#------------------------------------------------------------------------------
#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/59/2205906.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2205906
loop_
_publ_author_name
'Ming-Xing Yang'
'Shen Lin'
_publ_section_title
;Bis(dimethylformamide-2κO)dipyridine-1κN,3κN-bis(μ-2'-salicylbenzohydrazidato)-1κ³O,N,O':2κ²N,O'';2κ²N,O'':3κ³O,N,O'-trinickel(II)
 dimethylformamide disolvate hemihydrate
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1095
_journal_page_last               m1096
_journal_paper_doi               10.1107/S1600536805013875
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac
'[Ni3 (C30 H20 N4 O6)2 (C5 H5 N)2 (C2 H6 N O)2], 2C3 H7 N O, 0.5H2 O'
_chemical_formula_moiety         'C44 H42 N8 Ni3 O8, 2C3 H7 N O, 0.5H2 O'
_chemical_formula_sum            'C50 H57 N10 Ni3 O10.5'
_chemical_formula_weight         1142.19
_chemical_name_systematic
'Bis(dimethylformamide)-2κ²O-dipyridine-1\kN,3\kN-bis(μ-2'-salicylbenzohydrazidato)-1κ⁴O,N,N',O':2κ²N,O'';2κ²N,O'':3κ⁴O,N,N',O'-trinickel(II) dimethylformamide disolvate hemihydrate'
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 115.389(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   29.4926(15)
_cell_length_b                   10.1678(3)
_cell_length_c                   19.7293(3)
_cell_measurement_reflns_used    5983
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      1.53
_cell_volume                     5344.9(3)
_computing_cell_refinement       RAPID-AUTO
_computing_data_collection
'TEXSAN (Molecular Structure Corporation, 1999)'
_computing_data_reduction        'CrystalStucture (Rigaku/MSC, 2002)'
_computing_molecular_graphics    'SHELXTL/PC (Sheldrick, 1998)'
_computing_publication_material  SHELXTL/PC
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.974
_diffrn_measured_fraction_theta_max 0.974
_diffrn_measurement_device_type  'Rigaku 18KW Weissenberg IP'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0000
_diffrn_reflns_av_sigmaI/netI    0.0528
_diffrn_reflns_limit_h_max       38
_diffrn_reflns_limit_h_min       0
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       0
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            5983
_diffrn_reflns_theta_full        27.48
_diffrn_reflns_theta_max         27.48
