#------------------------------------------------------------------------------
#$Date: 2016-02-14 06:40:26 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176432 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/72/2207275.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2207275
loop_
_publ_author_name
'Diao, Chun-Hua'
'Guo, Min-Jie'
'Yu, Ming'
'Chen, Xin'
'Jing, Zuo-Liang'
'Deng, Qi-Liang'
_publ_section_title
;
 4-[2-(4-Formyl-2-methoxyphenoxy)ethoxy]-3-methoxybenzaldehyde
;
_journal_coeditor_code           KP6051
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              o3741
_journal_page_last               o3742
_journal_paper_doi               10.1107/S1600536805032861
_journal_volume                  61
_journal_year                    2005
_chemical_formula_iupac          'C18 H18 O6'
_chemical_formula_moiety         'C18 H18 O6'
_chemical_formula_sum            'C18 H18 O6'
_chemical_formula_weight         330.32
_chemical_name_systematic
;
4-[2-(4-Formyl-2-methoxyphenoxy)ethoxy]-3-methoxybenzaldehyde
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 108.551(4)
_cell_angle_gamma                90.00
_cell_formula_units_Z            6
_cell_length_a                   14.692(4)
_cell_length_b                   7.805(2)
_cell_length_c                   22.048(6)
_cell_measurement_reflns_used    4375
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      26.27
_cell_measurement_theta_min      2.79
_cell_volume                     2396.9(11)
_computing_cell_refinement       'SAINT (Bruker, 1999)'
_computing_data_collection       'SMART (Bruker, 1999)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Bruker, 1999)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0383
_diffrn_reflns_av_sigmaI/netI    0.0494
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -17
_diffrn_reflns_limit_k_max       8
_diffrn_reflns_limit_k_min       -9
_diffrn_reflns_limit_l_max       26
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            11241
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         1.95
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.103
_exptl_absorpt_correction_T_max  0.978
_exptl_absorpt_correction_T_min  0.960
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 1999)'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.373
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             1044
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.444
_refine_diff_density_min         -0.328
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.078
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     328
_refine_ls_number_reflns         4170
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.078
_refine_ls_R_factor_all          0.0944
_refine_ls_R_factor_gt           0.0624
