#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/38/2213833.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2213833
loop_
_publ_author_name
'Rong Li'
_publ_section_title
Bis{tris[μ-2-(1H-pyrazol-3-yl-κN¹:κN²)pyridinato-κN]trisilver(I)}(2Ag---Ag)
_journal_coeditor_code           HK2246
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1640
_journal_page_last               m1640
_journal_paper_doi               10.1107/S1600536807022581
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag6 (C8 H6 N3)6]'
_chemical_formula_moiety         'C48 H36 Ag6 N18'
_chemical_formula_sum            'C48 H36 Ag6 N18'
_chemical_formula_weight         1512.17
_chemical_name_systematic
;
Bis{tris[μ-2-(1H-pyrazol-3-yl-κN¹:κN²)pyridinato-
κN]trisilver(I)}(2 Ag---Ag)
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL97
_cell_angle_alpha                90.00
_cell_angle_beta                 103.16(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            2
_cell_length_a                   11.5599(17)
_cell_length_b                   8.5424(13)
_cell_length_c                   25.389(4)
_cell_measurement_reflns_used    4311
_cell_measurement_temperature    294(2)
_cell_measurement_theta_max      25.9200
_cell_measurement_theta_min      2.5226
_cell_volume                     2441.3(7)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        SAINT
_computing_molecular_graphics    'SHELXTL (Bruker, 1998)'
_computing_publication_material  SHELXTL
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      294(2)
_diffrn_measured_fraction_theta_full 0.994
_diffrn_measured_fraction_theta_max 0.994
_diffrn_measurement_device_type  'Bruker SMART CCD area-detecter'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0341
_diffrn_reflns_av_sigmaI/netI    0.0374
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -10
_diffrn_reflns_limit_k_max       10
_diffrn_reflns_limit_k_min       -10
_diffrn_reflns_limit_l_max       28
_diffrn_reflns_limit_l_min       -30
_diffrn_reflns_number            11942
_diffrn_reflns_theta_full        25.01
_diffrn_reflns_theta_max         25.01
_diffrn_reflns_theta_min         2.52
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.416
_exptl_absorpt_correction_T_max  0.7942
_exptl_absorpt_correction_T_min  0.6185
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    2.057
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1464
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.323
_refine_diff_density_min         -0.285
_refine_ls_extinction_coef       0.00435(13)
