#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/57/2205717.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2205717
loop_
_publ_author_name
'Linfang Jia'
'Wenfu Fu'
'Mingming Yu'
'Junfeng Zhang'
'Yong Chen'
_publ_section_title
;(Trans-dichloro-κCl)bis[(dicyclohexylphosphino)methane-κ²P,P']
 ruthenium(II)
;
_journal_issue                   5
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m858
_journal_page_last               m859
_journal_paper_doi               10.1107/S1600536805010743
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Ru (C25 H46 P2)2 Cl2]'
_chemical_formula_moiety         'C50 H92 Cl2 P4 Ru'
_chemical_formula_sum            'C50 H92 Cl2 P4 Ru'
_chemical_formula_weight         989.09
_chemical_name_systematic
;
 ?
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.098(8)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.120(11)
_cell_length_b                   10.732(5)
_cell_length_c                   21.780(11)
_cell_measurement_reflns_used    858
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.30
_cell_measurement_theta_min      2.68
_cell_volume                     5359(4)
_computing_cell_refinement       SMART
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  SHELXTL
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0396
_diffrn_reflns_av_sigmaI/netI    0.0443
_diffrn_reflns_limit_h_max       24
_diffrn_reflns_limit_h_min       -28
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            13674
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.97
_diffrn_standards_decay_%        0
_exptl_absorpt_coefficient_mu    0.543
_exptl_absorpt_correction_T_max  0.937
_exptl_absorpt_correction_T_min  0.796
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 1998)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    1.226
_exptl_crystal_density_meas      ?
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2120
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.18
_exptl_crystal_size_min          0.12
_refine_diff_density_max         0.295
_refine_diff_density_min         -0.423
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.085
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     259
_refine_ls_number_reflns         4717
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.085
_refine_ls_R_factor_all          0.0504
_refine_ls_R_factor_gt           0.0324
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0366P)²+1.6382P] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0743
_refine_ls_wR_factor_ref         0.0827
_reflns_number_gt                3644
_reflns_number_total             4717
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hb6174.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 

The following automatic conversions were performed:

'_exptl_crystal_density_meas' value 'none' was changed to '?' - the
value is perceived as not measured.

Automatic conversion script
