#------------------------------------------------------------------------------
#$Date: 2016-02-20 05:06:23 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176774 $
#$URL: svn://www.crystallography.net/cod/cif/2/20/91/2209108.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2209108
loop_
_publ_author_name
'S. Sugaleshini'
'D. Gayathri'
'D. Velmurugan'
'K. Ravikumar'
'A. R. Sureshbabu'
_publ_section_title
Acenapthene-2-spiro-5'-perhydrodipyrrolo[1,2-a;2',1'-c]pyrazine-6'-spiro-2''-acenapthene-1,1''-dione
_journal_coeditor_code           BT2082
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              o2432
_journal_page_last               o2434
_journal_paper_doi               10.1107/S1600536806017661
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          'C32 H26 N2 O2'
_chemical_formula_moiety         'C32 H26 N2 O2'
_chemical_formula_sum            'C32 H26 N2 O2'
_chemical_formula_weight         470.55
_chemical_name_systematic
;
Acenapthene-2-spiro-5'-perhydrodipyrrole[1,2-a;2',1'-c]pyrazine-6'-
spiro-2''-acenapthene-1,1''-dione
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                109.4180(10)
_cell_angle_beta                 100.5840(10)
_cell_angle_gamma                102.4470(10)
_cell_formula_units_Z            2
_cell_length_a                   8.8721(7)
_cell_length_b                   10.7042(8)
_cell_length_c                   14.2846(11)
_cell_measurement_reflns_used    2635
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      1.57
_cell_volume                     1200.38(16)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        SAINT
_computing_molecular_graphics
;
PLATON (Spek, 1990)
;
_computing_publication_material  'SHELXL97 and PARST (Nardelli, 1995)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.997
_diffrn_measured_fraction_theta_max 0.945
_diffrn_measurement_device       'Bruker SMART APEX'
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area detector'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0179
_diffrn_reflns_av_sigmaI/netI    0.0204
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       18
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            13844
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         27.98
_diffrn_reflns_theta_min         1.57
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.081
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.302
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             496
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.23
_exptl_crystal_size_min          0.21
_refine_diff_density_max         0.295
_refine_diff_density_min         -0.186
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.024
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     325
_refine_ls_number_reflns         5468
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.024
_refine_ls_R_factor_all          0.0522
_refine_ls_R_factor_gt           0.0453
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0680P)²+0.2170P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1220
_refine_ls_wR_factor_ref         0.1283
_reflns_number_gt                4621
_reflns_number_total             5468
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            bt2082.cif
_cod_data_source_block           I
_cod_original_cell_volume        1200.37(16)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               2209108
_cod_database_fobs_code          2209108
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
N N1 1.20128(12) 0.73893(11) 0.34162(8) 0.0405(2) Uani d . 1
