#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/42/2204294.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2204294
loop_
_publ_author_name
'Reto Dorta'
'Georg Süss-Fink'
'Helen Stoeckli-Evans'
_publ_section_title
Di-μ-acetato-κ⁴O:O'-tetracarbonylbis(pyridyl-2-yl-κN-amine)diruthenium(I)(Ru---Ru)
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1397
_journal_page_last               m1399
_journal_paper_doi               10.1107/S160053680402166X
_journal_volume                  60
_journal_year                    2004
_chemical_formula_iupac          '[Ru2 (C2 H3 O2)2 (C5 H6 N2)2 (C O)4]'
_chemical_formula_moiety         'C18 H18 N4 O8 Ru2'
_chemical_formula_sum            'C18 H18 N4 O8 Ru2'
_chemical_formula_weight         620.50
_chemical_name_systematic
;
Di-μ-acetato-κ⁴O:O'-tetracarbonylbis(pyridyl-2-yl-\kN-
amine)diruthenium(I)(Ru---Ru)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                83.82(2)
_cell_angle_beta                 78.925(17)
_cell_angle_gamma                76.881(15)
_cell_formula_units_Z            2
_cell_length_a                   9.3027(15)
_cell_length_b                   9.952(2)
_cell_length_c                   12.474(3)
_cell_measurement_reflns_used    23
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      16.8
_cell_measurement_theta_min      14.0
_cell_volume                     1101.3(4)
_computing_cell_refinement       STADI4
_computing_data_collection       'STADI4 (Stoe & Cie, 1997)'
_computing_data_reduction        'X-RED (Stoe & Cie, 1997)'
_computing_molecular_graphics
'PLATON  (Spek, 2003) and MERCURY (Bruno et al., 2002)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1990)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Stoe AED2 four-circle'
_diffrn_measurement_method       2θ/ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0195
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       15
_diffrn_reflns_limit_l_min       0
_diffrn_reflns_number            4092
_diffrn_reflns_theta_full        25.49
_diffrn_reflns_theta_max         25.49
_diffrn_reflns_theta_min         2.11
_diffrn_standards_decay_%        1
_diffrn_standards_interval_time  60
_diffrn_standards_number         3
_exptl_absorpt_coefficient_mu    1.423
_exptl_absorpt_correction_T_max  0.764
_exptl_absorpt_correction_T_min  0.363
_exptl_absorpt_correction_type   refdelf
_exptl_absorpt_process_details   '(DELrefABS in PLATON; Spek, 2003)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.871
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             612
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.34
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.421
_refine_diff_density_min         -0.377
