#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/14/2211488.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2211488
loop_
_publ_author_name
'Meijboom, Reinout'
'Muller, Alfred'
_publ_section_title
;
 Di-μ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]
;
_journal_coeditor_code           KP2051
_journal_issue                   12
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m3191
_journal_page_last               m3193
_journal_paper_doi               10.1107/S1600536806043601
_journal_volume                  62
_journal_year                    2006
_chemical_formula_iupac          'C52 H52 Ag2 I2 N2 P2'
_chemical_formula_moiety         'C52 H52 Ag2 I2 N2 P2'
_chemical_formula_sum            'C52 H52 Ag2 I2 N2 P2'
_chemical_formula_weight         1236.44
_chemical_name_systematic
;
Di-μ-iodo-bis[pyridine(tri-p-tolylphosphine)silver(I)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                104.67(3)
_cell_angle_beta                 113.24(3)
_cell_angle_gamma                96.44(3)
_cell_formula_units_Z            1
_cell_length_a                   10.006(2)
_cell_length_b                   11.957(2)
_cell_length_c                   12.184(2)
_cell_measurement_reflns_used    946
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      27.77
_cell_measurement_theta_min      3.44
_cell_volume                     1258.3(6)
_computing_cell_refinement       'SAINT-Plus (Bruker, 1999)'
_computing_data_collection       'SMART-NT (Bruker, 1999)'
_computing_data_reduction        'SAINT-Plus and XPREP (Bruker, 1999)'
_computing_molecular_graphics    'DIAMOND (Brandenburg & Putz, 2005)'
_computing_publication_material  'WinGX (Farrugia, 1999)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      298(2)
_diffrn_detector_area_resol_mean 512
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.015
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -12
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -11
_diffrn_reflns_number            6862
_diffrn_reflns_theta_full        25
_diffrn_reflns_theta_max         25
_diffrn_reflns_theta_min         1.81
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.104
_exptl_absorpt_correction_T_max  0.6285
_exptl_absorpt_correction_T_min  0.4396
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2004)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.632
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       cuboid
_exptl_crystal_F_000             608
_exptl_crystal_size_max          0.44
_exptl_crystal_size_mid          0.24
_exptl_crystal_size_min          0.22
_refine_diff_density_max         1.052
_refine_diff_density_min         -0.51
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.032
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     295
_refine_ls_number_reflns         4400
_refine_ls_number_restraints     8
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_gt           0.03
_refine_ls_shift/su_max          0
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0385P)²+0.8633P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.0784
_reflns_number_gt                3631
_reflns_number_total             4400
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            kp2051.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        1258.4(6)
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               2211488
_cod_database_fobs_code          2211488
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.40816(3) 0.37172(3) 0.41150(3) 0.05861(11) Uani d . 1 . .
I I 0.32215(3) 0.58235(2) 0.36615(3) 0.06131(11) Uani d . 1 . .
P P 0.42104(10) 0.24610(9) 0.22467(9) 0.0445(2) Uani d . 1 A .
C C11 0.4627(4) 0.1032(3) 0.2325(3) 0.0446(8) Uani d . 1 . .
C C12 0.5363(4) 0.0896(3) 0.3498(4) 0.0536(9) Uani d . 1 . .
H H12 0.56 0.1524 0.4227 0.064 Uiso calc R 1 . .
C C13 0.5748(4) -0.0160(4) 0.3596(4) 0.0580(10) Uani d . 1 . .
H H13 0.6261 -0.0224 0.4393 0.07 Uiso calc R 1 . .
C C14 0.5388(4) -0.1125(3) 0.2537(4) 0.0525(9) Uani d . 1 . .
C C15 0.4610(5) -0.0997(4) 0.1376(4) 0.0570(10) Uani d . 1 . .
H H15 0.4322 -0.1642 0.0649 0.068 Uiso calc R 1 . .
C C16 0.4249(4) 0.0054(4) 0.1259(4) 0.0548(10) Uani d . 1 . .
H H16 0.3746 0.0114 0.0459 0.066 Uiso calc R 1 . .
C C17 0.5786(6) -0.2283(4) 0.2638(5) 0.0759(13) Uani d . 1 . .
H H17A 0.6834 -0.2206 0.2861 0.114 Uiso calc R 1 . .
H H17B 0.5209 -0.2901 0.184 0.114 Uiso calc R 1 . .
