 1_666 1_666 56.44(7)
C2 C1 Ag1 . . 163(2)
C2 C1 Ag3 . . 102(2)
Ag1 C1 Ag3 . . 81.6(9)
C2 C1 Ag2 . . 118.8(18)
Ag1 C1 Ag2 . . 77.9(8)
Ag3 C1 Ag2 . . 81.6(9)
C2 C1 Ag4 . . 84.8(17)
Ag1 C1 Ag4 . . 79.1(8)
Ag3 C1 Ag4 . . 118.5(11)
Ag2 C1 Ag4 . . 146.6(13)
C1 C2 C3 . . 175(2)
C1 C2 Ag4 . . 65.9(15)
C3 C2 Ag4 . . 109.4(16)
C4 C3 C2 . . 112(2)
C4 C3 C6 . . 123(2)
C2 C3 C6 . . 124(2)
C5 C4 C3 . . 174(3)
C5 C4 Ag6 . . 70.1(15)
C3 C4 Ag6 . . 114.3(18)
C4 C5 Ag5 . . 135(2)
C4 C5 Ag7 . . 133.1(19)
Ag5 C5 Ag7 . . 84.9(11)
C4 C5 Ag8 . . 113.2(18)
Ag5 C5 Ag8 . . 84.2(10)
Ag7 C5 Ag8 . . 90.8(12)
C4 C5 Ag6 . . 79.7(17)
Ag5 C5 Ag6 . . 84.7(8)
Ag7 C5 Ag6 . . 81.3(8)
Ag8 C5 Ag6 . . 166.9(14)
C13 C6 C3 . . 121(3)
C13 C6 C7 . . 121(3)
C3 C6 C7 . . 118(2)
C8 C7 C6 . . 118(3)
C8 C7 H7A . . 107.8
C6 C7 H7A . . 107.8
C8 C7 H7B . . 107.8
C6 C7 H7B . . 107.8
H7A C7 H7B . . 107.1
C7 C8 C9 . . 112(3)
C7 C8 H8A . . 109.2
C9 C8 H8A . . 109.2
C7 C8 H8B . . 109.2
C9 C8 H8B . . 109.2
H8A C8 H8B . . 107.9
C10 C9 C8 . . 120(4)
C10 C9 H9A . . 107.4
C8 C9 H9A . . 107.4
C10 C9 H9B . . 107.4
C8 C9 H9B . . 107.4
H9A C9 H9B . . 106.9
C9 C10 C11 . . 110(4)
C9 C10 H10A . . 109.6
C11 C10 H10A . . 109.6
C9 C10 H10B . . 109.6
C11 C10 H10B . . 109.6
H10A C10 H10B . . 108.1
C12 C11 C10 . . 115(4)
C12 C11 H11A . . 108.5
C10 C11 H11A . . 108.5
C12 C11 H11B . . 108.5
C10 C11 H11B . . 108.5
H11A C11 H11B . . 107.5
C11 C12 C13 . . 120(4)
C11 C12 H12A . . 107.4
C13 C12 H12A . . 107.4
C11 C12 H12B . . 107.4
C13 C12 H12B . . 107.4
H12A C12 H12B . . 106.9
C6 C13 C12 . . 113(3)
C6 C13 H13A . . 108.9
C12 C13 H13A . . 108.9
C6 C13 H13B . . 108.9
C12 C13 H13B . . 108.9
H13A C13 H13B . . 107.8
C15 C14 Ag10 . . 145(2)
C15 C14 Ag7 . . 133(2)
Ag10 C14 Ag7 . . 81.3(9)
C15 C14 Ag11 . . 98.5(19)
Ag10 C14 Ag11 . . 84.2(8)
Ag7 C14 Ag11 . . 84.0(9)
C15 C14 Ag9 . . 78.8(18)
Ag10 C14 Ag9 . . 78.3(8)
Ag7 C14 Ag9 . . 125.5(11)
Ag11 C14 Ag9 . . 141.9(12)
C14 C15 C16 . . 170(3)
C14 C15 Ag9 . . 72.2(17)
C16 C15 Ag9 . . 112.1(18)
C19 C16 C15 . . 126(2)
C19 C16 C17 . . 121(2)
C15 C16 C17 . . 112(2)
C18 C17 C16 . . 161(3)
C17 C18 Ag14 . . 127(2)
C17 C18 Ag13 . . 129(2)
Ag14 C18 Ag13 . . 82.6(8)
C17 C18 Ag12 . . 98(2)
Ag14 C18 Ag12 . . 133.9(12)
Ag13 C18 Ag12 . . 78.3(8)
C17 C18 Ag2 . 1_666 99.9(19)
Ag14 C18 Ag2 . 1_666 80.7(8)
Ag13 C18 Ag2 . 1_666 128.1(12)
Ag12 C18 Ag2 . 1_666 79.0(8)
C16 C19 C20 . . 126(3)
C16 C19 C26 . . 115(3)
C20 C19 C26 . . 118(3)
