#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/87/2208774.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2208774
loop_
_publ_author_name
'da Silva, Luiz Everson'
'Joussef, Antonio Carlos'
'Foro, Sabine'
'Schmidt, Boris'
_publ_section_title
Bis[2,4,6-triisopropyl-N-(quinolin-8-yl)benzenesulfonamidato-κ²N,N']copper(II)
_journal_coeditor_code           YA2004
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m912
_journal_page_last               m913
_journal_paper_doi               10.1107/S1600536806010920
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Cu (C24 H29 N2 O2 S )2]'
_chemical_formula_moiety         'C48 H58 Cu N4 O4 S2'
_chemical_formula_sum            'C48 H58 Cu N4 O4 S2'
_chemical_formula_weight         882.64
_chemical_name_systematic
;
Bis[N-(quinolin-8-yl)-2,4,6-triisopropylbenzene-sulfonamidato-κ²N,\
N'] copper(II)
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 102.140(6)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   24.513(2)
_cell_length_b                   9.4679(7)
_cell_length_c                   19.6000(10)
_cell_measurement_reflns_used    3257
_cell_measurement_temperature    299(2)
_cell_measurement_theta_max      21.0
_cell_measurement_theta_min      2.1
_cell_volume                     4447.2(5)
_computing_cell_refinement
;
CrysAlis RED (Oxford Diffraction, 2004)
;
_computing_data_collection
;
CrysAlis CCD (Oxford Diffraction, 2004)
;
_computing_data_reduction
;
CrysAlis RED (Oxford Diffraction, 2004)
;
_computing_molecular_graphics    'PLATON (Spek, 2003)'
_computing_publication_material  SHELXL-97
_computing_structure_refinement  'SHELXL-97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS-97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      299(2)
_diffrn_measured_fraction_theta_full 0.985
_diffrn_measured_fraction_theta_max 0.985
_diffrn_measurement_device_type
;
Oxford Diffraction Xcalibur diffractometer with
a Sapphire CCD detector.
;
_diffrn_measurement_method
;
Rotation method data acquisition using omega- and phi-scans
;
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.061
_diffrn_reflns_av_sigmaI/netI    0.051
_diffrn_reflns_limit_h_max       29
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       23
_diffrn_reflns_limit_l_min       -23
_diffrn_reflns_number            15625
_diffrn_reflns_theta_full        26.4
_diffrn_reflns_theta_max         26.4
_diffrn_reflns_theta_min         4.1
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.63
_exptl_absorpt_correction_T_max  0.893
_exptl_absorpt_correction_T_min  0.788
_exptl_absorpt_correction_type   analytical
_exptl_absorpt_process_details
;
(CrysAlis RED; Oxford Diffraction, 2004)
;
_exptl_crystal_colour            black
_exptl_crystal_density_diffrn    1.318
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             1868
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.22
_refine_diff_density_max         0.68
_refine_diff_density_min         -0.32
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.02
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     267
_refine_ls_number_reflns         4493
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.02
_refine_ls_R_factor_all          0.060
_refine_ls_R_factor_gt           0.043
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0752P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.118
_refine_ls_wR_factor_ref         0.126
_reflns_number_gt                3310
_reflns_number_total             4493
