#------------------------------------------------------------------------------
#$Date: 2017-10-13 09:09:21 +0300 (Fri, 13 Oct 2017) $
#$Revision: 201973 $
#$URL: file:///home/coder/svn-repositories/cod/cif/2/20/63/2206314.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2206314
loop_
_publ_author_name
'Suchada Chantrapromma'
'Nawong Boonnak'
'Hoong-Kun Fun'
'Shazia Anjum'
Atta-ur-Rahman
'Chatchanok Karalai'
_publ_section_title
;5,9,10-Trihydroxy-2,2-dimethyl-12-(3-methylbut-2-enyl)-2H,6H-pyrano[3,2-b]xanthen-6-one
 methanol solvate
;
_journal_issue                   7
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              o2136
_journal_page_last               o2138
_journal_paper_doi               10.1107/S1600536805018192
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          'C23 H22 O6, C H4 O'
_chemical_formula_moiety         'C23 H22 O6, C H4 O'
_chemical_formula_sum            'C24 H26 O7'
_chemical_formula_weight         426.45
_chemical_melting_point          .491E-305
_chemical_name_common            'xanthone V1'
_chemical_name_systematic
;
5,9,10-Trihydroxy-2,2-dimethyl-12-(3-methylbut-2-enyl)-2H,6H-
pyrano[3,2-b]xanthen-6-one methanol solvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 111.324(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   9.9258(11)
_cell_length_b                   20.089(2)
_cell_length_c                   11.8605(13)
_cell_measurement_reflns_used    11187
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.00
_cell_measurement_theta_min      2.03
_cell_volume                     2203.1(4)
_computing_cell_refinement       'SAINT (Siemens, 1996)'
_computing_data_collection       'SMART (Siemens, 1996)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    SHELXTL
_computing_publication_material  'SHELXTL and PLATON (Spek, 2003)'
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_detector_area_resol_mean 8.33
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Siemens SMART CCD area-detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0234
_diffrn_reflns_av_sigmaI/netI    0.0248
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       6
_diffrn_reflns_limit_l_min       -14
_diffrn_reflns_number            11187
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         2.03
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.094
_exptl_absorpt_correction_T_max  0.988
_exptl_absorpt_correction_T_min  0.968
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            brown
_exptl_crystal_density_diffrn    1.286
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             904
_exptl_crystal_size_max          0.66
_exptl_crystal_size_mid          0.29
_exptl_crystal_size_min          0.13
_refine_diff_density_max         0.249
_refine_diff_density_min         -0.258
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.107
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     289
_refine_ls_number_reflns         3875
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.107
_refine_ls_R_factor_all          0.0953
_refine_ls_R_factor_gt           0.0868
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'w = 1/[σ²(Fo²)+(0.0696P)²+5.0192P] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.2245
_refine_ls_wR_factor_ref         0.2298
_reflns_number_gt                3309
_reflns_number_total             3875
