#------------------------------------------------------------------------------
#$Date: 2016-02-20 18:35:30 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176787 $
#$URL: svn://www.crystallography.net/cod/cif/2/21/97/2219704.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2219704
loop_
_publ_author_name
'Kurawa, Mukhtar A.'
'Adams, Christopher J.'
'Orpen, A. Guy'
_publ_section_title
;
 A tetranuclear chlorido-bridged manganese(II) cluster with imidazole
 ligands
;
_journal_issue                   10
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1276
_journal_page_last               m1277
_journal_paper_doi               10.1107/S1600536808029139
_journal_volume                  64
_journal_year                    2008
_chemical_formula_iupac          '[Mn4 Cl8 (C3 H4 N2)8], 1.234C2 H5 O'
_chemical_formula_moiety         'C24 H32 Cl8 Mn4 N16, 1.234(C2 H5 O)'
_chemical_formula_sum            'C26.47 H38.17 Cl8 Mn4 N16 O1.23'
_chemical_formula_weight         1103.45
_chemical_name_systematic
;
di-μ₃-chlorido-tetra-μ₂-chlorido-dichloridoocta(imidazole-
κN)tetramanganese(II) ethanol 1.234-solvate
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                99.206(3)
_cell_angle_beta                 105.706(4)
_cell_angle_gamma                96.187(3)
_cell_formula_units_Z            1
_cell_length_a                   8.4763(16)
_cell_length_b                   10.696(2)
_cell_length_c                   12.764(2)
_cell_measurement_reflns_used    3784
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.46
_cell_measurement_theta_min      2.32
_cell_volume                     1085.7(3)
_computing_cell_refinement       'SAINT (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2001)'
_computing_data_reduction        'SAINT (Bruker, 2001)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008b)'
_computing_publication_material  'SHELXTL (Sheldrick, 2008b)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008b)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008b)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.987
_diffrn_measured_fraction_theta_max 0.987
_diffrn_measurement_device_type  'Bruker APEX CCD area-detector'
_diffrn_measurement_method       'phi and omega scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0482
_diffrn_reflns_av_sigmaI/netI    0.0688
_diffrn_reflns_limit_h_max       10
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       13
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            11294
_diffrn_reflns_theta_full        27.52
_diffrn_reflns_theta_max         27.52
_diffrn_reflns_theta_min         1.69
_exptl_absorpt_coefficient_mu    1.679
_exptl_absorpt_correction_T_max  0.850
_exptl_absorpt_correction_T_min  0.815
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 2008a)'
_exptl_crystal_colour            Colourless
_exptl_crystal_density_diffrn    1.688
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       Needle
_exptl_crystal_F_000             554.8
_exptl_crystal_size_max          0.35
_exptl_crystal_size_mid          0.10
_exptl_crystal_size_min          0.10
_refine_diff_density_max         1.172
_refine_diff_density_min         -0.766
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.039
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     265
_refine_ls_number_reflns         4920
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.039
_refine_ls_R_factor_all          0.0946
_refine_ls_R_factor_gt           0.0575
_refine_ls_shift/su_max          0.000
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0550P)²+2.4170P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.1293
_refine_ls_wR_factor_ref         0.1424
_reflns_number_gt                3315
_reflns_number_total             4920
_reflns_threshold_expression     >2sigma(I)
_cod_data_source_file            sg2263.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Triclinic' changed to 'triclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      P-1
_cod_database_code               2219704
_cod_database_fobs_code          2219704
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Mn Mn1 0.11612(8) 0.13627(6) 0.44334(5) 0.01743(18) Uani d . 1 . .
Mn Mn2 0.14342(8) 0.17089(6) 0.75623(5) 0.01930(19) Uani d . 1 . .
Cl Cl1 0.15783(14) -0.04351(11) 0.30310(9) 0.0227(3) Uani d . 1 . .
Cl Cl2 -0.18410(13) 0.00684(10) 0.40027(9) 0.0191(2) Uani d . 1 . .
Cl Cl3 0.05611(13) 0.29485(10) 0.59545(9) 0.0194(2) Uani d . 1 . .
Cl Cl4 0.07690(15) 0.33793(11) 0.88887(9) 0.0258(3) Uani d . 1 . .
N N1 0.0440(5) 0.2621(4) 0.3243(3) 0.0242(9) Uani d . 1 . .
N N2 -0.0167(5) 0.4279(4) 0.2492(3) 0.0319(10) Uani d . 1 . .