_diffrn_reflns_theta_min         2.14
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.112
_exptl_absorpt_correction_T_max  0.66
_exptl_absorpt_correction_T_min  0.5167
_exptl_absorpt_correction_type   psi-scan
_exptl_absorpt_process_details   '(North et al., 1968)'
_exptl_crystal_colour            red
_exptl_crystal_density_diffrn    1.419
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2380
_exptl_crystal_size_max          0.56
_exptl_crystal_size_mid          0.46
_exptl_crystal_size_min          0.38
_refine_diff_density_max         0.572
_refine_diff_density_min         -0.370
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.981
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     334
_refine_ls_number_reflns         5983
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      0.981
_refine_ls_R_factor_all          0.0729
_refine_ls_R_factor_gt           0.0471
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.08P)²] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1245
_refine_ls_wR_factor_ref         0.1371
_reflns_number_gt                4085
_reflns_number_total             5983
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            cv6487.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C50 H57 N10 Ni3 O10.50'
_cod_database_code               2205906
_cod_database_fobs_code          2205906
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Ni1 0.184347(14) 0.45860(4) 0.14812(2) 0.04812(14) Uani d . 1 Ni
Ni2 0.2500 0.2500 0.0000 0.04125(15) Uani d S 1 Ni
O1 0.23490(8) 0.5400(2) 0.22655(12) 0.0630(6) Uani d . 1 O
O2 0.29690(7) 0.3229(2) 0.10137(10) 0.0486(5) Uani d . 1 O
O3 0.13322(7) 0.3793(2) 0.06545(11) 0.0520(5) Uani d . 1 O
O4 0.25179(8) 0.0593(2) 0.04667(12) 0.0582(5) Uani d . 1 O
N1 0.22496(9) 0.3890(2) 0.10772(12) 0.0439(5) Uani d . 1 N
N2 0.19907(9) 0.3104(2) 0.04246(11) 0.0441(5) Uani d . 1 N
N3 0.13785(10) 0.5107(3) 0.18978(15) 0.0586(7) Uani d . 1 N
N4 0.28364(12) -0.1367(3) 0.09696(17) 0.0701(8) Uani d . 1 N
C1 0.28326(12) 0.5341(3) 0.24377(17) 0.0517(7) Uani d . 1 C
C2 0.30473(11) 0.4643(3) 0.20247(15) 0.0453(6) Uani d . 1 C
C3 0.35732(12) 0.4685(3) 0.22726(17) 0.0532(7) Uani d . 1 C
H3A 0.3716 0.4214 0.2009 0.064 Uiso calc R 1 H
C4 0.38792(13) 0.5393(3) 0.28875(19) 0.0629(8) Uani d . 1 C
H4A 0.4224 0.5420 0.3032 0.076 Uiso calc R 1 H
