#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/00/2210001.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2210001
loop_
_publ_author_name
'Elsegood, Mark R. J.'
'Smith, Martin B.'
'Dale, Sophie H.'
_publ_section_title
;
 [2-(Diphenylphosphino-κP)benzaldehyde]gold(I) chloride
;
_journal_coeditor_code           SG2043
_journal_issue                   8
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1850
_journal_page_last               m1852
_journal_paper_doi               10.1107/S1600536806026432
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Au Cl (C19 H15 O P)]'
_chemical_formula_moiety         'C19 H15 Au Cl O P'
_chemical_formula_sum            'C19 H15 Au Cl O P'
_chemical_formula_weight         522.70
_chemical_name_systematic
;
[2-(Diphenylphosphino-\kP)benzaldehyde]gold(I) chloride
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                97.1857(7)
_cell_angle_beta                 103.5519(9)
_cell_angle_gamma                101.4375(9)
_cell_formula_units_Z            4
_cell_length_a                   10.2431(2)
_cell_length_b                   10.4949(2)
_cell_length_c                   16.6533(3)
_cell_measurement_reflns_used    61735
_cell_measurement_temperature    120(2)
_cell_measurement_theta_max      27.48
_cell_measurement_theta_min      2.91
_cell_volume                     1677.96(6)
_computing_cell_refinement       'DENZO and COLLECT'
_computing_data_collection
'DENZO (Otwinowski & Minor, 1997) and COLLECT (Nonius, 1998)'
_computing_data_reduction        'DENZO and COLLECT'
_computing_molecular_graphics    SHELXTL
_computing_publication_material  'SHELXTL and local programs'
_computing_structure_refinement  SHELXTL
_computing_structure_solution    'SHELXTL (Bruker, 2000)'
_diffrn_ambient_temperature      120(2)
_diffrn_detector_area_resol_mean 9.091
_diffrn_measured_fraction_theta_full 0.980
_diffrn_measured_fraction_theta_max 0.980
_diffrn_measurement_device_type  'Bruker Nonius KappaCCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  '10cm confocal mirrors'
_diffrn_radiation_source         'Enraf Nonius FR591 rotating anode'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0625
_diffrn_reflns_av_sigmaI/netI    0.0412
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -13
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -21
_diffrn_reflns_number            29712
_diffrn_reflns_theta_full        27.69
_diffrn_reflns_theta_max         27.69
_diffrn_reflns_theta_min         2.94
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    9.023
_exptl_absorpt_correction_T_max  0.697
_exptl_absorpt_correction_T_min  0.128
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details
;
using multiple and symmetry-related data measurements
(SORTAV; Blessing, 1995)
;
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.069
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       'thick plate'
_exptl_crystal_F_000             992
_exptl_crystal_size_max          0.25
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.04
_refine_diff_density_max         3.099
_refine_diff_density_min         -1.399
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.055
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     415
_refine_ls_number_reflns         7704
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.055
_refine_ls_R_factor_all          0.0422
_refine_ls_R_factor_gt           0.0373
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0588P)²+5.6P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0971
_refine_ls_wR_factor_ref         0.1002
_reflns_number_gt                6936
_reflns_number_total             7704
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            sg2043.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (12
times).

'_geom_angle_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (2 times).

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (12
times).

'_geom_angle_publ_flag' value 'Y' changed to 'y' according
to /home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary
named 'cif_core.dic' version 2.4.1 from 2010-06-29 (2 times).