C19 C20 C21 . . 120(3)
C19 C20 H20A . . 107.4
C21 C20 H20A . . 107.4
C19 C20 H20B . . 107.4
C21 C20 H20B . . 107.4
H20A C20 H20B . . 106.9
C20 C21 C22 . . 111(3)
C20 C21 H21A . . 109.4
C22 C21 H21A . . 109.4
C20 C21 H21B . . 109.4
C22 C21 H21B . . 109.4
H21A C21 H21B . . 108.0
C23 C22 C21 . . 128(5)
C23 C22 H22A . . 105.3
C21 C22 H22A . . 105.3
C23 C22 H22B . . 105.3
C21 C22 H22B . . 105.3
H22A C22 H22B . . 106.0
C22 C23 C24 . . 111(5)
C22 C23 H23A . . 109.5
C24 C23 H23A . . 109.5
C22 C23 H23B . . 109.5
C24 C23 H23B . . 109.5
H23A C23 H23B . . 108.1
C23 C24 C25 . . 122(4)
C23 C24 H24A . . 106.9
C25 C24 H24A . . 106.9
C23 C24 H24B . . 106.9
C25 C24 H24B . . 106.9
H24A C24 H24B . . 106.7
C26 C25 C24 . . 112(4)
C26 C25 H25A . . 109.3
C24 C25 H25A . . 109.3
C26 C25 H25B . . 109.3
C24 C25 H25B . . 109.3
H25A C25 H25B . . 107.9
C25 C26 C19 . . 118(3)
C25 C26 H26A . . 107.9
C19 C26 H26A . . 107.9
C25 C26 H26B . . 107.9
C19 C26 H26B . . 107.9
H26A C26 H26B . . 107.2
O21 S1 C48 . . 105.9(13)
O21 S1 C47 . . 106.2(14)
C48 S1 C47 . . 103.1(19)
S1 O21 Ag6 . . 124.4(10)
S1 O21 Ag3 . . 111.5(10)
Ag6 O21 Ag3 . . 114.2(8)
S1 C47 H47A . . 109.5
S1 C47 H47B . . 109.5
H47A C47 H47B . . 109.5
S1 C47 H47C . . 109.5
H47A C47 H47C . . 109.5
H47B C47 H47C . . 109.5
S1 C48 H48A . . 109.5
S1 C48 H48B . . 109.5
H48A C48 H48B . . 109.5
S1 C48 H48C . . 109.5
H48A C48 H48C . . 109.5
H48B C48 H48C . . 109.5
O22 S2 C49 . . 105.2(15)
O22 S2 C50 . . 105(2)
C49 S2 C50 . . 99(2)
S2 O22 Ag4 . . 131.5(13)
S2 O22 Ag5 . . 117.4(11)
Ag4 O22 Ag5 . . 98.2(8)
S2 C49 H49A . . 109.5
S2 C49 H49B . . 109.5
H49A C49 H49B . . 109.5
S2 C49 H49C . . 109.5
H49A C49 H49C . . 109.5
H49B C49 H49C . . 109.5
S2 C50 H50A . . 109.5
S2 C50 H50B . . 109.5
H50A C50 H50B . . 109.5
S2 C50 H50C . . 109.5
H50A C50 H50C . . 109.5
H50B C50 H50C . . 109.5
O23 S3 C52 . . 104.6(14)
O23 S3 C51 . . 105.6(13)
C52 S3 C51 . . 101.8(15)
S3 O23 Ag4 . . 130.8(12)
S3 C51 H51A . . 109.5
S3 C51 H51B . . 109.5
H51A C51 H51B . . 109.5
S3 C51 H51C . . 109.5
H51A C51 H51C . . 109.5
H51B C51 H51C . . 109.5
S3 C52 H52A . . 109.5
S3 C52 H52B . . 109.5
H52A C52 H52B . . 109.5
S3 C52 H52C . . 109.5
H52A C52 H52C . . 109.5
H52B C52 H52C . . 109.5
O24 S4 C53 . . 107.6(18)
O24 S4 C54 . . 108.0(17)
C53 S4 C54 . . 98(2)
S4 O24 Ag6 . . 134.7(15)
S4 O24 Ag5 . . 135.8(12)
Ag6 O24 Ag5 . . 79.5(7)
S4 C53 H53A . . 109.5
S4 C53 H53B . . 109.5
H53A C53 H53B . . 109.5
