#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/85/2218569.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2218569
loop_
_publ_author_name
'Li, Hong'
'Hu, Tai Qiu'
'Zhang, Shi Guo'
_publ_section_title
;
 Dichlorido(2-methoxy-1,10-phenanthroline-κ²N,N')zinc(II)
;
_journal_coeditor_code           WW2117
_journal_issue                   6
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m771
_journal_paper_doi               10.1107/S160053680801180X
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '[Zn Cl2 (C13 H10 N2 O)]'
_chemical_formula_moiety         'C13 H10 Cl2 N2 O Zn '
_chemical_formula_sum            'C13 H10 Cl2 N2 O Zn'
_chemical_formula_weight         346.50
_chemical_name_systematic
;
Dichlorido(2-methoxy-1,10-phenanthroline-κ²N,N')zinc(II)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                91.849(2)
_cell_angle_beta                 108.295(2)
_cell_angle_gamma                98.672(2)
_cell_formula_units_Z            4
_cell_length_a                   9.9051(17)
_cell_length_b                   11.5654(19)
_cell_length_c                   12.774(2)
_cell_measurement_reflns_used    3641
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      26.9725
_cell_measurement_theta_min      2.3505
_cell_volume                     1368.5(4)
_computing_cell_refinement       'SAINT (Bruker, 1997)'
_computing_data_collection       'SMART (Bruker, 1997)'
_computing_data_reduction        'SAINT (Bruker, 1997)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      446(2)
_diffrn_measured_fraction_theta_full 0.978
_diffrn_measured_fraction_theta_max 0.978
_diffrn_measurement_device_type  'Bruker SMART APEX CCD'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0188
_diffrn_reflns_av_sigmaI/netI    0.0386
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -12
_diffrn_reflns_limit_k_max       12
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       14
_diffrn_reflns_limit_l_min       -15
_diffrn_reflns_number            7507
_diffrn_reflns_theta_full        26.00
_diffrn_reflns_theta_max         26.00
_diffrn_reflns_theta_min         1.69
_diffrn_standards_decay_%        0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.176
_exptl_absorpt_correction_T_max  0.8118
_exptl_absorpt_correction_T_min  0.4033
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colorless
_exptl_crystal_density_diffrn    1.682
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             696
_exptl_crystal_size_max          0.51
_exptl_crystal_size_mid          0.40
_exptl_crystal_size_min          0.10
_refine_diff_density_max         0.594
_refine_diff_density_min         -0.354
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.052
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     345
_refine_ls_number_reflns         5264
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.052
_refine_ls_R_factor_all          0.0421
_refine_ls_R_factor_gt           0.0341
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0513P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0887
_refine_ls_wR_factor_ref         0.0917
_reflns_number_gt                4386
_reflns_number_total             5264
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            ww2117.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (8
times).

'_geom_angle_publ_flag' value 'Y' changed to 'y' according to
'/home/saulius/struct/CIF-dictionaries/cif_core.dic' dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (12 times).

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_geom_bond_publ_flag' value 'Y' changed to 'y' according to
/home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary named
'cif_core.dic' version 2.4.1 from 2010-06-29 (8
times).

'_geom_angle_publ_flag' value 'Y' changed to 'y' according
to /home/saulius/struct/CIF-dictionaries/cif_core.dic dictionary
named 'cif_core.dic' version 2.4.1 from 2010-06-29 (12 times).