Id: cif_fix_values 3008 2015-01-20 13:52:24Z robertas 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2205717
_cod_database_fobs_code          2205717
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Ru1 0.5000 1.0000 0.0000 0.02355(10) Uani d S 1 Ru
P1 0.44129(3) 0.91073(6) 0.05829(3) 0.02707(17) Uani d . 1 P
P2 0.55080(3) 1.01477(6) 0.11180(3) 0.02706(17) Uani d . 1 P
Cl1 0.45482(3) 1.19734(6) 0.01211(3) 0.03483(18) Uani d . 1 Cl
C1 0.44881(12) 0.7423(2) 0.07839(13) 0.0320(6) Uani d . 1 C
H1 0.4909 0.7270 0.0918 0.038 Uiso calc R 1 H
C2 0.42999(15) 0.6997(3) 0.13569(16) 0.0519(9) Uani d . 1 C
H2A 0.4469 0.7542 0.1723 0.062 Uiso calc R 1 H
H2B 0.3879 0.7049 0.1246 0.062 Uiso calc R 1 H
C3 0.44952(17) 0.5662(3) 0.15408(18) 0.0651(10) Uani d . 1 C
H3A 0.4918 0.5624 0.1682 0.078 Uiso calc R 1 H
H3B 0.4363 0.5400 0.1898 0.078 Uiso calc R 1 H
C4 0.42556(18) 0.4785(3) 0.09782(19) 0.0644(11) Uani d . 1 C
H4A 0.3834 0.4742 0.0871 0.077 Uiso calc R 1 H
H4B 0.4411 0.3956 0.1100 0.077 Uiso calc R 1 H
C5 0.44154(17) 0.5217(3) 0.03885(18) 0.0599(10) Uani d . 1 C
H5A 0.4833 0.5136 0.0475 0.072 Uiso calc R 1 H
H5B 0.4225 0.4682 0.0025 0.072 Uiso calc R 1 H
C6 0.42390(14) 0.6554(3) 0.02102(15) 0.0441(8) Uani d . 1 C
H6A 0.3817 0.6616 0.0065 0.053 Uiso calc R 1 H
H6B 0.4378 0.6808 -0.0143 0.053 Uiso calc R 1 H
C7 0.36543(11) 0.9644(3) 0.04876(14) 0.0354(7) Uani d . 1 C
H7 0.3642 1.0503 0.0331 0.042 Uiso calc R 1 H
C8 0.34868(14) 0.9746(3) 0.11041(16) 0.0558(9) Uani d . 1 C
H8A 0.3786 1.0203 0.1427 0.067 Uiso calc R 1 H
H8B 0.3461 0.8918 0.1272 0.067 Uiso calc R 1 H
C9 0.29017(14) 1.0411(4) 0.0976(2) 0.0701(11) Uani d . 1 C
H9A 0.2795 1.0428 0.1371 0.084 Uiso calc R 1 H
H9B 0.2940 1.1266 0.0850 0.084 Uiso calc R 1 H
C10 0.24279(15) 0.9781(4) 0.0455(2) 0.0775(13) Uani d . 1 C
H10A 0.2072 1.0265 0.0364 0.093 Uiso calc R 1 H
H10B 0.2354 0.8965 0.0604 0.093 Uiso calc R 1 H
C11 0.25912(14) 0.9641(4) -0.01534(19) 0.0724(12) Uani d . 1 C
H11A 0.2612 1.0459 -0.0334 0.087 Uiso calc R 1 H
H11B 0.2290 0.9170 -0.0467 0.087 Uiso calc R 1 H
C12 0.31793(12) 0.8975(3) -0.00307(16) 0.0507(8) Uani d . 1 C
H12A 0.3147 0.8124 0.0104 0.061 Uiso calc R 1 H
H12B 0.3281 0.8951 -0.0428 0.061 Uiso calc R 1 H
C13 0.48444(11) 0.9853(2) 0.13472(13) 0.0310(6) Uani d . 1 C
H13A 0.4666 1.0616 0.1433 0.037 Uiso calc R 1 H
H13B 0.4916 0.9294 0.1714 0.037 Uiso calc R 1 H
C14 0.60040(11) 0.8843(3) 0.14725(13) 0.0334(6) Uani d . 1 C
H14 0.5804 0.8110 0.1238 0.040 Uiso calc R 1 H
C15 0.65766(12) 0.8886(3) 0.13140(16) 0.0479(8) Uani d . 1 C
H15A 0.6825 0.9535 0.1566 0.058 Uiso calc R 1 H
H15B 0.6500 0.9080 0.0860 0.058 Uiso calc R 1 H
C16 0.68857(15) 0.7628(4) 0.14665(18) 0.0645(10) Uani d . 1 C
H16A 0.6653 0.6999 0.1181 0.077 Uiso calc R 1 H
H16B 0.7258 0.7678 0.1385 0.077 Uiso calc R 1 H
C17 0.69845(15) 0.7244(4) 0.21538(19) 0.0675(11) Uani d . 1 C
H17A 0.7262 0.7810 0.2438 0.081 Uiso calc R 1 H
H17B 0.7151 0.6414 0.2220 0.081 Uiso calc R 1 H
C18 0.64246(16) 0.7251(3) 0.23263(18) 0.0665(11) Uani d . 1 C
