#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/59/2205924.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2205924
loop_
_publ_author_name
'Zhu, Li-Hong'
'Zeng, Ming-Hua'
'Ng, Seik Weng'
_publ_section_title
;
 Bis(quinolin-8-olato-κ²N,O)lead(II)
;
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1082
_journal_page_last               m1084
_journal_paper_doi               10.1107/S1600536805011852
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          '[Pb (C9 H6 N O)2]'
_chemical_formula_moiety         'Pb 2+ , 2C9 H6 N O -'
_chemical_formula_sum            'C18 H12 N2 O2 Pb'
_chemical_formula_weight         495.59
_chemical_name_systematic
;
Bis(8-hydroxyquinolinato-κ²N,O) lead(II)
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 126.0760(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            16
_cell_length_a                   35.937(2)
_cell_length_b                   8.3365(4)
_cell_length_c                   25.4320(10)
_cell_measurement_reflns_used    4994
_cell_measurement_temperature    295(2)
_cell_measurement_theta_max      27.4
_cell_measurement_theta_min      2.5
_cell_volume                     6158.1(5)
_computing_cell_refinement       'SAINT (Bruker, 2002)'
_computing_data_collection       'SMART (Bruker, 2002)'
_computing_data_reduction        SAINT
_computing_molecular_graphics
'ORTEPIII (Burnett & Johnson, 1996) and ORTEPIII for Windows (Farrugia, 1997)'
_computing_publication_material  SHELXL97
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      295(2)
_diffrn_measured_fraction_theta_full 0.98
_diffrn_measured_fraction_theta_max 0.98
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.028
_diffrn_reflns_av_sigmaI/netI    0.038
_diffrn_reflns_limit_h_max       46
_diffrn_reflns_limit_h_min       -41
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       31
_diffrn_reflns_limit_l_min       -32
_diffrn_reflns_number            20725
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         1.4
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    10.969
_exptl_absorpt_correction_T_max  0.193
_exptl_absorpt_correction_T_min  0.077
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2002)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    2.138