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.117
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     305
_refine_ls_number_reflns         4092
_refine_ls_number_restraints     4
_refine_ls_restrained_S_all      1.117
_refine_ls_R_factor_all          0.0307
_refine_ls_R_factor_gt           0.0252
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         <0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0207P)²+1.3224P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0547
_refine_ls_wR_factor_ref         0.0581
_reflns_number_gt                3678
_reflns_number_total             4092
_reflns_threshold_expression     'I > 2σ(I)'
_cod_data_source_file            ci6437.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2204294
_cod_database_fobs_code          2204294
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Ru1 0.81649(3) 0.24089(2) 0.32290(2) 0.02656(7) Uani d . 1 Ru
Ru2 1.08333(3) 0.18889(2) 0.19130(2) 0.02594(7) Uani d . 1 Ru
O1 0.7364(2) 0.3021(2) 0.17226(17) 0.0342(5) Uani d . 1 O
O2 0.9619(2) 0.3138(2) 0.07518(17) 0.0329(5) Uani d . 1 O
O3 0.8575(2) 0.4451(2) 0.30466(18) 0.0344(5) Uani d . 1 O
O4 1.1011(2) 0.3856(2) 0.23392(18) 0.0333(5) Uani d . 1 O
O5 1.2456(3) 0.0260(3) 0.3636(3) 0.0683(9) Uani d . 1 O
O6 1.0494(3) -0.0786(3) 0.1224(3) 0.0630(8) Uani d . 1 O
O7 0.9554(3) 0.1836(3) 0.5242(2) 0.0626(8) Uani d . 1 O
O8 0.7785(3) -0.0503(3) 0.3327(2) 0.0564(7) Uani d . 1 O
N1 0.5768(3) 0.3439(3) 0.3892(2) 0.0330(6) Uani d . 1 N
N2 0.5285(4) 0.1594(4) 0.5101(3) 0.0593(10) Uani d D 1 N
H21 0.462(4) 0.125(5) 0.558(3) 0.075(15) Uiso d D 1 H
H22 0.623(2) 0.126(4) 0.509(3) 0.055(12) Uiso d D 1 H
N3 1.2812(3) 0.1995(3) 0.0582(2) 0.0300(6) Uani d . 1 N
N4 1.4300(3) 0.2434(4) 0.1744(3) 0.0457(8) Uani d D 1 N
H41 1.513(3) 0.266(3) 0.180(3) 0.027(8) Uiso d D 1 H
H42 1.346(3) 0.286(4) 0.214(3) 0.052(12) Uiso d D 1 H
C1 0.8211(3) 0.3464(3) 0.0908(3) 0.0297(7) Uani d . 1 C
C2 0.7477(4) 0.4465(4) 0.0084(3) 0.0502(10) Uani d . 1 C
H2C 0.8104 0.5106 -0.0218 0.075 Uiso calc R 1 H
H2B 0.6523 0.4961 0.0434 0.075 Uiso calc R 1 H
H2A 0.7335 0.3968 -0.0493 0.075 Uiso calc R 1 H
C3 0.9837(4) 0.4731(3) 0.2668(2) 0.0304(7) Uani d . 1 C
C4 0.9936(4) 0.6223(4) 0.2581(3) 0.0465(9) Uani d . 1 C
H4A 0.9275 0.6680 0.3185 0.070 Uiso calc R 1 H
H4B 0.9649 0.6658 0.1906 0.070 Uiso calc R 1 H
H4C 1.0946 0.6288 0.2595 0.070 Uiso calc R 1 H
C5 1.1840(4) 0.0895(4) 0.2972(3) 0.0399(8) Uani d . 1 C
C6 1.0606(4) 0.0249(3) 0.1502(3) 0.0378(8) Uani d . 1 C
C7 0.8998(4) 0.2024(4) 0.4475(3) 0.0379(8) Uani d . 1 C
C8 0.7921(4) 0.0624(4) 0.3286(3) 0.0352(7) Uani d . 1 C
C10 0.4779(4) 0.2826(4) 0.4584(3) 0.0390(8) Uani d . 1 C
C11 0.3250(4) 0.3427(4) 0.4776(3) 0.0497(10) Uani d . 1 C
