#------------------------------------------------------------------------------
#$Date: 2018-12-07 05:37:15 +0200 (Fri, 07 Dec 2018) $
#$Revision: 212436 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/10/83/2108348.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2108348
loop_
_publ_author_name
'Siidra, Oleg I.'
'Kozin, Michael S.'
'Depmeier, Wulf'
'Kayukov, Roman A.'
'Kovrugin, Vadim M.'
_publ_section_title
;
 Copper--lead selenite bromides: a new large family of compounds partly
 having Cu²⁺ substructures derivable from kagome nets
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section B'
_journal_page_first              712
_journal_page_last               724
_journal_paper_doi               10.1107/S2052520618016542
_journal_volume                  74
_journal_year                    2018
_chemical_formula_sum            'Br22.16 Cu28 O64 Pb17.06 Se16'
_chemical_formula_weight         9371.95
_space_group_crystal_system      orthorhombic
_space_group_IT_number           65
_space_group_name_Hall           '-C 2 2'
_space_group_name_H-M_alt        'C m m m'
_symmetry_space_group_name_Hall  '-C 2 2'
_symmetry_space_group_name_H-M   'C m m m'
_audit_creation_method           SHELXL-2018/3
_cell_angle_alpha                90
_cell_angle_beta                 90
_cell_angle_gamma                90
_cell_formula_units_Z            1
_cell_length_a                   23.943(12)
_cell_length_b                   20.268(10)
_cell_length_c                   6.313(4)
_cell_measurement_reflns_used    740
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      21.382
_cell_measurement_theta_min      2.010
_cell_volume                     3064(3)
_computing_structure_refinement  'SHELXL-2018/3 (Sheldrick, 2018)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker Apex 2 Duo'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0976
_diffrn_reflns_av_unetI/netI     0.0549
_diffrn_reflns_Laue_measured_fraction_full 0.980
_diffrn_reflns_Laue_measured_fraction_max 0.980
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -24
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -3
_diffrn_reflns_number            6846
_diffrn_reflns_point_group_measured_fraction_full 0.980
_diffrn_reflns_point_group_measured_fraction_max 0.980
_diffrn_reflns_theta_full        21.382
_diffrn_reflns_theta_max         21.382
_diffrn_reflns_theta_min         2.010
_exptl_absorpt_coefficient_mu    40.126
_exptl_crystal_density_diffrn    5.080
_exptl_crystal_description       plate
_exptl_crystal_F_000             4043
_refine_diff_density_max         4.131
_refine_diff_density_min         -2.796
_refine_diff_density_rms         0.634
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.198
_refine_ls_hydrogen_treatment    undef
_refine_ls_matrix_type           full
_refine_ls_number_parameters     128
_refine_ls_number_reflns         1013
_refine_ls_number_restraints     6
_refine_ls_restrained_S_all      1.194
_refine_ls_R_factor_all          0.0963
_refine_ls_R_factor_gt           0.0726
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w=1/[σ²(Fo²)+(0.1072P)²+857.5312P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2085
_refine_ls_wR_factor_ref         0.2308
_reflns_Friedel_coverage         0.000
_reflns_number_gt                764
_reflns_number_total             1013
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ps5074sup1.cif
_cod_data_source_block           CuPbOXO4
_cod_database_code               2108348
_shelx_shelxl_version_number     2018/3
_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
loop_
_space_group_symop_operation_xyz
'x, y, z'
'-x, -y, z'
'x, -y, -z'
'-x, y, -z'
'x+1/2, y+1/2, z'
'-x+1/2, -y+1/2, z'
'x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z'
'-x, -y, -z'
'x, y, -z'
'-x, y, z'
'x, -y, z'
'-x+1/2, -y+1/2, -z'
'x+1/2, y+1/2, -z'
'-x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z'
loop_
_atom_site_label
_atom_site_type_symbol
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_occupancy
_atom_site_site_symmetry_order
_atom_site_calc_flag
_atom_site_refinement_flags_posn
_atom_site_refinement_flags_adp
_atom_site_refinement_flags_occupancy
Pb1 Pb 0.22507(12) 0.500000 0.500000 0.0237(9) Uani 1 4 d S T P
Pb2 Pb 0.10858(10) 0.22925(10) 0.000000 0.0356(9) Uani 1 2 d S T P
Se1 Se 0.1838(2) 0.3915(2) 0.000000 0.0209(14) Uani 1 2 d S T P
Se2 Se 0.0783(2) 0.1446(3) 0.500000 0.0236(14) Uani 1 2 d S T P
Cu1 Cu 0.19745(17) 0.12228(19) -0.2505(7) 0.0210(12) Uani 1 1 d . . .
Cu2 Cu 0.1377(4) 0.000000 0.500000 0.022(2) Uani 1 4 d S T P
Cu3 Cu 0.250000 0.250000 0.000000 0.022(2) Uani 1 4 d S T P
O1 O 0.1977(12) 0.1786(15) 0.000000 0.021(9) Uani 1 2 d S T P
O2 O 0.3046(13) 0.4319(15) 0.500000 0.019(8) Uani 1 2 d S T P
O3 O 0.0726(14) 0.0600(17) 0.500000 0.029(9) Uani 1 2 d S T P
O4 O 0.1855(14) 0.3079(16) 0.000000 0.026(9) Uani 1 2 d S TU P
O5 O 0.1218(10) 0.1573(12) 0.291(4) 0.031(7) Uani 1 1 d . . .
O6 O 0.2264(12) 0.4087(12) 0.216(5) 0.044(8) Uani 1 1 d . . .
Br1 Br 0.1454(5) 0.000000 0.000000 0.050(3) Uani 1 4 d S T P
Br2 Br 0.000000 0.1202(7) 0.000000 0.074(4) Uani 1 4 d S T P
Pb3A Pb 0.000000 0.000000 0.2913(12) 0.0373(18) Uani 0.5 4 d S T P
Pb3B Pb 0.0552(12) 0.000000 0.000000 0.043(7) Uiso 0.125 4 d S . P
Br3 Br 0.0914(4) 0.3131(5) 0.500000 0.022(2) Uani 0.5 2 d S T P
Br4 Br 0.1881(9) 0.3280(12) 0.500000 0.101(7) Uani 0.5 2 d S T P
Cu4 Cu 0.250000 0.250000 0.500000 0.029(2) Uani 1 4 d S T P
Pb4 Pb 0.000000 0.4069(5) 0.500000 0.128(4) Uani 0.64 4 d S T P
Br6 Br 0.4190(6) 0.000000 0.254(6) 0.144(14) Uani 0.5 2 d S T P
Br7 Br 0.000000 0.3485(9) 0.000000 0.051(5) Uani 0.54 4 d S T P
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Se Se -0.0929 2.2259 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
O2 Pb1 O2 71.8(15) 3_566 .
O2 Pb1 O6 114.3(9) 3_566 .
O2 Pb1 O6 64.4(8) . .
O2 Pb1 O6 64.4(8) 3_566 3_566
O2 Pb1 O6 114.3(9) . 3_566
O6 Pb1 O6 178.6(13) . 3_566
O2 Pb1 O6 64.4(8) 3_566 12_565
O2 Pb1 O6 114.3(9) . 12_565
O6 Pb1 O6 91.8(14) . 12_565
O6 Pb1 O6 88.2(14) 3_566 12_565
O2 Pb1 O6 114.3(9) 3_566 10_556
O2 Pb1 O6 64.4(8) . 10_556
O6 Pb1 O6 88.2(14) . 10_556
O6 Pb1 O6 91.8(14) 3_566 10_556
O6 Pb1 O6 178.6(13) 12_565 10_556
O2 Pb1 Cu2 35.9(8) 3_566 13_556
O2 Pb1 Cu2 35.9(8) . 13_556
O6 Pb1 Cu2 89.3(6) . 13_556
O6 Pb1 Cu2 89.3(6) 3_566 13_556
O6 Pb1 Cu2 89.3(6) 12_565 13_556
O6 Pb1 Cu2 89.3(6) 10_556 13_556
O2 Pb1 Cu1 31.7(4) 3_566 15_556
O2 Pb1 Cu1 89.2(7) . 15_556
O6 Pb1 Cu1 145.2(7) . 15_556
O6 Pb1 Cu1 33.4(6) 3_566 15_556
O6 Pb1 Cu1 78.2(6) 12_565 15_556
O6 Pb1 Cu1 101.0(7) 10_556 15_556
Cu2 Pb1 Cu1 57.72(8) 13_556 15_556
O2 Pb1 Cu1 31.7(4) 3_566 8
O2 Pb1 Cu1 89.2(7) . 8
O6 Pb1 Cu1 101.0(7) . 8
O6 Pb1 Cu1 78.2(6) 3_566 8
O6 Pb1 Cu1 33.4(6) 12_565 8
O6 Pb1 Cu1 145.2(7) 10_556 8
Cu2 Pb1 Cu1 57.72(8) 13_556 8
Cu1 Pb1 Cu1 53.93(15) 15_556 8
O2 Pb1 Cu1 89.2(7) 3_566 13
O2 Pb1 Cu1 31.7(4) . 13
O6 Pb1 Cu1 33.4(6) . 13
O6 Pb1 Cu1 145.2(7) 3_566 13
O6 Pb1 Cu1 101.0(7) 12_565 13
O6 Pb1 Cu1 78.2(6) 10_556 13
Cu2 Pb1 Cu1 57.72(8) 13_556 13
Cu1 Pb1 Cu1 115.44(16) 15_556 13
Cu1 Pb1 Cu1 91.05(15) 8 13
O2 Pb1 Cu1 89.2(7) 3_566 6_556
O2 Pb1 Cu1 31.7(4) . 6_556
O6 Pb1 Cu1 78.2(6) . 6_556
O6 Pb1 Cu1 101.0(7) 3_566 6_556
O6 Pb1 Cu1 145.2(7) 12_565 6_556
O6 Pb1 Cu1 33.4(6) 10_556 6_556
Cu2 Pb1 Cu1 57.72(8) 13_556 6_556
Cu1 Pb1 Cu1 91.05(15) 15_556 6_556
Cu1 Pb1 Cu1 115.44(16) 8 6_556
Cu1 Pb1 Cu1 53.93(15) 13 6_556
O2 Pb1 Br4 140.2(8) 3_566 .
O2 Pb1 Br4 68.3(8) . .
O6 Pb1 Br4 46.1(7) . .
O6 Pb1 Br4 134.4(7) 3_566 .
O6 Pb1 Br4 134.4(7) 12_565 .
O6 Pb1 Br4 46.1(7) 10_556 .
Cu2 Pb1 Br4 104.2(3) 13_556 .