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       column
_exptl_crystal_F_000             3712
_exptl_crystal_size_max          0.18
_exptl_crystal_size_mid          0.17
_exptl_crystal_size_min          0.15
_refine_diff_density_max         1.07
_refine_diff_density_min         -1.12
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.00
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         6956
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.00
_refine_ls_R_factor_all          0.051
_refine_ls_R_factor_gt           0.030
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.001
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0333P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.065
_refine_ls_wR_factor_ref         0.075
_reflns_number_gt                4910
_reflns_number_total             6956
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            dn6216.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2205924
_cod_database_fobs_code          2205924
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'x, -y, z+1/2'
'x+1/2, y+1/2, z'
'x+1/2, -y+1/2, z+1/2'
'-x, -y, -z'
'-x, y, -z-1/2'
'-x+1/2, -y+1/2, -z'
'-x+1/2, y+1/2, -z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
Pb1 0.231838(7) 0.50370(2) 0.489411(8) 0.03595(7) Uani d . 1 Pb
Pb2 0.002870(5) 0.25041(2) 0.502647(7) 0.03364(7) Uani d . 1 Pb
O1 0.20490(10) 0.7784(3) 0.4769(2) 0.0450(10) Uani d . 1 O
O2 0.21010(10) 0.2648(3) 0.4259(2) 0.0460(10) Uani d . 1 O
O3 0.00930(10) 0.0165(3) 0.5623(2) 0.0410(10) Uani d . 1 O
O4 0.04400(10) 0.4799(3) 0.5029(2) 0.0450(10) Uani d . 1 O
N1 0.1452(2) 0.5296(4) 0.4204(2) 0.0370(10) Uani d . 1 N
N2 0.22020(10) 0.5482(5) 0.3842(2) 0.0390(10) Uani d . 1 N
N3 0.04570(10) 0.3040(4) 0.6206(2) 0.0330(10) Uani d . 1 N
N4 0.08500(10) 0.1902(4) 0.5504(2) 0.0370(10) Uani d . 1 N
C1 0.1165(2) 0.4073(6) 0.3925(3) 0.051(2) Uani d . 1 C
C2 0.0687(2) 0.4261(8) 0.3615(3) 0.067(2) Uani d . 1 C
C3 0.0515(2) 0.5730(8) 0.3599(3) 0.067(2) Uani d . 1 C
C4 0.0816(2) 0.7037(6) 0.3901(3) 0.0490(10) Uani d . 1 C
C5 0.0663(2) 0.8559(7) 0.3928(3) 0.069(2) Uani d . 1 C