S4 C53 H53C . . 109.5
H53A C53 H53C . . 109.5
H53B C53 H53C . . 109.5
S4 C54 H54A . . 109.5
S4 C54 H54B . . 109.5
H54A C54 H54B . . 109.5
S4 C54 H54C . . 109.5
H54A C54 H54C . . 109.5
H54B C54 H54C . . 109.5
O25 S5 C55 . . 104.2(16)
O25 S5 C56 . . 107.7(11)
C55 S5 C56 . . 96.8(15)
S5 O25 Ag9 . . 123.9(10)
S5 C55 H55A . . 109.5
S5 C55 H55B . . 109.5
H55A C55 H55B . . 109.5
S5 C55 H55C . . 109.5
H55A C55 H55C . . 109.5
H55B C55 H55C . . 109.5
S5 C56 H56A . . 109.5
S5 C56 H56B . . 109.5
H56A C56 H56B . . 109.5
S5 C56 H56C . . 109.5
H56A C56 H56C . . 109.5
H56B C56 H56C . . 109.5
O26 S6 C58 . . 105.3(14)
O26 S6 C57 . . 104.9(16)
C58 S6 C57 . . 98.3(19)
S6 O26 Ag13 . . 127.8(11)
S6 O26 Ag10 . . 110.3(10)
Ag13 O26 Ag10 . . 121.8(9)
S6 C57 H57A . . 109.5
S6 C57 H57B . . 109.5
H57A C57 H57B . . 109.5
S6 C57 H57C . . 109.5
H57A C57 H57C . . 109.5
H57B C57 H57C . . 109.5
S6 C58 H58A . . 109.5
S6 C58 H58B . . 109.5
H58A C58 H58B . . 109.5
S6 C58 H58C . . 109.5
H58A C58 H58C . . 109.5
H58B C58 H58C . . 109.5
O27 S7 C60 . . 104.9(15)
O27 S7 C59 . . 107.4(18)
C60 S7 C59 . . 96(2)
S7 O27 Ag11 . . 131.3(13)
S7 O27 Ag13 . . 118.1(13)
Ag11 O27 Ag13 . . 104.4(7)
S7 C59 H59A . . 109.5
S7 C59 H59B . . 109.5
H59A C59 H59B . . 109.5
S7 C59 H59C . . 109.5
H59A C59 H59C . . 109.5
H59B C59 H59C . . 109.5
S7 C60 H60A . . 109.5
S7 C60 H60B . . 109.5
H60A C60 H60B . . 109.5
S7 C60 H60C . . 109.5
H60A C60 H60C . . 109.5
H60B C60 H60C . . 109.5
O28 S8 C62 . . 102.0(19)
O28 S8 C61 . . 109(2)
C62 S8 C61 . . 99(2)
S8 O28 Ag11 . . 131.8(16)
S8 O28 Ag14 . . 121.6(14)
Ag11 O28 Ag14 . . 101.6(9)
S8 C61 H61A . . 109.5
S8 C61 H61B . . 109.5
H61A C61 H61B . . 109.5
S8 C61 H61C . . 109.5
H61A C61 H61C . . 109.5
H61B C61 H61C . . 109.5
S8 C62 H62A . . 109.5
S8 C62 H62B . . 109.5
H62A C62 H62B . . 109.5
S8 C62 H62C . . 109.5
H62A C62 H62C . . 109.5
H62B C62 H62C . . 109.5
C27 O1 Ag1 . . 119.0(17)
C27 O2 Ag13 . 1_444 115.7(18)
O2 C27 O1 . . 134(3)
O2 C27 C28 . . 113(2)
O1 C27 C28 . . 112(2)
F1 C28 F3 . . 108.3(15)
F1 C28 F2 . . 107.6(14)
F3 C28 F2 . . 108.3(15)
F1 C28 C27 . . 111.2(19)
F3 C28 C27 . . 109(2)
F2 C28 C27 . . 112(2)
C29 O3 Ag1 . . 119(2)
C29 O4 Ag12 . 1_444 120(2)
O3 C29 O4 . . 133(3)
O3 C29 C30 . . 114(2)
O4 C29 C30 . . 112(3)
F6 C30 F5 . . 109.4(15)
F6 C30 F4 . . 109.5(15)
F5 C30 F4 . . 109.0(14)
F6 C30 C29 . . 108(2)
F5 C30 C29 . . 111(2)
F4 C30 C29 . . 110(2)
C31 O5 Ag2 . . 125.3(16)
C31 O6 Ag12 . 1_444 126.0(18)
