#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/51/2205138.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2205138
loop_
_publ_author_name
'Yang, De-Suo'
_publ_section_title
;
 Bis[4-bromo-2-(cyclohexyliminomethyl)phenolato]copper(II)
;
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m249
_journal_page_last               m250
_journal_paper_doi               10.1107/S1600536805000280
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Cu (C13 H15 Br1 N1 O1)2]'
_chemical_formula_moiety         'C26 H30 Br2 Cu N2 O2'
_chemical_formula_sum            'C26 H30 Br2 Cu N2 O2'
_chemical_formula_weight         625.88
_chemical_name_systematic
;
Bis[4-bromo-2-(cyclohexyliminomethyl)phenolato]copper(II)
;
_space_group_IT_number           61
_symmetry_cell_setting           orthorhombic
_symmetry_space_group_name_Hall  '-P 2ac 2ab'
_symmetry_space_group_name_H-M   'P b c a'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 90.00
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   14.9960(10)
_cell_length_b                   13.5970(10)
_cell_length_c                   25.156(2)
_cell_measurement_reflns_used    10170
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      22.8
_cell_measurement_theta_min      2.6
_cell_volume                     5129.3(7)
_computing_cell_refinement       'SAINT (Bruker, 2002)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Sheldrick, 1997b)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997a)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997a)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.996
_diffrn_measured_fraction_theta_max 0.996
_diffrn_measurement_device_type  'Bruker APEX area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0459
_diffrn_reflns_av_sigmaI/netI    0.0297
_diffrn_reflns_limit_h_max       19
_diffrn_reflns_limit_h_min       -19
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       32
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            56364
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         1.62
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    3.993
_exptl_absorpt_correction_T_max  0.487
_exptl_absorpt_correction_T_min  0.433
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.621
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2520
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.712
_refine_diff_density_min         -0.355
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     298
_refine_ls_number_reflns         5866
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.032
_refine_ls_R_factor_all          0.0705
_refine_ls_R_factor_gt           0.0431
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0513P)²+4.6248P] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1043
_refine_ls_wR_factor_ref         0.1169
_reflns_number_gt                4083
_reflns_number_total             5866
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ob6467.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Orthorhombic' changed to 'orthorhombic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Orthorhombic' changed to
'orthorhombic' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2205138
_cod_database_fobs_code          2205138
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, -y, z+1/2'
'-x, y+1/2, -z+1/2'
'x+1/2, -y+1/2, -z'
'-x, -y, -z'
'x-1/2, y, -z-1/2'
'x, -y-1/2, z-1/2'
'-x-1/2, y-1/2, z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Cu1 0.14073(3) 0.58035(3) 0.307450(17) 0.04668(13) Uani d . 1 Cu
Br1 -0.11579(4) 0.89451(4) 0.48997(2) 0.0925(2) Uani d . 1 Br
