#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/13/2211358.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2211358
loop_
_publ_author_name
'Zhen-Ming Zhang'
'Da-Qi Wang'
'Gao Jian'
'Shuan Li'
_publ_section_title
;μ-4,4'-Bipyridine-κ²N:N'-bis{[N-(2-aminoethyl)-1,3-propyldiamine-κ³N,N',N'']aquacopper(II)}
 tetrakis(perchlorate)
;
_journal_coeditor_code           CV2158
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m3570
_journal_page_last               m3572
_journal_paper_doi               10.1107/S1600536806050586
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          '[Cu2 (C10 H21 N4 O)2] (Cl O4)4'
_chemical_formula_moiety         'C20 H42 Cl4 Cu2 N8 O18 4+, 4(Cl1 O4 -)'
_chemical_formula_sum            'C20 H42 Cl4 Cu2 N8 O18'
_chemical_formula_weight         951.50
_chemical_name_systematic
;
μ₂-4,4'-Bipyridine-κ²N:N'-bis{[N-(2-aminoethyl)-1,3-propyldiamine-
κ³N,N',N'']aquacopper(II)} tetrakis(perchlorate)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2yn'
_symmetry_space_group_name_H-M   'P 1 21/n 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 98.359(2)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   7.6572(9)
_cell_length_b                   17.218(2)
_cell_length_c                   14.4430(17)
_cell_measurement_reflns_used    4327
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      26.539
_cell_measurement_theta_min      2.452
_cell_volume                     1884.0(4)
_computing_cell_refinement       'SAINT (Bruker, 2003)'
_computing_data_collection       'SMART (Bruker, 2003)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXLTL (Sheldrick, 1997b)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997a)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997a)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker APEX area-dectector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0267
_diffrn_reflns_av_sigmaI/netI    0.0253
_diffrn_reflns_limit_h_max       9
_diffrn_reflns_limit_h_min       -9
_diffrn_reflns_limit_k_max       20
_diffrn_reflns_limit_k_min       -20
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -17
_diffrn_reflns_number            13315
_diffrn_reflns_theta_full        25.00
_diffrn_reflns_theta_max         25.00
_diffrn_reflns_theta_min         1.85
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.494
_exptl_absorpt_correction_T_max  0.6798
_exptl_absorpt_correction_T_min  0.6306
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2002)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.677
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             976
_exptl_crystal_size_max          0.34
_exptl_crystal_size_mid          0.30
_exptl_crystal_size_min          0.28
_refine_diff_density_max         0.782
_refine_diff_density_min         -0.422
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.073
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     300
_refine_ls_number_reflns         3311
_refine_ls_number_restraints     511
_refine_ls_restrained_S_all      1.120
_refine_ls_R_factor_all          0.0713
_refine_ls_R_factor_gt           0.0606
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0813P)²+2.7723P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1527
_refine_ls_wR_factor_ref         0.1604
_reflns_number_gt                2755
_reflns_number_total             3311
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            cv2158.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/n'
_cod_database_code               2211358
_cod_database_fobs_code          2211358
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x-1/2, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Cu Cu1 0.30576(8) 0.22001(3) 0.63203(4) 0.0494(2) Uani d . 1 . .
Cl Cl1 0.0696(3) 0.01588(11) 0.24452(14) 0.0989(7) Uani d DU 1 . .
Cl Cl2 0.6592(2) 0.22192(10) 0.46318(12) 0.0824(5) Uani d DU 1 . .
N N1 0.1955(5) 0.3237(2) 0.5875(3) 0.0541(10) Uani d U 1 . .
N N2 0.1856(6) 0.1678(3) 0.5159(3) 0.0640(11) Uani d . 1 . .
H H2A 0.0834 0.1928 0.4972 0.077 Uiso calc R 1 . .
H H2B 0.2538 0.1741 0.4707 0.077 Uiso calc R 1 . .
N N3 0.4579(7) 0.1251(3) 0.6707(3) 0.0675(12) Uani d . 1 . .
H H3 0.5493 0.1282 0.6370 0.081 Uiso calc R 1 . .
N N4 0.4523(7) 0.2702(3) 0.7417(4) 0.0713(13) Uani d . 1 . .
H H4A 0.4937 0.3160 0.7242 0.086 Uiso calc R 1 . .
H H4B 0.3851 0.2794 0.7868 0.086 Uiso calc R 1 . .