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2210001
_cod_database_fobs_code          2210001
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Au Au1 0.69934(2) 0.116173(19) 0.424881(11) 0.01437(7) Uani d . 1
Cl Cl1 0.65437(14) 0.03133(14) 0.28557(8) 0.0213(3) Uani d . 1
P P1 0.73885(14) 0.19673(13) 0.56099(8) 0.0134(3) Uani d . 1
C C1 0.8005(5) 0.0849(5) 0.6285(3) 0.0148(10) Uani d . 1
C C2 0.7170(6) 0.0265(5) 0.6749(3) 0.0159(10) Uani d . 1
H H2 0.6295 0.0461 0.6716 0.019 Uiso calc R 1
C C3 0.7597(6) -0.0604(5) 0.7263(3) 0.0201(11) Uani d . 1
H H3 0.7004 -0.1005 0.7569 0.024 Uiso calc R 1
C C4 0.8878(6) -0.0890(6) 0.7333(4) 0.0225(12) Uani d . 1
H H4 0.9180 -0.1464 0.7696 0.027 Uiso calc R 1
C C5 0.9703(6) -0.0332(5) 0.6869(4) 0.0191(11) Uani d . 1
H H5 1.0577 -0.0533 0.6908 0.023 Uiso calc R 1
C C6 0.9285(6) 0.0528(5) 0.6339(3) 0.0170(10) Uani d . 1
C C7 1.0229(6) 0.1008(5) 0.5849(3) 0.0183(11) Uani d . 1
H H7 1.1072 0.0731 0.5933 0.022 Uiso calc R 1
O O1 1.0025(4) 0.1729(4) 0.5346(2) 0.0205(8) Uani d . 1
C C8 0.5803(6) 0.2252(5) 0.5844(3) 0.0163(10) Uani d . 1
C C9 0.4615(6) 0.1980(5) 0.5197(3) 0.0184(11) Uani d . 1
H H9 0.4607 0.1564 0.4655 0.022 Uiso calc R 1
C C10 0.3421(6) 0.2316(6) 0.5336(4) 0.0245(12) Uani d . 1
H H10 0.2603 0.2129 0.4888 0.029 Uiso calc R 1
C C11 0.3431(6) 0.2918(6) 0.6123(4) 0.0217(12) Uani d . 1
H H11 0.2625 0.3157 0.6217 0.026 Uiso calc R 1
C C12 0.4626(6) 0.3173(6) 0.6780(4) 0.0202(11) Uani d . 1
H H12 0.4630 0.3574 0.7325 0.024 Uiso calc R 1
C C13 0.5815(6) 0.2844(5) 0.6641(3) 0.0182(11) Uani d . 1
H H13 0.6632 0.3023 0.7089 0.022 Uiso calc R 1
C C14 0.8589(5) 0.3577(5) 0.6010(3) 0.0156(10) Uani d . 1
C C15 0.8508(6) 0.4559(6) 0.5518(4) 0.0212(11) Uani d . 1
H H15 0.7859 0.4366 0.4982 0.025 Uiso calc R 1
C C16 0.9366(7) 0.5807(6) 0.5808(4) 0.0271(13) Uani d . 1
H H16 0.9299 0.6473 0.5473 0.032 Uiso calc R 1
C C17 1.0325(6) 0.6093(6) 0.6586(4) 0.0248(12) Uani d . 1
H H17 1.0924 0.6948 0.6782 0.030 Uiso calc R 1
C C18 1.0402(6) 0.5130(6) 0.7074(4) 0.0232(12) Uani d . 1
H H18 1.1059 0.5326 0.7608 0.028 Uiso calc R 1
C C19 0.9529(6) 0.3871(6) 0.6796(4) 0.0205(11) Uani d . 1
H H19 0.9577 0.3218 0.7143 0.025 Uiso calc R 1
Au Au2 1.02900(2) 0.690763(19) 0.904323(12) 0.01608(7) Uani d . 1
Cl Cl2 1.24726(15) 0.77100(15) 0.89367(9) 0.0260(3) Uani d . 1
P P2 0.81313(14) 0.61296(13) 0.91035(8) 0.0144(3) Uani d . 1
