#------------------------------------------------------------------------------
#$Date: 2016-02-20 02:53:41 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176768 $
#$URL: svn://www.crystallography.net/cod/cif/2/10/59/2105969.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2105969
loop_
_publ_author_name
Jin-Long
'Uemura, Kazuhiro'
'Ebihara, Masahiro'
_publ_section_title
;
 Assembled structures of tetrakis(biimidazole)dirhodium complexes
 hydrogen-bonded with common inorganic anions
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              1006
_journal_page_last               1019
_journal_paper_doi               10.1107/S2052520614021428
_journal_volume                  70
_journal_year                    2014
_chemical_formula_moiety         'C30 H38 N18 O2 Rh2, 4(B F4)'
_chemical_formula_sum            'C30 H38 B4 F16 N18 O2 Rh2'
_chemical_formula_weight         1235.84
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.673(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   16.073(10)
_cell_length_b                   19.104(11)
_cell_length_c                   16.399(10)
_cell_measurement_reflns_used    4208
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.5
_cell_measurement_theta_min      3.0
_cell_volume                     4679(5)
_computing_cell_refinement       CrystalClear
_computing_data_collection
'CrystalClear (Molecular Structure Corporation & Rigaku Corporation, 2001)'
_computing_data_reduction        CrystalClear
_computing_molecular_graphics    'Mercury (Macrae et al., 2008)'
_computing_publication_material
'Yadokari-XG 2009 (Wakita, Nemoto et al., 2009)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 2008)'
_computing_structure_solution    'SIR97 (Altomare et al., 1999)'
_diffrn_ambient_temperature      296(2)
_diffrn_detector_area_resol_mean 14.62
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Rigaku/MSC Mercury CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.0562
_diffrn_reflns_av_sigmaI/netI    0.0579
_diffrn_reflns_limit_h_max       20
_diffrn_reflns_limit_h_min       -20
_diffrn_reflns_limit_k_max       24
_diffrn_reflns_limit_k_min       -22
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            17721
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         3.03
_diffrn_source                   'rotating-anode X-ray tube'
_exptl_absorpt_coefficient_mu    0.822
_exptl_absorpt_correction_T_max  0.8910
_exptl_absorpt_correction_T_min  0.7651
_exptl_absorpt_correction_type   numerical
_exptl_absorpt_process_details   'NUMABS (Higashi, 1999)'
_exptl_crystal_colour            green
_exptl_crystal_density_diffrn    1.754
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prismatic
_exptl_crystal_F_000             2456
_exptl_crystal_size_max          0.47
_exptl_crystal_size_mid          0.38
_exptl_crystal_size_min          0.23
_refine_diff_density_max         2.601
_refine_diff_density_min         -0.943
_refine_diff_density_rms         0.146
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.053
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     392
_refine_ls_number_reflns         5356
_refine_ls_number_restraints     474
_refine_ls_restrained_S_all      1.120
_refine_ls_R_factor_all          0.0921
_refine_ls_R_factor_gt           0.0658
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.1143P)²+8.0854P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1833
_refine_ls_wR_factor_ref         0.2127
_reflns_number_gt                3475
_reflns_number_total             5356
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            ry5061sup1.cif
_cod_data_source_block           IV
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               2105969
#BEGIN Tags that were not found in dictionaries:
_publcif_datablock.id            {17564ba7-9d7f-429b-b71e-f93e47174cf3}
#END Tags that were not found in dictionaries
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_symmetry_multiplicity
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_disorder_assembly
_atom_site_disorder_group
Rh1 Rh 0.41335(3) 0.249529(18) 0.23305(3) 0.03572(19) Uani 1 1 d . . .
N1 N 0.4147(3) 0.1473(2) 0.2727(3) 0.0445(10) Uani 1 1 d . . .
C1 C 0.3907(4) 0.1019(3) 0.2065(4) 0.0484(13) Uani 1 1 d . . .
N2 N 0.3880(4) 0.0366(3) 0.2348(4) 0.0600(14) Uani 1 1 d . . .
H2N H 0.3739 -0.0006 0.2031 0.072 Uiso 1 1 calc R . .
C2 C 0.4115(5) 0.0404(3) 0.3226(4) 0.0667(18) Uani 1 1 d . . .
H2 H 0.4163 0.0031 0.3605 0.080 Uiso 1 1 calc R . .
C3 C 0.4269(4) 0.1089(3) 0.3455(4) 0.0547(15) Uani 1 1 d . . .
H3 H 0.4432 0.1265 0.4022 0.066 Uiso 1 1 calc R . .