N N2 0.88722(12) 0.56861(10) 0.26268(8) 0.0388(2) Uani d . 1
O O1 0.93123(13) 0.83443(10) 0.44283(7) 0.0528(3) Uani d . 1
O O2 1.12021(13) 0.55941(9) 0.11471(7) 0.0524(3) Uani d . 1
C C1 0.88698(14) 0.81798(12) 0.35332(9) 0.0384(3) Uani d . 1
C C2 0.78277(14) 0.88773(12) 0.30958(10) 0.0399(3) Uani d . 1
C C3 0.72907(17) 0.99867(14) 0.35429(12) 0.0490(3) Uani d . 1
H H3 0.7625 1.0491 0.4253 0.059 Uiso calc R 1
C C4 0.62161(18) 1.03264(15) 0.28818(14) 0.0572(4) Uani d . 1
H H4 0.5858 1.1084 0.3167 0.069 Uiso calc R 1
C C5 0.56748(18) 0.95874(16) 0.18340(13) 0.0565(4) Uani d . 1
H H5 0.4949 0.9843 0.1432 0.068 Uiso calc R 1
C C6 0.62052(15) 0.84406(14) 0.13558(11) 0.0467(3) Uani d . 1
C C7 0.57400(17) 0.75505(16) 0.02976(12) 0.0541(4) Uani d . 1
H H7 0.4995 0.7692 -0.0176 0.065 Uiso calc R 1
C C8 0.63816(17) 0.64832(16) -0.00299(11) 0.0525(3) Uani d . 1
H H8 0.6053 0.5908 -0.0727 0.063 Uiso calc R 1
C C9 0.75307(16) 0.62217(14) 0.06551(10) 0.0441(3) Uani d . 1
H H9 0.7950 0.5490 0.0411 0.053 Uiso calc R 1
C C10 0.80085(14) 0.70636(12) 0.16782(9) 0.0366(3) Uani d . 1
C C11 0.73210(14) 0.81465(12) 0.20214(10) 0.0387(3) Uani d . 1
C C12 0.91854(14) 0.70607(12) 0.25984(8) 0.0348(2) Uani d . 1
C C13 1.09847(14) 0.75716(12) 0.25847(8) 0.0350(2) Uani d . 1
C C14 1.14204(14) 0.90671(12) 0.26590(9) 0.0374(3) Uani d . 1
C C15 1.16731(16) 1.02998(13) 0.34522(10) 0.0463(3) Uani d . 1
H H15 1.1642 1.0329 0.4106 0.056 Uiso calc R 1
C C16 1.19837(18) 1.15353(15) 0.32628(13) 0.0562(4) Uani d . 1
H H16 1.2150 1.2374 0.3804 0.067 Uiso calc R 1
C C17 1.20488(19) 1.15439(15) 0.23167(13) 0.0571(4) Uani d . 1
H H17 1.2241 1.2376 0.2222 0.069 Uiso calc R 1
C C18 1.18233(16) 1.02853(14) 0.14794(11) 0.0467(3) Uani d . 1
C C19 1.18662(18) 1.00925(17) 0.04555(12) 0.0563(4) Uani d . 1
H H19 1.2033 1.0854 0.0269 0.068 Uiso calc R 1
C C20 1.16662(19) 0.88028(17) -0.02647(12) 0.0567(4) Uani d . 1
H H20 1.1695 0.8715 -0.0931 0.068 Uiso calc R 1
C C21 1.14197(17) 0.76071(15) -0.00353(10) 0.0486(3) Uani d . 1
H H21 1.1307 0.6743 -0.0531 0.058 Uiso calc R 1
C C22 1.13520(14) 0.77648(13) 0.09519(9) 0.0398(3) Uani d . 1
C C23 1.15329(14) 0.90764(13) 0.16880(9) 0.0385(3) Uani d . 1
C C24 1.11555(14) 0.67750(12) 0.14728(9) 0.0384(3) Uani d . 1
C C25 1.37471(17) 0.78453(17) 0.35572(12) 0.0556(4) Uani d . 1
H H25A 1.4160 0.8850 0.3831 0.067 Uiso calc R 1
H H25B 1.4009 0.7464 0.2911 0.067 Uiso calc R 1
C C26 1.4416(2) 0.7268(2) 0.43320(14) 0.0721(5) Uani d . 1
H H26A 1.5237 0.6857 0.4127 0.086 Uiso calc R 1
H H26B 1.4882 0.7999 0.5016 0.086 Uiso calc R 1
C C27 1.2991(2) 0.61722(19) 0.43276(13) 0.0660(4) Uani d . 1
H H27A 1.3244 0.5310 0.4241 0.079 Uiso calc R 1
H H27B 1.2691 0.6489 0.4966 0.079 Uiso calc R 1
C C28 1.16447(17) 0.59791(14) 0.34102(10) 0.0457(3) Uani d . 1
H H28 1.1757 0.5334 0.2773 0.055 Uiso calc R 1
C C29 0.99523(17) 0.55459(14) 0.34736(10) 0.0447(3) Uani d . 1
H H29 0.9865 0.6143 0.4138 0.054 Uiso calc R 1
C C30 0.9210(2) 0.40269(16) 0.32806(13) 0.0609(4) Uani d . 1
H H30A 0.9432 0.3874 0.3918 0.073 Uiso calc R 1
H H30B 0.9623 0.3427 0.2786 0.073 Uiso calc R 1
C C31 0.7407(2) 0.37578(18) 0.28484(14) 0.0669(4) Uani d . 1
H H31A 0.6971 0.2928 0.2218 0.080 Uiso calc R 1
H H31B 0.6838 0.3642 0.3347 0.080 Uiso calc R 1
C C32 0.72517(18) 0.50312(15) 0.26331(12) 0.0546(3) Uani d . 1
H H32A 0.6484 0.4769 0.1971 0.065 Uiso calc R 1
H H32B 0.6919 0.5646 0.3170 0.065 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C13 N1 C25 117.00(10) y
C13 N1 C28 116.00(10) y
C25 N1 C28 105.90(10) y
C12 N2 C32 116.80(10) y
C12 N2 C29 116.30(10) y
C32 N2 C29 105.20(10) y
O1 C1 C2 127.02(11) ?