C C20 0.7804(5) 0.6774(5) 1.0097(3) 0.0146(10) Uani d . 1
C C21 0.7514(6) 0.5895(5) 1.0624(4) 0.0182(11) Uani d . 1
H H21 0.7419 0.4978 1.0447 0.022 Uiso calc R 1
C C22 0.7360(6) 0.6354(6) 1.1419(4) 0.0222(12) Uani d . 1
H H22 0.7164 0.5743 1.1775 0.027 Uiso calc R 1
C C23 0.7489(6) 0.7667(6) 1.1685(4) 0.0218(11) Uani d . 1
H H23 0.7374 0.7969 1.2220 0.026 Uiso calc R 1
C C24 0.7788(6) 0.8559(6) 1.1167(4) 0.0210(11) Uani d . 1
H H24 0.7892 0.9475 1.1355 0.025 Uiso calc R 1
C C25 0.7937(6) 0.8128(5) 1.0380(3) 0.0179(11) Uani d . 1
C C26 0.8287(6) 0.9151(6) 0.9893(4) 0.0229(12) Uani d . 1
H H26 0.8349 1.0040 1.0130 0.027 Uiso calc R 1
O O2 0.8505(4) 0.8949(4) 0.9205(3) 0.0248(9) Uani d . 1
C C27 0.7707(6) 0.4343(5) 0.9010(3) 0.0161(10) Uani d . 1
C C28 0.6382(6) 0.3653(6) 0.8953(3) 0.0193(11) Uani d . 1
H H28 0.5688 0.4120 0.8991 0.023 Uiso calc R 1
C C29 0.6054(7) 0.2272(6) 0.8841(4) 0.0238(12) Uani d . 1
H H29 0.5147 0.1802 0.8816 0.029 Uiso calc R 1
C C30 0.7064(6) 0.1600(5) 0.8768(4) 0.0228(12) Uani d . 1
H H30 0.6845 0.0662 0.8692 0.027 Uiso calc R 1
C C31 0.8379(6) 0.2264(6) 0.8803(4) 0.0239(12) Uani d . 1
H H31 0.9055 0.1788 0.8735 0.029 Uiso calc R 1
C C32 0.8715(6) 0.3641(6) 0.8938(3) 0.0188(11) Uani d . 1
H H32 0.9632 0.4105 0.8983 0.023 Uiso calc R 1
C C33 0.6813(5) 0.6367(5) 0.8240(3) 0.0160(10) Uani d . 1
C C34 0.5582(6) 0.6684(6) 0.8326(4) 0.0210(11) Uani d . 1
H H34 0.5423 0.6830 0.8866 0.025 Uiso calc R 1
C C35 0.4597(6) 0.6786(6) 0.7625(4) 0.0246(12) Uani d . 1
H H35 0.3773 0.7024 0.7685 0.030 Uiso calc R 1
C C36 0.4815(6) 0.6542(6) 0.6840(4) 0.0230(12) Uani d . 1
H H36 0.4138 0.6613 0.6360 0.028 Uiso calc R 1
C C37 0.6008(6) 0.6195(6) 0.6745(3) 0.0214(11) Uani d . 1
H H37 0.6135 0.6009 0.6200 0.026 Uiso calc R 1
C C38 0.7025(6) 0.6114(5) 0.7442(4) 0.0207(11) Uani d . 1
H H38 0.7853 0.5891 0.7377 0.025 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
P1 Au1 Cl1 178.79(5) y
C14 P1 C1 106.5(2) ?
C14 P1 C8 102.6(2) ?
C1 P1 C8 106.9(2) ?
C14 P1 Au1 116.77(18) ?
C1 P1 Au1 112.69(17) ?
C8 P1 Au1 110.53(18) ?
C2 C1 C6 118.3(5) ?
C2 C1 P1 119.2(4) ?
C6 C1 P1 122.5(4) ?
C1 C2 C3 120.9(5) ?
C1 C2 H2 119.5 ?
C3 C2 H2 119.5 ?
C4 C3 C2 120.6(5) ?
C4 C3 H3 119.7 ?
C2 C3 H3 119.7 ?
C5 C4 C3 118.9(5) ?
C5 C4 H4 120.5 ?
C3 C4 H4 120.5 ?
C4 C5 C6 121.4(5) ?
C4 C5 H5 119.3 ?
C6 C5 H5 119.3 ?
C5 C6 C1 119.9(5) ?
C5 C6 C7 116.0(5) ?
