#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/39/2223976.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2223976
loop_
_publ_author_name
'Olaru, Marian'
'Roşca, Sorin'
'Raţ, Ciprian I.'
'Silvestru, Cristian'
_publ_section_title
;
 Chloridobis{2-[(dimethylamino)methyl]phenyl}antimony(III)
;
_journal_coeditor_code           PV2214
_journal_issue                   11
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1383
_journal_page_last               m1384
_journal_paper_doi               10.1107/S1600536809041890
_journal_volume                  65
_journal_year                    2009
_chemical_formula_iupac          '[Sb (C9 H12 N)2 Cl]'
_chemical_formula_moiety         'C18 H24 Cl1 N2 Sb'
_chemical_formula_sum            'C18 H24 Cl N2 Sb'
_chemical_formula_weight         425.60
_chemical_name_systematic
;
Chloridobis{2-[(dimethylamino)methyl]phenyl}antimony(III)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           'WinGX routine CIF_UPDATE'
_cell_angle_alpha                98.073(13)
_cell_angle_beta                 103.611(13)
_cell_angle_gamma                116.819(12)
_cell_formula_units_Z            2
_cell_length_a                   9.289(7)
_cell_length_b                   9.367(7)
_cell_length_c                   12.888(10)
_cell_measurement_reflns_used    3906
_cell_measurement_temperature    297(2)
_cell_measurement_theta_max      24.4
_cell_measurement_theta_min      2.5
_cell_volume                     932.5(12)
_computing_cell_refinement       'SAINT-Plus (Bruker, 2001)'
_computing_data_collection       'SMART (Bruker, 2000)'
_computing_data_reduction        'SAINT-Plus (Bruker, 2001)'
_computing_molecular_graphics    'DIAMOND (Brandenburg, 2009)'
_computing_publication_material  'publCIF (Westrip, 2009)'
_computing_structure_refinement
'SHELXL97 (Sheldrick, 2008) and WinGX (Farrugia, 1999)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      297(2)
_diffrn_measured_fraction_theta_full 0.995
_diffrn_measured_fraction_theta_max 0.995
_diffrn_measurement_device_type  'Bruker SMART APEX CCD area-detector'
_diffrn_measurement_method       'φ and ω'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.027
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       11
_diffrn_reflns_limit_k_min       -11
_diffrn_reflns_limit_l_max       16
_diffrn_reflns_limit_l_min       -16
_diffrn_reflns_number            10065
_diffrn_reflns_theta_full        26.37
_diffrn_reflns_theta_max         26.4
_diffrn_reflns_theta_min         2.54
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    1.62
_exptl_absorpt_correction_T_max  0.669
_exptl_absorpt_correction_T_min  0.617
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2000)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.516
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       blocks
_exptl_crystal_F_000             428
_exptl_crystal_size_max          0.33
_exptl_crystal_size_mid          0.31
_exptl_crystal_size_min          0.27
_refine_diff_density_max         0.78
_refine_diff_density_min         -0.45
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.13
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     263
_refine_ls_number_reflns         3801
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.13
