#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/70/2217007.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2217007
loop_
_publ_author_name
'Chong-Bo Liu'
'Hui-Liang Wen'
'Fan Deng'
'Jun-Hui Zuo'
_publ_section_title
;Tetrakis[μ-3-(3-pyridyl)acrylato-κ²O:O']bis{(1,10-phenanthroline-κ²N,N')[3-(3-pyridyl)acrylato-κ²O,O']europium(III)}
 pentahydrate
;
_journal_coeditor_code           DN2276
_journal_issue                   1
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m201
_journal_page_last               m201
_journal_paper_doi               10.1107/S1600536807066263
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '[Eu2 (C8 H6 N O2)6 (C12 H8 N2)2], 5H2 O'
_chemical_formula_moiety         'C72 H52 Eu2 N10 O12, 4(H2 O), H2 O'
_chemical_formula_sum            'C72 H62 Eu2 N10 O17'
_chemical_formula_weight         1643.24
_chemical_name_systematic
;
tetrakis[μ-3-(3-pyridyl)acrylato-κ²O:O']bis{(1,10-phenanthroline-
κ²N,N')[3-(3-pyridyl)acrylato-κ²O,O']europium(III)] pentahydrate
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 100.330(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   25.434(2)
_cell_length_b                   12.320(10)
_cell_length_c                   22.595(19)
_cell_measurement_reflns_used    7048
_cell_measurement_temperature    293(2)
_cell_measurement_theta_max      28.07
_cell_measurement_theta_min      2.66
_cell_volume                     6965(8)
_computing_cell_refinement       'SAINT (Bruker, 1998)'
_computing_data_collection       'SMART (Bruker, 1998)'
_computing_data_reduction        'SAINT (Bruker, 1998)'
_computing_molecular_graphics
'ORTEPIII (Burnett & Johnson, 1996)and ORTEP-3 for Windows (Farrugia, 1997)'
_computing_publication_material  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 1997)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 1997)'
_diffrn_ambient_temperature      293(2)
_diffrn_measured_fraction_theta_full 0.999
_diffrn_measured_fraction_theta_max 0.999
_diffrn_measurement_device_type  'Bruker SMART CCD area-detector'
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0215
_diffrn_reflns_av_sigmaI/netI    0.0186
_diffrn_reflns_limit_h_max       30
_diffrn_reflns_limit_h_min       -30
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       27
_diffrn_reflns_limit_l_min       -27
_diffrn_reflns_number            25928
_diffrn_reflns_theta_full        25.50
_diffrn_reflns_theta_max         25.50
_diffrn_reflns_theta_min         2.49
_exptl_absorpt_coefficient_mu    1.862
_exptl_absorpt_correction_T_max  0.7912