H18A 0.6510 0.7070 0.2783 0.080 Uiso calc R 1 H
H18B 0.6168 0.6604 0.2085 0.080 Uiso calc R 1 H
C19 0.61168(15) 0.8507(3) 0.21771(16) 0.0570(9) Uani d . 1 C
H19A 0.5750 0.8470 0.2271 0.068 Uiso calc R 1 H
H19B 0.6357 0.9145 0.2449 0.068 Uiso calc R 1 H
C20 0.57681(12) 1.1626(3) 0.15535(14) 0.0370(7) Uani d . 1 C
H20 0.5465 1.2232 0.1343 0.044 Uiso calc R 1 H
C21 0.57884(14) 1.1659(3) 0.22569(15) 0.0497(8) Uani d . 1 C
H21A 0.6101 1.1125 0.2507 0.060 Uiso calc R 1 H
H21B 0.5425 1.1337 0.2294 0.060 Uiso calc R 1 H
C22 0.58848(17) 1.2972(3) 0.25312(19) 0.0684(11) Uani d . 1 C
H22A 0.5546 1.3478 0.2320 0.082 Uiso calc R 1 H
H22B 0.5926 1.2944 0.2988 0.082 Uiso calc R 1 H
C23 0.64155(16) 1.3561(3) 0.24406(18) 0.0656(10) Uani d . 1 C
H23A 0.6760 1.3141 0.2714 0.079 Uiso calc R 1 H
H23B 0.6435 1.4426 0.2576 0.079 Uiso calc R 1 H
C24 0.64144(16) 1.3502(3) 0.17453(18) 0.0632(10) Uani d . 1 C
H24A 0.6784 1.3811 0.1718 0.076 Uiso calc R 1 H
H24B 0.6108 1.4037 0.1482 0.076 Uiso calc R 1 H
C25 0.63184(14) 1.2179(3) 0.14798(16) 0.0517(8) Uani d . 1 C
H25A 0.6293 1.2187 0.1026 0.062 Uiso calc R 1 H
H25B 0.6649 1.1665 0.1708 0.062 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
P2 Ru1 P2 5_675 . 180.0 n
P2 Ru1 P1 5_675 5_675 71.43(4) n
P2 Ru1 P1 . 5_675 108.57(4) n
P2 Ru1 P1 5_675 . 108.58(4) n
P2 Ru1 P1 . . 71.42(4) yes
P1 Ru1 P1 5_675 . 180.0 n
P2 Ru1 Cl1 5_675 5_675 86.35(3) n
P2 Ru1 Cl1 . 5_675 93.65(3) n
P1 Ru1 Cl1 5_675 5_675 86.09(3) n
P1 Ru1 Cl1 . 5_675 93.91(3) n
P2 Ru1 Cl1 5_675 . 93.65(3) n
P2 Ru1 Cl1 . . 86.35(3) n
P1 Ru1 Cl1 5_675 . 93.91(3) n
P1 Ru1 Cl1 . . 86.09(3) n
Cl1 Ru1 Cl1 5_675 . 180.0 n
C13 P1 C1 . . 102.87(13) ?
C13 P1 C7 . . 103.00(12) ?
C1 P1 C7 . . 110.32(12) ?
C13 P1 Ru1 . . 92.54(9) ?
C1 P1 Ru1 . . 119.19(9) ?
C7 P1 Ru1 . . 122.82(10) ?
C13 P2 C14 . . 105.09(12) ?
C13 P2 C20 . . 101.09(12) ?
C14 P2 C20 . . 111.25(13) ?
C13 P2 Ru1 . . 92.95(9) ?
C14 P2 Ru1 . . 116.11(9) ?
C20 P2 Ru1 . . 124.61(10) ?
C2 C1 C6 . . 110.2(2) ?
C2 C1 P1 . . 116.96(19) ?
C6 C1 P1 . . 114.7(2) ?
C2 C1 H1 . . 104.5 ?
C6 C1 H1 . . 104.5 ?
P1 C1 H1 . . 104.5 ?
C3 C2 C1 . . 110.6(3) ?
C3 C2 H2A . . 109.5 ?
C1 C2 H2A . . 109.5 ?
C3 C2 H2B . . 109.5 ?
C1 C2 H2B . . 109.5 ?
H2A C2 H2B . . 108.1 ?
C4 C3 C2 . . 111.3(3) ?
C4 C3 H3A . . 109.4 ?
C2 C3 H3A . . 109.4 ?
C4 C3 H3B . . 109.4 ?
C2 C3 H3B . . 109.4 ?
H3A C3 H3B . . 108.0 ?
C3 C4 C5 . . 111.2(3) ?
C3 C4 H4A . . 109.4 ?
C5 C4 H4A . . 109.4 ?
C3 C4 H4B . . 109.4 ?
C5 C4 H4B . . 109.4 ?
H4A C4 H4B . . 108.0 ?
C6 C5 C4 . . 112.4(3) ?
C6 C5 H5A . . 109.1 ?
C4 C5 H5A . . 109.1 ?
C6 C5 H5B . . 109.1 ?
C4 C5 H5B . . 109.1 ?
H5A C5 H5B . . 107.9 ?
C5 C6 C1 . . 111.2(3) ?
C5 C6 H6A . . 109.4 ?
C1 C6 H6A . . 109.4 ?
C5 C6 H6B . . 109.4 ?
C1 C6 H6B . . 109.4 ?
H6A C6 H6B . . 108.0 ?
C12 C7 C8 . . 110.2(2) ?
C12 C7 P1 . . 115.1(2) ?
C8 C7 P1 . . 116.3(2) ?
C12 C7 H7 . . 104.6 ?
C8 C7 H7 . . 104.6 ?
P1 C7 H7 . . 104.6 ?
C7 C8 C9 . . 110.9(3) ?
C7 C8 H8A . . 109.5 ?
C9 C8 H8A . . 109.5 ?
