#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/78/2217800.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2217800
loop_
_publ_author_name
'Li, Hong'
'Zhao, Hong Yan'
'Zhang, Shi Guo'
_publ_section_title
;
 (Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate
;
_journal_coeditor_code           LH2594
_journal_issue                   3
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m495
_journal_paper_doi               10.1107/S1600536808004741
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '[Zn (C2 N3) (C18 H18 N4)] Cl O4'
_chemical_formula_moiety         'C20 H18 N7 Zn +, Cl O4 -'
_chemical_formula_sum            'C20 H18 Cl N7 O4 Zn'
_chemical_formula_weight         521.23
_chemical_name_systematic
;
(Dicyanamido)[tris(2-pyridylmethyl)amine]zinc(II) perchlorate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 91.590(3)
_cell_angle_gamma                90.00
_cell_formula_units_Z            4
_cell_length_a                   13.931(2)
_cell_length_b                   10.8578(18)
_cell_length_c                   14.653(2)
_cell_measurement_reflns_used    2616
_cell_measurement_temperature    298(2)
_cell_measurement_theta_max      21.961
_cell_measurement_theta_min      2.335
_cell_volume                     2215.6(6)
_computing_cell_refinement       'SAINT (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 1997)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      298(2)
_diffrn_measured_fraction_theta_full 0.993
_diffrn_measured_fraction_theta_max 0.993
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0346
_diffrn_reflns_av_sigmaI/netI    0.0497
_diffrn_reflns_limit_h_max       17
_diffrn_reflns_limit_h_min       -15
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            12346
_diffrn_reflns_theta_full        27.00
_diffrn_reflns_theta_max         27.00
_diffrn_reflns_theta_min         2.33
_exptl_absorpt_coefficient_mu    1.272
_exptl_absorpt_correction_T_max  0.8034
_exptl_absorpt_correction_T_min  0.7015
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.563
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1064
_exptl_crystal_size_max          0.30
_exptl_crystal_size_mid          0.20
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.360
_refine_diff_density_min         -0.249
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   0.992
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     308
_refine_ls_number_reflns         4800
_refine_ls_number_restraints     1
_refine_ls_restrained_S_all      0.993
_refine_ls_R_factor_all          0.0670
_refine_ls_R_factor_gt           0.0426
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.053P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0996
_refine_ls_wR_factor_ref         0.1061
_reflns_number_gt                3352
_reflns_number_total             4800
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            lh2594.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (5
times).

'_geom_angle_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (10 times).

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from
2010-06-29.

'_geom_bond_publ_flag' value 'Y' changed to 'y'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29 (5
times).

'_geom_angle_publ_flag' value 'Y' changed to 'y' according