C5 0.36686(14) 0.6076(4) 0.32950(18) 0.0679(9) Uani d . 1 C
H5A 0.3875 0.6550 0.3718 0.081 Uiso calc R 1 H
C6 0.31588(13) 0.6054(3) 0.30768(18) 0.0640(9) Uani d . 1 C
H6A 0.3026 0.6518 0.3356 0.077 Uiso calc R 1 H
C7 0.27450(10) 0.3875(3) 0.13377(14) 0.0429(6) Uani d . 1 C
C8 0.15126(10) 0.3097(3) 0.02634(14) 0.0439(6) Uani d . 1 C
C9 0.11458(11) 0.2254(3) -0.03405(15) 0.0462(6) Uani d . 1 C
C10 0.12635(12) 0.0973(3) -0.04407(18) 0.0562(7) Uani d . 1 C
H10A 0.1584 0.0646 -0.0154 0.067 Uiso calc R 1 H
C11 0.09005(15) 0.0171(4) -0.0974(2) 0.0712(10) Uani d . 1 C
H11A 0.0980 -0.0694 -0.1032 0.085 Uiso calc R 1 H
C12 0.04265(15) 0.0641(4) -0.1415(2) 0.0722(10) Uani d . 1 C
H12A 0.0188 0.0102 -0.1772 0.087 Uiso calc R 1 H
C13 0.03090(13) 0.1930(4) -0.13194(19) 0.0736(10) Uani d . 1 C
H13A -0.0009 0.2259 -0.1618 0.088 Uiso calc R 1 H
C14 0.06609(13) 0.2726(3) -0.07847(18) 0.0611(8) Uani d . 1 C
H14A 0.0576 0.3582 -0.0718 0.073 Uiso calc R 1 H
C15 0.09140(15) 0.4619(5) 0.1626(3) 0.0901(14) Uani d . 1 C
H15A 0.0807 0.4098 0.1198 0.108 Uiso calc R 1 H
C16 0.05754(17) 0.4841(5) 0.1942(3) 0.1060(17) Uani d . 1 C
H16A 0.0257 0.4469 0.1737 0.127 Uiso calc R 1 H
C17 0.07332(16) 0.5629(4) 0.2568(3) 0.0889(13) Uani d . 1 C
H17A 0.0523 0.5783 0.2801 0.107 Uiso calc R 1 H
C18 0.11952(14) 0.6178(4) 0.2842(2) 0.0724(10) Uani d . 1 C
H18A 0.1301 0.6737 0.3255 0.087 Uiso calc R 1 H
C19 0.15118(13) 0.5898(4) 0.25016(18) 0.0629(8) Uani d . 1 C
H19A 0.1830 0.6274 0.2700 0.075 Uiso calc R 1 H
C20 0.28434(14) -0.0232(3) 0.06481(18) 0.0600(8) Uani d . 1 C
H20A 0.3121 -0.0055 0.0554 0.072 Uiso calc R 1 H
C21 0.24322(18) -0.1710(4) 0.1162(3) 0.0932(13) Uani d . 1 C
H21A 0.2179 -0.1039 0.0983 0.140 Uiso calc R 1 H
H21B 0.2559 -0.1784 0.1697 0.140 Uiso calc R 1 H
H21C 0.2289 -0.2535 0.0933 0.140 Uiso calc R 1 H
C22 0.3250(2) -0.2287(5) 0.1202(3) 0.128(2) Uani d . 1 C
H22A 0.3498 -0.1966 0.1048 0.191 Uiso calc R 1 H
H22B 0.3129 -0.3127 0.0973 0.191 Uiso calc R 1 H
H22C 0.3397 -0.2379 0.1737 0.191 Uiso calc R 1 H
N5 0.0625(2) 0.2515(4) 0.5021(3) 0.1091(13) Uani d . 1 N
O5 0.06184(19) 0.3711(5) 0.4041(3) 0.1551(17) Uani d . 1 O
C23 0.0820(3) 0.3310(6) 0.4681(4) 0.127(2) Uani d . 1 C
H23A 0.1148 0.3590 0.4966 0.153 Uiso calc R 1 H
C24 0.0116(3) 0.2040(9) 0.4621(5) 0.182(3) Uani d . 1 C