Br2 0.32284(3) 0.25746(4) 0.101200(18) 0.07509(16) Uani d . 1 Br
O1 0.15852(17) 0.66642(19) 0.36704(11) 0.0614(7) Uani d . 1 O
O2 0.21850(17) 0.58901(17) 0.24711(11) 0.0570(6) Uani d . 1 O
N1 0.01424(19) 0.6249(2) 0.29250(11) 0.0459(6) Uani d . 1 N
N2 0.1724(2) 0.4384(2) 0.32252(12) 0.0487(7) Uani d . 1 N
C1 0.0055(2) 0.7203(2) 0.37494(14) 0.0470(8) Uani d . 1 C
C2 0.0948(3) 0.7099(2) 0.39320(14) 0.0507(9) Uani d . 1 C
C3 0.1138(3) 0.7531(3) 0.44319(16) 0.0601(10) Uani d . 1 C
H3 0.1704 0.7448 0.4575 0.072 Uiso calc R 1 H
C4 0.0533(3) 0.8060(3) 0.47094(15) 0.0645(11) Uani d . 1 C
H4 0.0692 0.8343 0.5032 0.077 Uiso calc R 1 H
C5 -0.0319(3) 0.8180(3) 0.45154(14) 0.0600(10) Uani d . 1 C
C6 -0.0558(3) 0.7753(3) 0.40463(14) 0.0548(9) Uani d . 1 C
H6 -0.1138 0.7829 0.3921 0.066 Uiso calc R 1 H
C7 -0.0266(2) 0.6806(3) 0.32519(14) 0.0490(8) Uani d . 1 C
H7 -0.0845 0.6978 0.3158 0.059 Uiso calc R 1 H
C8 -0.0334(2) 0.5972(2) 0.24355(14) 0.0481(8) Uani d . 1 C
H8 -0.0970 0.6116 0.2483 0.058 Uiso calc R 1 H
C9 -0.0232(3) 0.4892(3) 0.23293(15) 0.0550(9) Uani d . 1 C
H9A -0.0501 0.4520 0.2616 0.066 Uiso calc R 1 H
H9B 0.0397 0.4725 0.2315 0.066 Uiso calc R 1 H
C10 -0.0674(3) 0.4616(3) 0.18054(16) 0.0677(11) Uani d . 1 C
H10A -0.0576 0.3923 0.1735 0.081 Uiso calc R 1 H
H10B -0.1312 0.4724 0.1833 0.081 Uiso calc R 1 H
C11 -0.0309(3) 0.5213(4) 0.13520(17) 0.0766(13) Uani d . 1 C
H11A 0.0321 0.5072 0.1308 0.092 Uiso calc R 1 H
H11B -0.0613 0.5032 0.1026 0.092 Uiso calc R 1 H
C12 -0.0435(4) 0.6289(3) 0.14551(16) 0.0788(13) Uani d . 1 C
H12A -0.1067 0.6438 0.1474 0.095 Uiso calc R 1 H
H12B -0.0181 0.6664 0.1164 0.095 Uiso calc R 1 H
C13 0.0015(3) 0.6589(3) 0.19768(15) 0.0667(11) Uani d . 1 C
H13A 0.0655 0.6502 0.1946 0.080 Uiso calc R 1 H
H13B -0.0100 0.7279 0.2047 0.080 Uiso calc R 1 H
C14 0.2364(2) 0.4137(2) 0.23458(13) 0.0463(8) Uani d . 1 C
C15 0.2394(2) 0.5131(3) 0.21718(15) 0.0511(8) Uani d . 1 C
C16 0.2703(3) 0.5295(3) 0.16496(15) 0.0598(10) Uani d . 1 C
H16 0.2748 0.5939 0.1529 0.072 Uiso calc R 1 H
C17 0.2937(3) 0.4556(3) 0.13154(16) 0.0606(10) Uani d . 1 C
H17 0.3119 0.4695 0.0970 0.073 Uiso calc R 1 H
C18 0.2903(2) 0.3594(3) 0.14933(14) 0.0533(9) Uani d . 1 C
C19 0.2636(2) 0.3378(3) 0.19992(14) 0.0506(8) Uani d . 1 C
H19 0.2634 0.2728 0.2116 0.061 Uiso calc R 1 H
C20 0.2090(2) 0.3838(3) 0.28718(14) 0.0479(8) Uani d . 1 C
H20 0.2190 0.3184 0.2963 0.058 Uiso calc R 1 H
C21 0.1532(2) 0.3957(3) 0.37550(15) 0.0524(9) Uani d . 1 C
H21 0.1624 0.3244 0.3739 0.063 Uiso calc R 1 H
C22 0.2179(3) 0.4392(3) 0.41604(15) 0.0623(10) Uani d . 1 C
H22A 0.2783 0.4196 0.4071 0.075 Uiso calc R 1 H
H22B 0.2148 0.5104 0.4146 0.075 Uiso calc R 1 H
C23 0.1958(3) 0.4045(4) 0.47222(17) 0.0718(12) Uani d . 1 C
H23A 0.2062 0.3343 0.4749 0.086 Uiso calc R 1 H
H23B 0.2349 0.4372 0.4974 0.086 Uiso calc R 1 H
C24 0.1004(3) 0.4265(3) 0.48611(16) 0.0695(11) Uani d . 1 C
H24A 0.0913 0.4972 0.4866 0.083 Uiso calc R 1 H
H24B 0.0874 0.4014 0.5214 0.083 Uiso calc R 1 H
C25 0.0368(3) 0.3798(3) 0.44595(15) 0.0632(10) Uani d . 1 C
H25A 0.0428 0.3088 0.4472 0.076 Uiso calc R 1 H
H25B -0.0242 0.3963 0.4552 0.076 Uiso calc R 1 H
C26 0.0569(2) 0.4158(3) 0.39027(15) 0.0553(9) Uani d . 1 C
H26A 0.0455 0.4859 0.3882 0.066 Uiso calc R 1 H
H26B 0.0179 0.3830 0.3652 0.066 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Br Br -0.2901 2.4595 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O2 Cu1 O1 119.73(12) y
O2 Cu1 N2 93.69(11) y
O1 Cu1 N2 113.74(12) y
O2 Cu1 N1 113.83(11) y
O1 Cu1 N1 95.32(11) y
N2 Cu1 N1 122.65(12) y
C2 O1 Cu1 124.7(2) ?