_exptl_absorpt_correction_T_min  0.5847
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.567
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             3304
_exptl_crystal_size_max          0.32
_exptl_crystal_size_mid          0.27
_exptl_crystal_size_min          0.13
_refine_diff_density_max         0.343
_refine_diff_density_min         -0.251
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.031
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         6480
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.031
_refine_ls_R_factor_all          0.0237
_refine_ls_R_factor_gt           0.0188
_refine_ls_shift/su_max          0.006
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0183P)²+8.1685P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0420
_refine_ls_wR_factor_ref         0.0443
_reflns_number_gt                5721
_reflns_number_total             6480
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            dn2276.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        6965.4(10)
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               2217007
_cod_database_fobs_code          2217007
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
Eu Eu1 0.528205(4) 0.611291(8) 0.562535(4) 0.02456(4) Uani d . 1
O O5 0.58593(7) 0.57165(15) 0.66055(7) 0.0457(4) Uani d . 1
O O6 0.62759(6) 0.62061(13) 0.58772(7) 0.0417(4) Uani d . 1
N N3 0.82161(9) 0.3750(2) 0.77152(12) 0.0627(7) Uani d . 1
N N4 0.55055(7) 0.81740(14) 0.56748(8) 0.0312(4) Uani d . 1
N N5 0.48983(7) 0.72683(15) 0.64279(8) 0.0311(4) Uani d . 1
C C17 0.62845(9) 0.58151(19) 0.63974(11) 0.0375(6) Uani d . 1
C C18 0.68033(10) 0.5427(2) 0.67463(12) 0.0442(6) Uani d . 1
H H18 0.7110 0.5515 0.6581 0.053 Uiso calc R 1
C C19 0.68467(10) 0.4966(2) 0.72778(11) 0.0430(6) Uani d . 1
H H19 0.6538 0.4954 0.7444 0.052 Uiso calc R 1
C C20 0.73241(10) 0.4467(2) 0.76421(11) 0.0415(6) Uani d . 1
C C21 0.73315(12) 0.4186(3) 0.82349(13) 0.0589(8) Uani d . 1
H H21 0.7035 0.4319 0.8412 0.071 Uiso calc R 1
C C22 0.77820(14) 0.3705(3) 0.85628(14) 0.0729(10) Uani d . 1
H H22 0.7796 0.3521 0.8964 0.087 Uiso calc R 1
C C23 0.82070(13) 0.3506(3) 0.82849(15) 0.0664(9) Uani d . 1
H H23 0.8508 0.3179 0.8509 0.080 Uiso calc R 1
C C24 0.77778(10) 0.4222(2) 0.74091(12) 0.0500(7) Uani d . 1
H H24 0.7777 0.4400 0.7009 0.060 Uiso calc R 1
C C25 0.58064(10) 0.8617(2) 0.53183(11) 0.0418(6) Uani d . 1
H H25 0.5997 0.8160 0.5106 0.050 Uiso calc R 1
C C26 0.58516(12) 0.9740(2) 0.52446(12) 0.0531(7) Uani d . 1
H H26 0.6067 1.0017 0.4988 0.064 Uiso calc R 1