to /home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary
named 'cif_core.dic' version 2.4.1 from 2010-06-29 (10 times).

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_cell_volume        2215.5(6)
_cod_original_sg_symbol_H-M      'P 21/c  '
_cod_database_code               2217800
_cod_database_fobs_code          2217800
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
C C1 0.0860(2) 0.9139(3) 0.2853(2) 0.0612(9) Uani d . 1
H H1 0.0337 0.8627 0.2947 0.073 Uiso calc R 1
C C2 0.1044(3) 1.0115(4) 0.3423(2) 0.0697(10) Uani d . 1
H H2 0.0648 1.0272 0.3910 0.084 Uiso calc R 1
C C3 0.1813(3) 1.0854(3) 0.3270(2) 0.0674(9) Uani d . 1
H H3 0.1952 1.1517 0.3654 0.081 Uiso calc R 1
C C4 0.2375(2) 1.0607(3) 0.2547(2) 0.0545(8) Uani d . 1
H H4 0.2894 1.1122 0.2439 0.065 Uiso calc R 1
C C5 0.14649(19) 0.8927(3) 0.21361(19) 0.0461(7) Uani d . 1
C C6 0.1355(2) 0.7823(3) 0.1528(2) 0.0562(8) Uani d . 1
H H6A 0.1669 0.7122 0.1816 0.067 Uiso calc R 1
H H6B 0.0678 0.7629 0.1445 0.067 Uiso calc R 1
C C7 0.1151(2) 0.8761(3) 0.0017(2) 0.0629(9) Uani d . 1
H H7A 0.0784 0.9345 0.0367 0.076 Uiso calc R 1
H H7B 0.0702 0.8217 -0.0301 0.076 Uiso calc R 1
C C8 0.1729(2) 0.9441(3) -0.0664(2) 0.0519(7) Uani d . 1
C C9 0.1372(3) 0.9713(3) -0.1530(2) 0.0691(9) Uani d . 1
H H9 0.0769 0.9431 -0.1722 0.083 Uiso calc R 1
C C10 0.1913(4) 1.0397(4) -0.2098(2) 0.0812(11) Uani d . 1
H H10 0.1684 1.0590 -0.2683 0.097 Uiso calc R 1
C C11 0.2798(3) 1.0797(3) -0.1801(2) 0.0786(11) Uani d . 1
H H11 0.3177 1.1267 -0.2180 0.094 Uiso calc R 1
C C12 0.3118(3) 1.0497(3) -0.0937(2) 0.0617(8) Uani d . 1
H H12 0.3719 1.0774 -0.0736 0.074 Uiso calc R 1
C C13 0.2121(2) 0.6901(3) 0.0215(2) 0.0628(9) Uani d . 1
H H13A 0.2159 0.7016 -0.0439 0.075 Uiso calc R 1
H H13B 0.1676 0.6233 0.0324 0.075 Uiso calc R 1
C C14 0.3093(2) 0.6574(3) 0.0606(2) 0.0554(8) Uani d . 1
C C15 0.3413(4) 0.5360(3) 0.0654(3) 0.0844(12) Uani d . 1
H H15 0.3010 0.4718 0.0469 0.101 Uiso calc R 1
C C16 0.4314(4) 0.5126(4) 0.0972(3) 0.1041(15) Uani d . 1
H H16 0.4535 0.4318 0.1008 0.125 Uiso calc R 1
C C17 0.4900(3) 0.6072(4) 0.1240(3) 0.0947(14) Uani d . 1
H H17 0.5526 0.5922 0.1448 0.114 Uiso calc R 1
C C18 0.4545(2) 0.7252(3) 0.1195(2) 0.0681(9) Uani d . 1
H H18 0.4936 0.7899 0.1392 0.082 Uiso calc R 1
C C19 0.4657(2) 1.1134(3) 0.1232(2) 0.0594(8) Uani d U 1
C C20 0.5964(3) 1.2341(3) 0.1587(2) 0.0670(9) Uani d . 1
Cl Cl1 0.13251(5) 0.26686(7) 0.06625(5) 0.0551(2) Uani d . 1
N N1 0.25963(17) 0.9822(2) -0.03743(15) 0.0474(6) Uani d . 1
N N2 0.22133(15) 0.9657(2) 0.19860(14) 0.0425(5) Uani d . 1
N N3 0.36571(17) 0.7501(2) 0.08790(16) 0.0500(6) Uani d . 1
N N4 0.17686(15) 0.8038(2) 0.06381(15) 0.0461(6) Uani d . 1
N N5 0.42095(18) 1.0295(3) 0.11270(19) 0.0626(7) Uani d U 1
N N6 0.6718(3) 1.2592(3) 0.1805(2) 0.1036(12) Uani d . 1
N N7 0.5015(14) 1.214(2) 0.157(3) 0.066(7) Uani d P 0.40(7)
N N7' 0.5148(16) 1.2179(15) 0.116(3) 0.100(5) Uani d P 0.60(7)
O O1 0.1054(2) 0.3925(2) 0.06831(17) 0.0854(8) Uani d . 1
O O2 0.08216(17) 0.2017(2) 0.13439(16) 0.0821(7) Uani d . 1
O O3 0.23268(17) 0.2569(3) 0.0827(2) 0.0980(8) Uani d . 1
O O4 0.1080(2) 0.2177(2) -0.02084(16) 0.0905(8) Uani d . 1
Zn Zn1 0.30405(2) 0.92245(3) 0.08979(2) 0.04138(12) Uani d . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
C2 C1 C5 119.0(3) ?
