#------------------------------------------------------------------------------
#$Date: 2016-02-20 22:30:07 +0200 (Sat, 20 Feb 2016) $
#$Revision: 176789 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/50/2225000.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2225000
loop_
_publ_author_name
'Meyer, Nadine'
'Mohr, Fabian'
'Tiekink, Edward R. T.'
_publ_section_title
;[μ-1,1'-Bis(diphenylphosphino)ferrocene-κ²P:P']bis[chloridogold(I)]--chloroform--hexane
 (2/2/1)
;
_journal_coeditor_code           HG2624
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m168
_journal_page_last               m169
_journal_paper_doi               10.1107/S1600536810001418
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac
'[Au2 Fe (C17 H14 P)2 Cl2], C H Cl3, 0.5C6 H14'
_chemical_formula_moiety         'C34 H28 Au2 Cl2 Fe P2, C H Cl3, 0.5(C6 H14)'
_chemical_formula_sum            'C38 H36 Au2 Cl5 Fe P2'
_chemical_formula_weight         1181.64
_chemical_name_systematic
;
[μ-1,1'-Bis(diphenylphosphino)ferrocene-
κ²P:P]bis[chloridogold(I)]--chloroform--hexane (2/2/1)
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                103.586(7)
_cell_angle_beta                 110.803(9)
_cell_angle_gamma                92.802(10)
_cell_formula_units_Z            2
_cell_length_a                   11.631(5)
_cell_length_b                   12.763(5)
_cell_length_c                   14.530(7)
_cell_measurement_reflns_used    7032
_cell_measurement_temperature    98(2)
_cell_measurement_theta_max      30.1
_cell_measurement_theta_min      2.0
_cell_volume                     1939.0(15)
_computing_cell_refinement       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_collection       'CrystalClear (Rigaku/MSC, 2005)'
_computing_data_reduction        'CrystalClear (Rigaku/MSC, 2005)'
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      98(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type  'Rigaku AFC12Κ/SATURN724'
_diffrn_measurement_method       ω
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71070
_diffrn_reflns_av_R_equivalents  0.041
_diffrn_reflns_av_sigmaI/netI    0.042
_diffrn_reflns_limit_h_max       14
_diffrn_reflns_limit_h_min       -14
_diffrn_reflns_limit_k_max       16
_diffrn_reflns_limit_k_min       -13
_diffrn_reflns_limit_l_max       17
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            19988
_diffrn_reflns_theta_full        26.5
_diffrn_reflns_theta_max         26.5
_diffrn_reflns_theta_min         1.9
_diffrn_standards_decay_%        '< 1'
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    8.371
_exptl_absorpt_correction_T_max  1
_exptl_absorpt_correction_T_min  0.222
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            orange
_exptl_crystal_density_diffrn    2.024
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             1126
_exptl_crystal_size_max          0.22
_exptl_crystal_size_mid          0.19
_exptl_crystal_size_min          0.04
_refine_diff_density_max         2.53
_refine_diff_density_min         -2.36
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.08
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     433
_refine_ls_number_reflns         8010
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.08
_refine_ls_R_factor_all          0.041
_refine_ls_R_factor_gt           0.039
_refine_ls_shift/su_max          0.002
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0508P)²+6.3295P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.097
_refine_ls_wR_factor_ref         0.099
_reflns_number_gt                7541
_reflns_number_total             8010
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            hg2624.cif
_cod_data_source_block           I
_cod_database_code               2225000
_cod_database_fobs_code          2225000
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Au Au1 0.581716(18) 0.161739(17) 0.103915(15) 0.01852(8) Uani d . 1 . .
Au Au2 0.735621(18) -0.075680(16) 0.585129(15) 0.01820(8) Uani d . 1 . .
Fe Fe 0.74224(7) 0.14693(6) 0.41137(6) 0.01708(16) Uani d . 1 . .
Cl Cl1 0.37269(12) 0.10792(13) 0.00408(10) 0.0270(3) Uani d . 1 . .
Cl Cl2 0.73374(14) -0.26065(11) 0.53407(11) 0.0265(3) Uani d . 1 . .
Cl Cl3 0.79521(19) 0.55203(16) 0.72594(19) 0.0530(5) Uani d . 1 . .
Cl Cl4 0.62630(15) 0.67474(14) 0.79754(13) 0.0349(4) Uani d . 1 . .
Cl Cl5 0.5292(2) 0.47710(15) 0.62931(16) 0.0477(4) Uani d . 1 . .
P P1 0.78213(13) 0.21388(11) 0.20723(10) 0.0179(3) Uani d . 1 . .
P P2 0.73597(12) 0.10415(11) 0.63297(10) 0.0168(3) Uani d . 1 . .
C C1 0.8941(5) 0.1834(4) 0.1473(4) 0.0187(11) Uani d . 1 . .