_refine_ls_extinction_expression Fc^*^=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4^
_refine_ls_extinction_method     'SHELXL97 (Sheldrick, 1997)'
_refine_ls_goodness_of_fit_ref   1.040
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     326
_refine_ls_number_reflns         4272
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.040
_refine_ls_R_factor_all          0.0489
_refine_ls_R_factor_gt           0.0265
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w = 1/[σ²(Fo²)+(0.0176P)²+0.4151P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0487
_refine_ls_wR_factor_ref         0.0562
_reflns_number_gt                3045
_reflns_number_total             4272
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hk2246.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_database_code               2213833
_cod_database_fobs_code          2213833
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Ag Ag1 0.22972(3) 0.51678(4) 0.144579(13) 0.05937(12) Uani d . 1
Ag Ag2 0.13707(3) 0.75885(4) 0.019264(12) 0.05891(12) Uani d . 1
Ag Ag3 0.08700(3) 0.50068(3) -0.069650(12) 0.05764(11) Uani d . 1
C C1 0.4993(4) 0.4002(5) 0.24241(17) 0.0697(12) Uani d . 1
H H1 0.4499 0.3419 0.2591 0.084 Uiso calc R 1
C C2 0.6178(4) 0.3998(5) 0.26535(17) 0.0667(12) Uani d . 1
H H2 0.6482 0.3438 0.2969 0.080 Uiso calc R 1
C C3 0.6911(4) 0.4843(5) 0.24049(17) 0.0623(11) Uani d . 1
H H3 0.7727 0.4855 0.2547 0.075 Uiso calc R 1
C C4 0.6425(3) 0.5671(4) 0.19450(15) 0.0518(10) Uani d . 1
H H4 0.6908 0.6255 0.1772 0.062 Uiso calc R 1
C C5 0.5205(3) 0.5630(4) 0.17397(15) 0.0449(9) Uani d . 1
C C6 0.4638(3) 0.6537(4) 0.12573(14) 0.0450(9) Uani d . 1
C C7 0.5113(4) 0.7506(5) 0.09238(17) 0.0661(12) Uani d . 1
H H7 0.5910 0.7732 0.0948 0.079 Uiso calc R 1
C C8 0.4152(4) 0.8060(5) 0.05497(17) 0.0668(12) Uani d . 1
H H8 0.4192 0.8742 0.0269 0.080 Uiso calc R 1
C C9 0.1409(4) 1.0506(5) -0.08115(18) 0.0613(11) Uani d . 1
H H9 0.2225 1.0554 -0.0672 0.074 Uiso calc R 1
C C10 0.0920(4) 1.1513(5) -0.12247(18) 0.0694(12) Uani d . 1
H H10 0.1390 1.2216 -0.1362 0.083 Uiso calc R 1
C C11 -0.0289(4) 1.1445(5) -0.14278(17) 0.0721(13) Uani d . 1
H H11 -0.0653 1.2105 -0.1708 0.087 Uiso calc R 1
C C12 -0.0954(4) 1.0389(5) -0.12118(16) 0.0621(11) Uani d . 1
H H12 -0.1773 1.0346 -0.1340 0.075 Uiso calc R 1
C C13 -0.0396(3) 0.9396(4) -0.08040(14) 0.0449(9) Uani d . 1
C C14 -0.1060(3) 0.8254(4) -0.05652(14) 0.0457(9) Uani d . 1
C C15 -0.2251(3) 0.7862(5) -0.06899(16) 0.0601(11) Uani d . 1
H H15 -0.2847 0.8297 -0.0959 0.072 Uiso calc R 1
C C16 -0.2374(3) 0.6695(5) -0.03332(17) 0.0622(12) Uani d . 1