C15 O2 Cu1 123.3(2) ?
C7 N1 C8 117.3(3) ?
C7 N1 Cu1 120.5(2) ?
C8 N1 Cu1 122.2(2) ?
C20 N2 C21 118.7(3) ?
C20 N2 Cu1 121.5(2) ?
C21 N2 Cu1 119.8(2) ?
C6 C1 C2 119.9(3) ?
C6 C1 C7 116.3(3) ?
C2 C1 C7 123.7(3) ?
O1 C2 C3 119.3(3) ?
O1 C2 C1 124.9(3) ?
C3 C2 C1 115.7(4) ?
C4 C3 C2 123.0(4) ?
C4 C3 H3 118.5 ?
C2 C3 H3 118.5 ?
C3 C4 C5 120.2(4) ?
C3 C4 H4 119.9 ?
C5 C4 H4 119.9 ?
C6 C5 C4 120.1(4) ?
C6 C5 Br1 120.0(3) ?
C4 C5 Br1 120.0(3) ?
C5 C6 C1 121.1(4) ?
C5 C6 H6 119.5 ?
C1 C6 H6 119.5 ?
N1 C7 C1 128.4(3) ?
N1 C7 H7 115.8 ?
C1 C7 H7 115.8 ?
N1 C8 C9 110.5(3) ?
N1 C8 C13 109.0(3) ?
C9 C8 C13 111.7(3) ?
N1 C8 H8 108.5 ?
C9 C8 H8 108.5 ?
C13 C8 H8 108.5 ?
C8 C9 C10 110.5(3) ?
C8 C9 H9A 109.5 ?
C10 C9 H9A 109.5 ?
C8 C9 H9B 109.5 ?
C10 C9 H9B 109.5 ?
H9A C9 H9B 108.1 ?
C11 C10 C9 111.4(3) ?
C11 C10 H10A 109.3 ?
C9 C10 H10A 109.3 ?
C11 C10 H10B 109.3 ?
C9 C10 H10B 109.3 ?
H10A C10 H10B 108.0 ?
C12 C11 C10 110.5(4) ?
C12 C11 H11A 109.5 ?
C10 C11 H11A 109.5 ?
C12 C11 H11B 109.5 ?
C10 C11 H11B 109.5 ?
H11A C11 H11B 108.1 ?
C11 C12 C13 110.7(4) ?
C11 C12 H12A 109.5 ?
C13 C12 H12A 109.5 ?
C11 C12 H12B 109.5 ?
C13 C12 H12B 109.5 ?
H12A C12 H12B 108.1 ?
C8 C13 C12 110.6(3) ?
C8 C13 H13A 109.5 ?
C12 C13 H13A 109.5 ?
C8 C13 H13B 109.5 ?
C12 C13 H13B 109.5 ?
H13A C13 H13B 108.1 ?
C19 C14 C15 119.8(3) ?
C19 C14 C20 116.2(3) ?
C15 C14 C20 124.0(3) ?
O2 C15 C16 119.1(3) ?
O2 C15 C14 124.2(3) ?
C16 C15 C14 116.6(3) ?
C17 C16 C15 123.0(4) ?
C17 C16 H16 118.5 ?
C15 C16 H16 118.5 ?
C16 C17 C18 119.3(3) ?
C16 C17 H17 120.3 ?
C18 C17 H17 120.3 ?
C19 C18 C17 121.1(4) ?
C19 C18 Br2 120.7(3) ?