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0898P)²+1.1951P] where P = (Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1587
_refine_ls_wR_factor_ref         0.1912
_reflns_number_gt                2809
_reflns_number_total             4170
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            kp6051.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2396.8(11)
_cod_original_sg_symbol_Hall     '-p 2yn'
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2207275
_cod_database_fobs_code          2207275
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_type_symbol
O1 0.73125(13) 0.6129(2) 0.95201(8) 0.0358(5) Uani d . 1 O
O2 0.60106(12) 0.3972(2) 1.04076(7) 0.0333(4) Uani d . 1 O
O3 0.82650(15) 0.8629(2) 0.92602(9) 0.0488(6) Uani d . 1 O
O4 0.90678(18) 0.6518(3) 0.72197(10) 0.0649(7) Uani d . 1 O
O5 0.51552(14) 0.1375(2) 1.06937(8) 0.0418(5) Uani d . 1 O
O6 0.44523(18) 0.3363(3) 1.27841(10) 0.0652(7) Uani d . 1 O
O7 0.93391(13) 0.3805(2) 0.04066(8) 0.0362(5) Uani d . 1 O
O8 0.83355(15) 0.1213(2) 0.05471(9) 0.0469(6) Uani d . 1 O
O9 0.80159(17) 0.4659(3) 0.28834(10) 0.0613(7) Uani d . 1 O
C1 0.76262(17) 0.5888(3) 0.90067(11) 0.0302(6) Uani d . 1 C
C2 0.81430(18) 0.7269(3) 0.88622(11) 0.0326(6) Uani d . 1 C
C3 0.84873(19) 0.7124(3) 0.83537(11) 0.0362(6) Uani d . 1 C
H3 0.8832 0.8023 0.8256 0.043 Uiso calc R 1 H
C4 0.83229(18) 0.5637(3) 0.79829(11) 0.0353(6) Uani d . 1 C
C5 0.78274(19) 0.4311(3) 0.81308(12) 0.0370(6) Uani d . 1 C
H5 0.7728 0.3316 0.7886 0.044 Uiso calc R 1 H
C6 0.74692(18) 0.4424(3) 0.86412(12) 0.0359(6) Uani d . 1 C
H6 0.7126 0.3517 0.8735 0.043 Uiso calc R 1 H
C7 0.8650(2) 0.5457(4) 0.74105(13) 0.0434(7) Uani d . 1 C
H7 0.8516 0.4429 0.7186 0.052 Uiso calc R 1 H
C8 0.8854(3) 1.0005(4) 0.91691(16) 0.0635(10) Uani d . 1 C
H8A 0.9483 0.9579 0.9209 0.095 Uiso calc R 1 H
H8B 0.8901 1.0873 0.9486 0.095 Uiso calc R 1 H
H8C 0.8572 1.0487 0.8751 0.095 Uiso calc R 1 H
C9 0.67984(18) 0.4744(3) 0.96822(11) 0.0306(6) Uani d . 1 C
H9A 0.7200 0.3732 0.9795 0.037 Uiso calc R 1 H
H9B 0.6231 0.4466 0.9326 0.037 Uiso calc R 1 H
C10 0.65239(18) 0.5365(3) 1.02446(11) 0.0310(6) Uani d . 1 C
H10A 0.7091 0.5646 1.0600 0.037 Uiso calc R 1 H
H10B 0.6120 0.6375 1.0132 0.037 Uiso calc R 1 H
C11 0.57300(17) 0.4173(3) 1.09334(10) 0.0281(6) Uani d . 1 C
C12 0.52692(18) 0.2742(3) 1.10936(11) 0.0304(6) Uani d . 1 C
C13 0.49662(19) 0.2828(3) 1.16230(11) 0.0349(6) Uani d . 1 C
H13 0.4671 0.1886 1.1739 0.042 Uiso calc R 1 H
C14 0.51023(19) 0.4340(3) 1.19897(11) 0.0343(6) Uani d . 1 C
C15 0.55290(18) 0.5727(3) 1.18162(12) 0.0361(6) Uani d . 1 C
H15 0.5602 0.6734 1.2053 0.043 Uiso calc R 1 H
C16 0.58550(18) 0.5653(3) 1.12926(12) 0.0347(6) Uani d . 1 C
H16 0.6157 0.6597 1.1184 0.042 Uiso calc R 1 H
C17 0.4652(3) -0.0070(4) 1.08213(15) 0.0585(9) Uani d . 1 C
H17A 0.4983 -0.0503 1.1241 0.088 Uiso calc R 1 H