H24A -0.0039 0.2456 0.4139 0.274 Uiso calc R 1 H
H24B -0.0071 0.2242 0.4904 0.274 Uiso calc R 1 H
H24C 0.0121 0.1105 0.4557 0.274 Uiso calc R 1 H
C25 0.0927(3) 0.2040(8) 0.5748(3) 0.179(3) Uani d . 1 C
H25A 0.1251 0.2450 0.5935 0.269 Uiso calc R 1 H
H25B 0.0964 0.1105 0.5729 0.269 Uiso calc R 1 H
H25C 0.0771 0.2243 0.6074 0.269 Uiso calc R 1 H
O6 0.0000 0.2198(13) 0.2500 0.135(4) Uiso d SP 0.50 O
HO6 0.0036 0.2643 0.2859 0.16 Uiso d PR 0.50 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ni Ni 0.3393 1.1124 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O1 Ni1 N1 . . 95.44(10)
O1 Ni1 O3 . . 177.84(10)
N1 Ni1 O3 . . 83.53(9)
O1 Ni1 N3 . . 89.20(11)
N1 Ni1 N3 . . 172.94(11)
O3 Ni1 N3 . . 92.01(10)
O2 Ni2 O2 7 . 180.00(17)
O2 Ni2 N2 7 7 78.54(8)
O2 Ni2 N2 . 7 101.46(8)
O2 Ni2 N2 7 . 101.46(8)
O2 Ni2 N2 . . 78.54(8)
N2 Ni2 N2 7 . 180.00(8)
O2 Ni2 O4 7 . 88.48(8)
O2 Ni2 O4 . . 91.52(8)
N2 Ni2 O4 7 . 90.95(8)
N2 Ni2 O4 . . 89.05(8)
O2 Ni2 O4 7 7 91.52(8)
O2 Ni2 O4 . 7 88.48(8)
N2 Ni2 O4 7 7 89.05(8)
N2 Ni2 O4 . 7 90.95(8)
O4 Ni2 O4 . 7 180.00(12)
C1 O1 Ni1 . . 126.79(19)
C7 O2 Ni2 . . 113.65(17)
C8 O3 Ni1 . . 111.52(17)
C20 O4 Ni2 . . 128.9(2)
C7 N1 N2 . . 114.7(2)
C7 N1 Ni1 . . 130.59(18)
N2 N1 Ni1 . . 114.21(17)
C8 N2 N1 . . 109.1(2)
C8 N2 Ni2 . . 141.56(18)
N1 N2 Ni2 . . 109.03(16)
C15 N3 C19 . . 115.9(3)
C15 N3 Ni1 . . 121.1(2)
C19 N3 Ni1 . . 122.9(2)
C20 N4 C21 . . 121.5(3)
C20 N4 C22 . . 122.1(3)
C21 N4 C22 . . 116.2(3)
O1 C1 C6 . . 117.0(3)
O1 C1 C2 . . 125.1(3)
C6 C1 C2 . . 117.9(3)
C3 C2 C1 . . 118.7(3)
C3 C2 C7 . . 118.2(2)
C1 C2 C7 . . 123.1(3)
C4 C3 C2 . . 122.2(3)
C4 C3 H3A . . 118.9
C2 C3 H3A . . 118.9
C3 C4 C5 . . 119.1(3)
C3 C4 H4A . . 120.4
C5 C4 H4A . . 120.4
C6 C5 C4 . . 120.6(3)
C6 C5 H5A . . 119.7
C4 C5 H5A . . 119.7
C5 C6 C1 . . 121.4(3)
C5 C6 H6A . . 119.3
C1 C6 H6A . . 119.3
O2 C7 N1 . . 122.1(2)
O2 C7 C2 . . 119.3(2)
N1 C7 C2 . . 118.6(2)
N2 C8 O3 . . 121.4(2)
N2 C8 C9 . . 122.4(2)
O3 C8 C9 . . 116.2(2)
C10 C9 C14 . . 118.9(3)
C10 C9 C8 . . 121.0(3)
C14 C9 C8 . . 119.9(3)
C9 C10 C11 . . 119.9(3)
C9 C10 H10A . . 120.0
C11 C10 H10A . . 120.0
C12 C11 C10 . . 121.1(4)
C12 C11 H11A . . 119.5
C10 C11 H11A . . 119.5
C11 C12 C13 . . 119.1(3)
C11 C12 H12A . . 120.4
C13 C12 H12A . . 120.4
C14 C13 C12 . . 120.5(3)
C14 C13 H13A . . 119.8
C12 C13 H13A . . 119.8
C13 C14 C9 . . 120.5(3)