N3 N 0.3833(3) 0.1988(2) 0.1155(3) 0.0461(10) Uani 1 1 d . . .
C4 C 0.3711(4) 0.1304(3) 0.1198(4) 0.0491(13) Uani 1 1 d . . .
N4 N 0.3405(3) 0.1017(3) 0.0403(3) 0.0596(13) Uani 1 1 d . . .
H4N H 0.3281 0.0582 0.0281 0.071 Uiso 1 1 calc R . .
C5 C 0.3327(4) 0.1545(4) -0.0182(4) 0.0645(17) Uani 1 1 d . . .
H5 H 0.3131 0.1502 -0.0789 0.077 Uiso 1 1 calc R . .
C6 C 0.3589(4) 0.2139(3) 0.0285(4) 0.0576(15) Uani 1 1 d . . .
H6 H 0.3601 0.2581 0.0052 0.069 Uiso 1 1 calc R . .
N5 N 0.4278(3) 0.2999(2) 0.3473(3) 0.0448(10) Uani 1 1 d . . .
C7 C 0.4072(4) 0.3678(3) 0.3355(4) 0.0482(13) Uani 1 1 d . . .
N6 N 0.4012(4) 0.3952(3) 0.4078(3) 0.0696(16) Uani 1 1 d . . .
H6N H 0.3886 0.4380 0.4148 0.084 Uiso 1 1 calc R . .
C8 C 0.4183(5) 0.3433(4) 0.4682(4) 0.075(2) Uani 1 1 d . . .
H8 H 0.4197 0.3476 0.5252 0.090 Uiso 1 1 calc R . .
C9 C 0.4330(4) 0.2843(3) 0.4305(4) 0.0551(14) Uani 1 1 d . . .
H9 H 0.4447 0.2404 0.4566 0.066 Uiso 1 1 calc R . .
N7 N 0.4008(3) 0.3510(2) 0.1913(3) 0.0442(10) Uani 1 1 d . . .
C10 C 0.3940(4) 0.3959(3) 0.2500(4) 0.0494(13) Uani 1 1 d . . .
N8 N 0.3768(5) 0.4606(3) 0.2165(4) 0.0656(15) Uani 1 1 d . . .
H8N H 0.3695 0.4976 0.2431 0.079 Uiso 1 1 calc R . .
C11 C 0.3732(5) 0.4568(3) 0.1329(4) 0.0699(19) Uani 1 1 d . . .
H11 H 0.3625 0.4938 0.0935 0.084 Uiso 1 1 calc R . .
C12 C 0.3880(4) 0.3886(3) 0.1169(4) 0.0517(14) Uani 1 1 d . . .
H12 H 0.3892 0.3710 0.0645 0.062 Uiso 1 1 calc R . .
O1 O 0.2648(3) 0.2572(2) 0.2061(3) 0.0508(11) Uani 1 1 d . . .
C13 C 0.2404(4) 0.2318(4) 0.2615(5) 0.0620(17) Uani 1 1 d . . .
H13 H 0.2794 0.2013 0.3020 0.074 Uiso 1 1 calc R . .
N9 N 0.1626(4) 0.2445(3) 0.2685(5) 0.0694(18) Uani 1 1 d . . .
C14 C 0.1026(7) 0.2945(7) 0.2105(7) 0.133(5) Uani 1 1 d . . .
H14 H 0.1353 0.3358 0.2074 0.200 Uiso 1 1 calc R . .
H14A H 0.0567 0.3066 0.2324 0.200 Uiso 1 1 calc R . .
H14B H 0.0756 0.2745 0.1530 0.200 Uiso 1 1 calc R . .
C15 C 0.1370(6) 0.2101(6) 0.3350(6) 0.102(3) Uani 1 1 d . . .
H15 H 0.1793 0.1738 0.3628 0.154 Uiso 1 1 calc R . .
H15A H 0.0784 0.1900 0.3079 0.154 Uiso 1 1 calc R . .
H15B H 0.1363 0.2438 0.3782 0.154 Uiso 1 1 calc R . .
B1 B 0.3728(6) 0.5813(4) 0.3763(5) 0.084(2) Uani 1 1 d DU . .
F1 F 0.3661(4) 0.6447(2) 0.4079(3) 0.119(2) Uani 1 1 d DU A .