H17B 0.4620 -0.0947 1.0510 0.088 Uiso calc R 1 H
H17C 0.4013 0.0267 1.0799 0.088 Uiso calc R 1 H
C18 0.4809(2) 0.4468(4) 1.25641(13) 0.0451(7) Uani d . 1 C
H18 0.4911 0.5515 1.2777 0.054 Uiso calc R 1 H
C19 0.89998(17) 0.3897(3) 0.09120(11) 0.0296(6) Uani d . 1 C
C20 0.91589(18) 0.5256(3) 0.13373(12) 0.0359(6) Uani d . 1 C
H20 0.9522 0.6190 0.1288 0.043 Uiso calc R 1 H
C21 0.87782(18) 0.5219(3) 0.18343(12) 0.0360(6) Uani d . 1 C
H21 0.8893 0.6124 0.2124 0.043 Uiso calc R 1 H
C22 0.82233(18) 0.3836(3) 0.19039(11) 0.0329(6) Uani d . 1 C
C23 0.80551(19) 0.2487(3) 0.14715(11) 0.0337(6) Uani d . 1 C
H23 0.7669 0.1577 0.1511 0.040 Uiso calc R 1 H
C24 0.84544(18) 0.2482(3) 0.09845(11) 0.0310(6) Uani d . 1 C
C25 0.7811(2) 0.3749(4) 0.24300(13) 0.0433(7) Uani d . 1 C
H25 0.7351 0.2909 0.2404 0.052 Uiso calc R 1 H
C26 0.7796(3) -0.0248(4) 0.06196(17) 0.0679(11) Uani d . 1 C
H26A 0.8122 -0.0808 0.1017 0.102 Uiso calc R 1 H
H26B 0.7734 -0.1029 0.0272 0.102 Uiso calc R 1 H
H26C 0.7170 0.0109 0.0618 0.102 Uiso calc R 1 H
C27 0.98484(18) 0.5254(3) 0.02818(11) 0.0333(6) Uani d . 1 C
H27A 1.0404 0.5508 0.0649 0.040 Uiso calc R 1 H
H27B 0.9436 0.6255 0.0182 0.040 Uiso calc R 1 H
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_diffrn_measured_fraction_theta_max
0.985
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C1 O1 C9 . . 116.68(18) yes
C11 O2 C10 . . 116.97(18) yes
C2 O3 C8 . . 117.3(2) yes
C12 O5 C17 . . 117.21(19) yes
C19 O7 C27 . . 117.84(18) yes
C24 O8 C26 . . 117.09(19) yes
O1 C1 C6 . . 124.2(2) ?
O1 C1 C2 . . 115.5(2) ?
C6 C1 C2 . . 120.3(2) ?
O3 C2 C3 . . 126.0(2) ?
O3 C2 C1 . . 115.0(2) ?
C3 C2 C1 . . 119.0(2) ?
C2 C3 C4 . . 120.4(2) ?
C2 C3 H3 . . 119.8 ?
C4 C3 H3 . . 119.8 ?
C5 C4 C3 . . 119.8(2) ?
C5 C4 C7 . . 118.1(2) ?
C3 C4 C7 . . 122.1(2) ?
C4 C5 C6 . . 120.9(2) ?
C4 C5 H5 . . 119.5 ?
C6 C5 H5 . . 119.5 ?
C1 C6 C5 . . 119.5(2) ?
C1 C6 H6 . . 120.3 ?
C5 C6 H6 . . 120.3 ?
O4 C7 C4 . . 125.2(3) ?
O4 C7 H7 . . 117.4 ?
C4 C7 H7 . . 117.4 ?
O3 C8 H8A . . 109.5 ?
O3 C8 H8B . . 109.5 ?
H8A C8 H8B . . 109.5 ?
O3 C8 H8C . . 109.5 ?
H8A C8 H8C . . 109.5 ?
H8B C8 H8C . . 109.5 ?
O1 C9 C10 . . 105.3(2) ?
O1 C9 H9A . . 110.7 ?
C10 C9 H9A . . 110.7 ?
O1 C9 H9B . . 110.7 ?
C10 C9 H9B . . 110.7 ?
H9A C9 H9B . . 108.8 ?
O2 C10 C9 . . 105.2(2) ?
O2 C10 H10A . . 110.7 ?
C9 C10 H10A . . 110.7 ?
O2 C10 H10B . . 110.7 ?
C9 C10 H10B . . 110.7 ?
H10A C10 H10B . . 108.8 ?
O2 C11 C16 . . 124.5(2) ?
O2 C11 C12 . . 115.1(2) ?
C16 C11 C12 . . 120.5(2) ?
O5 C12 C13 . . 125.6(2) ?
O5 C12 C11 . . 115.43(19) ?
C13 C12 C11 . . 119.0(2) ?
C12 C13 C14 . . 120.2(2) ?
C12 C13 H13 . . 119.9 ?
C14 C13 H13 . . 119.9 ?
C15 C14 C13 . . 119.8(2) ?
C15 C14 C18 . . 118.4(2) ?
C13 C14 C18 . . 121.8(2) ?
C14 C15 C16 . . 120.8(2) ?
C14 C15 H15 . . 119.6 ?
C16 C15 H15 . . 119.6 ?
C11 C16 C15 . . 119.7(2) ?
C11 C16 H16 . . 120.2 ?