H H17C 0.557 -0.248 0.3276 0.114 Uiso calc R 1 . .
C C21 0.2517(4) 0.2091(3) 0.0767(3) 0.0452(8) Uani d D 1 . .
C C24 -0.0192(4) 0.1549(3) -0.1437(4) 0.0551(10) Uani d D 1 . .
C C27 -0.1620(5) 0.1300(4) -0.2610(4) 0.0754(13) Uani d D 1 A .
H H27A -0.1992 0.2007 -0.2591 0.113 Uiso calc R 1 . .
H H27B -0.235 0.0676 -0.2651 0.113 Uiso calc R 1 . .
H H27C -0.1433 0.1056 -0.3339 0.113 Uiso calc R 1 . .
C C22 0.1162(9) 0.2037(12) 0.0813(7) 0.065(3) Uani d PD 0.81(2) A 1
H H22 0.1133 0.2186 0.159 0.078 Uiso calc PR 0.81(2) A 1
C C23 -0.0156(7) 0.1766(13) -0.0270(7) 0.073(3) Uani d PD 0.81(2) A 1
H H23 -0.1053 0.173 -0.0203 0.088 Uiso calc PR 0.81(2) A 1
C C25 0.1185(7) 0.1614(11) -0.1486(6) 0.059(2) Uani d PD 0.81(2) A 1
H H25 0.121 0.148 -0.2263 0.07 Uiso calc PR 0.81(2) A 1
C C26 0.2508(7) 0.1870(12) -0.0409(7) 0.059(2) Uani d PD 0.81(2) A 1
H H26 0.3406 0.1896 -0.0473 0.071 Uiso calc PR 0.81(2) A 1
C C22B 0.123(5) 0.147(4) 0.073(4) 0.074(11) Uani d PD 0.19(2) A 2
H H22B 0.1257 0.1241 0.1417 0.089 Uiso calc PR 0.19(2) A 2
C C23B -0.020(4) 0.118(3) -0.044(3) 0.071(10) Uiso d PD 0.19(2) A 2
H H23B -0.1077 0.075 -0.0503 0.085 Uiso calc PR 0.19(2) A 2
C C25B 0.109(3) 0.210(3) -0.131(3) 0.055(9) Uiso d PD 0.19(2) A 2
H H25B 0.111 0.2374 -0.1958 0.065 Uiso calc PR 0.19(2) A 2
C C26B 0.243(4) 0.230(3) -0.025(3) 0.041(8) Uiso d PD 0.19(2) A 2
H H26B 0.3313 0.2603 -0.027 0.05 Uiso calc PR 0.19(2) A 2
C C31 0.5664(4) 0.3147(3) 0.1909(3) 0.0447(8) Uani d . 1 . .
C C32 0.5510(4) 0.4149(4) 0.1533(4) 0.0609(10) Uani d . 1 A .
H H32 0.4688 0.4466 0.148 0.073 Uiso calc R 1 . .
C C33 0.6558(5) 0.4676(4) 0.1238(4) 0.0670(11) Uani d . 1 . .
H H33 0.6418 0.5337 0.0974 0.08 Uiso calc R 1 A .
C C34 0.7813(4) 0.4255(4) 0.1323(4) 0.0618(11) Uani d . 1 A .
C C35 0.8001(4) 0.3300(4) 0.1770(4) 0.0626(11) Uani d . 1 . .
H H35 0.8864 0.3023 0.1889 0.075 Uiso calc R 1 A .
C C36 0.6937(4) 0.2748(4) 0.2043(4) 0.0534(9) Uani d . 1 A .
H H36 0.7085 0.2097 0.2322 0.064 Uiso calc R 1 . .
C C37 0.8918(6) 0.4806(5) 0.0947(6) 0.0922(16) Uani d . 1 . .
H H37A 0.9711 0.4396 0.1072 0.138 Uiso calc PR 0.5 A .
H H37B 0.9329 0.5629 0.1455 0.138 Uiso calc PR 0.5 . .
H H37C 0.8422 0.4744 0.0072 0.138 Uiso calc PR 0.5 . .
H H37D 0.8597 0.545 0.0661 0.138 Uiso calc PR 0.5 . .
H H37E 0.8979 0.4217 0.0278 0.138 Uiso calc PR 0.5 . .
H H37F 0.9886 0.5102 0.1661 0.138 Uiso calc PR 0.5 . .