C2 C1 H1 120.5 ?
C5 C1 H1 120.5 ?
C3 C2 C1 119.4(3) ?
C3 C2 H2 120.3 ?
C1 C2 H2 120.3 ?
C2 C3 C4 118.9(3) ?
C2 C3 H3 120.5 ?
C4 C3 H3 120.5 ?
N2 C4 C3 122.7(3) ?
N2 C4 H4 118.6 ?
C3 C4 H4 118.6 ?
N2 C5 C1 121.4(3) ?
N2 C5 C6 116.4(2) ?
C1 C5 C6 122.0(3) ?
N4 C6 C5 111.5(2) ?
N4 C6 H6A 109.3 ?
C5 C6 H6A 109.3 ?
N4 C6 H6B 109.3 ?
C5 C6 H6B 109.3 ?
H6A C6 H6B 108.0 ?
N4 C7 C8 111.2(2) ?
N4 C7 H7A 109.4 ?
C8 C7 H7A 109.4 ?
N4 C7 H7B 109.4 ?
C8 C7 H7B 109.4 ?
H7A C7 H7B 108.0 ?
N1 C8 C9 121.7(3) ?
N1 C8 C7 116.1(2) ?
C9 C8 C7 122.1(3) ?
C10 C9 C8 119.2(4) ?
C10 C9 H9 120.4 ?
C8 C9 H9 120.4 ?
C9 C10 C11 119.3(3) ?
C9 C10 H10 120.4 ?
C11 C10 H10 120.4 ?
C10 C11 C12 119.1(3) ?
C10 C11 H11 120.4 ?
C12 C11 H11 120.4 ?
N1 C12 C11 122.2(3) ?
N1 C12 H12 118.9 ?
C11 C12 H12 118.9 ?
N4 C13 C14 110.3(2) ?
N4 C13 H13A 109.6 ?
C14 C13 H13A 109.6 ?
N4 C13 H13B 109.6 ?
C14 C13 H13B 109.6 ?
H13A C13 H13B 108.1 ?
N3 C14 C15 121.0(3) ?
N3 C14 C13 117.1(3) ?
C15 C14 C13 121.9(3) ?
C16 C15 C14 119.3(4) ?
C16 C15 H15 120.4 ?
C14 C15 H15 120.4 ?
C15 C16 C17 120.0(4) ?
C15 C16 H16 120.0 ?
C17 C16 H16 120.0 ?
C16 C17 C18 118.5(4) ?
C16 C17 H17 120.7 ?
C18 C17 H17 120.7 ?
N3 C18 C17 122.3(4) ?
N3 C18 H18 118.9 ?
C17 C18 H18 118.9 ?
N5 C19 N7 162.3(19) ?
N5 C19 N7' 166.9(17) ?
N6 C20 N7' 166.3(18) ?
N6 C20 N7 163.6(17) ?
O3 Cl1 O4 109.71(18) ?
O3 Cl1 O1 109.44(17) ?
O4 Cl1 O1 108.92(16) ?
O3 Cl1 O2 110.20(16) ?
O4 Cl1 O2 109.48(16) ?
O1 Cl1 O2 109.07(16) ?
C12 N1 C8 118.5(3) ?
C12 N1 Zn1 125.4(2) ?
C8 N1 Zn1 115.97(19) ?
C5 N2 C4 118.6(3) ?
C5 N2 Zn1 116.86(19) ?
C4 N2 Zn1 124.6(2) ?
C14 N3 C18 118.9(3) ?
C14 N3 Zn1 116.6(2) ?
C18 N3 Zn1 124.2(2) ?
C6 N4 C7 113.7(2) ?
C6 N4 C13 112.7(2) ?
C7 N4 C13 112.7(2) ?
C6 N4 Zn1 105.89(16) ?
C7 N4 Zn1 104.41(17) ?