C C2 1.0085(5) 0.1529(5) 0.1977(5) 0.0255(12) Uani d . 1 . .
H H2 1.0277 0.1439 0.2644 0.031 Uiso calc R 1 . .
C C3 1.0948(6) 0.1357(6) 0.1512(5) 0.0328(14) Uani d . 1 . .
H H3 1.1730 0.1165 0.1867 0.039 Uiso calc R 1 . .
C C4 1.0667(6) 0.1466(6) 0.0532(5) 0.0314(14) Uani d . 1 . .
H H4 1.1240 0.1324 0.0203 0.038 Uiso calc R 1 . .
C C5 0.9536(6) 0.1787(6) 0.0035(5) 0.0361(15) Uani d . 1 . .
H H5 0.9349 0.1880 -0.0630 0.043 Uiso calc R 1 . .
C C6 0.8673(6) 0.1974(5) 0.0497(4) 0.0283(13) Uani d . 1 . .
H H6 0.7906 0.2195 0.0150 0.034 Uiso calc R 1 . .
C C7 0.8213(6) 0.3588(4) 0.2703(4) 0.0222(12) Uani d . 1 . .
C C8 0.7257(6) 0.4229(5) 0.2624(5) 0.0263(13) Uani d . 1 . .
H H8 0.6418 0.3902 0.2237 0.032 Uiso calc R 1 . .
C C9 0.7524(7) 0.5335(6) 0.3104(5) 0.0355(15) Uani d . 1 . .
H H9 0.6872 0.5764 0.3063 0.043 Uiso calc R 1 . .
C C10 0.8745(7) 0.5806(5) 0.3643(5) 0.0360(16) Uani d . 1 . .
H H10 0.8931 0.6569 0.3951 0.043 Uiso calc R 1 . .
C C11 0.9705(7) 0.5189(6) 0.3743(5) 0.0354(15) Uani d . 1 . .
H H11 1.0539 0.5529 0.4135 0.042 Uiso calc R 1 . .
C C12 0.9458(6) 0.4076(5) 0.3274(5) 0.0286(13) Uani d . 1 . .
H H12 1.0117 0.3651 0.3336 0.034 Uiso calc R 1 . .
C C13 0.8234(5) 0.1463(4) 0.3073(4) 0.0191(11) Uani d . 1 . .
C C14 0.7668(5) 0.0387(5) 0.2938(4) 0.0216(11) Uani d . 1 . .
H H14 0.7026 -0.0056 0.2337 0.026 Uiso calc R 1 . .
C C15 0.8246(6) 0.0102(5) 0.3874(4) 0.0240(12) Uani d . 1 . .
H H15 0.8053 -0.0569 0.4002 0.029 Uiso calc R 1 . .
C C16 0.9153(5) 0.0984(5) 0.4582(4) 0.0267(13) Uani d . 1 . .
H H16 0.9667 0.1010 0.5264 0.032 Uiso calc R 1 . .
C C17 0.9160(5) 0.1821(5) 0.4094(4) 0.0226(12) Uani d . 1 . .
H H17 0.9686 0.2503 0.4391 0.027 Uiso calc R 1 . .
C C18 0.6783(5) 0.1609(4) 0.5259(4) 0.0167(10) Uani d . 1 . .
C C19 0.7099(5) 0.2673(4) 0.5177(4) 0.0204(11) Uani d . 1 . .
H H19 0.7694 0.3245 0.5696 0.024 Uiso calc R 1 . .
C C20 0.6348(5) 0.2711(5) 0.4162(4) 0.0229(12) Uani d . 1 . .
H H20 0.6367 0.3319 0.3893 0.028 Uiso calc R 1 . .
C C21 0.5572(5) 0.1694(5) 0.3625(4) 0.0232(12) Uani d . 1 . .
H H21 0.4986 0.1506 0.2940 0.028 Uiso calc R 1 . .
C C22 0.5828(5) 0.1011(5) 0.4293(4) 0.0193(11) Uani d . 1 . .
H H22 0.5438 0.0285 0.4133 0.023 Uiso calc R 1 . .
C C23 0.6329(5) 0.1383(4) 0.7019(4) 0.0188(11) Uani d . 1 . .
C C24 0.6470(5) 0.0969(5) 0.7854(4) 0.0223(11) Uani d . 1 . .
H H24 0.7115 0.0546 0.8066 0.027 Uiso calc R 1 . .
C C25 0.5684(6) 0.1168(5) 0.8376(4) 0.0261(12) Uani d . 1 . .
H H25 0.5780 0.0873 0.8937 0.031 Uiso calc R 1 . .
C C26 0.4740(6) 0.1807(5) 0.8078(5) 0.0261(13) Uani d . 1 . .
H H26 0.4217 0.1970 0.8451 0.031 Uiso calc R 1 . .