_refine_ls_R_factor_all          0.039
_refine_ls_R_factor_gt           0.035
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0350P)²+0.2481P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_ref         0.078
_reflns_number_gt                3530
_reflns_number_total             3801
_reflns_threshold_expression     >2σ(I)
_cod_data_source_file            pv2214.cif
_cod_data_source_block           I
_cod_original_cell_volume        932.6(13)
_cod_database_code               2223976
_cod_database_fobs_code          2223976
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
C C1 0.7468(8) 0.4324(9) 0.6493(5) 0.047(6) Uani d PG 0.501(6) A 1
C C2 0.6306(6) 0.2626(10) 0.6213(6) 0.048(2) Uani d PG 0.501(6) A 1
C C3 0.6832(9) 0.1477(7) 0.5996(7) 0.065(3) Uani d PG 0.501(6) A 1
H H3 0.6055 0.034 0.5808 0.078 Uiso calc PR 0.501(6) A 1
C C4 0.8521(10) 0.2026(8) 0.6058(7) 0.065(4) Uani d PG 0.501(6) A 1
H H4 0.8873 0.1257 0.5913 0.078 Uiso calc PR 0.501(6) A 1
C C5 0.9683(8) 0.3724(8) 0.6339(7) 0.067(2) Uani d PG 0.501(6) A 1
H H5 1.0813 0.4091 0.6381 0.081 Uiso calc PR 0.501(6) A 1
C C6 0.9156(8) 0.4873(6) 0.6556(6) 0.058(2) Uani d PG 0.501(6) A 1
H H6 0.9934 0.601 0.6744 0.069 Uiso calc PR 0.501(6) A 1
C C7 0.4477(9) 0.2067(9) 0.6097(6) 0.055(2) Uani d P 0.501(6) A 1
H H7A 0.3864 0.2057 0.5372 0.065 Uiso calc PR 0.501(6) A 1
H H7B 0.3913 0.0952 0.6181 0.065 Uiso calc PR 0.501(6) A 1
C C8 0.2676(10) 0.3037(11) 0.6608(8) 0.074(3) Uani d P 0.501(6) A 1
H H8A 0.2416 0.3183 0.5877 0.111 Uiso calc PR 0.501(6) A 1
H H8B 0.2619 0.3844 0.712 0.111 Uiso calc PR 0.501(6) A 1
H H8C 0.1859 0.1933 0.6589 0.111 Uiso calc PR 0.501(6) A 1
C C9 0.4842(13) 0.2998(11) 0.8043(7) 0.069(3) Uani d P 0.501(6) A 1
H H9A 0.391 0.1953 0.8018 0.104 Uiso calc PR 0.501(6) A 1
H H9B 0.495 0.3882 0.859 0.104 Uiso calc PR 0.501(6) A 1
H H9C 0.5886 0.2963 0.8238 0.104 Uiso calc PR 0.501(6) A 1
C C1A 0.7522(8) 0.4295(8) 0.6416(5) 0.042(5) Uani d PG 0.499(6) A 2
C C2A 0.6821(9) 0.2798(10) 0.6685(5) 0.048(2) Uani d PG 0.499(6) A 2
C C3A 0.7282(10) 0.1620(8) 0.6387(7) 0.056(3) Uani d PG 0.499(6) A 2
H H3A 0.6813 0.0618 0.6568 0.067 Uiso calc PR 0.499(6) A 2
C C4A 0.8444(10) 0.1940(7) 0.5819(7) 0.068(4) Uani d PG 0.499(6) A 2
H H4A 0.8752 0.1152 0.562 0.081 Uiso calc PR 0.499(6) A 2
C C5A 0.9145(7) 0.3438(8) 0.5549(6) 0.060(2) Uani d PG 0.499(6) A 2
H H5A 0.9922 0.3652 0.5169 0.072 Uiso calc PR 0.499(6) A 2
C C6A 0.8684(7) 0.4615(6) 0.5847(6) 0.0510(19) Uani d PG 0.499(6) A 2
H H6A 0.9153 0.5617 0.5667 0.061 Uiso calc PR 0.499(6) A 2
C C7A 0.5589(10) 0.2447(9) 0.7299(7) 0.057(2) Uani d P 0.499(6) A 2
H H7A1 0.6209 0.2862 0.8093 0.068 Uiso calc PR 0.499(6) A 2
H H7A2 0.4835 0.1251 0.7115 0.068 Uiso calc PR 0.499(6) A 2
C C8A 0.3298(10) 0.2411(10) 0.5935(7) 0.064(2) Uani d P 0.499(6) A 2
H H8A1 0.2438 0.1354 0.5954 0.096 Uiso calc PR 0.499(6) A 2
H H8A2 0.3839 0.2235 0.5421 0.096 Uiso calc PR 0.499(6) A 2
H H8A3 0.2773 0.3044 0.5702 0.096 Uiso calc PR 0.499(6) A 2
C C9A 0.3800(12) 0.3423(11) 0.7886(7) 0.070(3) Uani d P 0.499(6) A 2
H H9A1 0.3175 0.3997 0.7735 0.105 Uiso calc PR 0.499(6) A 2
H H9A2 0.4715 0.4034 0.8587 0.105 Uiso calc PR 0.499(6) A 2
H H9A3 0.3043 0.2327 0.7915 0.105 Uiso calc PR 0.499(6) A 2
C C10 0.7798(4) 0.6853(4) 0.8586(3) 0.0469(8) Uani d . 1 . .