H11A 0.2576 0.2959 0.5224 0.060 Uiso calc R 1 H
C12 0.2755(4) 0.4707(4) 0.4301(3) 0.0517(10) Uani d . 1 C
H12A 0.1743 0.5128 0.4436 0.062 Uiso calc R 1 H
C13 0.3765(4) 0.5370(4) 0.3618(3) 0.0489(9) Uani d . 1 C
H13A 0.3452 0.6245 0.3291 0.059 Uiso calc R 1 H
C14 0.5236(4) 0.4711(4) 0.3435(3) 0.0412(8) Uani d . 1 C
H14A 0.5913 0.5160 0.2970 0.049 Uiso calc R 1 H
C15 1.4171(3) 0.2103(3) 0.0748(3) 0.0332(7) Uani d . 1 C
C16 1.5427(4) 0.1841(4) -0.0085(3) 0.0409(8) Uani d . 1 C
H16A 1.6372 0.1855 0.0053 0.049 Uiso calc R 1 H
C17 1.5261(4) 0.1569(4) -0.1093(3) 0.0505(10) Uani d . 1 C
H17A 1.6091 0.1401 -0.1649 0.061 Uiso calc R 1 H
C18 1.3843(4) 0.1540(4) -0.1294(3) 0.0494(9) Uani d . 1 C
H18A 1.3697 0.1393 -0.1985 0.059 Uiso calc R 1 H
C19 1.2678(4) 0.1736(4) -0.0435(3) 0.0377(8) Uani d . 1 C
H19A 1.1735 0.1690 -0.0555 0.045 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C8 Ru1 C7 90.59(15) y
C8 Ru1 O1 95.02(12) y
C7 Ru1 O1 173.35(12) y
C8 Ru1 O3 175.45(12) y
C7 Ru1 O3 91.21(12) y
O1 Ru1 O3 82.94(9) y
C8 Ru1 N1 98.68(12) y
C7 Ru1 N1 102.03(13) y
O1 Ru1 N1 80.68(9) y
O3 Ru1 N1 85.03(9) y
C8 Ru1 Ru2 93.73(10) y
C7 Ru1 Ru2 93.02(11) y
O1 Ru1 Ru2 83.07(6) y
O3 Ru1 Ru2 82.01(6) y
N1 Ru1 Ru2 160.31(7) y
C6 Ru2 C5 88.00(16) y
C6 Ru2 O2 94.91(13) y
C5 Ru2 O2 176.54(13) y
C6 Ru2 O4 176.91(12) y
C5 Ru2 O4 95.01(13) y
O2 Ru2 O4 82.06(9) y
C6 Ru2 N3 93.14(13) y
C5 Ru2 N3 98.45(13) y
O2 Ru2 N3 83.27(9) y
O4 Ru2 N3 87.11(9) y
C6 Ru2 Ru1 94.75(11) y
C5 Ru2 Ru1 95.08(11) y
O2 Ru2 Ru1 82.83(6) y
O4 Ru2 Ru1 84.31(6) y
N3 Ru2 Ru1 164.55(7) y
C1 O1 Ru1 119.59(19) ?
C1 O2 Ru2 122.7(2) ?
C3 O3 Ru1 123.8(2) ?
C3 O4 Ru2 119.6(2) ?
C10 N1 C14 117.1(3) ?
C10 N1 Ru1 125.3(2) ?
C14 N1 Ru1 116.9(2) ?
C10 N2 H21 116(3) ?
C10 N2 H22 122(3) ?
H21 N2 H22 120(4) ?
C15 N3 C19 118.0(3) ?
C15 N3 Ru2 124.7(2) ?
C19 N3 Ru2 116.7(2) ?
C15 N4 H41 117(2) ?
C15 N4 H42 115(3) ?
H41 N4 H42 118(3) ?
O2 C1 O1 124.5(3) ?
O2 C1 C2 118.0(3) ?
O1 C1 C2 117.5(3) ?
C1 C2 H2C 109.5 ?
C1 C2 H2B 109.5 ?
H2C C2 H2B 109.5 ?
C1 C2 H2A 109.5 ?
H2C C2 H2A 109.5 ?
H2B C2 H2A 109.5 ?
O3 C3 O4 124.9(3) ?
O3 C3 C4 117.2(3) ?
O4 C3 C4 117.9(3) ?
C3 C4 H4A 109.5 ?
C3 C4 H4B 109.5 ?
H4A C4 H4B 109.5 ?
C3 C4 H4C 109.5 ?
H4A C4 H4C 109.5 ?
H4B C4 H4C 109.5 ?
O5 C5 Ru2 179.0(3) ?
O6 C6 Ru2 178.3(3) ?
O7 C7 Ru1 176.7(3) ?
O8 C8 Ru1 179.1(3) ?
N1 C10 N2 118.7(3) ?
N1 C10 C11 121.6(3) ?
N2 C10 C11 119.6(3) ?
C12 C11 C10 119.4(4) ?
C12 C11 H11A 120.3 ?
C10 C11 H11A 120.3 ?
C11 C12 C13 119.4(3) ?
C11 C12 H12A 120.3 ?
C13 C12 H12A 120.3 ?
C14 C13 C12 118.4(4) ?
C14 C13 H13A 120.8 ?
C12 C13 H13A 120.8 ?
N1 C14 C13 123.8(4) ?
N1 C14 H14A 118.1 ?
C13 C14 H14A 118.1 ?
N3 C15 N4 118.5(3) ?
N3 C15 C16 120.7(3) ?
N4 C15 C16 120.8(3) ?
C17 C16 C15 119.8(3) ?
C17 C16 H16A 120.1 ?