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ya2004.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_database_code               2208774
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
C C1 0.57658(11) -0.0731(3) 0.86693(16) 0.0538(7) Uani d . 1
H H1 0.6058 -0.0562 0.8444 0.065 Uiso calc R 1
C C2 0.58609(12) -0.1605(3) 0.92585(16) 0.0620(8) Uani d . 1
H H2 0.6211 -0.1999 0.9424 0.074 Uiso calc R 1
C C3 0.54367(12) -0.1869(3) 0.95849(15) 0.0556(7) Uani d . 1
H H3 0.5497 -0.2451 0.9976 0.067 Uiso calc R 1
C C4 0.49099(11) -0.1279(3) 0.93418(13) 0.0436(6) Uani d . 1
C C5 0.44404(11) -0.1514(3) 0.96315(14) 0.0506(7) Uani d . 1
H H5 0.4470 -0.2084 1.0024 0.061 Uiso calc R 1
C C6 0.39453(12) -0.0914(3) 0.93415(15) 0.0513(7) Uani d . 1
H H6 0.3638 -0.1085 0.9539 0.062 Uiso calc R 1
C C7 0.38814(10) -0.0044(3) 0.87541(13) 0.0456(6) Uani d . 1
H H7 0.3533 0.0334 0.8563 0.055 Uiso calc R 1
C C8 0.43277(10) 0.0260(2) 0.84544(12) 0.0354(5) Uani d . 1
C C9 0.48464(9) -0.0387(2) 0.87496(12) 0.0353(5) Uani d . 1
C C10 0.35309(9) 0.2981(2) 0.80408(12) 0.0348(5) Uani d . 1
C C11 0.38922(10) 0.4027(2) 0.83936(12) 0.0374(6) Uani d . 1
C C12 0.37181(10) 0.4791(3) 0.89105(13) 0.0450(6) Uani d . 1
H H12 0.3962 0.5454 0.9158 0.054 Uiso calc R 1
C C13 0.32041(11) 0.4624(3) 0.90787(14) 0.0474(6) Uani d . 1
C C14 0.28491(10) 0.3648(3) 0.86963(14) 0.0482(6) Uani d . 1
H H14 0.2494 0.3552 0.8788 0.058 Uiso calc R 1
C C15 0.29909(9) 0.2797(2) 0.81801(13) 0.0387(6) Uani d . 1
C C16 0.44558(10) 0.4446(3) 0.82426(13) 0.0431(6) Uani d . 1
H H16 0.4524 0.3852 0.7860 0.052 Uiso calc R 1
C C17 0.49293(12) 0.4219(4) 0.88589(16) 0.0726(10) Uani d . 1
H H17A 0.4886 0.4838 0.9232 0.087 Uiso calc R 1
H H17B 0.5277 0.4418 0.8726 0.087 Uiso calc R 1
H H17C 0.4928 0.3256 0.9012 0.087 Uiso calc R 1
C C18 0.44289(14) 0.5981(3) 0.79949(18) 0.0687(9) Uani d . 1
H H18A 0.4268 0.6555 0.8305 0.082 Uiso calc R 1
H H18B 0.4203 0.6040 0.7532 0.082 Uiso calc R 1
H H18C 0.4799 0.6311 0.7992 0.082 Uiso calc R 1
C C19 0.30335(12) 0.5573(4) 0.96267(15) 0.0629(8) Uani d . 1
H H19 0.3081 0.6539 0.9470 0.075 Uiso calc R 1
C C20 0.34394(15) 0.5439(5) 1.03163(16) 0.0850(11) Uani d . 1
H H20A 0.3351 0.6125 1.0637 0.102 Uiso calc R 1
H H20B 0.3812 0.5600 1.0250 0.102 Uiso calc R 1
H H20C 0.3415 0.4508 1.0501 0.102 Uiso calc R 1
C C21 0.24439(15) 0.5481(4) 0.96770(18) 0.0855(11) Uani d . 1
H H21A 0.2211 0.5508 0.9217 0.103 Uiso calc R 1
H H21B 0.2354 0.6262 0.9945 0.103 Uiso calc R 1
H H21C 0.2382 0.4611 0.9901 0.103 Uiso calc R 1
C C22 0.25369(10) 0.1829(3) 0.77851(15) 0.0482(7) Uani d . 1
H H22 0.2721 0.1028 0.7611 0.058 Uiso calc R 1
C C23 0.22075(14) 0.2600(4) 0.71649(18) 0.0813(11) Uani d . 1
H H23A 0.1928 0.1983 0.6907 0.098 Uiso calc R 1
H H23B 0.2453 0.2901 0.6870 0.098 Uiso calc R 1
H H23C 0.2031 0.3410 0.7320 0.098 Uiso calc R 1
C C24 0.21503(15) 0.1232(4) 0.8238(2) 0.0890(12) Uani d . 1
H H24A 0.1887 0.1944 0.8304 0.107 Uiso calc R 1
H H24B 0.2368 0.0951 0.8683 0.107 Uiso calc R 1
H H24C 0.1953 0.0429 0.8009 0.107 Uiso calc R 1
N N1 0.52776(8) -0.0138(2) 0.84226(10) 0.0397(5) Uani d . 1
N N2 0.43478(8) 0.1141(2) 0.78861(10) 0.0367(5) Uani d . 1
O O1 0.33859(7) 0.08290(19) 0.71556(9) 0.0522(5) Uani d . 1
O O2 0.39817(7) 0.27419(19) 0.69314(8) 0.0490(5) Uani d . 1
S S1 0.37909(2) 0.18783(6) 0.74342(3) 0.03771(18) Uani d . 1
Cu Cu1 0.5000 0.08553(4) 0.7500 0.03548(16) Uani d S 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N1 C1 C2 . . 122.3(3) ?
