#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/27/2212769.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2212769
loop_
_publ_author_name
'Yun-Feng Feng'
'Hong-Yan Wu'
'Bao-Lin Zhu'
'Shu-Rong Wang'
'Wei-Ping Huang'
_publ_section_title
Bis[μ₂-bis(salicylidene)propane-1,3-diaminato-κ⁴O,N,N',O':κ²O,O']bis(μ₂-nitrato-κO:κO')tricopper(II)
_journal_coeditor_code           BH2077
_journal_issue                   4
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1107
_journal_page_last               m1108
_journal_paper_doi               10.1107/S1600536807012172
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Cu3 (C17 H16 N2 O2)2 (N O3)2]'
_chemical_formula_moiety         'C34 H32 Cu3 N6 O10'
_chemical_formula_sum            'C34 H32 Cu3 N6 O10'
_chemical_formula_weight         875.28
_chemical_name_systematic
;
Bis[μ₂-bis(salicylidene)propane-1,3-diaminato-
\k^4^O,N,N',O':\k^2^O,O']bis(\m~2~-nitrato-\kO:\kO')tricopper(II)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_cell_angle_alpha                90.00
_cell_angle_beta                 101.038(5)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   8.897(3)
_cell_length_b                   11.658(3)
_cell_length_c                   16.107(5)
_cell_measurement_reflns_used    4051
_cell_measurement_temperature    113(2)
_cell_measurement_theta_max      27.9
_cell_measurement_theta_min      2.2
_cell_volume                     1639.7(9)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'CrystalStructure (Rigaku/MSC, 2005)'
_computing_publication_material  'SHELXTL (Bruker, 1998)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      113(2)
_diffrn_detector_area_resol_mean 7.31
_diffrn_measured_fraction_theta_full 1.000
_diffrn_measured_fraction_theta_max 1.000
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.0552
_diffrn_reflns_av_sigmaI/netI    0.0591
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       19
_diffrn_reflns_limit_l_min       -19
_diffrn_reflns_number            13271
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         2.17
_diffrn_standards_decay_%        0
_diffrn_standards_interval_count 0
_diffrn_standards_interval_time  0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.000
_exptl_absorpt_correction_T_max  0.9243
_exptl_absorpt_correction_T_min  0.8251