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_database_code               2218569
_cod_database_fobs_code          2218569
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
C C1 0.5226(3) 0.3267(3) 1.0172(2) 0.0481(7) Uani d . 1
H H1A 0.5587 0.2596 0.9974 0.072 Uiso calc R 1
H H1B 0.4565 0.3028 1.0567 0.072 Uiso calc R 1
H H1C 0.6016 0.3835 1.0634 0.072 Uiso calc R 1
C C2 0.5263(3) 0.4341(2) 0.8608(2) 0.0368(6) Uani d . 1
C C3 0.6781(3) 0.4562(2) 0.8936(2) 0.0462(7) Uani d . 1
H H3 0.7326 0.4304 0.9593 0.055 Uiso calc R 1
C C4 0.7431(3) 0.5151(3) 0.8286(3) 0.0505(7) Uani d . 1
H H4 0.8433 0.5282 0.8487 0.061 Uiso calc R 1
C C5 0.6615(3) 0.5573(2) 0.7302(2) 0.0429(6) Uani d . 1
C C6 0.5121(3) 0.5345(2) 0.7051(2) 0.0334(5) Uani d . 1
C C7 0.4210(3) 0.5801(2) 0.6104(2) 0.0370(6) Uani d . 1
C C8 0.1928(4) 0.6050(3) 0.5073(2) 0.0518(7) Uani d . 1
H H8 0.0938 0.5918 0.4950 0.062 Uiso calc R 1
C C9 0.2462(4) 0.6718(3) 0.4356(3) 0.0622(9) Uani d . 1
H H9 0.1838 0.7031 0.3772 0.075 Uiso calc R 1
C C10 0.3897(4) 0.6909(3) 0.4518(2) 0.0581(9) Uani d . 1
H H10 0.4259 0.7341 0.4034 0.070 Uiso calc R 1
C C11 0.4844(3) 0.6458(2) 0.5413(2) 0.0453(7) Uani d . 1
C C12 0.6372(4) 0.6614(3) 0.5662(3) 0.0540(8) Uani d . 1
H H12 0.6791 0.7013 0.5191 0.065 Uiso calc R 1
C C13 0.7222(3) 0.6196(3) 0.6564(3) 0.0518(8) Uani d . 1
H H13 0.8215 0.6315 0.6707 0.062 Uiso calc R 1
C C14 0.7048(3) 0.9284(3) 1.0543(2) 0.0493(7) Uani d . 1
H H14 0.6289 0.9633 1.0609 0.059 Uiso calc R 1
C C15 0.7847(4) 0.8771(3) 1.1450(2) 0.0577(8) Uani d . 1
H H15 0.7612 0.8760 1.2100 0.069 Uiso calc R 1
C C16 0.8981(4) 0.8284(3) 1.1366(2) 0.0593(9) Uani d . 1
H H16 0.9532 0.7941 1.1966 0.071 Uiso calc R 1
C C17 0.9327(3) 0.8296(2) 1.0379(2) 0.0463(7) Uani d . 1
C C18 0.8429(3) 0.8819(2) 0.9508(2) 0.0396(6) Uani d . 1
C C19 0.8719(3) 0.8864(2) 0.8467(2) 0.0388(6) Uani d . 1
C C20 0.9915(3) 0.8434(2) 0.8365(3) 0.0474(7) Uani d . 1
C C21 1.0808(4) 0.7921(3) 0.9269(3) 0.0642(9) Uani d . 1
H H21 1.1610 0.7640 0.9198 0.077 Uiso calc R 1
C C22 1.0512(4) 0.7837(3) 1.0217(3) 0.0628(9) Uani d . 1
H H22 1.1092 0.7472 1.0784 0.075 Uiso calc R 1
C C23 1.0158(4) 0.8553(3) 0.7330(3) 0.0594(9) Uani d . 1
H H23 1.0949 0.8294 0.7215 0.071 Uiso calc R 1
C C24 0.9236(3) 0.9045(3) 0.6509(3) 0.0526(8) Uani d . 1
H H24 0.9398 0.9134 0.5834 0.063 Uiso calc R 1
C C25 0.8042(3) 0.9416(3) 0.6693(2) 0.0486(7) Uani d . 1
C C26 0.7173(5) 1.0057(4) 0.4866(3) 0.0829(13) Uani d . 1
H H26A 0.8048 1.0594 0.4954 0.124 Uiso calc R 1
H H26B 0.6365 1.0377 0.4417 0.124 Uiso calc R 1
H H26C 0.7209 0.9322 0.4514 0.124 Uiso calc R 1
Cl Cl1 0.57382(10) 1.15815(7) 0.79281(6) 0.0581(2) Uani d . 1
Cl Cl2 0.40833(9) 0.84139(7) 0.75709(6) 0.0574(2) Uani d . 1
Cl Cl3 0.09774(8) 0.51212(8) 0.79552(7) 0.0641(2) Uani d . 1
Cl Cl4 0.12965(8) 0.27076(6) 0.60771(5) 0.04690(18) Uani d . 1
N N1 0.4460(2) 0.47186(17) 0.76905(16) 0.0327(5) Uani d . 1
N N2 0.2774(2) 0.55965(19) 0.59217(17) 0.0393(5) Uani d . 1
N N3 0.7313(3) 0.93004(19) 0.95981(17) 0.0410(5) Uani d . 1
N N4 0.7788(3) 0.93342(19) 0.76405(17) 0.0398(5) Uani d . 1
O O1 0.4488(2) 0.37827(16) 0.91786(14) 0.0420(4) Uani d . 1
O O2 0.7019(3) 0.9874(2) 0.59364(16) 0.0640(6) Uani d . 1
Zn Zn1 0.22524(3) 0.44580(3) 0.70131(2) 0.03586(10) Uani d . 1
Zn Zn2 0.60675(3) 0.97534(3) 0.80582(2) 0.03979(11) Uani d . 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Zn Zn 0.2839 1.4301 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle
_geom_angle_publ_flag
O1 C1 H1A 109.5 ?