C6 0.0976(3) 0.9764(6) 0.4249(3) 0.061(2) Uani d . 1 C
C7 0.1445(2) 0.9525(6) 0.4535(3) 0.049(2) Uani d . 1 C
C8 0.1612(2) 0.8055(5) 0.4510(2) 0.0390(10) Uani d . 1 C
C9 0.1286(2) 0.6775(6) 0.4195(2) 0.0370(10) Uani d . 1 C
C10 0.2257(2) 0.6878(6) 0.3645(3) 0.054(2) Uani d . 1 C
C11 0.2173(2) 0.7050(7) 0.3029(3) 0.065(2) Uani d . 1 C
C12 0.2027(2) 0.5777(8) 0.2625(3) 0.064(2) Uani d . 1 C
C13 0.1960(2) 0.4308(7) 0.2820(3) 0.054(2) Uani d . 1 C
C14 0.1795(2) 0.2975(8) 0.2408(3) 0.074(2) Uani d . 1 C
C15 0.1731(2) 0.1567(8) 0.2630(3) 0.080(2) Uani d . 1 C
C16 0.1829(2) 0.1433(6) 0.3252(3) 0.061(2) Uani d . 1 C
C17 0.1998(2) 0.2731(6) 0.3675(2) 0.0410(10) Uani d . 1 C
C18 0.2050(2) 0.4186(6) 0.3434(2) 0.0380(10) Uani d . 1 C
C19 0.0629(2) 0.4435(6) 0.6490(2) 0.0420(10) Uani d . 1 C
C20 0.0866(2) 0.4699(6) 0.7152(3) 0.052(2) Uani d . 1 C
C21 0.0928(2) 0.3424(7) 0.7533(2) 0.057(2) Uani d . 1 C
C22 0.0744(2) 0.1887(6) 0.7259(2) 0.0440(10) Uani d . 1 C
C23 0.0777(2) 0.0557(7) 0.7621(3) 0.065(2) Uani d . 1 C
C24 0.0590(2) -0.0830(8) 0.7309(3) 0.068(2) Uani d . 1 C
C25 0.0362(2) -0.1030(6) 0.6639(3) 0.053(2) Uani d . 1 C
C26 0.0317(2) 0.0262(5) 0.6255(3) 0.0370(10) Uani d . 1 C
C27 0.0513(2) 0.1743(5) 0.6583(2) 0.0340(10) Uani d . 1 C
C28 0.1054(2) 0.0505(6) 0.5748(3) 0.0480(10) Uani d . 1 C
C29 0.1524(2) 0.0263(6) 0.6074(3) 0.057(2) Uani d . 1 C
C30 0.1792(2) 0.1538(7) 0.6147(3) 0.056(2) Uani d . 1 C
C31 0.1595(2) 0.3048(6) 0.5895(2) 0.0400(10) Uani d . 1 C
C32 0.1844(2) 0.4418(7) 0.5952(3) 0.055(2) Uani d . 1 C
C33 0.1623(2) 0.5842(7) 0.5710(3) 0.053(2) Uani d . 1 C
C34 0.1153(2) 0.5998(6) 0.5401(2) 0.0460(10) Uani d . 1 C
C35 0.0881(2) 0.4711(5) 0.5315(2) 0.0380(10) Uani d . 1 C
C36 0.1112(2) 0.3197(5) 0.5573(2) 0.0330(10) Uani d . 1 C
H1 0.1280 0.3066 0.3934 0.061 Uiso calc R 1 H
H2 0.0491 0.3384 0.3423 0.080 Uiso calc R 1 H
H3 0.0201 0.5866 0.3388 0.081 Uiso calc R 1 H
H5 0.0352 0.8745 0.3729 0.083 Uiso calc R 1 H
H6 0.0876 1.0766 0.4279 0.074 Uiso calc R 1 H
H7 0.1649 1.0376 0.4745 0.059 Uiso calc R 1 H
H10 0.2353 0.7765 0.3918 0.065 Uiso calc R 1 H
H11 0.2218 0.8036 0.2903 0.077 Uiso calc R 1 H
H12 0.1971 0.5879 0.2220 0.077 Uiso calc R 1 H
H14 0.1730 0.3037 0.1996 0.088 Uiso calc R 1 H
