#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/27/2222767.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2222767
loop_
_publ_author_name
'Niu, Cao-Yuan'
'Ning, Ai-Min'
'Kou, Chun-Hong'
'He, Yong'
'Fen, Zhi-Qiang'
_publ_section_title
;catena-Poly[[[[N'-(4-cyanobenzylidene)nicotinohydrazide]silver(I)]-μ-[N'-4-cyanobenzylidene)nicotinohydrazide]]
 hexafluoridoarsenate]
;
_journal_coeditor_code           JH2084
_journal_issue                   8
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m924
_journal_page_last               m925
_journal_paper_doi               10.1107/S1600536809026907
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Ag (C14 H10 N4 O)2] As F6'
_chemical_formula_moiety         'C28 H20 Ag N8 O2 +, As F6 -'
_chemical_formula_sum            'C28 H20 Ag As F6 N8 O2'
_chemical_formula_weight         797.31
_chemical_name_systematic
;
catena-Poly[[[[N'-(4-
cyanobenzylidene)nicotinohydrazide]silver(I)]-μ-[N'-4-
cyanobenzylidene)nicotinohydrazide]] hexafluoridoarsenate]
;
_space_group_IT_number           15
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-C 2yc'
_symmetry_space_group_name_H-M   'C 1 2/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90.00
_cell_angle_beta                 99.9480(10)
_cell_angle_gamma                90.00
_cell_formula_units_Z            8
_cell_length_a                   22.3785(15)
_cell_length_b                   13.7662(9)
_cell_length_c                   19.8482(14)
_cell_measurement_reflns_used    5377
_cell_measurement_temperature    173(2)
_cell_measurement_theta_max      27.50
_cell_measurement_theta_min      2.08
_cell_volume                     6022.6(7)
_computing_cell_refinement       'SAINT (Siemens, 1996)'
_computing_data_collection       'SMART (Siemens, 1996)'
_computing_data_reduction        'SAINT (Siemens, 1994)'
_computing_molecular_graphics
;
SHELXTL (Sheldrick, 2008) and DIAMOND (Brandenburg, 2005)
;
_computing_publication_material  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXL97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      173(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Bruker APEXII CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.0276
_diffrn_reflns_av_sigmaI/netI    0.0321
_diffrn_reflns_limit_h_max       18
_diffrn_reflns_limit_h_min       -29
_diffrn_reflns_limit_k_max       17
_diffrn_reflns_limit_k_min       -17
_diffrn_reflns_limit_l_max       25
_diffrn_reflns_limit_l_min       -25
_diffrn_reflns_number            19207
_diffrn_reflns_theta_full        27.50
_diffrn_reflns_theta_max         27.50
_diffrn_reflns_theta_min         2.08
_exptl_absorpt_coefficient_mu    1.839
_exptl_absorpt_correction_T_max  0.8233
_exptl_absorpt_correction_T_min  0.4481
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Sheldrick, 1996)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.759
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       prism
_exptl_crystal_F_000             3152
_exptl_crystal_size_max          0.52
_exptl_crystal_size_mid          0.12
_exptl_crystal_size_min          0.11
_refine_diff_density_max         0.626
_refine_diff_density_min         -0.465
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.016
_refine_ls_hydrogen_treatment    mixed
_refine_ls_matrix_type           full
_refine_ls_number_parameters     460
_refine_ls_number_reflns         6896
_refine_ls_number_restraints     96
_refine_ls_restrained_S_all      1.087
_refine_ls_R_factor_all          0.0579
_refine_ls_R_factor_gt           0.0377
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0526P)²+5.7237P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.0942
_refine_ls_wR_factor_ref         0.1048
_reflns_number_gt                5017
_reflns_number_total             6896
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            jh2084.cif
_cod_data_source_block           I
_cod_original_sg_symbol_H-M      C2/c
_cod_database_code               2222767
_cod_database_fobs_code          2222767
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y, -z+1/2'
'x+1/2, y+1/2, z'
'-x+1/2, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y, z-1/2'
'-x+1/2, -y+1/2, -z'
'x+1/2, -y+1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag1 0.183850(14) 0.187891(18) 0.197856(15) 0.05547(11) Uani d . 1 . .
N N1 0.20655(13) 0.32823(17) 0.15519(13) 0.0404(6) Uani d . 1 . .
N N2 0.33194(14) 0.3474(2) 0.02005(14) 0.0471(7) Uani d D 1 . .
N N3 0.37007(13) 0.3480(2) -0.02752(14) 0.0480(7) Uani d . 1 . .
