#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/13/2211316.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2211316
loop_
_publ_author_name
'S. Selvanayagam'
'M. N. Devi'
'D. Velmurugan'
'K. Ravikumar'
'M. Poornachandran'
_publ_section_title
1'-Methyl-4'-phenylindan-2-spiro-2'-pyrrolidine-3'-spiro-1''-cyclooctane-1,3,2''-trione
_journal_coeditor_code           CF2061
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              o5551
_journal_page_last               o5553
_journal_paper_doi               10.1107/S1600536806044412
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          'C26 H27 N O3'
_chemical_formula_moiety         'C26 H27 N O3'
_chemical_formula_sum            'C26 H27 N O3'
_chemical_formula_weight         401.49
_chemical_name_systematic
;
1'-Methyl-4'-phenylindan-2-spiro-2'-pyrrolidine-3'-spiro-1''-cyclooctane-
1,3,2''-trione
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 113.7000(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   14.3552(8)
_cell_length_b                   9.9061(6)
_cell_length_c                   15.9692(9)
_cell_measurement_reflns_used    6503
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      25.75
_cell_measurement_theta_min      2.48
_cell_volume                     2079.4(2)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        SAINT
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and PLATON (Spek, 2003)'
_computing_publication_material  'SHELXL97 and PARST (Nardelli, 1995)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.976
_diffrn_measurement_device       'Bruker SMART APEX'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0260
_diffrn_reflns_av_sigmaI/netI    0.0231
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       21
_diffrn_reflns_limit_l_min       -20
_diffrn_reflns_number            23284
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         28.01
_diffrn_reflns_theta_min         1.55
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.083
_exptl_absorpt_correction_type   none
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.282
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Block
_exptl_crystal_F_000             856
_exptl_crystal_size_max          0.24
_exptl_crystal_size_mid          0.22
_exptl_crystal_size_min          0.19
_refine_diff_density_max         0.598
_refine_diff_density_min         -0.216
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.019
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     272
_refine_ls_number_reflns         4895
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.019
_refine_ls_R_factor_all          0.0767
_refine_ls_R_factor_gt           0.0613
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0889P)²+0.6378P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1547
_refine_ls_wR_factor_ref         0.1670
_reflns_number_gt                3862
_reflns_number_total             4895
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            cf2061.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2211316
_cod_database_fobs_code          2211316
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
N N1 0.11396(12) 0.51225(17) 0.48481(11) 0.0497(4) Uani d . 1