H15 0.1619 0.0674 0.2359 0.096 Uiso calc R 1 H
H16 0.1780 0.0460 0.3382 0.073 Uiso calc R 1 H
H19 0.0589 0.5299 0.6229 0.051 Uiso calc R 1 H
H20 0.0979 0.5710 0.7331 0.062 Uiso calc R 1 H
H21 0.1093 0.3564 0.7980 0.068 Uiso calc R 1 H
H23 0.0927 0.0636 0.8068 0.078 Uiso calc R 1 H
H24 0.0612 -0.1710 0.7551 0.082 Uiso calc R 1 H
H25 0.0241 -0.2026 0.6448 0.064 Uiso calc R 1 H
H28 0.0873 -0.0364 0.5698 0.058 Uiso calc R 1 H
H29 0.1654 -0.0741 0.6240 0.068 Uiso calc R 1 H
H30 0.2107 0.1399 0.6367 0.067 Uiso calc R 1 H
H32 0.2160 0.4351 0.6155 0.066 Uiso calc R 1 H
H33 0.1791 0.6742 0.5754 0.064 Uiso calc R 1 H
H34 0.1017 0.7000 0.5246 0.055 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Pb Pb -3.3944 10.1111 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O1 Pb1 O1 . 7_566 66.00(10)
O1 Pb1 O2 . . 138.60(10)
O1 Pb1 O2 . 7_556 149.90(10)
O1 Pb1 N1 . . 66.20(10)
O1 Pb1 N2 . . 85.20(10)
O1 Pb1 O2 7_566 . 132.30(10)
O1 Pb1 O2 7_566 7_556 100.50(10)
O1 Pb1 N1 7_566 . 130.00(10)
O1 Pb1 N2 7_566 . 79.20(10)
O2 Pb1 O2 . 7_556 70.80(10)
O2 Pb1 N1 . . 79.80(10)
O2 Pb1 N2 . . 67.30(10)
O2 Pb1 N1 7_556 . 128.60(10)
O2 Pb1 N2 7_556 . 119.90(10)
N1 Pb1 N2 . . 83.30(10)
O3 Pb2 O3 . 5_556 68.30(10)
O3 Pb2 O4 . . 144.30(10)
O3 Pb2 O4 . 5_566 121.50(10)
O3 Pb2 N3 . . 67.70(10)
O3 Pb2 N4 . . 83.30(10)
O3 Pb2 O4 5_556 . 122.90(10)
O3 Pb2 O4 5_556 5_566 141.30(10)
O3 Pb2 N3 5_556 . 131.60(10)
O3 Pb2 N4 5_556 . 81.20(10)
O4 Pb2 O4 . 5_566 73.10(10)
O4 Pb2 N3 . . 84.90(10)
O4 Pb2 N4 . . 67.10(10)
O4 Pb2 N3 5_566 . 80.80(10)
O4 Pb2 N4 5_566 . 134.40(10)
N3 Pb2 N4 . . 74.50(10)
C8 O1 Pb1 . . 119.4(3)
C8 O1 Pb1 . 7_566 126.4(3)
Pb1 O1 Pb1 . 7_566 114.10(10)
C17 O2 Pb1 . . 119.2(3)
C26 O3 Pb2 . . 119.2(3)
C26 O3 Pb2 . 5_556 125.0(3)
Pb2 O3 Pb2 . 5_556 111.70(10)
C35 O4 Pb2 . . 120.0(3)
C1 N1 C9 . . 119.6(5)
C1 N1 Pb1 . . 124.1(3)
C9 N1 Pb1 . . 115.8(3)
C10 N2 C18 . . 119.4(5)
C10 N2 Pb1 . . 124.7(3)
C18 N2 Pb1 . . 115.8(3)
C19 N3 C27 . . 118.8(4)
C19 N3 Pb2 . . 125.5(3)
C27 N3 Pb2 . . 115.7(3)
C28 N4 C36 . . 118.9(4)
C28 N4 Pb2 . . 125.3(3)
C36 N4 Pb2 . . 115.5(3)
N1 C1 C2 . . 121.4(5)
C3 C2 C1 . . 119.8(6)
C2 C3 C4 . . 119.6(5)
C3 C4 C5 . . 122.3(5)
C3 C4 C9 . . 117.9(5)
C5 C4 C9 . . 119.8(5)