O6 C31 O5 . . 127(2)
O6 C31 C32 . . 119(2)
O5 C31 C32 . . 114(2)
F8 C32 F9 . . 108.7(14)
F8 C32 F7 . . 108.6(13)
F9 C32 F7 . . 108.0(13)
F8 C32 C31 . . 109.8(16)
F9 C32 C31 . . 109.2(17)
F7 C32 C31 . . 112.6(17)
C33 O7 Ag2 . . 118(2)
C33 O8 Ag3 . . 121(2)
O7 C33 O8 . . 129(3)
O7 C33 C34 . . 120(3)
O8 C33 C34 . . 110(3)
F10 C34 F12 . . 109.2(16)
F10 C34 F11 . . 108.0(16)
F12 C34 F11 . . 107.7(16)
F10 C34 C33 . . 110(3)
F12 C34 C33 . . 113(3)
F11 C34 C33 . . 109(3)
C35 O9 Ag3 . . 124.8(19)
C35 O10 Ag14 . 1_444 127.6(18)
O9 C35 O10 . . 128(3)
O9 C35 C36 . . 115(2)
O10 C35 C36 . . 117(2)
F13 C36 F14 . . 108.7(14)
F13 C36 F15 . . 108.0(15)
F14 C36 F15 . . 107.4(15)
F13 C36 C35 . . 115(2)
F14 C36 C35 . . 110(2)
F15 C36 C35 . . 107(2)
C37 O11 Ag8 . . 128(2)
C37 O12 Ag9 . . 126(2)
O11 C37 O12 . . 128(3)
O11 C37 C38 . . 116(2)
O12 C37 C38 . . 116(2)
F17 C38 F18 . . 109.3(15)
F17 C38 F16 . . 108.8(15)
F18 C38 F16 . . 108.2(15)
F17 C38 C37 . . 109.9(19)
F18 C38 C37 . . 114(2)
F16 C38 C37 . . 106.6(19)
C39 O13 Ag8 . . 127.7(19)
C39 O14 Ag9 . . 124(2)
O14 C39 O13 . . 130(3)
O14 C39 C40 . . 114(3)
O13 C39 C40 . . 115(2)
F21 C40 F19 . . 108.6(15)
F21 C40 F20 . . 108.2(15)
F19 C40 F20 . . 107.2(14)
F21 C40 C39 . . 109(2)
F19 C40 C39 . . 112(2)
F20 C40 C39 . . 112(2)
C41 O15 Ag5 . . 125.8(17)
C41 O16 Ag10 . . 126.4(19)
O15 C41 O16 . . 131(3)
O15 C41 C42 . . 114(2)
O16 C41 C42 . . 115(2)
F24 C42 F22 . . 108.0(14)
F24 C42 F23 . . 108.1(14)
F22 C42 F23 . . 107.3(14)
F24 C42 C41 . . 110.5(18)
F22 C42 C41 . . 113.4(18)
F23 C42 C41 . . 109.4(19)
C43 O17 Ag6 . . 121(2)
C43 O18 Ag7 . . 123.9(18)
O17 C43 O18 . . 132(3)
O17 C43 C44 . . 115(2)
O18 C43 C44 . . 113(2)
F26 C44 F25 . . 109.0(14)
F26 C44 F27 . . 107.7(14)
F25 C44 F27 . . 107.7(14)
F26 C44 C43 . . 111.1(19)
F25 C44 C43 . . 107.0(19)
F27 C44 C43 . . 114.1(19)
C45 O19 Ag7 . . 118.4(19)
C45 O20 Ag11 . . 117.4(17)
O19 C45 O20 . . 132(2)
O19 C45 C46 . . 116(2)
O20 C45 C46 . . 111.6(19)
F29 C46 F28 . . 109.5(14)
F29 C46 F30 . . 108.5(14)
F28 C46 F30 . . 108.3(14)
F29 C46 C45 . . 111.4(18)
F28 C46 C45 . . 109.8(18)
F30 C46 C45 . . 109.3(18)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ag1 C1 . 2.21(2)
Ag1 O1 . 2.25(2)
Ag1 O3 . 2.53(3)
Ag1 Ag2 . 2.857(3)
Ag1 Ag4 . 2.906(3)
Ag1 Ag3 . 2.912(3)
Ag1 Ag12 1_444 3.066(3)
Ag1 Ag14 1_444 3.105(3)
Ag1 Ag13 1_444 3.112(3)
Ag2 O7 . 2.32(2)
Ag2 O5 . 2.323(18)
Ag2 C1 . 2.34(3)