F2A F 0.3234(11) 0.5794(7) 0.2867(6) 0.097(5) Uani 0.54(3) 1 d PDU A 1
F3A F 0.4522(8) 0.5549(8) 0.3920(12) 0.135(6) Uani 0.54(3) 1 d PDU A 1
F4A F 0.3269(15) 0.5346(6) 0.4113(12) 0.135(6) Uani 0.54(3) 1 d PDU A 1
F2B F 0.3065(11) 0.5591(12) 0.3080(13) 0.138(8) Uani 0.46(3) 1 d PDU A 2
F3B F 0.4468(12) 0.5868(13) 0.3499(17) 0.162(8) Uani 0.46(3) 1 d PDU A 2
F4B F 0.399(3) 0.5367(7) 0.4449(9) 0.159(10) Uani 0.46(3) 1 d PDU A 2
B2A B 0.3488(12) -0.0920(9) 0.0443(9) 0.116(6) Uani 0.421(17) 1 d PDU B 1
B2B B 0.3638(10) -0.0916(7) 0.0493(8) 0.118(5) Uani 0.579(17) 1 d PDU B 2
F5 F 0.3608(7) -0.0812(4) 0.1280(4) 0.204(4) Uani 1 1 d DU . .
F6A F 0.2633(11) -0.1049(16) -0.0042(11) 0.216(11) Uani 0.421(17) 1 d PDU B 1
F7A F 0.3754(16) -0.0348(8) 0.0129(11) 0.149(8) Uani 0.421(17) 1 d PDU B 1
F8A F 0.3993(17) -0.1463(9) 0.0386(12) 0.149(9) Uani 0.421(17) 1 d PDU B 1
F6B F 0.4504(8) -0.0890(11) 0.0576(10) 0.202(8) Uani 0.579(17) 1 d PDU B 2
F7B F 0.3295(13) -0.1534(6) 0.0162(9) 0.167(8) Uani 0.579(17) 1 d PDU B 2
F8B F 0.3172(11) -0.0413(7) -0.0046(9) 0.176(7) Uani 0.579(17) 1 d PDU B 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
B B 0.0013 0.0007 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rh Rh -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N7 Rh1 N5 . 79.88(18) y
N7 Rh1 N3 . 99.97(18) y
N5 Rh1 N3 . 173.40(17) y
N7 Rh1 N1 . 175.25(17) y
N5 Rh1 N1 . 99.96(18) y
N3 Rh1 N1 . 79.63(18) y
N7 Rh1 O1 . 84.66(16) y
N5 Rh1 O1 . 84.44(17) y
N3 Rh1 O1 . 88.97(17) y
N1 Rh1 O1 . 90.60(16) y
N7 Rh1 Rh1 2_655 92.08(13) y
N5 Rh1 Rh1 2_655 93.04(13) y
N3 Rh1 Rh1 2_655 93.55(13) y
N1 Rh1 Rh1 2_655 92.67(13) y
O1 Rh1 Rh1 2_655 176.18(10) y
C1 N1 C3 . 105.8(5) ?
C1 N1 Rh1 . 113.2(4) ?
C3 N1 Rh1 . 140.8(4) ?
N1 C1 N2 . 111.1(5) ?
N1 C1 C4 . 116.7(5) ?
N2 C1 C4 . 132.1(6) ?
C1 N2 C2 . 106.7(5) ?
C1 N2 H2N . 126.6 ?
C2 N2 H2N . 126.6 ?
N2 C2 C3 . 107.3(5) ?
N2 C2 H2 . 126.3 ?
C3 C2 H2 . 126.3 ?
N1 C3 C2 . 109.0(5) ?
N1 C3 H3 . 125.5 ?
C2 C3 H3 . 125.5 ?
C4 N3 C6 . 105.8(5) ?
C4 N3 Rh1 . 113.7(4) ?
C6 N3 Rh1 . 139.6(4) ?
N3 C4 N4 . 111.2(5) ?
N3 C4 C1 . 116.2(5) ?
N4 C4 C1 . 132.6(6) ?
C4 N4 C5 . 106.8(5) ?
C4 N4 H4N . 126.6 ?
C5 N4 H4N . 126.6 ?
C6 C5 N4 . 107.1(5) ?
C6 C5 H5 . 126.5 ?
N4 C5 H5 . 126.5 ?
C5 C6 N3 . 109.0(6) ?
C5 C6 H6 . 125.5 ?
N3 C6 H6 . 125.5 ?
C7 N5 C9 . 106.1(5) ?
C7 N5 Rh1 . 112.7(3) ?
C9 N5 Rh1 . 139.2(4) ?
N6 C7 N5 . 110.4(5) ?