O1 C1 C12 125.08(11) ?
C2 C1 C12 107.69(10) ?
C3 C2 C11 120.15(12) ?
C3 C2 C1 132.65(12) ?
C11 C2 C1 107.16(10) ?
C2 C3 C4 117.31(13) ?
C2 C3 H3 121.3 ?
C4 C3 H3 121.3 ?
C5 C4 C3 122.81(13) ?
C5 C4 H4 118.6 ?
C3 C4 H4 118.6 ?
C4 C5 C6 120.96(13) ?
C4 C5 H5 119.5 ?
C6 C5 H5 119.5 ?
C11 C6 C5 115.48(13) ?
C11 C6 C7 116.29(12) ?
C5 C6 C7 128.22(13) ?
C8 C7 C6 120.25(12) ?
C8 C7 H7 119.9 ?
C6 C7 H7 119.9 ?
C7 C8 C9 122.44(13) ?
C7 C8 H8 118.8 ?
C9 C8 H8 118.8 ?
C10 C9 C8 118.73(12) ?
C10 C9 H9 120.6 ?
C8 C9 H9 120.6 ?
C9 C10 C11 118.91(11) ?
C9 C10 C12 131.78(11) ?
C11 C10 C12 109.29(10) ?
C2 C11 C6 123.19(12) ?
C2 C11 C10 113.46(11) ?
C6 C11 C10 123.33(12) ?
N2 C12 C10 111.23(9) ?
N2 C12 C13 108.82(9) ?
C10 C12 C13 111.92(9) ?
N2 C12 C1 114.08(9) ?
C10 C12 C1 101.44(9) ?
C13 C12 C1 109.24(9) ?
N1 C13 C14 112.79(9) ?
N1 C13 C12 108.39(9) ?
C14 C13 C12 110.81(9) ?
N1 C13 C24 114.08(9) ?
C14 C13 C24 101.22(9) ?
C12 C13 C24 109.41(9) ?
C15 C14 C23 118.67(12) ?
C15 C14 C13 132.18(11) ?
C23 C14 C13 109.14(10) ?
C14 C15 C16 118.85(13) ?
C14 C15 H15 120.6 ?
C16 C15 H15 120.6 ?
C17 C16 C15 122.61(13) ?
C17 C16 H16 118.7 ?
C15 C16 H16 118.7 ?
C16 C17 C18 120.09(13) ?
C16 C17 H17 120.0 ?
C18 C17 H17 120.0 ?
C23 C18 C19 115.62(13) ?
C23 C18 C17 116.28(13) ?
C19 C18 C17 128.11(13) ?
C20 C19 C18 121.14(13) ?
C20 C19 H19 119.4 ?
C18 C19 H19 119.4 ?
C19 C20 C21 122.53(13) ?
C19 C20 H20 118.7 ?
C21 C20 H20 118.7 ?
C22 C21 C20 117.43(13) ?
C22 C21 H21 121.3 ?
C20 C21 H21 121.3 ?
C21 C22 C23 120.36(12) ?
C21 C22 C24 132.56(12) ?
