#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/00/2200064.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2200064
loop_
_publ_author_name
'Baba, Ibrahim'
'Farina, Yang'
'Othman, A. Hamid'
'Razak, Ibrahim Abdul'
'Fun, Hoong-Kun'
'Ng, Seik Weng'
_publ_section_title
Bis(N-cyclohexyl-N-ethyldithiocarbamato-S,S')lead(II)
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m35
_journal_page_last               m36
_journal_paper_doi               10.1107/S1600536800020146
_journal_volume                  57
_journal_year                    2001
_chemical_formula_iupac          '[Pb (C9 H16 N S2)2]'
_chemical_formula_moiety         '(C9 H16 N S2)2, Pb'
_chemical_formula_sum            'C18 H32 N2 Pb S4'
_chemical_formula_weight         611.89
_chemical_name_systematic
;
Di(N-cyclohexyl-N-ethyldithiocarbamato)lead(II)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.5860(10)
_cell_angle_beta                 92.9780(10)
_cell_angle_gamma                99.1420(10)
_cell_formula_units_Z            2
_cell_length_a                   9.7180(2)
_cell_length_b                   10.1871(2)
_cell_length_c                   11.8751(3)
_cell_measurement_reflns_used    4596
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      33.15
_cell_measurement_theta_min      2.65
_cell_volume                     1152.45(4)
_computing_cell_refinement       'SAINT (Siemens, 1996)'
_computing_data_collection       'SMART (Siemens, 1996)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'ORTEPII (Johnson, 1976)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean 8.33
_diffrn_measured_fraction_theta_full .905
_diffrn_measured_fraction_theta_max .905
_diffrn_measurement_device_type  'Siemens CCD area-detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .030
_diffrn_reflns_av_sigmaI/netI    .0736
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            10652
_diffrn_reflns_theta_full        33.18
_diffrn_reflns_theta_max         33.18
_diffrn_reflns_theta_min         2.65
_exptl_absorpt_coefficient_mu    7.687
_exptl_absorpt_correction_T_max  .158
_exptl_absorpt_correction_T_min  .073
_exptl_absorpt_correction_type   empirical
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            Yellow
_exptl_crystal_density_diffrn    1.763
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Parallelepiped
_exptl_crystal_F_000             600
_exptl_crystal_size_max          .48
_exptl_crystal_size_mid          .28
_exptl_crystal_size_min          .24
_refine_diff_density_max         1.324
_refine_diff_density_min         -2.085
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   .991