C C27 0.55780(12) 1.0418(2) 0.55515(13) 0.0562(7) Uani d . 1
H H27 0.5599 1.1165 0.5501 0.067 Uiso calc R 1
C C28 0.52609(10) 0.99896(19) 0.59464(12) 0.0450(6) Uani d . 1
C C29 0.49626(13) 1.0650(2) 0.62910(15) 0.0629(8) Uani d . 1
H H29 0.4973 1.1401 0.6255 0.076 Uiso calc R 1
C C30 0.46693(12) 1.0205(2) 0.66633(15) 0.0611(8) Uani d . 1
H H30 0.4485 1.0655 0.6886 0.073 Uiso calc R 1
C C31 0.46320(10) 0.9054(2) 0.67276(12) 0.0435(6) Uani d . 1
C C32 0.43288(10) 0.8555(2) 0.71132(12) 0.0505(7) Uani d . 1
H H32 0.4134 0.8978 0.7338 0.061 Uiso calc R 1
C C33 0.43197(10) 0.7457(2) 0.71572(11) 0.0472(6) Uani d . 1
H H33 0.4124 0.7120 0.7415 0.057 Uiso calc R 1
C C34 0.46102(9) 0.6843(2) 0.68077(10) 0.0395(6) Uani d . 1
H H34 0.4602 0.6091 0.6842 0.047 Uiso calc R 1
C C35 0.49140(8) 0.83702(18) 0.63913(10) 0.0318(5) Uani d . 1
C C36 0.52348(9) 0.88490(17) 0.59938(10) 0.0331(5) Uani d . 1
O O1 0.44766(7) 0.35404(12) 0.53195(7) 0.0375(4) Uani d . 1
O O2 0.47138(6) 0.48567(12) 0.60014(7) 0.0389(4) Uani d . 1
O O3 0.44546(6) 0.55841(12) 0.47089(7) 0.0367(4) Uani d . 1
O O4 0.44788(6) 0.71259(12) 0.51991(7) 0.0382(4) Uani d . 1
N N1 0.40521(14) 0.2529(3) 0.83252(12) 0.0830(9) Uani d . 1
N N2 0.21675(9) 0.92111(19) 0.44666(11) 0.0541(6) Uani d . 1
C C1 0.44874(9) 0.39752(17) 0.58251(10) 0.0328(5) Uani d . 1
C C2 0.42104(10) 0.33633(19) 0.62482(10) 0.0395(5) Uani d . 1
H H2 0.3976 0.2814 0.6090 0.047 Uiso calc R 1
C C3 0.42757(10) 0.35487(19) 0.68318(11) 0.0390(6) Uani d . 1
H H3 0.4495 0.4129 0.6979 0.047 Uiso calc R 1
C C4 0.40369(11) 0.2931(2) 0.72740(11) 0.0428(6) Uani d . 1
C C5 0.36142(13) 0.2224(2) 0.71075(14) 0.0632(8) Uani d . 1
H H5 0.3466 0.2118 0.6704 0.076 Uiso calc R 1
C C6 0.34154(17) 0.1676(3) 0.75602(19) 0.0866(12) Uani d . 1
H H6 0.3129 0.1199 0.7466 0.104 Uiso calc R 1
C C7 0.36502(18) 0.1855(3) 0.81466(18) 0.0882(12) Uani d . 1
H H7 0.3516 0.1473 0.8442 0.106 Uiso calc R 1
C C8 0.42271(12) 0.3066(3) 0.78849(12) 0.0584(8) Uani d . 1
H H8 0.4498 0.3571 0.7997 0.070 Uiso calc R 1
C C9 0.42372(9) 0.64675(17) 0.48230(9) 0.0295(5) Uani d . 1
C C10 0.36825(9) 0.67176(18) 0.45216(10) 0.0336(5) Uani d . 1
H H10 0.3514 0.6266 0.4216 0.040 Uiso calc R 1
C C11 0.34228(9) 0.75715(18) 0.46803(10) 0.0346(5) Uani d . 1
H H11 0.3607 0.7998 0.4989 0.041 Uiso calc R 1
C C12 0.28771(9) 0.79227(19) 0.44256(11) 0.0392(6) Uani d . 1
C C13 0.25486(11) 0.7384(3) 0.39657(14) 0.0658(9) Uani d . 1
H H13 0.2674 0.6777 0.3789 0.079 Uiso calc R 1
C C14 0.20331(12) 0.7750(3) 0.37698(17) 0.0795(11) Uani d . 1