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            blue
_exptl_crystal_density_diffrn    1.773
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             890
_exptl_crystal_size_max          0.10
_exptl_crystal_size_mid          0.04
_exptl_crystal_size_min          0.04
_refine_diff_density_max         0.834
_refine_diff_density_min         -0.579
_refine_ls_extinction_coef       0.0018(3)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 1997)'
_refine_ls_goodness_of_fit_ref   1.110
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     243
_refine_ls_number_reflns         3218
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.110
_refine_ls_R_factor_all          0.0585
_refine_ls_R_factor_gt           0.0494
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0233P)²+4.2519P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0910
_refine_ls_wR_factor_ref         0.0955
_reflns_number_gt                2858
_reflns_number_total             3218
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            bh2077.cif
_cod_data_source_block           I
_cod_original_cell_volume        1639.7(8)
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2212769
_cod_database_fobs_code          2212769
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Cu Cu1 0.72320(5) 0.31586(4) 0.05836(3) 0.01300(15) Uani d . 1
Cu Cu2 0.5000 0.5000 0.0000 0.01269(18) Uani d S 1
O O1 0.6782(3) 0.4258(2) -0.03469(17) 0.0143(6) Uani d . 1
O O2 0.6062(3) 0.4308(2) 0.10639(16) 0.0148(6) Uani d . 1
O O3 0.6453(3) 0.6716(2) 0.03865(18) 0.0200(6) Uani d . 1
O O4 0.4784(3) 0.8069(2) -0.00358(19) 0.0211(6) Uani d . 1
O O5 0.7131(3) 0.8504(2) 0.0518(2) 0.0256(7) Uani d . 1
N N1 0.8876(3) 0.2432(3) 0.0113(2) 0.0136(7) Uani d . 1
N N2 0.7400(3) 0.2203(3) 0.1593(2) 0.0152(7) Uani d . 1
N N3 0.6130(4) 0.7764(3) 0.0298(2) 0.0162(7) Uani d . 1
C C1 0.7806(4) 0.4677(3) -0.0778(2) 0.0127(8) Uani d . 1
C C2 0.7535(4) 0.5710(3) -0.1223(2) 0.0153(8) Uani d . 1
H H2 0.6635 0.6136 -0.1196 0.018 Uiso calc R 1
C C3 0.8552(4) 0.6121(3) -0.1702(2) 0.0173(8) Uani d . 1
H H3 0.8331 0.6814 -0.2011 0.021 Uiso calc R 1
C C4 0.9902(4) 0.5526(4) -0.1735(3) 0.0183(9) Uani d . 1
H H4 1.0600 0.5813 -0.2063 0.022 Uiso calc R 1
C C5 1.0209(4) 0.4523(3) -0.1289(2) 0.0168(8) Uani d . 1
H H5 1.1132 0.4122 -0.1306 0.020 Uiso calc R 1