O1 C1 H1B 109.5 ?
H1A C1 H1B 109.5 ?
O1 C1 H1C 109.5 ?
H1A C1 H1C 109.5 ?
H1B C1 H1C 109.5 ?
N1 C2 O1 113.0(2) ?
N1 C2 C3 121.8(2) ?
O1 C2 C3 125.1(2) ?
C4 C3 C2 119.0(3) ?
C4 C3 H3 120.5 ?
C2 C3 H3 120.5 ?
C3 C4 C5 120.9(3) ?
C3 C4 H4 119.5 ?
C5 C4 H4 119.5 ?
C6 C5 C4 116.5(3) ?
C6 C5 C13 119.2(3) ?
C4 C5 C13 124.3(3) ?
N1 C6 C5 122.6(2) ?
N1 C6 C7 117.0(2) ?
C5 C6 C7 120.3(2) ?
N2 C7 C11 122.8(3) ?
N2 C7 C6 118.0(2) ?
C11 C7 C6 119.2(3) ?
N2 C8 C9 122.5(3) ?
N2 C8 H8 118.7 ?
C9 C8 H8 118.7 ?
C10 C9 C8 119.4(3) ?
C10 C9 H9 120.3 ?
C8 C9 H9 120.3 ?
C9 C10 C11 120.3(3) ?
C9 C10 H10 119.8 ?
C11 C10 H10 119.8 ?
C10 C11 C7 116.4(3) ?
C10 C11 C12 124.8(3) ?
C7 C11 C12 118.8(3) ?
C13 C12 C11 121.6(3) ?
C13 C12 H12 119.2 ?
C11 C12 H12 119.2 ?
C12 C13 C5 120.8(3) ?
C12 C13 H13 119.6 ?
C5 C13 H13 119.6 ?
N3 C14 C15 123.2(3) ?
N3 C14 H14 118.4 ?
C15 C14 H14 118.4 ?
C16 C15 C14 118.5(3) ?
C16 C15 H15 120.7 ?
C14 C15 H15 120.7 ?
C15 C16 C17 120.5(3) ?
C15 C16 H16 119.7 ?
C17 C16 H16 119.7 ?
C16 C17 C18 116.1(3) ?
C16 C17 C22 124.9(3) ?
C18 C17 C22 119.1(3) ?
N3 C18 C17 123.0(3) ?
N3 C18 C19 117.8(2) ?
C17 C18 C19 119.2(3) ?
N4 C19 C20 123.9(3) ?
N4 C19 C18 116.8(2) ?
C20 C19 C18 119.3(3) ?
C19 C20 C23 115.8(3) ?
C19 C20 C21 119.9(3) ?
C23 C20 C21 124.3(3) ?
C22 C21 C20 121.0(3) ?
C22 C21 H21 119.5 ?
C20 C21 H21 119.5 ?
C21 C22 C17 121.5(3) ?
C21 C22 H22 119.3 ?
C17 C22 H22 119.3 ?
C24 C23 C20 120.2(3) ?
C24 C23 H23 119.9 ?
C20 C23 H23 119.9 ?
C23 C24 C25 119.1(3) ?
C23 C24 H24 120.5 ?
C25 C24 H24 120.5 ?
N4 C25 O2 112.3(3) ?
N4 C25 C24 122.7(3) ?
O2 C25 C24 125.0(3) ?
O2 C26 H26A 109.5 ?
O2 C26 H26B 109.5 ?
H26A C26 H26B 109.5 ?
O2 C26 H26C 109.5 ?
H26A C26 H26C 109.5 ?
H26B C26 H26C 109.5 ?
C2 N1 C6 119.0(2) ?
C2 N1 Zn1 128.98(18) ?
C6 N1 Zn1 111.96(16) ?
C8 N2 C7 118.5(2) ?
C8 N2 Zn1 130.2(2) ?
C7 N2 Zn1 111.08(17) ?
C14 N3 C18 118.5(2) ?
C14 N3 Zn2 129.7(2) ?
C18 N3 Zn2 111.10(17) ?