C13 N4 Zn1 106.58(17) ?
C19 N5 Zn1 160.0(3) ?
C19 N7 C20 120.9(14) ?
C20 N7' C19 121.4(13) ?
N5 Zn1 N2 101.94(10) y
N5 Zn1 N1 100.96(11) y
N2 Zn1 N1 118.19(9) y
N5 Zn1 N3 100.98(10) y
N2 Zn1 N3 117.58(9) y
N1 Zn1 N3 112.99(9) y
N5 Zn1 N4 179.41(10) y
N2 Zn1 N4 78.60(9) y
N1 Zn1 N4 78.95(9) y
N3 Zn1 N4 78.55(9) y
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
C1 C2 1.368(5) ?
C1 C5 1.384(4) ?
C1 H1 0.9300 ?
C2 C3 1.362(5) ?
C2 H2 0.9300 ?
C3 C4 1.362(4) ?
C3 H3 0.9300 ?
C4 N2 1.334(3) ?
C4 H4 0.9300 ?
C5 N2 1.333(3) ?
C5 C6 1.499(4) ?
C6 N4 1.458(3) ?
C6 H6A 0.9700 ?
C6 H6B 0.9700 ?
C7 N4 1.463(4) ?
C7 C8 1.495(4) ?
C7 H7A 0.9700 ?
C7 H7B 0.9700 ?
C8 N1 1.335(4) ?
C8 C9 1.382(4) ?
C9 C10 1.359(5) ?
C9 H9 0.9300 ?
C10 C11 1.367(6) ?
C10 H10 0.9300 ?
C11 C12 1.369(5) ?
C11 H11 0.9300 ?
C12 N1 1.334(4) ?
C12 H12 0.9300 ?
C13 N4 1.472(4) ?
C13 C14 1.498(4) ?
C13 H13A 0.9700 ?
C13 H13B 0.9700 ?
C14 N3 1.332(4) ?
C14 C15 1.392(5) ?
C15 C16 1.352(6) ?
C15 H15 0.9300 ?
C16 C17 1.363(6) ?
C16 H16 0.9300 ?
C17 C18 1.374(5) ?
C17 H17 0.9300 ?
C18 N3 1.336(4) ?
C18 H18 0.9300 ?
C19 N5 1.112(4) ?
C19 N7 1.294(17) ?
C19 N7' 1.331(14) ?
C20 N6 1.122(4) ?
C20 N7' 1.298(16) ?
C20 N7 1.34(2) ?
Cl1 O3 1.414(2) ?
Cl1 O4 1.416(2) ?
Cl1 O1 1.416(2) ?
Cl1 O2 1.424(2) ?
N1 Zn1 2.053(2) y
N2 Zn1 2.048(2) y
N3 Zn1 2.059(2) y
N4 Zn1 2.215(2) y
N5 Zn1 2.021(3) y
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C3 H3 O4 4_576 0.93 2.53 3.272(4) 137.5
C7 H7B O2 3_565 0.97 2.59 3.455(4) 148.1
C10 H10 O1 4_575 0.93 2.58 3.511(5) 178.7
C13 H13A N6 3_675 0.97 2.61 3.457(5) 146.0
C16 H16 N7' 1_545 0.93 2.48 3.412(18) 178.1
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
C5 C1 C2 C3 0.2(5)
C1 C2 C3 C4 0.6(5)
C2 C3 C4 N2 -1.0(5)
C2 C1 C5 N2 -0.6(4)
C2 C1 C5 C6 175.2(3)
N2 C5 C6 N4 -27.9(3)
C1 C5 C6 N4 156.1(3)
N4 C7 C8 N1 -33.0(4)
N4 C7 C8 C9 150.0(3)
N1 C8 C9 C10 -0.7(5)