C C6 0.9177(4) 0.4076(3) -0.0804(2) 0.0143(8) Uani d . 1
C C7 0.9581(4) 0.2976(3) -0.0399(2) 0.0144(8) Uani d . 1
H H7 1.0468 0.2614 -0.0524 0.017 Uiso calc R 1
C C8 0.9422(5) 0.1258(3) 0.0351(3) 0.0197(9) Uani d . 1
H H8A 1.0479 0.1178 0.0248 0.024 Uiso calc R 1
H H8B 0.8770 0.0705 -0.0022 0.024 Uiso calc R 1
C C9 0.9418(4) 0.0939(3) 0.1260(3) 0.0184(9) Uani d . 1
H H9A 1.0128 0.1457 0.1633 0.022 Uiso calc R 1
H H9B 0.9821 0.0149 0.1359 0.022 Uiso calc R 1
C C10 0.7856(4) 0.0997(3) 0.1514(3) 0.0184(9) Uani d . 1
H H10A 0.7085 0.0605 0.1082 0.022 Uiso calc R 1
H H10B 0.7900 0.0598 0.2061 0.022 Uiso calc R 1
C C11 0.7050(4) 0.2517(3) 0.2292(2) 0.0157(8) Uani d . 1
H H11 0.7103 0.1949 0.2720 0.019 Uiso calc R 1
C C12 0.6577(4) 0.3658(3) 0.2493(2) 0.0143(8) Uani d . 1
C C13 0.6185(4) 0.4541(3) 0.1889(2) 0.0136(8) Uani d . 1
C C14 0.5902(4) 0.5643(3) 0.2165(2) 0.0165(8) Uani d . 1
H H14 0.5675 0.6250 0.1767 0.020 Uiso calc R 1
C C15 0.5951(4) 0.5851(4) 0.3018(3) 0.0221(9) Uani d . 1
H H15 0.5792 0.6610 0.3199 0.027 Uiso calc R 1
C C16 0.6229(5) 0.4977(4) 0.3613(3) 0.0237(10) Uani d . 1
H H16 0.6205 0.5124 0.4191 0.028 Uiso calc R 1
C C17 0.6539(4) 0.3894(4) 0.3350(3) 0.0204(9) Uani d . 1
H H17 0.6731 0.3291 0.3753 0.025 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cu Cu 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O2 Cu1 N2 . . 91.35(12)
O2 Cu1 O1 . . 78.85(11)
N2 Cu1 O1 . . 169.87(12)
O2 Cu1 N1 . . 160.95(12)
N2 Cu1 N1 . . 97.56(13)
O1 Cu1 N1 . . 92.57(12)
O2 Cu1 O4 . 3_665 98.17(11)
N2 Cu1 O4 . 3_665 84.00(12)
O1 Cu1 O4 . 3_665 94.75(10)
N1 Cu1 O4 . 3_665 99.48(12)
O2 Cu1 Cu2 . . 41.20(8)
N2 Cu1 Cu2 . . 128.28(9)
O1 Cu1 Cu2 . . 41.64(7)
N1 Cu1 Cu2 . . 134.08(9)
O4 Cu1 Cu2 3_665 . 84.51(7)
O2 Cu2 O2 . 3_665 180.0
O2 Cu2 O1 . 3_665 102.16(10)
O2 Cu2 O1 3_665 3_665 77.84(10)
O2 Cu2 O1 . . 77.84(10)
O2 Cu2 O1 3_665 . 102.16(10)
O1 Cu2 O1 3_665 . 180.00(14)
O2 Cu2 O3 . 3_665 91.67(10)
O2 Cu2 O3 3_665 3_665 88.33(10)
O1 Cu2 O3 3_665 3_665 90.95(10)
O1 Cu2 O3 . 3_665 89.05(10)
O2 Cu2 O3 . . 88.33(10)
O2 Cu2 O3 3_665 . 91.67(10)
O1 Cu2 O3 3_665 . 89.05(10)
O1 Cu2 O3 . . 90.95(10)
O3 Cu2 O3 3_665 . 180.0
O2 Cu2 Cu1 . 3_665 139.28(7)
O2 Cu2 Cu1 3_665 3_665 40.72(7)
O1 Cu2 Cu1 3_665 3_665 41.03(8)
O1 Cu2 Cu1 . 3_665 138.97(8)
O3 Cu2 Cu1 3_665 3_665 103.15(7)
O3 Cu2 Cu1 . 3_665 76.85(7)