N N4 0.61376(15) 0.2368(3) -0.23488(16) 0.0667(9) Uani d . 1 . .
N N5 0.17227(13) 0.03059(19) 0.20139(13) 0.0435(6) Uani d . 1 . .
N N6 0.26690(13) -0.16253(19) 0.09119(14) 0.0440(6) Uani d D 1 . .
N N7 0.30676(13) -0.2188(2) 0.06251(14) 0.0452(6) Uani d . 1 . .
N N8 0.5343(2) -0.4267(3) -0.1374(2) 0.0990(15) Uani d . 1 . .
O O1 0.29409(11) 0.49652(17) -0.01123(12) 0.0540(6) Uani d . 1 . .
O O2 0.25137(12) -0.28036(16) 0.16611(13) 0.0569(6) Uani d . 1 . .
C C1 0.19143(15) 0.4121(2) 0.18267(16) 0.0426(7) Uani d . 1 . .
H H1 0.1669 0.4098 0.2172 0.051 Uiso calc R 1 . .
C C2 0.21021(17) 0.5008(2) 0.16271(17) 0.0478(8) Uani d . 1 . .
H H2 0.1992 0.5585 0.1838 0.057 Uiso calc R 1 . .
C C3 0.24503(16) 0.5056(2) 0.11201(16) 0.0448(8) Uani d . 1 . .
H H3 0.2582 0.5665 0.0975 0.054 Uiso calc R 1 . .
C C4 0.26041(14) 0.4200(2) 0.08263(15) 0.0365(7) Uani d . 1 . .
C C5 0.24032(15) 0.3332(2) 0.10548(16) 0.0389(7) Uani d . 1 . .
H H5 0.2508 0.2745 0.0852 0.047 Uiso calc R 1 . .
C C6 0.29680(15) 0.4257(2) 0.02645(15) 0.0400(7) Uani d . 1 . .
C C7 0.40093(16) 0.2709(3) -0.02952(17) 0.0513(8) Uani d . 1 . .
H H7 0.3955 0.2179 -0.0005 0.062 Uiso calc R 1 . .
C C8 0.44496(15) 0.2627(3) -0.07618(16) 0.0461(8) Uani d . 1 . .
C C9 0.46234(17) 0.3429(3) -0.11026(18) 0.0499(8) Uani d . 1 . .
H H9 0.4440 0.4042 -0.1055 0.060 Uiso calc R 1 . .
C C10 0.50556(18) 0.3345(3) -0.15064(18) 0.0528(9) Uani d . 1 . .
H H10 0.5178 0.3901 -0.1732 0.063 Uiso calc R 1 . .
C C11 0.53175(15) 0.2446(3) -0.15883(16) 0.0476(8) Uani d . 1 . .
C C12 0.51410(18) 0.1635(3) -0.1266(2) 0.0594(10) Uani d . 1 . .
H H12 0.5312 0.1018 -0.1330 0.071 Uiso calc R 1 . .
C C13 0.47112(18) 0.1734(3) -0.0847(2) 0.0588(10) Uani d . 1 . .
H H13 0.4594 0.1181 -0.0615 0.071 Uiso calc R 1 . .
C C14 0.57804(17) 0.2385(3) -0.20097(18) 0.0527(9) Uani d . 1 . .
C C15 0.13563(17) -0.0091(2) 0.24079(17) 0.0491(8) Uani d . 1 . .
H H15 0.1117 0.0327 0.2633 0.059 Uiso calc R 1 . .
C C16 0.13129(18) -0.1077(3) 0.24988(19) 0.0538(9) Uani d . 1 . .
H H16 0.1051 -0.1333 0.2784 0.065 Uiso calc R 1 . .
C C17 0.16547(17) -0.1682(2) 0.21708(18) 0.0473(8) Uani d . 1 . .
H H17 0.1633 -0.2366 0.2228 0.057 Uiso calc R 1 . .
C C18 0.20314(14) -0.1297(2) 0.17564(15) 0.0370(7) Uani d . 1 . .
C C19 0.20477(15) -0.0293(2) 0.16906(15) 0.0397(7) Uani d . 1 . .
H H19 0.2301 -0.0021 0.1402 0.048 Uiso calc R 1 . .
C C20 0.24264(15) -0.1984(2) 0.14389(16) 0.0398(7) Uani d . 1 . .
C C21 0.33262(17) -0.1765(2) 0.01809(18) 0.0488(8) Uani d . 1 . .
