#------------------------------------------------------------------------------
#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/51/2215137.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2215137
loop_
_publ_author_name
'Broker, Grant A.'
'Tiekink, Edward R. T.'
_publ_section_title
;
 catena-Poly[[silver(I)-μ-1,4-di-4-pyridyl-2,3-diazabuta-1,3-diene]
 methanesulfonate]
;
_journal_coeditor_code           HB2517
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m2436
_journal_page_last               m2436
_journal_paper_doi               10.1107/S1600536807041645
_journal_volume                  63
_journal_year                    2007
_chemical_formula_iupac          '[Ag (C12 H10 N4)] C H3 O3 S'
_chemical_formula_moiety         'C12 H10 Ag1 N4 +, C H3 O3 S -'
_chemical_formula_sum            'C13 H13 Ag N4 O3 S'
_chemical_formula_weight         413.22
_chemical_name_systematic
;
catena-Poly[[silver(I)-μ-1,4-di-4-pyridyl-2,3-diazabuta-1,3-diene]
methanesulfonate]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 113.790(7)
_cell_angle_gamma                90
_cell_formula_units_Z            16
_cell_length_a                   25.083(9)
_cell_length_b                   12.284(4)
_cell_length_c                   21.009(7)
_cell_measurement_reflns_used    10582
_cell_measurement_temperature    153(2)
_cell_measurement_theta_max      25.0
_cell_measurement_theta_min      1.9
_cell_volume                     5923(3)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC, 2005)'
_computing_molecular_graphics
'ORTEPII (Johnson, 1976) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SIR92 (Altomare et al.,  1994)'
_diffrn_ambient_temperature      153(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Rigaku AFC12κ/SATURN724'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.048
_diffrn_reflns_av_sigmaI/netI    0.031
_diffrn_reflns_limit_h_max       31
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       15
_diffrn_reflns_limit_k_min       -15
_diffrn_reflns_limit_l_max       22
_diffrn_reflns_limit_l_min       -26
_diffrn_reflns_number            37758
_diffrn_reflns_theta_full        26.5
_diffrn_reflns_theta_max         26.5
_diffrn_reflns_theta_min         1.9
_diffrn_standards_decay_%        '< 1'
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.520
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.645
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            yellow
_exptl_crystal_density_diffrn    1.853
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Prism
_exptl_crystal_F_000             3296
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.08
_exptl_crystal_size_min          0.07
_refine_diff_density_max         1.98
_refine_diff_density_min         -1.28
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.16
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     397
_refine_ls_number_reflns         6151
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.16
_refine_ls_R_factor_all          0.057
_refine_ls_R_factor_gt           0.054
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.056P)²+41.7048P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.130
_refine_ls_wR_factor_ref         0.132
_reflns_number_gt                5879
_reflns_number_total             6151
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hb2517.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      'C 2/c'
_cod_original_formula_sum        'C13 H13 Ag1 N4 O3 S1'
_cod_database_code               2215137
_cod_database_fobs_code          2215137
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Ag Ag1 0.264234(14) 0.11412(3) 0.115089(16) 0.02522(12) Uani d . 1
Ag Ag2 0.761261(15) 0.13780(3) 0.867951(17) 0.02714(12) Uani d . 1
S S1 0.14174(4) -0.00296(9) 0.18189(5) 0.0232(2) Uani d . 1
