#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/01/2200113.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2200113
loop_
_publ_author_name
'Skakle, Janet M. S.'
'Foreman, Mark R. St J.'
'Plater, M. John'
_publ_section_title
catena-Poly[[(2,2'-bipyridine-N,N')cobalt(II)]-μ-4,4'-oxydibenzoato-O,O':O'',O''']
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m169
_journal_page_last               m171
_journal_paper_doi               10.1107/S1600536801004949
_journal_volume                  57
_journal_year                    2001
_chemical_formula_iupac          '[Co (C14 H8 O5) (C10 H8 N2)]'
_chemical_formula_moiety         'C24 H16 Co N2 O5'
_chemical_formula_sum            'C24 H16 Co N2 O5'
_chemical_formula_weight         471.32
_chemical_name_systematic
;
catena-Poly[[(2,2'-bipyridine-N,N')cobalt(II)]-
μ-4,4'-oxydibenzoato-O,O':O'',O''']
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 96.3600(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   7.8975(4)
_cell_length_b                   17.6323(8)
_cell_length_c                   15.1057(7)
_cell_measurement_reflns_used    18261
_cell_measurement_temperature    302(2)
_cell_measurement_theta_max      29.99
_cell_measurement_theta_min      2.31
_cell_volume                     2090.54(17)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1999)'
_computing_data_reduction        SAINT
_computing_molecular_graphics
'ORTEP-3 for Windows (Farrugia, 1997) and PLATON (Spek, 2000)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      302(2)
_diffrn_measured_fraction_theta_full .995
_diffrn_measured_fraction_theta_max .995
_diffrn_measurement_device_type  'Bruker SMART 1000 area CCD'
_diffrn_measurement_method       φ--ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     .71073
_diffrn_reflns_av_R_equivalents  .0501
_diffrn_reflns_av_sigmaI/netI    .0523
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       22
_diffrn_reflns_limit_k_min       -24
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            18261
_diffrn_reflns_theta_full        29.99
_diffrn_reflns_theta_max         29.99
_diffrn_reflns_theta_min         2.31
_exptl_absorpt_coefficient_mu    .861
_exptl_absorpt_correction_T_max  .928
_exptl_absorpt_correction_T_min  .816
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 1999)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.497
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       needle
_exptl_crystal_F_000             964
_exptl_crystal_size_max          .4
_exptl_crystal_size_mid          .1
_exptl_crystal_size_min          .1
_refine_diff_density_max         .296
_refine_diff_density_min         -.341
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   .936
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         6071
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      .936
_refine_ls_R_factor_all          .0810
_refine_ls_R_factor_gt           .0416
_refine_ls_shift/su_max          .001
_refine_ls_shift/su_mean         .000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.075P)²] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         .1350
_reflns_number_gt                3584
_reflns_number_total             6071
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            bt6026.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2200113
_cod_database_fobs_code          2200113
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x+1/2, -y+1/2, z+1/2'
'-x, -y, -z'
'-x-1/2, y-1/2, -z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