C7 C8 C9 C10 176.1(3)
C8 C9 C10 C11 0.1(6)
C9 C10 C11 C12 0.1(6)
C10 C11 C12 N1 0.2(5)
N4 C13 C14 N3 -30.8(4)
N4 C13 C14 C15 151.5(3)
N3 C14 C15 C16 -0.8(5)
C13 C14 C15 C16 176.8(4)
C14 C15 C16 C17 -0.1(7)
C15 C16 C17 C18 1.3(7)
C16 C17 C18 N3 -1.6(6)
C11 C12 N1 C8 -0.8(5)
C11 C12 N1 Zn1 175.7(2)
C9 C8 N1 C12 1.0(4)
C7 C8 N1 C12 -176.0(3)
C9 C8 N1 Zn1 -175.8(2)
C7 C8 N1 Zn1 7.2(3)
C1 C5 N2 C4 0.2(4)
C6 C5 N2 C4 -175.8(2)
C1 C5 N2 Zn1 -180.0(2)
C6 C5 N2 Zn1 4.0(3)
C3 C4 N2 C5 0.6(4)
C3 C4 N2 Zn1 -179.2(2)
C15 C14 N3 C18 0.6(4)
C13 C14 N3 C18 -177.2(3)
C15 C14 N3 Zn1 -173.6(2)
C13 C14 N3 Zn1 8.6(3)
C17 C18 N3 C14 0.7(5)
C17 C18 N3 Zn1 174.4(3)
C5 C6 N4 C7 -79.4(3)
C5 C6 N4 C13 150.8(2)
C5 C6 N4 Zn1 34.7(3)
C8 C7 N4 C6 153.5(3)
C8 C7 N4 C13 -76.7(3)
C8 C7 N4 Zn1 38.6(3)
C14 C13 N4 C6 -80.8(3)
C14 C13 N4 C7 148.9(2)
C14 C13 N4 Zn1 34.9(3)
N7 C19 N5 Zn1 63(5)
N7' C19 N5 Zn1 -71(7)
N5 C19 N7 C20 138.7(19)
N7' C19 N7 C20 -61(3)
N6 C20 N7 C19 -134(2)
N7' C20 N7 C19 65(3)
N6 C20 N7' C19 141(3)
N7 C20 N7' C19 -62(2)
N5 C19 N7' C20 -142(3)
N7 C19 N7' C20 66(3)
C19 N5 Zn1 N2 -60.5(8)
C19 N5 Zn1 N1 61.7(8)
C19 N5 Zn1 N3 178.0(8)
C5 N2 Zn1 N5 -167.30(19)
C4 N2 Zn1 N5 12.5(2)
C5 N2 Zn1 N1 83.2(2)
C4 N2 Zn1 N1 -97.0(2)
C5 N2 Zn1 N3 -58.0(2)
C4 N2 Zn1 N3 121.8(2)
C5 N2 Zn1 N4 12.47(18)
C4 N2 Zn1 N4 -167.7(2)
C12 N1 Zn1 N5 14.7(3)
C8 N1 Zn1 N5 -168.7(2)
C12 N1 Zn1 N2 124.8(2)
C8 N1 Zn1 N2 -58.7(2)
C12 N1 Zn1 N3 -92.3(2)
C8 N1 Zn1 N3 84.2(2)
C12 N1 Zn1 N4 -164.7(3)
C8 N1 Zn1 N4 11.9(2)
C14 N3 Zn1 N5 -170.4(2)
C18 N3 Zn1 N5 15.8(3)
C14 N3 Zn1 N2 79.8(2)
C18 N3 Zn1 N2 -94.1(3)
C14 N3 Zn1 N1 -63.4(2)
C18 N3 Zn1 N1 122.8(2)
C14 N3 Zn1 N4 9.3(2)
C18 N3 Zn1 N4 -164.6(3)
C6 N4 Zn1 N2 -25.66(18)
C7 N4 Zn1 N2 94.61(19)
C13 N4 Zn1 N2 -145.91(19)
C6 N4 Zn1 N1 -147.68(19)
C7 N4 Zn1 N1 -27.42(18)
C13 N4 Zn1 N1 92.06(19)
C6 N4 Zn1 N3 95.86(18)
C7 N4 Zn1 N3 -143.9(2)
C13 N4 Zn1 N3 -24.39(18)