C13 C14 H14A . . 119.8
C9 C14 H14A . . 119.8
N3 C15 C16 . . 124.4(4)
N3 C15 H15A . . 117.8
C16 C15 H15A . . 117.8
C17 C16 C15 . . 117.5(4)
C17 C16 H16A . . 121.3
C15 C16 H16A . . 121.3
C18 C17 C16 . . 119.7(4)
C18 C17 H17A . . 120.1
C16 C17 H17A . . 120.1
C17 C18 C19 . . 119.4(3)
C17 C18 H18A . . 120.3
C19 C18 H18A . . 120.3
N3 C19 C18 . . 123.1(3)
N3 C19 H19A . . 118.5
C18 C19 H19A . . 118.5
O4 C20 N4 . . 125.1(3)
O4 C20 H20A . . 117.5
N4 C20 H20A . . 117.5
N4 C21 H21A . . 109.5
N4 C21 H21B . . 109.5
H21A C21 H21B . . 109.5
N4 C21 H21C . . 109.5
H21A C21 H21C . . 109.5
H21B C21 H21C . . 109.5
N4 C22 H22A . . 109.5
N4 C22 H22B . . 109.5
H22A C22 H22B . . 109.5
N4 C22 H22C . . 109.5
H22A C22 H22C . . 109.5
H22B C22 H22C . . 109.5
C23 N5 C25 . . 120.0(7)
C23 N5 C24 . . 120.1(5)
C25 N5 C24 . . 119.6(6)
O5 C23 N5 . . 127.2(7)
O5 C23 H23A . . 116.4
N5 C23 H23A . . 116.4
N5 C24 H24A . . 109.5
N5 C24 H24B . . 109.5
H24A C24 H24B . . 109.5
N5 C24 H24C . . 109.5
H24A C24 H24C . . 109.5
H24B C24 H24C . . 109.5
N5 C25 H25A . . 109.5
N5 C25 H25B . . 109.5
H25A C25 H25B . . 109.5
N5 C25 H25C . . 109.5
H25A C25 H25C . . 109.5
H25B C25 H25C . . 109.5
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Ni1 O1 . 1.823(2)
Ni1 N1 . 1.841(2)
Ni1 O3 . 1.8642(19)
Ni1 N3 . 1.950(3)
Ni2 O2 7 2.0226(18)
Ni2 O2 . 2.0226(18)
Ni2 N2 7 2.101(2)
Ni2 N2 . 2.101(2)
Ni2 O4 . 2.137(2)
Ni2 O4 7 2.137(2)
O1 C1 . 1.318(4)
O2 C7 . 1.280(3)
O3 C8 . 1.316(3)
O4 C20 . 1.208(4)
N1 C7 . 1.325(4)
N1 N2 . 1.427(3)
N2 C8 . 1.306(3)
N3 C15 . 1.334(5)
N3 C19 . 1.349(4)
N4 C20 . 1.321(4)
N4 C21 . 1.440(5)
N4 C22 . 1.447(5)
C1 C6 . 1.414(4)
C1 C2 . 1.418(4)
C2 C3 . 1.413(4)
C2 C7 . 1.485(4)
C3 C4 . 1.366(4)
C3 H3A . 0.9300
C4 C5 . 1.393(5)
C4 H4A . 0.9300
C5 C6 . 1.375(5)
C5 H5A . 0.9300
C6 H6A . 0.9300
C8 C9 . 1.490(4)
C9 C10 . 1.384(4)
C9 C14 . 1.403(4)
C10 C11 . 1.397(5)
C10 H10A . 0.9300
C11 C12 . 1.377(6)
C11 H11A . 0.9300
C12 C13 . 1.389(5)
C12 H12A . 0.9300
C13 C14 . 1.381(5)
C13 H13A . 0.9300
C14 H14A . 0.9300
C15 C16 . 1.404(5)
C15 H15A . 0.9300
C16 C17 . 1.374(5)
C16 H16A . 0.9300
C17 C18 . 1.352(5)
C17 H17A . 0.9300
C18 C19 . 1.394(5)
C18 H18A . 0.9300
C19 H19A . 0.9300
C20 H20A . 0.9300
C21 H21A . 0.9600
C21 H21B . 0.9600
C21 H21C . 0.9600
C22 H22A . 0.9600
C22 H22B . 0.9600
C22 H22C . 0.9600
N5 C23 . 1.328(7)