Cu1 Pb1 Br4 145.4(2) 15_556 .
Cu1 Pb1 Br4 145.4(2) 8 .
Cu1 Pb1 Br4 55.9(3) 13 .
Cu1 Pb1 Br4 55.9(3) 6_556 .
O5 Pb2 O5 101.7(12) . 10
O5 Pb2 O1 67.2(7) . .
O5 Pb2 O1 67.2(7) 10 .
O5 Pb2 O4 107.6(8) . .
O5 Pb2 O4 107.6(8) 10 .
O1 Pb2 O4 66.6(11) . .
O5 Pb2 Br2 72.7(6) . .
O5 Pb2 Br2 72.7(6) 10 .
O1 Pb2 Br2 113.9(8) . .
O4 Pb2 Br2 179.5(8) . .
O5 Pb2 Cu3 86.8(6) . .
O5 Pb2 Cu3 86.8(6) 10 .
O1 Pb2 Cu3 32.8(7) . .
O4 Pb2 Cu3 33.8(8) . .
Br2 Pb2 Cu3 146.7(2) . .
O5 Pb2 Cu1 83.4(6) . .
O5 Pb2 Cu1 33.7(6) 10 .
O1 Pb2 Cu1 33.5(4) . .
O4 Pb2 Cu1 86.8(7) . .
Br2 Pb2 Cu1 93.64(19) . .
Cu3 Pb2 Cu1 57.42(8) . .
O5 Pb2 Cu1 33.7(6) . 10
O5 Pb2 Cu1 83.4(6) 10 10
O1 Pb2 Cu1 33.5(4) . 10
O4 Pb2 Cu1 86.8(7) . 10
Br2 Pb2 Cu1 93.64(19) . 10
Cu3 Pb2 Cu1 57.42(8) . 10
Cu1 Pb2 Cu1 55.01(15) . 10
O5 Pb2 Br7 121.2(6) . .
O5 Pb2 Br7 121.2(6) 10 .
O1 Pb2 Br7 162.8(8) . .
O4 Pb2 Br7 96.2(8) . .
Br2 Pb2 Br7 83.3(3) . .
Cu3 Pb2 Br7 130.0(2) . .
Cu1 Pb2 Br7 152.38(8) . .
Cu1 Pb2 Br7 152.38(8) 10 .
O5 Pb2 Br3 169.8(6) . 1_554
O5 Pb2 Br3 68.1(6) 10 1_554
O1 Pb2 Br3 107.9(3) . 1_554
O4 Pb2 Br3 77.2(4) . 1_554
Br2 Pb2 Br3 102.59(18) . 1_554
Cu3 Pb2 Br3 93.16(16) . 1_554
Cu1 Pb2 Br3 87.99(16) . 1_554
Cu1 Pb2 Br3 140.62(17) 10 1_554
Br7 Pb2 Br3 66.16(16) . 1_554
O5 Pb2 Br3 68.1(6) . .
O5 Pb2 Br3 169.8(6) 10 .
O1 Pb2 Br3 107.9(3) . .
O4 Pb2 Br3 77.2(4) . .
Br2 Pb2 Br3 102.59(18) . .
Cu3 Pb2 Br3 93.16(16) . .
Cu1 Pb2 Br3 140.62(17) . .
Cu1 Pb2 Br3 87.99(16) 10 .
Br7 Pb2 Br3 66.16(16) . .
Br3 Pb2 Br3 122.0(3) 1_554 .
O5 Pb2 Se2 21.5(6) . .
O5 Pb2 Se2 113.9(6) 10 .
O1 Pb2 Se2 88.6(4) . .
O4 Pb2 Se2 117.1(2) . .
Br2 Pb2 Se2 63.01(10) . .
Cu3 Pb2 Se2 104.71(9) . .
Cu1 Pb2 Se2 102.95(12) . .
Cu1 Pb2 Se2 55.16(11) 10 .
Br7 Pb2 Se2 100.02(14) . .
Br3 Pb2 Se2 162.04(19) 1_554 .
Br3 Pb2 Se2 56.26(17) . .
O4 Se1 O6 100.7(11) . 10
O4 Se1 O6 100.7(11) . .
O6 Se1 O6 103(2) 10 .
O4 Se1 Cu1 83.9(10) . 13
O6 Se1 Cu1 83.5(10) 10 13
O6 Se1 Cu1 29.1(9) . 13
O4 Se1 Cu1 83.9(10) . 6
O6 Se1 Cu1 29.1(9) 10 6
O6 Se1 Cu1 83.5(10) . 6
Cu1 Se1 Cu1 57.95(18) 13 6
O4 Se1 Cu3 27.6(12) . .
O6 Se1 Cu3 83.8(8) 10 .
O6 Se1 Cu3 83.8(8) . .
Cu1 Se1 Cu3 60.27(11) 13 .
Cu1 Se1 Cu3 60.27(11) 6 .
O4 Se1 Br4 67.8(4) . 1_554
O6 Se1 Br4 48.1(11) 10 1_554
O6 Se1 Br4 141.6(10) . 1_554
Cu1 Se1 Br4 112.9(4) 13 1_554
Cu1 Se1 Br4 59.5(4) 6 1_554
Cu3 Se1 Br4 69.8(3) . 1_554
O4 Se1 Br4 67.8(4) . .
O6 Se1 Br4 141.6(10) 10 .
O6 Se1 Br4 48.1(11) . .
Cu1 Se1 Br4 59.5(4) 13 .
Cu1 Se1 Br4 112.9(4) 6 .
Cu3 Se1 Br4 69.8(3) . .
Br4 Se1 Br4 135.5(7) 1_554 .
O4 Se1 Br6 127.9(10) . 13
O6 Se1 Br6 86.1(10) 10 13
O6 Se1 Br6 128.0(9) . 13
Cu1 Se1 Br6 147.9(2) 13 13
Cu1 Se1 Br6 115.1(5) 6 13
Cu3 Se1 Br6 148.1(4) . 13
Br4 Se1 Br6 80.9(6) 1_554 13
Br4 Se1 Br6 130.6(6) . 13
O4 Se1 Br6 127.9(10) . 6
O6 Se1 Br6 128.0(9) 10 6
O6 Se1 Br6 86.1(10) . 6
Cu1 Se1 Br6 115.1(5) 13 6
Cu1 Se1 Br6 147.9(2) 6 6
Cu3 Se1 Br6 148.1(4) . 6
Br4 Se1 Br6 130.6(6) 1_554 6
Br4 Se1 Br6 80.9(6) . 6
Br6 Se1 Br6 51.8(11) 13 6
O4 Se1 Pb2 30.1(12) . .
O6 Se1 Pb2 117.2(10) 10 .
O6 Se1 Pb2 117.2(10) . .
Cu1 Se1 Pb2 110.07(15) 13 .
Cu1 Se1 Pb2 110.07(15) 6 .
Cu3 Se1 Pb2 57.63(9) . .
Br4 Se1 Pb2 71.5(4) 1_554 .
Br4 Se1 Pb2 71.5(4) . .
Br6 Se1 Pb2 101.71(19) 13 .
Br6 Se1 Pb2 101.71(19) 6 .
O4 Se1 Pb1 123.2(4) . .
O6 Se1 Pb1 111.5(10) 10 .
O6 Se1 Pb1 28.3(8) . .
Cu1 Se1 Pb1 56.35(10) 13 .
Cu1 Se1 Pb1 102.47(15) 6 .
Cu3 Se1 Pb1 111.37(10) . .
Br4 Se1 Pb1 159.6(4) 1_554 .
Br4 Se1 Pb1 57.7(4) . .
Br6 Se1 Pb1 100.5(4) 13 .
Br6 Se1 Pb1 59.2(4) 6 .
Pb2 Se1 Pb1 127.23(6) . .
O5 Se2 O5 101.9(17) 10_556 .
O5 Se2 O3 101.5(11) 10_556 .
O5 Se2 O3 101.5(11) . .
O5 Se2 Cu2 82.5(8) 10_556 .
O5 Se2 Cu2 82.5(8) . .
O3 Se2 Cu2 30.4(11) . .
O5 Se2 Cu1 28.2(8) 10_556 1_556
O5 Se2 Cu1 82.1(8) . 1_556
O3 Se2 Cu1 86.1(10) . 1_556
Cu2 Se2 Cu1 59.86(16) . 1_556
O5 Se2 Cu1 82.1(8) 10_556 10
O5 Se2 Cu1 28.2(8) . 10
O3 Se2 Cu1 86.1(10) . 10
Cu2 Se2 Cu1 59.86(16) . 10
Cu1 Se2 Cu1 57.21(18) 1_556 10
O5 Se2 Br3 78.1(9) 10_556 .
O5 Se2 Br3 78.1(9) . .
O3 Se2 Br3 179.3(12) . .
Cu2 Se2 Br3 148.9(3) . .
Cu1 Se2 Br3 93.3(2) 1_556 .
Cu1 Se2 Br3 93.3(2) 10 .
O5 Se2 Pb2 118.5(9) 10_556 .
O5 Se2 Pb2 30.6(8) . .
O3 Se2 Pb2 118.8(2) . .
Cu2 Se2 Pb2 109.57(11) . .
Cu1 Se2 Pb2 107.77(15) 1_556 .
Cu1 Se2 Pb2 58.71(10) 10 .
Br3 Se2 Pb2 61.03(9) . .
O5 Se2 Pb2 30.6(8) 10_556 1_556
O5 Se2 Pb2 118.5(9) . 1_556
O3 Se2 Pb2 118.8(2) . 1_556
Cu2 Se2 Pb2 109.57(11) . 1_556
Cu1 Se2 Pb2 58.71(10) 1_556 1_556
Cu1 Se2 Pb2 107.77(15) 10 1_556
Br3 Se2 Pb2 61.03(9) . 1_556
Pb2 Se2 Pb2 118.91(16) . 1_556
O5 Se2 Br2 70.6(8) 10_556 1_556
O5 Se2 Br2 172.5(9) . 1_556
O3 Se2 Br2 80.0(6) . 1_556
Cu2 Se2 Br2 95.8(2) . 1_556
Cu1 Se2 Br2 90.72(10) 1_556 1_556
Cu1 Se2 Br2 145.95(18) 10 1_556
Br3 Se2 Br2 100.3(3) . 1_556
Pb2 Se2 Br2 153.7(2) . 1_556
Pb2 Se2 Br2 55.15(16) 1_556 1_556
O5 Se2 Br2 172.5(9) 10_556 .
O5 Se2 Br2 70.6(8) . .
O3 Se2 Br2 80.0(6) . .
Cu2 Se2 Br2 95.8(2) . .