H H14 0.1807 0.7390 0.3464 0.095 Uiso calc R 1
C C15 0.18612(11) 0.8654(3) 0.40342(15) 0.0651(9) Uani d . 1
H H15 0.1512 0.8888 0.3904 0.078 Uiso calc R 1
C C16 0.26665(10) 0.8837(2) 0.46531(12) 0.0457(6) Uani d . 1
H H16 0.2886 0.9220 0.4956 0.055 Uiso calc R 1
O O1W 0.69847(9) 0.61683(17) 0.50760(12) 0.0848(8) Uani d . 1
H H11W 0.6788 0.6122 0.5340 0.127 Uiso d R 1
H H12W 0.6986 0.5565 0.4895 0.127 Uiso d R 1
O O2W 0.30658(11) 0.1792(3) 0.55009(14) 0.1219(11) Uani d . 1
H H21W 0.2805 0.2095 0.5594 0.183 Uiso d R 1
H H22W 0.2973 0.1433 0.5193 0.183 Uiso d R 1
O O3W 0.3341(3) 0.9915(5) 0.6047(3) 0.133(2) Uani d P 0.50
H H32W 0.3035 1.0082 0.6078 0.199 Uiso d PR 0.50
H H31W 0.3521 1.0410 0.5944 0.199 Uiso d PR 0.50
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Eu Eu -0.1578 3.6682 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
O3 Eu1 O1 5_666 5_666 74.72(5)
O3 Eu1 O2 5_666 . 76.31(5)
O1 Eu1 O2 5_666 . 135.54(5)
O3 Eu1 O4 5_666 . 126.32(5)
O1 Eu1 O4 5_666 . 83.44(6)
O2 Eu1 O4 . . 87.38(6)
O3 Eu1 O5 5_666 . 87.40(6)
O1 Eu1 O5 5_666 . 129.42(6)
O2 Eu1 O5 . . 81.54(6)
O4 Eu1 O5 . . 140.72(5)
O3 Eu1 O6 5_666 . 77.26(5)
O1 Eu1 O6 5_666 . 77.34(6)
O2 Eu1 O6 . . 127.26(6)
O4 Eu1 O6 . . 144.08(5)
O5 Eu1 O6 . . 52.45(6)
O3 Eu1 N4 5_666 . 143.74(6)
O1 Eu1 N4 5_666 . 76.83(5)
O2 Eu1 N4 . . 139.73(5)
O4 Eu1 N4 . . 71.25(5)
O5 Eu1 N4 . . 93.68(6)
O6 Eu1 N4 . . 74.94(6)
O3 Eu1 N5 5_666 . 149.61(6)
O1 Eu1 N5 5_666 . 135.59(5)
O2 Eu1 N5 . . 77.35(5)
O4 Eu1 N5 . . 66.85(5)
O5 Eu1 N5 . . 73.95(6)
O6 Eu1 N5 . . 107.73(5)
N4 Eu1 N5 . . 63.04(6)
O3 Eu1 O3 5_666 . 76.84(5)
O1 Eu1 O3 5_666 . 69.55(5)
O2 Eu1 O3 . . 71.51(5)
O4 Eu1 O3 . . 49.54(5)
O5 Eu1 O3 . . 151.25(6)
O6 Eu1 O3 . . 142.18(5)
N4 Eu1 O3 . . 113.28(5)
N5 Eu1 O3 . . 108.60(5)
O3 Eu1 C17 5_666 . 78.89(6)
O1 Eu1 C17 5_666 . 103.18(7)
O2 Eu1 C17 . . 103.45(7)
O4 Eu1 C17 . . 154.62(6)
O5 Eu1 C17 . . 26.26(6)
O6 Eu1 C17 . . 26.44(6)
N4 Eu1 C17 . . 86.25(6)
N5 Eu1 C17 . . 92.85(6)
O3 Eu1 C17 . . 155.71(6)
O3 Eu1 C9 5_666 . 102.08(6)
O1 Eu1 C9 5_666 . 76.75(6)
O2 Eu1 C9 . . 77.23(6)
O4 Eu1 C9 . . 24.37(5)
O5 Eu1 C9 . . 153.82(6)
O6 Eu1 C9 . . 153.25(6)
N4 Eu1 C9 . . 92.72(6)
N5 Eu1 C9 . . 86.51(6)
O3 Eu1 C9 . . 25.25(5)
C17 Eu1 C9 . . 178.95(6)
O3 Eu1 Eu1 5_666 5_666 41.90(4)
O1 Eu1 Eu1 5_666 5_666 66.76(4)
O2 Eu1 Eu1 . 5_666 69.10(4)
O4 Eu1 Eu1 . 5_666 84.45(4)
O5 Eu1 Eu1 . 5_666 125.08(4)
O6 Eu1 Eu1 . 5_666 114.34(4)
N4 Eu1 Eu1 . 5_666 138.18(4)
N5 Eu1 Eu1 . 5_666 136.55(4)
O3 Eu1 Eu1 . 5_666 34.93(3)
C17 Eu1 Eu1 . 5_666 120.79(5)
C9 Eu1 Eu1 . 5_666 60.18(4)