_atom_site_type_symbol
Co1 .71362(4) .112194(19) .66625(2) .04221(12) Uani d . 1 . . Co
N1 .6977(2) -.00583(12) .65353(13) .0471(5) Uani d . 1 . . N
C1 .6777(4) -.05433(17) .72072(19) .0605(7) Uani d . 1 . . C
H1 .6596 -.0346 .7760 .073 Uiso calc R 1 . . H
C2 .6829(4) -.13155(19) .7107(2) .0754(9) Uani d . 1 . . C
H2 .6713 -.1637 .7585 .090 Uiso calc R 1 . . H
C3 .7059(4) -.16034(19) .6280(3) .0839(10) Uani d . 1 . . C
H3 .7059 -.2124 .6185 .101 Uiso calc R 1 . . H
C4 .7285(4) -.11147(17) .5602(2) .0727(9) Uani d . 1 . . C
H4 .7459 -.1302 .5044 .087 Uiso calc R 1 . . H
C5 .7256(3) -.03433(14) .57465(16) .0468(6) Uani d . 1 . . C
C6 .7472(3) .02364(16) .50406(16) .0499(6) Uani d . 1 . . C
C7 .7806(4) .0048(2) .41884(18) .0687(8) Uani d . 1 . . C
H7 .7901 -.0457 .4024 .082 Uiso calc R 1 . . H
C8 .7995(5) .0616(2) .3590(2) .0903(12) Uani d . 1 . . C
H8 .8218 .0499 .3014 .108 Uiso calc R 1 . . H
C9 .7856(5) .1354(2) .3841(2) .0831(11) Uani d . 1 . . C
H9 .7983 .1744 .3440 .100 Uiso calc R 1 . . H
C10 .7523(4) .15140(19) .46979(18) .0630(7) Uani d . 1 . . C
H10 .7396 .2017 .4863 .076 Uiso calc R 1 . . H
N2 .7377(3) .09658(12) .53017(13) .0487(5) Uani d . 1 . . N
O1 .4563(2) .14167(10) .65881(11) .0475(4) Uani d . 1 . . O
O2 .6458(2) .23221(10) .65684(13) .0548(4) Uani d . 1 . . O
C11 .4927(3) .21155(13) .65381(14) .0401(5) Uani d . 1 . . C
C12 .3518(3) .26841(13) .63932(14) .0378(5) Uani d . 1 . . C
C13 .1832(3) .24523(13) .62057(16) .0448(5) Uani d . 1 . . C
H13 .1560 .1941 .6240 .054 Uiso calc R 1 . . H
C14 .0562(3) .29751(14) .59699(17) .0487(6) Uani d . 1 . . C
H14 -.0564 .2818 .5846 .058 Uiso calc R 1 . . H
C15 .0976(3) .37312(13) .59204(14) .0403(5) Uani d . 1 . . C
C16 .2609(3) .39787(13) .61628(16) .0458(6) Uani d . 1 . . C
H16 .2861 .4494 .6171 .055 Uiso calc R 1 . . H
C17 .3870(3) .34521(14) .63931(16) .0474(6) Uani d . 1 . . C
H17 .4981 .3617 .6552 .057 Uiso calc R 1 . . H
O3 -.0255(2) .42793(10) .56850(12) .0547(5) Uani d . 1 . . O
C18 -.1506(3) .41133(14) .49901(15) .0439(5) Uani d . 1 . . C
C19 -.1116(3) .39169(14) .41517(17) .0511(6) Uani d . 1 . . C
H19 .0011 .3841 .4048 .061 Uiso calc R 1 . . H
C20 -.2422(3) .38335(14) .34665(16) .0476(6) Uani d . 1 . . C
H20 -.2169 .3714 .2896 .057 Uiso calc R 1 . . H
C21 -.4106(3) .39274(13) .36270(14) .0407(5) Uani d . 1 . . C
C22 -.4461(3) .41129(18) .44726(16) .0586(7) Uani d . 1 . . C
H22 -.5588 .4168 .4587 .070 Uiso calc R 1 . . H
C23 -.3167(3) .42171(19) .51502(17) .0607(7) Uani d . 1 . . C
H23 -.3417 .4357 .5715 .073 Uiso calc R 1 . . H
C24 -.5535(3) .38767(13) .28909(15) .0430(5) Uani d . 1 . . C
O4 -.5215(2) .38604(10) .20919(11) .0517(4) Uani d . 1 . . O
O5 -.7061(2) .38766(11) .30707(12) .0588(5) Uani d . 1 . . O
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C .0033 .0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H .0000 .0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Co Co .3494 .9721 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O .0106 .0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N .0061 .0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
O1 Co1 N1 . . 101.21(7) yes
O1 Co1 N2 . . 99.95(8) yes
N1 Co1 N2 . . 77.94(8) yes
O1 Co1 O4 . 2_655 159.03(7) yes
N1 Co1 O4 . 2_655 95.15(7) yes
N2 Co1 O4 . 2_655 96.20(7) yes
O1 Co1 O5 . 2_655 103.38(7) yes
N1 Co1 O5 . 2_655 95.75(8) yes
N2 Co1 O5 . 2_655 156.61(8) yes
O4 Co1 O5 2_655 2_655 61.62(6) yes
O1 Co1 O2 . . 61.65(6) yes
N1 Co1 O2 . . 161.10(7) yes
N2 Co1 O2 . . 96.39(8) yes
O4 Co1 O2 2_655 . 103.43(6) yes
O5 Co1 O2 2_655 . 96.11(7) yes
C5 N1 C1 . . 118.5(2) ?