Cu1 Se2 Br2 145.95(18) 1_556 .
Cu1 Se2 Br2 90.72(10) 10 .
Br3 Se2 Br2 100.3(3) . .
Pb2 Se2 Br2 55.15(16) . .
Pb2 Se2 Br2 153.7(2) 1_556 .
Br2 Se2 Br2 116.88(17) 1_556 .
O5 Se2 Pb3A 98.8(9) 10_556 9_556
O5 Se2 Pb3A 134.6(9) . 9_556
O3 Se2 Pb3A 34.4(9) . 9_556
Cu2 Se2 Pb3A 60.73(16) . 9_556
Cu1 Se2 Pb3A 99.16(14) 1_556 9_556
Cu1 Se2 Pb3A 119.89(17) 10 9_556
Br3 Se2 Pb3A 146.15(19) . 9_556
Pb2 Se2 Pb3A 140.67(15) . 9_556
Pb2 Se2 Pb3A 99.41(12) 1_556 9_556
Br2 Se2 Pb3A 48.6(2) 1_556 9_556
Br2 Se2 Pb3A 86.7(2) . 9_556
O2 Cu1 O6 86.0(12) 13 13
O2 Cu1 O1 178.4(12) 13 .
O6 Cu1 O1 95.5(12) 13 .
O2 Cu1 O5 94.4(12) 13 10
O6 Cu1 O5 177.4(11) 13 10
O1 Cu1 O5 84.0(12) . 10
O2 Cu1 Cu1 34.9(7) 13 10_554
O6 Cu1 Cu1 96.4(9) 13 10_554
O1 Cu1 Cu1 144.2(8) . 10_554
O5 Cu1 Cu1 82.6(8) 10 10_554
O2 Cu1 Cu1 145.1(7) 13 10
O6 Cu1 Cu1 83.6(9) 13 10
O1 Cu1 Cu1 35.8(8) . 10
O5 Cu1 Cu1 97.4(8) 10 10
Cu1 Cu1 Cu1 180.0 10_554 10
O2 Cu1 Br1 87.2(8) 13 .
O6 Cu1 Br1 93.4(9) 13 .
O1 Cu1 Br1 93.1(8) . .
O5 Cu1 Br1 89.1(8) 10 .
Cu1 Cu1 Br1 119.69(9) 10_554 .
Cu1 Cu1 Br1 60.31(9) 10 .
O2 Cu1 Se1 111.8(9) 13 13
O6 Cu1 Se1 25.8(8) 13 13
O1 Cu1 Se1 69.8(9) . 13
O5 Cu1 Se1 153.8(8) 10 13
Cu1 Cu1 Se1 118.97(9) 10_554 13
Cu1 Cu1 Se1 61.03(9) 10 13
Br1 Cu1 Se1 91.9(2) . 13
O2 Cu1 Cu2 32.8(9) 13 1_554
O6 Cu1 Cu2 102.7(7) 13 1_554
O1 Cu1 Cu2 146.7(9) . 1_554
O5 Cu1 Cu2 78.9(8) 10 1_554
Cu1 Cu1 Cu2 61.18(9) 10_554 1_554
Cu1 Cu1 Cu2 118.82(9) 10 1_554
Br1 Cu1 Cu2 58.60(10) . 1_554
Se1 Cu1 Cu2 123.37(19) 13 1_554
O2 Cu1 Cu4 93.9(8) 13 1_554
O6 Cu1 Cu4 87.1(9) 13 1_554
O1 Cu1 Cu4 85.8(8) . 1_554
O5 Cu1 Cu4 90.4(8) 10 1_554
Cu1 Cu1 Cu4 61.31(8) 10_554 1_554
Cu1 Cu1 Cu4 118.69(8) 10 1_554
Br1 Cu1 Cu4 178.79(17) . 1_554
Se1 Cu1 Cu4 88.06(13) 13 1_554
Cu2 Cu1 Cu4 122.36(14) 1_554 1_554
O2 Cu1 Cu3 148.8(9) 13 .
O6 Cu1 Cu3 80.9(7) 13 .
O1 Cu1 Cu3 31.5(8) . .
O5 Cu1 Cu3 97.5(8) 10 .
Cu1 Cu1 Cu3 118.79(8) 10_554 .
Cu1 Cu1 Cu3 61.21(8) 10 .
Br1 Cu1 Cu3 121.52(15) . .
Se1 Cu1 Cu3 60.04(11) 13 .
Cu2 Cu1 Cu3 176.42(19) 1_554 .
Cu4 Cu1 Cu3 57.47(8) 1_554 .
O2 Cu1 Se2 70.3(9) 13 1_554
O6 Cu1 Se2 155.9(8) 13 1_554
O1 Cu1 Se2 108.1(9) . 1_554
O5 Cu1 Se2 24.2(7) 10 1_554
Cu1 Cu1 Se2 61.40(9) 10_554 1_554
Cu1 Cu1 Se2 118.61(9) 10 1_554
Br1 Cu1 Se2 90.3(2) . 1_554
Se1 Cu1 Se2 177.01(19) 13 1_554
Cu2 Cu1 Se2 59.57(16) 1_554 1_554
Cu4 Cu1 Se2 89.68(13) 1_554 1_554
Cu3 Cu1 Se2 117.03(15) . 1_554
O2 Cu2 O2 89.9(18) 13_556 15_545
O2 Cu2 O3 173.0(14) 13_556 3_556
O2 Cu2 O3 97.1(13) 15_545 3_556
O2 Cu2 O3 97.1(13) 13_556 .
O2 Cu2 O3 173.0(14) 15_545 .
O3 Cu2 O3 76(2) 3_556 .
O2 Cu2 Br1 87.6(2) 13_556 1_556
O2 Cu2 Br1 87.6(2) 15_545 1_556
O3 Cu2 Br1 92.6(2) 3_556 1_556
O3 Cu2 Br1 92.6(2) . 1_556
O2 Cu2 Br1 87.6(2) 13_556 .
O2 Cu2 Br1 87.6(2) 15_545 .
O3 Cu2 Br1 92.6(2) 3_556 .
O3 Cu2 Br1 92.6(2) . .
Br1 Cu2 Br1 173.3(5) 1_556 .
O2 Cu2 Se2 160.8(9) 13_556 3_556
O2 Cu2 Se2 70.9(9) 15_545 3_556
O3 Cu2 Se2 26.1(10) 3_556 3_556
O3 Cu2 Se2 102.1(10) . 3_556
Br1 Cu2 Se2 91.46(11) 1_556 3_556
Br1 Cu2 Se2 91.46(11) . 3_556
O2 Cu2 Se2 70.9(9) 13_556 .
O2 Cu2 Se2 160.8(9) 15_545 .
O3 Cu2 Se2 102.1(10) 3_556 .
O3 Cu2 Se2 26.1(10) . .
Br1 Cu2 Se2 91.46(11) 1_556 .
Br1 Cu2 Se2 91.46(11) . .
Se2 Cu2 Se2 128.3(3) 3_556 .
O2 Cu2 Cu1 32.2(4) 13_556 1_556
O2 Cu2 Cu1 103.1(8) 15_545 1_556
O3 Cu2 Cu1 144.3(6) 3_556 1_556
O3 Cu2 Cu1 83.0(9) . 1_556
Br1 Cu2 Cu1 59.54(14) 1_556 1_556
Br1 Cu2 Cu1 117.11(19) . 1_556
Se2 Cu2 Cu1 150.91(8) 3_556 1_556
Se2 Cu2 Cu1 60.57(11) . 1_556
O2 Cu2 Cu1 103.1(8) 13_556 3
O2 Cu2 Cu1 32.2(4) 15_545 3
O3 Cu2 Cu1 83.0(9) 3_556 3
O3 Cu2 Cu1 144.3(6) . 3
Br1 Cu2 Cu1 117.11(19) 1_556 3
Br1 Cu2 Cu1 59.54(14) . 3
Se2 Cu2 Cu1 60.57(11) 3_556 3
Se2 Cu2 Cu1 150.91(8) . 3
Cu1 Cu2 Cu1 128.0(3) 1_556 3
O2 Cu2 Cu1 32.2(4) 13_556 10
O2 Cu2 Cu1 103.1(8) 15_545 10
O3 Cu2 Cu1 144.3(6) 3_556 10
O3 Cu2 Cu1 83.0(9) . 10
Br1 Cu2 Cu1 117.11(19) 1_556 10
Br1 Cu2 Cu1 59.54(14) . 10
Se2 Cu2 Cu1 150.91(8) 3_556 10
Se2 Cu2 Cu1 60.57(11) . 10
Cu1 Cu2 Cu1 57.65(17) 1_556 10
Cu1 Cu2 Cu1 98.7(2) 3 10
O2 Cu2 Cu1 103.1(8) 13_556 12_556
O2 Cu2 Cu1 32.2(4) 15_545 12_556
O3 Cu2 Cu1 83.0(9) 3_556 12_556
O3 Cu2 Cu1 144.3(6) . 12_556
Br1 Cu2 Cu1 59.54(14) 1_556 12_556
Br1 Cu2 Cu1 117.11(19) . 12_556
Se2 Cu2 Cu1 60.57(11) 3_556 12_556
Se2 Cu2 Cu1 150.91(8) . 12_556
Cu1 Cu2 Cu1 98.7(2) 1_556 12_556
Cu1 Cu2 Cu1 57.65(17) 3 12_556
Cu1 Cu2 Cu1 128.0(3) 10 12_556
O1 Cu3 O1 180.0 13 .
O1 Cu3 O4 86.3(13) 13 13
O1 Cu3 O4 93.7(13) . 13
O1 Cu3 O4 93.7(13) 13 .
O1 Cu3 O4 86.3(13) . .
O4 Cu3 O4 180.0 13 .
O1 Cu3 Cu4 90.0 13 1_554
O1 Cu3 Cu4 90.0 . 1_554
O4 Cu3 Cu4 90.0 13 1_554
O4 Cu3 Cu4 90.0 . 1_554
O1 Cu3 Cu4 90.0 13 .
O1 Cu3 Cu4 90.0 . .
O4 Cu3 Cu4 90.0 13 .
O4 Cu3 Cu4 90.0 . .
Cu4 Cu3 Cu4 180.0 1_554 .
O1 Cu3 Se1 69.8(9) 13 .
O1 Cu3 Se1 110.2(9) . .
O4 Cu3 Se1 156.1(10) 13 .
O4 Cu3 Se1 23.9(10) . .
Cu4 Cu3 Se1 90.0 1_554 .
Cu4 Cu3 Se1 90.0 . .