C1 C6 C7 124.0(5) ?
O1 C7 C6 125.3(5) ?
O1 C7 H7 117.4 ?
C6 C7 H7 117.4 ?
C9 C8 C13 120.1(5) ?
C9 C8 P1 118.6(4) ?
C13 C8 P1 121.0(4) ?
C8 C9 C10 120.2(5) ?
C8 C9 H9 119.9 ?
C10 C9 H9 119.9 ?
C11 C10 C9 120.0(5) ?
C11 C10 H10 120.0 ?
C9 C10 H10 120.0 ?
C10 C11 C12 119.8(5) ?
C10 C11 H11 120.1 ?
C12 C11 H11 120.1 ?
C11 C12 C13 120.2(5) ?
C11 C12 H12 119.9 ?
C13 C12 H12 119.9 ?
C8 C13 C12 119.8(5) ?
C8 C13 H13 120.1 ?
C12 C13 H13 120.1 ?
C19 C14 C15 119.4(5) ?
C19 C14 P1 122.3(4) ?
C15 C14 P1 118.2(4) ?
C16 C15 C14 120.3(6) ?
C16 C15 H15 119.9 ?
C14 C15 H15 119.9 ?
C15 C16 C17 120.2(5) ?
C15 C16 H16 119.9 ?
C17 C16 H16 119.9 ?
C18 C17 C16 119.6(5) ?
C18 C17 H17 120.2 ?
C16 C17 H17 120.2 ?
C17 C18 C19 120.9(6) ?
C17 C18 H18 119.6 ?
C19 C18 H18 119.6 ?
C14 C19 C18 119.6(5) ?
C14 C19 H19 120.2 ?
C18 C19 H19 120.2 ?
P2 Au2 Cl2 178.12(5) y
C33 P2 C27 101.7(2) ?
C33 P2 C20 109.0(2) ?
C27 P2 C20 105.5(2) ?
C33 P2 Au2 114.41(18) ?
C27 P2 Au2 112.05(18) ?
C20 P2 Au2 113.34(18) ?
C21 C20 C25 118.2(5) ?
C21 C20 P2 118.3(4) ?
C25 C20 P2 123.3(4) ?
C20 C21 C22 120.4(5) ?
C20 C21 H21 119.8 ?
C22 C21 H21 119.8 ?
C23 C22 C21 120.7(5) ?
C23 C22 H22 119.6 ?
C21 C22 H22 119.6 ?
C22 C23 C24 119.5(5) ?
C22 C23 H23 120.2 ?
C24 C23 H23 120.2 ?
C25 C24 C23 120.7(5) ?
C25 C24 H24 119.6 ?
C23 C24 H24 119.6 ?
C24 C25 C20 120.4(5) ?
C24 C25 C26 116.4(5) ?
C20 C25 C26 123.2(5) ?
O2 C26 C25 124.9(5) ?
O2 C26 H26 117.6 ?
C25 C26 H26 117.6 ?
C28 C27 C32 119.1(5) ?
C28 C27 P2 121.2(4) ?
C32 C27 P2 119.6(4) ?
C27 C28 C29 120.7(5) ?
C27 C28 H28 119.7 ?
C29 C28 H28 119.7 ?
C30 C29 C28 119.2(6) ?
C30 C29 H29 120.4 ?
C28 C29 H29 120.4 ?
C31 C30 C29 121.1(5) ?
C31 C30 H30 119.4 ?
C29 C30 H30 119.4 ?
C30 C31 C32 119.6(5) ?
C30 C31 H31 120.2 ?
C32 C31 H31 120.2 ?
C31 C32 C27 120.3(5) ?
C31 C32 H32 119.8 ?
C27 C32 H32 119.8 ?
C38 C33 C34 119.8(5) ?
C38 C33 P2 116.2(4) ?
C34 C33 P2 123.8(4) ?
C35 C34 C33 120.1(5) ?
C35 C34 H34 120.0 ?
C33 C34 H34 120.0 ?
C36 C35 C34 119.9(5) ?