O O1 0.0783(6) 0.1877(2) 0.7206(3) 0.0807(12) Uani d . 1 . .
H H1A 0.0068 0.1499 0.7095 0.097 Uiso d R 1 . .
H H1B 0.0566 0.2087 0.7709 0.097 Uiso d R 1 . .
O O2 -0.0813(6) 0.0533(3) 0.2680(5) 0.131(2) Uani d DU 1 A .
O O3 0.065(2) -0.0117(11) 0.1524(5) 0.147(5) Uani d PDU 0.512(19) A 1
O O4 0.2019(13) 0.0733(6) 0.2578(13) 0.142(5) Uani d PDU 0.512(19) A 1
O O5 0.117(2) -0.0444(7) 0.3091(10) 0.091(4) Uani d PDU 0.512(19) A 1
O O6 0.7222(13) 0.1532(4) 0.5093(7) 0.142(4) Uani d PDU 0.672(8) B 1
O O7 0.8059(8) 0.2521(6) 0.4267(6) 0.113(3) Uani d PDU 0.672(8) B 1
O O8 0.5042(9) 0.2162(8) 0.3979(6) 0.151(4) Uani d PDU 0.672(8) B 1
O O9 0.6205(13) 0.2669(5) 0.5390(5) 0.115(3) Uani d PDU 0.672(8) B 1
O O3' -0.006(2) -0.0410(7) 0.1806(10) 0.152(5) Uani d PDU 0.488(19) A 2
O O4' 0.166(2) 0.0647(8) 0.1917(13) 0.141(5) Uani d PDU 0.488(19) A 2
O O5' 0.161(2) -0.0279(10) 0.3189(10) 0.115(6) Uani d PDU 0.488(19) A 2
O O6' 0.617(3) 0.2933(6) 0.4173(12) 0.147(6) Uani d PDU 0.328(8) B 2
O O7' 0.8233(14) 0.1980(13) 0.4395(14) 0.139(6) Uani d PDU 0.328(8) B 2
O O8' 0.653(3) 0.2312(12) 0.5597(4) 0.130(6) Uani d PDU 0.328(8) B 2
O O9' 0.534(2) 0.1675(9) 0.4212(13) 0.140(6) Uani d PDU 0.328(8) B 2
C C1 0.0385(9) 0.3450(4) 0.6039(6) 0.096(2) Uani d U 1 . .
H H1 -0.0220 0.3124 0.6397 0.115 Uiso calc R 1 . .
C C2 -0.0413(8) 0.4132(4) 0.5708(6) 0.094(2) Uani d U 1 . .
H H2 -0.1533 0.4252 0.5842 0.113 Uiso calc R 1 . .
C C3 0.0415(6) 0.4632(2) 0.5187(3) 0.0475(11) Uani d U 1 . .
C C4 0.2060(7) 0.4412(3) 0.5031(4) 0.0603(13) Uani d . 1 . .
H H4 0.2706 0.4733 0.4690 0.072 Uiso calc R 1 . .
C C5 0.2764(7) 0.3721(3) 0.5375(4) 0.0645(14) Uani d . 1 . .
H H5 0.3880 0.3585 0.5247 0.077 Uiso calc R 1 . .
C C6 0.1461(8) 0.0842(3) 0.5222(5) 0.0743(17) Uani d . 1 . .
H H6A 0.0613 0.0770 0.5652 0.089 Uiso calc R 1 . .
H H6B 0.0927 0.0657 0.4612 0.089 Uiso calc R 1 . .
C C7 0.3007(9) 0.0389(4) 0.5535(6) 0.090(2) Uani d . 1 . .
H H7A 0.3882 0.0503 0.5131 0.108 Uiso calc R 1 . .
H H7B 0.2696 -0.0156 0.5450 0.108 Uiso calc R 1 . .
C C8 0.3832(10) 0.0498(4) 0.6505(6) 0.096(2) Uani d . 1 . .
H H8A 0.2954 0.0403 0.6913 0.115 Uiso calc R 1 . .
H H8B 0.4755 0.0112 0.6650 0.115 Uiso calc R 1 . .
C C9 0.5388(10) 0.1376(5) 0.7696(4) 0.090(2) Uani d . 1 . .
H H9A 0.6374 0.1024 0.7860 0.108 Uiso calc R 1 . .