C25 N4 C19 118.4(3) ?
C25 N4 Zn2 128.8(2) ?
C19 N4 Zn2 112.72(17) ?
C2 O1 C1 118.9(2) ?
C25 O2 C26 118.9(3) ?
N1 Zn1 N2 81.15(8) y
N1 Zn1 Cl3 119.22(6) y
N2 Zn1 Cl3 114.55(7) y
N1 Zn1 Cl4 113.92(6) y
N2 Zn1 Cl4 107.63(6) y
Cl3 Zn1 Cl4 115.13(3) y
N4 Zn2 N3 80.57(9) y
N4 Zn2 Cl1 116.23(7) y
N3 Zn2 Cl1 117.56(7) y
N4 Zn2 Cl2 116.69(7) y
N3 Zn2 Cl2 104.48(7) y
Cl1 Zn2 Cl2 115.82(4) y
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_distance
_geom_bond_publ_flag
C1 O1 1.449(3) ?
C1 H1A 0.9600 ?
C1 H1B 0.9600 ?
C1 H1C 0.9600 ?
C2 N1 1.323(3) ?
C2 O1 1.330(3) ?
C2 C3 1.409(4) ?
C3 C4 1.345(4) ?
C3 H3 0.9300 ?
C4 C5 1.411(4) ?
C4 H4 0.9300 ?
C5 C6 1.393(4) ?
C5 C13 1.428(4) ?
C6 N1 1.361(3) ?
C6 C7 1.434(4) ?
C7 N2 1.349(3) ?
C7 C11 1.412(4) ?
C8 N2 1.323(3) ?
C8 C9 1.394(4) ?
C8 H8 0.9300 ?
C9 C10 1.353(5) ?
C9 H9 0.9300 ?
C10 C11 1.404(4) ?
C10 H10 0.9300 ?
C11 C12 1.427(4) ?
C12 C13 1.349(5) ?
C12 H12 0.9300 ?
C13 H13 0.9300 ?
C14 N3 1.313(3) ?
C14 C15 1.389(4) ?
C14 H14 0.9300 ?
C15 C16 1.361(5) ?
C15 H15 0.9300 ?
C16 C17 1.406(4) ?
C16 H16 0.9300 ?
C17 C18 1.407(4) ?
C17 C22 1.427(5) ?
C18 N3 1.344(4) ?
C18 C19 1.447(4) ?
C19 N4 1.356(3) ?
C19 C20 1.392(4) ?
C20 C23 1.423(4) ?
C20 C21 1.424(4) ?
C21 C22 1.336(5) ?
C21 H21 0.9300 ?
C22 H22 0.9300 ?
C23 C24 1.361(5) ?
C23 H23 0.9300 ?
C24 C25 1.400(4) ?
C24 H24 0.9300 ?
C25 N4 1.315(3) ?
C25 O2 1.349(4) ?
C26 O2 1.441(3) ?
C26 H26A 0.9600 ?
C26 H26B 0.9600 ?
C26 H26C 0.9600 ?
Cl1 Zn2 2.1911(8) y
Cl2 Zn2 2.2139(9) y
Cl3 Zn1 2.1949(8) y
Cl4 Zn1 2.2315(8) y
N1 Zn1 2.054(2) y
N2 Zn1 2.076(2) y
N3 Zn2 2.098(2) y
N4 Zn2 2.056(2) y
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion
N1 C2 C3 C4 -1.5(4)
O1 C2 C3 C4 -179.2(3)
C2 C3 C4 C5 1.7(4)
C3 C4 C5 C6 0.0(4)
C3 C4 C5 C13 -179.4(3)
C4 C5 C6 N1 -2.0(4)
C13 C5 C6 N1 177.4(2)
C4 C5 C6 C7 176.2(2)
C13 C5 C6 C7 -4.3(4)
N1 C6 C7 N2 1.0(3)
C5 C6 C7 N2 -177.3(2)
N1 C6 C7 C11 -180.0(2)
C5 C6 C7 C11 1.6(4)
N2 C8 C9 C10 0.6(5)
C8 C9 C10 C11 -1.3(5)
C9 C10 C11 C7 0.6(4)
C9 C10 C11 C12 -179.6(3)
N2 C7 C11 C10 0.7(4)
C6 C7 C11 C10 -178.2(2)