O1 Cu3 Se1 110.2(9) 13 13
O1 Cu3 Se1 69.8(9) . 13
O4 Cu3 Se1 23.9(10) 13 13
O4 Cu3 Se1 156.1(10) . 13
Cu4 Cu3 Se1 90.0 1_554 13
Cu4 Cu3 Se1 90.0 . 13
Se1 Cu3 Se1 180.0 . 13
O1 Cu3 Cu1 147.9(4) 13 .
O1 Cu3 Cu1 32.1(4) . .
O4 Cu3 Cu1 80.1(8) 13 .
O4 Cu3 Cu1 99.9(8) . .
Cu4 Cu3 Cu1 61.21(8) 1_554 .
Cu4 Cu3 Cu1 118.79(8) . .
Se1 Cu3 Cu1 120.31(11) . .
Se1 Cu3 Cu1 59.69(11) 13 .
O1 Cu3 Cu1 32.1(4) 13 13
O1 Cu3 Cu1 147.9(4) . 13
O4 Cu3 Cu1 99.9(8) 13 13
O4 Cu3 Cu1 80.1(8) . 13
Cu4 Cu3 Cu1 118.79(8) 1_554 13
Cu4 Cu3 Cu1 61.21(8) . 13
Se1 Cu3 Cu1 59.69(11) . 13
Se1 Cu3 Cu1 120.31(11) 13 13
Cu1 Cu3 Cu1 180.0 . 13
O1 Cu3 Cu1 147.9(4) 13 10
O1 Cu3 Cu1 32.1(4) . 10
O4 Cu3 Cu1 80.1(8) 13 10
O4 Cu3 Cu1 99.9(8) . 10
Cu4 Cu3 Cu1 118.79(8) 1_554 10
Cu4 Cu3 Cu1 61.21(8) . 10
Se1 Cu3 Cu1 120.31(11) . 10
Se1 Cu3 Cu1 59.69(11) 13 10
Cu1 Cu3 Cu1 57.58(16) . 10
Cu1 Cu3 Cu1 122.42(16) 13 10
O1 Cu3 Cu1 32.1(4) 13 6
O1 Cu3 Cu1 147.9(4) . 6
O4 Cu3 Cu1 99.9(8) 13 6
O4 Cu3 Cu1 80.1(8) . 6
Cu4 Cu3 Cu1 61.21(8) 1_554 6
Cu4 Cu3 Cu1 118.79(8) . 6
Se1 Cu3 Cu1 59.69(11) . 6
Se1 Cu3 Cu1 120.31(11) 13 6
Cu1 Cu3 Cu1 122.42(16) . 6
Cu1 Cu3 Cu1 57.58(16) 13 6
Cu1 Cu3 Cu1 180.00(8) 10 6
Cu3 O1 Cu1 116.4(10) . .
Cu3 O1 Cu1 116.4(10) . 10
Cu1 O1 Cu1 108.4(15) . 10
Cu3 O1 Pb2 105.2(14) . .
Cu1 O1 Pb2 104.5(10) . .
Cu1 O1 Pb2 104.5(10) 10 .
Cu1 O2 Cu1 110.1(15) 13 6_556
Cu1 O2 Cu2 115.0(10) 13 13_556
Cu1 O2 Cu2 115.0(10) 6_556 13_556
Cu1 O2 Pb1 108.3(10) 13 .
Cu1 O2 Pb1 108.3(10) 6_556 .
Cu2 O2 Pb1 99.1(12) 13_556 .
Se2 O3 Cu2 123.5(19) . .
Se2 O3 Pb3A 122.7(14) . 9_556
Cu2 O3 Pb3A 104.4(13) . 9_556
Se2 O3 Pb3A 122.7(14) . .
Cu2 O3 Pb3A 104.4(13) . .
Pb3A O3 Pb3A 63.7(9) 9_556 .
Se1 O4 Cu3 128.5(19) . .
Se1 O4 Pb2 129.5(18) . .
Cu3 O4 Pb2 101.9(14) . .
Se2 O5 Cu1 127.6(14) . 10
Se2 O5 Pb2 127.9(13) . .
Cu1 O5 Pb2 104.2(11) 10 .
Se1 O6 Cu1 125.1(14) . 13
Se1 O6 Pb1 133.0(13) . .
Cu1 O6 Pb1 99.6(11) 13 .
Se1 O6 Br4 102.0(13) . .
Cu1 O6 Br4 92.9(12) 13 .
Pb1 O6 Br4 88.2(10) . .
Pb3B Br1 Cu2 86.6(3) . .
Pb3B Br1 Cu2 86.6(3) . 1_554
Cu2 Br1 Cu2 173.3(5) . 1_554
Pb3B Br1 Cu1 113.0(2) . 10
Cu2 Br1 Cu1 61.86(12) . 10
Cu2 Br1 Cu1 121.15(16) 1_554 10
Pb3B Br1 Cu1 113.0(2) . 12
Cu2 Br1 Cu1 121.15(16) . 12
Cu2 Br1 Cu1 61.86(12) 1_554 12
Cu1 Br1 Cu1 134.0(4) 10 12
Pb3B Br1 Cu1 113.0(2) . 3
Cu2 Br1 Cu1 61.86(12) . 3
Cu2 Br1 Cu1 121.15(16) 1_554 3
Cu1 Br1 Cu1 101.8(3) 10 3
Cu1 Br1 Cu1 59.38(19) 12 3
Pb3B Br1 Cu1 113.0(2) . .
Cu2 Br1 Cu1 121.15(16) . .
Cu2 Br1 Cu1 61.86(12) 1_554 .
Cu1 Br1 Cu1 59.38(19) 10 .
Cu1 Br1 Cu1 101.8(3) 12 .
Cu1 Br1 Cu1 134.0(4) 3 .
Pb3B Br1 Pb3A 27.85(13) . .
Cu2 Br1 Pb3A 58.8(2) . .
Cu2 Br1 Pb3A 114.5(3) 1_554 .
Cu1 Br1 Pb3A 96.53(16) 10 .
Cu1 Br1 Pb3A 125.2(2) 12 .
Cu1 Br1 Pb3A 96.53(16) 3 .
Cu1 Br1 Pb3A 125.2(2) . .
Pb3B Br1 Pb3A 27.85(13) . 9
Cu2 Br1 Pb3A 114.5(3) . 9
Cu2 Br1 Pb3A 58.8(2) 1_554 9
Cu1 Br1 Pb3A 125.2(2) 10 9
Cu1 Br1 Pb3A 96.53(16) 12 9
Cu1 Br1 Pb3A 125.2(2) 3 9
Cu1 Br1 Pb3A 96.53(16) . 9
Pb3A Br1 Pb3A 55.7(3) . 9
Pb3B Br1 Br2 35.00(19) . .
Cu2 Br1 Br2 87.3(2) . .
Cu2 Br1 Br2 87.3(2) 1_554 .
Cu1 Br1 Br2 82.80(19) 10 .
Cu1 Br1 Br2 139.9(3) 12 .
Cu1 Br1 Br2 139.9(3) 3 .
Cu1 Br1 Br2 82.80(19) . .
Pb3A Br1 Br2 43.59(17) . .
Pb3A Br1 Br2 43.59(17) 9 .
Pb3B Br1 Br2 35.00(19) . 9
Cu2 Br1 Br2 87.3(2) . 9
Cu2 Br1 Br2 87.3(2) 1_554 9
Cu1 Br1 Br2 139.9(3) 10 9
Cu1 Br1 Br2 82.80(19) 12 9
Cu1 Br1 Br2 82.80(19) 3 9
Cu1 Br1 Br2 139.9(3) . 9
Pb3A Br1 Br2 43.59(17) . 9
Pb3A Br1 Br2 43.59(17) 9 9
Br2 Br1 Br2 70.0(4) . 9
Pb3B Br1 Pb1 134.50(11) . 13_556
Cu2 Br1 Pb1 47.85(19) . 13_556
Cu2 Br1 Pb1 138.9(4) 1_554 13_556
Cu1 Br1 Pb1 51.18(13) 10 13_556
Cu1 Br1 Pb1 94.6(2) 12 13_556
Cu1 Br1 Pb1 51.18(14) 3 13_556
Cu1 Br1 Pb1 94.6(2) . 13_556
Pb3A Br1 Pb1 106.65(11) . 13_556
Pb3A Br1 Pb1 162.3(2) 9 13_556
Br2 Br1 Pb1 125.04(9) . 13_556
Br2 Br1 Pb1 125.04(9) 9 13_556
Pb3B Br2 Pb3B 56.9(11) . 9
Pb3B Br2 Pb3A 45.4(4) . .
Pb3B Br2 Pb3A 45.4(4) 9 .
Pb3B Br2 Pb3A 45.4(4) . 9
Pb3B Br2 Pb3A 45.4(4) 9 9
Pb3A Br2 Pb3A 74.1(4) . 9
Pb3B Br2 Pb2 101.9(5) . .
Pb3B Br2 Pb2 158.8(6) 9 .
Pb3A Br2 Pb2 121.12(8) . .
Pb3A Br2 Pb2 121.12(8) 9 .
Pb3B Br2 Pb2 158.8(6) . 11
Pb3B Br2 Pb2 101.9(5) 9 11
Pb3A Br2 Pb2 121.12(8) . 11
Pb3A Br2 Pb2 121.12(8) 9 11
Pb2 Br2 Pb2 99.3(4) . 11
Pb3B Br2 Se2 111.0(3) . 11_554
Pb3B Br2 Se2 82.9(3) 9 11_554
Pb3A Br2 Se2 128.3(4) . 11_554
Pb3A Br2 Se2 65.98(14) 9 11_554
Pb2 Br2 Se2 107.4(3) . 11_554
Pb2 Br2 Se2 61.84(13) 11 11_554
Pb3B Br2 Se2 111.0(3) . 11
Pb3B Br2 Se2 82.9(3) 9 11
Pb3A Br2 Se2 65.98(14) . 11
Pb3A Br2 Se2 128.3(4) 9 11
Pb2 Br2 Se2 107.4(3) . 11
Pb2 Br2 Se2 61.84(13) 11 11
Se2 Br2 Se2 116.88(17) 11_554 11
Pb3B Br2 Se2 82.9(3) . 1_554
Pb3B Br2 Se2 111.0(3) 9 1_554
Pb3A Br2 Se2 128.3(4) . 1_554
Pb3A Br2 Se2 65.98(14) 9 1_554
Pb2 Br2 Se2 61.84(13) . 1_554
Pb2 Br2 Se2 107.4(3) 11 1_554
Se2 Br2 Se2 60.81(15) 11_554 1_554
Se2 Br2 Se2 164.7(5) 11 1_554
Pb3B Br2 Se2 82.9(3) . .