C C11 0.7516(5) 0.7975(4) 0.9215(3) 0.0555(9) Uani d . 1 . .
C C12 0.8347(6) 0.8557(5) 1.0355(3) 0.0677(11) Uani d . 1 . .
H H12 0.818 0.9321 1.078 0.081 Uiso calc R 1 . .
C C13 0.9393(6) 0.8043(6) 1.0865(3) 0.0768(14) Uani d . 1 . .
H H13 0.9908 0.8421 1.1635 0.092 Uiso calc R 1 . .
C C14 0.9696(5) 0.6964(6) 1.0246(4) 0.0748(13) Uani d . 1 . .
H H14 1.0441 0.6632 1.0595 0.09 Uiso calc R 1 . .
C C15 0.8894(5) 0.6365(5) 0.9100(3) 0.0606(10) Uani d . 1 . .
H H15 0.9101 0.5631 0.8681 0.073 Uiso calc R 1 . .
C C16 0.6406(6) 0.8609(5) 0.8671(4) 0.0683(11) Uani d . 1 . .
H H16A 0.6536 0.9523 0.9217 0.082 Uiso calc R 1 . .
H H16B 0.6789 0.9041 0.8086 0.082 Uiso calc R 1 . .
C C17 0.3876(7) 0.6916(8) 0.9063(5) 0.1067(18) Uani d . 1 . .
H H17A 0.4441 0.6456 0.9508 0.16 Uiso calc R 1 . .
H H17B 0.2676 0.6111 0.8728 0.16 Uiso calc R 1 . .
H H17C 0.4023 0.7903 0.9526 0.16 Uiso calc R 1 . .
C C18 0.3679(9) 0.7882(9) 0.7445(6) 0.133(3) Uani d . 1 . .
H H18A 0.3749 0.8867 0.785 0.199 Uiso calc R 1 . .
H H18B 0.25 0.7014 0.7116 0.199 Uiso calc R 1 . .
H H18C 0.417 0.8127 0.687 0.199 Uiso calc R 1 . .
N N1 0.4519(4) 0.3284(4) 0.6993(2) 0.0517(7) Uani d . 1 . .
N N2 0.4613(5) 0.7338(5) 0.8199(3) 0.0714(9) Uani d . 1 . .
Sb Sb1 0.65485(3) 0.59640(3) 0.680735(17) 0.04391(10) Uani d . 1 A .
Cl Cl1 0.92046(15) 0.84267(12) 0.66663(9) 0.0677(3) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0 0 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Sb Sb -0.5866 1.5461 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C2 C1 C6 . . 120 ?
C2 C1 Sb1 . . 117.2(4) ?
C6 C1 Sb1 . . 122.8(4) ?
C3 C2 C1 . . 120 ?
C3 C2 C7 . . 121.1(6) ?
C1 C2 C7 . . 118.9(6) ?
C4 C3 C2 . . 120 ?
C4 C3 H3 . . 120 ?
C2 C3 H3 . . 120 ?
C5 C4 C3 . . 120 ?
C5 C4 H4 . . 120 ?
C3 C4 H4 . . 120 ?
C6 C5 C4 . . 120 ?
C6 C5 H5 . . 120 ?
C4 C5 H5 . . 120 ?
C5 C6 C1 . . 120 ?
C5 C6 H6 . . 120 ?
C1 C6 H6 . . 120 ?
N1 C7 C2 . . 106.2(5) ?
N1 C7 H7A . . 110.5 ?