N2 C7 C11 C12 -179.1(2)
C6 C7 C11 C12 2.0(4)
C10 C11 C12 C13 177.2(3)
C7 C11 C12 C13 -3.0(4)
C11 C12 C13 C5 0.3(5)
C6 C5 C13 C12 3.3(4)
C4 C5 C13 C12 -177.2(3)
N3 C14 C15 C16 1.6(5)
C14 C15 C16 C17 -0.4(5)
C15 C16 C17 C18 -0.7(4)
C15 C16 C17 C22 178.3(3)
C16 C17 C18 N3 0.9(4)
C22 C17 C18 N3 -178.2(3)
C16 C17 C18 C19 180.0(2)
C22 C17 C18 C19 0.9(4)
N3 C18 C19 N4 -3.5(4)
C17 C18 C19 N4 177.4(2)
N3 C18 C19 C20 176.4(2)
C17 C18 C19 C20 -2.7(4)
N4 C19 C20 C23 2.3(4)
C18 C19 C20 C23 -177.5(2)
N4 C19 C20 C21 -178.0(3)
C18 C19 C20 C21 2.1(4)
C19 C20 C21 C22 0.5(5)
C23 C20 C21 C22 -179.9(3)
C20 C21 C22 C17 -2.4(5)
C16 C17 C22 C21 -177.3(3)
C18 C17 C22 C21 1.7(5)
C19 C20 C23 C24 -1.0(4)
C21 C20 C23 C24 179.3(3)
C20 C23 C24 C25 -0.8(5)
C23 C24 C25 N4 1.6(5)
C23 C24 C25 O2 -177.3(3)
O1 C2 N1 C6 177.4(2)
C3 C2 N1 C6 -0.5(4)
O1 C2 N1 Zn1 -4.6(3)
C3 C2 N1 Zn1 177.47(19)
C5 C6 N1 C2 2.3(4)
C7 C6 N1 C2 -176.0(2)
C5 C6 N1 Zn1 -175.99(19)
C7 C6 N1 Zn1 5.7(3)
C9 C8 N2 C7 0.7(4)
C9 C8 N2 Zn1 -173.7(2)
C11 C7 N2 C8 -1.4(4)
C6 C7 N2 C8 177.6(2)
C11 C7 N2 Zn1 174.0(2)
C6 C7 N2 Zn1 -7.1(3)
C15 C14 N3 C18 -1.4(4)
C15 C14 N3 Zn2 168.3(2)
C17 C18 N3 C14 0.1(4)
C19 C18 N3 C14 -179.0(2)
C17 C18 N3 Zn2 -171.4(2)
C19 C18 N3 Zn2 9.5(3)
O2 C25 N4 C19 178.6(2)
C24 C25 N4 C19 -0.5(4)
O2 C25 N4 Zn2 2.1(4)
C24 C25 N4 Zn2 -177.0(2)
C20 C19 N4 C25 -1.6(4)
C18 C19 N4 C25 178.2(2)
C20 C19 N4 Zn2 175.5(2)
C18 C19 N4 Zn2 -4.7(3)
N1 C2 O1 C1 176.7(2)
C3 C2 O1 C1 -5.4(4)
N4 C25 O2 C26 177.9(3)
C24 C25 O2 C26 -3.1(5)
C2 N1 Zn1 N2 174.7(2)
C6 N1 Zn1 N2 -7.20(16)
C2 N1 Zn1 Cl3 61.5(2)
C6 N1 Zn1 Cl3 -120.45(15)
C2 N1 Zn1 Cl4 -79.8(2)
C6 N1 Zn1 Cl4 98.24(15)
C8 N2 Zn1 N1 -177.6(3)
C7 N2 Zn1 N1 7.67(16)
C8 N2 Zn1 Cl3 -59.5(3)
C7 N2 Zn1 Cl3 125.84(16)
C8 N2 Zn1 Cl4 70.0(3)
C7 N2 Zn1 Cl4 -104.74(16)
C25 N4 Zn2 N3 -175.9(3)
C19 N4 Zn2 N3 7.41(18)
C25 N4 Zn2 Cl1 -59.7(3)
C19 N4 Zn2 Cl1 123.57(17)
C25 N4 Zn2 Cl2 82.5(2)
C19 N4 Zn2 Cl2 -94.14(18)
C14 N3 Zn2 N4 -179.4(3)
C18 N3 Zn2 N4 -9.09(18)
C14 N3 Zn2 Cl1 65.8(3)
C18 N3 Zn2 Cl1 -123.84(17)
C14 N3 Zn2 Cl2 -64.1(3)
C18 N3 Zn2 Cl2 106.21(17)