Pb3B Br2 Se2 111.0(3) 9 .
Pb3A Br2 Se2 65.98(14) . .
Pb3A Br2 Se2 128.3(4) 9 .
Pb2 Br2 Se2 61.84(13) . .
Pb2 Br2 Se2 107.4(3) 11 .
Se2 Br2 Se2 164.7(5) 11_554 .
Se2 Br2 Se2 60.81(15) 11 .
Se2 Br2 Se2 116.88(17) 1_554 .
Pb3B Br2 Br1 83.5(6) . 9
Pb3B Br2 Br1 26.5(5) 9 9
Pb3A Br2 Br1 62.8(2) . 9
Pb3A Br2 Br1 62.8(2) 9 9
Pb2 Br2 Br1 174.6(4) . 9
Pb2 Br2 Br1 75.35(11) 11 9
Se2 Br2 Br1 70.23(12) 11_554 9
Se2 Br2 Br1 70.23(12) 11 9
Se2 Br2 Br1 119.41(18) 1_554 9
Se2 Br2 Br1 119.41(18) . 9
Pb3B Br2 Br1 26.5(5) . .
Pb3B Br2 Br1 83.5(6) 9 .
Pb3A Br2 Br1 62.8(2) . .
Pb3A Br2 Br1 62.8(2) 9 .
Pb2 Br2 Br1 75.35(11) . .
Pb2 Br2 Br1 174.6(4) 11 .
Se2 Br2 Br1 119.41(18) 11_554 .
Se2 Br2 Br1 119.41(18) 11 .
Se2 Br2 Br1 70.23(12) 1_554 .
Se2 Br2 Br1 70.23(12) . .
Br1 Br2 Br1 110.0(4) 9 .
Pb3B Pb3A Pb3B 71.4(12) . 9
Pb3B Pb3A O3 91.3(7) . .
Pb3B Pb3A O3 146.6(7) 9 .
Pb3B Pb3A O3 91.3(7) . 3_556
Pb3B Pb3A O3 146.6(7) 9 3_556
O3 Pb3A O3 58.3(15) . 3_556
Pb3B Pb3A O3 146.6(7) . 9_556
Pb3B Pb3A O3 91.3(7) 9 9_556
O3 Pb3A O3 116.3(9) . 9_556
O3 Pb3A O3 88.2(14) 3_556 9_556
Pb3B Pb3A O3 146.6(7) . 11
Pb3B Pb3A O3 91.3(7) 9 11
O3 Pb3A O3 88.2(14) . 11
O3 Pb3A O3 116.3(9) 3_556 11
O3 Pb3A O3 58.3(15) 9_556 11
Pb3B Pb3A Pb3A 144.3(6) . 9_556
Pb3B Pb3A Pb3A 144.3(6) 9 9_556
O3 Pb3A Pb3A 58.2(4) . 9_556
O3 Pb3A Pb3A 58.2(4) 3_556 9_556
O3 Pb3A Pb3A 58.2(4) 9_556 9_556
O3 Pb3A Pb3A 58.2(4) 11 9_556
Pb3B Pb3A Br2 60.7(3) . .
Pb3B Pb3A Br2 60.7(3) 9 .
O3 Pb3A Br2 85.9(6) . .
O3 Pb3A Br2 135.0(7) 3_556 .
O3 Pb3A Br2 135.0(7) 9_556 .
O3 Pb3A Br2 85.9(6) 11 .
Pb3A Pb3A Br2 127.0(2) 9_556 .
Pb3B Pb3A Br2 60.7(3) . 9
Pb3B Pb3A Br2 60.7(3) 9 9
O3 Pb3A Br2 135.0(7) . 9
O3 Pb3A Br2 85.9(6) 3_556 9
O3 Pb3A Br2 85.9(6) 9_556 9
O3 Pb3A Br2 135.0(7) 11 9
Pb3A Pb3A Br2 127.0(2) 9_556 9
Br2 Pb3A Br2 105.9(4) . 9
Pb3B Pb3A Cu2 147.5(6) . 9_556
Pb3B Pb3A Cu2 76.1(6) 9 9_556
O3 Pb3A Cu2 116.8(6) . 9_556
O3 Pb3A Cu2 116.8(6) 3_556 9_556
O3 Pb3A Cu2 32.6(8) 9_556 9_556
O3 Pb3A Cu2 32.6(8) 11 9_556
Pb3A Pb3A Cu2 68.21(12) 9_556 9_556
Br2 Pb3A Cu2 102.92(7) . 9_556
Br2 Pb3A Cu2 102.92(7) 9 9_556
Pb3B Pb3A Cu2 76.1(6) . .
Pb3B Pb3A Cu2 147.5(6) 9 .
O3 Pb3A Cu2 32.6(8) . .
O3 Pb3A Cu2 32.6(8) 3_556 .
O3 Pb3A Cu2 116.8(6) 9_556 .
O3 Pb3A Cu2 116.8(6) 11 .
Pb3A Pb3A Cu2 68.21(12) 9_556 .
Br2 Pb3A Cu2 102.92(7) . .
Br2 Pb3A Cu2 102.92(7) 9 .
Cu2 Pb3A Cu2 136.4(2) 9_556 .
Pb3B Pb3A Pb3A 35.7(6) . 9
Pb3B Pb3A Pb3A 35.7(6) 9 9
O3 Pb3A Pb3A 121.8(4) . 9
O3 Pb3A Pb3A 121.8(4) 3_556 9
O3 Pb3A Pb3A 121.8(4) 9_556 9
O3 Pb3A Pb3A 121.8(4) 11 9
Pb3A Pb3A Pb3A 180.0 9_556 9
Br2 Pb3A Pb3A 53.0(2) . 9
Br2 Pb3A Pb3A 53.0(2) 9 9
Cu2 Pb3A Pb3A 111.79(12) 9_556 9
Cu2 Pb3A Pb3A 111.79(12) . 9
Br1 Pb3B Pb3A 125.7(6) . .
Br1 Pb3B Pb3A 125.7(6) . 9
Pb3A Pb3B Pb3A 108.6(12) . 9
Br1 Pb3B Pb3B 180.0 . 9
Pb3A Pb3B Pb3B 54.3(6) . 9
Pb3A Pb3B Pb3B 54.3(6) 9 9
Br1 Pb3B Br2 118.5(6) . .
Pb3A Pb3B Br2 73.9(5) . .
Pb3A Pb3B Br2 73.9(5) 9 .
Pb3B Pb3B Br2 61.5(6) 9 .
Br1 Pb3B Br2 118.5(6) . 9
Pb3A Pb3B Br2 73.9(5) . 9
Pb3A Pb3B Br2 73.9(5) 9 9
Pb3B Pb3B Br2 61.5(6) 9 9
Br2 Pb3B Br2 123.1(11) . 9
Br1 Pb3B Cu2 58.0(4) . 1_554
Pb3A Pb3B Cu2 176.3(10) . 1_554
Pb3A Pb3B Cu2 67.7(3) 9 1_554
Pb3B Pb3B Cu2 122.0(4) 9 1_554
Br2 Pb3B Cu2 104.64(13) . 1_554
Br2 Pb3B Cu2 104.64(13) 9 1_554
Br1 Pb3B Cu2 58.0(4) . .
Pb3A Pb3B Cu2 67.7(3) . .
Pb3A Pb3B Cu2 176.3(10) 9 .
Pb3B Pb3B Cu2 122.0(4) 9 .
Br2 Pb3B Cu2 104.64(13) . .
Br2 Pb3B Cu2 104.64(13) 9 .
Cu2 Pb3B Cu2 115.9(8) 1_554 .
Br1 Pb3B Se2 82.7(4) . 3
Pb3A Pb3B Se2 131.7(5) . 3
Pb3A Pb3B Se2 58.94(12) 9 3
Pb3B Pb3B Se2 97.3(4) 9 3
Br2 Pb3B Se2 130.8(4) . 3
Br2 Pb3B Se2 57.83(10) 9 3
Cu2 Pb3B Se2 46.85(12) 1_554 3
Cu2 Pb3B Se2 123.3(5) . 3
Br1 Pb3B Se2 82.7(4) . 3_556
Pb3A Pb3B Se2 58.94(12) . 3_556
Pb3A Pb3B Se2 131.7(5) 9 3_556
Pb3B Pb3B Se2 97.3(4) 9 3_556
Br2 Pb3B Se2 130.8(4) . 3_556
Br2 Pb3B Se2 57.83(10) 9 3_556
Cu2 Pb3B Se2 123.3(5) 1_554 3_556
Cu2 Pb3B Se2 46.85(12) . 3_556
Se2 Pb3B Se2 93.25(15) 3 3_556
Br1 Pb3B Se2 82.7(4) . 1_554
Pb3A Pb3B Se2 131.7(5) . 1_554
Pb3A Pb3B Se2 58.94(12) 9 1_554
Pb3B Pb3B Se2 97.3(4) 9 1_554
Br2 Pb3B Se2 57.83(10) . 1_554
Br2 Pb3B Se2 130.8(4) 9 1_554
Cu2 Pb3B Se2 46.85(12) 1_554 1_554
Cu2 Pb3B Se2 123.3(5) . 1_554
Se2 Pb3B Se2 84.88(14) 3 1_554
Se2 Pb3B Se2 165.3(8) 3_556 1_554
Br1 Pb3B Se2 82.7(4) . .
Pb3A Pb3B Se2 58.94(12) . .
Pb3A Pb3B Se2 131.7(5) 9 .
Pb3B Pb3B Se2 97.3(4) 9 .
Br2 Pb3B Se2 57.83(10) . .
Br2 Pb3B Se2 130.8(4) 9 .
Cu2 Pb3B Se2 123.3(5) 1_554 .
Cu2 Pb3B Se2 46.85(12) . .
Se2 Pb3B Se2 165.3(8) 3 .
Se2 Pb3B Se2 84.88(14) 3_556 .
Se2 Pb3B Se2 93.25(15) 1_554 .
Br4 Br3 Pb4 131.6(7) . .
Br4 Br3 Se2 102.7(7) . .
Pb4 Br3 Se2 125.8(4) . .
Br4 Br3 Pb2 87.0(3) . 1_556
Pb4 Br3 Pb2 113.26(18) . 1_556
Se2 Br3 Pb2 62.71(14) . 1_556
Br4 Br3 Pb2 87.0(3) . .
Pb4 Br3 Pb2 113.26(18) . .
Se2 Br3 Pb2 62.71(14) . .
Pb2 Br3 Pb2 122.0(3) 1_556 .