C2 C7 H7A . . 110.5 ?
N1 C7 H7B . . 110.5 ?
C2 C7 H7B . . 110.5 ?
H7A C7 H7B . . 108.7 ?
N1 C8 H8A . . 109.5 ?
N1 C8 H8B . . 109.5 ?
N1 C8 H8C . . 109.5 ?
N1 C9 H9A . . 109.5 ?
N1 C9 H9B . . 109.5 ?
N1 C9 H9C . . 109.5 ?
C2A C1A C6A . . 120 ?
C2A C1A Sb1 . . 116.7(4) ?
C6A C1A Sb1 . . 123.1(4) ?
C3A C2A C1A . . 120 ?
C3A C2A C7A . . 119.5(6) ?
C1A C2A C7A . . 120.5(6) ?
C2A C3A C4A . . 120 ?
C2A C3A H3A . . 120 ?
C4A C3A H3A . . 120 ?
C5A C4A C3A . . 120 ?
C5A C4A H4A . . 120 ?
C3A C4A H4A . . 120 ?
C6A C5A C4A . . 120 ?
C6A C5A H5A . . 120 ?
C4A C5A H5A . . 120 ?
C5A C6A C1A . . 120 ?
C5A C6A H6A . . 120 ?
C1A C6A H6A . . 120 ?
C2A C7A N1 . . 110.5(5) ?
C2A C7A H7A1 . . 109.5 ?
N1 C7A H7A1 . . 109.5 ?
C2A C7A H7A2 . . 109.5 ?
N1 C7A H7A2 . . 109.5 ?
H7A1 C7A H7A2 . . 108.1 ?
N1 C8A H8A1 . . 109.5 ?
N1 C8A H8A2 . . 109.5 ?
H8A1 C8A H8A2 . . 109.5 ?
N1 C8A H8A3 . . 109.5 ?
H8A1 C8A H8A3 . . 109.5 ?
H8A2 C8A H8A3 . . 109.5 ?
N1 C9A H9A1 . . 109.5 ?
N1 C9A H9A2 . . 109.5 ?
H9A1 C9A H9A2 . . 109.5 ?
N1 C9A H9A3 . . 109.5 ?
H9A1 C9A H9A3 . . 109.5 ?
H9A2 C9A H9A3 . . 109.5 ?
C15 C10 C11 . . 119.7(3) ?
C15 C10 Sb1 . . 121.0(3) ?
C11 C10 Sb1 . . 119.3(3) ?
C12 C11 C10 . . 118.7(4) ?
C12 C11 C16 . . 120.2(4) ?
C10 C11 C16 . . 121.0(3) ?
C13 C12 C11 . . 121.5(4) ?
C13 C12 H12 . . 119.2 ?
C11 C12 H12 . . 119.2 ?
C12 C13 C14 . . 119.8(4) ?
C12 C13 H13 . . 120.1 ?
C14 C13 H13 . . 120.1 ?
C13 C14 C15 . . 120.2(4) ?
C13 C14 H14 . . 119.9 ?
C15 C14 H14 . . 119.9 ?
C10 C15 C14 . . 120.0(4) ?
C10 C15 H15 . . 120 ?
C14 C15 H15 . . 120 ?
N2 C16 C11 . . 112.9(3) ?
N2 C16 H16A . . 109 ?
C11 C16 H16A . . 109 ?
N2 C16 H16B . . 109 ?
C11 C16 H16B . . 109 ?
H16A C16 H16B . . 107.8 ?
N2 C17 H17A . . 109.5 ?
N2 C17 H17B . . 109.5 ?
H17A C17 H17B . . 109.5 ?
N2 C17 H17C . . 109.5 ?
H17A C17 H17C . . 109.5 ?
H17B C17 H17C . . 109.5 ?
N2 C18 H18A . . 109.5 ?
N2 C18 H18B . . 109.5 ?
H18A C18 H18B . . 109.5 ?
N2 C18 H18C . . 109.5 ?
H18A C18 H18C . . 109.5 ?
H18B C18 H18C . . 109.5 ?