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            wn6357.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2206314
_cod_database_fobs_code          2206314
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
O1 0.3815(3) 0.50062(18) 0.7232(3) 0.0587(9) Uani d . 1 O
H1A 0.3679 0.5209 0.6599 0.088 Uiso calc R 1 H
O2 0.3884(3) 0.44443(16) 0.9337(3) 0.0518(8) Uani d . 1 O
H2A 0.4533 0.4452 0.9063 0.078 Uiso calc R 1 H
O3 0.1514(3) 0.42220(12) 0.9752(2) 0.0365(6) Uani d . 1 O
O4 -0.2532(3) 0.46949(15) 0.7344(2) 0.0472(7) Uani d . 1 O
O5 -0.3615(3) 0.42156(16) 0.8837(3) 0.0500(8) Uani d . 1 O
H5A -0.3605 0.4371 0.8200 0.075 Uiso calc R 1 H
O6 -0.0345(3) 0.32540(15) 1.2452(3) 0.0535(8) Uani d . 1 O
O7 0.3567(5) 0.5574(3) 0.5132(3) 0.1121(19) Uani d . 1 O
H7A 0.3271 0.5451 0.4424 0.168 Uiso calc R 1 H
C1 -0.0035(4) 0.5024(2) 0.6770(3) 0.0428(9) Uani d . 1 C
H1B -0.0917 0.5160 0.6204 0.051 Uiso calc R 1 H
C2 0.1213(4) 0.5136(2) 0.6556(4) 0.0454(10) Uani d . 1 C
H2B 0.1174 0.5351 0.5850 0.055 Uiso calc R 1 H
C3 0.2539(4) 0.4931(2) 0.7393(4) 0.0421(9) Uani d . 1 C
C4 0.2626(4) 0.46356(19) 0.8469(3) 0.0378(8) Uani d . 1 C
C5 0.1344(4) 0.45256(17) 0.8679(3) 0.0348(8) Uani d . 1 C
C6 0.0003(4) 0.47058(18) 0.7833(3) 0.0340(8) Uani d . 1 C
C7 -0.1296(4) 0.45594(18) 0.8085(3) 0.0353(8) Uani d . 1 C
C8 -0.1076(4) 0.42374(17) 0.9222(3) 0.0322(8) Uani d . 1 C
C9 0.0315(4) 0.40749(17) 1.0021(3) 0.0341(8) Uani d . 1 C
C10 0.0593(4) 0.37492(18) 1.1109(3) 0.0380(9) Uani d . 1 C
C11 -0.0621(5) 0.35662(18) 1.1376(3) 0.0408(9) Uani d . 1 C
C12 -0.2042(4) 0.37204(19) 1.0630(4) 0.0406(9) Uani d . 1 C
C13 -0.2259(4) 0.40600(18) 0.9562(3) 0.0362(8) Uani d . 1 C
C14 -0.3197(5) 0.3547(2) 1.1063(4) 0.0559(11) Uani d . 1 C
H14A -0.4127 0.3711 1.0666 0.067 Uiso calc R 1 H
C15 -0.2924(6) 0.3159(2) 1.2018(5) 0.0647(14) Uani d . 1 C
H15A -0.3658 0.3074 1.2312 0.078 Uiso calc R 1 H
C16 -0.1491(6) 0.2856(2) 1.2633(4) 0.0595(12) Uani d . 1 C
C17 0.2122(5) 0.3589(2) 1.1945(4) 0.0479(10) Uani d . 1 C
H17A 0.2747 0.3962 1.1952 0.058 Uiso calc R 1 H
H17B 0.2137 0.3531 1.2761 0.058 Uiso calc R 1 H
C18 0.2696(5) 0.2977(2) 1.1571(4) 0.0590(12) Uani d . 1 C
H18A 0.2821 0.3003 1.0833 0.071 Uiso calc R 1 H
C19 0.3050(7) 0.2406(3) 1.2143(5) 0.0763(16) Uani d . 1 C
C20 0.3641(11) 0.1845(4) 1.1638(8) 0.139(4) Uani d . 1 C
H20A 0.3665 0.1972 1.0865 0.208 Uiso calc R 1 H
H20B 0.3035 0.1461 1.1543 0.208 Uiso calc R 1 H
H20C 0.4603 0.1743 1.2180 0.208 Uiso calc R 1 H
C21 0.2963(9) 0.2268(4) 1.3351(7) 0.114(3) Uani d . 1 C
H21A 0.2538 0.2643 1.3598 0.171 Uiso calc R 1 H
H21B 0.3918 0.2192 1.3933 0.171 Uiso calc R 1 H
H21C 0.2379 0.1880 1.3298 0.171 Uiso calc R 1 H
C22 -0.1414(8) 0.2161(3) 1.2154(6) 0.0850(18) Uani d . 1 C
H22A -0.1627 0.2183 1.1298 0.127 Uiso calc R 1 H
H22B -0.2106 0.1879 1.2311 0.127 Uiso calc R 1 H
H22C -0.0460 0.1984 1.2551 0.127 Uiso calc R 1 H
C23 -0.1075(7) 0.2843(3) 1.3997(5) 0.0813(17) Uani d . 1 C
H23A -0.1215 0.3277 1.4275 0.122 Uiso calc R 1 H
H23B -0.0078 0.2718 1.4372 0.122 Uiso calc R 1 H
H23C -0.1670 0.2527 1.4207 0.122 Uiso calc R 1 H
C24 0.4596(9) 0.6056(5) 0.5301(7) 0.139(4) Uani d . 1 C
H24C 0.4151 0.6452 0.4875 0.208 Uiso calc R 1 H
H24D 0.5315 0.5902 0.4997 0.208 Uiso calc R 1 H
H24A 0.5045 0.6152 0.6149 0.208 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C3 O1 H1A 109.5 ?