N N 0.2038(4) 0.3047(3) 0.4527(3) 0.0577(8) Uani d . 1 . .
C C42 0.1603(5) 0.3825(4) 0.5214(4) 0.0663(11) Uani d . 1 . .
H H42 0.2147 0.4613 0.5553 0.08 Uiso calc R 1 . .
C C43 0.0411(6) 0.3559(6) 0.5466(5) 0.0811(14) Uani d . 1 . .
H H43 0.0163 0.4147 0.5964 0.097 Uiso calc R 1 . .
C C44 -0.0389(6) 0.2430(6) 0.4977(5) 0.0896(17) Uani d . 1 . .
H H44 -0.1208 0.2221 0.5129 0.107 Uiso calc R 1 . .
C C45 0.0005(7) 0.1591(5) 0.4257(6) 0.0993(18) Uani d . 1 . .
H H45 -0.054 0.0803 0.3905 0.119 Uiso calc R 1 . .
C C46 0.1239(6) 0.1937(4) 0.4059(5) 0.0801(14) Uani d . 1 . .
H H46 0.1516 0.1361 0.3574 0.096 Uiso calc R 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
I I -0.4742 1.8119 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N Ag P . . 117.09(9) y
N Ag I . 2_666 107.99(8) y
P Ag I . 2_666 111.63(4) y
N Ag I . . 96.24(8) y
P Ag I . . 109.32(3) y
I Ag I 2_666 . 113.84(4) y
N Ag Ag . 2_666 112.44(9) ?
P Ag Ag . 2_666 129.83(4) ?
I Ag Ag 2_666 2_666 57.29(4) ?
I Ag Ag . 2_666 56.54(3) ?
Ag I Ag 2_666 . 66.16(4) y
C11 P C21 . . 104.54(17) ?
C11 P C31 . . 103.59(16) ?
C21 P C31 . . 103.37(16) ?
C11 P Ag . . 115.47(12) ?
C21 P Ag . . 115.15(12) ?
C31 P Ag . . 113.29(12) ?
C12 C11 C16 . . 117.5(3) ?
C12 C11 P . . 119.1(3) ?
C16 C11 P . . 123.3(3) ?
C13 C12 C11 . . 120.8(4) ?
C13 C12 H12 . . 119.6 ?
C11 C12 H12 . . 119.6 ?
C12 C13 C14 . . 121.5(4) ?
C12 C13 H13 . . 119.2 ?
C14 C13 H13 . . 119.2 ?
C15 C14 C13 . . 117.3(4) ?
C15 C14 C17 . . 120.9(4) ?
C13 C14 C17 . . 121.8(4) ?
C16 C15 C14 . . 121.9(4) ?
C16 C15 H15 . . 119 ?
C14 C15 H15 . . 119 ?
C15 C16 C11 . . 120.8(4) ?
C15 C16 H16 . . 119.6 ?
C11 C16 H16 . . 119.6 ?
C14 C17 H17A . . 109.5 ?
C14 C17 H17B . . 109.5 ?
H17A C17 H17B . . 109.5 ?
C14 C17 H17C . . 109.5 ?
H17A C17 H17C . . 109.5 ?
H17B C17 H17C . . 109.5 ?
C22 C21 C26 . . 117.4(5) ?
C26B C21 C22B . . 118(2) ?
C26B C21 P . . 126.3(14) ?
C22 C21 P . . 118.5(4) ?
C26 C21 P . . 124.1(3) ?
C22B C21 P . . 115.5(15) ?
C23 C24 C25 . . 116.6(4) ?
C25B C24 C23B . . 118(2) ?
C25B C24 C27 . . 122.0(14) ?
C23 C24 C27 . . 122.3(4) ?
C25 C24 C27 . . 121.1(4) ?
C23B C24 C27 . . 120.2(16) ?
C24 C27 H27A . . 109.5 ?
C24 C27 H27B . . 109.5 ?
H27A C27 H27B . . 109.5 ?
C24 C27 H27C . . 109.5 ?
H27A C27 H27C . . 109.5 ?
H27B C27 H27C . . 109.5 ?
C21 C22 C23 . . 121.2(6) ?
C21 C22 H22 . . 119.4 ?
C23 C22 H22 . . 119.4 ?
C24 C23 C22 . . 122.4(5) ?