_refine_ls_hydrogen_treatment    riding
_refine_ls_matrix_type           full
_refine_ls_number_parameters     226
_refine_ls_number_reflns         7977
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      .991
_refine_ls_R_factor_all          .108
_refine_ls_R_factor_gt           .053
_refine_ls_shift/su_max          .000
_refine_ls_shift/su_mean         <0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0650P)²] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .146
_reflns_number_gt                4557
_reflns_number_total             7977
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            na6024.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2200064
_cod_database_fobs_code          2200064
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Pb1 .26984(2) .58470(2) .01673(2) .06438(12) Uani d . 1 . . Pb
S1 .2738(2) .6822(2) .2377(2) .0620(4) Uani d . 1 . . S
S2 .0133(2) .6614(2) .09080(10) .0527(4) Uani d . 1 . . S
S3 .3307(2) .8183(2) -.0739(2) .0670(5) Uani d . 1 . . S
S4 .5590(2) .6878(2) .0151(2) .0589(4) Uani d . 1 . . S
N1 .0238(5) .6901(5) .3178(4) .0480(10) Uani d . 1 . . N
N2 .5912(5) .8659(5) -.1366(4) .0460(10) Uani d . 1 . . N
C1 .0955(6) .6786(6) .2237(5) .0470(10) Uani d . 1 . . C
C2 -.1298(6) .6725(6) .3106(5) .0450(10) Uani d . 1 . . C
C3 -.1934(7) .5330(7) .3345(7) .063(2) Uani d . 1 . . C
C4 -.3511(8) .5127(9) .3260(9) .082(2) Uani d . 1 . . C
C5 -.4042(8) .6166(9) .4025(7) .076(2) Uani d . 1 . . C
C6 -.3440(8) .7535(9) .3749(7) .073(2) Uani d . 1 . . C
C7 -.1849(8) .7787(7) .3862(6) .064(2) Uani d . 1 . . C
C8 .0969(8) .7050(10) .4313(6) .077(2) Uani d . 1 . . C
C9 .1640(10) .8490(10) .4694(7) .107(4) Uani d . 1 . . C
C10 .5050(6) .7973(6) -.0719(5) .0480(10) Uani d . 1 . . C
C11 .7372(5) .8396(6) -.1447(5) .0420(10) Uani d . 1 . . C
C12 .7452(7) .7291(6) -.2378(6) .056(2) Uani d . 1 . . C
C13 .8931(8) .6965(8) -.2398(7) .067(2) Uani d . 1 . . C
C14 .9985(7) .8210(8) -.2514(6) .064(2) Uani d . 1 . . C
C15 .9891(6) .9292(7) -.1576(6) .061(2) Uani d . 1 . . C
C16 .8413(7) .9647(6) -.1588(6) .0550(10) Uani d . 1 . . C
C17 .5429(7) .9666(7) -.2039(6) .061(2) Uani d . 1 . . C
C18 .4910(10) .9120(10) -.3226(8) .107(3) Uani d . 1 . . C
H2a -.1598 .6821 .2322 .054 Uiso calc R 1 . . H
H3a -.1623 .4678 .2808 .076 Uiso calc R 1 . . H
H3b -.1608 .5180 .4100 .076 Uiso calc R 1 . . H
H4a -.3844 .5173 .2483 .099 Uiso calc R 1 . . H
H4b -.3876 .4246 .3465 .099 Uiso calc R 1 . . H
H5a -.5054 .6040 .3930 .091 Uiso calc R 1 . . H
H5b -.3780 .6073 .4809 .091 Uiso calc R 1 . . H
H6a -.3785 .8197 .4254 .088 Uiso calc R 1 . . H