C4 O2 H2A 109.5 ?
C5 O3 C9 119.3(3) yes
C13 O5 H5A 109.5 ?
C11 O6 C16 119.1(3) yes
C24 O7 H7A 109.5 ?
C2 C1 C6 120.7(4) ?
C2 C1 H1B 119.6 ?
C6 C1 H1B 119.6 ?
C1 C2 C3 120.2(4) ?
C1 C2 H2B 119.9 ?
C3 C2 H2B 119.9 ?
O1 C3 C4 115.5(4) ?
O1 C3 C2 123.8(4) ?
C4 C3 C2 120.8(3) ?
O2 C4 C3 123.7(3) ?
O2 C4 C5 117.8(3) ?
C3 C4 C5 118.5(3) ?
O3 C5 C6 123.3(3) ?
O3 C5 C4 115.1(3) ?
C6 C5 C4 121.5(3) ?
C5 C6 C1 118.2(3) ?
C5 C6 C7 119.0(3) ?
C1 C6 C7 122.7(3) ?
O4 C7 C8 122.1(3) ?
O4 C7 C6 121.8(3) ?
C8 C7 C6 116.1(3) ?
C9 C8 C13 117.6(3) ?
C9 C8 C7 121.1(3) ?
C13 C8 C7 121.3(3) ?
O3 C9 C10 115.1(3) ?
O3 C9 C8 121.1(3) ?
C10 C9 C8 123.8(3) ?
C9 C10 C11 116.0(4) ?
C9 C10 C17 121.6(3) yes
C11 C10 C17 122.4(3) yes
O6 C11 C12 120.6(3) ?
O6 C11 C10 116.0(4) ?
C12 C11 C10 123.4(3) ?
C13 C12 C11 118.2(3) ?
C13 C12 C14 124.0(4) ?
C11 C12 C14 117.7(4) ?
O5 C13 C12 119.1(3) ?
O5 C13 C8 119.9(3) ?
C12 C13 C8 121.0(3) ?
C15 C14 C12 120.0(4) ?
C15 C14 H14A 120.0 ?
C12 C14 H14A 120.0 ?
C14 C15 C16 121.9(4) ?
C14 C15 H15A 119.0 ?
C16 C15 H15A 119.0 ?
O6 C16 C15 111.2(3) ?
O6 C16 C23 103.9(4) yes
C15 C16 C23 112.0(4) yes
O6 C16 C22 107.4(4) yes
C15 C16 C22 111.4(5) yes
C23 C16 C22 110.6(4) ?
C18 C17 C10 112.4(4) ?
C18 C17 H17A 109.1 ?
C10 C17 H17A 109.1 ?
C18 C17 H17B 109.1 ?
C10 C17 H17B 109.1 ?
H17A C17 H17B 107.9 ?
C19 C18 C17 128.9(4) ?
C19 C18 H18A 115.5 ?
C17 C18 H18A 115.5 ?
C18 C19 C20 121.5(5) ?
C18 C19 C21 124.0(5) ?
C20 C19 C21 114.4(5) ?
C19 C20 H20A 109.5 ?