C15 C16 H16A 120.1 ?
C16 C17 C18 119.9(3) ?
C16 C17 H17A 120.1 ?
C18 C17 H17A 120.1 ?
C19 C18 C17 117.4(3) ?
C19 C18 H18A 121.3 ?
C17 C18 H18A 121.3 ?
N3 C19 C18 124.0(3) ?
N3 C19 H19A 118.0 ?
C18 C19 H19A 118.0 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Ru1 C8 1.833(3) y
Ru1 C7 1.834(4) y
Ru1 O1 2.131(2) y
Ru1 O3 2.132(2) y
Ru1 N1 2.267(3) y
Ru1 Ru2 2.6756(7) y
Ru2 C6 1.830(3) y
Ru2 C5 1.837(4) y
Ru2 O2 2.127(2) y
Ru2 O4 2.133(2) y
Ru2 N3 2.243(3) y
O1 C1 1.265(4) ?
O2 C1 1.258(4) ?
O3 C3 1.260(4) ?
O4 C3 1.262(4) ?
O5 C5 1.148(4) ?
O6 C6 1.154(4) ?
O7 C7 1.151(4) ?
O8 C8 1.152(4) ?
N1 C10 1.342(4) ?
N1 C14 1.357(4) ?
N2 C10 1.351(5) ?
N2 H21 0.880(19) ?
N2 H22 0.865(19) ?
N3 C15 1.349(4) ?
N3 C19 1.355(4) ?
N4 C15 1.353(4) ?
N4 H41 0.874(18) ?
N4 H42 0.882(19) ?
C1 C2 1.502(4) ?
C2 H2C 0.96 ?
C2 H2B 0.96 ?
C2 H2A 0.96 ?
C3 C4 1.499(4) ?
C4 H4A 0.96 ?
C4 H4B 0.96 ?
C4 H4C 0.96 ?
C10 C11 1.397(5) ?
C11 C12 1.365(6) ?
C11 H11A 0.93 ?
C12 C13 1.377(6) ?
C12 H12A 0.93 ?
C13 C14 1.363(5) ?
C13 H13A 0.93 ?
C14 H14A 0.93 ?
C15 C16 1.402(5) ?
C16 C17 1.359(5) ?
C16 H16A 0.93 ?
C17 C18 1.396(5) ?
C17 H17A 0.93 ?
C18 C19 1.365(5) ?
C18 H18A 0.93 ?
C19 H19A 0.93 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N2 H21 O8 2_656 0.880(19) 2.60(2) 3.461(4) 166(4)
N2 H22 O5 2_756 0.865(19) 2.39(3) 3.031(5) 132(3)
N4 H41 O1 1_655 0.874(18) 2.17(2) 3.032(4) 171(3)
N4 H42 O4 . 0.882(19) 2.24(3) 3.050(4) 152(3)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
C8 Ru1 Ru2 C6 16.29(15) ?
C7 Ru1 Ru2 C6 107.08(15) ?
O1 Ru1 Ru2 C6 -78.32(13) ?
O3 Ru1 Ru2 C6 -162.12(13) ?
N1 Ru1 Ru2 C6 -112.8(2) ?
C8 Ru1 Ru2 C5 -72.12(15) ?
C7 Ru1 Ru2 C5 18.67(15) ?
O1 Ru1 Ru2 C5 -166.73(13) ?
O3 Ru1 Ru2 C5 109.47(13) ?
N1 Ru1 Ru2 C5 158.7(2) ?
C8 Ru1 Ru2 O2 110.66(12) ?
C7 Ru1 Ru2 O2 -158.55(12) ?
O1 Ru1 Ru2 O2 16.05(9) y
O3 Ru1 Ru2 O2 -67.75(9) ?
N1 Ru1 Ru2 O2 -18.5(2) ?
C8 Ru1 Ru2 O4 -166.66(12) ?
C7 Ru1 Ru2 O4 -75.87(12) ?
O1 Ru1 Ru2 O4 98.72(9) ?
O3 Ru1 Ru2 O4 14.93(9) y
N1 Ru1 Ru2 O4 64.2(2) ?
C8 Ru1 Ru2 N3 136.7(3) ?