C6 C5 C4 . . 119.4(5)
C5 C6 C7 . . 121.3(5)
C8 C7 C6 . . 121.6(5)
O1 C8 C7 . . 123.4(5)
O1 C8 C9 . . 119.6(4)
C7 C8 C9 . . 117.0(5)
N1 C9 C4 . . 121.7(5)
N1 C9 C8 . . 117.4(4)
C4 C9 C8 . . 120.9(5)
N2 C10 C11 . . 121.5(5)
C12 C11 C10 . . 119.7(6)
C11 C12 C13 . . 119.4(6)
C12 C13 C14 . . 121.2(6)
C12 C13 C18 . . 119.1(5)
C14 C13 C18 . . 119.7(6)
C15 C14 C13 . . 118.0(6)
C14 C15 C16 . . 122.4(5)
C17 C16 C15 . . 120.9(6)
O2 C17 C16 . . 122.8(5)
O2 C17 C18 . . 121.0(4)
C16 C17 C18 . . 116.2(5)
N2 C18 C13 . . 120.8(5)
N2 C18 C17 . . 116.4(5)
C13 C18 C17 . . 122.7(5)
N3 C19 C20 . . 124.1(5)
C21 C20 C19 . . 117.7(5)
C20 C21 C22 . . 121.3(5)
C23 C22 C27 . . 119.8(5)
C23 C22 C21 . . 123.8(5)
C27 C22 C21 . . 116.4(5)
C24 C23 C22 . . 118.4(5)
C23 C24 C25 . . 123.6(6)
C24 C25 C26 . . 120.2(5)
O3 C26 C25 . . 123.0(5)
O3 C26 C27 . . 120.4(4)
C25 C26 C27 . . 116.5(5)
N3 C27 C22 . . 121.6(4)
N3 C27 C26 . . 117.0(4)
C22 C27 C26 . . 121.4(5)
N4 C28 C29 . . 123.5(5)
C30 C29 C28 . . 118.5(5)
C29 C30 C31 . . 120.7(5)
C30 C31 C32 . . 124.4(5)
C30 C31 C36 . . 117.2(5)
C32 C31 C36 . . 118.4(5)
C33 C32 C31 . . 119.7(5)
C32 C33 C34 . . 122.2(5)
C33 C34 C35 . . 121.9(5)
O4 C35 C34 . . 124.1(4)
O4 C35 C36 . . 119.4(4)
C34 C35 C36 . . 116.5(5)
N4 C36 C31 . . 121.2(4)
N4 C36 C35 . . 117.5(4)
C31 C36 C35 . . 121.3(5)
N1 C1 H1 . . 119.3
C2 C1 H1 . . 119.3
C3 C2 H2 . . 120.1
C1 C2 H2 . . 120.1
C2 C3 H3 . . 120.2
C4 C3 H3 . . 120.2
C6 C5 H5 . . 120.3
C4 C5 H5 . . 120.3
C5 C6 H6 . . 119.3
C7 C6 H6 . . 119.3
C8 C7 H7 . . 119.2
C6 C7 H7 . . 119.2
N2 C10 H10 . . 119.2
C11 C10 H10 . . 119.2
C12 C11 H11 . . 120.1
C10 C11 H11 . . 120.1
C11 C12 H12 . . 120.3
C13 C12 H12 . . 120.3
C15 C14 H14 . . 121.0
C13 C14 H14 . . 121.0
C14 C15 H15 . . 118.8
C16 C15 H15 . . 118.8
C17 C16 H16 . . 119.5
C15 C16 H16 . . 119.5
N3 C19 H19 . . 117.9
C20 C19 H19 . . 117.9
C21 C20 H20 . . 121.1
C19 C20 H20 . . 121.1
C20 C21 H21 . . 119.3
C22 C21 H21 . . 119.3
C24 C23 H23 . . 120.8
C22 C23 H23 . . 120.8
C23 C24 H24 . . 118.2
C25 C24 H24 . . 118.2
C24 C25 H25 . . 119.9
C26 C25 H25 . . 119.9
N4 C28 H28 . . 118.2
C29 C28 H28 . . 118.2
C30 C29 H29 . . 120.7
C28 C29 H29 . . 120.7
C29 C30 H30 . . 119.6
C31 C30 H30 . . 119.6