H H2A -0.0456 0.5033 0.2418 0.038 Uiso calc R 1 . .
N N3 0.3775(5) 0.2228(3) 0.4924(3) 0.0208(8) Uani d . 1 . .
N N4 0.6483(5) 0.2509(4) 0.5285(4) 0.0313(10) Uani d . 1 . .
H H6A 0.7486 0.2343 0.5312 0.038 Uiso calc R 1 . .
N N5 0.4062(5) 0.2587(4) 0.7973(3) 0.0273(9) Uani d . 1 . .
N N6 0.6744(5) 0.2843(4) 0.8230(4) 0.0339(10) Uani d . 1 . .
H H10A 0.7720 0.2686 0.8176 0.041 Uiso calc R 1 . .
N N7 0.2169(5) 0.0477(4) 0.8769(3) 0.0305(10) Uani d . 1 A .
C C11 0.2455(11) -0.0398(8) 1.0273(6) 0.093(4) Uani d P 0.14(9) A 1
H H11 0.2351 -0.0564 1.0963 0.111 Uiso calc R 1 A 1
N N8' 0.2455(11) -0.0398(8) 1.0273(6) 0.093(4) Uani d P 0.86(9) A 2
C C1 -0.0020(6) 0.3753(5) 0.3382(4) 0.0276(11) Uani d . 1 . .
H H1A -0.0224 0.4151 0.4043 0.033 Uiso calc R 1 . .
C C2 0.0570(9) 0.2431(6) 0.2190(4) 0.0452(16) Uani d . 1 . .
H H4B 0.0877 0.1684 0.1835 0.054 Uiso calc R 1 . .
C C3 0.0209(8) 0.3439(5) 0.1723(5) 0.0419(15) Uani d . 1 . .
H H3B 0.0216 0.3543 0.0999 0.050 Uiso calc R 1 . .
C C4 0.5062(6) 0.1690(5) 0.4816(4) 0.0274(11) Uani d . 1 . .
H H5A 0.4992 0.0830 0.4451 0.033 Uiso calc R 1 . .
C C5 0.6102(6) 0.3629(5) 0.5705(5) 0.0346(13) Uani d . 1 . .
H H7B 0.6861 0.4390 0.6082 0.042 Uiso calc R 1 . .
C C6 0.4431(6) 0.3469(5) 0.5491(4) 0.0280(11) Uani d . 1 . .
H H8A 0.3811 0.4105 0.5697 0.034 Uiso calc R 1 . .
C C7 0.5294(6) 0.2089(5) 0.7709(4) 0.0266(11) Uani d . 1 . .
H H9A 0.5164 0.1296 0.7212 0.032 Uiso calc R 1 . .
C C8 0.6458(8) 0.3888(6) 0.8853(6) 0.0563(19) Uani d . 1 . .
H H11A 0.7259 0.4591 0.9312 0.068 Uiso calc R 1 . .
C C9 0.4800(8) 0.3732(6) 0.8693(6) 0.060(2) Uani d . 1 . .
H H12B 0.4230 0.4321 0.9026 0.072 Uiso calc R 1 . .
C C10 0.1834(11) 0.0537(8) 0.9716(6) 0.071(2) Uani d . 1 . .
H H13A 0.1235 0.1149 0.9989 0.085 Uiso calc R 1 A 1
N N8 0.3293(11) -0.1058(8) 0.9569(8) 0.079(4) Uani d P 0.14(9) A 1
H H8 0.3828 -0.1704 0.9700 0.095 Uiso calc R 1 A 1
C C11' 0.3293(11) -0.1058(8) 0.9569(8) 0.079(4) Uani d P 0.86(9) A 2
C C12 0.3115(11) -0.0513(9) 0.8673(8) 0.090(3) Uani d . 1 . .