C24 C23 H23 . . 118.8 ?
C22 C23 H23 . . 118.8 ?
C26 C25 C24 . . 121.5(5) ?
C26 C25 H25 . . 119.3 ?
C24 C25 H25 . . 119.3 ?
C25 C26 C21 . . 120.9(5) ?
C25 C26 H26 . . 119.5 ?
C21 C26 H26 . . 119.5 ?
C21 C22B C23B . . 118(3) ?
C21 C22B H22B . . 121.1 ?
C23B C22B H22B . . 121.1 ?
C24 C23B C22B . . 119(3) ?
C24 C23B H23B . . 120.4 ?
C22B C23B H23B . . 120.4 ?
C24 C25B C26B . . 122(3) ?
C24 C25B H25B . . 118.8 ?
C26B C25B H25B . . 118.8 ?
C21 C26B C25B . . 124(3) ?
C21 C26B H26B . . 118 ?
C25B C26B H26B . . 118 ?
C36 C31 C32 . . 117.7(3) ?
C36 C31 P . . 123.5(3) ?
C32 C31 P . . 118.8(3) ?
C33 C32 C31 . . 120.8(4) ?
C33 C32 H32 . . 119.6 ?
C31 C32 H32 . . 119.6 ?
C32 C33 C34 . . 122.0(4) ?
C32 C33 H33 . . 119 ?
C34 C33 H33 . . 119 ?
C33 C34 C35 . . 116.7(4) ?
C33 C34 C37 . . 121.6(4) ?
C35 C34 C37 . . 121.7(4) ?
C36 C35 C34 . . 121.5(4) ?
C36 C35 H35 . . 119.2 ?
C34 C35 H35 . . 119.2 ?
C31 C36 C35 . . 121.1(4) ?
C31 C36 H36 . . 119.5 ?
C35 C36 H36 . . 119.5 ?
C34 C37 H37A . . 109.5 ?
C34 C37 H37B . . 109.5 ?
H37A C37 H37B . . 109.5 ?
C34 C37 H37C . . 109.5 ?
H37A C37 H37C . . 109.5 ?
H37B C37 H37C . . 109.5 ?
C34 C37 H37D . . 109.5 ?
H37A C37 H37D . . 141.1 ?
H37B C37 H37D . . 56.3 ?
H37C C37 H37D . . 56.3 ?
C34 C37 H37E . . 109.5 ?
H37A C37 H37E . . 56.3 ?
H37B C37 H37E . . 141.1 ?
H37C C37 H37E . . 56.3 ?
H37D C37 H37E . . 109.5 ?
C34 C37 H37F . . 109.5 ?
H37A C37 H37F . . 56.3 ?
H37B C37 H37F . . 56.3 ?
H37C C37 H37F . . 141.1 ?
H37D C37 H37F . . 109.5 ?
H37E C37 H37F . . 109.5 ?
C42 N C46 . . 116.0(4) ?
C42 N Ag . . 119.5(3) ?
C46 N Ag . . 124.4(3) ?
N C42 C43 . . 124.9(5) ?
N C42 H42 . . 117.6 ?
C43 C42 H42 . . 117.6 ?
C44 C43 C42 . . 118.2(5) ?
C44 C43 H43 . . 120.9 ?
C42 C43 H43 . . 120.9 ?
C43 C44 C45 . . 119.5(5) ?
C43 C44 H44 . . 120.3 ?
C45 C44 H44 . . 120.3 ?
C44 C45 C46 . . 118.5(5) ?
C44 C45 H45 . . 120.7 ?
C46 C45 H45 . . 120.7 ?
N C46 C45 . . 122.9(5) ?
N C46 H46 . . 118.5 ?
C45 C46 H46 . . 118.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag N . 2.392(3) y
Ag P . 2.4489(12) y
Ag I 2_666 2.8402(14) y
Ag I . 2.8644(8) y
Ag Ag 2_666 3.1138(8) y
I Ag 2_666 2.8402(14) y
P C11 . 1.820(4) ?
P C21 . 1.825(4) ?
P C31 . 1.826(4) ?
C11 C12 . 1.387(5) ?
C11 C16 . 1.394(5) ?
C12 C13 . 1.381(5) ?
C12 H12 . 0.93 ?
C13 C14 . 1.382(6) ?
C13 H13 . 0.93 ?
C14 C15 . 1.378(5) ?