C17 C18 Br2 118.2(3) ?
C18 C19 C14 120.2(3) ?
C18 C19 H19 119.9 ?
C14 C19 H19 119.9 ?
N2 C20 C14 126.4(3) ?
N2 C20 H20 116.8 ?
C14 C20 H20 116.8 ?
N2 C21 C26 109.5(3) ?
N2 C21 C22 109.1(3) ?
C26 C21 C22 111.8(3) ?
N2 C21 H21 108.8 ?
C26 C21 H21 108.8 ?
C22 C21 H21 108.8 ?
C23 C22 C21 111.2(3) ?
C23 C22 H22A 109.4 ?
C21 C22 H22A 109.4 ?
C23 C22 H22B 109.4 ?
C21 C22 H22B 109.4 ?
H22A C22 H22B 108.0 ?
C24 C23 C22 111.1(4) ?
C24 C23 H23A 109.4 ?
C22 C23 H23A 109.4 ?
C24 C23 H23B 109.4 ?
C22 C23 H23B 109.4 ?
H23A C23 H23B 108.0 ?
C23 C24 C25 111.0(3) ?
C23 C24 H24A 109.4 ?
C25 C24 H24A 109.4 ?
C23 C24 H24B 109.4 ?
C25 C24 H24B 109.4 ?
H24A C24 H24B 108.0 ?
C26 C25 C24 110.6(3) ?
C26 C25 H25A 109.5 ?
C24 C25 H25A 109.5 ?
C26 C25 H25B 109.5 ?
C24 C25 H25B 109.5 ?
H25A C25 H25B 108.1 ?
C25 C26 C21 111.0(3) ?
C25 C26 H26A 109.4 ?
C21 C26 H26A 109.4 ?
C25 C26 H26B 109.4 ?
C21 C26 H26B 109.4 ?
H26A C26 H26B 108.0 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 O2 1.918(3) y
Cu1 O1 1.920(3) y
Cu1 N2 2.024(3) y
Cu1 N1 2.027(3) y
Br1 C5 1.898(4) ?
Br2 C18 1.904(4) ?
O1 C2 1.302(4) ?
O2 C15 1.316(4) ?
N1 C7 1.274(4) ?
N1 C8 1.473(4) ?
N2 C20 1.282(4) ?
N2 C21 1.482(4) ?
C1 C6 1.401(5) ?
C1 C2 1.423(5) ?
C1 C7 1.446(5) ?
C2 C3 1.417(5) ?
C3 C4 1.351(6) ?
C3 H3 0.9300 ?
C4 C5 1.377(6) ?
C4 H4 0.9300 ?
C5 C6 1.363(5) ?
C6 H6 0.9300 ?
C7 H7 0.9300 ?
C8 C9 1.501(5) ?
C8 C13 1.520(5) ?
C8 H8 0.9800 ?
C9 C10 1.522(5) ?
C9 H9A 0.9700 ?
C9 H9B 0.9700 ?
C10 C11 1.503(6) ?
C10 H10A 0.9700 ?
C10 H10B 0.9700 ?
C11 C12 1.499(7) ?
C11 H11A 0.9700 ?
C11 H11B 0.9700 ?
C12 C13 1.531(5) ?
C12 H12A 0.9700 ?
C12 H12B 0.9700 ?
C13 H13A 0.9700 ?
C13 H13B 0.9700 ?
C14 C19 1.411(5) ?
C14 C15 1.421(5) ?
C14 C20 1.444(5) ?
C15 C16 1.411(5) ?
C16 C17 1.356(5) ?
C16 H16 0.9300 ?
C17 C18 1.384(5) ?
C17 H17 0.9300 ?
C18 C19 1.366(5) ?
C19 H19 0.9300 ?
C20 H20 0.9300 ?
C21 C26 1.515(5) ?
C21 C22 1.526(6) ?
C21 H21 0.9800 ?
C22 C23 1.526(5) ?
C22 H22A 0.9700 ?
C22 H22B 0.9700 ?
C23 C24 1.504(6) ?
C23 H23A 0.9700 ?
C23 H23B 0.9700 ?
C24 C25 1.528(6) ?
C24 H24A 0.9700 ?
C24 H24B 0.9700 ?
C25 C26 1.514(5) ?