H H16 -0.3083 0.6196 -0.0322 0.075 Uiso calc R 1
C C17 0.3620(4) 0.6835(6) -0.0800(2) 0.0778(14) Uani d . 1
H H17 0.3966 0.6296 -0.0485 0.093 Uiso calc R 1
C C18 0.4308(5) 0.7882(7) -0.1007(3) 0.0953(17) Uani d . 1
H H18 0.5093 0.8064 -0.0830 0.114 Uiso calc R 1
C C19 0.3823(5) 0.8637(6) -0.1472(3) 0.0904(17) Uani d . 1
H H19 0.4279 0.9328 -0.1623 0.109 Uiso calc R 1
C C20 0.2645(4) 0.8382(5) -0.1722(2) 0.0720(13) Uani d . 1
H H20 0.2296 0.8900 -0.2041 0.086 Uiso calc R 1
C C21 0.1997(3) 0.7331(5) -0.14861(17) 0.0537(10) Uani d . 1
C C22 0.0750(3) 0.6993(4) -0.17222(15) 0.0475(9) Uani d . 1
C C23 -0.0011(4) 0.7552(5) -0.21866(17) 0.0630(11) Uani d . 1
H H23 0.0162 0.8268 -0.2434 0.076 Uiso calc R 1
C C24 0.1065(4) 0.3171(5) 0.22022(16) 0.0602(11) Uani d . 1
H H24 0.1751 0.3028 0.2472 0.072 Uiso calc R 1
N N1 0.4490(3) 0.4793(4) 0.19730(13) 0.0556(8) Uani d . 1
N N2 0.3454(2) 0.6541(3) 0.10872(12) 0.0486(8) Uani d . 1
N N3 0.3155(3) 0.7482(4) 0.06472(12) 0.0550(8) Uani d . 1
N N4 0.0787(3) 0.9466(3) -0.05986(12) 0.0502(8) Uani d . 1
N N5 -0.0509(3) 0.7343(3) -0.01512(11) 0.0463(7) Uani d . 1
N N6 -0.1315(3) 0.6389(4) -0.00049(12) 0.0522(8) Uani d . 1
N N7 0.2489(3) 0.6559(4) -0.10277(14) 0.0598(9) Uani d . 1
N N8 0.0148(3) 0.5983(3) -0.14802(12) 0.0497(8) Uani d . 1
N N9 0.0978(3) 0.4114(4) 0.17768(12) 0.0521(8) Uani d . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N9 Ag1 N2 . . 171.11(12)
N9 Ag1 N1 . . 116.85(11)
N2 Ag1 N1 . . 69.83(10)
N3 Ag2 N5 . . 168.18(12)
N3 Ag2 N4 . . 120.48(11)
N5 Ag2 N4 . . 71.33(10)
N3 Ag2 Ag3 . . 111.15(9)
N5 Ag2 Ag3 . . 68.55(7)
N4 Ag2 Ag3 . . 84.36(7)
N6 Ag3 N8 3_565 . 166.69(12)
N6 Ag3 N7 3_565 . 120.62(11)
N8 Ag3 N7 . . 69.91(11)
N6 Ag3 Ag2 3_565 . 79.55(9)
N8 Ag3 Ag2 . . 111.48(8)
N7 Ag3 Ag2 . . 81.01(7)
N1 C1 C2 . . 124.4(4)
N1 C1 H1 . . 117.8
C2 C1 H1 . . 117.8
C1 C2 C3 . . 117.9(4)
C1 C2 H2 . . 121.0
C3 C2 H2 . . 121.0
C2 C3 C4 . . 119.2(4)
C2 C3 H3 . . 120.4
C4 C3 H3 . . 120.4
C3 C4 C5 . . 119.4(4)
C3 C4 H4 . . 120.3
C5 C4 H4 . . 120.3
N1 C5 C4 . . 121.9(3)
N1 C5 C6 . . 116.7(3)
C4 C5 C6 . . 121.4(3)
N2 C6 C7 . . 108.7(3)
N2 C6 C5 . . 119.9(3)
C7 C6 C5 . . 131.4(3)
C8 C7 C6 . . 105.0(3)
C8 C7 H7 . . 127.5
C6 C7 H7 . . 127.5
N3 C8 C7 . . 110.1(4)
N3 C8 H8 . . 125.0
C7 C8 H8 . . 125.0
N4 C9 C10 . . 124.1(4)
N4 C9 H9 . . 118.0
C10 C9 H9 . . 118.0
C9 C10 C11 . . 117.8(4)
C9 C10 H10 . . 121.1
C11 C10 H10 . . 121.1
C10 C11 C12 . . 119.3(4)
C10 C11 H11 . . 120.3
C12 C11 H11 . . 120.3
C11 C12 C13 . . 119.6(4)
C11 C12 H12 . . 120.2
C13 C12 H12 . . 120.2
N4 C13 C12 . . 121.5(4)
N4 C13 C14 . . 116.9(3)
C12 C13 C14 . . 121.6(4)