S S2 0.63856(4) 0.00487(9) 0.93140(5) 0.0227(2) Uani d . 1
O O1 0.17575(14) 0.0433(3) 0.14587(17) 0.0349(8) Uani d . 1
O O2 0.15577(14) 0.0447(3) 0.24999(17) 0.0355(8) Uani d . 1
O O3 0.14380(15) -0.1215(3) 0.1835(2) 0.0354(8) Uani d . 1
O O4 0.66998(14) 0.0630(3) 0.89604(16) 0.0297(7) Uani d . 1
O O5 0.64598(14) -0.1133(3) 0.92975(17) 0.0282(7) Uani d . 1
O O6 0.65091(14) 0.0461(3) 1.00060(16) 0.0331(8) Uani d . 1
N N1 0.32271(16) 0.1270(3) 0.2246(2) 0.0233(8) Uani d . 1
N N2 0.49505(16) 0.1637(3) 0.45649(18) 0.0272(8) Uani d . 1
N N3 0.52542(16) 0.1634(4) 0.52935(19) 0.0273(8) Uani d . 1
N N4 0.70009(16) 0.1535(3) 0.76056(19) 0.0225(8) Uani d . 1
N N5 0.19914(16) 0.1277(3) 0.00882(19) 0.0233(8) Uani d . 1
N N6 0.01700(17) 0.1235(3) -0.21380(19) 0.0281(9) Uani d . 1
N N7 0.81773(16) 0.1530(3) 0.97678(19) 0.0225(8) Uani d . 1
N N8 0.98552(16) 0.1972(3) 1.21342(18) 0.0269(8) Uani d . 1
C C1 0.38045(19) 0.1436(4) 0.2423(2) 0.0235(9) Uani d . 1
H H1 0.3938 0.1523 0.2062 0.028 Uiso calc R 1
C C2 0.42060(19) 0.1483(4) 0.3104(2) 0.0243(9) Uani d . 1
H H2 0.4606 0.1615 0.3208 0.029 Uiso calc R 1
C C3 0.40169(19) 0.1335(4) 0.3639(2) 0.0229(9) Uani d . 1
C C4 0.34180(19) 0.1144(4) 0.3451(2) 0.0235(9) Uani d . 1
H H4 0.3274 0.1026 0.3800 0.028 Uiso calc R 1
C C5 0.30417(19) 0.1131(4) 0.2757(2) 0.0224(9) Uani d . 1
H H5 0.2638 0.1018 0.2637 0.027 Uiso calc R 1
C C6 0.4412(2) 0.1367(4) 0.4377(2) 0.0249(9) Uani d . 1
H H6 0.4269 0.1187 0.4720 0.030 Uiso calc R 1
C C7 0.58074(19) 0.1619(4) 0.5471(2) 0.0232(9) Uani d . 1
H H7 0.5959 0.1612 0.5124 0.028 Uiso calc R 1
C C8 0.62066(18) 0.1611(4) 0.6211(2) 0.0224(9) Uani d . 1
C C9 0.68083(19) 0.1661(4) 0.6398(2) 0.0250(9) Uani d . 1
H H9 0.6955 0.1719 0.6048 0.030 Uiso calc R 1
C C10 0.71890(19) 0.1625(4) 0.7088(2) 0.0252(9) Uani d . 1
H H10 0.7596 0.1664 0.7204 0.030 Uiso calc R 1
C C11 0.64189(19) 0.1490(4) 0.7429(2) 0.0244(9) Uani d . 1
H H11 0.6283 0.1422 0.7789 0.029 Uiso calc R 1
C C12 0.60160(19) 0.1539(4) 0.6752(2) 0.0240(9) Uani d . 1
H H12 0.5611 0.1525 0.6651 0.029 Uiso calc R 1
C C13 0.1417(2) 0.1261(4) -0.0053(2) 0.0247(9) Uani d . 1
H H13 0.1302 0.1240 0.0327 0.030 Uiso calc R 1
C C14 0.0987(2) 0.1274(4) -0.0716(2) 0.0248(9) Uani d . 1
H H14 0.0588 0.1280 -0.0790 0.030 Uiso calc R 1
C C15 0.11503(19) 0.1277(4) -0.1282(2) 0.0224(9) Uani d . 1
C C16 0.1747(2) 0.1291(4) -0.1137(2) 0.0252(9) Uani d . 1
H H16 0.1873 0.1296 -0.1507 0.030 Uiso calc R 1
C C17 0.2149(2) 0.1297(4) -0.0456(2) 0.0249(9) Uani d . 1
H H17 0.2551 0.1316 -0.0365 0.030 Uiso calc R 1
C C18 0.0717(2) 0.1261(4) -0.2006(2) 0.0245(9) Uani d . 1
H H18 0.0842 0.1271 -0.2377 0.029 Uiso calc R 1
C C19 0.87543(19) 0.1692(4) 0.9965(2) 0.0255(9) Uani d . 1
H H19 0.8900 0.1758 0.9614 0.031 Uiso calc R 1
C C20 0.91447(19) 0.1767(4) 1.0653(2) 0.0252(9) Uani d . 1
H H20 0.9547 0.1892 1.0768 0.030 Uiso calc R 1
C C21 0.89386(19) 0.1656(4) 1.1176(2) 0.0226(9) Uani d . 1
C C22 0.83412(19) 0.1478(4) 1.0970(2) 0.0235(9) Uani d . 1
H H22 0.8186 0.1389 1.1311 0.028 Uiso calc R 1
C C23 0.7977(2) 0.1432(4) 1.0272(2) 0.0245(9) Uani d . 1
H H23 0.7572 0.1326 1.0142 0.029 Uiso calc R 1
C C24 0.93200(19) 0.1704(4) 1.1924(2) 0.0245(9) Uani d . 1
H H24 0.9164 0.1531 1.2255 0.029 Uiso calc R 1
C C25 0.06786(19) 0.0330(4) 0.1304(3) 0.0315(10) Uani d . 1
H H25A 0.0561 0.0026 0.0836 0.047 Uiso calc R 1
H H25B 0.0642 0.1125 0.1275 0.047 Uiso calc R 1
H H25C 0.0427 0.0038 0.1519 0.047 Uiso calc R 1
C C26 0.56288(19) 0.0300(4) 0.8806(2) 0.0279(10) Uani d . 1
H H26A 0.5524 0.0033 0.8331 0.042 Uiso calc R 1
H H26B 0.5553 0.1084 0.8794 0.042 Uiso calc R 1
H H26C 0.5395 -0.0080 0.9014 0.042 Uiso calc R 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N1 Ag1 N5 . 169.88(15) y
N5 Ag1 Ag2 5_656 95.02(10) ?