Ag2 C18 1_444 2.40(2)
Ag2 Ag14 1_444 2.980(3)
Ag2 Ag3 . 2.999(3)
Ag2 Ag12 1_444 3.011(3)
Ag3 C1 . 2.25(3)
Ag3 O9 . 2.27(2)
Ag3 O8 . 2.42(2)
Ag3 O21 . 2.438(17)
Ag3 Ag14 1_444 3.052(3)
Ag4 O22 . 2.276(19)
Ag4 C1 . 2.35(3)
Ag4 O23 . 2.38(2)
Ag4 C2 . 2.57(2)
Ag5 C5 . 2.13(3)
Ag5 O15 . 2.203(18)
Ag5 O24 . 2.54(2)
Ag5 O22 . 2.56(2)
Ag5 Ag8 . 2.894(3)
Ag5 Ag7 . 2.908(3)
Ag5 Ag6 . 3.162(3)
Ag5 Ag10 . 3.186(3)
Ag6 O17 . 2.28(2)
Ag6 O24 . 2.40(2)
Ag6 O21 . 2.435(19)
Ag6 C5 . 2.54(3)
Ag6 C4 . 2.66(3)
Ag6 Ag7 . 3.092(3)
Ag7 C5 . 2.18(3)
Ag7 C14 . 2.25(3)
Ag7 O18 . 2.32(2)
Ag7 O19 . 2.54(2)
Ag7 Ag10 . 2.872(3)
Ag7 Ag11 . 3.062(3)
Ag7 Ag8 . 3.110(3)
Ag8 C5 . 2.19(3)
Ag8 O11 . 2.277(18)
Ag8 O13 . 2.28(2)
Ag8 Ag9 . 3.191(3)
Ag8 Ag10 . 3.220(3)
Ag9 O12 . 2.26(2)
Ag9 O14 . 2.38(2)
Ag9 O25 . 2.412(18)
Ag9 C14 . 2.45(3)
Ag9 C15 . 2.52(3)
Ag9 Ag10 . 2.918(3)
Ag10 O16 . 2.16(2)
Ag10 C14 . 2.16(3)
Ag10 O26 . 2.58(2)
Ag10 Ag11 . 3.012(3)
Ag11 O20 . 2.28(2)
Ag11 C14 . 2.33(2)
Ag11 O28 . 2.41(2)
Ag11 O27 . 2.42(2)
Ag12 O4 1_666 2.31(3)
Ag12 O6 1_666 2.322(19)
Ag12 C18 . 2.33(3)
Ag12 Ag13 . 2.868(3)
Ag12 Ag2 1_666 3.011(3)
Ag12 Ag1 1_666 3.066(3)
Ag13 C18 . 2.21(2)
Ag13 O2 1_666 2.32(2)
Ag13 O26 . 2.41(2)
Ag13 O27 . 2.53(2)
Ag13 Ag14 . 2.907(3)
Ag13 Ag1 1_666 3.112(3)
Ag14 C18 . 2.19(3)
Ag14 O10 1_666 2.215(19)
Ag14 O28 . 2.51(3)
Ag14 Ag2 1_666 2.980(3)
Ag14 Ag3 1_666 3.052(3)
Ag14 Ag1 1_666 3.105(3)
C1 C2 . 1.26(4)
C2 C3 . 1.41(3)
C3 C4 . 1.39(4)
C3 C6 . 1.44(4)
C4 C5 . 1.36(4)
C6 C13 . 1.42(5)
C6 C7 . 1.51(4)
C7 C8 . 1.46(4)
C7 H7A . 0.9900
C7 H7B . 0.9900
C8 C9 . 1.57(7)
C8 H8A . 0.9900
C8 H8B . 0.9900
C9 C10 . 1.52(7)
C9 H9A . 0.9900
C9 H9B . 0.9900
C10 C11 . 1.59(6)
C10 H10A . 0.9900
C10 H10B . 0.9900
C11 C12 . 1.42(6)
C11 H11A . 0.9900
C11 H11B . 0.9900
C12 C13 . 1.54(7)
C12 H12A . 0.9900
C12 H12B . 0.9900
C13 H13A . 0.9900
C13 H13B . 0.9900
C14 C15 . 1.25(4)
C15 C16 . 1.40(3)
C16 C19 . 1.37(4)
C16 C17 . 1.45(4)
C17 C18 . 1.20(4)
C18 Ag2 1_666 2.40(2)
C19 C20 . 1.45(4)
C19 C26 . 1.58(4)
C20 C21 . 1.54(5)
C20 H20A . 0.9900
C20 H20B . 0.9900
C21 C22 . 1.59(6)
C21 H21A . 0.9900
C21 H21B . 0.9900
C22 C23 . 1.48(7)
C22 H22A . 0.9900
C22 H22B . 0.9900
C23 C24 . 1.49(7)
C23 H23A . 0.9900
C23 H23B . 0.9900
C24 C25 . 1.60(7)
C24 H24A . 0.9900
C24 H24B . 0.9900
C25 C26 . 1.46(6)
C25 H25A . 0.9900
C25 H25B . 0.9900
C26 H26A . 0.9900
C26 H26B . 0.9900
S1 O21 . 1.51(2)
S1 C48 . 1.79(3)
S1 C47 . 1.80(3)