Br4 Br3 Br7 122.1(2) . 1_556
Pb4 Br3 Br7 57.1(2) . 1_556
Se2 Br3 Br7 97.6(3) . 1_556
Pb2 Br3 Br7 56.20(19) 1_556 1_556
Pb2 Br3 Br7 149.0(3) . 1_556
Br4 Br3 Br7 122.1(2) . .
Pb4 Br3 Br7 57.1(2) . .
Se2 Br3 Br7 97.6(3) . .
Pb2 Br3 Br7 149.0(3) 1_556 .
Pb2 Br3 Br7 56.20(19) . .
Br7 Br3 Br7 107.8(3) 1_556 .
Br4 Br3 Cu4 26.0(6) . .
Pb4 Br3 Cu4 157.6(4) . .
Se2 Br3 Cu4 76.6(2) . .
Pb2 Br3 Cu4 75.03(16) 1_556 .
Pb2 Br3 Cu4 75.03(16) . .
Br7 Br3 Cu4 126.11(14) 1_556 .
Br7 Br3 Cu4 126.11(14) . .
Br4 Br3 Br6 86.6(6) . 13_556
Pb4 Br3 Br6 49.3(3) . 13_556
Se2 Br3 Br6 156.1(5) . 13_556
Pb2 Br3 Br6 96.3(5) 1_556 13_556
Pb2 Br3 Br6 140.7(5) . 13_556
Br7 Br3 Br6 59.3(5) 1_556 13_556
Br7 Br3 Br6 95.9(5) . 13_556
Cu4 Br3 Br6 110.6(3) . 13_556
Br4 Br3 Br6 86.6(6) . 6
Pb4 Br3 Br6 49.3(3) . 6
Se2 Br3 Br6 156.1(5) . 6
Pb2 Br3 Br6 140.7(5) 1_556 6
Pb2 Br3 Br6 96.3(5) . 6
Br7 Br3 Br6 95.9(5) 1_556 6
Br7 Br3 Br6 59.3(5) . 6
Cu4 Br3 Br6 110.6(3) . 6
Br6 Br3 Br6 44.5(9) 13_556 6
Br4 Br3 Se1 54.9(3) . .
Pb4 Br3 Se1 98.7(2) . .
Se2 Br3 Se1 115.35(19) . .
Pb2 Br3 Se1 141.4(3) 1_556 .
Pb2 Br3 Se1 57.10(9) . .
Br7 Br3 Se1 147.0(4) 1_556 .
Br7 Br3 Se1 67.40(13) . .
Cu4 Br3 Se1 67.58(15) . .
Br6 Br3 Se1 88.1(5) 13_556 .
Br6 Br3 Se1 52.7(3) 6 .
Br4 Br3 Se1 54.9(3) . 1_556
Pb4 Br3 Se1 98.7(2) . 1_556
Se2 Br3 Se1 115.35(19) . 1_556
Pb2 Br3 Se1 57.10(9) 1_556 1_556
Pb2 Br3 Se1 141.4(3) . 1_556
Br7 Br3 Se1 67.40(13) 1_556 1_556
Br7 Br3 Se1 147.0(4) . 1_556
Cu4 Br3 Se1 67.58(15) . 1_556
Br6 Br3 Se1 52.7(3) 13_556 1_556
Br6 Br3 Se1 88.1(5) 6 1_556
Se1 Br3 Se1 98.4(2) . 1_556
Cu4 Br4 Br3 125.7(11) . .
Cu4 Br4 O6 102.6(8) . 10_556
Br3 Br4 O6 115.6(9) . 10_556
Cu4 Br4 O6 102.6(8) . .
Br3 Br4 O6 115.6(9) . .
O6 Br4 O6 87.4(14) 10_556 .
Cu4 Br4 Cu1 69.9(5) . 6_556
Br3 Br4 Cu1 149.1(4) . 6_556
O6 Br4 Cu1 35.7(7) 10_556 6_556
O6 Br4 Cu1 81.0(9) . 6_556
Cu4 Br4 Cu1 69.9(5) . 13
Br3 Br4 Cu1 149.1(4) . 13
O6 Br4 Cu1 81.0(9) 10_556 13
O6 Br4 Cu1 35.7(7) . 13
Cu1 Br4 Cu1 56.7(4) 6_556 13
Cu4 Br4 Se1 107.2(4) . .
Br3 Br4 Se1 91.1(4) . .
O6 Br4 Se1 114.3(9) 10_556 .
O6 Br4 Se1 29.9(6) . .
Cu1 Br4 Se1 110.4(6) 6_556 .
Cu1 Br4 Se1 58.0(3) 13 .
Cu4 Br4 Se1 107.2(4) . 1_556
Br3 Br4 Se1 91.1(4) . 1_556
O6 Br4 Se1 29.9(6) 10_556 1_556
O6 Br4 Se1 114.3(9) . 1_556
Cu1 Br4 Se1 58.0(3) 6_556 1_556
Cu1 Br4 Se1 110.4(6) 13 1_556
Se1 Br4 Se1 135.5(7) . 1_556
Cu4 Br4 Pb1 122.6(8) . .
Br3 Br4 Pb1 111.7(8) . .
O6 Br4 Pb1 45.7(7) 10_556 .
O6 Br4 Pb1 45.7(7) . .
Cu1 Br4 Pb1 60.1(4) 6_556 .
Cu1 Br4 Pb1 60.1(4) 13 .
Se1 Br4 Pb1 69.0(4) . .
Se1 Br4 Pb1 69.0(4) 1_556 .
Cu4 Br4 Cu3 55.5(3) . .
Br3 Br4 Cu3 109.3(5) . .
O6 Br4 Cu3 133.9(9) 10_556 .
O6 Br4 Cu3 63.5(5) . .
Cu1 Br4 Cu3 101.4(5) 6_556 .
Cu1 Br4 Cu3 54.2(2) 13 .
Se1 Br4 Cu3 53.45(12) . .
Se1 Br4 Cu3 158.5(6) 1_556 .
Pb1 Br4 Cu3 107.7(4) . .
Cu4 Br4 Cu3 55.5(3) . 1_556
Br3 Br4 Cu3 109.3(5) . 1_556
O6 Br4 Cu3 63.5(5) 10_556 1_556
O6 Br4 Cu3 133.9(9) . 1_556
Cu1 Br4 Cu3 54.2(2) 6_556 1_556
Cu1 Br4 Cu3 101.4(5) 13 1_556
Se1 Br4 Cu3 158.5(6) . 1_556
Se1 Br4 Cu3 53.45(12) 1_556 1_556
Pb1 Br4 Cu3 107.7(4) . 1_556
Cu3 Br4 Cu3 111.1(5) . 1_556
Cu4 Br4 Pb2 87.9(5) . 1_556
Br3 Br4 Pb2 59.2(4) . 1_556
O6 Br4 Pb2 86.6(6) 10_556 1_556
O6 Br4 Pb2 168.9(9) . 1_556
Cu1 Br4 Pb2 99.36(16) 6_556 1_556
Cu1 Br4 Pb2 151.3(5) 13 1_556
Se1 Br4 Pb2 149.7(6) . 1_556
Se1 Br4 Pb2 58.00(17) 1_556 1_556
Pb1 Br4 Pb2 125.0(3) . 1_556
Cu3 Br4 Pb2 126.8(6) . 1_556
Cu3 Br4 Pb2 50.08(16) 1_556 1_556
Br4 Cu4 Br4 180.0 . 13_556
Br4 Cu4 Cu3 90.0 . 1_556
Br4 Cu4 Cu3 90.0 13_556 1_556
Br4 Cu4 Cu3 90.0 . .
Br4 Cu4 Cu3 90.0 13_556 .
Cu3 Cu4 Cu3 180.0 1_556 .
Br4 Cu4 Cu1 108.3(5) . 10
Br4 Cu4 Cu1 71.7(5) 13_556 10
Cu3 Cu4 Cu1 118.69(8) 1_556 10
Cu3 Cu4 Cu1 61.31(8) . 10
Br4 Cu4 Cu1 71.7(5) . 6_556
Br4 Cu4 Cu1 108.3(5) 13_556 6_556
Cu3 Cu4 Cu1 61.31(8) 1_556 6_556
Cu3 Cu4 Cu1 118.69(8) . 6_556
Cu1 Cu4 Cu1 180.00(16) 10 6_556
Br4 Cu4 Cu1 108.3(5) . 1_556
Br4 Cu4 Cu1 71.7(5) 13_556 1_556
Cu3 Cu4 Cu1 61.31(8) 1_556 1_556
Cu3 Cu4 Cu1 118.69(8) . 1_556
Cu1 Cu4 Cu1 57.37(16) 10 1_556
Cu1 Cu4 Cu1 122.63(16) 6_556 1_556
Br4 Cu4 Cu1 71.7(5) . 13
Br4 Cu4 Cu1 108.3(5) 13_556 13
Cu3 Cu4 Cu1 118.69(8) 1_556 13
Cu3 Cu4 Cu1 61.31(8) . 13
Cu1 Cu4 Cu1 122.63(16) 10 13
Cu1 Cu4 Cu1 57.37(16) 6_556 13
Cu1 Cu4 Cu1 180.00(8) 1_556 13
Br4 Cu4 Br3 151.8(6) . 13_556
Br4 Cu4 Br3 28.2(6) 13_556 13_556
Cu3 Cu4 Br3 90.0 1_556 13_556
Cu3 Cu4 Br3 90.0 . 13_556
Cu1 Cu4 Br3 96.41(15) 10 13_556
Cu1 Cu4 Br3 83.59(15) 6_556 13_556
Cu1 Cu4 Br3 96.41(15) 1_556 13_556
Cu1 Cu4 Br3 83.59(15) 13 13_556
Br4 Cu4 Br3 28.2(6) . .
Br4 Cu4 Br3 151.8(6) 13_556 .
Cu3 Cu4 Br3 90.0 1_556 .
Cu3 Cu4 Br3 90.0 . .
Cu1 Cu4 Br3 83.59(15) 10 .
Cu1 Cu4 Br3 96.41(15) 6_556 .
Cu1 Cu4 Br3 83.59(15) 1_556 .
Cu1 Cu4 Br3 96.41(15) 13 .
Br3 Cu4 Br3 180.0 13_556 .
Br3 Pb4 Br3 98.0(5) . 11
Br3 Pb4 Br6 85.9(3) . 13_556
Br3 Pb4 Br6 149.9(6) 11 13_556
Br3 Pb4 Br6 85.9(3) . 6
Br3 Pb4 Br6 149.9(6) 11 6
Br6 Pb4 Br6 59.8(12) 13_556 6
Br3 Pb4 Br6 149.9(6) . 14_456
Br3 Pb4 Br6 85.9(3) 11 14_456
Br6 Pb4 Br6 76.8(8) 13_556 14_456
Br6 Pb4 Br6 105.6(6) 6 14_456
Br3 Pb4 Br6 149.9(6) . 5_455
Br3 Pb4 Br6 85.9(3) 11 5_455
Br6 Pb4 Br6 105.6(6) 13_556 5_455
Br6 Pb4 Br6 76.8(8) 6 5_455
Br6 Pb4 Br6 59.8(12) 14_456 5_455
Br3 Pb4 Br7 76.7(2) . .