C C27 0.4581(6) 0.2194(5) 0.7238(5) 0.0273(13) Uani d . 1 . .
H H27 0.3923 0.2603 0.7020 0.033 Uiso calc R 1 . .
C C28 0.5369(5) 0.1997(4) 0.6704(4) 0.0209(11) Uani d . 1 . .
H H28 0.5256 0.2276 0.6131 0.025 Uiso calc R 1 . .
C C29 0.8855(5) 0.1835(5) 0.7195(4) 0.0191(11) Uani d . 1 . .
C C30 0.8942(6) 0.2915(5) 0.7667(5) 0.0253(12) Uani d . 1 . .
H H30 0.8219 0.3261 0.7529 0.030 Uiso calc R 1 . .
C C31 1.0095(6) 0.3513(5) 0.8356(5) 0.0306(14) Uani d . 1 . .
H H31 1.0158 0.4266 0.8674 0.037 Uiso calc R 1 . .
C C32 1.1147(6) 0.2991(6) 0.8568(5) 0.0318(14) Uani d . 1 . .
H H32 1.1928 0.3393 0.9037 0.038 Uiso calc R 1 . .
C C33 1.1069(5) 0.1903(5) 0.8108(5) 0.0280(13) Uani d . 1 . .
H H33 1.1789 0.1553 0.8269 0.034 Uiso calc R 1 . .
C C34 0.9930(5) 0.1316(5) 0.7406(4) 0.0209(11) Uani d . 1 . .
H H34 0.9876 0.0570 0.7071 0.025 Uiso calc R 1 . .
C C35 0.6456(7) 0.5917(6) 0.6900(6) 0.0385(16) Uani d . 1 . .
H H35 0.6385 0.6357 0.6401 0.046 Uiso calc R 1 . .
C C36 0.5378(6) 0.4984(6) 0.9665(5) 0.0350(15) Uani d . 1 . .
H H36A 0.5662 0.5739 0.9693 0.042 Uiso calc R 1 . .
H H36B 0.4838 0.4610 0.8947 0.042 Uiso calc R 1 . .
C C37 0.6526(7) 0.4386(6) 0.9999(5) 0.0357(15) Uani d . 1 . .
H H37A 0.7074 0.4771 1.0711 0.043 Uiso calc R 1 . .
H H37B 0.6242 0.3638 0.9988 0.043 Uiso calc R 1 . .
C C38 0.7268(7) 0.4324(6) 0.9323(6) 0.0436(18) Uani d . 1 . .
H H38A 0.7500 0.3593 0.9179 0.065 Uiso calc R 1 . .
H H38B 0.8021 0.4864 0.9673 0.065 Uiso calc R 1 . .
H H38C 0.6763 0.4475 0.8680 0.065 Uiso calc R 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Au Au -2.0133 8.8022 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Fe Fe 0.3463 0.8444 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
P1 Au1 Cl1 . . 177.27(5) y
P2 Au2 Cl2 . . 179.34(5) y
C18 Fe C22 . . 41.7(2) ?
C18 Fe C14 . . 144.2(2) ?
C22 Fe C14 . . 112.3(2) ?
C18 Fe C13 . . 173.4(2) ?
C22 Fe C13 . . 144.7(2) ?
C14 Fe C13 . . 41.0(2) ?
C18 Fe C15 . . 113.2(2) ?
C22 Fe C15 . . 107.2(2) ?
C14 Fe C15 . . 40.8(2) ?
C13 Fe C15 . . 68.5(2) ?
C18 Fe C19 . . 41.0(2) ?
C22 Fe C19 . . 69.1(2) ?
C14 Fe C19 . . 173.1(2) ?
C13 Fe C19 . . 134.4(2) ?
C15 Fe C19 . . 145.9(2) ?
C18 Fe C17 . . 133.0(2) ?
C22 Fe C17 . . 171.6(2) ?
C14 Fe C17 . . 68.6(2) ?
C13 Fe C17 . . 41.0(2) ?
C15 Fe C17 . . 67.8(2) ?
C19 Fe C17 . . 111.0(2) ?
C18 Fe C16 . . 108.3(2) ?
C22 Fe C16 . . 131.8(2) ?
C14 Fe C16 . . 68.6(2) ?
C13 Fe C16 . . 68.6(2) ?
C15 Fe C16 . . 40.3(2) ?
C19 Fe C16 . . 115.9(2) ?
C17 Fe C16 . . 40.2(2) ?
C18 Fe C20 . . 68.6(2) ?
C22 Fe C20 . . 67.8(2) ?
C14 Fe C20 . . 132.9(2) ?
C13 Fe C20 . . 110.8(2) ?
C15 Fe C20 . . 171.0(2) ?
C19 Fe C20 . . 40.7(2) ?