H6b -.3755 .7638 .2979 .088 Uiso calc R 1 . . H
H7a -.1500 .8666 .3644 .076 Uiso calc R 1 . . H
H7b -.1525 .7762 .4645 .076 Uiso calc R 1 . . H
H8a .1688 .6494 .4305 .093 Uiso calc R 1 . . H
H8b .0309 .6749 .4855 .093 Uiso calc R 1 . . H
H9a .2095 .8544 .5436 .160 Uiso calc R 1 . . H
H9b .0925 .9050 .4718 .160 Uiso calc R 1 . . H
H9c .2305 .8794 .4170 .160 Uiso calc R 1 . . H
H11a .7649 .8079 -.0730 .050 Uiso calc R 1 . . H
H12a .7179 .7567 -.3104 .068 Uiso calc R 1 . . H
H12b .6806 .6497 -.2254 .068 Uiso calc R 1 . . H
H13a .9165 .6596 -.1704 .080 Uiso calc R 1 . . H
H13b .8975 .6297 -.3030 .080 Uiso calc R 1 . . H
H14a 1.0920 .7989 -.2485 .077 Uiso calc R 1 . . H
H14b .9807 .8530 -.3241 .077 Uiso calc R 1 . . H
H15a 1.0560 1.0082 -.1671 .073 Uiso calc R 1 . . H
H15b 1.0125 .8992 -.0851 .073 Uiso calc R 1 . . H
H16a .8363 1.0336 -.0974 .066 Uiso calc R 1 . . H
H16b .8190 .9987 -.2298 .066 Uiso calc R 1 . . H
H17a .6194 1.0398 -.2063 .073 Uiso calc R 1 . . H
H17b .4684 1.0023 -.1663 .073 Uiso calc R 1 . . H
H18a .4612 .9816 -.3620 .160 Uiso calc R 1 . . H
H18b .4137 .8407 -.3211 .160 Uiso calc R 1 . . H
H18c .5648 .8783 -.3611 .160 Uiso calc R 1 . . H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0033 .0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0061 .0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S .1246 .1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
S1 Pb1 S2 . . 64.00(10) yes
S1 Pb1 S2 . 2_565 117.30(10) yes
S1 Pb1 S3 . . 98.90(10) yes
S1 Pb1 S4 . . 90.00(10) yes
S1 Pb1 S4 . 2_665 111.40(10) yes
S2 Pb1 S2 . 2_565 70.40(10) yes
S2 Pb1 S3 . . 89.90(10) yes
S2 Pb1 S4 . . 140.90(10) yes
S2 Pb1 S4 . 2_665 141.60(10) yes
S2 Pb1 S3 2_565 . 122.10(10) yes
S2 Pb1 S4 2_565 . 148.00(10) yes
S2 Pb1 S4 2_565 2_665 80.80(10) yes
S3 Pb1 S4 . . 64.60(10) yes
S3 Pb1 S4 . 2_665 127.50(10) yes
S4 Pb1 S4 . 2_665 73.30(10) yes
C1 S1 Pb1 . . 90.0(2) no
C1 S2 Pb1 . . 84.6(2) no
C10 S3 Pb1 . . 88.9(2) no
C10 S4 Pb1 . . 84.9(2) no
C1 N1 C2 . . 121.4(5) no
C1 N1 C8 . . 120.4(5) no
C2 N1 C8 . . 117.9(5) no
C10 N2 C17 . . 120.6(5) no
C10 N2 C11 . . 120.3(4) no
C17 N2 C11 . . 119.0(5) no
N1 C1 S2 . . 121.4(4) no
N1 C1 S1 . . 119.4(5) no
S2 C1 S1 . . 119.2(3) no
N1 C2 C3 . . 111.3(5) no
N1 C2 C7 . . 112.7(5) no
C3 C2 C7 . . 111.2(5) no
C4 C3 C2 . . 112.0(6) no
C5 C4 C3 . . 111.2(7) no
C6 C5 C4 . . 109.9(6) no
C5 C6 C7 . . 112.3(6) no
C2 C7 C6 . . 109.6(6) no
N1 C8 C9 . . 112.5(7) no
N2 C10 S4 . . 122.4(4) no
N2 C10 S3 . . 119.5(4) no
S4 C10 S3 . . 118.0(3) no
N2 C11 C12 . . 111.2(5) no
N2 C11 C16 . . 113.1(5) no
C12 C11 C16 . . 111.1(5) no
C11 C12 C13 . . 110.7(5) no