C19 C20 H20B 109.5 ?
H20A C20 H20B 109.5 ?
C19 C20 H20C 109.5 ?
H20A C20 H20C 109.5 ?
H20B C20 H20C 109.5 ?
C19 C21 H21A 109.5 ?
C19 C21 H21B 109.5 ?
H21A C21 H21B 109.5 ?
C19 C21 H21C 109.5 ?
H21A C21 H21C 109.5 ?
H21B C21 H21C 109.5 ?
C16 C22 H22A 109.5 ?
C16 C22 H22B 109.5 ?
H22A C22 H22B 109.5 ?
C16 C22 H22C 109.5 ?
H22A C22 H22C 109.5 ?
H22B C22 H22C 109.5 ?
C16 C23 H23A 109.5 ?
C16 C23 H23B 109.5 ?
H23A C23 H23B 109.5 ?
C16 C23 H23C 109.5 ?
H23A C23 H23C 109.5 ?
H23B C23 H23C 109.5 ?
O7 C24 H24C 109.5 ?
O7 C24 H24D 109.5 ?
H24C C24 H24D 109.5 ?
O7 C24 H24A 109.5 ?
H24C C24 H24A 109.5 ?
H24D C24 H24A 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
O1 C3 1.356(4) yes
O1 H1A 0.8200 ?
O2 C4 1.354(5) yes
O2 H2A 0.8200 ?
O3 C5 1.365(4) yes
O3 C9 1.372(4) yes
O4 C7 1.252(4) yes
O5 C13 1.344(5) yes
O5 H5A 0.8200 ?
O6 C11 1.358(5) yes
O6 C16 1.468(5) yes
O7 C24 1.369(8) yes
O7 H7A 0.8200 ?
C1 C2 1.371(5) ?
C1 C6 1.401(5) ?
C1 H1B 0.9300 ?
C2 C3 1.391(6) ?
C2 H2B 0.9300 ?
C3 C4 1.381(5) ?
C4 C5 1.400(5) ?
C5 C6 1.393(5) ?
C6 C7 1.456(5) ?
C7 C8 1.439(5) ?
C8 C9 1.400(5) ?
C8 C13 1.419(5) ?
C9 C10 1.381(5) ?
C10 C11 1.402(5) ?
C10 C17 1.515(6) ?
C11 C12 1.401(6) ?
C12 C13 1.385(5) ?
C12 C14 1.459(5) ?
C14 C15 1.320(6) ?
C14 H14A 0.9300 ?
C15 C16 1.474(7) ?
C15 H15A 0.9300 ?
C16 C23 1.517(7) ?
C16 C22 1.519(7) ?
C17 C18 1.488(6) ?
C17 H17A 0.9700 ?
C17 H17B 0.9700 ?
C18 C19 1.314(7) yes
C18 H18A 0.9300 ?
C19 C20 1.492(8) ?
C19 C21 1.492(8) ?
C20 H20A 0.9600 ?
C20 H20B 0.9600 ?
C20 H20C 0.9600 ?
C21 H21A 0.9600 ?
C21 H21B 0.9600 ?
C21 H21C 0.9600 ?
C22 H22A 0.9600 ?
C22 H22B 0.9600 ?
C22 H22C 0.9600 ?
C23 H23A 0.9600 ?
C23 H23B 0.9600 ?
C23 H23C 0.9600 ?
C24 H24C 0.9600 ?
C24 H24D 0.9600 ?
C24 H24A 0.9600 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
O1 H1A O7 1_555 0.82 1.85 2.668(5) 171 yes
O2 H2A O1 1_555 0.82 2.31 2.718(5) 111 yes
O2 H2A O5 1_655 0.82 2.01 2.792(5) 160 yes
O5 H5A O4 1_555 0.82 1.84 2.570(4) 148 yes
O7 H7A O4 3_566 0.82 1.97 2.789(4) 171 yes
C14 H14A O2 1_455 0.93 2.51 3.394(6) 159 yes
C17 H17B O6 1_555 0.97 2.42 2.807(6) 103 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
C6 C1 C2 C3 0.4(6) ?