O O1 0.30743(12) 0.62835(16) 0.48188(11) 0.0675(4) Uani d . 1
O O2 0.01162(10) 0.38437(16) 0.30966(10) 0.0615(4) Uani d . 1
O O3 0.11081(11) 0.14531(15) 0.47676(9) 0.0575(4) Uani d . 1
C C1 0.16898(12) 0.46080(17) 0.43284(11) 0.0403(4) Uani d . 1
C C2 0.22520(12) 0.32934(16) 0.48804(10) 0.0359(3) Uani d . 1
C C3 0.22285(13) 0.35375(18) 0.58518(11) 0.0412(4) Uani d . 1
H H3 0.1721 0.2913 0.5897 0.049 Uiso calc R 1
C C4 0.17952(16) 0.4958(2) 0.58069(13) 0.0535(5) Uani d . 1
H H4A 0.1411 0.5029 0.6185 0.064 Uiso calc R 1
H H4B 0.2333 0.5629 0.6004 0.064 Uiso calc R 1
C C5 0.06928(18) 0.6464(2) 0.45974(16) 0.0662(6) Uani d . 1
H H5A 0.1224 0.7117 0.4711 0.099 Uiso calc R 1
H H5B 0.0314 0.6682 0.4956 0.099 Uiso calc R 1
H H5C 0.0247 0.6475 0.3960 0.099 Uiso calc R 1
C C6 0.24463(14) 0.56397(18) 0.42099(13) 0.0462(4) Uani d . 1
C C7 0.22103(14) 0.57730(18) 0.32238(13) 0.0470(4) Uani d . 1
C C8 0.27179(18) 0.6509(2) 0.27928(17) 0.0608(5) Uani d . 1
H H8 0.3307 0.6991 0.3127 0.073 Uiso calc R 1
C C9 0.2312(2) 0.6495(2) 0.18491(18) 0.0707(7) Uani d . 1
H H9 0.2636 0.6980 0.1545 0.085 Uiso calc R 1
C C10 0.1440(2) 0.5784(2) 0.13436(16) 0.0683(6) Uani d . 1
H H10 0.1187 0.5803 0.0708 0.082 Uiso calc R 1
C C11 0.09410(16) 0.5050(2) 0.17641(14) 0.0571(5) Uani d . 1
H H11 0.0354 0.4569 0.1424 0.069 Uiso calc R 1
C C12 0.13379(14) 0.50468(18) 0.27124(12) 0.0456(4) Uani d . 1
C C13 0.09309(13) 0.43910(18) 0.33261(12) 0.0437(4) Uani d . 1
C C14 0.33186(12) 0.31379(18) 0.48606(11) 0.0409(4) Uani d . 1
H H14A 0.3222 0.3147 0.4224 0.049 Uiso calc R 1
H H14B 0.3704 0.3942 0.5140 0.049 Uiso calc R 1
C C15 0.39954(14) 0.1917(2) 0.53107(12) 0.0492(4) Uani d . 1
H H15A 0.4599 0.1990 0.5182 0.059 Uiso calc R 1
H H15B 0.4216 0.2020 0.5967 0.059 Uiso calc R 1
C C16 0.3603(2) 0.0498(2) 0.50762(17) 0.0716(7) Uani d . 1
H H16A 0.3067 0.0369 0.5293 0.086 Uiso calc R 1
H H16B 0.4151 -0.0114 0.5420 0.086 Uiso calc R 1
C C17 0.3191(2) 0.0072(3) 0.40831(18) 0.0747(7) Uani d . 1
H H17A 0.3422 -0.0838 0.4049 0.090 Uiso calc R 1
H H17B 0.3474 0.0661 0.3760 0.090 Uiso calc R 1
C C18 0.20404(18) 0.0106(2) 0.36002(15) 0.0622(5) Uani d . 1
H H18A 0.1755 -0.0465 0.3931 0.075 Uiso calc R 1
H H18B 0.1842 -0.0269 0.2992 0.075 Uiso calc R 1
C C19 0.15843(15) 0.15170(19) 0.35173(12) 0.0479(4) Uani d . 1
H H19A 0.1963 0.2135 0.3301 0.057 Uiso calc R 1
H H19B 0.0887 0.1499 0.3066 0.057 Uiso calc R 1
C C20 0.15985(12) 0.20390(17) 0.44215(11) 0.0409(4) Uani d . 1
C C21 0.32018(12) 0.32937(17) 0.66870(10) 0.0379(4) Uani d . 1
C C22 0.40125(14) 0.41944(18) 0.69695(12) 0.0449(4) Uani d . 1
H H22 0.3962 0.4989 0.6644 0.054 Uiso calc R 1
C C23 0.48941(14) 0.3922(2) 0.77302(13) 0.0503(4) Uani d . 1
H H23 0.5430 0.4534 0.7908 0.060 Uiso calc R 1
C C24 0.49864(14) 0.2758(2) 0.82259(12) 0.0505(4) Uani d . 1
H H24 0.5585 0.2575 0.8732 0.061 Uiso calc R 1
C C25 0.41858(15) 0.18653(18) 0.79663(12) 0.0466(4) Uani d . 1
H H25 0.4238 0.1080 0.8302 0.056 Uiso calc R 1
C C26 0.32988(13) 0.21345(18) 0.72035(11) 0.0424(4) Uani d . 1
H H26 0.2760 0.1527 0.7036 0.051 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C4 N1 C1 107.10(10) y
C4 N1 C5 114.8(2) y
C1 N1 C5 116.4(2) y
N1 C1 C13 108.79(13) ?