C23 C22 C24 107.05(10) ?
C22 C23 C18 122.89(12) ?
C22 C23 C14 113.65(11) ?
C18 C23 C14 123.45(12) ?
O2 C24 C22 127.00(11) ?
O2 C24 C13 125.01(11) ?
C22 C24 C13 107.88(10) ?
N1 C25 C26 103.03(12) ?
N1 C25 H25A 111.2 ?
C26 C25 H25A 111.2 ?
N1 C25 H25B 111.2 ?
C26 C25 H25B 111.2 ?
H25A C25 H25B 109.1 ?
C27 C26 C25 105.89(12) ?
C27 C26 H26A 110.6 ?
C25 C26 H26A 110.6 ?
C27 C26 H26B 110.6 ?
C25 C26 H26B 110.6 ?
H26A C26 H26B 108.7 ?
C28 C27 C26 104.57(12) ?
C28 C27 H27A 110.8 ?
C26 C27 H27A 110.8 ?
C28 C27 H27B 110.8 ?
C26 C27 H27B 110.8 ?
H27A C27 H27B 108.9 ?
N1 C28 C29 108.90(10) ?
N1 C28 C27 101.02(11) ?
C29 C28 C27 117.20(12) ?
N1 C28 H28 109.8 ?
C29 C28 H28 109.8 ?
C27 C28 H28 109.8 ?
N2 C29 C28 108.59(10) ?
N2 C29 C30 101.03(11) ?
C28 C29 C30 117.76(12) ?
N2 C29 H29 109.7 ?
C28 C29 H29 109.7 ?
C30 C29 H29 109.7 ?
C29 C30 C31 104.25(12) ?
C29 C30 H30A 110.9 ?
C31 C30 H30A 110.9 ?
C29 C30 H30B 110.9 ?
C31 C30 H30B 110.9 ?
H30A C30 H30B 108.9 ?
C32 C31 C30 105.51(12) ?
C32 C31 H31A 110.6 ?
C30 C31 H31A 110.6 ?
C32 C31 H31B 110.6 ?
C30 C31 H31B 110.6 ?
H31A C31 H31B 108.8 ?
N2 C32 C31 103.42(12) ?
N2 C32 H32A 111.1 ?
C31 C32 H32A 111.1 ?
N2 C32 H32B 111.1 ?
C31 C32 H32B 111.1 ?
H32A C32 H32B 109.0 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
N1 C13 1.4540(10) y
N1 C25 1.464(2) y
N1 C28 1.471(2) y
N2 C12 1.453(2) y
N2 C32 1.461(2) y
N2 C29 1.470(2) y
O1 C1 1.207(2) y
O2 C24 1.206(2) y
C1 C2 1.4826(17) ?
C1 C12 1.586(2) y
C2 C3 1.3772(17) ?
C2 C11 1.4021(18) ?
C3 C4 1.407(2) ?
C3 H3 0.9300 ?
C4 C5 1.372(2) ?
C4 H4 0.9300 ?
C5 C6 1.416(2) ?
C5 H5 0.9300 ?
C6 C11 1.4038(17) ?
C6 C7 1.417(2) ?
C7 C8 1.368(2) ?
C7 H7 0.9300 ?
C8 C9 1.4190(18) ?
C8 H8 0.9300 ?
C9 C10 1.3638(17) ?
C9 H9 0.9300 ?
C10 C11 1.4117(16) ?
C10 C12 1.522(2) y
C12 C13 1.578(2) y
C13 C14 1.526(2) y
C13 C24 1.586(2) y
C14 C15 1.3638(17) ?
C14 C23 1.4119(17) ?
C15 C16 1.417(2) ?
C15 H15 0.9300 ?
C16 C17 1.366(2) ?
C16 H16 0.9300 ?
C17 C18 1.418(2) ?
C17 H17 0.9300 ?
C18 C23 1.4037(18) ?
C18 C19 1.416(2) ?
C19 C20 1.371(2) ?
C19 H19 0.9300 ?
C20 C21 1.406(2) ?
C20 H20 0.9300 ?