C15 C16 H16 . . 120.2 ?
O5 C17 H17A . . 109.5 ?
O5 C17 H17B . . 109.5 ?
H17A C17 H17B . . 109.5 ?
O5 C17 H17C . . 109.5 ?
H17A C17 H17C . . 109.5 ?
H17B C17 H17C . . 109.5 ?
O6 C18 C14 . . 126.3(3) ?
O6 C18 H18 . . 116.9 ?
C14 C18 H18 . . 116.9 ?
O7 C19 C20 . . 124.6(2) ?
O7 C19 C24 . . 115.1(2) ?
C20 C19 C24 . . 120.3(2) ?
C21 C20 C19 . . 119.9(2) ?
C21 C20 H20 . . 120.1 ?
C19 C20 H20 . . 120.1 ?
C20 C21 C22 . . 120.2(2) ?
C20 C21 H21 . . 119.9 ?
C22 C21 H21 . . 119.9 ?
C23 C22 C21 . . 119.7(2) ?
C23 C22 C25 . . 118.6(2) ?
C21 C22 C25 . . 121.7(2) ?
C24 C23 C22 . . 120.7(2) ?
C24 C23 H23 . . 119.7 ?
C22 C23 H23 . . 119.7 ?
O8 C24 C23 . . 124.5(2) ?
O8 C24 C19 . . 116.3(2) ?
C23 C24 C19 . . 119.1(2) ?
O9 C25 C22 . . 125.4(3) ?
O9 C25 H25 . . 117.3 ?
C22 C25 H25 . . 117.3 ?
O8 C26 H26A . . 109.5 ?
O8 C26 H26B . . 109.5 ?
H26A C26 H26B . . 109.5 ?
O8 C26 H26C . . 109.5 ?
H26A C26 H26C . . 109.5 ?
H26B C26 H26C . . 109.5 ?
O7 C27 C27 . 3_765 105.2(2) ?
O7 C27 H27A . . 110.7 ?
C27 C27 H27A 3_765 . 110.7 ?
O7 C27 H27B . . 110.7 ?
C27 C27 H27B 3_765 . 110.7 ?
H27A C27 H27B . . 108.8 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
O1 C1 . 1.364(3) yes
O1 C9 . 1.428(3) yes
O2 C11 . 1.358(3) yes
O2 C10 . 1.433(3) yes
O3 C2 . 1.352(3) yes
O3 C8 . 1.433(3) yes
O4 C7 . 1.185(3) yes
O5 C12 . 1.360(3) yes
O5 C17 . 1.425(3) yes
O6 C18 . 1.190(3) yes
O7 C19 . 1.360(3) yes
O7 C27 . 1.430(3) yes
O8 C24 . 1.355(3) yes
O8 C26 . 1.426(3) yes
O9 C25 . 1.185(3) yes
C1 C6 . 1.375(4) ?
C1 C2 . 1.412(3) ?
C2 C3 . 1.373(3) ?
C3 C4 . 1.396(4) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.364(4) ?
C4 C7 . 1.493(4) ?
C5 C6 . 1.388(3) ?
C5 H5 . 0.9300 ?
C6 H6 . 0.9300 ?
C7 H7 . 0.9300 ?
C8 H8A . 0.9600 ?
C8 H8B . 0.9600 ?
C8 H8C . 0.9600 ?
C9 C10 . 1.501(3) ?
C9 H9A . 0.9700 ?
C9 H9B . 0.9700 ?
C10 H10A . 0.9700 ?
C10 H10B . 0.9700 ?
C11 C16 . 1.379(3) ?
C11 C12 . 1.408(3) ?
C12 C13 . 1.377(3) ?
C13 C14 . 1.408(4) ?
C13 H13 . 0.9300 ?
C14 C15 . 1.365(4) ?
C14 C18 . 1.465(4) ?
C15 C16 . 1.385(3) ?
C15 H15 . 0.9300 ?
C16 H16 . 0.9300 ?
C17 H17A . 0.9600 ?
C17 H17B . 0.9600 ?