H H21 0.3241 -0.1102 0.0072 0.059 Uiso calc R 1 . .
C C22 0.37552(16) -0.2300(3) -0.01634(17) 0.0473(8) Uani d . 1 . .
C C23 0.38639(17) -0.3282(3) -0.00388(19) 0.0507(8) Uani d . 1 . .
H H23 0.3654 -0.3614 0.0269 0.061 Uiso calc R 1 . .
C C24 0.42693(18) -0.3782(3) -0.03525(19) 0.0552(9) Uani d . 1 . .
H H24 0.4341 -0.4453 -0.0260 0.066 Uiso calc R 1 . .
C C25 0.45761(17) -0.3300(3) -0.0808(2) 0.0556(9) Uani d . 1 . .
C C26 0.44726(19) -0.2317(3) -0.0942(2) 0.0625(10) Uani d . 1 . .
H H26 0.4682 -0.1987 -0.1251 0.075 Uiso calc R 1 . .
C C27 0.40629(19) -0.1822(3) -0.0622(2) 0.0587(10) Uani d . 1 . .
H H27 0.3990 -0.1152 -0.0715 0.070 Uiso calc R 1 . .
C C28 0.5002(2) -0.3825(3) -0.1133(2) 0.0700(12) Uani d . 1 . .
As As1 0.377276(19) 0.09939(3) 0.14799(2) 0.05697(13) Uani d D 1 . .
F F5 0.38907(15) 0.21973(18) 0.13618(16) 0.1020(9) Uani d DU 1 A .
F F6 0.36110(16) -0.01902(19) 0.1542(2) 0.1292(13) Uani d DU 1 A .
H H28 0.3375(17) 0.306(2) 0.0537(14) 0.056(11) Uiso d D 1 . .
H H29 0.2555(17) -0.1086(19) 0.0702(18) 0.061(12) Uiso d D 1 . .
F F1 0.3247(3) 0.1084(5) 0.0751(3) 0.142(3) Uani d PDU 0.732(9) A 1
F F2 0.3208(3) 0.1242(3) 0.1925(3) 0.111(2) Uani d PDU 0.732(9) A 1
F F3 0.4252(4) 0.0990(7) 0.2174(5) 0.203(4) Uani d PDU 0.732(9) A 1
F F4 0.4308(3) 0.0776(4) 0.1007(5) 0.135(3) Uani d PDU 0.732(9) A 1
F F1' 0.3034(4) 0.1259(9) 0.1417(10) 0.111(5) Uani d PDU 0.268(9) A 2
F F2' 0.3871(8) 0.1196(8) 0.2320(4) 0.095(5) Uani d PDU 0.268(9) A 2
F F3' 0.4516(4) 0.0732(7) 0.1563(8) 0.084(4) Uani d PDU 0.268(9) A 2
F F4' 0.3710(9) 0.0775(9) 0.0641(5) 0.116(5) Uani d PDU 0.268(9) A 2
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N5 Ag1 N1 . . 156.68(9) y
N5 Ag1 N4 . 8_456 108.09(11) y
N1 Ag1 N4 . 8_456 92.87(11) y
C5 N1 C1 . . 117.8(3) ?
C5 N1 Ag1 . . 121.53(19) ?
C1 N1 Ag1 . . 120.4(2) ?
C6 N2 N3 . . 119.9(3) ?
C6 N2 H28 . . 117(2) ?
N3 N2 H28 . . 120(3) ?
C7 N3 N2 . . 114.9(3) ?
C14 N4 Ag1 . 8 153.9(3) ?
C19 N5 C15 . . 117.8(3) ?
C19 N5 Ag1 . . 121.3(2) ?
C15 N5 Ag1 . . 120.7(2) ?
C20 N6 N7 . . 119.3(3) ?
C20 N6 H29 . . 124(3) ?
N7 N6 H29 . . 116(3) ?
C21 N7 N6 . . 115.7(3) ?
N1 C1 C2 . . 122.4(3) ?
N1 C1 H1 . . 118.8 ?
C2 C1 H1 . . 118.8 ?
C1 C2 C3 . . 119.6(3) ?
C1 C2 H2 . . 120.2 ?
C3 C2 H2 . . 120.2 ?
C2 C3 C4 . . 118.7(3) ?
C2 C3 H3 . . 120.7 ?
C4 C3 H3 . . 120.7 ?
C5 C4 C3 . . 118.7(3) ?
C5 C4 C6 . . 122.8(3) ?
C3 C4 C6 . . 118.5(3) ?