C25 H25A 0.9700 ?
C25 H25B 0.9700 ?
C26 H26A 0.9700 ?
C26 H26B 0.9700 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
O2 Cu1 O1 C2 138.7(3)
N2 Cu1 O1 C2 -111.9(3)
N1 Cu1 O1 C2 17.3(3)
O1 Cu1 O2 C15 148.6(3)
N2 Cu1 O2 C15 28.5(3)
N1 Cu1 O2 C15 -99.8(3)
O2 Cu1 N1 C7 -135.4(3)
O1 Cu1 N1 C7 -9.6(3)
N2 Cu1 N1 C7 113.1(3)
O2 Cu1 N1 C8 43.0(3)
O1 Cu1 N1 C8 168.9(2)
N2 Cu1 N1 C8 -68.5(3)
O2 Cu1 N2 C20 -18.3(3)
O1 Cu1 N2 C20 -143.1(3)
N1 Cu1 N2 C20 103.2(3)
O2 Cu1 N2 C21 161.6(3)
O1 Cu1 N2 C21 36.8(3)
N1 Cu1 N2 C21 -76.9(3)
Cu1 O1 C2 C3 165.7(3)
Cu1 O1 C2 C1 -16.0(5)
C6 C1 C2 O1 -174.9(3)
C7 C1 C2 O1 2.1(6)
C6 C1 C2 C3 3.4(5)
C7 C1 C2 C3 -179.5(3)
O1 C2 C3 C4 174.8(4)
C1 C2 C3 C4 -3.7(5)
C2 C3 C4 C5 1.5(6)
C3 C4 C5 C6 1.0(6)
C3 C4 C5 Br1 -178.7(3)
C4 C5 C6 C1 -1.1(6)
Br1 C5 C6 C1 178.6(3)
C2 C1 C6 C5 -1.2(5)
C7 C1 C6 C5 -178.5(3)
C8 N1 C7 C1 -178.3(3)
Cu1 N1 C7 C1 0.3(5)
C6 C1 C7 N1 -176.5(4)
C2 C1 C7 N1 6.4(6)
C7 N1 C8 C9 -134.6(3)
Cu1 N1 C8 C9 46.9(4)
C7 N1 C8 C13 102.3(4)
Cu1 N1 C8 C13 -76.2(3)
N1 C8 C9 C10 -176.4(3)
C13 C8 C9 C10 -54.9(4)
C8 C9 C10 C11 56.3(5)
C9 C10 C11 C12 -57.9(5)
C10 C11 C12 C13 57.5(5)
N1 C8 C13 C12 177.4(3)
C9 C8 C13 C12 55.1(5)
C11 C12 C13 C8 -56.1(5)
Cu1 O2 C15 C16 158.5(3)
Cu1 O2 C15 C14 -24.1(5)
C19 C14 C15 O2 -177.5(3)
C20 C14 C15 O2 0.7(5)
C19 C14 C15 C16 0.0(5)
C20 C14 C15 C16 178.2(3)
O2 C15 C16 C17 179.7(4)
C14 C15 C16 C17 2.0(6)
C15 C16 C17 C18 -2.1(6)
C16 C17 C18 C19 0.1(6)
C16 C17 C18 Br2 179.6(3)
C17 C18 C19 C14 1.9(6)
Br2 C18 C19 C14 -177.6(3)
C15 C14 C19 C18 -1.9(5)
C20 C14 C19 C18 179.7(3)
C21 N2 C20 C14 -176.8(3)
Cu1 N2 C20 C14 3.1(5)
C19 C14 C20 N2 -171.2(3)
C15 C14 C20 N2 10.5(6)
C20 N2 C21 C26 -129.2(3)
Cu1 N2 C21 C26 50.9(4)
C20 N2 C21 C22 108.1(4)
Cu1 N2 C21 C22 -71.7(3)
N2 C21 C22 C23 175.0(3)
C26 C21 C22 C23 53.7(4)
C21 C22 C23 C24 -54.7(5)
C22 C23 C24 C25 56.7(5)
C23 C24 C25 C26 -57.7(5)
C24 C25 C26 C21 56.4(4)
N2 C21 C26 C25 -175.8(3)
C22 C21 C26 C25 -54.8(4)