C33 C32 H32 . . 120.1
C31 C32 H32 . . 120.1
C32 C33 H33 . . 118.9
C34 C33 H33 . . 118.9
C33 C34 H34 . . 119.0
C35 C34 H34 . . 119.0
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Pb1 O1 . 2.433(3)
Pb1 O1 7_566 2.627(3)
Pb1 O2 . 2.387(3)
Pb1 O2 7_556 2.952(3)
Pb1 N1 . 2.528(4)
Pb1 N2 . 2.482(4)
Pb2 O3 . 2.396(3)
Pb2 O3 5_556 2.649(3)
Pb2 O4 . 2.416(3)
Pb2 O4 5_566 2.763(3)
Pb2 N3 . 2.475(4)
Pb2 N4 . 2.493(4)
O1 C8 . 1.318(5)
O2 C17 . 1.303(6)
O3 C26 . 1.311(6)
O4 C35 . 1.299(7)
N1 C1 . 1.320(6)
N1 C9 . 1.364(5)
N2 C10 . 1.326(6)
N2 C18 . 1.368(6)
N3 C19 . 1.315(5)
N3 C27 . 1.378(5)
N4 C28 . 1.320(5)
N4 C36 . 1.375(5)
C1 C2 . 1.414(7)
C2 C3 . 1.361(8)
C3 C4 . 1.402(7)
C4 C5 . 1.399(7)
C4 C9 . 1.406(7)
C5 C6 . 1.363(8)
C6 C7 . 1.405(9)
C7 C8 . 1.381(6)
C8 C9 . 1.430(6)
C10 C11 . 1.417(7)
C11 C12 . 1.349(7)
C12 C13 . 1.394(8)
C13 C14 . 1.398(7)
C13 C18 . 1.401(7)
C14 C15 . 1.380(8)
C15 C16 . 1.410(8)
C16 C17 . 1.388(6)
C17 C18 . 1.419(7)
C19 C20 . 1.387(7)
C20 C21 . 1.365(7)
C21 C22 . 1.422(7)
C22 C23 . 1.400(7)
C22 C27 . 1.407(6)
C23 C24 . 1.339(8)
C24 C25 . 1.401(7)
C25 C26 . 1.396(7)
C26 C27 . 1.423(6)
C28 C29 . 1.389(8)
C29 C30 . 1.371(7)
C30 C31 . 1.400(7)
C31 C32 . 1.404(7)
C31 C36 . 1.423(6)
C32 C33 . 1.359(7)
C33 C34 . 1.385(7)
C34 C35 . 1.378(6)
C35 C36 . 1.440(6)
C1 H1 . 0.93
C2 H2 . 0.93
C3 H3 . 0.93
C5 H5 . 0.93
C6 H6 . 0.93
C7 H7 . 0.93
C10 H10 . 0.93
C11 H11 . 0.93
C12 H12 . 0.93
C14 H14 . 0.93
C15 H15 . 0.93
C16 H16 . 0.93
C19 H19 . 0.93
C20 H20 . 0.93
C21 H21 . 0.93
C23 H23 . 0.93
C24 H24 . 0.93
C25 H25 . 0.93
C28 H28 . 0.93
C29 H29 . 0.93
C30 H30 . 0.93
C32 H32 . 0.93
C33 H33 . 0.93
C34 H34 . 0.93
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
O2 Pb1 O1 C8 . . 48.4(4)
N2 Pb1 O1 C8 . . 95.6(3)
N1 Pb1 O1 C8 . . 10.8(3)
O1 Pb1 O1 C8 7_566 . 175.9(4)
O2 Pb1 O1 C8 7_556 . -116.0(3)
O2 Pb1 O1 Pb1 . 7_566 -127.5(2)
N2 Pb1 O1 Pb1 . 7_566 -80.3(2)
N1 Pb1 O1 Pb1 . 7_566 -165.0(2)
O1 Pb1 O1 Pb1 7_566 7_566 0.0
O2 Pb1 O1 Pb1 7_556 7_566 68.1(3)
O1 Pb1 O2 C17 . . 47.7(4)
N2 Pb1 O2 C17 . . -4.7(3)
N1 Pb1 O2 C17 . . 82.2(3)
O1 Pb1 O2 C17 7_566 . -53.8(4)
O2 Pb1 O2 C17 7_556 . -140.6(4)
O4 Pb2 O3 C26 . . 41.7(5)
N3 Pb2 O3 C26 . . -0.9(4)
N4 Pb2 O3 C26 . . 75.0(4)