N5 C14 C15 . . 108.0(3)
N5 C14 C13 . . 120.8(3)
C15 C14 C13 . . 131.2(3)
C16 C15 C14 . . 105.7(3)
C16 C15 H15 . . 127.1
C14 C15 H15 . . 127.1
N6 C16 C15 . . 109.5(4)
N6 C16 H16 . . 125.2
C15 C16 H16 . . 125.2
N7 C17 C18 . . 123.2(5)
N7 C17 H17 . . 118.4
C18 C17 H17 . . 118.4
C19 C18 C17 . . 118.8(5)
C19 C18 H18 . . 120.6
C17 C18 H18 . . 120.6
C18 C19 C20 . . 119.8(5)
C18 C19 H19 . . 120.1
C20 C19 H19 . . 120.1
C19 C20 C21 . . 118.4(5)
C19 C20 H20 . . 120.8
C21 C20 H20 . . 120.8
N7 C21 C20 . . 121.7(4)
N7 C21 C22 . . 116.3(3)
C20 C21 C22 . . 122.0(4)
N8 C22 C23 . . 108.4(3)
N8 C22 C21 . . 120.4(3)
C23 C22 C21 . . 131.2(4)
C24 C23 C22 3_565 . 105.0(4)
C24 C23 H23 3_565 . 127.5
C22 C23 H23 . . 127.5
N9 C24 C23 . 3_565 110.5(4)
N9 C24 H24 . . 124.8
C23 C24 H24 3_565 . 124.8
C5 N1 C1 . . 117.2(3)
C5 N1 Ag1 . . 109.7(2)
C1 N1 Ag1 . . 133.0(3)
C6 N2 N3 . . 108.5(3)
C6 N2 Ag1 . . 123.8(2)
N3 N2 Ag1 . . 127.7(2)
C8 N3 N2 . . 107.7(3)
C8 N3 Ag2 . . 131.3(3)
N2 N3 Ag2 . . 120.5(2)
C9 N4 C13 . . 117.7(3)
C9 N4 Ag2 . . 132.2(3)
C13 N4 Ag2 . . 110.0(2)
C14 N5 N6 . . 109.3(3)
C14 N5 Ag2 . . 120.9(2)
N6 N5 Ag2 . . 129.8(2)
C16 N6 N5 . . 107.5(3)
C16 N6 Ag3 . 3_565 130.4(3)
N5 N6 Ag3 . 3_565 121.5(2)
C17 N7 C21 . . 118.1(4)
C17 N7 Ag3 . . 131.7(3)
C21 N7 Ag3 . . 109.7(2)
C22 N8 N9 . 3_565 108.6(3)
C22 N8 Ag3 . . 122.8(2)
N9 N8 Ag3 3_565 . 128.0(2)
C24 N9 N8 . 3_565 107.5(3)
C24 N9 Ag1 . . 130.9(3)
N8 N9 Ag1 3_565 . 119.9(2)
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 N9 . 2.103(3) yes
Ag1 N2 . 2.132(3) yes
Ag1 N1 . 2.603(3) yes
Ag2 N3 . 2.124(3) yes
Ag2 N5 . 2.160(3) yes
Ag2 N4 . 2.539(3) yes
Ag2 Ag3 . 3.1144(6) yes
Ag3 N6 3_565 2.107(3) yes?
Ag3 N8 . 2.144(3) yes
Ag3 N7 . 2.586(3) yes
C1 N1 . 1.343(5) ?
C1 C2 . 1.361(5) ?
C1 H1 . 0.9300 ?
C2 C3 . 1.371(6) ?
C2 H2 . 0.9300 ?
C3 C4 . 1.371(5) ?
C3 H3 . 0.9300 ?
C4 C5 . 1.387(5) ?
C4 H4 . 0.9300 ?
C5 N1 . 1.330(5) ?
C5 C6 . 1.471(5) ?
C6 N2 . 1.338(4) ?
C6 C7 . 1.384(5) ?
C7 C8 . 1.371(5) ?
C7 H7 . 0.9300 ?
C8 N3 . 1.328(5) ?
C8 H8 . 0.9300 ?
C9 N4 . 1.333(5) ?
C9 C10 . 1.375(6) ?
C9 H9 . 0.9300 ?
C10 C11 . 1.376(6) ?
C10 H10 . 0.9300 ?
C11 C12 . 1.377(6) ?
C11 H11 . 0.9300 ?
C12 C13 . 1.380(5) ?
C12 H12 . 0.9300 ?
C13 N4 . 1.350(4) ?
C13 C14 . 1.456(5) ?
C14 N5 . 1.346(4) ?
C14 C15 . 1.382(5) ?
C15 C16 . 1.376(5) ?
C15 H15 . 0.9300 ?
C16 N6 . 1.341(4) ?
C16 H16 . 0.9300 ?
C17 N7 . 1.324(5) ?
C17 C18 . 1.379(7) ?
C17 H17 . 0.9300 ?
C18 C19 . 1.349(7) ?
C18 H18 . 0.9300 ?
C19 C20 . 1.382(6) ?
C19 H19 . 0.9300 ?
C20 C21 . 1.390(5) ?
C20 H20 . 0.9300 ?
C21 N7 . 1.346(5) ?
C21 C22 . 1.458(5) ?