N1 C5 C4 . . 122.8(3) ?
N1 C5 H5 . . 118.6 ?
C4 C5 H5 . . 118.6 ?
O1 C6 N2 . . 123.1(3) ?
O1 C6 C4 . . 121.5(3) ?
N2 C6 C4 . . 115.4(3) ?
N3 C7 C8 . . 120.7(3) ?
N3 C7 H7 . . 119.6 ?
C8 C7 H7 . . 119.6 ?
C13 C8 C9 . . 119.2(3) ?
C13 C8 C7 . . 119.3(3) ?
C9 C8 C7 . . 121.5(3) ?
C10 C9 C8 . . 120.5(3) ?
C10 C9 H9 . . 119.8 ?
C8 C9 H9 . . 119.8 ?
C9 C10 C11 . . 120.0(3) ?
C9 C10 H10 . . 120.0 ?
C11 C10 H10 . . 120.0 ?
C12 C11 C10 . . 120.4(3) ?
C12 C11 C14 . . 121.0(3) ?
C10 C11 C14 . . 118.6(3) ?
C11 C12 C13 . . 119.0(3) ?
C11 C12 H12 . . 120.5 ?
C13 C12 H12 . . 120.5 ?
C12 C13 C8 . . 120.9(3) ?
C12 C13 H13 . . 119.5 ?
C8 C13 H13 . . 119.5 ?
N4 C14 C11 . . 177.6(4) ?
N5 C15 C16 . . 122.9(3) ?
N5 C15 H15 . . 118.6 ?
C16 C15 H15 . . 118.6 ?
C17 C16 C15 . . 118.7(3) ?
C17 C16 H16 . . 120.6 ?
C15 C16 H16 . . 120.6 ?
C16 C17 C18 . . 119.8(3) ?
C16 C17 H17 . . 120.1 ?
C18 C17 H17 . . 120.1 ?
C17 C18 C19 . . 117.8(3) ?
C17 C18 C20 . . 118.0(3) ?
C19 C18 C20 . . 124.0(3) ?
N5 C19 C18 . . 123.0(3) ?
N5 C19 H19 . . 118.5 ?
C18 C19 H19 . . 118.5 ?
O2 C20 N6 . . 124.0(3) ?
O2 C20 C18 . . 120.1(3) ?
N6 C20 C18 . . 115.9(3) ?
N7 C21 C22 . . 120.3(3) ?
N7 C21 H21 . . 119.8 ?
C22 C21 H21 . . 119.8 ?
C23 C22 C27 . . 118.9(3) ?
C23 C22 C21 . . 120.9(3) ?
C27 C22 C21 . . 120.2(3) ?
C24 C23 C22 . . 121.2(3) ?
C24 C23 H23 . . 119.4 ?
C22 C23 H23 . . 119.4 ?
C23 C24 C25 . . 119.6(4) ?
C23 C24 H24 . . 120.2 ?
C25 C24 H24 . . 120.2 ?
C26 C25 C24 . . 120.2(3) ?
C26 C25 C28 . . 120.3(4) ?
C24 C25 C28 . . 119.5(4) ?
C27 C26 C25 . . 119.6(4) ?
C27 C26 H26 . . 120.2 ?
C25 C26 H26 . . 120.2 ?
C26 C27 C22 . . 120.6(4) ?
C26 C27 H27 . . 119.7 ?
C22 C27 H27 . . 119.7 ?
N8 C28 C25 . . 177.5(5) ?
F3 As1 F4 . . 92.5(4) ?
F2' As1 F4 . . 127.4(6) ?
F3 As1 F4' . . 142.0(7) ?
F2' As1 F4' . . 177.2(7) ?
F4 As1 F4' . . 49.8(6) ?
F3 As1 F1' . . 125.0(7) ?
F2' As1 F1' . . 89.8(6) ?
F4 As1 F1' . . 142.2(6) ?
F4' As1 F1' . . 93.0(7) ?
F3 As1 F6 . . 93.1(3) ?
F2' As1 F6 . . 94.7(4) ?
F4 As1 F6 . . 92.9(2) ?
F4' As1 F6 . . 85.2(4) ?
F1' As1 F6 . . 89.7(4) ?
F3 As1 F3' . . 53.7(5) ?
F2' As1 F3' . . 88.9(6) ?
F4' As1 F3' . . 88.3(6) ?
F1' As1 F3' . . 178.7(7) ?
F6 As1 F3' . . 90.4(4) ?
F3 As1 F2 . . 90.1(4) ?
