#------------------------------------------------------------------------------
#$Date: 2018-10-05 15:19:55 +0300 (Fri, 05 Oct 2018) $
#$Revision: 211332 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/10/72/2107297.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2107297
loop_
_publ_author_name
'McMillen, Colin D.'
'Comer, Sara'
'Fulle, Kyle'
'Sanjeewa, Liurukara D.'
'Kolis, Joseph W.'
_publ_section_title
;
 Crystal chemistry of hydrothermally grown ternary alkali rare earth
 fluorides
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              768
_journal_page_last               776
_journal_paper_doi               10.1107/S2052520615017916
_journal_volume                  71
_journal_year                    2015
_chemical_formula_sum            'F10 Rb Y3'
_chemical_formula_weight         542.20
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           186
_symmetry_cell_setting           hexagonal
_symmetry_space_group_name_Hall  'P 6c -2c'
_symmetry_space_group_name_H-M   'P 63 m c'
_atom_sites_solution_hydrogens   none
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                120.00
_cell_formula_units_Z            4
_cell_length_a                   8.1976(12)
_cell_length_b                   8.1976(12)
_cell_length_c                   13.384(3)
_cell_measurement_reflns_used    3303
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.7371
_cell_measurement_theta_min      2.8691
_cell_volume                     778.9(2)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC, 2006)'
_computing_data_collection       'CrystalClear (Rigaku/MSC, 2006)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC, 2006)'
_computing_molecular_graphics    'DIAMOND (Bradenburg, 1999)'
_computing_publication_material  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 14.6199
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Rigaku AFC8S'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0572
_diffrn_reflns_av_sigmaI/netI    0.0219
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       9
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            6434
_diffrn_reflns_theta_full        25.24
_diffrn_reflns_theta_max         25.24
_diffrn_reflns_theta_min         2.87
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    28.509
_exptl_absorpt_correction_T_max  1.0000
_exptl_absorpt_correction_T_min  0.6920
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   'REQAB, CrystalClear'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    4.624