C7 C8 H8B . . 109.5 ?
C9 C8 H8B . . 109.5 ?
H8A C8 H8B . . 108.1 ?
C10 C9 C8 . . 111.7(3) ?
C10 C9 H9A . . 109.3 ?
C8 C9 H9A . . 109.3 ?
C10 C9 H9B . . 109.3 ?
C8 C9 H9B . . 109.3 ?
H9A C9 H9B . . 107.9 ?
C9 C10 C11 . . 111.5(3) ?
C9 C10 H10A . . 109.3 ?
C11 C10 H10A . . 109.3 ?
C9 C10 H10B . . 109.3 ?
C11 C10 H10B . . 109.3 ?
H10A C10 H10B . . 108.0 ?
C10 C11 C12 . . 112.0(3) ?
C10 C11 H11A . . 109.2 ?
C12 C11 H11A . . 109.2 ?
C10 C11 H11B . . 109.2 ?
C12 C11 H11B . . 109.2 ?
H11A C11 H11B . . 107.9 ?
C7 C12 C11 . . 110.7(3) ?
C7 C12 H12A . . 109.5 ?
C11 C12 H12A . . 109.5 ?
C7 C12 H12B . . 109.5 ?
C11 C12 H12B . . 109.5 ?
H12A C12 H12B . . 108.1 ?
P2 C13 P1 . . 97.10(13) y
P2 C13 H13A . . 112.3 ?
P1 C13 H13A . . 112.3 ?
P2 C13 H13B . . 112.3 ?
P1 C13 H13B . . 112.3 ?
H13A C13 H13B . . 109.9 ?
C19 C14 C15 . . 110.2(2) ?
C19 C14 P2 . . 119.50(19) ?
C15 C14 P2 . . 113.39(19) ?
C19 C14 H14 . . 103.9 ?
C15 C14 H14 . . 103.9 ?
P2 C14 H14 . . 103.9 ?
C14 C15 C16 . . 109.8(3) ?
C14 C15 H15A . . 109.7 ?
C16 C15 H15A . . 109.7 ?
C14 C15 H15B . . 109.7 ?
C16 C15 H15B . . 109.7 ?
H15A C15 H15B . . 108.2 ?
C17 C16 C15 . . 112.1(3) ?
C17 C16 H16A . . 109.2 ?
C15 C16 H16A . . 109.2 ?
C17 C16 H16B . . 109.2 ?
C15 C16 H16B . . 109.2 ?
H16A C16 H16B . . 107.9 ?
C16 C17 C18 . . 111.7(3) ?
C16 C17 H17A . . 109.3 ?
C18 C17 H17A . . 109.3 ?
C16 C17 H17B . . 109.3 ?
C18 C17 H17B . . 109.3 ?
H17A C17 H17B . . 107.9 ?
C17 C18 C19 . . 111.4(3) ?
C17 C18 H18A . . 109.3 ?
C19 C18 H18A . . 109.3 ?
C17 C18 H18B . . 109.3 ?
C19 C18 H18B . . 109.3 ?
H18A C18 H18B . . 108.0 ?
C14 C19 C18 . . 110.4(3) ?
C14 C19 H19A . . 109.6 ?
C18 C19 H19A . . 109.6 ?
C14 C19 H19B . . 109.6 ?
C18 C19 H19B . . 109.6 ?
H19A C19 H19B . . 108.1 ?
C25 C20 C21 . . 110.2(2) ?
C25 C20 P2 . . 116.8(2) ?
C21 C20 P2 . . 115.8(2) ?
C25 C20 H20 . . 104.1 ?
C21 C20 H20 . . 104.1 ?
P2 C20 H20 . . 104.1 ?
C20 C21 C22 . . 111.8(3) ?
C20 C21 H21A . . 109.3 ?
C22 C21 H21A . . 109.3 ?
C20 C21 H21B . . 109.3 ?
C22 C21 H21B . . 109.3 ?
H21A C21 H21B . . 107.9 ?
C23 C22 C21 . . 111.9(3) ?
C23 C22 H22A . . 109.2 ?
C21 C22 H22A . . 109.2 ?
C23 C22 H22B . . 109.2 ?
C21 C22 H22B . . 109.2 ?
H22A C22 H22B . . 107.9 ?
C22 C23 C24 . . 112.2(3) ?
C22 C23 H23A . . 109.2 ?
C24 C23 H23A . . 109.2 ?
C22 C23 H23B . . 109.2 ?
C24 C23 H23B . . 109.2 ?