C5 N1 Co1 . . 116.28(17) ?
C1 N1 Co1 . . 124.88(19) ?
N1 C1 C2 . . 122.6(3) ?
N1 C1 H1 . . 118.7 ?
C2 C1 H1 . . 118.7 ?
C1 C2 C3 . . 118.3(3) ?
C1 C2 H2 . . 120.9 ?
C3 C2 H2 . . 120.9 ?
C4 C3 C2 . . 119.2(3) ?
C4 C3 H3 . . 120.4 ?
C2 C3 H3 . . 120.4 ?
C3 C4 C5 . . 119.9(3) ?
C3 C4 H4 . . 120.0 ?
C5 C4 H4 . . 120.0 ?
N1 C5 C4 . . 121.4(3) ?
N1 C5 C6 . . 114.9(2) ?
C4 C5 C6 . . 123.7(3) ?
N2 C6 C7 . . 121.6(3) ?
N2 C6 C5 . . 115.3(2) ?
C7 C6 C5 . . 123.1(3) ?
C8 C7 C6 . . 119.0(3) ?
C8 C7 H7 . . 120.5 ?
C6 C7 H7 . . 120.5 ?
C9 C8 C7 . . 119.8(3) ?
C9 C8 H8 . . 120.1 ?
C7 C8 H8 . . 120.1 ?
C8 C9 C10 . . 119.1(3) ?
C8 C9 H9 . . 120.4 ?
C10 C9 H9 . . 120.4 ?
N2 C10 C9 . . 122.0(3) ?
N2 C10 H10 . . 119.0 ?
C9 C10 H10 . . 119.0 ?
C10 N2 C6 . . 118.4(2) ?
C10 N2 Co1 . . 126.4(2) ?
C6 N2 Co1 . . 115.10(16) ?
C11 O1 Co1 . . 91.10(13) ?
C11 O2 Co1 . . 87.11(14) ?
O2 C11 O1 . . 120.1(2) ?
O2 C11 C12 . . 120.5(2) ?
O1 C11 C12 . . 119.3(2) ?
C17 C12 C13 . . 118.4(2) ?
C17 C12 C11 . . 120.7(2) ?
C13 C12 C11 . . 120.8(2) ?
C14 C13 C12 . . 120.5(2) ?
C14 C13 H13 . . 119.7 ?
C12 C13 H13 . . 119.7 ?
C15 C14 C13 . . 119.4(2) ?
C15 C14 H14 . . 120.3 ?
C13 C14 H14 . . 120.3 ?
C16 C15 C14 . . 121.0(2) ?
C16 C15 O3 . . 117.2(2) ?
C14 C15 O3 . . 121.6(2) ?
C15 C16 C17 . . 119.0(2) ?
C15 C16 H16 . . 120.5 ?
C17 C16 H16 . . 120.5 ?
C16 C17 C12 . . 121.4(2) ?
C16 C17 H17 . . 119.3 ?
C12 C17 H17 . . 119.3 ?
C15 O3 C18 . . 117.73(18) ?
C23 C18 C19 . . 120.7(2) ?
C23 C18 O3 . . 116.9(2) ?
C19 C18 O3 . . 122.2(2) ?
C18 C19 C20 . . 119.3(2) ?
C18 C19 H19 . . 120.4 ?
C20 C19 H19 . . 120.4 ?
C19 C20 C21 . . 120.3(2) ?
C19 C20 H20 . . 119.8 ?
C21 C20 H20 . . 119.8 ?
C22 C21 C20 . . 119.2(2) ?
C22 C21 C24 . . 119.3(2) ?
C20 C21 C24 . . 121.4(2) ?
C23 C22 C21 . . 120.7(2) ?
C23 C22 H22 . . 119.7 ?
C21 C22 H22 . . 119.7 ?
C18 C23 C22 . . 119.8(2) ?
C18 C23 H23 . . 120.1 ?