C22 N8 . 1.342(4) ?
C22 C23 . 1.385(5) ?
C23 C24 3_565 1.359(5) ?
C23 H23 . 0.9300 ?
C24 N9 . 1.333(5) ?
C24 C23 3_565 1.359(5) ?
C24 H24 . 0.9300 ?
N2 N3 . 1.356(4) ?
N5 N6 . 1.352(4) ?
N6 Ag3 3_565 2.107(3) ?
N8 N9 3_565 1.350(4) ?
N9 N8 3_565 1.350(4) ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
N3 Ag2 Ag3 N6 . 3_565 61.47(13)
N5 Ag2 Ag3 N6 . 3_565 -105.85(11)
N4 Ag2 Ag3 N6 . 3_565 -177.98(11)
N3 Ag2 Ag3 N8 . . -126.29(13)
N5 Ag2 Ag3 N8 . . 66.39(12)
N4 Ag2 Ag3 N8 . . -5.75(11)
N3 Ag2 Ag3 N7 . . -62.14(12)
N5 Ag2 Ag3 N7 . . 130.54(12)
N4 Ag2 Ag3 N7 . . 58.41(11)
N1 C1 C2 C3 . . -0.7(7)
C1 C2 C3 C4 . . 1.0(6)
C2 C3 C4 C5 . . -0.3(6)
C3 C4 C5 N1 . . -0.8(6)
C3 C4 C5 C6 . . 178.1(3)
N1 C5 C6 N2 . . 2.6(5)
C4 C5 C6 N2 . . -176.3(3)
N1 C5 C6 C7 . . -179.7(4)
C4 C5 C6 C7 . . 1.3(6)
N2 C6 C7 C8 . . -0.5(5)
C5 C6 C7 C8 . . -178.4(4)
C6 C7 C8 N3 . . 0.3(5)
N4 C9 C10 C11 . . 0.4(6)
C9 C10 C11 C12 . . 0.2(6)
C10 C11 C12 C13 . . -1.4(6)
C11 C12 C13 N4 . . 2.1(6)
C11 C12 C13 C14 . . -179.6(4)
N4 C13 C14 N5 . . 1.4(5)
C12 C13 C14 N5 . . -177.0(3)
N4 C13 C14 C15 . . -177.9(4)
C12 C13 C14 C15 . . 3.8(6)
N5 C14 C15 C16 . . 0.2(4)
C13 C14 C15 C16 . . 179.5(4)
C14 C15 C16 N6 . . 0.2(5)
N7 C17 C18 C19 . . -1.8(8)
C17 C18 C19 C20 . . 1.7(8)
C18 C19 C20 C21 . . -0.6(7)
C19 C20 C21 N7 . . -0.5(6)
C19 C20 C21 C22 . . 179.9(4)
N7 C21 C22 N8 . . 1.1(5)
C20 C21 C22 N8 . . -179.3(4)
N7 C21 C22 C23 . . -179.0(4)
C20 C21 C22 C23 . . 0.6(6)
N8 C22 C23 C24 . 3_565 -0.1(4)
C21 C22 C23 C24 . 3_565 -180.0(4)
C4 C5 N1 C1 . . 1.1(6)
C6 C5 N1 C1 . . -177.8(3)
C4 C5 N1 Ag1 . . 178.7(3)
C6 C5 N1 Ag1 . . -0.3(4)
C2 C1 N1 C5 . . -0.4(6)
C2 C1 N1 Ag1 . . -177.2(3)
N9 Ag1 N1 C5 . . -174.8(2)
N2 Ag1 N1 C5 . . -1.2(2)
N9 Ag1 N1 C1 . . 2.2(4)
N2 Ag1 N1 C1 . . 175.8(4)
C7 C6 N2 N3 . . 0.5(4)
C5 C6 N2 N3 . . 178.7(3)
C7 C6 N2 Ag1 . . 177.7(3)
C5 C6 N2 Ag1 . . -4.2(5)