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             976
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.170
_refine_diff_density_min         -0.859
_refine_ls_abs_structure_details 'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack   0.21(3)
_refine_ls_extinction_coef       0.0057(5)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     SHELXL
_refine_ls_goodness_of_fit_ref   1.160
_refine_ls_hydrogen_treatment    none
_refine_ls_matrix_type           full
_refine_ls_number_parameters     60
_refine_ls_number_reflns         557
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      1.159
_refine_ls_R_factor_all          0.0324
_refine_ls_R_factor_gt           0.0303
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0412P)²+3.0565P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0845
_refine_ls_wR_factor_ref         0.0857
_reflns_number_gt                522
_reflns_number_total             557
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            bp5082sup1.cif
_cod_data_source_block           RbY3F10
_cod_depositor_comments
;
The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Hexagonal' changed to 'hexagonal'
according to
/usr/data/users/saulius/crontab/automatic-downloads/rss-feeds/IUCr/lib/dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.2 from 2011-04-26.

'_exptl_crystal_density_meas' value 'not measured' was changed to '?'
- the value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 4268 2015-11-12 08:31:59Z antanas 
;
_cod_original_sg_symbol_H-M      P6(3)mc
_cod_database_code               2107297
_cod_database_fobs_code          2107297
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-y, x-y, z'
'-x+y, -x, z'
'-x, -y, z+1/2'
'y, -x+y, z+1/2'
'x-y, x, z+1/2'
'-y, -x, z'
'-x+y, y, z'
'x, x-y, z'
'y, x, z+1/2'
'x-y, -y, z+1/2'
'-x, -x+y, z+1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_symmetry_multiplicity
Rb Rb1 0.3333 0.6667 0.95169(17) 0.0163(6) Uani d S 1 6
Rb Rb2 0.0000 1.0000 0.70814(19) 0.0209(9) Uani d S 1 6
Y Y1 0.01072(15) 0.50536(7) 0.69776(8) 0.0085(3) Uani d S 1 2
Y Y2 0.34722(14) 0.17361(7) 0.95759(8) 0.0083(4) Uani d S 1 2
F F1 0.3333 0.6667 0.7412(12) 0.017(3) Uani d S 1 6
F F2 0.6667 0.3333 0.9128(11) 0.010(3) Uani d S 1 6
F F3 0.0435(9) 0.5217(5) 0.5225(6) 0.0115(15) Uani d S 1 2
F F4 0.3664(10) 0.1832(5) 1.1334(7) 0.0136(17) Uani d S 1 2
F F5 0.3396(7) 0.0032(9) 0.8284(9) 0.0188(8) Uani d . 1 1
F F6 -0.2218(5) 0.2218(5) 0.6594(7) 0.0167(15) Uani d S 1 2