C17 O5 Eu1 . . 93.33(14)
C17 O6 Eu1 . . 92.42(14)
C23 N3 C24 . . 116.3(3)
C25 N4 C36 . . 118.12(19)
C25 N4 Eu1 . . 121.48(15)
C36 N4 Eu1 . . 119.38(14)
C34 N5 C35 . . 117.2(2)
C34 N5 Eu1 . . 123.15(15)
C35 N5 Eu1 . . 118.67(14)
O5 C17 O6 . . 120.7(2)
O5 C17 C18 . . 120.6(2)
O6 C17 C18 . . 118.6(2)
O5 C17 Eu1 . . 60.41(12)
O6 C17 Eu1 . . 61.14(12)
C18 C17 Eu1 . . 168.00(16)
C19 C18 C17 . . 122.9(2)
C19 C18 H18 . . 118.5
C17 C18 H18 . . 118.5
C18 C19 C20 . . 128.0(3)
C18 C19 H19 . . 116.0
C20 C19 H19 . . 116.0
C21 C20 C24 . . 116.6(2)
C21 C20 C19 . . 120.9(2)
C24 C20 C19 . . 122.5(2)
C20 C21 C22 . . 119.6(3)
C20 C21 H21 . . 120.2
C22 C21 H21 . . 120.2
C23 C22 C21 . . 118.6(3)
C23 C22 H22 . . 120.7
C21 C22 H22 . . 120.7
N3 C23 C22 . . 123.9(3)
N3 C23 H23 . . 118.0
C22 C23 H23 . . 118.0
N3 C24 C20 . . 125.0(3)
N3 C24 H24 . . 117.5
C20 C24 H24 . . 117.5
N4 C25 C26 . . 123.3(2)
N4 C25 H25 . . 118.4
C26 C25 H25 . . 118.4
C27 C26 C25 . . 119.2(3)
C27 C26 H26 . . 120.4
C25 C26 H26 . . 120.4
C26 C27 C28 . . 119.9(2)
C26 C27 H27 . . 120.1
C28 C27 H27 . . 120.1
C27 C28 C36 . . 117.5(2)
C27 C28 C29 . . 123.4(2)
C36 C28 C29 . . 119.1(3)
C30 C29 C28 . . 121.2(3)
C30 C29 H29 . . 119.4
C28 C29 H29 . . 119.4
C29 C30 C31 . . 121.6(3)
C29 C30 H30 . . 119.2
C31 C30 H30 . . 119.2
C32 C31 C35 . . 117.5(2)
C32 C31 C30 . . 123.4(2)
C35 C31 C30 . . 119.1(3)
C33 C32 C31 . . 120.0(2)
C33 C32 H32 . . 120.0
C31 C32 H32 . . 120.0
C32 C33 C34 . . 118.8(2)
C32 C33 H33 . . 120.6
C34 C33 H33 . . 120.6
N5 C34 C33 . . 124.0(2)
N5 C34 H34 . . 118.0
C33 C34 H34 . . 118.0
N5 C35 C31 . . 122.6(2)
N5 C35 C36 . . 118.14(19)
C31 C35 C36 . . 119.3(2)
N4 C36 C28 . . 122.1(2)
N4 C36 C35 . . 118.33(19)
C28 C36 C35 . . 119.6(2)
C1 O1 Eu1 . 5_666 140.95(14)
C1 O2 Eu1 . . 136.14(14)
C9 O3 Eu1 . 5_666 169.88(14)
C9 O3 Eu1 . . 86.92(12)
Eu1 O3 Eu1 5_666 . 103.16(5)
C9 O4 Eu1 . . 102.16(13)
C7 N1 C8 . . 115.2(3)
C15 N2 C16 . . 116.7(2)
O1 C1 O2 . . 126.1(2)
O1 C1 C2 . . 115.56(19)
O2 C1 C2 . . 118.4(2)
C3 C2 C1 . . 124.4(2)
C3 C2 H2 . . 117.8
C1 C2 H2 . . 117.8
C2 C3 C4 . . 126.6(2)
C2 C3 H3 . . 116.7
C4 C3 H3 . . 116.7
C5 C4 C8 . . 117.5(2)
C5 C4 C3 . . 122.5(2)
C8 C4 C3 . . 120.0(2)
C4 C5 C6 . . 118.2(3)
C4 C5 H5 . . 120.9
C6 C5 H5 . . 120.9
C7 C6 C5 . . 118.6(3)
C7 C6 H6 . . 120.7
C5 C6 H6 . . 120.7
N1 C7 C6 . . 125.1(3)
N1 C7 H7 . . 117.4
C6 C7 H7 . . 117.4
N1 C8 C4 . . 125.3(3)
N1 C8 H8 . . 117.4
C4 C8 H8 . . 117.4
O4 C9 O3 . . 120.99(19)
O4 C9 C10 . . 119.13(19)
O3 C9 C10 . . 119.86(19)
O4 C9 Eu1 . . 53.47(10)
O3 C9 Eu1 . . 67.83(11)
C10 C9 Eu1 . . 169.61(15)