N1 Ag1 Ag2 5_656 91.85(10) ?
N4 Ag2 N7 . 169.32(15) y
N7 Ag2 Ag1 5_656 92.34(10) ?
N4 Ag2 Ag1 5_656 96.46(10) ?
O2 S1 O3 . 112.8(2) ?
O2 S1 O1 . 113.1(2) ?
O3 S1 O1 . 112.2(2) ?
O2 S1 C25 . 106.1(2) ?
O3 S1 C25 . 106.3(2) ?
O1 S1 C25 . 105.7(2) ?
O6 S2 O5 . 113.1(2) ?
O6 S2 O4 . 113.3(2) ?
O5 S2 O4 . 111.8(2) ?
O6 S2 C26 . 106.5(2) ?
O5 S2 C26 . 105.7(2) ?
O4 S2 C26 . 105.7(2) ?
C5 N1 C1 . 118.5(4) ?
C5 N1 Ag1 . 122.2(3) ?
C1 N1 Ag1 . 119.2(3) ?
C6 N2 N3 . 111.9(4) ?
C7 N3 N2 . 111.3(4) ?
C10 N4 C11 . 118.1(4) ?
C10 N4 Ag2 . 120.9(3) ?
C11 N4 Ag2 . 120.9(3) ?
C13 N5 C17 . 117.7(4) ?
C13 N5 Ag1 . 121.1(3) ?
C17 N5 Ag1 . 121.0(3) ?
C18 N6 N6 2_554 111.2(5) ?
C23 N7 C19 . 117.7(4) ?
C23 N7 Ag2 . 122.1(3) ?
C19 N7 Ag2 . 120.2(3) ?
C24 N8 N8 2_757 112.6(4) ?
N1 C1 C2 . 122.8(4) ?
N1 C1 H1 . 118.6 ?
C2 C1 H1 . 118.6 ?
C1 C2 C3 . 119.1(4) ?
C1 C2 H2 . 120.5 ?
C3 C2 H2 . 120.5 ?
C2 C3 C4 . 117.8(4) ?
C2 C3 C6 . 123.0(4) ?
C4 C3 C6 . 119.3(4) ?
C5 C4 C3 . 119.6(4) ?
C5 C4 H4 . 120.2 ?
C3 C4 H4 . 120.2 ?
N1 C5 C4 . 122.2(4) ?
N1 C5 H5 . 118.9 ?
C4 C5 H5 . 118.9 ?
N2 C6 C3 . 120.5(4) ?
N2 C6 H6 . 119.7 ?
C3 C6 H6 . 119.7 ?
N3 C7 C8 . 120.2(4) ?
N3 C7 H7 . 119.9 ?
C8 C7 H7 . 119.9 ?
C9 C8 C12 . 117.2(4) ?
C9 C8 C7 . 119.6(4) ?
C12 C8 C7 . 123.2(4) ?
C10 C9 C8 . 120.4(4) ?
C10 C9 H9 . 119.8 ?
C8 C9 H9 . 119.8 ?
N4 C10 C9 . 122.0(4) ?
N4 C10 H10 . 119.0 ?
C9 C10 H10 . 119.0 ?
N4 C11 C12 . 122.8(4) ?
N4 C11 H11 . 118.6 ?
C12 C11 H11 . 118.6 ?
C11 C12 C8 . 119.6(4) ?
C11 C12 H12 . 120.2 ?
C8 C12 H12 . 120.2 ?
N5 C13 C14 . 123.6(4) ?
N5 C13 H13 . 118.2 ?
C14 C13 H13 . 118.2 ?
C13 C14 C15 . 118.8(4) ?
C13 C14 H14 . 120.6 ?
C15 C14 H14 . 120.6 ?
C16 C15 C14 . 117.8(4) ?
C16 C15 C18 . 120.2(4) ?
C14 C15 C18 . 122.0(4) ?