F F7 0.1105(5) -0.1105(5) 0.9894(7) 0.0177(16) Uani d S 1 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Rb Rb -0.9393 2.9676 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Y Y -2.7962 3.5667 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
F1 Rb1 F3 . 6_665 109.51(19)
F1 Rb1 F3 . 4_565 109.51(19)
F3 Rb1 F3 6_665 4_565 109.43(19)
F1 Rb1 F3 . 5 109.51(19)
F3 Rb1 F3 6_665 5 109.43(19)
F3 Rb1 F3 4_565 5 109.43(19)
F1 Rb1 F5 . 7_565 58.9(2)
F3 Rb1 F5 6_665 7_565 100.71(13)
F3 Rb1 F5 4_565 7_565 57.8(2)
F3 Rb1 F5 5 7_565 149.85(15)
F1 Rb1 F5 . 2 58.9(2)
F3 Rb1 F5 6_665 2 149.85(15)
F3 Rb1 F5 4_565 2 57.8(2)
F3 Rb1 F5 5 2 100.71(13)
F5 Rb1 F5 7_565 2 49.1(2)
F1 Rb1 F5 . 1_565 58.9(2)
F3 Rb1 F5 6_665 1_565 57.8(2)
F3 Rb1 F5 4_565 1_565 100.71(13)
F3 Rb1 F5 5 1_565 149.85(15)
F5 Rb1 F5 7_565 1_565 52.2(2)
F5 Rb1 F5 2 1_565 95.7(3)
F1 Rb1 F5 . 8_665 58.9(2)
F3 Rb1 F5 6_665 8_665 57.8(2)
F3 Rb1 F5 4_565 8_665 149.85(15)
F3 Rb1 F5 5 8_665 100.71(13)
F5 Rb1 F5 7_565 8_665 95.7(3)
F5 Rb1 F5 2 8_665 117.7(4)
F5 Rb1 F5 1_565 8_665 49.1(2)
F1 Rb1 F5 . 9 58.9(2)
F3 Rb1 F5 6_665 9 149.85(15)
F3 Rb1 F5 4_565 9 100.71(13)
F3 Rb1 F5 5 9 57.8(2)
F5 Rb1 F5 7_565 9 95.7(3)
F5 Rb1 F5 2 9 52.2(2)
F5 Rb1 F5 1_565 9 117.7(4)
F5 Rb1 F5 8_665 9 95.7(3)
F1 Rb1 F5 . 3_665 58.9(2)
F3 Rb1 F5 6_665 3_665 100.71(13)
F3 Rb1 F5 4_565 3_665 149.85(15)
F3 Rb1 F5 5 3_665 57.8(2)
F5 Rb1 F5 7_565 3_665 117.7(4)
F5 Rb1 F5 2 3_665 95.7(3)
F5 Rb1 F5 1_565 3_665 95.7(3)
F5 Rb1 F5 8_665 3_665 52.2(2)
F5 Rb1 F5 9 3_665 49.1(2)
F1 Rb1 F6 . 4_565 150.33(15)
F3 Rb1 F6 6_665 4_565 58.44(15)
F3 Rb1 F6 4_565 4_565 58.44(15)
F3 Rb1 F6 5 4_565 100.2(3)
F5 Rb1 F6 7_565 4_565 94.9(2)
F5 Rb1 F6 2 4_565 116.24(18)
F5 Rb1 F6 1_565 4_565 94.9(2)
F5 Rb1 F6 8_665 4_565 116.24(18)
F5 Rb1 F6 9 4_565 145.0(2)
F5 Rb1 F6 3_665 4_565 145.0(2)
F1 Rb1 F6 . 6_665 150.33(15)
F3 Rb1 F6 6_665 6_665 58.44(15)
F3 Rb1 F6 4_565 6_665 100.2(3)
F3 Rb1 F6 5 6_665 58.44(15)
F5 Rb1 F6 7_565 6_665 145.0(2)
F5 Rb1 F6 2 6_665 145.0(2)
F5 Rb1 F6 1_565 6_665 116.24(18)
F5 Rb1 F6 8_665 6_665 94.9(2)
F5 Rb1 F6 9 6_665 116.24(18)
F5 Rb1 F6 3_665 6_665 94.9(2)
F6 Rb1 F6 4_565 6_665 50.8(2)
F4 Rb2 F4 4_564 5_564 107.9(2)
F4 Rb2 F4 4_564 6_564 107.9(2)
F4 Rb2 F4 5_564 6_564 107.9(2)
F4 Rb2 F5 4_564 9_565 151.95(15)
F4 Rb2 F5 5_564 9_565 100.01(16)
F4 Rb2 F5 6_564 9_565 59.0(2)
F4 Rb2 F5 4_564 2_565 100.01(16)
F4 Rb2 F5 5_564 2_565 151.95(15)
F4 Rb2 F5 6_564 2_565 59.0(2)
F5 Rb2 F5 9_565 2_565 52.0(3)
F4 Rb2 F5 4_564 3_565 59.0(2)
F4 Rb2 F5 5_564 3_565 100.01(16)
F4 Rb2 F5 6_564 3_565 151.95(15)