C47 H47A . 0.9800
C47 H47B . 0.9800
C47 H47C . 0.9800
C48 H48A . 0.9800
C48 H48B . 0.9800
C48 H48C . 0.9800
S2 O22 . 1.53(2)
S2 C49 . 1.77(3)
S2 C50 . 1.78(5)
C49 H49A . 0.9800
C49 H49B . 0.9800
C49 H49C . 0.9800
C50 H50A . 0.9800
C50 H50B . 0.9800
C50 H50C . 0.9800
S3 O23 . 1.52(2)
S3 C52 . 1.75(3)
S3 C51 . 1.92(4)
C51 H51A . 0.9800
C51 H51B . 0.9800
C51 H51C . 0.9800
C52 H52A . 0.9800
C52 H52B . 0.9800
C52 H52C . 0.9800
S4 O24 . 1.48(2)
S4 C53 . 1.74(4)
S4 C54 . 1.76(4)
C53 H53A . 0.9800
C53 H53B . 0.9800
C53 H53C . 0.9800
C54 H54A . 0.9800
C54 H54B . 0.9800
C54 H54C . 0.9800
S5 O25 . 1.59(2)
S5 C55 . 1.75(3)
S5 C56 . 1.80(3)
C55 H55A . 0.9800
C55 H55B . 0.9800
C55 H55C . 0.9800
C56 H56A . 0.9800
C56 H56B . 0.9800
C56 H56C . 0.9800
S6 O26 . 1.55(2)
S6 C58 . 1.77(3)
S6 C57 . 1.78(4)
C57 H57A . 0.9800
C57 H57B . 0.9800
C57 H57C . 0.9800
C58 H58A . 0.9800
C58 H58B . 0.9800
C58 H58C . 0.9800
S7 O27 . 1.51(2)
S7 C60 . 1.74(4)
S7 C59 . 1.80(5)
C59 H59A . 0.9800
C59 H59B . 0.9800
C59 H59C . 0.9800
C60 H60A . 0.9800
C60 H60B . 0.9800
C60 H60C . 0.9800
S8 O28 . 1.49(3)
S8 C62 . 1.86(5)
S8 C61 . 1.86(5)
C61 H61A . 0.9800
C61 H61B . 0.9800
C61 H61C . 0.9800
C62 H62A . 0.9800
C62 H62B . 0.9800
C62 H62C . 0.9800
O1 C27 . 1.29(3)
O2 C27 . 1.19(3)
O2 Ag13 1_444 2.32(2)
C27 C28 . 1.57(3)
C28 F1 . 1.299(15)
C28 F3 . 1.300(15)
C28 F2 . 1.303(15)
O3 C29 . 1.23(4)
O4 C29 . 1.24(4)
O4 Ag12 1_444 2.31(3)
C29 C30 . 1.60(4)
C30 F6 . 1.290(15)
C30 F5 . 1.294(14)
C30 F4 . 1.295(14)
O5 C31 . 1.29(3)
O6 C31 . 1.20(3)
O6 Ag12 1_444 2.323(19)
C31 C32 . 1.56(3)
C32 F8 . 1.302(14)
C32 F9 . 1.304(14)
C32 F7 . 1.305(14)
O7 C33 . 1.23(4)
O8 C33 . 1.27(4)
C33 C34 . 1.56(4)
C34 F10 . 1.295(15)
C34 F12 . 1.296(15)
C34 F11 . 1.305(15)
O9 C35 . 1.21(4)
O10 C35 . 1.25(4)
O10 Ag14 1_444 2.215(19)
C35 C36 . 1.53(3)
C36 F13 . 1.298(15)
C36 F14 . 1.301(14)
C36 F15 . 1.307(15)
O11 C37 . 1.20(4)
O12 C37 . 1.26(4)
C37 C38 . 1.59(4)
C38 F17 . 1.295(15)
C38 F18 . 1.297(15)
C38 F16 . 1.300(15)
O13 C39 . 1.25(4)
O14 C39 . 1.21(4)
C39 C40 . 1.60(3)
C40 F21 . 1.297(15)
C40 F19 . 1.302(15)
C40 F20 . 1.305(15)
O15 C41 . 1.22(4)
O16 C41 . 1.27(4)
C41 C42 . 1.57(3)
C42 F24 . 1.295(14)
C42 F22 . 1.306(14)
C42 F23 . 1.307(14)
O17 C43 . 1.19(4)
O18 C43 . 1.29(4)
C43 C44 . 1.59(4)
C44 F26 . 1.301(15)
C44 F25 . 1.301(15)
C44 F27 . 1.307(15)
O19 C45 . 1.21(4)
O20 C45 . 1.27(3)
C45 C46 . 1.60(3)
C46 F29 . 1.294(14)
C46 F28 . 1.299(15)