C36 C35 H35 120.1 ?
C34 C35 H35 120.1 ?
C37 C36 C35 120.6(5) ?
C37 C36 H36 119.7 ?
C35 C36 H36 119.7 ?
C36 C37 C38 120.6(5) ?
C36 C37 H37 119.7 ?
C38 C37 H37 119.7 ?
C37 C38 C33 119.1(5) ?
C37 C38 H38 120.4 ?
C33 C38 H38 120.4 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
Au1 P1 2.2297(13) y
Au1 Cl1 2.2819(13) y
P1 C14 1.822(5) y
P1 C1 1.825(5) y
P1 C8 1.827(5) y
C1 C2 1.388(7) ?
C1 C6 1.402(8) ?
C2 C3 1.389(7) ?
C2 H2 0.9500 ?
C3 C4 1.386(8) ?
C3 H3 0.9500 ?
C4 C5 1.370(8) ?
C4 H4 0.9500 ?
C5 C6 1.396(7) ?
C5 H5 0.9500 ?
C6 C7 1.461(8) ?
C7 O1 1.207(7) y
C7 H7 0.9500 ?
C8 C9 1.376(8) ?
C8 C13 1.389(7) ?
C9 C10 1.399(8) ?
C9 H9 0.9500 ?
C10 C11 1.379(8) ?
C10 H10 0.9500 ?
C11 C12 1.391(8) ?
C11 H11 0.9500 ?
C12 C13 1.391(8) ?
C12 H12 0.9500 ?
C13 H13 0.9500 ?
C14 C19 1.388(8) ?
C14 C15 1.398(7) ?
C15 C16 1.382(8) ?
C15 H15 0.9500 ?
C16 C17 1.387(9) ?
C16 H16 0.9500 ?
C17 C18 1.377(9) ?
C17 H17 0.9500 ?
C18 C19 1.395(8) ?
C18 H18 0.9500 ?
C19 H19 0.9500 ?
Au2 P2 2.2304(14) y
Au2 Cl2 2.2836(14) y
P2 C33 1.807(5) y
P2 C27 1.817(6) y
P2 C20 1.838(5) y
C20 C21 1.388(7) ?
C20 C25 1.409(7) ?
C21 C22 1.406(8) ?
C21 H21 0.9500 ?
C22 C23 1.364(8) ?
C22 H22 0.9500 ?
C23 C24 1.387(8) ?
C23 H23 0.9500 ?
C24 C25 1.385(8) ?
C24 H24 0.9500 ?
C25 C26 1.465(8) ?
C26 O2 1.219(7) y
C26 H26 0.9500 ?
C27 C28 1.381(8) ?
C27 C32 1.400(7) ?
C28 C29 1.399(8) ?
C28 H28 0.9500 ?
C29 C30 1.382(9) ?
C29 H29 0.9500 ?
C30 C31 1.372(9) ?
C30 H30 0.9500 ?
C31 C32 1.394(8) ?
C31 H31 0.9500 ?
C32 H32 0.9500 ?
C33 C38 1.398(7) ?
C33 C34 1.400(8) ?
C34 C35 1.383(8) ?
C34 H34 0.9500 ?
C35 C36 1.379(8) ?
C35 H35 0.9500 ?
C36 C37 1.379(8) ?
C36 H36 0.9500 ?
C37 C38 1.390(8) ?
C37 H37 0.9500 ?