C11 C10 C9 . . 121.3(2)
C11 C10 H10 . . 119.4
C9 C10 H10 . . 119.4
C10 C11 C12 . . 127.6(2)
C10 C11 H11 . . 116.2
C12 C11 H11 . . 116.2
C13 C12 C16 . . 116.6(2)
C13 C12 C11 . . 123.7(2)
C16 C12 C11 . . 119.7(2)
C12 C13 C14 . . 119.7(3)
C12 C13 H13 . . 120.2
C14 C13 H13 . . 120.2
C15 C14 C13 . . 119.0(3)
C15 C14 H14 . . 120.5
C13 C14 H14 . . 120.5
N2 C15 C14 . . 123.4(3)
N2 C15 H15 . . 118.3
C14 C15 H15 . . 118.3
N2 C16 C12 . . 124.6(3)
N2 C16 H16 . . 117.7
C12 C16 H16 . . 117.7
H11W O1W H12W . . 109.4
H21W O2W H22W . . 109.8
H32W O3W H31W . . 115.1
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Eu1 O3 5_666 2.3604(15)
Eu1 O1 5_666 2.3638(15)
Eu1 O2 . 2.3763(15)
Eu1 O4 . 2.4400(15)
Eu1 O5 . 2.4765(16)
Eu1 O6 . 2.4922(16)
Eu1 N4 . 2.6001(18)
Eu1 N5 . 2.6272(18)
Eu1 O3 . 2.7530(16)
Eu1 C17 . 2.843(2)
Eu1 C9 . 2.969(2)
Eu1 Eu1 5_666 4.0137(3)
O5 C17 . 1.260(3)
O6 C17 . 1.267(3)
N3 C23 . 1.326(4)
N3 C24 . 1.335(3)
N4 C25 . 1.324(3)
N4 C36 . 1.365(3)
N5 C34 . 1.332(3)
N5 C35 . 1.361(3)
C17 C18 . 1.489(3)
C18 C19 . 1.315(3)
C18 H18 . 0.9300
C19 C20 . 1.474(3)
C19 H19 . 0.9300
C20 C21 . 1.380(4)
C20 C24 . 1.385(4)
C21 C22 . 1.381(4)
C21 H21 . 0.9300
C22 C23 . 1.366(5)
C22 H22 . 0.9300
C23 H23 . 0.9300
C24 H24 . 0.9300
C25 C26 . 1.400(3)
C25 H25 . 0.9300
C26 C27 . 1.355(4)
C26 H26 . 0.9300
C27 C28 . 1.408(4)
C27 H27 . 0.9300
C28 C36 . 1.412(3)
C28 C29 . 1.434(4)
C29 C30 . 1.338(4)
C29 H29 . 0.9300
C30 C31 . 1.431(4)
C30 H30 . 0.9300
C31 C32 . 1.404(4)
C31 C35 . 1.413(3)
C32 C33 . 1.357(4)
C32 H32 . 0.9300
C33 C34 . 1.397(3)
C33 H33 . 0.9300
C34 H34 . 0.9300
C35 C36 . 1.443(3)
O1 C1 . 1.258(3)
O1 Eu1 5_666 2.3638(15)
O2 C1 . 1.260(3)
O3 C9 . 1.268(3)
O3 Eu1 5_666 2.3604(15)
O4 C9 . 1.253(3)
N1 C7 . 1.322(5)
N1 C8 . 1.336(4)
N2 C15 . 1.327(4)
N2 C16 . 1.345(3)
C1 C2 . 1.490(3)
C2 C3 . 1.319(3)
C2 H2 . 0.9300
C3 C4 . 1.471(3)
C3 H3 . 0.9300
C4 C5 . 1.382(4)
C4 C8 . 1.388(4)
C5 C6 . 1.394(4)
C5 H5 . 0.9300
C6 C7 . 1.370(5)
C6 H6 . 0.9300
C7 H7 . 0.9300
C8 H8 . 0.9300
C9 C10 . 1.485(3)
C10 C11 . 1.325(3)
C10 H10 . 0.9300
C11 C12 . 1.469(3)
C11 H11 . 0.9300
C12 C13 . 1.381(4)
C12 C16 . 1.385(3)
C13 C14 . 1.382(4)
C13 H13 . 0.9300
C14 C15 . 1.371(4)
C14 H14 . 0.9300
C15 H15 . 0.9300
C16 H16 . 0.9300
O1W H11W . 0.8462
O1W H12W . 0.8481
O2W H21W . 0.8204
O2W H22W . 0.8227
O3W H32W . 0.8204
O3W H31W . 0.8198
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
O1W H11W O6 . 0.85 1.94 2.775(3) 170.9
O1W H12W N2 3_545 0.85 2.02 2.856(3) 166.8
O2W H21W O1W 3_445 0.82 2.48 2.851(4) 108.6
O3W H31W O2W 1_565 0.82 2.20 2.655(7) 115.5