N6 C7 C10 . 133.3(6) ?
N5 C7 C10 . 116.3(5) ?
C7 N6 C8 . 107.5(5) ?
C7 N6 H6N . 126.2 ?
C8 N6 H6N . 126.2 ?
C9 C8 N6 . 107.4(6) ?
C9 C8 H8 . 126.3 ?
N6 C8 H8 . 126.3 ?
C8 C9 N5 . 108.6(6) ?
C8 C9 H9 . 125.7 ?
N5 C9 H9 . 125.7 ?
C10 N7 C12 . 106.4(5) ?
C10 N7 Rh1 . 113.3(4) ?
C12 N7 Rh1 . 139.9(4) ?
N7 C10 N8 . 111.1(5) ?
N7 C10 C7 . 116.3(5) ?
N8 C10 C7 . 132.5(6) ?
C10 N8 C11 . 106.9(5) ?
C10 N8 H8N . 126.6 ?
C11 N8 H8N . 126.6 ?
N8 C11 C12 . 107.5(5) ?
N8 C11 H11 . 126.3 ?
C12 C11 H11 . 126.3 ?
N7 C12 C11 . 108.1(5) ?
N7 C12 H12 . 125.9 ?
C11 C12 H12 . 125.9 ?
C13 O1 Rh1 . 115.8(4) ?
O1 C13 N9 . 124.7(7) ?
O1 C13 H13 . 117.7 ?
N9 C13 H13 . 117.7 ?
C13 N9 C14 . 119.4(7) ?
C13 N9 C15 . 121.4(7) ?
C14 N9 C15 . 119.2(7) ?
N9 C14 H14 . 109.5 ?
N9 C14 H14A . 109.5 ?
H14 C14 H14A . 109.5 ?
N9 C14 H14B . 109.5 ?
H14 C14 H14B . 109.5 ?
H14A C14 H14B . 109.5 ?
N9 C15 H15 . 109.5 ?
N9 C15 H15A . 109.5 ?
H15 C15 H15A . 109.5 ?
N9 C15 H15B . 109.5 ?
H15 C15 H15B . 109.5 ?
H15A C15 H15B . 109.5 ?
F2B B1 F1 . 118.2(10) ?
F3A B1 F1 . 119.1(9) ?
F2B B1 F4B . 114.8(11) ?
F1 B1 F4B . 107.1(7) ?
F3A B1 F2A . 109.5(9) ?
F1 B1 F2A . 109.7(7) ?
F3A B1 F4A . 107.2(8) ?
F1 B1 F4A . 106.6(8) ?
F2A B1 F4A . 103.5(9) ?
F2B B1 F3B . 106.0(10) ?
F1 B1 F3B . 104.4(9) ?
F4B B1 F3B . 105.0(9) ?
F5 B2A F6A . 111.6(13) ?
F5 B2A F8A . 109.3(12) ?
F6A B2A F8A . 109.5(13) ?
F5 B2A F7A . 108.9(12) ?
F6A B2A F7A . 109.0(13) ?
F8A B2A F7A . 108.4(12) ?
F5 B2B F7B . 111.9(12) ?
F5 B2B F8B . 108.9(12) ?
F7B B2B F8B . 108.8(12) ?
F5 B2B F6B . 107.7(11) ?
F7B B2B F6B . 109.3(12) ?
F8B B2B F6B . 110.2(12) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Rh1 N7 . 2.041(5) y
Rh1 N5 . 2.042(4) y
Rh1 N3 . 2.049(4) y
Rh1 N1 . 2.057(4) y
Rh1 O1 . 2.266(5) y
Rh1 Rh1 2_655 2.6313(18) y
N1 C1 . 1.331(7) ?
N1 C3 . 1.352(7) ?
C1 N2 . 1.337(7) ?
C1 C4 . 1.444(8) ?
N2 C2 . 1.350(8) ?
N2 H2N . 0.8600 ?
C2 C3 . 1.358(9) ?
C2 H2 . 0.9300 ?
C3 H3 . 0.9300 ?
N3 C4 . 1.328(7) ?
N3 C6 . 1.363(7) ?
C4 N4 . 1.331(7) ?
N4 C5 . 1.365(8) ?
N4 H4N . 0.8600 ?
C5 C6 . 1.348(9) ?
C5 H5 . 0.9300 ?
C6 H6 . 0.9300 ?
N5 C7 . 1.336(7) ?
N5 C9 . 1.368(7) ?
C7 N6 . 1.332(7) ?
C7 C10 . 1.442(8) ?