C14 C17 . 1.504(6) ?
C15 C16 . 1.371(5) ?
C15 H15 . 0.93 ?
C16 H16 . 0.93 ?
C17 H17A . 0.96 ?
C17 H17B . 0.96 ?
C17 H17C . 0.96 ?
C21 C26B . 1.30(3) ?
C21 C22 . 1.374(9) ?
C21 C26 . 1.386(8) ?
C21 C22B . 1.40(5) ?
C24 C25B . 1.31(3) ?
C24 C23 . 1.364(7) ?
C24 C25 . 1.397(8) ?
C24 C23B . 1.40(4) ?
C24 C27 . 1.500(5) ?
C27 H27A . 0.96 ?
C27 H27B . 0.96 ?
C27 H27C . 0.96 ?
C22 C23 . 1.378(10) ?
C22 H22 . 0.93 ?
C23 H23 . 0.93 ?
C25 C26 . 1.379(9) ?
C25 H25 . 0.93 ?
C26 H26 . 0.93 ?
C22B C23B . 1.49(5) ?
C22B H22B . 0.93 ?
C23B H23B . 0.93 ?
C25B C26B . 1.39(4) ?
C25B H25B . 0.93 ?
C26B H26B . 0.93 ?
C31 C36 . 1.374(5) ?
C31 C32 . 1.390(5) ?
C32 C33 . 1.375(6) ?
C32 H32 . 0.93 ?
C33 C34 . 1.381(6) ?
C33 H33 . 0.93 ?
C34 C35 . 1.385(6) ?
C34 C37 . 1.502(6) ?
C35 C36 . 1.384(5) ?
C35 H35 . 0.93 ?
C36 H36 . 0.93 ?
C37 H37A . 0.96 ?
C37 H37B . 0.96 ?
C37 H37C . 0.96 ?
C37 H37D . 0.96 ?
C37 H37E . 0.96 ?
C37 H37F . 0.96 ?
N C42 . 1.320(5) ?
N C46 . 1.320(6) ?
C42 C43 . 1.367(6) ?
C42 H42 . 0.93 ?
C43 C44 . 1.339(7) ?
C43 H43 . 0.93 ?
C44 C45 . 1.359(8) ?
C44 H44 . 0.93 ?
C45 C46 . 1.388(7) ?
C45 H45 . 0.93 ?
C46 H46 . 0.93 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
N Ag I Ag . 2_666 112.83(9) y
P Ag I Ag . 2_666 -125.58(4) y
I Ag I Ag 2_666 2_666 0 y
N Ag P C11 . . -68.25(16) ?
I Ag P C11 2_666 . 56.92(13) ?
I Ag P C11 . . -176.23(12) ?
Ag Ag P C11 2_666 . 121.69(13) ?
N Ag P C21 . . 53.82(16) ?
I Ag P C21 2_666 . 178.99(13) ?
I Ag P C21 . . -54.16(14) ?
Ag Ag P C21 2_666 . -116.24(13) ?
N Ag P C31 . . 172.51(15) ?
I Ag P C31 2_666 . -62.32(13) ?
I Ag P C31 . . 64.53(13) ?
Ag Ag P C31 2_666 . 2.46(13) ?
C21 P C11 C12 . . -150.9(3) ?
C31 P C11 C12 . . 101.1(3) ?
Ag P C11 C12 . . -23.3(3) ?
C21 P C11 C16 . . 29.4(4) ?
C31 P C11 C16 . . -78.5(3) ?
Ag P C11 C16 . . 157.0(3) ?
C16 C11 C12 C13 . . 2.1(6) ?
P C11 C12 C13 . . -177.5(3) ?
C11 C12 C13 C14 . . -1.4(6) ?
C12 C13 C14 C15 . . -0.8(6) ?
C12 C13 C14 C17 . . -179.2(4) ?
C13 C14 C15 C16 . . 2.4(6) ?
C17 C14 C15 C16 . . -179.2(4) ?
C14 C15 C16 C11 . . -1.7(6) ?
C12 C11 C16 C15 . . -0.6(6) ?
P C11 C16 C15 . . 179.0(3) ?
C11 P C21 C26B . . -109.0(18) ?
C31 P C21 C26B . . -0.9(18) ?
Ag P C21 C26B . . 123.2(17) ?
C11 P C21 C22 . . 99.2(7) ?