C38 H38 0.9500 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C14 P1 C1 C2 117.8(4)
C8 P1 C1 C2 8.6(5)
Au1 P1 C1 C2 -113.0(4)
C14 P1 C1 C6 -63.7(5)
C8 P1 C1 C6 -172.9(4)
Au1 P1 C1 C6 65.5(5)
C6 C1 C2 C3 0.7(8)
P1 C1 C2 C3 179.3(4)
C1 C2 C3 C4 1.0(8)
C2 C3 C4 C5 -1.8(9)
C3 C4 C5 C6 0.9(9)
C4 C5 C6 C1 0.9(8)
C4 C5 C6 C7 -177.2(5)
C2 C1 C6 C5 -1.7(8)
P1 C1 C6 C5 179.8(4)
C2 C1 C6 C7 176.3(5)
P1 C1 C6 C7 -2.2(7)
C5 C6 C7 O1 178.1(5)
C1 C6 C7 O1 0.1(9)
C14 P1 C8 C9 124.1(4)
C1 P1 C8 C9 -124.0(4)
Au1 P1 C8 C9 -1.1(5)
C14 P1 C8 C13 -50.0(5)
C1 P1 C8 C13 61.8(5)
Au1 P1 C8 C13 -175.2(4)
C13 C8 C9 C10 0.9(8)
P1 C8 C9 C10 -173.2(4)
C8 C9 C10 C11 -0.2(9)
C9 C10 C11 C12 -0.8(9)
C10 C11 C12 C13 1.1(9)
C9 C8 C13 C12 -0.7(8)
P1 C8 C13 C12 173.3(4)
C11 C12 C13 C8 -0.3(8)
C1 P1 C14 C19 -14.6(5)
C8 P1 C14 C19 97.6(5)
Au1 P1 C14 C19 -141.4(4)
C1 P1 C14 C15 168.4(4)
C8 P1 C14 C15 -79.5(5)
Au1 P1 C14 C15 41.5(5)
C19 C14 C15 C16 0.7(8)
P1 C14 C15 C16 177.9(5)
C14 C15 C16 C17 0.6(9)
C15 C16 C17 C18 -1.0(9)
C16 C17 C18 C19 0.0(9)
C15 C14 C19 C18 -1.7(8)
P1 C14 C19 C18 -178.7(4)
C17 C18 C19 C14 1.3(8)
C33 P2 C20 C21 117.1(4)
C27 P2 C20 C21 8.7(5)
Au2 P2 C20 C21 -114.2(4)
C33 P2 C20 C25 -68.0(5)
C27 P2 C20 C25 -176.4(4)
Au2 P2 C20 C25 60.6(5)
C25 C20 C21 C22 0.0(8)
P2 C20 C21 C22 175.1(4)
C20 C21 C22 C23 0.2(8)
C21 C22 C23 C24 -0.6(9)
C22 C23 C24 C25 0.9(9)
C23 C24 C25 C20 -0.8(8)
C23 C24 C25 C26 -178.5(5)
C21 C20 C25 C24 0.3(8)
P2 C20 C25 C24 -174.6(4)
C21 C20 C25 C26 177.9(5)
P2 C20 C25 C26 3.0(8)
C24 C25 C26 O2 177.2(6)
C20 C25 C26 O2 -0.5(9)
C33 P2 C27 C28 -51.3(5)
C20 P2 C27 C28 62.3(5)
Au2 P2 C27 C28 -173.9(4)
C33 P2 C27 C32 124.5(4)
C20 P2 C27 C32 -121.8(4)
Au2 P2 C27 C32 1.9(5)
C32 C27 C28 C29 1.1(8)
P2 C27 C28 C29 176.9(4)
C27 C28 C29 C30 -1.4(8)
C28 C29 C30 C31 0.0(9)
C29 C30 C31 C32 1.9(9)
C30 C31 C32 C27 -2.2(8)
C28 C27 C32 C31 0.8(8)
P2 C27 C32 C31 -175.2(4)
C27 P2 C33 C38 -78.4(5)
C20 P2 C33 C38 170.6(4)
Au2 P2 C33 C38 42.6(5)
C27 P2 C33 C34 96.8(5)
C20 P2 C33 C34 -14.2(6)
Au2 P2 C33 C34 -142.2(4)
C38 C33 C34 C35 -1.9(9)
P2 C33 C34 C35 -176.9(5)
C33 C34 C35 C36 1.6(9)
C34 C35 C36 C37 0.0(9)
C35 C36 C37 C38 -1.5(9)
C36 C37 C38 C33 1.2(9)
C34 C33 C38 C37 0.5(8)
P2 C33 C38 C37 175.9(4)