N1 C1 C6 113.96(14) ?
C13 C1 C6 101.59(14) ?
N1 C1 C2 103.98(13) ?
C13 C1 C2 116.56(13) ?
C6 C1 C2 112.32(13) ?
C20 C2 C14 108.97(13) ?
C20 C2 C3 109.76(13) ?
C14 C2 C3 116.40(13) ?
C20 C2 C1 108.46(12) ?
C14 C2 C1 110.70(13) ?
C3 C2 C1 102.18(12) ?
C21 C3 C4 113.72(14) ?
C21 C3 C2 117.60(13) ?
C4 C3 C2 105.26(14) ?
C21 C3 H3 106.5 ?
C4 C3 H3 106.5 ?
C2 C3 H3 106.5 ?
N1 C4 C3 103.42(14) ?
N1 C4 H4A 111.1 ?
C3 C4 H4A 111.1 ?
N1 C4 H4B 111.1 ?
C3 C4 H4B 111.1 ?
H4A C4 H4B 109.0 ?
N1 C5 H5A 109.5 ?
N1 C5 H5B 109.5 ?
H5A C5 H5B 109.5 ?
N1 C5 H5C 109.5 ?
H5A C5 H5C 109.5 ?
H5B C5 H5C 109.5 ?
O1 C6 C7 126.00(18) ?
O1 C6 C1 125.43(18) ?
C7 C6 C1 108.41(15) ?
C12 C7 C8 120.50(19) ?
C12 C7 C6 110.28(16) ?
C8 C7 C6 129.20(19) ?
C9 C8 C7 117.3(2) ?
C9 C8 H8 121.3 ?
C7 C8 H8 121.3 ?
C10 C9 C8 122.0(2) ?
C10 C9 H9 119.0 ?
C8 C9 H9 119.0 ?
C11 C10 C9 120.9(2) ?
C11 C10 H10 119.5 ?
C9 C10 H10 119.5 ?
C10 C11 C12 118.0(2) ?
C10 C11 H11 121.0 ?
C12 C11 H11 121.0 ?
C11 C12 C7 121.20(19) ?
C11 C12 C13 128.81(19) ?
C7 C12 C13 109.93(16) ?
O2 C13 C12 126.17(17) ?
O2 C13 C1 124.83(17) ?
C12 C13 C1 108.87(15) ?
C15 C14 C2 120.80(15) ?
C15 C14 H14A 107.1 ?
C2 C14 H14A 107.1 ?
C15 C14 H14B 107.1 ?
C2 C14 H14B 107.1 ?
H14A C14 H14B 106.8 ?
C16 C15 C14 121.04(16) ?
C16 C15 H15A 107.1 ?
C14 C15 H15A 107.1 ?
C16 C15 H15B 107.1 ?
C14 C15 H15B 107.1 ?
H15A C15 H15B 106.8 ?
C15 C16 C17 118.1(2) ?
C15 C16 H16A 107.8 ?
C17 C16 H16A 107.8 ?
C15 C16 H16B 107.8 ?
C17 C16 H16B 107.8 ?
H16A C16 H16B 107.1 ?
C16 C17 C18 114.5(2) ?
C16 C17 H17A 108.6 ?
C18 C17 H17A 108.6 ?
C16 C17 H17B 108.6 ?
C18 C17 H17B 108.6 ?
H17A C17 H17B 107.6 ?
C17 C18 C19 113.96(18) ?
C17 C18 H18A 108.8 ?
C19 C18 H18A 108.8 ?
C17 C18 H18B 108.8 ?
C19 C18 H18B 108.8 ?
H18A C18 H18B 107.7 ?