C8A N1 C9 . . 137.0(6) ?
C8A N1 C9A . . 114.3(6) ?
C9 N1 C9A . . 48.6(5) ?
C8A N1 C7 . . 51.7(5) ?
C9 N1 C7 . . 114.1(6) ?
C9A N1 C7 . . 143.2(5) ?
C8A N1 C7A . . 110.2(5) ?
C9 N1 C7A . . 59.8(5) ?
C9A N1 C7A . . 107.8(6) ?
C7 N1 C7A . . 61.0(4) ?
C8A N1 C8 . . 54.1(5) ?
C9 N1 C8 . . 108.4(6) ?
C9A N1 C8 . . 64.2(6) ?
C7 N1 C8 . . 104.2(5) ?
C7A N1 C8 . . 145.7(5) ?
C8A N1 Sb1 . . 105.1(4) ?
C9 N1 Sb1 . . 117.9(4) ?
C9A N1 Sb1 . . 114.6(4) ?
C7 N1 Sb1 . . 102.2(3) ?
C7A N1 Sb1 . . 104.3(3) ?
C8 N1 Sb1 . . 109.2(4) ?
C16 N2 C18 . . 110.2(4) ?
C16 N2 C17 . . 111.2(4) ?
C18 N2 C17 . . 110.9(5) ?
C1 Sb1 C10 . . 96.9(2) ?
C1 Sb1 C1A . . 2.6(3) yes
C10 Sb1 C1A . . 98.77(18) yes
C1 Sb1 N1 . . 73.2(2) yes
C10 Sb1 N1 . . 89.75(12) yes
C1A Sb1 N1 . . 75.0(2) yes
C1 Sb1 Cl1 . . 91.9(2) yes
C10 Sb1 Cl1 . . 87.61(10) yes
C1A Sb1 Cl1 . . 90.3(2) yes
N1 Sb1 Cl1 . . 164.43(8) yes
N2 Sb1 Cl1 . . 110.65(8) yes
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
C1 C2 . 1.39 ?
C1 C6 . 1.39 ?
C1 Sb1 . 2.103(5) yes
C2 C3 . 1.39 ?
C2 C7 . 1.496(9) ?
C3 C4 . 1.39 ?
C3 H3 . 0.93 ?
C4 C5 . 1.39 ?
C4 H4 . 0.93 ?
C5 C6 . 1.39 ?
C5 H5 . 0.93 ?
C6 H6 . 0.93 ?
C7 N1 . 1.484(8) ?
C7 H7A . 0.97 ?
C7 H7B . 0.97 ?
C8 N1 . 1.563(9) ?
C8 H8A . 0.96 ?
C8 H8B . 0.96 ?
C8 H8C . 0.96 ?
C9 N1 . 1.406(8) ?
C9 H9A . 0.96 ?
C9 H9B . 0.96 ?
C9 H9C . 0.96 ?
C1A C2A . 1.39 ?
C1A C6A . 1.39 ?
C1A Sb1 . 2.188(5) yes
C2A C3A . 1.39 ?
C2A C7A . 1.484(9) ?
C3A C4A . 1.39 ?
C3A H3A . 0.93 ?
C4A C5A . 1.39 ?
C4A H4A . 0.93 ?
C5A C6A . 1.39 ?
C5A H5A . 0.93 ?
C6A H6A . 0.93 ?
C7A N1 . 1.537(8) ?
C7A H7A1 . 0.97 ?
C7A H7A2 . 0.97 ?
C8A N1 . 1.391(8) ?
C8A H8A1 . 0.96 ?
C8A H8A2 . 0.96 ?
C8A H8A3 . 0.96 ?
C9A N1 . 1.479(9) ?
C9A H9A1 . 0.96 ?
C9A H9A2 . 0.96 ?
C9A H9A3 . 0.96 ?
C10 C15 . 1.369(5) ?
C10 C11 . 1.393(5) ?
C10 Sb1 . 2.153(4) ?
C11 C12 . 1.383(5) ?