H23A C23 H23B . . 107.9 ?
C23 C24 C25 . . 111.8(3) ?
C23 C24 H24A . . 109.3 ?
C25 C24 H24A . . 109.3 ?
C23 C24 H24B . . 109.3 ?
C25 C24 H24B . . 109.3 ?
H24A C24 H24B . . 107.9 ?
C20 C25 C24 . . 111.2(3) ?
C20 C25 H25A . . 109.4 ?
C24 C25 H25A . . 109.4 ?
C20 C25 H25B . . 109.4 ?
C24 C25 H25B . . 109.4 ?
H25A C25 H25B . . 108.0 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ru1 P2 5_675 2.3668(13) n
Ru1 P2 . 2.3669(12) yes
Ru1 P1 5_675 2.3775(9) n
Ru1 P1 . 2.3775(10) yes
Ru1 Cl1 5_675 2.4333(11) n
Ru1 Cl1 . 2.4334(11) yes
P1 C13 . 1.849(3) ?
P1 C1 . 1.855(3) ?
P1 C7 . 1.867(3) ?
P2 C13 . 1.846(3) ?
P2 C14 . 1.848(3) ?
P2 C20 . 1.855(3) ?
C1 C2 . 1.525(4) ?
C1 C6 . 1.526(4) ?
C1 H1 . 0.9800 ?
C2 C3 . 1.523(4) ?
C2 H2A . 0.9700 ?
C2 H2B . 0.9700 ?
C3 C4 . 1.510(5) ?
C3 H3A . 0.9700 ?
C3 H3B . 0.9700 ?
C4 C5 . 1.524(5) ?
C4 H4A . 0.9700 ?
C4 H4B . 0.9700 ?
C5 C6 . 1.512(4) ?
C5 H5A . 0.9700 ?
C5 H5B . 0.9700 ?
C6 H6A . 0.9700 ?
C6 H6B . 0.9700 ?
C7 C12 . 1.516(4) ?
C7 C8 . 1.522(4) ?
C7 H7 . 0.9800 ?
C8 C9 . 1.528(5) ?
C8 H8A . 0.9700 ?
C8 H8B . 0.9700 ?
C9 C10 . 1.499(5) ?
C9 H9A . 0.9700 ?
C9 H9B . 0.9700 ?
C10 C11 . 1.502(5) ?
C10 H10A . 0.9700 ?
C10 H10B . 0.9700 ?
C11 C12 . 1.536(4) ?
C11 H11A . 0.9700 ?
C11 H11B . 0.9700 ?
C12 H12A . 0.9700 ?
C12 H12B . 0.9700 ?
C13 H13A . 0.9700 ?
C13 H13B . 0.9700 ?
C14 C19 . 1.517(4) ?
C14 C15 . 1.525(4) ?
C14 H14 . 0.9800 ?
C15 C16 . 1.528(4) ?
C15 H15A . 0.9700 ?
C15 H15B . 0.9700 ?
C16 C17 . 1.498(5) ?
C16 H16A . 0.9700 ?
C16 H16B . 0.9700 ?
C17 C18 . 1.510(5) ?
C17 H17A . 0.9700 ?
C17 H17B . 0.9700 ?
C18 C19 . 1.524(4) ?
C18 H18A . 0.9700 ?
C18 H18B . 0.9700 ?
C19 H19A . 0.9700 ?
C19 H19B . 0.9700 ?
C20 C25 . 1.507(4) ?
C20 C21 . 1.518(4) ?
C20 H20 . 0.9800 ?
C21 C22 . 1.519(4) ?
C21 H21A . 0.9700 ?
C21 H21B . 0.9700 ?
C22 C23 . 1.495(5) ?
C22 H22A . 0.9700 ?
C22 H22B . 0.9700 ?
C23 C24 . 1.515(5) ?
C23 H23A . 0.9700 ?
C23 H23B . 0.9700 ?
C24 C25 . 1.523(4) ?
C24 H24A . 0.9700 ?
C24 H24B . 0.9700 ?
C25 H25A . 0.9700 ?