N1 C1 H1 . . 118.8 ?
C2 C1 H1 . . 118.8 ?
C3 C2 C1 . . 119.2(3) ?
C3 C2 H2 . . 120.4 ?
C1 C2 H2 . . 120.4 ?
C2 C3 C4 . . 120.8(2) ?
C2 C3 H3 . . 119.6 ?
C4 C3 H3 . . 119.6 ?
C3 C4 C5 . . 125.2(2) ?
C3 C4 C9 . . 116.9(2) ?
C5 C4 C9 . . 117.9(2) ?
C6 C5 C4 . . 120.2(2) ?
C6 C5 H5 . . 119.9 ?
C4 C5 H5 . . 119.9 ?
C5 C6 C7 . . 122.0(2) ?
C5 C6 H6 . . 119.0 ?
C7 C6 H6 . . 119.0 ?
C8 C7 C6 . . 120.9(2) ?
C8 C7 H7 . . 119.5 ?
C6 C7 H7 . . 119.5 ?
C7 C8 N2 . . 128.9(2) ?
C7 C8 C9 . . 117.3(2) ?
N2 C8 C9 . . 113.75(19) ?
N1 C9 C4 . . 121.6(2) ?
N1 C9 C8 . . 116.7(2) ?
C4 C9 C8 . . 121.7(2) ?
C11 C10 C15 . . 120.5(2) ?
C11 C10 S1 . . 117.35(17) ?
C15 C10 S1 . . 122.10(17) ?
C12 C11 C10 . . 117.9(2) ?
C12 C11 C16 . . 116.0(2) ?
C10 C11 C16 . . 126.1(2) ?
C13 C12 C11 . . 123.6(2) ?
C13 C12 H12 . . 118.2 ?
C11 C12 H12 . . 118.2 ?
C12 C13 C14 . . 116.9(2) ?
C12 C13 C19 . . 120.1(2) ?
C14 C13 C19 . . 122.9(2) ?
C13 C14 C15 . . 123.9(2) ?
C13 C14 H14 . . 118.1 ?
C15 C14 H14 . . 118.1 ?
C14 C15 C10 . . 117.0(2) ?
C14 C15 C22 . . 116.8(2) ?
C10 C15 C22 . . 126.1(2) ?
C17 C16 C11 . . 112.6(2) ?
C17 C16 C18 . . 111.5(3) ?
C11 C16 C18 . . 109.2(2) ?
C17 C16 H16 . . 107.8 ?
C11 C16 H16 . . 107.8 ?
C18 C16 H16 . . 107.8 ?
C16 C17 H17A . . 109.5 ?
C16 C17 H17B . . 109.5 ?
H17A C17 H17B . . 109.5 ?
C16 C17 H17C . . 109.5 ?
H17A C17 H17C . . 109.5 ?
H17B C17 H17C . . 109.5 ?
C16 C18 H18A . . 109.5 ?
C16 C18 H18B . . 109.5 ?
H18A C18 H18B . . 109.5 ?
C16 C18 H18C . . 109.5 ?
H18A C18 H18C . . 109.5 ?
H18B C18 H18C . . 109.5 ?
C21 C19 C20 . . 114.1(3) ?
C21 C19 C13 . . 115.5(3) ?
C20 C19 C13 . . 110.8(3) ?
C21 C19 H19 . . 105.1 ?
C20 C19 H19 . . 105.1 ?
C13 C19 H19 . . 105.1 ?
C19 C20 H20A . . 109.5 ?
C19 C20 H20B . . 109.5 ?
H20A C20 H20B . . 109.5 ?
C19 C20 H20C . . 109.5 ?
H20A C20 H20C . . 109.5 ?
H20B C20 H20C . . 109.5 ?
C19 C21 H21A . . 109.5 ?
C19 C21 H21B . . 109.5 ?
H21A C21 H21B . . 109.5 ?
C19 C21 H21C . . 109.5 ?
H21A C21 H21C . . 109.5 ?
H21B C21 H21C . . 109.5 ?
C23 C22 C15 . . 109.3(2) ?
C23 C22 C24 . . 110.8(3) ?