F2' As1 F2 . . 55.1(5) ?
F4 As1 F2 . . 177.1(3) ?
F4' As1 F2 . . 127.7(6) ?
F6 As1 F2 . . 88.16(19) ?
F3' As1 F2 . . 143.6(5) ?
F3 As1 F5 . . 91.5(3) ?
F2' As1 F5 . . 88.8(4) ?
F4 As1 F5 . . 87.4(2) ?
F4' As1 F5 . . 91.5(4) ?
F1' As1 F5 . . 87.3(4) ?
F6 As1 F5 . . 175.38(19) ?
F3' As1 F5 . . 92.8(4) ?
F2 As1 F5 . . 91.32(19) ?
F3 As1 F1 . . 175.8(4) ?
F2' As1 F1 . . 142.2(5) ?
F4 As1 F1 . . 89.6(3) ?
F1' As1 F1 . . 52.7(6) ?
F6 As1 F1 . . 90.4(3) ?
F3' As1 F1 . . 128.6(5) ?
F2 As1 F1 . . 87.7(3) ?
F5 As1 F1 . . 85.0(2) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag1 N5 . 2.183(3) y
Ag1 N1 . 2.204(2) y
Ag1 N4 8_456 2.458(3) y
N1 C5 . 1.344(4) ?
N1 C1 . 1.345(4) ?
N2 C6 . 1.353(4) ?
N2 N3 . 1.378(3) ?
N2 H28 . 0.868(19) ?
N3 C7 . 1.271(5) ?
N4 C14 . 1.131(4) ?
N4 Ag1 8 2.458(3) ?
N5 C19 . 1.335(4) ?
N5 C15 . 1.343(4) ?
N6 C20 . 1.353(4) ?
N6 N7 . 1.376(4) ?
N6 H29 . 0.868(19) ?
N7 C21 . 1.275(4) ?
N8 C28 . 1.144(5) ?
O1 C6 . 1.224(4) ?
O2 C20 . 1.214(4) ?
C1 C2 . 1.372(4) ?
C1 H1 . 0.9500 ?
C2 C3 . 1.377(4) ?
C2 H2 . 0.9500 ?
C3 C4 . 1.384(4) ?
C3 H3 . 0.9500 ?
C4 C5 . 1.381(4) ?
C4 C6 . 1.492(4) ?
C5 H5 . 0.9500 ?
C7 C8 . 1.468(4) ?
C7 H7 . 0.9500 ?
C8 C13 . 1.384(5) ?
C8 C9 . 1.386(5) ?
C9 C10 . 1.363(5) ?
C9 H9 . 0.9500 ?
C10 C11 . 1.392(5) ?
C10 H10 . 0.9500 ?
C11 C12 . 1.378(5) ?
C11 C14 . 1.442(4) ?
C12 C13 . 1.382(5) ?
C12 H12 . 0.9500 ?
C13 H13 . 0.9500 ?
C15 C16 . 1.374(5) ?
C15 H15 . 0.9500 ?
C16 C17 . 1.370(5) ?
C16 H16 . 0.9500 ?
C17 C18 . 1.382(4) ?
C17 H17 . 0.9500 ?
C18 C19 . 1.389(4) ?
C18 C20 . 1.506(4) ?
C19 H19 . 0.9500 ?
C21 C22 . 1.468(5) ?
C21 H21 . 0.9500 ?
C22 C23 . 1.389(5) ?
C22 C27 . 1.397(5) ?
C23 C24 . 1.371(5) ?
C23 H23 . 0.9500 ?
C24 C25 . 1.394(5) ?
C24 H24 . 0.9500 ?
C25 C26 . 1.391(6) ?
C25 C28 . 1.436(5) ?
C26 C27 . 1.381(5) ?
C26 H26 . 0.9500 ?
C27 H27 . 0.9500 ?
As1 F3 . 1.593(6) ?
As1 F2' . 1.667(8) ?
As1 F4 . 1.671(4) ?
As1 F4' . 1.674(9) ?
As1 F1' . 1.675(10) ?
As1 F6 . 1.679(3) ?
As1 F3' . 1.682(8) ?
As1 F2 . 1.696(4) ?
As1 F5 . 1.700(2) ?
As1 F1 . 1.704(5) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N6 H29 O1 7 0.868(19) 2.13(2) 2.976(4) 165(4)
N2 H28 F5 . 0.868(19) 2.19(2) 3.003(4) 157(3)
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
N5 Ag1 N1 C5 . . . . -17.9(4) ?