C14 C13 C12 . . 110.9(6) no
C15 C14 C13 . . 110.7(5) no
C14 C15 C16 . . 110.7(6) no
C11 C16 C15 . . 109.0(5) no
N2 C17 C18 . . 113.3(6) no
N1 C2 H2a . . 107.1 no
C3 C2 H2a . . 107.1 no
C7 C2 H2a . . 107.1 no
C4 C3 H3a . . 109.2 no
C2 C3 H3a . . 109.2 no
C4 C3 H3b . . 109.2 no
C2 C3 H3b . . 109.2 no
H3a C3 H3b . . 107.9 no
C5 C4 H4a . . 109.4 no
C3 C4 H4a . . 109.4 no
C5 C4 H4b . . 109.4 no
C3 C4 H4b . . 109.4 no
H4a C4 H4b . . 108.0 no
C6 C5 H5a . . 109.7 no
C4 C5 H5a . . 109.7 no
C6 C5 H5b . . 109.7 no
C4 C5 H5b . . 109.7 no
H5a C5 H5b . . 108.2 no
C5 C6 H6a . . 109.2 no
C7 C6 H6a . . 109.2 no
C5 C6 H6b . . 109.2 no
C7 C6 H6b . . 109.2 no
H6a C6 H6b . . 107.9 no
C2 C7 H7a . . 109.7 no
C6 C7 H7a . . 109.7 no
C2 C7 H7b . . 109.7 no
C6 C7 H7b . . 109.7 no
H7a C7 H7b . . 108.2 no
N1 C8 H8a . . 109.1 no
C9 C8 H8a . . 109.1 no
N1 C8 H8b . . 109.1 no
C9 C8 H8b . . 109.1 no
H8a C8 H8b . . 107.8 no
C8 C9 H9a . . 109.5 no
C8 C9 H9b . . 109.5 no
H9a C9 H9b . . 109.5 no
C8 C9 H9c . . 109.5 no
H9a C9 H9c . . 109.5 no
H9b C9 H9c . . 109.5 no
N2 C11 H11a . . 107.0 no
C12 C11 H11a . . 107.0 no
C16 C11 H11a . . 107.0 no
C11 C12 H12a . . 109.5 no
C13 C12 H12a . . 109.5 no
C11 C12 H12b . . 109.5 no
C13 C12 H12b . . 109.5 no
H12a C12 H12b . . 108.1 no
C14 C13 H13a . . 109.5 no
C12 C13 H13a . . 109.5 no
C14 C13 H13b . . 109.5 no
C12 C13 H13b . . 109.5 no
H13a C13 H13b . . 108.0 no
C15 C14 H14a . . 109.5 no
C13 C14 H14a . . 109.5 no
C15 C14 H14b . . 109.5 no
C13 C14 H14b . . 109.5 no
H14a C14 H14b . . 108.1 no
C14 C15 H15a . . 109.5 no
C16 C15 H15a . . 109.5 no
C14 C15 H15b . . 109.5 no
C16 C15 H15b . . 109.5 no
H15a C15 H15b . . 108.1 no
C11 C16 H16a . . 109.9 no
C15 C16 H16a . . 109.9 no
C11 C16 H16b . . 109.9 no
C15 C16 H16b . . 109.9 no
H16a C16 H16b . . 108.3 no
N2 C17 H17a . . 108.9 no
C18 C17 H17a . . 108.9 no
N2 C17 H17b . . 108.9 no
C18 C17 H17b . . 108.9 no
H17a C17 H17b . . 107.7 no
C17 C18 H18a . . 109.5 no
C17 C18 H18b . . 109.5 no
H18a C18 H18b . . 109.5 no
C17 C18 H18c . . 109.5 no
H18a C18 H18c . . 109.5 no
H18b C18 H18c . . 109.5 no
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Pb1 S1 . 2.710(2) yes
Pb1 S2 . 2.883(2) yes
Pb1 S2 2_565 3.508(2) yes
Pb1 S3 . 2.700(2) yes
Pb1 S4 . 2.841(2) yes
Pb1 S4 2_665 3.457(2) yes
S1 C1 . 1.726(6) no
S2 C1 . 1.712(6) no
S3 C10 . 1.740(6) no
S4 C10 . 1.714(6) no
N1 C1 . 1.353(7) no
N1 C2 . 1.472(7) no
N1 C8 . 1.473(9) no
N2 C10 . 1.329(7) no
N2 C17 . 1.478(8) no
N2 C11 . 1.492(7) no
C2 C3 . 1.517(8) no
C2 C7 . 1.520(8) no
C3 C4 . 1.510(10) no
C4 C5 . 1.500(10) no
C5 C6 . 1.500(10) no
C6 C7 . 1.520(10) no
C8 C9 . 1.520(10) no