Br3 Pb4 Br7 76.7(2) 11 .
Br6 Pb4 Br7 132.8(6) 13_556 .
Br6 Pb4 Br7 75.3(6) 6 .
Br6 Pb4 Br7 132.8(6) 14_456 .
Br6 Pb4 Br7 75.3(6) 5_455 .
Br3 Pb4 Br7 76.7(2) . 1_556
Br3 Pb4 Br7 76.7(2) 11 1_556
Br6 Pb4 Br7 75.3(6) 13_556 1_556
Br6 Pb4 Br7 132.8(6) 6 1_556
Br6 Pb4 Br7 75.3(6) 14_456 1_556
Br6 Pb4 Br7 132.8(6) 5_455 1_556
Br7 Pb4 Br7 138.9(7) . 1_556
Br3 Pb4 Pb4 131.0(3) . 9_566
Br3 Pb4 Pb4 131.0(3) 11 9_566
Br6 Pb4 Pb4 52.8(3) 13_556 9_566
Br6 Pb4 Pb4 52.8(3) 6 9_566
Br6 Pb4 Pb4 52.8(3) 14_456 9_566
Br6 Pb4 Pb4 52.8(3) 5_455 9_566
Br7 Pb4 Pb4 110.6(3) . 9_566
Br7 Pb4 Pb4 110.6(3) 1_556 9_566
Br6 Br6 Pb4 60.1(6) 10_556 13_556
Br6 Br6 Pb4 60.1(6) 10_556 5_545
Pb4 Br6 Pb4 74.4(6) 13_556 5_545
Br6 Br6 Br6 180.0 10_556 10
Pb4 Br6 Br6 119.9(6) 13_556 10
Pb4 Br6 Br6 119.9(6) 5_545 10
Br6 Br6 Se1 115.9(5) 10_556 15_545
Pb4 Br6 Se1 175.4(11) 13_556 15_545
Pb4 Br6 Se1 105.79(18) 5_545 15_545
Br6 Br6 Se1 64.1(5) 10 15_545
Br6 Br6 Se1 115.9(5) 10_556 13
Pb4 Br6 Se1 105.79(18) 13_556 13
Pb4 Br6 Se1 175.4(11) 5_545 13
Br6 Br6 Se1 64.1(5) 10 13
Se1 Br6 Se1 73.6(4) 15_545 13
Br6 Br6 Pb1 65.7(5) 10_556 13_556
Pb4 Br6 Pb1 111.2(8) 13_556 13_556
Pb4 Br6 Pb1 111.2(8) 5_545 13_556
Br6 Br6 Pb1 114.3(5) 10 13_556
Se1 Br6 Pb1 64.4(2) 15_545 13_556
Se1 Br6 Pb1 64.4(2) 13 13_556
Br6 Br6 Br6 89.999(1) 10_556 2_655
Pb4 Br6 Br6 51.6(4) 13_556 2_655
Pb4 Br6 Br6 51.6(4) 5_545 2_655
Br6 Br6 Br6 90.0 10 2_655
Se1 Br6 Br6 132.2(3) 15_545 2_655
Se1 Br6 Br6 132.2(3) 13 2_655
Pb1 Br6 Br6 155.7(5) 13_556 2_655
Br6 Br6 Br7 113.8(5) 10_556 13
Pb4 Br6 Br7 55.2(2) 13_556 13
Pb4 Br6 Br7 111.4(4) 5_545 13
Br6 Br6 Br7 66.2(5) 10 13
Se1 Br6 Br7 128.0(9) 15_545 13
Se1 Br6 Br7 71.8(3) 13 13
Pb1 Br6 Br7 127.7(2) 13_556 13
Br6 Br6 Br7 60.8(2) 2_655 13
Br6 Br6 Br7 113.8(5) 10_556 5_545
Pb4 Br6 Br7 111.4(4) 13_556 5_545
Pb4 Br6 Br7 55.2(2) 5_545 5_545
Br6 Br6 Br7 66.2(5) 10 5_545
Se1 Br6 Br7 71.8(3) 15_545 5_545
Se1 Br6 Br7 128.0(9) 13 5_545
Pb1 Br6 Br7 127.7(2) 13_556 5_545
Br6 Br6 Br7 60.8(2) 2_655 5_545
Br7 Br6 Br7 101.4(7) 13 5_545
Br6 Br6 Br3 67.7(5) 10_556 13_556
Pb4 Br6 Br3 44.8(3) 13_556 13_556
Pb4 Br6 Br3 114.0(8) 5_545 13_556
Br6 Br6 Br3 112.3(5) 10 13_556
Se1 Br6 Br3 132.7(4) 15_545 13_556
Se1 Br6 Br3 64.61(16) 13 13_556
Pb1 Br6 Br3 77.8(4) 13_556 13_556
Br6 Br6 Br3 93.5(3) 2_655 13_556
Br7 Br6 Br3 57.87(19) 13 13_556
Br7 Br6 Br3 153.8(5) 5_545 13_556
Br6 Br6 Br3 67.7(5) 10_556 15_545
Pb4 Br6 Br3 114.0(8) 13_556 15_545
Pb4 Br6 Br3 44.8(3) 5_545 15_545
Br6 Br6 Br3 112.3(5) 10 15_545
Se1 Br6 Br3 64.61(16) 15_545 15_545
Se1 Br6 Br3 132.7(4) 13 15_545
Pb1 Br6 Br3 77.8(4) 13_556 15_545
Br6 Br6 Br3 93.5(3) 2_655 15_545
Br7 Br6 Br3 153.8(5) 13 15_545
Br7 Br6 Br3 57.87(19) 5_545 15_545
Br3 Br6 Br3 134.9(9) 13_556 15_545
Pb4 Br7 Pb4 138.9(7) 1_554 .
Pb4 Br7 Pb2 103.83(17) 1_554 .
Pb4 Br7 Pb2 103.83(17) . .
Pb4 Br7 Pb2 103.83(17) 1_554 11
Pb4 Br7 Pb2 103.83(17) . 11
Pb2 Br7 Pb2 94.2(4) . 11
Pb4 Br7 Br3 145.2(2) 1_554 .
Pb4 Br7 Br3 46.22(16) . .
Pb2 Br7 Br3 57.64(17) . .
Pb2 Br7 Br3 106.6(3) 11 .
Pb4 Br7 Br3 46.22(16) 1_554 11_554
Pb4 Br7 Br3 145.2(2) . 11_554
Pb2 Br7 Br3 106.6(3) . 11_554
Pb2 Br7 Br3 57.64(17) 11 11_554
Br3 Br7 Br3 158.8(6) . 11_554
Pb4 Br7 Br3 46.22(16) 1_554 1_554
Pb4 Br7 Br3 145.2(2) . 1_554
Pb2 Br7 Br3 57.64(17) . 1_554
Pb2 Br7 Br3 106.6(3) 11 1_554
Br3 Br7 Br3 107.8(3) . 1_554
Br3 Br7 Br3 68.1(3) 11_554 1_554
Pb4 Br7 Br3 145.2(2) 1_554 11
Pb4 Br7 Br3 46.22(16) . 11
Pb2 Br7 Br3 106.6(3) . 11
Pb2 Br7 Br3 57.64(17) 11 11
Br3 Br7 Br3 68.1(3) . 11
Br3 Br7 Br3 107.8(3) 11_554 11
Br3 Br7 Br3 158.8(6) 1_554 11
Pb4 Br7 Br6 96.1(6) 1_554 6
Pb4 Br7 Br6 49.5(5) . 6
Pb2 Br7 Br6 99.7(2) . 6
Pb2 Br7 Br6 152.2(4) 11 6
Br3 Br7 Br6 62.8(4) . 6
Br3 Br7 Br6 137.9(6) 11_554 6
Br3 Br7 Br6 101.2(4) 1_554 6
Br3 Br7 Br6 95.1(5) 11 6
Pb4 Br7 Br6 49.5(5) 1_554 13
Pb4 Br7 Br6 96.1(6) . 13
Pb2 Br7 Br6 99.7(2) . 13
Pb2 Br7 Br6 152.2(4) 11 13
Br3 Br7 Br6 101.2(4) . 13
Br3 Br7 Br6 95.1(5) 11_554 13
Br3 Br7 Br6 62.8(4) 1_554 13
Br3 Br7 Br6 137.9(6) 11 13
Br6 Br7 Br6 47.6(9) 6 13
Pb4 Br7 Br6 96.1(6) 1_554 5_455
Pb4 Br7 Br6 49.5(5) . 5_455
Pb2 Br7 Br6 152.2(4) . 5_455
Pb2 Br7 Br6 99.7(2) 11 5_455
Br3 Br7 Br6 95.1(5) . 5_455
Br3 Br7 Br6 101.2(4) 11_554 5_455
Br3 Br7 Br6 137.9(6) 1_554 5_455
Br3 Br7 Br6 62.8(4) 11 5_455
Br6 Br7 Br6 58.5(5) 6 5_455
Br6 Br7 Br6 78.6(7) 13 5_455
Pb4 Br7 Br6 49.5(5) 1_554 14_455
Pb4 Br7 Br6 96.1(6) . 14_455
Pb2 Br7 Br6 152.2(4) . 14_455
Pb2 Br7 Br6 99.7(2) 11 14_455
Br3 Br7 Br6 137.9(6) . 14_455
Br3 Br7 Br6 62.8(4) 11_554 14_455
Br3 Br7 Br6 95.1(5) 1_554 14_455
Br3 Br7 Br6 101.2(4) 11 14_455
Br6 Br7 Br6 78.6(7) 6 14_455
Br6 Br7 Br6 58.5(5) 13 14_455
Br6 Br7 Br6 47.6(9) 5_455 14_455
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_site_symmetry_2
Pb1 O2 2.35(3) 3_566
Pb1 O2 2.35(3) .
Pb1 O6 2.58(2) .
Pb1 O6 2.58(2) 3_566
Pb1 O6 2.58(2) 12_565
Pb1 O6 2.58(2) 10_556
Pb1 Cu2 3.287(9) 13_556
Pb1 Cu1 3.473(5) 15_556
Pb1 Cu1 3.473(5) 8
Pb1 Cu1 3.473(5) 13
Pb1 Cu1 3.473(5) 6_556
Pb1 Br4 3.60(2) .