H H9B 0.4526 0.1279 0.8113 0.108 Uiso calc R 1 . .
C C10 0.6008(9) 0.2197(5) 0.7787(5) 0.094(2) Uani d . 1 . .
H H10A 0.6409 0.2320 0.8439 0.112 Uiso calc R 1 . .
H H10B 0.6983 0.2275 0.7437 0.112 Uiso calc R 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N4 Cu1 N2 . 173.2(2) y
N4 Cu1 N3 . 84.06(19) y
N2 Cu1 N3 . 92.54(19) y
N4 Cu1 N1 . 91.76(18) y
N2 Cu1 N1 . 90.58(18) y
N3 Cu1 N1 . 169.45(19) y
N4 Cu1 O1 . 92.60(19) y
N2 Cu1 O1 . 93.58(18) y
N3 Cu1 O1 . 95.69(18) y
N1 Cu1 O1 . 94.17(16) y
O2 Cl1 O3 . 118.2(6) ?
O2 Cl1 O5 . 108.7(8) ?
O3 Cl1 O5 . 110.2(9) ?
O2 Cl1 O4 . 104.2(6) ?
O3 Cl1 O4 . 106.5(8) ?
O5 Cl1 O4 . 108.4(8) ?
O2 Cl1 O4' . 111.6(6) ?
O3 Cl1 O4' . 68.6(8) ?
O5 Cl1 O4' . 133.7(10) ?
O4 Cl1 O4' . 40.1(7) ?
O2 Cl1 O5' . 113.2(9) ?
O3 Cl1 O5' . 118.7(11) ?
O5 Cl1 O5' . 18.1(11) ?
O4 Cl1 O5' . 90.3(9) ?
O4' Cl1 O5' . 119.4(9) ?
O2 Cl1 O3' . 101.6(8) ?
O3 Cl1 O3' . 36.5(6) ?
O5 Cl1 O3' . 87.9(9) ?
O4 Cl1 O3' . 142.7(8) ?
O4' Cl1 O3' . 104.9(8) ?
O5' Cl1 O3' . 103.7(9) ?
O8 Cl2 O7 . 114.6(6) ?
O8 Cl2 O9 . 107.9(6) ?
O7 Cl2 O9 . 111.0(6) ?
O8 Cl2 O6 . 117.1(7) ?
O7 Cl2 O6 . 104.5(5) ?
O9 Cl2 O6 . 101.0(5) ?
O8 Cl2 O8' . 121.6(11) ?
O7 Cl2 O8' . 118.1(10) ?
O9 Cl2 O8' . 29.3(8) ?
O6 Cl2 O8' . 71.7(9) ?
O8 Cl2 O7' . 120.7(10) ?
O7 Cl2 O7' . 39.6(9) ?
O9 Cl2 O7' . 130.2(10) ?
O6 Cl2 O7' . 67.3(9) ?
O8' Cl2 O7' . 115.5(11) ?
O8 Cl2 O9' . 38.1(8) ?
O7 Cl2 O9' . 127.8(10) ?
O9 Cl2 O9' . 119.5(10) ?
O6 Cl2 O9' . 79.0(9) ?
O8' Cl2 O9' . 112.4(11) ?
O7' Cl2 O9' . 106.0(10) ?
O8 Cl2 O6' . 68.5(9) ?
O7 Cl2 O6' . 69.0(9) ?
O9 Cl2 O6' . 80.0(8) ?
O6 Cl2 O6' . 173.2(10) ?
O8' Cl2 O6' . 109.1(10) ?
O7' Cl2 O6' . 106.9(10) ?
O9' Cl2 O6' . 106.4(10) ?
C1 N1 C5 . 116.1(4) ?
C1 N1 Cu1 . 122.5(4) ?
C5 N1 Cu1 . 121.4(3) ?
C6 N2 Cu1 . 117.3(4) ?
C6 N2 H2A . 108.0 ?
Cu1 N2 H2A . 108.0 ?
C6 N2 H2B . 108.0 ?
Cu1 N2 H2B . 108.0 ?
H2A N2 H2B . 107.2 ?
C8 N3 C9 . 115.2(6) ?
C8 N3 Cu1 . 118.4(4) ?
C9 N3 Cu1 . 106.8(3) ?
C8 N3 H3 . 105.1 ?
C9 N3 H3 . 105.1 ?
Cu1 N3 H3 . 105.1 ?