C11 C16 . 1.496(6) ?
C12 C13 . 1.348(7) ?
C12 H12 . 0.93 ?
C13 C14 . 1.368(7) ?
C13 H13 . 0.93 ?
C14 C15 . 1.387(6) ?
C14 H14 . 0.93 ?
C15 H15 . 0.93 ?
C16 N2 . 1.446(6) ?
C16 H16A . 0.97 ?
C16 H16B . 0.97 ?
C17 N2 . 1.451(6) ?
C17 H17A . 0.96 ?
C17 H17B . 0.96 ?
C17 H17C . 0.96 ?
C18 N2 . 1.448(6) ?
C18 H18A . 0.96 ?
C18 H18B . 0.96 ?
C18 H18C . 0.96 ?
N1 Sb1 . 2.454(3) yes
N2 Sb1 . 3.326(5) yes
Sb1 Cl1 . 2.5759(18) yes
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_D
_geom_hbond_site_symmetry_H
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
_geom_hbond_publ_flag
C6 H6 Cl1 . . . 0.93 2.65 3.291(7) 127 yes
C6A H6A Cl1 . . . 0.93 2.74 3.353(7) 125 yes
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C6 C1 C2 C3 . . . . 0 ?
Sb1 C1 C2 C3 . . . . 180.0(5) ?
C6 C1 C2 C7 . . . . -177.0(7) ?
Sb1 C1 C2 C7 . . . . 3.0(7) ?
C1 C2 C3 C4 . . . . 0 ?
C7 C2 C3 C4 . . . . 177.0(7) ?
C2 C3 C4 C5 . . . . 0 ?
C3 C4 C5 C6 . . . . 0 ?
C4 C5 C6 C1 . . . . 0 ?
C2 C1 C6 C5 . . . . 0 ?
Sb1 C1 C6 C5 . . . . 180.0(5) ?
C3 C2 C7 N1 . . . . 144.3(5) ?
C1 C2 C7 N1 . . . . -38.6(8) ?
C6A C1A C2A C3A . . . . 0 ?
Sb1 C1A C2A C3A . . . . 175.2(4) ?
C6A C1A C2A C7A . . . . 179.6(7) ?
Sb1 C1A C2A C7A . . . . -5.2(7) ?
C1A C2A C3A C4A . . . . 0 ?
C7A C2A C3A C4A . . . . -179.6(7) ?
C2A C3A C4A C5A . . . . 0 ?
C3A C4A C5A C6A . . . . 0 ?
C4A C5A C6A C1A . . . . 0 ?
C2A C1A C6A C5A . . . . 0 ?
Sb1 C1A C6A C5A . . . . -174.9(5) ?
C3A C2A C7A N1 . . . . -148.5(4) ?
C1A C2A C7A N1 . . . . 31.9(8) ?
C15 C10 C11 C12 . . . . -0.6(5) ?
Sb1 C10 C11 C12 . . . . -179.0(3) ?
C15 C10 C11 C16 . . . . 176.5(4) ?
Sb1 C10 C11 C16 . . . . -1.9(5) ?
C10 C11 C12 C13 . . . . -1.1(6) ?
C16 C11 C12 C13 . . . . -178.2(4) ?
C11 C12 C13 C14 . . . . 2.2(6) ?
C12 C13 C14 C15 . . . . -1.7(7) ?
C11 C10 C15 C14 . . . . 1.1(6) ?
Sb1 C10 C15 C14 . . . . 179.5(3) ?
C13 C14 C15 C10 . . . . 0.1(6) ?
C12 C11 C16 N2 . . . . -113.5(4) ?
C10 C11 C16 N2 . . . . 69.5(5) ?
C2 C7 N1 C8A . . . . 147.4(8) ?
C2 C7 N1 C9 . . . . -80.7(7) ?
C2 C7 N1 C9A . . . . -133.0(9) ?
C2 C7 N1 C7A . . . . -52.1(6) ?
C2 C7 N1 C8 . . . . 161.3(6) ?