F5 Rb2 F5 9_565 3_565 119.7(4)
F5 Rb2 F5 2_565 3_565 97.0(3)
F4 Rb2 F5 4_564 1_565 151.95(15)
F4 Rb2 F5 5_564 1_565 59.0(2)
F4 Rb2 F5 6_564 1_565 100.01(16)
F5 Rb2 F5 9_565 1_565 50.5(2)
F5 Rb2 F5 2_565 1_565 97.0(3)
F5 Rb2 F5 3_565 1_565 97.0(3)
F4 Rb2 F5 4_564 8_565 59.0(2)
F4 Rb2 F5 5_564 8_565 151.95(15)
F4 Rb2 F5 6_564 8_565 100.01(16)
F5 Rb2 F5 9_565 8_565 97.0(3)
F5 Rb2 F5 2_565 8_565 50.5(2)
F5 Rb2 F5 3_565 8_565 52.0(3)
F5 Rb2 F5 1_565 8_565 119.7(4)
F4 Rb2 F5 4_564 7_565 100.01(16)
F4 Rb2 F5 5_564 7_565 59.0(2)
F4 Rb2 F5 6_564 7_565 151.95(15)
F5 Rb2 F5 9_565 7_565 97.0(3)
F5 Rb2 F5 2_565 7_565 119.7(4)
F5 Rb2 F5 3_565 7_565 50.5(2)
F5 Rb2 F5 1_565 7_565 52.0(3)
F5 Rb2 F5 8_565 7_565 97.0(3)
F4 Rb2 F6 4_564 2_565 58.01(6)
F4 Rb2 F6 5_564 2_565 58.01(6)
F4 Rb2 F6 6_564 2_565 147.3(3)
F5 Rb2 F6 9_565 2_565 146.3(2)
F5 Rb2 F6 2_565 2_565 146.3(2)
F5 Rb2 F6 3_565 2_565 50.60(19)
F5 Rb2 F6 1_565 2_565 96.25(14)
F5 Rb2 F6 8_565 2_565 96.25(15)
F5 Rb2 F6 7_565 2_565 50.60(19)
F4 Rb2 F6 4_564 3_565 147.3(3)
F4 Rb2 F6 5_564 3_565 58.01(6)
F4 Rb2 F6 6_564 3_565 58.01(6)
F5 Rb2 F6 9_565 3_565 50.60(19)
F5 Rb2 F6 2_565 3_565 96.25(15)
F5 Rb2 F6 3_565 3_565 146.3(2)
F5 Rb2 F6 1_565 3_565 50.60(19)
F5 Rb2 F6 8_565 3_565 146.3(2)
F5 Rb2 F6 7_565 3_565 96.25(14)
F6 Rb2 F6 2_565 3_565 115.99(12)
F4 Rb2 F6 4_564 1_565 58.01(6)
F4 Rb2 F6 5_564 1_565 147.3(3)
F4 Rb2 F6 6_564 1_565 58.01(6)
F5 Rb2 F6 9_565 1_565 96.25(14)
F5 Rb2 F6 2_565 1_565 50.60(19)
F5 Rb2 F6 3_565 1_565 96.25(14)
F5 Rb2 F6 1_565 1_565 146.3(2)
F5 Rb2 F6 8_565 1_565 50.60(19)
F5 Rb2 F6 7_565 1_565 146.3(2)
F6 Rb2 F6 2_565 1_565 115.99(13)
F6 Rb2 F6 3_565 1_565 115.99(13)
F5 Y1 F5 7_565 2 74.3(4)
F5 Y1 F6 7_565 . 121.8(3)
F5 Y1 F6 2 . 77.1(3)
F5 Y1 F6 7_565 2_565 77.1(3)
F5 Y1 F6 2 2_565 121.8(3)
F6 Y1 F6 . 2_565 76.9(4)
F5 Y1 F3 7_565 . 142.8(2)
F5 Y1 F3 2 . 142.8(2)
F6 Y1 F3 . . 80.9(3)
F6 Y1 F3 2_565 . 80.9(3)
F5 Y1 F1 7_565 . 81.2(4)
F5 Y1 F1 2 . 81.2(4)
F6 Y1 F1 . . 141.5(2)
F6 Y1 F1 2_565 . 141.5(2)
F3 Y1 F1 . . 98.6(4)
F5 Y1 F4 7_565 5_564 80.9(3)
F5 Y1 F4 2 5_564 141.3(3)
F6 Y1 F4 . 5_564 141.6(3)
F6 Y1 F4 2_565 5_564 79.5(2)
F3 Y1 F4 . 5_564 65.7(2)
F1 Y1 F4 . 5_564 65.8(2)
F5 Y1 F4 7_565 6_554 141.3(3)
F5 Y1 F4 2 6_554 80.9(3)
F6 Y1 F4 . 6_554 79.5(2)
F6 Y1 F4 2_565 6_554 141.6(3)
F3 Y1 F4 . 6_554 65.7(2)
F1 Y1 F4 . 6_554 65.8(2)
F4 Y1 F4 5_564 6_554 101.9(4)
F5 Y1 Y2 7_565 6_554 164.43(18)
F5 Y1 Y2 2 6_554 111.2(2)
F6 Y1 Y2 . 6_554 73.7(2)
F6 Y1 Y2 2_565 6_554 109.8(2)
F3 Y1 Y2 . 6_554 32.78(6)
F1 Y1 Y2 . 6_554 85.2(3)