C15 C22 C24 . . 113.7(2) ?
C23 C22 H22 . . 107.6 ?
C15 C22 H22 . . 107.6 ?
C24 C22 H22 . . 107.6 ?
C22 C23 H23A . . 109.5 ?
C22 C23 H23B . . 109.5 ?
H23A C23 H23B . . 109.5 ?
C22 C23 H23C . . 109.5 ?
H23A C23 H23C . . 109.5 ?
H23B C23 H23C . . 109.5 ?
C22 C24 H24A . . 109.5 ?
C22 C24 H24B . . 109.5 ?
H24A C24 H24B . . 109.5 ?
C22 C24 H24C . . 109.5 ?
H24A C24 H24C . . 109.5 ?
H24B C24 H24C . . 109.5 ?
C1 N1 C9 . . 119.1(2) ?
C1 N1 Cu1 . . 129.34(18) ?
C9 N1 Cu1 . . 110.56(15) ?
C8 N2 S1 . . 121.64(16) ?
C8 N2 Cu1 . . 113.54(14) ?
S1 N2 Cu1 . . 121.27(11) ?
O1 S1 O2 . . 115.79(11) ?
O1 S1 N2 . . 110.31(11) ?
O2 S1 N2 . . 105.21(10) ?
O1 S1 C10 . . 110.01(11) ?
O2 S1 C10 . . 109.64(11) ?
N2 S1 C10 . . 105.28(10) ?
N2 Cu1 N2 2_656 . 163.83(11) y
N2 Cu1 N1 2_656 2_656 82.25(8) ?
N2 Cu1 N1 . 2_656 105.39(8) y
N2 Cu1 N1 2_656 . 105.39(8) ?
N2 Cu1 N1 . . 82.25(8) y
N1 Cu1 N1 2_656 . 124.65(12) y
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 N1 . 1.318(3) ?
C1 C2 . 1.400(4) ?
C1 H1 . 0.9300 ?
C2 C3 . 1.354(4) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.396(4) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.404(4) ?
C4 C9 . 1.417(3) ?
C5 C6 . 1.352(4) ?
C5 H5 . 0.9300 ?
C6 C7 . 1.397(4) ?
C6 H6 . 0.9300 ?
C7 C8 . 1.377(3) ?
C7 H7 . 0.9300 ?
C8 N2 . 1.401(3) ?
C8 C9 . 1.420(3) ?
C9 N1 . 1.367(3) ?
C10 C11 . 1.409(3) ?
C10 C15 . 1.418(3) ?
C10 S1 . 1.797(2) ?
C11 C12 . 1.383(3) ?
C11 C16 . 1.525(3) ?
C12 C13 . 1.377(3) ?
C12 H12 . 0.9300 ?
C13 C14 . 1.377(4) ?
C13 C19 . 1.525(4) ?
C14 C15 . 1.394(3) ?
C14 H14 . 0.9300 ?
C15 C22 . 1.521(3) ?
C16 C17 . 1.504(4) ?
C16 C18 . 1.529(4) ?
C16 H16 . 0.9800 ?
C17 H17A . 0.9600 ?
C17 H17B . 0.9600 ?
C17 H17C . 0.9600 ?
C18 H18A . 0.9600 ?
C18 H18B . 0.9600 ?
C18 H18C . 0.9600 ?
C19 C21 . 1.472(4) ?
C19 C20 . 1.506(4) ?
C19 H19 . 0.9800 ?
C20 H20A . 0.9600 ?
C20 H20B . 0.9600 ?
C20 H20C . 0.9600 ?
C21 H21A . 0.9600 ?
C21 H21B . 0.9600 ?
C21 H21C . 0.9600 ?
C22 C23 . 1.500(4) ?
C22 C24 . 1.535(4) ?
C22 H22 . 0.9800 ?
C23 H23A . 0.9600 ?
C23 H23B . 0.9600 ?
C23 H23C . 0.9600 ?
C24 H24A . 0.9600 ?
C24 H24B . 0.9600 ?
C24 H24C . 0.9600 ?
N1 Cu1 . 2.0248(19) y
N2 S1 . 1.621(2) ?
N2 Cu1 . 1.9265(19) y
O1 S1 . 1.4292(18) ?
O2 S1 . 1.4326(17) ?
Cu1 N2 2_656 1.9265(19) ?