O3 Pb2 O3 C26 5_556 . 158.3(5)
O4 Pb2 O3 C26 5_566 . -64.0(4)
O4 Pb2 O3 Pb2 . 5_556 -116.6(2)
N3 Pb2 O3 Pb2 . 5_556 -159.2(2)
N4 Pb2 O3 Pb2 . 5_556 -83.2(2)
O3 Pb2 O3 Pb2 5_556 5_556 0.0
O4 Pb2 O3 Pb2 5_566 5_556 137.80(10)
O3 Pb2 O4 C35 . . 30.2(5)
N3 Pb2 O4 C35 . . 69.2(4)
N4 Pb2 O4 C35 . . -6.1(4)
O3 Pb2 O4 C35 5_556 . -68.1(4)
O4 Pb2 O4 C35 5_566 . 151.1(5)
O2 Pb1 N1 C1 . . 23.3(4)
O1 Pb1 N1 C1 . . 179.2(4)
N2 Pb1 N1 C1 . . 91.4(4)
O1 Pb1 N1 C1 7_566 . 161.2(4)
O2 Pb1 N1 C1 7_556 . -31.7(5)
O2 Pb1 N1 C9 . . -164.8(3)
O1 Pb1 N1 C9 . . -9.0(3)
N2 Pb1 N1 C9 . . -96.7(3)
O1 Pb1 N1 C9 7_566 . -26.9(4)
O2 Pb1 N1 C9 7_556 . 140.1(3)
O2 Pb1 N2 C10 . . -179.4(4)
O1 Pb1 N2 C10 . . 32.3(4)
N1 Pb1 N2 C10 . . 98.8(4)
O1 Pb1 N2 C10 7_566 . -34.1(4)
O2 Pb1 N2 C10 7_556 . -130.1(4)
O2 Pb1 N2 C18 . . 3.9(3)
O1 Pb1 N2 C18 . . -144.4(3)
N1 Pb1 N2 C18 . . -77.8(3)
O1 Pb1 N2 C18 7_566 . 149.2(3)
O2 Pb1 N2 C18 7_556 . 53.2(3)
O3 Pb2 N3 C19 . . -179.0(4)
O4 Pb2 N3 C19 . . 24.3(4)
N4 Pb2 N3 C19 . . 92.0(4)
O3 Pb2 N3 C19 5_556 . 154.8(4)
O4 Pb2 N3 C19 5_566 . -49.4(4)
O3 Pb2 N3 C27 . . 0.8(3)
O4 Pb2 N3 C27 . . -155.8(3)
N4 Pb2 N3 C27 . . -88.2(3)
O3 Pb2 N3 C27 5_556 . -25.3(4)
O4 Pb2 N3 C27 5_566 . 130.5(3)
O3 Pb2 N4 C28 . . 19.0(4)
O4 Pb2 N4 C28 . . 178.6(4)
N3 Pb2 N4 C28 . . 87.6(4)
O3 Pb2 N4 C28 5_556 . -50.0(4)
O4 Pb2 N4 C28 5_566 . 147.4(4)
O3 Pb2 N4 C36 . . -154.0(3)
O4 Pb2 N4 C36 . . 5.6(3)
N3 Pb2 N4 C36 . . -85.3(3)
O3 Pb2 N4 C36 5_556 . 137.0(3)
O4 Pb2 N4 C36 5_566 . -25.6(4)
C9 N1 C1 C2 . . 0.2(8)
Pb1 N1 C1 C2 . . 171.8(4)
N1 C1 C2 C3 . . 0.1(9)
C1 C2 C3 C4 . . -1.2(9)
C2 C3 C4 C5 . . -176.9(6)
C2 C3 C4 C9 . . 1.8(9)
C3 C4 C5 C6 . . 177.7(6)
C9 C4 C5 C6 . . -0.9(9)
C4 C5 C6 C7 . . 2.1(10)
C5 C6 C7 C8 . . -0.8(10)
Pb1 O1 C8 C7 . . 166.9(4)
Pb1 O1 C8 C7 7_566 . -17.8(7)
Pb1 O1 C8 C9 . . -11.9(6)
Pb1 O1 C8 C9 7_566 . 163.4(3)
C6 C7 C8 O1 . . 179.6(5)
C6 C7 C8 C9 . . -1.6(8)
C1 N1 C9 C4 . . 0.5(8)
Pb1 N1 C9 C4 . . -171.8(4)
C1 N1 C9 C8 . . 179.3(5)
Pb1 N1 C9 C8 . . 7.1(5)
C3 C4 C9 N1 . . -1.5(8)
C5 C4 C9 N1 . . 177.2(5)
C3 C4 C9 C8 . . 179.7(5)
C5 C4 C9 C8 . . -1.6(8)
O1 C8 C9 N1 . . 2.8(7)
C7 C8 C9 N1 . . -176.1(4)
O1 C8 C9 C4 . . -178.4(5)
C7 C8 C9 C4 . . 2.8(7)
C18 N2 C10 C11 . . -1.8(8)