C11 C12 . 1.513(8) no
C11 C16 . 1.524(8) no
C12 C13 . 1.527(9) no
C13 C14 . 1.520(10) no
C14 C15 . 1.510(10) no
C15 C16 . 1.535(9) no
C17 C18 . 1.500(10) no
C2 H2a . .9800 no
C3 H3a . .9700 no
C3 H3b . .9700 no
C4 H4a . .9700 no
C4 H4b . .9700 no
C5 H5a . .9700 no
C5 H5b . .9700 no
C6 H6a . .9700 no
C6 H6b . .9700 no
C7 H7a . .9700 no
C7 H7b . .9700 no
C8 H8a . .9700 no
C8 H8b . .9700 no
C9 H9a . .9600 no
C9 H9b . .9600 no
C9 H9c . .9600 no
C11 H11a . .9800 no
C12 H12a . .9700 no
C12 H12b . .9700 no
C13 H13a . .9700 no
C13 H13b . .9700 no
C14 H14a . .9700 no
C14 H14b . .9700 no
C15 H15a . .9700 no
C15 H15b . .9700 no
C16 H16a . .9700 no
C16 H16b . .9700 no
C17 H17a . .9700 no
C17 H17b . .9700 no
C18 H18a . .9600 no
C18 H18b . .9600 no
C18 H18c . .9600 no
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
_geom_torsion_publ_flag
S3 Pb1 S1 C1 . 94.1(2) no
S4 Pb1 S1 C1 . 158.4(2) no
S2 Pb1 S1 C1 . 8.7(2) no
S4 Pb1 S1 C1 2_665 -129.6(2) no
S2 Pb1 S1 C1 2_565 -39.1(2) no
S3 Pb1 S2 C1 . -108.7(2) no
S1 Pb1 S2 C1 . -8.8(2) no
S4 Pb1 S2 C1 . -61.8(2) no
S4 Pb1 S2 C1 2_665 83.3(2) no
S2 Pb1 S2 C1 2_565 126.9(2) no
S1 Pb1 S3 C10 . 96.7(2) no
S4 Pb1 S3 C10 . 11.0(2) no
S2 Pb1 S3 C10 . 160.3(2) no
S4 Pb1 S3 C10 2_665 -29.0(2) no
S2 Pb1 S3 C10 2_565 -133.1(2) no
S3 Pb1 S4 C10 . -11.2(2) no
S1 Pb1 S4 C10 . -111.0(2) no
S2 Pb1 S4 C10 . -65.1(2) no
S4 Pb1 S4 C10 2_665 136.7(2) no
S2 Pb1 S4 C10 2_565 99.2(2) no
C2 N1 C1 S2 . 7.3(8) no
C8 N1 C1 S2 . -179.7(5) no
C2 N1 C1 S1 . -173.0(4) no
C8 N1 C1 S1 . -.1(8) no
Pb1 S2 C1 N1 . -166.1(5) no
Pb1 S2 C1 S1 . 14.3(3) no
Pb1 S1 C1 N1 . 165.2(5) no
Pb1 S1 C1 S2 . -15.1(3) no
C1 N1 C2 C3 . 98.6(7) no
C8 N1 C2 C3 . -74.5(8) no
C1 N1 C2 C7 . -135.6(6) no
C8 N1 C2 C7 . 51.3(8) no
N1 C2 C3 C4 . -179.3(6) no
C7 C2 C3 C4 . 54.2(9) no
C2 C3 C4 C5 . -56.0(10) no
C3 C4 C5 C6 . 57.0(10) no
C4 C5 C6 C7 . -58.3(9) no
N1 C2 C7 C6 . -179.6(5) no
C3 C2 C7 C6 . -53.8(7) no
C5 C6 C7 C2 . 56.8(8) no
C1 N1 C8 C9 . 82.7(9) no
C2 N1 C8 C9 . -104.1(7) no
C17 N2 C10 S4 . -175.5(5) no
C11 N2 C10 S4 . 6.2(8) no
C17 N2 C10 S3 . 4.3(8) no
C11 N2 C10 S3 . -174.0(4) no
Pb1 S4 C10 N2 . -162.3(5) no
Pb1 S4 C10 S3 . 17.9(3) no
Pb1 S3 C10 N2 . 161.4(5) no
Pb1 S3 C10 S4 . -18.8(3) no
C10 N2 C11 C12 . 88.0(7) no
C17 N2 C11 C12 . -90.4(6) no
C10 N2 C11 C16 . -146.2(5) no
C17 N2 C11 C16 . 35.4(7) no
N2 C11 C12 C13 . -176.1(5) no
C16 C11 C12 C13 . 57.0(7) no
C11 C12 C13 C14 . -55.4(8) no
C12 C13 C14 C15 . 56.2(8) no
C13 C14 C15 C16 . -58.2(8) no
N2 C11 C16 C15 . 176.0(5) no
C12 C11 C16 C15 . -58.1(7) no
C14 C15 C16 C11 . 58.7(7) no
C10 N2 C17 C18 . -93.5(9) no
C11 N2 C17 C18 . 84.8(8) no