N5 C25 . 1.410(7)
N5 C24 . 1.447(8)
O5 C23 . 1.213(6)
C23 H23A . 0.9300
C24 H24A . 0.9600
C24 H24B . 0.9600
C24 H24C . 0.9600
C25 H25A . 0.9600
C25 H25B . 0.9600
C25 H25C . 0.9600
O6 HO6 . 0.81
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
N1 Ni1 O1 C1 . -3.8(3)
N3 Ni1 O1 C1 . 170.9(3)
N2 Ni2 O2 C7 7 168.53(18)
N2 Ni2 O2 C7 . -11.47(18)
O4 Ni2 O2 C7 . -100.18(19)
O4 Ni2 O2 C7 7 79.82(19)
N1 Ni1 O3 C8 . 4.85(18)
N3 Ni1 O3 C8 . -169.67(19)
O2 Ni2 O4 C20 7 103.0(3)
O2 Ni2 O4 C20 . -77.0(3)
N2 Ni2 O4 C20 7 24.5(3)
N2 Ni2 O4 C20 . -155.5(3)
O1 Ni1 N1 C7 . 7.1(3)
O3 Ni1 N1 C7 . -174.8(3)
O1 Ni1 N1 N2 . 178.48(17)
O3 Ni1 N1 N2 . -3.43(17)
C7 N1 N2 C8 . 174.1(2)
Ni1 N1 N2 C8 . 1.3(3)
C7 N1 N2 Ni2 . -11.0(3)
Ni1 N1 N2 Ni2 . 176.24(10)
O2 Ni2 N2 C8 7 4.0(3)
O2 Ni2 N2 C8 . -176.0(3)
O4 Ni2 N2 C8 . -84.3(3)
O4 Ni2 N2 C8 7 95.7(3)
O2 Ni2 N2 N1 7 -168.30(15)
O2 Ni2 N2 N1 . 11.70(15)
O4 Ni2 N2 N1 . 103.44(16)
O4 Ni2 N2 N1 7 -76.56(16)
O1 Ni1 N3 C15 . -169.5(3)
O3 Ni1 N3 C15 . 12.3(3)
O1 Ni1 N3 C19 . 5.9(3)
O3 Ni1 N3 C19 . -172.3(3)
Ni1 O1 C1 C6 . -179.8(2)
Ni1 O1 C1 C2 . 1.5(4)
O1 C1 C2 C3 . 179.1(3)
C6 C1 C2 C3 . 0.5(4)
O1 C1 C2 C7 . -0.4(5)
C6 C1 C2 C7 . -179.1(3)
C1 C2 C3 C4 . -1.2(4)
C7 C2 C3 C4 . 178.3(3)
C2 C3 C4 C5 . 1.4(5)
C3 C4 C5 C6 . -0.9(5)
C4 C5 C6 C1 . 0.2(6)
O1 C1 C6 C5 . -178.8(3)
C2 C1 C6 C5 . 0.0(5)
Ni2 O2 C7 N1 . 9.2(3)
Ni2 O2 C7 C2 . -170.25(18)
N2 N1 C7 O2 . 1.7(4)
Ni1 N1 C7 O2 . 173.01(19)
N2 N1 C7 C2 . -178.8(2)
Ni1 N1 C7 C2 . -7.5(4)
C3 C2 C7 O2 . 3.2(4)
C1 C2 C7 O2 . -177.3(3)
C3 C2 C7 N1 . -176.3(3)
C1 C2 C7 N1 . 3.3(4)
N1 N2 C8 O3 . 3.1(3)
Ni2 N2 C8 O3 . -169.2(2)
N1 N2 C8 C9 . -173.5(2)
Ni2 N2 C8 C9 . 14.2(5)
Ni1 O3 C8 N2 . -5.9(3)
Ni1 O3 C8 C9 . 170.87(18)
N2 C8 C9 C10 . 40.8(4)
O3 C8 C9 C10 . -135.8(3)
N2 C8 C9 C14 . -143.5(3)
O3 C8 C9 C14 . 39.8(4)
C14 C9 C10 C11 . -0.5(4)
C8 C9 C10 C11 . 175.3(3)
C9 C10 C11 C12 . 1.2(5)
C10 C11 C12 C13 . -0.6(6)
C11 C12 C13 C14 . -0.6(6)
C12 C13 C14 C9 . 1.3(5)
C10 C9 C14 C13 . -0.8(5)
C8 C9 C14 C13 . -176.5(3)
C19 N3 C15 C16 . -2.4(7)
Ni1 N3 C15 C16 . 173.3(4)
N3 C15 C16 C17 . 0.9(8)
C15 C16 C17 C18 . 1.5(8)
C16 C17 C18 C19 . -2.3(7)
C15 N3 C19 C18 . 1.6(6)
Ni1 N3 C19 C18 . -174.1(3)
C17 C18 C19 N3 . 0.7(6)
Ni2 O4 C20 N4 . 176.4(2)
C21 N4 C20 O4 . -2.3(6)
C22 N4 C20 O4 . -177.3(4)
C25 N5 C23 O5 . 173.9(6)
C24 N5 C23 O5 . -0.5(10)