Pb1 N2 C10 C11 . . -178.3(4)
N2 C10 C11 C12 . . 1.0(9)
C10 C11 C12 C13 . . 0.1(9)
C11 C12 C13 C14 . . 177.8(6)
C11 C12 C13 C18 . . -0.4(8)
C12 C13 C14 C15 . . -179.0(6)
C18 C13 C14 C15 . . -0.9(9)
C13 C14 C15 C16 . . .0(10)
C14 C15 C16 C17 . . .0(10)
Pb1 O2 C17 C16 . . -174.1(4)
Pb1 O2 C17 C18 . . 5.3(6)
C15 C16 C17 O2 . . -178.7(5)
C15 C16 C17 C18 . . 1.9(8)
C10 N2 C18 C13 . . 1.4(7)
Pb1 N2 C18 C13 . . 178.3(4)
C10 N2 C18 C17 . . -179.8(4)
Pb1 N2 C18 C17 . . -2.9(5)
C12 C13 C18 N2 . . -0.4(8)
C14 C13 C18 N2 . . -178.6(5)
C12 C13 C18 C17 . . -179.0(5)
C14 C13 C18 C17 . . 2.8(8)
O2 C17 C18 N2 . . -1.4(7)
C16 C17 C18 N2 . . 178.1(4)
O2 C17 C18 C13 . . 177.3(5)
C16 C17 C18 C13 . . -3.2(7)
C27 N3 C19 C20 . . -0.1(8)
Pb2 N3 C19 C20 . . 179.7(4)
N3 C19 C20 C21 . . 0.6(9)
C19 C20 C21 C22 . . -1.9(9)
C20 C21 C22 C23 . . -176.9(6)
C20 C21 C22 C27 . . 2.5(8)
C27 C22 C23 C24 . . 0.5(9)
C21 C22 C23 C24 . . 179.9(6)
C22 C23 C24 C25 . . .0(10)
C23 C24 C25 C26 . . -1.0(10)
Pb2 O3 C26 C25 . . 178.6(4)
Pb2 O3 C26 C25 5_556 . -26.3(7)
Pb2 O3 C26 C27 . . 1.0(6)
Pb2 O3 C26 C27 5_556 . 156.1(3)
C24 C25 C26 O3 . . -177.3(5)
C24 C25 C26 C27 . . 0.4(8)
C19 N3 C27 C22 . . 0.9(7)
Pb2 N3 C27 C22 . . -179.0(3)
C19 N3 C27 C26 . . 179.2(4)
Pb2 N3 C27 C26 . . -0.7(5)
C23 C22 C27 N3 . . 177.4(5)
C21 C22 C27 N3 . . -2.0(7)
C23 C22 C27 C26 . . -0.8(8)
C21 C22 C27 C26 . . 179.8(5)
O3 C26 C27 N3 . . -0.2(7)
C25 C26 C27 N3 . . -177.9(4)
O3 C26 C27 C22 . . 178.1(5)
C25 C26 C27 C22 . . 0.4(7)
C36 N4 C28 C29 . . 0.2(8)
Pb2 N4 C28 C29 . . -172.6(5)
N4 C28 C29 C30 . . .0(10)
C28 C29 C30 C31 . . 0.3(9)
C29 C30 C31 C32 . . 179.4(6)
C29 C30 C31 C36 . . 1.0(8)
C30 C31 C32 C33 . . -177.6(5)
C36 C31 C32 C33 . . 0.9(8)
C31 C32 C33 C34 . . -0.4(9)
C32 C33 C34 C35 . . -0.5(9)
Pb2 O4 C35 C34 . . -173.0(4)
Pb2 O4 C35 C36 . . 6.0(6)
C33 C34 C35 O4 . . 179.8(5)
C33 C34 C35 C36 . . 0.9(8)
C28 N4 C36 C31 . . 0.5(7)
Pb2 N4 C36 C31 . . 173.9(3)
C28 N4 C36 C35 . . -178.6(5)
Pb2 N4 C36 C35 . . -5.2(5)
C30 C31 C36 N4 . . -1.0(7)
C32 C31 C36 N4 . . -179.6(4)
C30 C31 C36 C35 . . 178.1(5)
C32 C31 C36 C35 . . -0.5(7)
O4 C35 C36 N4 . . -0.2(7)
C34 C35 C36 N4 . . 178.7(4)
O4 C35 C36 C31 . . -179.4(5)
C34 C35 C36 C31 . . -0.4(7)