N1 Ag1 N2 C6 . . 2.8(3)
N1 Ag1 N2 N3 . . 179.4(3)
C7 C8 N3 N2 . . 0.0(5)
C7 C8 N3 Ag2 . . -171.5(3)
C6 N2 N3 C8 . . -0.3(4)
Ag1 N2 N3 C8 . . -177.3(3)
C6 N2 N3 Ag2 . . 172.3(2)
Ag1 N2 N3 Ag2 . . -4.7(4)
N5 Ag2 N3 C8 . . 169.4(5)
N4 Ag2 N3 C8 . . -12.9(4)
Ag3 Ag2 N3 C8 . . 83.1(4)
N5 Ag2 N3 N2 . . -1.2(8)
N4 Ag2 N3 N2 . . 176.5(2)
Ag3 Ag2 N3 N2 . . -87.5(3)
C10 C9 N4 C13 . . 0.3(6)
C10 C9 N4 Ag2 . . -175.4(3)
C12 C13 N4 C9 . . -1.5(5)
C14 C13 N4 C9 . . -179.9(3)
C12 C13 N4 Ag2 . . 175.0(3)
C14 C13 N4 Ag2 . . -3.3(4)
N3 Ag2 N4 C9 . . -0.4(4)
N5 Ag2 N4 C9 . . 179.1(4)
Ag3 Ag2 N4 C9 . . -111.7(3)
N3 Ag2 N4 C13 . . -176.3(2)
N5 Ag2 N4 C13 . . 3.2(2)
Ag3 Ag2 N4 C13 . . 72.4(2)
C15 C14 N5 N6 . . -0.5(4)
C13 C14 N5 N6 . . -179.9(3)
C15 C14 N5 Ag2 . . -178.6(2)
C13 C14 N5 Ag2 . . 2.0(4)
N3 Ag2 N5 C14 . . 175.2(5)
N4 Ag2 N5 C14 . . -2.7(2)
Ag3 Ag2 N5 C14 . . -93.9(3)
N3 Ag2 N5 N6 . . -2.5(8)
N4 Ag2 N5 N6 . . 179.6(3)
Ag3 Ag2 N5 N6 . . 88.4(3)
C15 C16 N6 N5 . . -0.5(4)
C15 C16 N6 Ag3 . 3_565 170.5(3)
C14 N5 N6 C16 . . 0.6(4)
Ag2 N5 N6 C16 . . 178.5(2)
C14 N5 N6 Ag3 . 3_565 -171.4(2)
Ag2 N5 N6 Ag3 . 3_565 6.5(4)
C18 C17 N7 C21 . . 0.7(7)
C18 C17 N7 Ag3 . . -170.4(4)
C20 C21 N7 C17 . . 0.5(6)
C22 C21 N7 C17 . . -179.9(3)
C20 C21 N7 Ag3 . . 173.5(3)
C22 C21 N7 Ag3 . . -7.0(4)
N6 Ag3 N7 C17 3_565 . -9.6(4)
N8 Ag3 N7 C17 . . 179.4(4)
Ag2 Ag3 N7 C17 . . 62.5(4)
N6 Ag3 N7 C21 3_565 . 178.7(2)
N8 Ag3 N7 C21 . . 7.8(2)
Ag2 Ag3 N7 C21 . . -109.1(2)
C23 C22 N8 N9 . 3_565 -0.2(4)
C21 C22 N8 N9 . 3_565 179.7(3)
C23 C22 N8 Ag3 . . -172.4(2)
C21 C22 N8 Ag3 . . 7.5(5)
N6 Ag3 N8 C22 3_565 . -152.0(5)
N7 Ag3 N8 C22 . . -7.9(3)
Ag2 Ag3 N8 C22 . . 63.2(3)
N6 Ag3 N8 N9 3_565 3_565 37.4(7)
N7 Ag3 N8 N9 . 3_565 -178.5(3)
Ag2 Ag3 N8 N9 . 3_565 -107.4(3)
C23 C24 N9 N8 3_565 3_565 0.4(4)
C23 C24 N9 Ag1 3_565 . -164.0(3)
N1 Ag1 N9 C24 . . -5.3(4)
N1 Ag1 N9 N8 . 3_565 -168.1(2)