N6 C8 . 1.357(8) ?
N6 H6N . 0.8600 ?
C8 C9 . 1.348(9) ?
C8 H8 . 0.9300 ?
C9 H9 . 0.9300 ?
N7 C10 . 1.324(7) ?
N7 C12 . 1.364(7) ?
C10 N8 . 1.339(7) ?
N8 C11 . 1.353(9) ?
N8 H8N . 0.8600 ?
C11 C12 . 1.366(9) ?
C11 H11 . 0.9300 ?
C12 H12 . 0.9300 ?
O1 C13 . 1.216(9) ?
C13 N9 . 1.319(9) ?
C13 H13 . 0.9300 ?
N9 C14 . 1.439(11) ?
N9 C15 . 1.458(10) ?
C14 H14 . 0.9600 ?
C14 H14A . 0.9600 ?
C14 H14B . 0.9600 ?
C15 H15 . 0.9600 ?
C15 H15A . 0.9600 ?
C15 H15B . 0.9600 ?
B1 F2B . 1.300(11) ?
B1 F3A . 1.306(10) ?
B1 F1 . 1.338(8) ?
B1 F4B . 1.349(10) ?
B1 F2A . 1.389(10) ?
B1 F4A . 1.408(11) ?
B1 F3B . 1.412(12) ?
B2A F5 . 1.330(13) ?
B2A F6A . 1.333(14) ?
B2A F8A . 1.341(14) ?
B2A F7A . 1.344(14) ?
B2B F5 . 1.324(13) ?
B2B F7B . 1.331(13) ?
B2B F8B . 1.333(13) ?
B2B F6B . 1.350(13) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
N2 H2N F5 0.86 1.93 2.786(8) 170.1 y
N4 H4N F8B 0.86 1.97 2.818(15) 170.7 y
N4 H4N F7A 0.86 1.98 2.738(17) 145.8 y
N6 H6N F4B 0.86 1.94 2.773(13) 162.7 y
N6 H6N F4A 0.86 2.09 2.927(16) 165.9 y
N6 H6N F3A 0.86 2.54 3.19(2) 133.6 y
N8 H8N F2A 0.86 1.97 2.817(15) 166.8 y
N8 H8N F2B 0.86 2.08 2.884(19) 154.9 y
N8 H8N F3B 0.86 2.43 3.169(19) 144.2 y
N8 H8N F3A 0.86 2.56 3.227(15) 135.7 y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
N1 Rh1 Rh1 N3 . 2_655 2_655 -43.72(18) y
N5 Rh1 Rh1 N7 . 2_655 2_655 -43.72(17) y
N7 Rh1 N1 C1 . . . 81(2) ?
N5 Rh1 N1 C1 . . . 169.0(4) ?
N3 Rh1 N1 C1 . . . -4.3(4) ?
O1 Rh1 N1 C1 . . . 84.5(4) ?
Rh1 Rh1 N1 C1 2_655 . . -97.4(4) ?
N7 Rh1 N1 C3 . . . -93(2) ?
N5 Rh1 N1 C3 . . . -5.4(7) ?
N3 Rh1 N1 C3 . . . -178.7(7) ?
O1 Rh1 N1 C3 . . . -89.8(6) ?
Rh1 Rh1 N1 C3 2_655 . . 88.2(6) ?
C3 N1 C1 N2 . . . -0.4(7) ?
Rh1 N1 C1 N2 . . . -176.7(4) ?
C3 N1 C1 C4 . . . 178.4(5) ?
Rh1 N1 C1 C4 . . . 2.1(7) ?
N1 C1 N2 C2 . . . -0.3(8) ?
C4 C1 N2 C2 . . . -178.8(7) ?
C1 N2 C2 C3 . . . 0.9(8) ?
C1 N1 C3 C2 . . . 1.0(7) ?
Rh1 N1 C3 C2 . . . 175.6(5) ?
N2 C2 C3 N1 . . . -1.2(8) ?
N7 Rh1 N3 C4 . . . -169.1(4) ?
N5 Rh1 N3 C4 . . . -81.0(15) ?
N1 Rh1 N3 C4 . . . 6.1(4) ?
O1 Rh1 N3 C4 . . . -84.7(4) ?
Rh1 Rh1 N3 C4 2_655 . . 98.2(4) ?
N7 Rh1 N3 C6 . . . -1.4(7) ?
N5 Rh1 N3 C6 . . . 86.7(16) ?
N1 Rh1 N3 C6 . . . 173.8(7) ?