C46 F30 . 1.307(15)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
Ag1 C1 C2 Ag4 . . -17(8)
Ag3 C1 C2 Ag4 . . -118.1(12)
Ag2 C1 C2 Ag4 . . 155(2)
Ag4 C2 C3 C4 . . 37(3)
Ag4 C2 C3 C6 . . -142(2)
C2 C3 C4 Ag6 . . 74(2)
C6 C3 C4 Ag6 . . -108(2)
Ag6 C4 C5 Ag5 . . -72(2)
Ag6 C4 C5 Ag7 . . 68(2)
Ag6 C4 C5 Ag8 . . -177.4(16)
C4 C3 C6 C13 . . 172(3)
C2 C3 C6 C13 . . -10(4)
C4 C3 C6 C7 . . -4(4)
C2 C3 C6 C7 . . 174(3)
C13 C6 C7 C8 . . -37(4)
C3 C6 C7 C8 . . 140(3)
C6 C7 C8 C9 . . -70(4)
C7 C8 C9 C10 . . 58(5)
C8 C9 C10 C11 . . 47(5)
C9 C10 C11 C12 . . -104(5)
C10 C11 C12 C13 . . 69(5)
C3 C6 C13 C12 . . -80(4)
C7 C6 C13 C12 . . 97(4)
C11 C12 C13 C6 . . -65(5)
Ag10 C14 C15 Ag9 . . -49(3)
Ag7 C14 C15 Ag9 . . 129(2)
Ag11 C14 C15 Ag9 . . -141.4(11)
Ag9 C15 C16 C19 . . -94(3)
Ag9 C15 C16 C17 . . 88(2)
C19 C16 C17 C18 . . -175(9)
C15 C16 C17 C18 . . 3(11)
C16 C17 C18 Ag14 . . 83(10)
C16 C17 C18 Ag13 . . -30(12)
C16 C17 C18 Ag12 . . -111(10)
C16 C17 C18 Ag2 . 1_666 168(9)
C15 C16 C19 C20 . . 174(3)
C17 C16 C19 C20 . . -8(5)
C15 C16 C19 C26 . . 3(4)
C17 C16 C19 C26 . . -179(3)
C16 C19 C20 C21 . . 145(3)
C26 C19 C20 C21 . . -45(4)
C19 C20 C21 C22 . . -55(4)
C20 C21 C22 C23 . . 55(6)
C21 C22 C23 C24 . . 43(7)
C22 C23 C24 C25 . . -100(6)
C23 C24 C25 C26 . . 67(6)
C24 C25 C26 C19 . . -62(4)
C16 C19 C26 C25 . . -81(4)
C20 C19 C26 C25 . . 107(4)
C48 S1 O21 Ag6 . . 31(2)
C47 S1 O21 Ag6 . . -78.3(19)
C48 S1 O21 Ag3 . . -112.7(16)
C47 S1 O21 Ag3 . . 138.1(15)
C49 S2 O22 Ag4 . . -14(2)
C50 S2 O22 Ag4 . . 90(3)
C49 S2 O22 Ag5 . . 118.3(16)
C50 S2 O22 Ag5 . . -138(2)
C52 S3 O23 Ag4 . . -76(2)
C51 S3 O23 Ag4 . . 31(2)
C53 S4 O24 Ag6 . . 101(2)
C54 S4 O24 Ag6 . . -154(2)
C53 S4 O24 Ag5 . . -29(3)
C54 S4 O24 Ag5 . . 76(2)
C55 S5 O25 Ag9 . . -70.3(16)
C56 S5 O25 Ag9 . . 31.7(16)
C58 S6 O26 Ag13 . . -68(2)
C57 S6 O26 Ag13 . . 36(2)
C58 S6 O26 Ag10 . . 114.7(15)
C57 S6 O26 Ag10 . . -142.1(17)
C60 S7 O27 Ag11 . . -39(2)
C59 S7 O27 Ag11 . . 62(2)
C60 S7 O27 Ag13 . . 108.4(19)
C59 S7 O27 Ag13 . . -150.3(18)
C62 S8 O28 Ag11 . . 47(3)
C61 S8 O28 Ag11 . . -57(3)
C62 S8 O28 Ag14 . . -163(2)
C61 S8 O28 Ag14 . . 93(2)
Ag13 O2 C27 O1 1_444 . 11(5)
Ag13 O2 C27 C28 1_444 . -158.2(17)
Ag1 O1 C27 O2 . . 30(5)
Ag1 O1 C27 C28 . . -160.0(16)
O2 C27 C28 F1 . . -5(3)
O1 C27 C28 F1 . . -177(2)
O2 C27 C28 F3 . . -125(3)
O1 C27 C28 F3 . . 63(3)
O2 C27 C28 F2 . . 115(3)
O1 C27 C28 F2 . . -57(3)
Ag1 O3 C29 O4 . . -36(6)