Cu1 N1 2_656 2.0248(19) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_4
_geom_torsion
N1 C1 C2 C3 . 0.8(5)
C1 C2 C3 C4 . -0.2(5)
C2 C3 C4 C5 . 178.3(3)
C2 C3 C4 C9 . -0.8(4)
C3 C4 C5 C6 . -178.3(3)
C9 C4 C5 C6 . 0.8(4)
C4 C5 C6 C7 . -0.3(4)
C5 C6 C7 C8 . -1.4(4)
C6 C7 C8 N2 . -177.5(2)
C6 C7 C8 C9 . 2.4(4)
C3 C4 C9 N1 . 1.3(4)
C5 C4 C9 N1 . -177.9(2)
C3 C4 C9 C8 . 179.4(2)
C5 C4 C9 C8 . 0.3(4)
C7 C8 C9 N1 . 176.4(2)
N2 C8 C9 N1 . -3.7(3)
C7 C8 C9 C4 . -1.8(3)
N2 C8 C9 C4 . 178.0(2)
C15 C10 C11 C12 . 4.5(3)
S1 C10 C11 C12 . -173.83(18)
C15 C10 C11 C16 . -173.1(2)
S1 C10 C11 C16 . 8.6(3)
C10 C11 C12 C13 . -2.7(4)
C16 C11 C12 C13 . 175.1(2)
C11 C12 C13 C14 . -0.9(4)
C11 C12 C13 C19 . -176.3(3)
C12 C13 C14 C15 . 2.9(4)
C19 C13 C14 C15 . 178.2(3)
C13 C14 C15 C10 . -1.2(4)
C13 C14 C15 C22 . -177.1(3)
C11 C10 C15 C14 . -2.7(3)
S1 C10 C15 C14 . 175.59(19)
C11 C10 C15 C22 . 172.8(2)
S1 C10 C15 C22 . -8.9(3)
C12 C11 C16 C17 . 63.0(3)
C10 C11 C16 C17 . -119.4(3)
C12 C11 C16 C18 . -61.3(3)
C10 C11 C16 C18 . 116.3(3)
C12 C13 C19 C21 . 169.5(3)
C14 C13 C19 C21 . -5.6(5)
C12 C13 C19 C20 . -58.8(4)
C14 C13 C19 C20 . 126.0(3)
C14 C15 C22 C23 . 88.9(3)
C10 C15 C22 C23 . -86.6(3)
C14 C15 C22 C24 . -35.5(4)
C10 C15 C22 C24 . 149.1(3)
C2 C1 N1 C9 . -0.3(4)
C2 C1 N1 Cu1 . -167.8(2)
C4 C9 N1 C1 . -0.7(4)
C8 C9 N1 C1 . -179.0(2)
C4 C9 N1 Cu1 . 168.93(18)
C8 C9 N1 Cu1 . -9.3(3)
C7 C8 N2 S1 . -5.3(3)
C9 C8 N2 S1 . 174.84(16)
C7 C8 N2 Cu1 . -164.3(2)
C9 C8 N2 Cu1 . 15.8(2)
C8 N2 S1 O1 . -57.4(2)
Cu1 N2 S1 O1 . 99.99(14)
C8 N2 S1 O2 . 177.06(17)
Cu1 N2 S1 O2 . -25.55(15)
C8 N2 S1 C10 . 61.3(2)
Cu1 N2 S1 C10 . -141.36(12)
C11 C10 S1 O1 . 176.62(18)
C15 C10 S1 O1 . -1.7(2)
C11 C10 S1 O2 . -54.9(2)
C15 C10 S1 O2 . 126.8(2)
C11 C10 S1 N2 . 57.8(2)
C15 C10 S1 N2 . -120.5(2)
C8 N2 Cu1 N2 2_656 -135.90(15)
S1 N2 Cu1 N2 2_656 65.01(11)
C8 N2 Cu1 N1 2_656 107.51(16)
S1 N2 Cu1 N1 2_656 -51.57(14)
C8 N2 Cu1 N1 . -16.38(16)
S1 N2 Cu1 N1 . -175.47(14)
C1 N1 Cu1 N2 2_656 -12.2(3)
C9 N1 Cu1 N2 2_656 179.48(15)
C1 N1 Cu1 N2 . -177.6(2)
C9 N1 Cu1 N2 . 14.04(16)
C1 N1 Cu1 N1 2_656 79.0(2)
C9 N1 Cu1 N1 2_656 -89.35(15)