C10 N4 Cu1 . 110.4(4) ?
C10 N4 H4A . 109.6 ?
Cu1 N4 H4A . 109.6 ?
C10 N4 H4B . 109.6 ?
Cu1 N4 H4B . 109.6 ?
H4A N4 H4B . 108.1 ?
Cu1 O1 H1A . 125.5 ?
Cu1 O1 H1B . 127.7 ?
H1A O1 H1B . 106.7 ?
N1 C1 C2 . 123.2(5) ?
N1 C1 H1 . 118.4 ?
C2 C1 H1 . 118.4 ?
C3 C2 C1 . 120.9(5) ?
C3 C2 H2 . 119.5 ?
C1 C2 H2 . 119.5 ?
C2 C3 C4 . 115.5(4) ?
C2 C3 C3 3_566 122.3(5) ?
C4 C3 C3 3_566 122.2(5) ?
C3 C4 C5 . 120.4(5) ?
C3 C4 H4 . 119.8 ?
C5 C4 H4 . 119.8 ?
N1 C5 C4 . 123.9(5) ?
N1 C5 H5 . 118.1 ?
C4 C5 H5 . 118.1 ?
C7 C6 N2 . 112.5(5) ?
C7 C6 H6A . 109.1 ?
N2 C6 H6A . 109.1 ?
C7 C6 H6B . 109.1 ?
N2 C6 H6B . 109.1 ?
H6A C6 H6B . 107.8 ?
C6 C7 C8 . 117.0(6) ?
C6 C7 H7A . 108.1 ?
C8 C7 H7A . 108.1 ?
C6 C7 H7B . 108.1 ?
C8 C7 H7B . 108.1 ?
H7A C7 H7B . 107.3 ?
N3 C8 C7 . 114.6(6) ?
N3 C8 H8A . 108.6 ?
C7 C8 H8A . 108.6 ?
N3 C8 H8B . 108.6 ?
C7 C8 H8B . 108.6 ?
H8A C8 H8B . 107.6 ?
N3 C9 C10 . 107.7(5) ?
N3 C9 H9A . 110.2 ?
C10 C9 H9A . 110.2 ?
N3 C9 H9B . 110.2 ?
C10 C9 H9B . 110.2 ?
H9A C9 H9B . 108.5 ?
N4 C10 C9 . 108.0(5) ?
N4 C10 H10A . 110.1 ?
C9 C10 H10A . 110.1 ?
N4 C10 H10B . 110.1 ?
C9 C10 H10B . 110.1 ?
H10A C10 H10B . 108.4 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Cu1 N4 . 2.000(5) y
Cu1 N2 . 2.006(4) y
Cu1 N3 . 2.037(4) y
Cu1 N1 . 2.038(4) y
Cu1 O1 . 2.372(4) y
Cl1 O2 . 1.408(2) ?
Cl1 O3 . 1.408(3) ?
Cl1 O5 . 1.408(3) ?
Cl1 O4 . 1.408(3) ?
Cl1 O4' . 1.411(4) ?
Cl1 O5' . 1.411(4) ?
Cl1 O3' . 1.412(4) ?
Cl2 O8 . 1.408(3) ?
Cl2 O7 . 1.408(3) ?
Cl2 O9 . 1.408(2) ?
Cl2 O6 . 1.408(2) ?
Cl2 O8' . 1.411(4) ?
Cl2 O7' . 1.411(4) ?
Cl2 O9' . 1.411(4) ?
Cl2 O6' . 1.412(4) ?
N1 C1 . 1.311(7) ?
N1 C5 . 1.315(6) ?
N2 C6 . 1.475(7) ?
N2 H2A . 0.9000 ?
N2 H2B . 0.9000 ?
N3 C8 . 1.431(8) ?
N3 C9 . 1.488(8) ?
N3 H3 . 0.9100 ?
N4 C10 . 1.468(8) ?
N4 H4A . 0.9000 ?
N4 H4B . 0.9000 ?
O1 H1A . 0.8500 ?
O1 H1B . 0.8500 ?
C1 C2 . 1.377(8) ?
C1 H1 . 0.9300 ?
C2 C3 . 1.359(7) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.365(6) ?
C3 C3 3_566 1.484(8) ?
C4 C5 . 1.369(7) ?
C4 H4 . 0.9300 ?
C5 H5 . 0.9300 ?