C22 C23 H23 . . 120.1 ?
O4 C24 O5 . . 120.2(2) ?
O4 C24 C21 . . 119.9(2) ?
O5 C24 C21 . . 119.9(2) ?
C24 O4 Co1 . 2_354 89.85(14) ?
C24 O5 Co1 . 2_354 88.35(14) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Co1 O1 . 2.0885(16) yes
Co1 N1 . 2.092(2) yes
Co1 N2 . 2.103(2) yes
Co1 O4 2_655 2.1203(17) yes
Co1 O5 2_655 2.1513(18) yes
Co1 O2 . 2.1837(18) yes
N1 C5 . 1.334(3) ?
N1 C1 . 1.350(3) ?
C1 C2 . 1.371(4) ?
C1 H1 . .9300 ?
C2 C3 . 1.380(5) ?
C2 H2 . .9300 ?
C3 C4 . 1.365(5) ?
C3 H3 . .9300 ?
C4 C5 . 1.378(4) ?
C4 H4 . .9300 ?
C5 C6 . 1.500(4) ?
C6 N2 . 1.350(3) ?
C6 C7 . 1.383(3) ?
C7 C8 . 1.368(5) ?
C7 H7 . .9300 ?
C8 C9 . 1.363(5) ?
C8 H8 . .9300 ?
C9 C10 . 1.378(4) ?
C9 H9 . .9300 ?
C10 N2 . 1.343(3) ?
C10 H10 . .9300 ?
O1 C11 . 1.269(3) ?
O2 C11 . 1.258(3) ?
C11 C12 . 1.496(3) ?
C12 C17 . 1.382(3) ?
C12 C13 . 1.392(3) ?
C13 C14 . 1.380(3) ?
C13 H13 . .9300 ?
C14 C15 . 1.377(3) ?
C14 H14 . .9300 ?
C15 C16 . 1.372(3) ?
C15 O3 . 1.389(3) ?
C16 C17 . 1.378(3) ?
C16 H16 . .9300 ?
C17 H17 . .9300 ?
O3 C18 . 1.391(3) ?
C18 C23 . 1.372(3) ?
C18 C19 . 1.380(3) ?
C19 C20 . 1.386(3) ?
C19 H19 . .9300 ?
C20 C21 . 1.388(3) ?
C20 H20 . .9300 ?
C21 C22 . 1.377(3) ?
C21 C24 . 1.496(3) ?
C22 C23 . 1.377(3) ?
C22 H22 . .9300 ?
C23 H23 . .9300 ?
C24 O4 . 1.260(3) ?
C24 O5 . 1.264(3) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C2 H2 O2 4_757 .93 2.58 3.317(4) 136.0
C13 H13 O4 2 .93 2.45 3.201(3) 137.4
C20 H20 O1 2_454 .93 2.53 3.419(3) 158.9
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
O1 Co1 N1 C5 . . 104.17(17)
N2 Co1 N1 C5 . . 6.25(16)
O4 Co1 N1 C5 2_655 . -89.00(17)
O5 Co1 N1 C5 2_655 . -150.93(17)
O2 Co1 N1 C5 . . 80.4(3)
O1 Co1 N1 C1 . . -82.3(2)
N2 Co1 N1 C1 . . 179.8(2)
O4 Co1 N1 C1 2_655 . 84.5(2)
O5 Co1 N1 C1 2_655 . 22.6(2)
O2 Co1 N1 C1 . . -106.0(3)
C5 N1 C1 C2 . . -.7(4)
Co1 N1 C1 C2 . . -174.1(2)
N1 C1 C2 C3 . . -1.5(5)
C1 C2 C3 C4 . . 2.3(5)
C2 C3 C4 C5 . . -1.0(5)
C1 N1 C5 C4 . . 2.1(4)
Co1 N1 C5 C4 . . 176.1(2)
C1 N1 C5 C6 . . -179.7(2)
Co1 N1 C5 C6 . . -5.8(3)
C3 C4 C5 N1 . . -1.3(5)
C3 C4 C5 C6 . . -179.2(3)