H H16A 0.3556 -0.0757 0.8075 0.108 Uiso calc R 1 A 1
O O1 0.5305(15) 0.7035(11) 0.9177(10) 0.111(4) Uani d P 0.617(10) B 1
C C13 0.443(2) 0.6632(16) 0.7342(11) 0.097(6) Uani d P 0.617(10) B 1
H H17A 0.3723 0.7299 0.7260 0.145 Uiso calc PR 0.617(10) B 1
H H18B 0.3765 0.5830 0.7359 0.145 Uiso calc PR 0.617(10) B 1
H H19C 0.4887 0.6497 0.6713 0.145 Uiso calc PR 0.617(10) B 1
C C14 0.548(3) 0.694(2) 0.8143(16) 0.128(8) Uani d P 0.617(10) B 1
H H20A 0.6028 0.7797 0.8117 0.154 Uiso calc PR 0.617(10) B 1
H H21B 0.6291 0.6350 0.8098 0.154 Uiso calc PR 0.617(10) B 1
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Mn Mn 0.3368 0.7283 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
N3 Mn1 N1 . . 92.56(14)
N3 Mn1 Cl1 . . 92.29(10)
N1 Mn1 Cl1 . . 95.12(11)
N3 Mn1 Cl3 . . 92.37(10)
N1 Mn1 Cl3 . . 90.64(11)
Cl1 Mn1 Cl3 . . 172.42(5)
N3 Mn1 Cl2 . . 171.84(10)
N1 Mn1 Cl2 . . 95.45(11)
Cl1 Mn1 Cl2 . . 85.48(4)
Cl3 Mn1 Cl2 . . 89.08(4)
N3 Mn1 Cl2 . 2_556 90.21(10)
N1 Mn1 Cl2 . 2_556 174.19(11)
Cl1 Mn1 Cl2 . 2_556 89.87(4)
Cl3 Mn1 Cl2 . 2_556 84.14(4)
Cl2 Mn1 Cl2 . 2_556 81.95(4)
N7 Mn2 N5 . . 89.13(16)
N7 Mn2 Cl4 . . 94.57(12)
N5 Mn2 Cl4 . . 94.27(11)
N7 Mn2 Cl3 . . 173.40(12)
N5 Mn2 Cl3 . . 91.82(11)
Cl4 Mn2 Cl3 . . 91.88(4)
N7 Mn2 Cl1 . 2_556 88.65(12)
N5 Mn2 Cl1 . 2_556 173.48(11)
Cl4 Mn2 Cl1 . 2_556 92.01(4)
Cl3 Mn2 Cl1 . 2_556 89.69(4)
N7 Mn2 Cl2 . 2_556 89.40(12)
N5 Mn2 Cl2 . 2_556 90.27(11)
Cl4 Mn2 Cl2 . 2_556 174.01(5)
Cl3 Mn2 Cl2 . 2_556 84.06(4)
Cl1 Mn2 Cl2 2_556 2_556 83.58(4)
Mn1 Cl1 Mn2 . 2_556 97.01(4)
Mn1 Cl2 Mn2 . 2_556 93.69(4)
Mn1 Cl2 Mn1 . 2_556 98.05(4)
Mn2 Cl2 Mn1 2_556 2_556 93.71(4)
Mn1 Cl3 Mn2 . . 97.74(4)
C1 N1 C2 . . 104.0(4)
C1 N1 Mn1 . . 130.2(3)
C2 N1 Mn1 . . 125.4(4)
C1 N2 C3 . . 107.1(4)
C1 N2 H2A . . 126.4
C3 N2 H2A . . 126.4
C4 N3 C6 . . 105.2(4)
C4 N3 Mn1 . . 128.8(3)
C6 N3 Mn1 . . 125.9(3)
C4 N4 C5 . . 107.7(4)
C4 N4 H6A . . 126.2
C5 N4 H6A . . 126.2
C7 N5 C9 . . 105.0(4)
C7 N5 Mn2 . . 128.7(3)
C9 N5 Mn2 . . 125.9(4)
C7 N6 C8 . . 108.2(5)
C7 N6 H10A . . 125.9
C8 N6 H10A . . 125.9
C10 N7 C12 . . 107.3(6)
C10 N7 Mn2 . . 126.6(5)
C12 N7 Mn2 . . 126.1(5)
C10 C11 N8 . . 104.1(7)
C10 C11 H11 . . 128.0
N8 C11 H11 . . 128.0
N1 C1 N2 . . 112.2(4)
N1 C1 H1A . . 123.9
N2 C1 H1A . . 123.9