O2 Cu2 Cu1 . . 40.72(7)
O2 Cu2 Cu1 3_665 . 139.28(7)
O1 Cu2 Cu1 3_665 . 138.97(8)
O1 Cu2 Cu1 . . 41.03(8)
O3 Cu2 Cu1 3_665 . 76.85(7)
O3 Cu2 Cu1 . . 103.15(7)
Cu1 Cu2 Cu1 3_665 . 180.0
C1 O1 Cu1 . . 125.3(2)
C1 O1 Cu2 . . 130.4(2)
Cu1 O1 Cu2 . . 97.33(11)
C13 O2 Cu1 . . 125.8(2)
C13 O2 Cu2 . . 135.7(2)
Cu1 O2 Cu2 . . 98.08(11)
N3 O3 Cu2 . . 132.9(2)
N3 O4 Cu1 . 3_665 125.8(2)
C7 N1 C8 . . 116.3(3)
C7 N1 Cu1 . . 121.5(3)
C8 N1 Cu1 . . 122.1(2)
C11 N2 C10 . . 117.8(3)
C11 N2 Cu1 . . 125.3(3)
C10 N2 Cu1 . . 116.8(3)
O5 N3 O3 . . 120.4(3)
O5 N3 O4 . . 119.6(3)
O3 N3 O4 . . 119.9(3)
O1 C1 C2 . . 120.8(3)
O1 C1 C6 . . 120.6(3)
C2 C1 C6 . . 118.5(3)
C3 C2 C1 . . 121.1(4)
C3 C2 H2 . . 119.4
C1 C2 H2 . . 119.4
C2 C3 C4 . . 120.6(4)
C2 C3 H3 . . 119.7
C4 C3 H3 . . 119.7
C5 C4 C3 . . 119.3(4)
C5 C4 H4 . . 120.4
C3 C4 H4 . . 120.4
C4 C5 C6 . . 121.2(3)
C4 C5 H5 . . 119.4
C6 C5 H5 . . 119.4
C1 C6 C5 . . 119.2(3)
C1 C6 C7 . . 124.5(3)
C5 C6 C7 . . 116.2(3)
N1 C7 C6 . . 127.6(3)
N1 C7 H7 . . 116.2
C6 C7 H7 . . 116.2
N1 C8 C9 . . 114.7(3)
N1 C8 H8A . . 108.6
C9 C8 H8A . . 108.6
N1 C8 H8B . . 108.6
C9 C8 H8B . . 108.6
H8A C8 H8B . . 107.6
C8 C9 C10 . . 114.9(3)
C8 C9 H9A . . 108.5
C10 C9 H9A . . 108.5
C8 C9 H9B . . 108.5
C10 C9 H9B . . 108.5
H9A C9 H9B . . 107.5
N2 C10 C9 . . 110.2(3)
N2 C10 H10A . . 109.6
C9 C10 H10A . . 109.6
N2 C10 H10B . . 109.6
C9 C10 H10B . . 109.6
H10A C10 H10B . . 108.1
N2 C11 C12 . . 126.1(4)
N2 C11 H11 . . 117.0
C12 C11 H11 . . 117.0
C17 C12 C13 . . 118.8(4)
C17 C12 C11 . . 117.3(4)
C13 C12 C11 . . 123.9(4)
O2 C13 C14 . . 121.1(4)
O2 C13 C12 . . 119.9(3)
C14 C13 C12 . . 119.0(4)
C15 C14 C13 . . 120.2(4)
C15 C14 H14 . . 119.9
C13 C14 H14 . . 119.9
C14 C15 C16 . . 121.5(4)
C14 C15 H15 . . 119.2
C16 C15 H15 . . 119.2
C17 C16 C15 . . 118.7(4)
C17 C16 H16 . . 120.7
C15 C16 H16 . . 120.7
C16 C17 C12 . . 121.5(4)
C16 C17 H17 . . 119.2
C12 C17 H17 . . 119.2
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Cu1 O2 . 1.946(3)
Cu1 N2 . 1.953(3)
Cu1 O1 . 1.955(3)
Cu1 N1 . 1.963(3)
Cu1 O4 3_665 2.332(3)
Cu1 Cu2 . 2.9531(7)
Cu2 O2 . 1.965(3)
Cu2 O2 3_665 1.965(3)
Cu2 O1 3_665 1.978(2)
Cu2 O1 . 1.978(2)
Cu2 O3 3_665 2.399(3)
Cu2 O3 . 2.399(3)
Cu2 Cu1 3_665 2.9531(7)
O1 C1 . 1.339(4)
O2 C13 . 1.340(4)
O3 N3 . 1.257(4)
O4 N3 . 1.266(4)
O4 Cu1 3_665 2.332(3)
O5 N3 . 1.242(4)
N1 C7 . 1.293(5)
N1 C8 . 1.479(5)