C17 C16 C15 . 119.6(4) ?
C17 C16 H16 . 120.2 ?
C15 C16 H16 . 120.2 ?
N5 C17 C16 . 122.5(4) ?
N5 C17 H17 . 118.7 ?
C16 C17 H17 . 118.7 ?
N6 C18 C15 . 120.2(4) ?
N6 C18 H18 . 119.9 ?
C15 C18 H18 . 119.9 ?
N7 C19 C20 . 123.4(4) ?
N7 C19 H19 . 118.3 ?
C20 C19 H19 . 118.3 ?
C19 C20 C21 . 119.0(4) ?
C19 C20 H20 . 120.5 ?
C21 C20 H20 . 120.5 ?
C20 C21 C22 . 117.5(4) ?
C20 C21 C24 . 123.2(4) ?
C22 C21 C24 . 119.3(4) ?
C23 C22 C21 . 120.1(4) ?
C23 C22 H22 . 120.0 ?
C21 C22 H22 . 120.0 ?
N7 C23 C22 . 122.3(4) ?
N7 C23 H23 . 118.8 ?
C22 C23 H23 . 118.8 ?
N8 C24 C21 . 121.3(4) ?
N8 C24 H24 . 119.4 ?
C21 C24 H24 . 119.4 ?
S1 C25 H25A . 109.5 ?
S1 C25 H25B . 109.5 ?
H25A C25 H25B . 109.5 ?
S1 C25 H25C . 109.5 ?
H25A C25 H25C . 109.5 ?
H25B C25 H25C . 109.5 ?
S2 C26 H26A . 109.5 ?
S2 C26 H26B . 109.5 ?
H26A C26 H26B . 109.5 ?
S2 C26 H26C . 109.5 ?
H26A C26 H26C . 109.5 ?
H26B C26 H26C . 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 N1 . 2.179(4) y
Ag1 N5 . 2.177(4) y
Ag2 N4 . 2.165(4) y
Ag2 N7 . 2.158(4) y
Ag1 Ag2 5_656 3.2088(10) y
Ag2 Ag1 5_656 3.2088(10) ?
S1 O2 . 1.452(3) ?
S1 O3 . 1.457(4) ?
S1 O1 . 1.464(3) ?
S1 C25 . 1.784(5) ?
S2 O6 . 1.450(3) ?
S2 O5 . 1.466(3) ?
S2 O4 . 1.468(3) ?
S2 C26 . 1.790(4) ?
N1 C5 . 1.341(6) ?
N1 C1 . 1.358(6) ?
N2 C6 . 1.289(6) ?
N2 N3 . 1.408(5) ?
N3 C7 . 1.283(6) ?
N4 C10 . 1.352(6) ?
N4 C11 . 1.355(6) ?
N5 C13 . 1.350(6) ?
N5 C17 . 1.351(6) ?
N6 C18 . 1.286(6) ?
N6 N6 2_554 1.412(7) ?
N7 C23 . 1.347(6) ?
N7 C19 . 1.350(6) ?
N8 C24 . 1.276(6) ?
N8 N8 2_757 1.411(7) ?
C1 C2 . 1.379(6) ?
C1 H1 . 0.9500 ?
C2 C3 . 1.397(6) ?
C2 H2 . 0.9500 ?
C3 C4 . 1.410(6) ?
C3 C6 . 1.466(6) ?
C4 C5 . 1.381(6) ?
C4 H4 . 0.9500 ?
C5 H5 . 0.9500 ?
C6 H6 . 0.9500 ?
C7 C8 . 1.471(6) ?
C7 H7 . 0.9500 ?
C8 C9 . 1.399(6) ?
C8 C12 . 1.402(6) ?
C9 C10 . 1.378(6) ?
C9 H9 . 0.9500 ?
C10 H10 . 0.9500 ?
C11 C12 . 1.375(6) ?
C11 H11 . 0.9500 ?
C12 H12 . 0.9500 ?
C13 C14 . 1.375(7) ?
C13 H13 . 0.9500 ?
C14 C15 . 1.404(6) ?
C14 H14 . 0.9500 ?
C15 C16 . 1.401(6) ?
C15 C18 . 1.470(6) ?
C16 C17 . 1.379(7) ?
C16 H16 . 0.9500 ?
C17 H17 . 0.9500 ?
C18 H18 . 0.9500 ?
C19 C20 . 1.384(6) ?
C19 H19 . 0.9500 ?
C20 C21 . 1.397(6) ?
C20 H20 . 0.9500 ?
C21 C22 . 1.399(6) ?
C21 C24 . 1.474(6) ?
C22 C23 . 1.382(6) ?