C3 C2 N1 . . 110.8(5)
C3 C2 H4B . . 124.6
N1 C2 H4B . . 124.6
C2 C3 N2 . . 105.9(5)
C2 C3 H3B . . 127.0
N2 C3 H3B . . 127.0
N3 C4 N4 . . 111.4(4)
N3 C4 H5A . . 124.3
N4 C4 H5A . . 124.3
N4 C5 C6 . . 107.0(5)
N4 C5 H7B . . 126.5
C6 C5 H7B . . 126.5
C5 C6 N3 . . 108.8(5)
C5 C6 H8A . . 125.6
N3 C6 H8A . . 125.6
N5 C7 N6 . . 111.2(4)
N5 C7 H9A . . 124.4
N6 C7 H9A . . 124.4
N6 C8 C9 . . 106.0(5)
N6 C8 H11A . . 127.0
C9 C8 H11A . . 127.0
C8 C9 N5 . . 109.6(5)
C8 C9 H12B . . 125.2
N5 C9 H12B . . 125.2
N7 C10 C11 . . 112.0(8)
N7 C10 H13A . . 124.0
C11 C10 H13A . . 124.0
C12 N8 C11 . . 107.9(8)
C12 N8 H8 . . 126.1
C11 N8 H8 . . 126.1
N8 C12 N7 . . 108.7(9)
N8 C12 H16A . . 125.7
N7 C12 H16A . . 125.7
C13 C14 O1 . . 125(2)
C13 C14 H20A . . 106.1
O1 C14 H20A . . 106.1
C13 C14 H21B . . 106.1
O1 C14 H21B . . 106.1
H20A C14 H21B . . 106.3
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
Mn1 N3 . 2.186(4)
Mn1 N1 . 2.196(4)
Mn1 Cl1 . 2.5328(13)
Mn1 Cl3 . 2.5636(13)
Mn1 Cl2 . 2.6332(13)
Mn1 Cl2 2_556 2.6841(13)
Mn2 N7 . 2.192(4)
Mn2 N5 . 2.208(4)
Mn2 Cl4 . 2.4784(14)
Mn2 Cl3 . 2.6033(13)
Mn2 Cl1 2_556 2.6121(14)
Mn2 Cl2 2_556 2.6498(13)
Cl1 Mn2 2_556 2.6121(14)
Cl2 Mn2 2_556 2.6498(13)
Cl2 Mn1 2_556 2.6841(13)
N1 C1 . 1.311(6)
N1 C2 . 1.364(6)
N2 C1 . 1.329(6)
N2 C3 . 1.349(7)
N2 H2A . 0.8800
N3 C4 . 1.316(6)
N3 C6 . 1.382(6)
N4 C4 . 1.338(6)
N4 C5 . 1.341(7)
N4 H6A . 0.8800
N5 C7 . 1.319(6)
N5 C9 . 1.378(7)
N6 C7 . 1.332(6)
N6 C8 . 1.349(7)
N6 H10A . 0.8800
N7 C10 . 1.308(8)
N7 C12 . 1.405(10)
C11 C10 . 1.387(10)
C11 N8 . 1.436(11)
C11 H11 . 0.9500
C1 H1A . 0.9500
C2 C3 . 1.338(8)
C2 H4B . 0.9500
C3 H3B . 0.9500
C4 H5A . 0.9500
C5 C6 . 1.355(7)
C5 H7B . 0.9500
C6 H8A . 0.9500
C7 H9A . 0.9500
C8 C9 . 1.353(8)
C8 H11A . 0.9500
C9 H12B . 0.9500
C10 H13A . 0.9500
N8 C12 . 1.345(10)
N8 H8 . 0.8800
C12 H16A . 0.9500
O1 C14 . 1.356(18)
C13 C14 . 1.13(2)
C13 H17A . 0.9800
C13 H18B . 0.9800
C13 H19C . 0.9800
C14 H20A . 0.9900
C14 H21B . 0.9900
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N8 H8 O1 1_545 0.88 2.09 2.865(15) 146.6
N4 H6A Cl3 1_655 0.88 2.49 3.289(4) 151.6
N6 H10A Cl4 1_655 0.88 2.48 3.247(4) 145.9
N2 H2A Cl4 2_566 0.88 2.55 3.292(4) 142.7
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_4
_geom_torsion