C17 H17C . 0.9600 ?
C18 H18 . 0.9300 ?
C19 C20 . 1.385(3) ?
C19 C24 . 1.403(3) ?
C20 C21 . 1.380(4) ?
C20 H20 . 0.9300 ?
C21 C22 . 1.391(4) ?
C21 H21 . 0.9300 ?
C22 C23 . 1.389(3) ?
C22 C25 . 1.471(4) ?
C23 C24 . 1.378(3) ?
C23 H23 . 0.9300 ?
C25 H25 . 0.9300 ?
C26 H26A . 0.9600 ?
C26 H26B . 0.9600 ?
C26 H26C . 0.9600 ?
C27 C27 3_765 1.500(5) ?
C27 H27A . 0.9700 ?
C27 H27B . 0.9700 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_4
_geom_torsion
C9 O1 C1 C6 . 0.7(3)
C9 O1 C1 C2 . -179.2(2)
C8 O3 C2 C3 . -3.9(4)
C8 O3 C2 C1 . 174.8(3)
O1 C1 C2 O3 . 0.9(3)
C6 C1 C2 O3 . -179.0(2)
O1 C1 C2 C3 . 179.7(2)
C6 C1 C2 C3 . -0.2(4)
O3 C2 C3 C4 . 179.1(2)
C1 C2 C3 C4 . 0.4(4)
C2 C3 C4 C5 . -0.8(4)
C2 C3 C4 C7 . 177.5(2)
C3 C4 C5 C6 . 1.0(4)
C7 C4 C5 C6 . -177.4(2)
O1 C1 C6 C5 . -179.5(2)
C2 C1 C6 C5 . 0.3(4)
C4 C5 C6 C1 . -0.7(4)
C5 C4 C7 O4 . 178.3(3)
C3 C4 C7 O4 . 0.0(4)
C1 O1 C9 C10 . -178.7(2)
C11 O2 C10 C9 . 176.1(2)
O1 C9 C10 O2 . -179.84(17)
C10 O2 C11 C16 . 4.1(3)
C10 O2 C11 C12 . -177.1(2)
C17 O5 C12 C13 . 2.2(4)
C17 O5 C12 C11 . -177.1(2)
O2 C11 C12 O5 . -1.1(3)
C16 C11 C12 O5 . 177.8(2)
O2 C11 C12 C13 . 179.6(2)
C16 C11 C12 C13 . -1.5(4)
O5 C12 C13 C14 . -178.1(2)
C11 C12 C13 C14 . 1.1(4)
C12 C13 C14 C15 . 0.5(4)
C12 C13 C14 C18 . -178.6(2)
C13 C14 C15 C16 . -1.8(4)
C18 C14 C15 C16 . 177.4(2)
O2 C11 C16 C15 . 179.1(2)
C12 C11 C16 C15 . 0.3(4)
C14 C15 C16 C11 . 1.4(4)
C15 C14 C18 O6 . -178.0(3)
C13 C14 C18 O6 . 1.2(5)
C27 O7 C19 C20 . -3.8(3)
C27 O7 C19 C24 . 176.1(2)
O7 C19 C20 C21 . 179.8(2)
C24 C19 C20 C21 . -0.1(4)
C19 C20 C21 C22 . -1.0(4)
C20 C21 C22 C23 . 0.1(4)
C20 C21 C22 C25 . 179.6(2)
C21 C22 C23 C24 . 1.8(4)
C25 C22 C23 C24 . -177.7(2)
C26 O8 C24 C23 . -3.1(4)
C26 O8 C24 C19 . 179.0(3)
C22 C23 C24 O8 . 179.3(2)
C22 C23 C24 C19 . -2.9(4)
O7 C19 C24 O8 . 0.1(3)
C20 C19 C24 O8 . -180.0(2)
O7 C19 C24 C23 . -177.9(2)
C20 C19 C24 C23 . 2.0(4)
C23 C22 C25 O9 . 167.5(3)
C21 C22 C25 O9 . -12.0(4)
C19 O7 C27 C27 3_765 178.3(2)