C21 C22 1.3777(17) ?
C21 H21 0.9300 ?
C22 C23 1.4006(17) ?
C22 C24 1.4828(17) ?
C25 C26 1.526(2) ?
C25 H25A 0.9700 ?
C25 H25B 0.9700 ?
C26 C27 1.526(3) ?
C26 H26A 0.9700 ?
C26 H26B 0.9700 ?
C27 C28 1.5247(19) ?
C27 H27A 0.9700 ?
C27 H27B 0.9700 ?
C28 C29 1.5019(19) y
C28 H28 0.9800 ?
C29 C30 1.5254(19) ?
C29 H29 0.9800 ?
C30 C31 1.531(2) ?
C30 H30A 0.9700 ?
C30 H30B 0.9700 ?
C31 C32 1.522(2) ?
C31 H31A 0.9700 ?
C31 H31B 0.9700 ?
C32 H32A 0.9700 ?
C32 H32B 0.9700 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C28 H28 O2 . 0.98 2.41 3.058(2) 124
C29 H29 O1 . 0.98 2.43 3.075(2) 123
C9 H9 O2 2_765 0.93 2.48 3.217(2) 136
C15 H15 O1 2_776 0.93 2.51 3.261(2) 138
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
_geom_torsion_publ_flag
O1 C1 C2 C3 11.1(2) ?
C12 C1 C2 C3 -173.99(13) ?
O1 C1 C2 C11 -166.31(13) ?
C12 C1 C2 C11 8.62(13) ?
C11 C2 C3 C4 0.85(19) ?
C1 C2 C3 C4 -176.27(13) ?
C2 C3 C4 C5 1.3(2) ?
C3 C4 C5 C6 -1.2(2) ?
C4 C5 C6 C11 -1.1(2) ?
C4 C5 C6 C7 178.22(14) ?
C11 C6 C7 C8 -0.66(19) ?
C5 C6 C7 C8 -179.94(14) ?
C6 C7 C8 C9 -0.5(2) ?
C7 C8 C9 C10 0.2(2) ?
C8 C9 C10 C11 1.19(18) ?
C8 C9 C10 C12 179.50(12) ?
C3 C2 C11 C6 -3.29(19) ?
C1 C2 C11 C6 174.49(11) ?
C3 C2 C11 C10 178.34(11) ?
C1 C2 C11 C10 -3.88(14) ?
C5 C6 C11 C2 3.31(18) ?
C7 C6 C11 C2 -176.06(12) ?
C5 C6 C11 C10 -178.48(12) ?
C7 C6 C11 C10 2.15(18) ?
C9 C10 C11 C2 175.91(11) ?
C12 C10 C11 C2 -2.75(14) ?
C9 C10 C11 C6 -2.46(18) ?
C12 C10 C11 C6 178.88(11) ?
C32 N2 C12 C10 -55.69(13) ?
C29 N2 C12 C10 178.97(9) ?
C32 N2 C12 C13 -179.43(10) ?
C29 N2 C12 C13 55.20(10) y
C32 N2 C12 C1 58.31(14) ?
C29 N2 C12 C1 -67.03(13) ?
C9 C10 C12 N2 -49.21(17) ?
C11 C10 C12 N2 129.22(10) ?
C9 C10 C12 C13 72.76(16) ?
C11 C10 C12 C13 -108.82(11) ?
C9 C10 C12 C1 -170.89(13) ?
C11 C10 C12 C1 7.53(12) ?
O1 C1 C12 N2 45.67(16) ?
C2 C1 C12 N2 -129.39(10) ?
O1 C1 C12 C10 165.34(12) ?
C2 C1 C12 C10 -9.71(12) ?
O1 C1 C12 C13 -76.36(15) ?
C2 C1 C12 C13 108.59(10) ?
C25 N1 C13 C14 -55.07(14) ?
C28 N1 C13 C14 178.73(9) ?
C25 N1 C13 C12 -178.14(10) ?
C28 N1 C13 C12 55.70(10) y
C25 N1 C13 C24 59.71(14) ?