N3 Mn1 Cl1 Mn2 . 2_556 175.98(10)
N1 Mn1 Cl1 Mn2 . 2_556 -91.24(11)
Cl2 Mn1 Cl1 Mn2 . 2_556 3.85(4)
Cl2 Mn1 Cl1 Mn2 2_556 2_556 85.78(4)
N1 Mn1 Cl2 Mn2 . 2_556 90.95(11)
Cl1 Mn1 Cl2 Mn2 . 2_556 -3.77(4)
Cl3 Mn1 Cl2 Mn2 . 2_556 -178.49(4)
Cl2 Mn1 Cl2 Mn2 2_556 2_556 -94.28(4)
N1 Mn1 Cl2 Mn1 . 2_556 -174.77(11)
Cl1 Mn1 Cl2 Mn1 . 2_556 90.51(4)
Cl3 Mn1 Cl2 Mn1 . 2_556 -84.21(4)
Cl2 Mn1 Cl2 Mn1 2_556 2_556 0.0
N3 Mn1 Cl3 Mn2 . . -85.49(10)
N1 Mn1 Cl3 Mn2 . . -178.08(11)
Cl2 Mn1 Cl3 Mn2 . . 86.47(4)
Cl2 Mn1 Cl3 Mn2 2_556 . 4.47(4)
N5 Mn2 Cl3 Mn1 . . 85.55(11)
Cl4 Mn2 Cl3 Mn1 . . 179.89(5)
Cl1 Mn2 Cl3 Mn1 2_556 . -88.11(4)
Cl2 Mn2 Cl3 Mn1 2_556 . -4.53(4)
N3 Mn1 N1 C1 . . -89.6(5)
Cl1 Mn1 N1 C1 . . 177.8(4)
Cl3 Mn1 N1 C1 . . 2.8(4)
Cl2 Mn1 N1 C1 . . 91.9(4)
N3 Mn1 N1 C2 . . 82.0(5)
Cl1 Mn1 N1 C2 . . -10.5(5)
Cl3 Mn1 N1 C2 . . 174.4(5)
Cl2 Mn1 N1 C2 . . -96.5(5)
N1 Mn1 N3 C4 . . -117.3(4)
Cl1 Mn1 N3 C4 . . -22.1(4)
Cl3 Mn1 N3 C4 . . 151.9(4)
Cl2 Mn1 N3 C4 2_556 . 67.8(4)
N1 Mn1 N3 C6 . . 67.3(4)
Cl1 Mn1 N3 C6 . . 162.5(4)
Cl3 Mn1 N3 C6 . . -23.4(4)
Cl2 Mn1 N3 C6 2_556 . -107.6(4)
N7 Mn2 N5 C7 . . 72.7(4)
Cl4 Mn2 N5 C7 . . 167.2(4)
Cl3 Mn2 N5 C7 . . -100.8(4)
Cl2 Mn2 N5 C7 2_556 . -16.7(4)
N7 Mn2 N5 C9 . . -98.3(5)
Cl4 Mn2 N5 C9 . . -3.8(5)
Cl3 Mn2 N5 C9 . . 88.3(5)
Cl2 Mn2 N5 C9 2_556 . 172.3(5)
N5 Mn2 N7 C10 . . 110.9(6)
Cl4 Mn2 N7 C10 . . 16.7(6)
Cl1 Mn2 N7 C10 2_556 . -75.2(6)
Cl2 Mn2 N7 C10 2_556 . -158.8(6)
N5 Mn2 N7 C12 . . -68.0(5)
Cl4 Mn2 N7 C12 . . -162.2(5)
Cl1 Mn2 N7 C12 2_556 . 105.9(5)
Cl2 Mn2 N7 C12 2_556 . 22.3(5)
C2 N1 C1 N2 . . -0.6(6)
Mn1 N1 C1 N2 . . 172.4(3)
C3 N2 C1 N1 . . 0.4(6)
C1 N1 C2 C3 . . 0.6(7)
Mn1 N1 C2 C3 . . -172.9(4)
N1 C2 C3 N2 . . -0.4(8)
C1 N2 C3 C2 . . 0.0(7)
C6 N3 C4 N4 . . 0.4(5)
Mn1 N3 C4 N4 . . -175.7(3)
C5 N4 C4 N3 . . -0.6(6)
C4 N4 C5 C6 . . 0.5(6)
N4 C5 C6 N3 . . -0.2(6)
C4 N3 C6 C5 . . -0.1(5)
Mn1 N3 C6 C5 . . 176.2(3)
C9 N5 C7 N6 . . 0.8(6)
Mn2 N5 C7 N6 . . -171.6(3)
C8 N6 C7 N5 . . -0.7(6)
C7 N6 C8 C9 . . 0.3(8)
N6 C8 C9 N5 . . 0.2(9)
C7 N5 C9 C8 . . -0.6(8)
Mn2 N5 C9 C8 . . 172.1(5)
C12 N7 C10 C11 . . -2.1(9)
Mn2 N7 C10 C11 . . 178.9(5)
N8 C11 C10 N7 . . 1.7(10)
C10 C11 N8 C12 . . -0.6(10)
C11 N8 C12 N7 . . -0.6(9)
C10 N7 C12 N8 . . 1.6(9)
Mn2 N7 C12 N8 . . -179.3(5)