F4 Y1 Y2 5_564 6_554 86.6(2)
F4 Y1 Y2 6_554 6_554 33.5(2)
F5 Y1 Y2 7_565 5_564 111.2(2)
F5 Y1 Y2 2 5_564 164.43(18)
F6 Y1 Y2 . 5_564 109.8(2)
F6 Y1 Y2 2_565 5_564 73.7(2)
F3 Y1 Y2 . 5_564 32.78(6)
F1 Y1 Y2 . 5_564 85.2(3)
F4 Y1 Y2 5_564 5_564 33.5(2)
F4 Y1 Y2 6_554 5_564 86.6(2)
Y2 Y1 Y2 6_554 5_564 59.79(4)
F5 Y1 Y1 7_565 3_565 74.74(18)
F5 Y1 Y1 2 3_565 109.9(2)
F6 Y1 Y1 . 3_565 163.4(2)
F6 Y1 Y1 2_565 3_565 109.70(19)
F3 Y1 Y1 . 3_565 85.10(14)
F1 Y1 Y1 . 3_565 32.93(14)
F4 Y1 Y1 5_564 3_565 33.44(15)
F4 Y1 Y1 6_554 3_565 86.69(15)
Y2 Y1 Y1 6_554 3_565 89.72(2)
Y2 Y1 Y1 5_564 3_565 59.777(17)
F5 Y1 Y1 7_565 2_665 109.93(19)
F5 Y1 Y1 2 2_665 74.74(17)
F6 Y1 Y1 . 2_665 109.70(19)
F6 Y1 Y1 2_565 2_665 163.4(2)
F3 Y1 Y1 . 2_665 85.10(14)
F1 Y1 Y1 . 2_665 32.93(14)
F4 Y1 Y1 5_564 2_665 86.69(15)
F4 Y1 Y1 6_554 2_665 33.44(15)
Y2 Y1 Y1 6_554 2_665 59.777(17)
Y2 Y1 Y1 5_564 2_665 89.72(2)
Y1 Y1 Y1 3_565 2_665 60.0
F7 Y2 F7 . 2 76.2(4)
F7 Y2 F5 . . 75.6(3)
F7 Y2 F5 2 . 121.0(3)
F7 Y2 F5 . 9 121.0(3)
F7 Y2 F5 2 9 75.6(3)
F5 Y2 F5 . 9 76.6(5)
F7 Y2 F3 . 5 143.4(3)
F7 Y2 F3 2 5 82.1(3)
F5 Y2 F3 . 5 141.0(3)
F5 Y2 F3 9 5 80.3(3)
F7 Y2 F3 . 6_655 82.1(3)
F7 Y2 F3 2 6_655 143.4(3)
F5 Y2 F3 . 6_655 80.3(3)
F5 Y2 F3 9 6_655 141.0(3)
F3 Y2 F3 5 6_655 99.3(3)
F7 Y2 F2 . . 141.91(19)
F7 Y2 F2 2 . 141.9(2)
F5 Y2 F2 . . 79.8(3)
F5 Y2 F2 9 . 79.8(3)
F3 Y2 F2 5 . 65.3(2)
F3 Y2 F2 6_655 . 65.3(2)
F7 Y2 F4 . . 81.4(3)
F7 Y2 F4 2 . 81.4(3)
F5 Y2 F4 . . 141.7(2)
F5 Y2 F4 9 . 141.7(2)
F3 Y2 F4 5 . 66.3(2)
F3 Y2 F4 6_655 . 66.3(2)
F2 Y2 F4 . . 101.5(4)
F7 Y2 Y2 . 3_665 165.7(2)
F7 Y2 Y2 2 3_665 110.63(19)
F5 Y2 Y2 . 3_665 109.33(18)
F5 Y2 Y2 9 3_665 73.22(15)
F3 Y2 Y2 5 3_665 32.85(16)
F3 Y2 Y2 6_655 3_665 85.53(15)
F2 Y2 Y2 . 3_665 33.15(14)
F4 Y2 Y2 . 3_665 87.13(15)
F7 Y2 Y2 . 2_655 110.63(18)
F7 Y2 Y2 2 2_655 165.7(2)
F5 Y2 Y2 . 2_655 73.22(15)
F5 Y2 Y2 9 2_655 109.33(18)
F3 Y2 Y2 5 2_655 85.53(15)
F3 Y2 Y2 6_655 2_655 32.85(16)
F2 Y2 Y2 . 2_655 33.15(14)
F4 Y2 Y2 . 2_655 87.13(15)
Y2 Y2 Y2 3_665 2_655 60.0
F7 Y2 Y1 . 5 111.7(3)
F7 Y2 Y1 2 5 75.5(2)
F5 Y2 Y1 . 5 163.49(15)
F5 Y2 Y1 9 5 109.6(2)
F3 Y2 Y1 5 5 33.09(19)
F3 Y2 Y1 6_655 5 85.96(19)
F2 Y2 Y1 . 5 86.2(3)
F4 Y2 Y1 . 5 33.81(7)
Y2 Y2 Y1 3_665 5 60.104(18)
Y2 Y2 Y1 2_655 5 90.28(2)
F7 Y2 Y1 . 6_655 75.5(2)
F7 Y2 Y1 2 6_655 111.7(3)
F5 Y2 Y1 . 6_655 109.6(2)
F5 Y2 Y1 9 6_655 163.49(15)
F3 Y2 Y1 5 6_655 85.96(19)
F3 Y2 Y1 6_655 6_655 33.09(19)
F2 Y2 Y1 . 6_655 86.2(3)
F4 Y2 Y1 . 6_655 33.81(7)
Y2 Y2 Y1 3_665 6_655 90.28(2)
Y2 Y2 Y1 2_655 6_655 60.104(18)