C20 C19 C18 112.71(15) ?
C20 C19 H19A 109.0 ?
C18 C19 H19A 109.0 ?
C20 C19 H19B 109.0 ?
C18 C19 H19B 109.0 ?
H19A C19 H19B 107.8 ?
O3 C20 C19 118.87(16) ?
O3 C20 C2 121.53(15) ?
C19 C20 C2 119.59(14) ?
C26 C21 C22 117.86(15) ?
C26 C21 C3 119.49(15) ?
C22 C21 C3 122.64(15) ?
C23 C22 C21 120.72(17) ?
C23 C22 H22 119.6 ?
C21 C22 H22 119.6 ?
C24 C23 C22 120.78(17) ?
C24 C23 H23 119.6 ?
C22 C23 H23 119.6 ?
C23 C24 C25 119.35(16) ?
C23 C24 H24 120.3 ?
C25 C24 H24 120.3 ?
C24 C25 C26 120.09(16) ?
C24 C25 H25 120.0 ?
C26 C25 H25 120.0 ?
C21 C26 C25 121.18(16) ?
C21 C26 H26 119.4 ?
C25 C26 H26 119.4 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
N1 C4 1.449(2) y
N1 C1 1.449(2) y
N1 C5 1.460(3) y
O1 C6 1.208(2) y
O2 C13 1.205(2) y
O3 C20 1.205(2) y
C1 C13 1.547(2) ?
C1 C6 1.557(2) ?
C1 C2 1.598(2) y
C2 C20 1.552(2) ?
C2 C14 1.552(2) ?
C2 C3 1.584(2) y
C3 C21 1.514(2) ?
C3 C4 1.529(3) y
C3 H3 0.980 ?
C4 H4A 0.970 ?
C4 H4B 0.970 ?
C5 H5A 0.960 ?
C5 H5B 0.960 ?
C5 H5C 0.960 ?
C6 C7 1.477(3) ?
C7 C12 1.389(3) ?
C7 C8 1.393(3) ?
C8 C9 1.380(3) ?
C8 H8 0.930 ?
C9 C10 1.379(4) ?
C9 H9 0.930 ?
C10 C11 1.371(3) ?
C10 H10 0.930 ?
C11 C12 1.387(3) ?
C11 H11 0.930 ?
C12 C13 1.478(3) ?
C14 C15 1.537(2) ?
C14 H14A 0.970 ?
C14 H14B 0.970 ?
C15 C16 1.505(3) ?
C15 H15A 0.970 ?
C15 H15B 0.970 ?
C16 C17 1.513(4) ?
C16 H16A 0.970 ?
C16 H16B 0.970 ?
C17 C18 1.516(3) ?
C17 H17A 0.970 ?
C17 H17B 0.970 ?
C18 C19 1.526(3) ?
C18 H18A 0.970 ?
C18 H18B 0.970 ?
C19 C20 1.526(2) ?
C19 H19A 0.970 ?
C19 H19B 0.970 ?
C21 C26 1.388(2) ?
C21 C22 1.390(2) ?
C22 C23 1.384(3) ?
C22 H22 0.930 ?
C23 C24 1.375(3) ?
C23 H23 0.930 ?
C24 C25 1.375(3) ?
C24 H24 0.930 ?
C25 C26 1.389(3) ?
C25 H25 0.930 ?