C6 C7 . 1.436(9) ?
C6 H6A . 0.9700 ?
C6 H6B . 0.9700 ?
C7 C8 . 1.462(11) ?
C7 H7A . 0.9700 ?
C7 H7B . 0.9700 ?
C8 H8A . 0.9700 ?
C8 H8B . 0.9700 ?
C9 C10 . 1.491(10) ?
C9 H9A . 0.9700 ?
C9 H9B . 0.9700 ?
C10 H10A . 0.9700 ?
C10 H10B . 0.9700 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N2 H2A O7' 1_455 0.90 2.05 2.880(14) 153.6
N2 H2A O7 1_455 0.90 2.44 3.336(10) 172.4
N2 H2B O9' . 0.90 2.36 3.17(2) 149.6
N2 H2B O8 . 0.90 2.43 3.280(12) 158.2
N3 H3 O8' . 0.91 2.30 2.972(19) 130.7
N3 H3 O6 . 0.91 2.46 3.337(10) 161.9
N4 H4A O2 4_666 0.90 2.43 3.078(7) 129.2
N4 H4A O4 4_666 0.90 2.49 3.292(14) 149.1
N4 H4A O4' 4_666 0.90 2.52 3.408(16) 168.9
N4 H4B O7 4_566 0.90 2.26 3.067(9) 149.3
N4 H4B O7' 4_566 0.90 2.35 3.202(18) 156.9
O1 H1A O5 3_556 0.85 2.05 2.886(16) 167.5
O1 H1A O3' 3_556 0.85 2.46 2.991(17) 121.5
O1 H1A O5' 3_556 0.85 2.46 3.31(2) 171.4
O1 H1B O6' 4_566 0.85 2.10 2.832(17) 144.3
O1 H1B O8 4_566 0.85 2.33 3.169(13) 171.5
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
N4 Cu1 N1 C1 . . -99.8(6)
N2 Cu1 N1 C1 . . 86.6(6)
N3 Cu1 N1 C1 . . -166.2(9)
O1 Cu1 N1 C1 . . -7.0(6)
N4 Cu1 N1 C5 . . 82.6(5)
N2 Cu1 N1 C5 . . -91.0(5)
N3 Cu1 N1 C5 . . 16.2(12)
O1 Cu1 N1 C5 . . 175.4(4)
N4 Cu1 N2 C6 . . 97.1(16)
N3 Cu1 N2 C6 . . 37.4(4)
N1 Cu1 N2 C6 . . -152.7(4)
O1 Cu1 N2 C6 . . -58.4(4)
N4 Cu1 N3 C8 . . 150.9(5)
N2 Cu1 N3 C8 . . -35.0(5)
N1 Cu1 N3 C8 . . -142.1(9)
O1 Cu1 N3 C8 . . 58.8(5)
N4 Cu1 N3 C9 . . 18.9(4)
N2 Cu1 N3 C9 . . -167.0(4)
N1 Cu1 N3 C9 . . 86.0(10)
O1 Cu1 N3 C9 . . -73.1(4)
N2 Cu1 N4 C10 . . -50.8(18)
N3 Cu1 N4 C10 . . 9.4(5)
N1 Cu1 N4 C10 . . -160.9(5)
O1 Cu1 N4 C10 . . 104.8(5)
C5 N1 C1 C2 . . 0.7(11)
Cu1 N1 C1 C2 . . -177.0(6)
N1 C1 C2 C3 . . -0.5(13)
C1 C2 C3 C4 . . -0.5(11)
C1 C2 C3 C3 . 3_566 179.4(7)
C2 C3 C4 C5 . . 1.2(9)
C3 C3 C4 C5 3_566 . -178.8(6)
C1 N1 C5 C4 . . 0.0(9)
Cu1 N1 C5 C4 . . 177.7(5)
C3 C4 C5 N1 . . -1.0(9)
Cu1 N2 C6 C7 . . -56.6(7)
N2 C6 C7 C8 . . 68.4(8)
C9 N3 C8 C7 . . 178.7(6)
Cu1 N3 C8 C7 . . 50.6(7)
C6 C7 C8 N3 . . -65.9(9)
C8 N3 C9 C10 . . -177.1(5)
Cu1 N3 C9 C10 . . -43.4(6)
Cu1 N4 C10 C9 . . -35.9(7)
N3 C9 C10 N4 . . 52.6(7)