C7 Ru1 Ru2 N3 -132.5(3) ?
O1 Ru1 Ru2 N3 42.1(3) ?
O3 Ru1 Ru2 N3 -41.7(3) ?
N1 Ru1 Ru2 N3 7.6(3) ?
C8 Ru1 O1 C1 -120.6(2) ?
O3 Ru1 O1 C1 55.3(2) ?
N1 Ru1 O1 C1 141.4(2) ?
Ru2 Ru1 O1 C1 -27.4(2) ?
C6 Ru2 O2 C1 81.3(3) ?
O4 Ru2 O2 C1 -98.1(2) ?
N3 Ru2 O2 C1 173.9(2) ?
Ru1 Ru2 O2 C1 -12.9(2) ?
C7 Ru1 O3 C3 78.3(3) ?
O1 Ru1 O3 C3 -98.6(2) ?
N1 Ru1 O3 C3 -179.8(2) ?
Ru2 Ru1 O3 C3 -14.6(2) ?
C5 Ru2 O4 C3 -117.7(2) ?
O2 Ru2 O4 C3 60.4(2) ?
N3 Ru2 O4 C3 144.0(2) ?
Ru1 Ru2 O4 C3 -23.1(2) ?
C8 Ru1 N1 C10 28.1(3) ?
C7 Ru1 N1 C10 -64.4(3) ?
O1 Ru1 N1 C10 121.8(3) ?
O3 Ru1 N1 C10 -154.6(3) ?
Ru2 Ru1 N1 C10 156.5(2) ?
C8 Ru1 N1 C14 -142.3(3) ?
C7 Ru1 N1 C14 125.2(3) ?
O1 Ru1 N1 C14 -48.6(2) ?
O3 Ru1 N1 C14 35.0(2) ?
Ru2 Ru1 N1 C14 -13.9(4) ?
C6 Ru2 N3 C15 -123.6(3) ?
C5 Ru2 N3 C15 -35.1(3) ?
O2 Ru2 N3 C15 141.8(3) ?
O4 Ru2 N3 C15 59.5(2) ?
Ru1 Ru2 N3 C15 115.8(3) ?
C6 Ru2 N3 C19 46.8(3) ?
C5 Ru2 N3 C19 135.2(2) ?
O2 Ru2 N3 C19 -47.8(2) ?
O4 Ru2 N3 C19 -130.2(2) ?
Ru1 Ru2 N3 C19 -73.9(4) ?
Ru2 O2 C1 O1 -5.0(4) ?
Ru2 O2 C1 C2 174.0(2) ?
Ru1 O1 C1 O2 27.0(4) ?
Ru1 O1 C1 C2 -152.0(2) ?
Ru1 O3 C3 O4 0.8(4) ?
Ru1 O3 C3 C4 179.3(2) ?
Ru2 O4 C3 O3 19.7(4) ?
Ru2 O4 C3 C4 -158.7(2) ?
C14 N1 C10 N2 -176.3(3) ?
Ru1 N1 C10 N2 13.4(5) ?
C14 N1 C10 C11 4.0(5) ?
Ru1 N1 C10 C11 -166.4(3) ?
N1 C10 C11 C12 -3.9(6) ?
N2 C10 C11 C12 176.3(4) ?
C10 C11 C12 C13 1.6(6) ?
C11 C12 C13 C14 0.5(6) ?
C10 N1 C14 C13 -1.8(5) ?
Ru1 N1 C14 C13 169.4(3) ?
C12 C13 C14 N1 -0.4(6) ?
C19 N3 C15 N4 176.5(3) ?
Ru2 N3 C15 N4 -13.3(4) ?
C19 N3 C15 C16 -5.2(5) ?
Ru2 N3 C15 C16 165.0(2) ?
N3 C15 C16 C17 4.5(5) ?
N4 C15 C16 C17 -177.2(4) ?
C15 C16 C17 C18 -0.5(6) ?
C16 C17 C18 C19 -2.7(6) ?
C15 N3 C19 C18 1.9(5) ?
Ru2 N3 C19 C18 -169.1(3) ?
C17 C18 C19 N3 2.0(6) ?