N4 Ag1 N1 C5 8_456 . . . -172.2(3) ?
N5 Ag1 N1 C1 . . . . 168.2(3) ?
N4 Ag1 N1 C1 8_456 . . . 13.8(3) ?
C6 N2 N3 C7 . . . . -179.8(3) ?
N1 Ag1 N5 C19 . . . . 27.0(4) ?
N4 Ag1 N5 C19 8_456 . . . 180.0(2) ?
N1 Ag1 N5 C15 . . . . -158.4(3) ?
N4 Ag1 N5 C15 8_456 . . . -5.4(3) ?
C20 N6 N7 C21 . . . . -172.9(3) ?
C5 N1 C1 C2 . . . . -1.3(5) ?
Ag1 N1 C1 C2 . . . . 172.9(3) ?
N1 C1 C2 C3 . . . . 1.1(6) ?
C1 C2 C3 C4 . . . . -0.3(5) ?
C2 C3 C4 C5 . . . . -0.1(5) ?
C2 C3 C4 C6 . . . . 178.4(3) ?
C1 N1 C5 C4 . . . . 0.9(5) ?
Ag1 N1 C5 C4 . . . . -173.2(2) ?
C3 C4 C5 N1 . . . . -0.2(5) ?
C6 C4 C5 N1 . . . . -178.7(3) ?
N3 N2 C6 O1 . . . . 4.6(5) ?
N3 N2 C6 C4 . . . . -176.0(3) ?
C5 C4 C6 O1 . . . . 150.3(3) ?
C3 C4 C6 O1 . . . . -28.2(5) ?
C5 C4 C6 N2 . . . . -29.0(5) ?
C3 C4 C6 N2 . . . . 152.4(3) ?
N2 N3 C7 C8 . . . . -177.9(3) ?
N3 C7 C8 C13 . . . . -170.4(4) ?
N3 C7 C8 C9 . . . . 11.7(6) ?
C13 C8 C9 C10 . . . . -1.3(6) ?
C7 C8 C9 C10 . . . . 176.7(4) ?
C8 C9 C10 C11 . . . . 1.2(6) ?
C9 C10 C11 C12 . . . . 0.3(6) ?
C9 C10 C11 C14 . . . . -179.0(4) ?
C10 C11 C12 C13 . . . . -1.6(6) ?
C14 C11 C12 C13 . . . . 177.7(4) ?
C11 C12 C13 C8 . . . . 1.4(6) ?
C9 C8 C13 C12 . . . . 0.0(6) ?
C7 C8 C13 C12 . . . . -178.0(4) ?
C19 N5 C15 C16 . . . . 1.2(5) ?
Ag1 N5 C15 C16 . . . . -173.6(3) ?
N5 C15 C16 C17 . . . . -0.4(6) ?
C15 C16 C17 C18 . . . . -0.3(6) ?
C16 C17 C18 C19 . . . . 0.1(5) ?
C16 C17 C18 C20 . . . . 176.5(3) ?
C15 N5 C19 C18 . . . . -1.4(5) ?
Ag1 N5 C19 C18 . . . . 173.4(2) ?
C17 C18 C19 N5 . . . . 0.7(5) ?
C20 C18 C19 N5 . . . . -175.4(3) ?
N7 N6 C20 O2 . . . . -3.8(5) ?
N7 N6 C20 C18 . . . . 175.7(3) ?
C17 C18 C20 O2 . . . . -16.5(5) ?
C19 C18 C20 O2 . . . . 159.6(3) ?
C17 C18 C20 N6 . . . . 164.0(3) ?
C19 C18 C20 N6 . . . . -19.9(5) ?
N6 N7 C21 C22 . . . . -179.3(3) ?
N7 C21 C22 C23 . . . . 3.3(5) ?
N7 C21 C22 C27 . . . . -176.5(3) ?
C27 C22 C23 C24 . . . . 0.6(6) ?
C21 C22 C23 C24 . . . . -179.2(3) ?
C22 C23 C24 C25 . . . . -0.4(6) ?
C23 C24 C25 C26 . . . . 0.2(6) ?
C23 C24 C25 C28 . . . . 179.8(4) ?
C24 C25 C26 C27 . . . . -0.2(6) ?
C28 C25 C26 C27 . . . . -179.7(4) ?
C25 C26 C27 C22 . . . . 0.4(6) ?
C23 C22 C27 C26 . . . . -0.6(6) ?
C21 C22 C27 C26 . . . . 179.2(4) ?