C2 C7 N1 Sb1 . . . . 47.7(6) ?
C2A C7A N1 C8A . . . . 74.7(7) ?
C2A C7A N1 C9 . . . . -151.9(8) ?
C2A C7A N1 C9A . . . . -159.9(6) ?
C2A C7A N1 C7 . . . . 58.5(6) ?
C2A C7A N1 C8 . . . . 130.0(9) ?
C2A C7A N1 Sb1 . . . . -37.7(6) ?
C11 C16 N2 C18 . . . . -165.1(4) ?
C11 C16 N2 C17 . . . . 71.6(5) ?
C2 C1 Sb1 C10 . . . . 106.9(4) ?
C6 C1 Sb1 C10 . . . . -73.1(4) ?
C2 C1 Sb1 C1A . . . . -114(7) ?
C6 C1 Sb1 C1A . . . . 66(7) ?
C2 C1 Sb1 N1 . . . . 19.3(4) ?
C6 C1 Sb1 N1 . . . . -160.7(4) ?
C2 C1 Sb1 Cl1 . . . . -165.3(4) ?
C6 C1 Sb1 Cl1 . . . . 14.7(4) ?
C15 C10 Sb1 C1 . . . . 4.3(4) ?
C11 C10 Sb1 C1 . . . . -177.3(3) ?
C15 C10 Sb1 C1A . . . . 2.6(4) ?
C11 C10 Sb1 C1A . . . . -179.0(3) ?
C15 C10 Sb1 N1 . . . . 77.3(3) ?
C11 C10 Sb1 N1 . . . . -104.3(3) ?
C15 C10 Sb1 Cl1 . . . . -87.3(3) ?
C11 C10 Sb1 Cl1 . . . . 91.1(3) ?
C2A C1A Sb1 C1 . . . . 33(7) ?
C6A C1A Sb1 C1 . . . . -152(7) ?
C2A C1A Sb1 C10 . . . . 74.1(3) ?
C6A C1A Sb1 C10 . . . . -110.8(4) ?
C2A C1A Sb1 N1 . . . . -13.3(3) ?
C6A C1A Sb1 N1 . . . . 161.8(4) ?
C2A C1A Sb1 Cl1 . . . . 161.7(3) ?
C6A C1A Sb1 Cl1 . . . . -23.2(4) ?
C8A N1 Sb1 C1 . . . . -90.6(5) ?
C9 N1 Sb1 C1 . . . . 88.5(6) ?
C9A N1 Sb1 C1 . . . . 143.0(5) ?
C7 N1 Sb1 C1 . . . . -37.4(4) ?
C7A N1 Sb1 C1 . . . . 25.4(4) ?
C8 N1 Sb1 C1 . . . . -147.3(5) ?
C8A N1 Sb1 C10 . . . . 172.1(4) ?
C9 N1 Sb1 C10 . . . . -8.7(5) ?
C9A N1 Sb1 C10 . . . . 45.8(5) ?
C7 N1 Sb1 C10 . . . . -134.6(4) ?
C7A N1 Sb1 C10 . . . . -71.8(4) ?
C8 N1 Sb1 C10 . . . . 115.5(4) ?
C8A N1 Sb1 C1A . . . . -88.7(4) ?
C9 N1 Sb1 C1A . . . . 90.4(6) ?
C9A N1 Sb1 C1A . . . . 145.0(5) ?
C7 N1 Sb1 C1A . . . . -35.5(4) ?
C7A N1 Sb1 C1A . . . . 27.3(4) ?
C8 N1 Sb1 C1A . . . . -145.4(4) ?
C8A N1 Sb1 Cl1 . . . . -107.7(5) ?
C9 N1 Sb1 Cl1 . . . . 71.4(6) ?
C9A N1 Sb1 Cl1 . . . . 126.0(5) ?
C7 N1 Sb1 Cl1 . . . . -54.5(5) ?
C7A N1 Sb1 Cl1 . . . . 8.3(5) ?
C8 N1 Sb1 Cl1 . . . . -164.4(4) ?