C25 H25B . 0.9700 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
P2 Ru1 P1 C13 5_675 -163.49(8)
P2 Ru1 P1 C13 . 16.51(8)
Cl1 Ru1 P1 C13 5_675 109.05(9)
Cl1 Ru1 P1 C13 . -70.95(9)
P2 Ru1 P1 C1 5_675 90.25(11)
P2 Ru1 P1 C1 . -89.75(11)
Cl1 Ru1 P1 C1 5_675 2.78(11)
Cl1 Ru1 P1 C1 . -177.21(11)
P2 Ru1 P1 C7 5_675 -56.24(11)
P2 Ru1 P1 C7 . 123.76(11)
Cl1 Ru1 P1 C7 5_675 -143.71(11)
Cl1 Ru1 P1 C7 . 36.30(11)
P1 Ru1 P2 C13 5_675 163.46(8)
P1 Ru1 P2 C13 . -16.55(8)
Cl1 Ru1 P2 C13 5_675 -109.45(9)
Cl1 Ru1 P2 C13 . 70.55(8)
P1 Ru1 P2 C14 5_675 -88.15(10)
P1 Ru1 P2 C14 . 91.85(10)
Cl1 Ru1 P2 C14 5_675 -1.05(10)
Cl1 Ru1 P2 C14 . 178.94(10)
P1 Ru1 P2 C20 5_675 57.82(11)
P1 Ru1 P2 C20 . -122.18(11)
Cl1 Ru1 P2 C20 5_675 144.91(11)
Cl1 Ru1 P2 C20 . -35.09(11)
C13 P1 C1 C2 . 56.4(2)
C7 P1 C1 C2 . -52.9(3)
Ru1 P1 C1 C2 . 156.78(19)
C13 P1 C1 C6 . -172.3(2)
C7 P1 C1 C6 . 78.4(2)
Ru1 P1 C1 C6 . -71.9(2)
C6 C1 C2 C3 . 57.6(4)
P1 C1 C2 C3 . -169.0(2)
C1 C2 C3 C4 . -57.5(4)
C2 C3 C4 C5 . 54.8(4)
C3 C4 C5 C6 . -53.4(4)
C4 C5 C6 C1 . 54.2(4)
C2 C1 C6 C5 . -56.1(3)
P1 C1 C6 C5 . 169.4(2)
C13 P1 C7 C12 . -168.2(2)
C1 P1 C7 C12 . -59.0(3)
Ru1 P1 C7 C12 . 90.1(2)
C13 P1 C7 C8 . -37.2(3)
C1 P1 C7 C8 . 72.0(2)
Ru1 P1 C7 C8 . -138.9(2)
C12 C7 C8 C9 . -56.9(4)
P1 C7 C8 C9 . 169.7(2)
C7 C8 C9 C10 . 56.1(5)
C8 C9 C10 C11 . -54.5(5)
C9 C10 C11 C12 . 54.2(5)
C8 C7 C12 C11 . 56.4(4)
P1 C7 C12 C11 . -169.6(2)
C10 C11 C12 C7 . -55.5(4)
C14 P2 C13 P1 . -97.58(14)
C20 P2 C13 P1 . 146.61(12)
Ru1 P2 C13 P1 . 20.48(10)
C1 P1 C13 P2 . 100.35(13)
C7 P1 C13 P2 . -144.92(12)
Ru1 P1 C13 P2 . -20.37(10)
C13 P2 C14 C19 . -49.6(3)
C20 P2 C14 C19 . 59.0(3)
Ru1 P2 C14 C19 . -150.7(2)
C13 P2 C14 C15 . 177.7(2)
C20 P2 C14 C15 . -73.7(2)
Ru1 P2 C14 C15 . 76.7(2)
C19 C14 C15 C16 . 57.9(4)
P2 C14 C15 C16 . -165.2(2)
C14 C15 C16 C17 . -56.0(4)
C15 C16 C17 C18 . 54.2(4)
C16 C17 C18 C19 . -54.1(4)
C15 C14 C19 C18 . -58.4(4)
P2 C14 C19 C18 . 167.6(2)
C17 C18 C19 C14 . 56.2(4)
C13 P2 C20 C25 . -179.9(2)
C14 P2 C20 C25 . 69.0(3)
Ru1 P2 C20 C25 . -78.4(3)
C13 P2 C20 C21 . 47.8(2)
C14 P2 C20 C21 . -63.4(3)
Ru1 P2 C20 C21 . 149.24(19)
C25 C20 C21 C22 . 56.3(4)
P2 C20 C21 C22 . -168.3(2)
C20 C21 C22 C23 . -54.4(4)
C21 C22 C23 C24 . 52.2(4)
C22 C23 C24 C25 . -52.7(4)
C21 C20 C25 C24 . -56.5(4)
P2 C20 C25 C24 . 168.6(2)
C23 C24 C25 C20 . 55.0(4)