C31 P C21 C22 . . -152.7(7) ?
Ag P C21 C22 . . -28.6(7) ?
C11 P C21 C26 . . -81.6(8) ?
C31 P C21 C26 . . 26.6(8) ?
Ag P C21 C26 . . 150.7(7) ?
C11 P C21 C22B . . 67.5(17) ?
C31 P C21 C22B . . 175.6(17) ?
Ag P C21 C22B . . -60.3(17) ?
C26B C21 C22 C23 . . 23.7(14) ?
C26 C21 C22 C23 . . 0.5(8) ?
C22B C21 C22 C23 . . -89(4) ?
P C21 C22 C23 . . 179.8(5) ?
C25B C24 C23 C22 . . -26.2(16) ?
C25 C24 C23 C22 . . 0.1(9) ?
C23B C24 C23 C22 . . 88(3) ?
C27 C24 C23 C22 . . -177.7(5) ?
C21 C22 C23 C24 . . -0.7(9) ?
C25B C24 C25 C26 . . 78(4) ?
C23 C24 C25 C26 . . 0.7(10) ?
C23B C24 C25 C26 . . -30.0(17) ?
C27 C24 C25 C26 . . 178.5(6) ?
C24 C25 C26 C21 . . -0.9(12) ?
C26B C21 C26 C25 . . -76(4) ?
C22 C21 C26 C25 . . 0.3(10) ?
C22B C21 C26 C25 . . 31.5(15) ?
P C21 C26 C25 . . -179.0(5) ?
C26B C21 C22B C23B . . -5.1(15) ?
C22 C21 C22B C23B . . 75(3) ?
C26 C21 C22B C23B . . -29.6(13) ?
P C21 C22B C23B . . 178.1(6) ?
C25B C24 C23B C22B . . 2.7(19) ?
C23 C24 C23B C22B . . -75(3) ?
C25 C24 C23B C22B . . 30.0(15) ?
C27 C24 C23B C22B . . -178.1(6) ?
C21 C22B C23B C24 . . -1.0(12) ?
C23 C24 C25B C26B . . 31(3) ?
C25 C24 C25B C26B . . -82(4) ?
C23B C24 C25B C26B . . 2(3) ?
C27 C24 C25B C26B . . -177.6(17) ?
C22 C21 C26B C25B . . -20(2) ?
C26 C21 C26B C25B . . 94(5) ?
C22B C21 C26B C25B . . 10(3) ?
P C21 C26B C25B . . -173.7(17) ?
C24 C25B C26B C21 . . -8(4) ?
C11 P C31 C36 . . -15.0(3) ?
C21 P C31 C36 . . -123.8(3) ?
Ag P C31 C36 . . 110.9(3) ?
C11 P C31 C32 . . 167.1(3) ?
C21 P C31 C32 . . 58.2(3) ?
Ag P C31 C32 . . -67.1(3) ?
C36 C31 C32 C33 . . 3.6(6) ?
P C31 C32 C33 . . -178.3(3) ?
C31 C32 C33 C34 . . -1.2(7) ?
C32 C33 C34 C35 . . -2.5(7) ?
C32 C33 C34 C37 . . 177.4(5) ?
C33 C34 C35 C36 . . 3.9(6) ?
C37 C34 C35 C36 . . -176.0(4) ?
C32 C31 C36 C35 . . -2.2(6) ?
P C31 C36 C35 . . 179.8(3) ?
C34 C35 C36 C31 . . -1.6(6) ?
P Ag N C42 . . -156.8(3) ?
I Ag N C42 2_666 . 76.2(3) ?
I Ag N C42 . . -41.3(3) ?
Ag Ag N C42 2_666 . 15.0(3) ?
P Ag N C46 . . 19.7(4) ?
I Ag N C46 2_666 . -107.3(4) ?
I Ag N C46 . . 135.2(3) ?
Ag Ag N C46 2_666 . -168.5(3) ?
C46 N C42 C43 . . 0.1(7) ?
Ag N C42 C43 . . 176.9(4) ?
N C42 C43 C44 . . -0.5(8) ?
C42 C43 C44 C45 . . 0.2(8) ?
C43 C44 C45 C46 . . 0.4(9) ?
C42 N C46 C45 . . 0.5(7) ?
Ag N C46 C45 . . -176.1(4) ?
C44 C45 C46 N . . -0.8(9) ?