N2 C11 . 1.278(5)
N2 C10 . 1.475(5)
C1 C2 . 1.398(5)
C1 C6 . 1.414(5)
C2 C3 . 1.382(5)
C2 H2 . 0.9500
C3 C4 . 1.396(5)
C3 H3 . 0.9500
C4 C5 . 1.373(6)
C4 H4 . 0.9500
C5 C6 . 1.414(5)
C5 H5 . 0.9500
C6 C7 . 1.452(5)
C7 H7 . 0.9500
C8 C9 . 1.510(6)
C8 H8A . 0.9900
C8 H8B . 0.9900
C9 C10 . 1.524(5)
C9 H9A . 0.9900
C9 H9B . 0.9900
C10 H10A . 0.9900
C10 H10B . 0.9900
C11 C12 . 1.451(5)
C11 H11 . 0.9500
C12 C17 . 1.413(5)
C12 C13 . 1.413(5)
C13 C14 . 1.398(5)
C14 C15 . 1.388(6)
C14 H14 . 0.9500
C15 C16 . 1.388(6)
C15 H15 . 0.9500
C16 C17 . 1.377(6)
C16 H16 . 0.9500
C17 H17 . 0.9500
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
N2 Cu1 Cu2 O2 . . 31.15(16)
O1 Cu1 Cu2 O2 . . -147.46(16)
N1 Cu1 Cu2 O2 . . -153.06(17)
O4 Cu1 Cu2 O2 3_665 . 109.05(14)
O2 Cu1 Cu2 O2 . 3_665 180.0
N2 Cu1 Cu2 O2 . 3_665 -148.85(16)
O1 Cu1 Cu2 O2 . 3_665 32.54(16)
N1 Cu1 Cu2 O2 . 3_665 26.94(17)
O4 Cu1 Cu2 O2 3_665 3_665 -70.95(14)
O2 Cu1 Cu2 O1 . 3_665 -32.54(16)
N2 Cu1 Cu2 O1 . 3_665 -1.39(17)
O1 Cu1 Cu2 O1 . 3_665 180.0
N1 Cu1 Cu2 O1 . 3_665 174.40(17)
O4 Cu1 Cu2 O1 3_665 3_665 76.51(14)
O2 Cu1 Cu2 O1 . . 147.46(16)
N2 Cu1 Cu2 O1 . . 178.61(17)
N1 Cu1 Cu2 O1 . . -5.60(17)
O4 Cu1 Cu2 O1 3_665 . -103.49(14)
O2 Cu1 Cu2 O3 . 3_665 -108.51(14)
N2 Cu1 Cu2 O3 . 3_665 -77.35(14)
O1 Cu1 Cu2 O3 . 3_665 104.04(13)
N1 Cu1 Cu2 O3 . 3_665 98.44(15)
O4 Cu1 Cu2 O3 3_665 3_665 0.55(10)
O2 Cu1 Cu2 O3 . . 71.49(14)
N2 Cu1 Cu2 O3 . . 102.65(14)
O1 Cu1 Cu2 O3 . . -75.96(13)
N1 Cu1 Cu2 O3 . . -81.56(15)
O4 Cu1 Cu2 O3 3_665 . -179.45(10)
O2 Cu1 O1 C1 . . 131.9(3)
N2 Cu1 O1 C1 . . 146.9(6)
N1 Cu1 O1 C1 . . -30.9(3)
O4 Cu1 O1 C1 3_665 . -130.7(3)
Cu2 Cu1 O1 C1 . . 153.1(3)
O2 Cu1 O1 Cu2 . . -21.17(11)
N2 Cu1 O1 Cu2 . . -6.2(7)
N1 Cu1 O1 Cu2 . . 175.98(12)
O4 Cu1 O1 Cu2 3_665 . 76.24(11)
O2 Cu2 O1 C1 . . -129.9(3)
O2 Cu2 O1 C1 3_665 . 50.1(3)
O3 Cu2 O1 C1 3_665 . 138.1(3)
O3 Cu2 O1 C1 . . -41.9(3)
Cu1 Cu2 O1 C1 3_665 . 29.0(4)
Cu1 Cu2 O1 C1 . . -151.0(4)
O2 Cu2 O1 Cu1 . . 21.04(11)
O2 Cu2 O1 Cu1 3_665 . -158.96(11)
O3 Cu2 O1 Cu1 3_665 . -70.88(11)
O3 Cu2 O1 Cu1 . . 109.12(11)
Cu1 Cu2 O1 Cu1 3_665 . 180.0
N2 Cu1 O2 C13 . . 29.9(3)
O1 Cu1 O2 C13 . . -152.7(3)
N1 Cu1 O2 C13 . . -88.2(5)
O4 Cu1 O2 C13 3_665 . 114.1(3)
Cu2 Cu1 O2 C13 . . -174.0(3)
N2 Cu1 O2 Cu2 . . -156.03(12)
O1 Cu1 O2 Cu2 . . 21.36(11)
N1 Cu1 O2 Cu2 . . 85.8(4)