Y1 Y2 Y1 5 6_655 60.45(3)
Y1 F1 Y1 . 3_565 114.1(3)
Y1 F1 Y1 . 2_665 114.1(3)
Y1 F1 Y1 3_565 2_665 114.1(3)
Y1 F1 Rb1 . . 104.3(4)
Y1 F1 Rb1 3_565 . 104.3(4)
Y1 F1 Rb1 2_665 . 104.3(4)
Y2 F2 Y2 2_655 3_665 113.7(3)
Y2 F2 Y2 2_655 . 113.7(3)
Y2 F2 Y2 3_665 . 113.7(3)
Y2 F3 Y2 6_554 5_564 114.3(3)
Y2 F3 Y1 6_554 . 114.1(2)
Y2 F3 Y1 5_564 . 114.1(2)
Y2 F3 Rb1 6_554 4_564 104.4(2)
Y2 F3 Rb1 5_564 4_564 104.4(2)
Y1 F3 Rb1 . 4_564 103.8(3)
Y2 F4 Y1 . 5 112.7(2)
Y2 F4 Y1 . 6_655 112.7(2)
Y1 F4 Y1 5 6_655 113.1(3)
Y2 F4 Rb2 . 4_565 107.7(3)
Y1 F4 Rb2 5 4_565 104.9(2)
Y1 F4 Rb2 6_655 4_565 104.9(2)
Y1 F5 Y2 3 . 145.4(3)
Y1 F5 Rb1 3 1_545 97.26(19)
Y2 F5 Rb1 . 1_545 97.2(4)
Y1 F5 Rb2 3 1_545 97.0(4)
Y2 F5 Rb2 . 1_545 98.52(18)
Rb1 F5 Rb2 1_545 1_545 127.9(2)
Y1 F6 Y1 . 3_455 146.9(4)
Y1 F6 Rb1 . 4_564 96.9(2)
Y1 F6 Rb1 3_455 4_564 96.9(2)
Y1 F6 Rb2 . 1_545 96.5(2)
Y1 F6 Rb2 3_455 1_545 96.5(2)
Rb1 F6 Rb2 4_564 1_545 131.4(3)
Y2 F7 Y2 3 . 151.5(4)
Y2 F7 Rb1 3 1_545 96.9(2)
Y2 F7 Rb1 . 1_545 96.9(2)
Y2 F7 Rb2 3 4_565 95.6(2)
Y2 F7 Rb2 . 4_565 95.6(2)
Rb1 F7 Rb2 1_545 4_565 127.2(3)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Rb1 F1 . 2.817(16)
Rb1 F3 6_665 2.838(7)
Rb1 F3 4_565 2.838(7)
Rb1 F3 5 2.838(7)
Rb1 F5 7_565 3.192(9)
Rb1 F5 2 3.192(9)
Rb1 F5 1_565 3.192(9)
Rb1 F5 8_665 3.192(9)
Rb1 F5 9 3.192(9)
Rb1 F5 3_665 3.192(9)
Rb1 F6 4_565 3.199(10)
Rb1 F6 6_665 3.199(10)
Rb2 F4 4_564 2.787(8)
Rb2 F4 5_564 2.787(7)
Rb2 F4 6_564 2.787(8)
Rb2 F5 9_565 3.205(8)
Rb2 F5 2_565 3.205(8)
Rb2 F5 3_565 3.205(8)
Rb2 F5 1_565 3.205(8)
Rb2 F5 8_565 3.205(8)
Rb2 F5 7_565 3.205(8)
Rb2 F6 2_565 3.216(8)
Rb2 F6 3_565 3.216(8)
Rb2 F6 1_565 3.216(8)
Y1 F5 7_565 2.198(10)
Y1 F5 2 2.198(10)
Y1 F6 . 2.207(3)
Y1 F6 2_565 2.207(3)
Y1 F3 . 2.357(8)
Y1 F1 . 2.363(4)
Y1 F4 5_564 2.377(4)
Y1 F4 6_554 2.377(4)
Y1 Y2 6_554 3.9405(15)
Y1 Y2 5_564 3.9405(15)
Y1 Y1 3_565 3.9670(19)
Y1 Y1 2_665 3.9670(19)
Y2 F7 . 2.203(2)
Y2 F7 2 2.203(2)
Y2 F5 . 2.204(10)
Y2 F5 9 2.204(10)
Y2 F3 5 2.338(4)
Y2 F3 6_655 2.338(4)
Y2 F2 . 2.346(4)
Y2 F4 . 2.357(9)
Y2 Y2 3_665 3.9281(19)
Y2 Y2 2_655 3.9280(18)
Y2 Y1 5 3.9405(15)
Y2 Y1 6_655 3.9405(15)
F1 Y1 3_565 2.363(4)
F1 Y1 2_665 2.363(4)
F2 Y2 2_655 2.346(4)
F2 Y2 3_665 2.346(4)
F3 Y2 6_554 2.338(4)
F3 Y2 5_564 2.338(4)
F3 Rb1 4_564 2.838(7)
F4 Y1 5 2.377(4)
F4 Y1 6_655 2.377(4)
F4 Rb2 4_565 2.787(7)
F5 Y1 3 2.198(10)
F5 Rb1 1_545 3.192(9)
F5 Rb2 1_545 3.205(8)
F6 Y1 3_455 2.207(3)
F6 Rb1 4_564 3.199(10)
F6 Rb2 1_545 3.216(8)
F7 Y2 3 2.203(2)
F7 Rb1 1_545 3.204(7)
F7 Rb2 4_565 3.321(10)