C26 H26 0.930 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C3 H3 O3 0.98 2.20 2.759(2) 115
C4 H4B O1 0.97 2.60 3.149(3) 116
C14 H14B O1 0.97 2.47 3.133(2) 126
C19 H19B O2 0.97 2.58 3.011(2) 107
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C4 N1 C1 C13 164.40(15)
C5 N1 C1 C13 -65.7(2)
C4 N1 C1 C6 -83.05(18)
C5 N1 C1 C6 46.9(2)
C4 N1 C1 C2 39.55(18)
C5 N1 C1 C2 169.47(16)
N1 C1 C2 C20 96.89(15)
C13 C1 C2 C20 -22.82(19)
C6 C1 C2 C20 -139.43(14)
N1 C1 C2 C14 -143.60(13)
C13 C1 C2 C14 96.69(16)
C6 C1 C2 C14 -19.93(18)
N1 C1 C2 C3 -19.00(15)
C13 C1 C2 C3 -138.71(14)
C6 C1 C2 C3 104.68(15)
C20 C2 C3 C21 111.11(16)
C14 C2 C3 C21 -13.2(2)
C1 C2 C3 C21 -133.94(15)
C20 C2 C3 C4 -121.08(15)
C14 C2 C3 C4 114.59(16)
C1 C2 C3 C4 -6.13(16)
C1 N1 C4 C3 -43.85(19)
C5 N1 C4 C3 -174.65(17)
C21 C3 C4 N1 159.36(15)
C2 C3 C4 N1 29.25(18)
N1 C1 C6 O1 49.9(2)
C13 C1 C6 O1 166.69(18)
C2 C1 C6 O1 -68.0(2)
N1 C1 C6 C7 -125.74(15)
C13 C1 C6 C7 -8.93(17)
C2 C1 C6 C7 116.35(15)
O1 C6 C7 C12 -169.90(19)
C1 C6 C7 C12 5.69(19)
O1 C6 C7 C8 8.8(3)
C1 C6 C7 C8 -175.59(18)
C12 C7 C8 C9 0.7(3)
C6 C7 C8 C9 -177.86(19)
C7 C8 C9 C10 -0.1(3)
C8 C9 C10 C11 -0.4(3)
C9 C10 C11 C12 0.1(3)
C10 C11 C12 C7 0.5(3)
C10 C11 C12 C13 177.37(18)
C8 C7 C12 C11 -1.0(3)
C6 C7 C12 C11 177.86(16)
C8 C7 C12 C13 -178.37(16)
C6 C7 C12 C13 0.5(2)
C11 C12 C13 O2 -7.7(3)
C7 C12 C13 O2 169.41(19)
C11 C12 C13 C1 176.36(17)
C7 C12 C13 C1 -6.52(19)
N1 C1 C13 O2 -46.2(2)
C6 C1 C13 O2 -166.75(18)
C2 C1 C13 O2 70.8(2)
N1 C1 C13 C12 129.75(15)
C6 C1 C13 C12 9.24(17)
C2 C1 C13 C12 -113.17(16)
C20 C2 C14 C15 -58.27(19)
C3 C2 C14 C15 66.5(2)
C1 C2 C14 C15 -177.47(14)
C2 C14 C15 C16 53.3(3)
C14 C15 C16 C17 56.2(3)
C15 C16 C17 C18 -99.6(3)
C16 C17 C18 C19 64.4(3)
C17 C18 C19 C20 -74.3(2)
C18 C19 C20 O3 -63.7(2)
C18 C19 C20 C2 115.45(18)
C14 C2 C20 O3 133.51(17)
C3 C2 C20 O3 5.0(2)
C1 C2 C20 O3 -105.90(18)
C14 C2 C20 C19 -45.61(19)
C3 C2 C20 C19 -174.15(14)
C1 C2 C20 C19 74.97(18)
C4 C3 C21 C26 132.01(17)
C2 C3 C21 C26 -104.35(18)
C4 C3 C21 C22 -47.5(2)
C2 C3 C21 C22 76.1(2)
C26 C21 C22 C23 1.4(3)
C3 C21 C22 C23 -179.07(16)
C21 C22 C23 C24 -0.3(3)
C22 C23 C24 C25 -0.8(3)
C23 C24 C25 C26 0.8(3)
C22 C21 C26 C25 -1.5(2)
C3 C21 C26 C25 179.00(15)
C24 C25 C26 C21 0.4(3)