C28 N1 C13 C24 -66.49(13) ?
N2 C12 C13 N1 -50.30(10) y
C10 C12 C13 N1 -173.64(9) ?
C1 C12 C13 N1 74.84(11) ?
N2 C12 C13 C14 -174.57(9) ?
C10 C12 C13 C14 62.09(12) ?
C1 C12 C13 C14 -49.43(12) ?
N2 C12 C13 C24 74.66(11) ?
C10 C12 C13 C24 -48.67(12) ?
C1 C12 C13 C24 -160.20(9) ?
N1 C13 C14 C15 -49.91(17) ?
C12 C13 C14 C15 71.81(16) ?
C24 C13 C14 C15 -172.23(13) ?
N1 C13 C14 C23 131.25(10) ?
C12 C13 C14 C23 -107.04(10) ?
C24 C13 C14 C23 8.92(12) ?
C23 C14 C15 C16 2.14(19) ?
C13 C14 C15 C16 -176.62(12) ?
C14 C15 C16 C17 -0.3(2) ?
C15 C16 C17 C18 -0.9(2) ?
C16 C17 C18 C23 0.2(2) ?
C16 C17 C18 C19 -179.22(14) ?
C23 C18 C19 C20 -1.3(2) ?
C17 C18 C19 C20 178.20(15) ?
C18 C19 C20 C21 -0.4(2) ?
C19 C20 C21 C22 1.2(2) ?
C20 C21 C22 C23 -0.31(19) ?
C20 C21 C22 C24 -178.21(13) ?
C21 C22 C23 C18 -1.46(19) ?
C24 C22 C23 C18 176.92(11) ?
C21 C22 C23 C14 179.47(11) ?
C24 C22 C23 C14 -2.15(14) ?
C19 C18 C23 C22 2.21(18) ?
C17 C18 C23 C22 -177.32(12) ?
C19 C18 C23 C14 -178.82(12) ?
C17 C18 C23 C14 1.65(19) ?
C15 C14 C23 C22 176.17(11) ?
C13 C14 C23 C22 -4.81(14) ?
C15 C14 C23 C18 -2.89(18) ?
C13 C14 C23 C18 176.14(11) ?
C21 C22 C24 O2 9.8(2) ?
C23 C22 C24 O2 -168.33(13) ?
C21 C22 C24 C13 -173.98(13) ?
C23 C22 C24 C13 7.91(13) ?
N1 C13 C24 O2 44.79(17) ?
C14 C13 C24 O2 166.21(12) ?
C12 C13 C24 O2 -76.80(15) ?
N1 C13 C24 C22 -131.55(10) ?
C14 C13 C24 C22 -10.13(12) ?
C12 C13 C24 C22 106.87(10) ?
C13 N1 C25 C26 -169.92(12) ?
C28 N1 C25 C26 -38.86(14) ?
N1 C25 C26 C27 16.49(17) ?
C25 C26 C27 C28 10.32(18) ?
C13 N1 C28 C29 -59.10(10) y
C25 N1 C28 C29 169.22(10) ?
C13 N1 C28 C27 176.89(11) ?
C25 N1 C28 C27 45.24(13) ?
C26 C27 C28 N1 -32.95(15) ?
C26 C27 C28 C29 -151.05(13) ?
C12 N2 C29 C28 -58.30(10) y
C32 N2 C29 C28 170.65(11) ?
C12 N2 C29 C30 177.20(10) ?
C32 N2 C29 C30 46.17(13) ?
N1 C28 C29 N2 55.10(10) y
C27 C28 C29 N2 168.90(12) ?
N1 C28 C29 C30 169.03(11) ?
C27 C28 C29 C30 -77.21(17) ?
N2 C29 C30 C31 -33.49(14) ?
C28 C29 C30 C31 -151.49(13) ?
C29 C30 C31 C32 10.17(17) ?
C12 N2 C32 C31 -170.69(11) ?
C29 N2 C32 C31 -39.96(14) ?
C30 C31 C32 N2 17.29(16) ?