Pb2 O5 2.37(2) .
Pb2 O5 2.37(2) 10
Pb2 O1 2.37(3) .
Pb2 O4 2.44(3) .
Pb2 Br2 3.412(10) .
Pb2 Cu3 3.412(3) .
Pb2 Cu1 3.425(5) .
Pb2 Cu1 3.425(5) 10
Pb2 Br7 3.549(13) .
Pb2 Br3 3.608(5) 1_554
Pb2 Br3 3.608(5) .
Pb2 Se2 3.665(3) .
Se1 O4 1.70(3) .
Se1 O6 1.74(3) 10
Se1 O6 1.74(3) .
Se1 Cu1 3.265(6) 13
Se1 Cu1 3.265(6) 6
Se1 Cu3 3.277(5) .
Se1 Br4 3.411(9) 1_554
Se1 Br4 3.411(9) .
Se1 Br6 3.670(17) 13
Se1 Br6 3.670(17) 6
Se2 O5 1.70(3) 10_556
Se2 O5 1.70(3) .
Se2 O3 1.72(3) .
Se2 Cu2 3.257(7) .
Se2 Cu1 3.290(6) 1_556
Se2 Cu1 3.290(6) 10
Se2 Br3 3.429(12) .
Se2 Br2 3.704(4) 1_556
Se2 Br2 3.704(4) .
Se2 Pb3A 3.720(6) 9_556
Cu1 O2 1.921(17) 13
Cu1 O6 1.94(3) 13
Cu1 O1 1.950(19) .
Cu1 O5 1.96(2) 10
Cu1 Cu1 3.150(9) 10_554
Cu1 Cu1 3.163(9) 10
Cu1 Br1 3.193(6) .
Cu1 Cu2 3.267(6) 1_554
Cu1 Cu4 3.281(4) 1_554
Cu1 Cu3 3.284(4) .
Cu2 O2 1.95(3) 13_556
Cu2 O2 1.95(3) 15_545
Cu2 O3 1.98(3) 3_556
Cu2 O3 1.98(3) .
Cu2 Br1 3.162(2) 1_556
Cu2 Br1 3.162(2) .
Cu3 O1 1.91(3) 13
Cu3 O1 1.91(3) .
Cu3 O4 1.94(3) 13
Cu3 O4 1.94(3) .
Cu3 Cu4 3.157(2) 1_554
Cu3 Cu4 3.157(2) .
O3 Pb3A 2.50(3) 9_556
O3 Pb3A 2.50(3) .
O6 Br4 2.59(4) .
Br1 Pb3B 2.16(3) .
Br1 Pb3A 3.937(11) .
Br1 Pb3A 3.937(11) 9
Br1 Br2 4.249(13) .
Br1 Br2 4.249(13) 9
Br2 Pb3B 2.772(19) .
Br2 Pb3B 2.772(19) 9
Br2 Pb3A 3.053(13) .
Br2 Pb3A 3.053(13) 9
Pb3A Pb3B 2.264(18) .
Pb3A Pb3B 2.264(18) 9
Pb3A Pb3A 2.635(15) 9_556
Pb3A Pb3A 3.678(15) 9
Pb3B Pb3B 2.64(6) 9
Br3 Br4 2.34(2) .
Br3 Pb4 2.899(12) .
Br3 Br7 3.907(7) 1_556
Br3 Br7 3.907(7) .
Br3 Cu4 4.007(10) .
Br3 Br6 4.103(17) 13_556
Br3 Br6 4.103(17) 6
Br4 Cu4 2.17(2) .
Pb4 Br6 3.120(19) 13_556
Pb4 Br6 3.120(19) 6
Pb4 Br6 3.120(19) 14_456
Pb4 Br6 3.120(19) 5_455
Pb4 Br7 3.371(8) .
Pb4 Br7 3.371(8) 1_556
Pb4 Pb4 3.77(2) 9_566
Br6 Br6 3.11(7) 10_556
Br6 Br6 3.20(7) 10
Br6 Br6 3.88(3) 2_655
Br6 Br7 3.97(2) 13
Br6 Br7 3.97(2) 5_545
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
O5 Se2 O3 Cu2 -52.4(9) 10_556 .
O5 Se2 O3 Cu2 52.4(9) . .
Cu1 Se2 O3 Cu2 -28.68(9) 1_556 .
Cu1 Se2 O3 Cu2 28.68(9) 10 .
Pb2 Se2 O3 Cu2 79.5(7) . .
Pb2 Se2 O3 Cu2 -79.5(7) 1_556 .
Br2 Se2 O3 Cu2 -120.10(18) 1_556 .
Br2 Se2 O3 Cu2 120.10(18) . .
Pb3A Se2 O3 Cu2 -141.2(11) 9_556 .
O5 Se2 O3 Pb3A 88.8(15) 10_556 9_556
O5 Se2 O3 Pb3A -166.4(12) . 9_556
Cu2 Se2 O3 Pb3A 141.2(11) . 9_556
Cu1 Se2 O3 Pb3A 112.5(10) 1_556 9_556
Cu1 Se2 O3 Pb3A 169.8(11) 10 9_556
Pb2 Se2 O3 Pb3A -139.4(5) . 9_556
Pb2 Se2 O3 Pb3A 61.7(17) 1_556 9_556
Br2 Se2 O3 Pb3A 21.1(9) 1_556 9_556
Br2 Se2 O3 Pb3A -98.7(12) . 9_556
O5 Se2 O3 Pb3A 166.4(12) 10_556 .
O5 Se2 O3 Pb3A -88.8(15) . .
Cu2 Se2 O3 Pb3A -141.2(11) . .
Cu1 Se2 O3 Pb3A -169.8(11) 1_556 .
Cu1 Se2 O3 Pb3A -112.5(10) 10 .
Pb2 Se2 O3 Pb3A -61.7(17) . .
Pb2 Se2 O3 Pb3A 139.4(5) 1_556 .
Br2 Se2 O3 Pb3A 98.7(12) 1_556 .
Br2 Se2 O3 Pb3A -21.1(9) . .
Pb3A Se2 O3 Pb3A 78(2) 9_556 .
O6 Se1 O4 Cu3 53.0(10) 10 .
O6 Se1 O4 Cu3 -53.0(10) . .
Cu1 Se1 O4 Cu3 -29.15(11) 13 .
Cu1 Se1 O4 Cu3 29.15(11) 6 .
Br4 Se1 O4 Cu3 88.7(6) 1_554 .
Br4 Se1 O4 Cu3 -88.7(6) . .
Br6 Se1 O4 Cu3 146.4(8) 13 .
Br6 Se1 O4 Cu3 -146.4(8) 6 .
Pb2 Se1 O4 Cu3 180.0 . .
Pb1 Se1 O4 Cu3 -71.8(8) . .
O6 Se1 O4 Pb2 -127.0(10) 10 .
O6 Se1 O4 Pb2 127.0(10) . .
Cu1 Se1 O4 Pb2 150.85(11) 13 .
Cu1 Se1 O4 Pb2 -150.85(11) 6 .
Cu3 Se1 O4 Pb2 180.0 . .
Br4 Se1 O4 Pb2 -91.3(6) 1_554 .
Br4 Se1 O4 Pb2 91.3(6) . .
Br6 Se1 O4 Pb2 -33.6(8) 13 .
Br6 Se1 O4 Pb2 33.6(8) 6 .
Pb1 Se1 O4 Pb2 108.2(8) . .
O5 Se2 O5 Cu1 46(2) 10_556 10
O3 Se2 O5 Cu1 -58(2) . 10
Cu2 Se2 O5 Cu1 -34.4(15) . 10
Cu1 Se2 O5 Cu1 26.1(15) 1_556 10
Br3 Se2 O5 Cu1 121.2(17) . 10
Pb2 Se2 O5 Cu1 173(3) . 10
Pb2 Se2 O5 Cu1 73.9(18) 1_556 10
Br2 Se2 O5 Cu1 -133.3(19) . 10
Pb3A Se2 O5 Cu1 -69(2) 9_556 10
O5 Se2 O5 Pb2 -127.0(11) 10_556 .
O3 Se2 O5 Pb2 128.5(17) . .
Cu2 Se2 O5 Pb2 152.4(16) . .
Cu1 Se2 O5 Pb2 -147.1(16) 1_556 .
Cu1 Se2 O5 Pb2 -173(3) 10 .
Br3 Se2 O5 Pb2 -52.0(14) . .
Pb2 Se2 O5 Pb2 -99.4(15) 1_556 .
Br2 Se2 O5 Pb2 53.5(13) . .
Pb3A Se2 O5 Pb2 117.8(13) 9_556 .
O4 Se1 O6 Cu1 56(2) . 13
O6 Se1 O6 Cu1 -48(3) 10 13
Cu1 Se1 O6 Cu1 -26.8(17) 6 13
Cu3 Se1 O6 Cu1 33.9(17) . 13
Br4 Se1 O6 Cu1 -12(3) 1_554 13
Br4 Se1 O6 Cu1 102(2) . 13
Br6 Se1 O6 Cu1 -143.7(13) 13 13
Br6 Se1 O6 Cu1 -176.4(19) 6 13
Pb2 Se1 O6 Cu1 82(2) . 13
Pb1 Se1 O6 Cu1 -159(4) . 13
O4 Se1 O6 Pb1 -145(2) . .
O6 Se1 O6 Pb1 110.7(18) 10 .
Cu1 Se1 O6 Pb1 159(4) 13 .
Cu1 Se1 O6 Pb1 132(2) 6 .
Cu3 Se1 O6 Pb1 -167(2) . .
Br4 Se1 O6 Pb1 147.0(12) 1_554 .
Br4 Se1 O6 Pb1 -99(2) . .
Br6 Se1 O6 Pb1 15(3) 13 .
Br6 Se1 O6 Pb1 -17.5(19) 6 .
Pb2 Se1 O6 Pb1 -118.7(17) . .
O4 Se1 O6 Br4 -46.5(14) . .
O6 Se1 O6 Br4 -150.4(8) 10 .
Cu1 Se1 O6 Br4 -102(2) 13 .
Cu1 Se1 O6 Br4 -129.0(9) 6 .
Cu3 Se1 O6 Br4 -68.4(8) . .
Br4 Se1 O6 Br4 -114.2(16) 1_554 .
Br6 Se1 O6 Br4 114.0(11) 13 .
Br6 Se1 O6 Br4 81.4(9) 6 .
Pb2 Se1 O6 Br4 -19.8(13) . .
Pb1 Se1 O6 Br4 99(2) . .

_cod_database_fobs_code 2108348