N1 C5 C6 N2 . . .8(3)
C4 C5 C6 N2 . . 178.9(3)
N1 C5 C6 C7 . . 178.6(2)
C4 C5 C6 C7 . . -3.3(4)
N2 C6 C7 C8 . . -2.0(4)
C5 C6 C7 C8 . . -179.6(3)
C6 C7 C8 C9 . . .1(5)
C7 C8 C9 C10 . . -.1(6)
C8 C9 C10 N2 . . 1.8(5)
C9 C10 N2 C6 . . -3.6(4)
C9 C10 N2 Co1 . . 173.0(2)
C7 C6 N2 C10 . . 3.6(4)
C5 C6 N2 C10 . . -178.6(2)
C7 C6 N2 Co1 . . -173.3(2)
C5 C6 N2 Co1 . . 4.5(3)
O1 Co1 N2 C10 . . 78.2(2)
N1 Co1 N2 C10 . . 177.7(2)
O4 Co1 N2 C10 2_655 . -88.4(2)
O5 Co1 N2 C10 2_655 . -106.0(3)
O2 Co1 N2 C10 . . 15.9(2)
O1 Co1 N2 C6 . . -105.15(18)
N1 Co1 N2 C6 . . -5.68(17)
O4 Co1 N2 C6 2_655 . 88.28(18)
O5 Co1 N2 C6 2_655 . 70.7(3)
O2 Co1 N2 C6 . . -167.40(17)
N1 Co1 O1 C11 . . -170.71(13)
N2 Co1 O1 C11 . . -91.16(14)
O4 Co1 O1 C11 2_655 . 48.7(2)
O5 Co1 O1 C11 2_655 . 90.54(14)
O2 Co1 O1 C11 . . .77(12)
O1 Co1 O2 C11 . . -.78(13)
N1 Co1 O2 C11 . . 25.9(3)
N2 Co1 O2 C11 . . 97.10(15)
O4 Co1 O2 C11 2_655 . -164.94(13)
O5 Co1 O2 C11 2_655 . -102.71(14)
Co1 O2 C11 O1 . . 1.3(2)
Co1 O2 C11 C12 . . -175.33(18)
Co1 O1 C11 O2 . . -1.4(2)
Co1 O1 C11 C12 . . 175.31(17)
O2 C11 C12 C17 . . -7.5(3)
O1 C11 C12 C17 . . 175.8(2)
O2 C11 C12 C13 . . 168.8(2)
O1 C11 C12 C13 . . -7.8(3)
C17 C12 C13 C14 . . 4.1(3)
C11 C12 C13 C14 . . -172.3(2)
C12 C13 C14 C15 . . .1(4)
C13 C14 C15 C16 . . -4.7(4)
C13 C14 C15 O3 . . 179.9(2)
C14 C15 C16 C17 . . 5.0(4)
O3 C15 C16 C17 . . -179.4(2)
C15 C16 C17 C12 . . -.7(4)
C13 C12 C17 C16 . . -3.8(3)
C11 C12 C17 C16 . . 172.6(2)
C16 C15 O3 C18 . . 142.4(2)
C14 C15 O3 C18 . . -42.1(3)
C15 O3 C18 C23 . . 128.7(3)
C15 O3 C18 C19 . . -56.9(3)
C23 C18 C19 C20 . . .7(4)
O3 C18 C19 C20 . . -173.5(2)
C18 C19 C20 C21 . . -1.6(4)
C19 C20 C21 C22 . . .8(4)
C19 C20 C21 C24 . . 177.1(2)
C20 C21 C22 C23 . . 1.1(4)
C24 C21 C22 C23 . . -175.3(3)
C19 C18 C23 C22 . . 1.0(5)
O3 C18 C23 C22 . . 175.6(2)
C21 C22 C23 C18 . . -2.0(5)
C22 C21 C24 O4 . . 165.7(2)
C20 C21 C24 O4 . . -10.6(4)
C22 C21 C24 O5 . . -11.9(4)
C20 C21 C24 O5 . . 171.8(2)
O5 C24 O4 Co1 . 2_354 1.6(2)
C21 C24 O4 Co1 . 2_354 -175.97(19)
O4 C24 O5 Co1 . 2_354 -1.6(2)
C21 C24 O5 Co1 . 2_354 175.99(19)