O1 Rh1 N3 C6 . . . 83.0(6) ?
Rh1 Rh1 N3 C6 2_655 . . -94.2(6) ?
C6 N3 C4 N4 . . . 0.2(7) ?
Rh1 N3 C4 N4 . . . 171.9(4) ?
C6 N3 C4 C1 . . . -178.6(5) ?
Rh1 N3 C4 C1 . . . -6.9(7) ?
N1 C1 C4 N3 . . . 3.2(8) ?
N2 C1 C4 N3 . . . -178.3(6) ?
N1 C1 C4 N4 . . . -175.2(6) ?
N2 C1 C4 N4 . . . 3.3(12) ?
N3 C4 N4 C5 . . . 0.0(7) ?
C1 C4 N4 C5 . . . 178.5(7) ?
C4 N4 C5 C6 . . . -0.2(7) ?
N4 C5 C6 N3 . . . 0.3(8) ?
C4 N3 C6 C5 . . . -0.3(7) ?
Rh1 N3 C6 C5 . . . -168.5(5) ?
N7 Rh1 N5 C7 . . . 10.7(4) ?
N3 Rh1 N5 C7 . . . -78.6(15) ?
N1 Rh1 N5 C7 . . . -164.4(4) ?
O1 Rh1 N5 C7 . . . -74.8(4) ?
Rh1 Rh1 N5 C7 2_655 . . 102.3(4) ?
N7 Rh1 N5 C9 . . . 171.5(6) ?
N3 Rh1 N5 C9 . . . 82.2(16) ?
N1 Rh1 N5 C9 . . . -3.7(6) ?
O1 Rh1 N5 C9 . . . 85.9(6) ?
Rh1 Rh1 N5 C9 2_655 . . -97.0(6) ?
C9 N5 C7 N6 . . . 1.2(7) ?
Rh1 N5 C7 N6 . . . 168.2(4) ?
C9 N5 C7 C10 . . . -177.3(5) ?
Rh1 N5 C7 C10 . . . -10.3(7) ?
N5 C7 N6 C8 . . . 0.0(8) ?
C10 C7 N6 C8 . . . 178.1(7) ?
C7 N6 C8 C9 . . . -1.2(9) ?
N6 C8 C9 N5 . . . 1.9(8) ?
C7 N5 C9 C8 . . . -1.9(7) ?
Rh1 N5 C9 C8 . . . -163.4(5) ?
N5 Rh1 N7 C10 . . . -9.7(4) ?
N3 Rh1 N7 C10 . . . 163.6(4) ?
N1 Rh1 N7 C10 . . . 79(2) ?
O1 Rh1 N7 C10 . . . 75.6(4) ?
Rh1 Rh1 N7 C10 2_655 . . -102.4(4) ?
N5 Rh1 N7 C12 . . . 179.1(6) ?
N3 Rh1 N7 C12 . . . -7.5(6) ?
N1 Rh1 N7 C12 . . . -92(2) ?
O1 Rh1 N7 C12 . . . -95.6(6) ?
Rh1 Rh1 N7 C12 2_655 . . 86.4(6) ?
C12 N7 C10 N8 . . . 0.4(7) ?
Rh1 N7 C10 N8 . . . -173.7(4) ?
C12 N7 C10 C7 . . . -178.7(5) ?
Rh1 N7 C10 C7 . . . 7.2(7) ?
N6 C7 C10 N7 . . . -175.9(7) ?
N5 C7 C10 N7 . . . 2.1(8) ?
N6 C7 C10 N8 . . . 5.1(13) ?
N5 C7 C10 N8 . . . -176.8(7) ?
N7 C10 N8 C11 . . . -0.5(8) ?
C7 C10 N8 C11 . . . 178.5(7) ?
C10 N8 C11 C12 . . . 0.3(9) ?
C10 N7 C12 C11 . . . -0.2(7) ?
Rh1 N7 C12 C11 . . . 171.3(5) ?
N8 C11 C12 N7 . . . -0.1(8) ?
N7 Rh1 O1 C13 . . . -136.6(5) ?
N5 Rh1 O1 C13 . . . -56.3(5) ?
N3 Rh1 O1 C13 . . . 123.3(5) ?
N1 Rh1 O1 C13 . . . 43.7(5) ?
Rh1 Rh1 O1 C13 2_655 . . -105.3(17) ?
Rh1 O1 C13 N9 . . . 163.8(6) ?
O1 C13 N9 C14 . . . -3.6(13) ?
O1 C13 N9 C15 . . . 177.8(8) ?