C1 C2 C3 O1 178.0(4) ?
C1 C2 C3 C4 -2.6(6) ?
O1 C3 C4 O2 1.7(6) ?
C2 C3 C4 O2 -177.8(4) ?
O1 C3 C4 C5 -178.2(3) ?
C2 C3 C4 C5 2.3(6) ?
C9 O3 C5 C6 0.9(5) ?
C9 O3 C5 C4 -178.0(3) ?
O2 C4 C5 O3 -1.0(5) ?
C3 C4 C5 O3 179.0(3) ?
O2 C4 C5 C6 -179.9(3) ?
C3 C4 C5 C6 0.1(6) ?
O3 C5 C6 C1 179.1(3) ?
C4 C5 C6 C1 -2.1(5) ?
O3 C5 C6 C7 -0.7(5) ?
C4 C5 C6 C7 178.0(3) ?
C2 C1 C6 C5 1.9(6) ?
C2 C1 C6 C7 -178.3(4) ?
C5 C6 C7 O4 -178.2(3) ?
C1 C6 C7 O4 2.0(6) ?
C5 C6 C7 C8 0.5(5) ?
C1 C6 C7 C8 -179.3(3) ?
O4 C7 C8 C9 178.3(3) ?
C6 C7 C8 C9 -0.4(5) ?
O4 C7 C8 C13 -0.4(5) ?
C6 C7 C8 C13 -179.0(3) ?
C5 O3 C9 C10 178.0(3) ?
C5 O3 C9 C8 -0.7(5) ?
C13 C8 C9 O3 179.2(3) ?
C7 C8 C9 O3 0.5(5) ?
C13 C8 C9 C10 0.6(5) ?
C7 C8 C9 C10 -178.1(3) ?
O3 C9 C10 C11 -177.1(3) ?
C8 C9 C10 C11 1.6(5) ?
O3 C9 C10 C17 1.7(5) ?
C8 C9 C10 C17 -179.6(3) ?
C16 O6 C11 C12 23.3(5) ?
C16 O6 C11 C10 -159.9(4) ?
C9 C10 C11 O6 -179.2(3) ?
C17 C10 C11 O6 2.0(5) ?
C9 C10 C11 C12 -2.5(6) ?
C17 C10 C11 C12 178.6(4) ?
O6 C11 C12 C13 177.8(3) ?
C10 C11 C12 C13 1.3(6) ?
O6 C11 C12 C14 1.3(6) ?
C10 C11 C12 C14 -175.1(4) ?
C11 C12 C13 O5 -179.7(3) ?
C14 C12 C13 O5 -3.5(6) ?
C11 C12 C13 C8 1.1(6) ?
C14 C12 C13 C8 177.2(4) ?
C9 C8 C13 O5 178.8(3) ?
C7 C8 C13 O5 -2.5(5) ?
C9 C8 C13 C12 -1.9(5) ?
C7 C8 C13 C12 176.7(3) ?
C13 C12 C14 C15 172.4(4) ?
C11 C12 C14 C15 -11.4(7) ?
C12 C14 C15 C16 -3.7(8) ?
C11 O6 C16 C15 -35.7(5) ?
C11 O6 C16 C23 -156.4(4) ?
C11 O6 C16 C22 86.4(5) ?
C14 C15 C16 O6 26.0(7) ?
C14 C15 C16 C23 141.8(5) yes
C14 C15 C16 C22 -93.7(6) yes
C9 C10 C17 C18 -81.4(5) yes
C11 C10 C17 C18 97.4(4) yes
C10 C17 C18 C19 -114.6(6) ?
C17 C18 C19 C20 -178.8(7) yes
C17 C18 C19 C21 -1.4(11) yes
loop_
_cod_related_entry_id
_cod_related_entry_database
_cod_related_entry_code
1 ChemSpider 21129211