Ag1 O3 C29 C30 . . 151.5(18)
Ag12 O4 C29 O3 1_444 . 16(6)
Ag12 O4 C29 C30 1_444 . -171.5(16)
O3 C29 C30 F6 . . 63(4)
O4 C29 C30 F6 . . -111(3)
O3 C29 C30 F5 . . -176(3)
O4 C29 C30 F5 . . 9(3)
O3 C29 C30 F4 . . -56(4)
O4 C29 C30 F4 . . 130(3)
Ag12 O6 C31 O5 1_444 . -3(4)
Ag12 O6 C31 C32 1_444 . 174.7(14)
Ag2 O5 C31 O6 . . -5(4)
Ag2 O5 C31 C32 . . 176.6(13)
O6 C31 C32 F8 . . -62(3)
O5 C31 C32 F8 . . 116(2)
O6 C31 C32 F9 . . 57(3)
O5 C31 C32 F9 . . -125(2)
O6 C31 C32 F7 . . 177(2)
O5 C31 C32 F7 . . -5(3)
Ag2 O7 C33 O8 . . 6(5)
Ag2 O7 C33 C34 . . -163(2)
Ag3 O8 C33 O7 . . -39(5)
Ag3 O8 C33 C34 . . 131(3)
O7 C33 C34 F10 . . -7(4)
O8 C33 C34 F10 . . -179(3)
O7 C33 C34 F12 . . -130(3)
O8 C33 C34 F12 . . 59(3)
O7 C33 C34 F11 . . 111(3)
O8 C33 C34 F11 . . -60(3)
Ag3 O9 C35 O10 . . -2(5)
Ag3 O9 C35 C36 . . -179.3(18)
Ag14 O10 C35 O9 1_444 . -10(5)
Ag14 O10 C35 C36 1_444 . 166.5(18)
O9 C35 C36 F13 . . -9(4)
O10 C35 C36 F13 . . 174(3)
O9 C35 C36 F14 . . -132(3)
O10 C35 C36 F14 . . 50(3)
O9 C35 C36 F15 . . 111(3)
O10 C35 C36 F15 . . -66(3)
Ag8 O11 C37 O12 . . -14(5)
Ag8 O11 C37 C38 . . 168.3(16)
Ag9 O12 C37 O11 . . -8(5)
Ag9 O12 C37 C38 . . 169.5(15)
O11 C37 C38 F17 . . 47(3)
O12 C37 C38 F17 . . -131(3)
O11 C37 C38 F18 . . 170(2)
O12 C37 C38 F18 . . -8(3)
O11 C37 C38 F16 . . -71(3)
O12 C37 C38 F16 . . 112(3)
Ag9 O14 C39 O13 . . 14(5)
Ag9 O14 C39 C40 . . -171.4(18)
Ag8 O13 C39 O14 . . 1(6)
Ag8 O13 C39 C40 . . -173.2(19)
O14 C39 C40 F21 . . 98(3)
O13 C39 C40 F21 . . -87(3)
O14 C39 C40 F19 . . -142(3)
O13 C39 C40 F19 . . 33(4)
O14 C39 C40 F20 . . -22(4)
O13 C39 C40 F20 . . 154(3)
Ag5 O15 C41 O16 . . -14(5)
Ag5 O15 C41 C42 . . 174.4(16)
Ag10 O16 C41 O15 . . 0(5)
Ag10 O16 C41 C42 . . 171.4(17)
O15 C41 C42 F24 . . -47(3)
O16 C41 C42 F24 . . 140(3)
O15 C41 C42 F22 . . -169(2)
O16 C41 C42 F22 . . 19(3)
O15 C41 C42 F23 . . 72(3)
O16 C41 C42 F23 . . -101(3)
Ag6 O17 C43 O18 . . 17(5)
Ag6 O17 C43 C44 . . -158.4(17)
Ag7 O18 C43 O17 . . 6(5)
Ag7 O18 C43 C44 . . -177.7(14)
O17 C43 C44 F26 . . 43(3)
O18 C43 C44 F26 . . -133(2)
O17 C43 C44 F25 . . -75(3)
O18 C43 C44 F25 . . 108(2)
O17 C43 C44 F27 . . 165(2)
O18 C43 C44 F27 . . -11(3)
Ag7 O19 C45 O20 . . 37(5)
Ag7 O19 C45 C46 . . -149.5(16)
Ag11 O20 C45 O19 . . -4(5)
Ag11 O20 C45 C46 . . -177.1(14)
O19 C45 C46 F29 . . 150(3)
O20 C45 C46 F29 . . -36(3)
O19 C45 C46 F28 . . 28(3)
O20 C45 C46 F28 . . -157(2)
O19 C45 C46 F30 . . -90(3)
O20 C45 C46 F30 . . 84(3)