O4 Cu1 O2 Cu2 3_665 . -71.90(12)
O1 Cu2 O2 C13 3_665 . -28.1(3)
O1 Cu2 O2 C13 . . 151.9(3)
O3 Cu2 O2 C13 3_665 . -119.4(3)
O3 Cu2 O2 C13 . . 60.6(3)
Cu1 Cu2 O2 C13 3_665 . -6.9(4)
Cu1 Cu2 O2 C13 . . 173.1(4)
O1 Cu2 O2 Cu1 3_665 . 158.82(11)
O1 Cu2 O2 Cu1 . . -21.18(11)
O3 Cu2 O2 Cu1 3_665 . 67.49(11)
O3 Cu2 O2 Cu1 . . -112.51(11)
Cu1 Cu2 O2 Cu1 3_665 . 180.0
O2 Cu2 O3 N3 . . -142.3(3)
O2 Cu2 O3 N3 3_665 . 37.7(3)
O1 Cu2 O3 N3 3_665 . -40.1(3)
O1 Cu2 O3 N3 . . 139.9(3)
Cu1 Cu2 O3 N3 3_665 . -0.5(3)
Cu1 Cu2 O3 N3 . . 179.5(3)
O2 Cu1 N1 C7 . . -38.8(6)
N2 Cu1 N1 C7 . . -156.0(3)
O1 Cu1 N1 C7 . . 23.6(3)
O4 Cu1 N1 C7 3_665 . 118.8(3)
Cu2 Cu1 N1 C7 . . 27.3(4)
O2 Cu1 N1 C8 . . 138.4(4)
N2 Cu1 N1 C8 . . 21.2(3)
O1 Cu1 N1 C8 . . -159.2(3)
O4 Cu1 N1 C8 3_665 . -64.0(3)
Cu2 Cu1 N1 C8 . . -155.5(2)
O2 Cu1 N2 C11 . . -11.3(3)
O1 Cu1 N2 C11 . . -26.0(9)
N1 Cu1 N2 C11 . . 151.8(3)
O4 Cu1 N2 C11 3_665 . -109.4(3)
Cu2 Cu1 N2 C11 . . -31.3(4)
O2 Cu1 N2 C10 . . 163.7(3)
O1 Cu1 N2 C10 . . 149.0(6)
N1 Cu1 N2 C10 . . -33.2(3)
O4 Cu1 N2 C10 3_665 . 65.6(3)
Cu2 Cu1 N2 C10 . . 143.8(2)
Cu2 O3 N3 O5 . . -176.1(3)
Cu2 O3 N3 O4 . . 2.2(5)
Cu1 O4 N3 O5 3_665 . 175.4(3)
Cu1 O4 N3 O3 3_665 . -2.9(5)
Cu1 O1 C1 C2 . . -158.4(3)
Cu2 O1 C1 C2 . . -14.5(5)
Cu1 O1 C1 C6 . . 22.5(5)
Cu2 O1 C1 C6 . . 166.4(3)
O1 C1 C2 C3 . . -177.0(3)
C6 C1 C2 C3 . . 2.1(6)
C1 C2 C3 C4 . . -1.6(6)
C2 C3 C4 C5 . . 0.2(6)
C3 C4 C5 C6 . . 0.7(6)
O1 C1 C6 C5 . . 177.8(3)
C2 C1 C6 C5 . . -1.2(5)
O1 C1 C6 C7 . . 1.5(6)
C2 C1 C6 C7 . . -177.6(4)
C4 C5 C6 C1 . . -0.1(6)
C4 C5 C6 C7 . . 176.5(4)
C8 N1 C7 C6 . . 172.6(4)
Cu1 N1 C7 C6 . . -10.0(5)
C1 C6 C7 N1 . . -8.0(6)
C5 C6 C7 N1 . . 175.5(4)
C7 N1 C8 C9 . . 142.3(4)
Cu1 N1 C8 C9 . . -35.1(4)
N1 C8 C9 C10 . . 59.4(5)
C11 N2 C10 C9 . . -125.1(4)
Cu1 N2 C10 C9 . . 59.5(4)
C8 C9 C10 N2 . . -73.3(4)
C10 N2 C11 C12 . . 179.9(3)
Cu1 N2 C11 C12 . . -5.1(5)
N2 C11 C12 C17 . . -167.5(4)
N2 C11 C12 C13 . . 11.4(6)
Cu1 O2 C13 C14 . . 149.7(3)
Cu2 O2 C13 C14 . . -21.8(5)
Cu1 O2 C13 C12 . . -31.5(5)
Cu2 O2 C13 C12 . . 157.0(3)
C17 C12 C13 O2 . . -173.3(3)
C11 C12 C13 O2 . . 7.9(5)
C17 C12 C13 C14 . . 5.5(5)
C11 C12 C13 C14 . . -173.3(3)
O2 C13 C14 C15 . . 176.4(3)
C12 C13 C14 C15 . . -2.4(6)
C13 C14 C15 C16 . . -2.2(6)
C14 C15 C16 C17 . . 3.4(6)
C15 C16 C17 C12 . . -0.1(6)
C13 C12 C17 C16 . . -4.3(6)
C11 C12 C17 C16 . . 174.6(4)