C22 H22 . 0.9500 ?
C23 H23 . 0.9500 ?
C24 H24 . 0.9500 ?
C25 H25A . 0.9800 ?
C25 H25B . 0.9800 ?
C25 H25C . 0.9800 ?
C26 H26A . 0.9800 ?
C26 H26B . 0.9800 ?
C26 H26C . 0.9800 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion
_geom_torsion_publ_flag
N5 Ag1 N1 C5 . 69.3(9) ?
Ag2 Ag1 N1 C5 5_656 -63.4(3) ?
N5 Ag1 N1 C1 . -114.5(8) ?
Ag2 Ag1 N1 C1 5_656 112.7(3) ?
C6 N2 N3 C7 . 163.0(4) n
N7 Ag2 N4 C10 . 106.9(8) ?
Ag1 Ag2 N4 C10 5_656 -107.7(3) ?
N7 Ag2 N4 C11 . -76.5(9) ?
Ag1 Ag2 N4 C11 5_656 68.8(3) ?
N1 Ag1 N5 C13 . -61.5(9) ?
Ag2 Ag1 N5 C13 5_656 71.0(3) ?
N1 Ag1 N5 C17 . 123.6(8) ?
Ag2 Ag1 N5 C17 5_656 -103.9(3) ?
N4 Ag2 N7 C23 . 79.9(9) ?
Ag1 Ag2 N7 C23 5_656 -65.6(3) ?
N4 Ag2 N7 C19 . -102.4(8) ?
Ag1 Ag2 N7 C19 5_656 112.1(3) ?
C5 N1 C1 C2 . -1.0(7) ?
Ag1 N1 C1 C2 . -177.3(3) ?
N1 C1 C2 C3 . 1.2(7) ?
C1 C2 C3 C4 . -0.1(7) ?
C1 C2 C3 C6 . 179.8(4) ?
C2 C3 C4 C5 . -1.2(6) ?
C6 C3 C4 C5 . 179.0(4) ?
C1 N1 C5 C4 . -0.4(6) ?
Ag1 N1 C5 C4 . 175.8(3) ?
C3 C4 C5 N1 . 1.4(7) ?
N3 N2 C6 C3 . 179.1(4) ?
C2 C3 C6 N2 . 6.5(7) ?
C4 C3 C6 N2 . -173.6(4) ?
N2 N3 C7 C8 . -179.9(4) ?
N3 C7 C8 C9 . -176.2(4) ?
N3 C7 C8 C12 . 4.8(7) ?
C12 C8 C9 C10 . 0.8(7) ?
C7 C8 C9 C10 . -178.3(4) ?
C11 N4 C10 C9 . -0.6(7) ?
Ag2 N4 C10 C9 . 176.1(4) ?
C8 C9 C10 N4 . 0.4(7) ?
C10 N4 C11 C12 . -0.4(7) ?
Ag2 N4 C11 C12 . -177.1(4) ?
N4 C11 C12 C8 . 1.7(7) ?
C9 C8 C12 C11 . -1.8(7) ?
C7 C8 C12 C11 . 177.2(4) ?
C17 N5 C13 C14 . -0.6(7) ?
Ag1 N5 C13 C14 . -175.7(3) ?
N5 C13 C14 C15 . 1.6(7) ?
C13 C14 C15 C16 . -1.3(7) ?
C13 C14 C15 C18 . 178.4(4) ?
C14 C15 C16 C17 . 0.2(7) ?
C18 C15 C16 C17 . -179.5(4) ?
C13 N5 C17 C16 . -0.6(7) ?
Ag1 N5 C17 C16 . 174.4(3) ?
C15 C16 C17 N5 . 0.8(7) ?
N6 N6 C18 C15 2_554 179.4(3) ?
C16 C15 C18 N6 . 179.1(4) ?
C14 C15 C18 N6 . -0.6(7) ?
C23 N7 C19 C20 . -0.4(7) ?
Ag2 N7 C19 C20 . -178.1(4) ?
N7 C19 C20 C21 . 0.9(7) ?
C19 C20 C21 C22 . -0.2(7) ?
C19 C20 C21 C24 . 178.9(4) ?
C20 C21 C22 C23 . -0.8(7) ?
C24 C21 C22 C23 . -180.0(4) ?
C19 N7 C23 C22 . -0.8(7) ?
Ag2 N7 C23 C22 . 177.0(3) ?
C21 C22 C23 N7 . 1.4(7) ?
N8 N8 C24 C21 2_757 179.8(3) ?
C20 C21 C24 N8 . 8.0(7) ?
C22 C21 C24 N8 . -172.9(4) ?