C17 Fe C20 . . 118.1(2) ?
C16 Fe C20 . . 148.5(3) ?
C18 Fe C21 . . 69.0(2) ?
C22 Fe C21 . . 40.3(2) ?
C14 Fe C21 . . 107.8(2) ?
C13 Fe C21 . . 115.0(2) ?
C15 Fe C21 . . 131.4(3) ?
C19 Fe C21 . . 68.6(2) ?
C17 Fe C21 . . 148.0(2) ?
C16 Fe C21 . . 170.5(3) ?
C20 Fe C21 . . 40.1(2) ?
C13 P1 C7 . . 106.1(3) ?
C13 P1 C1 . . 104.4(3) ?
C7 P1 C1 . . 105.0(3) ?
C13 P1 Au1 . . 110.77(19) ?
C7 P1 Au1 . . 113.9(2) ?
C1 P1 Au1 . . 115.77(19) ?
C18 P2 C29 . . 107.8(3) ?
C18 P2 C23 . . 104.4(2) ?
C29 P2 C23 . . 104.2(2) ?
C18 P2 Au2 . . 112.56(18) ?
C29 P2 Au2 . . 115.27(19) ?
C23 P2 Au2 . . 111.73(18) ?
C6 C1 C2 . . 119.2(5) ?
C6 C1 P1 . . 118.4(4) ?
C2 C1 P1 . . 122.3(4) ?
C3 C2 C1 . . 120.6(6) ?
C3 C2 H2 . . 119.7 ?
C1 C2 H2 . . 119.7 ?
C4 C3 C2 . . 120.2(6) ?
C4 C3 H3 . . 119.9 ?
C2 C3 H3 . . 119.9 ?
C3 C4 C5 . . 119.2(6) ?
C3 C4 H4 . . 120.4 ?
C5 C4 H4 . . 120.4 ?
C4 C5 C6 . . 121.1(6) ?
C4 C5 H5 . . 119.4 ?
C6 C5 H5 . . 119.4 ?
C5 C6 C1 . . 119.7(6) ?
C5 C6 H6 . . 120.2 ?
C1 C6 H6 . . 120.2 ?
C8 C7 C12 . . 119.6(5) ?
C8 C7 P1 . . 119.1(5) ?
C12 C7 P1 . . 121.3(5) ?
C9 C8 C7 . . 120.6(6) ?
C9 C8 H8 . . 119.7 ?
C7 C8 H8 . . 119.7 ?
C10 C9 C8 . . 119.3(6) ?
C10 C9 H9 . . 120.4 ?
C8 C9 H9 . . 120.4 ?
C9 C10 C11 . . 121.3(6) ?
C9 C10 H10 . . 119.4 ?
C11 C10 H10 . . 119.4 ?
C10 C11 C12 . . 120.4(6) ?
C10 C11 H11 . . 119.8 ?
C12 C11 H11 . . 119.8 ?
C11 C12 C7 . . 118.8(6) ?
C11 C12 H12 . . 120.6 ?
C7 C12 H12 . . 120.6 ?
C14 C13 C17 . . 107.5(5) ?
C14 C13 P1 . . 122.8(4) ?
C17 C13 P1 . . 129.7(4) ?
C14 C13 Fe . . 69.5(3) ?
C17 C13 Fe . . 70.0(3) ?
P1 C13 Fe . . 127.4(3) ?
C15 C14 C13 . . 107.4(5) ?
C15 C14 Fe . . 69.7(3) ?
C13 C14 Fe . . 69.5(3) ?
C15 C14 H14 . . 126.3 ?
C13 C14 H14 . . 126.3 ?
Fe C14 H14 . . 126.0 ?
C16 C15 C14 . . 108.8(5) ?
C16 C15 Fe . . 70.3(3) ?
C14 C15 Fe . . 69.5(3) ?
C16 C15 H15 . . 125.6 ?
C14 C15 H15 . . 125.6 ?
Fe C15 H15 . . 126.3 ?
C17 C16 C15 . . 108.0(5) ?
C17 C16 Fe . . 69.9(3) ?
C15 C16 Fe . . 69.4(3) ?
C17 C16 H16 . . 126.0 ?
C15 C16 H16 . . 126.0 ?
Fe C16 H16 . . 126.3 ?
C16 C17 C13 . . 108.4(5) ?
C16 C17 Fe . . 69.9(3) ?
C13 C17 Fe . . 69.0(3) ?
C16 C17 H17 . . 125.8 ?
C13 C17 H17 . . 125.8 ?
Fe C17 H17 . . 126.9 ?
C19 C18 C22 . . 107.6(5) ?
C19 C18 P2 . . 129.7(4) ?
C22 C18 P2 . . 122.6(4) ?
C19 C18 Fe . . 70.7(3) ?
C22 C18 Fe . . 69.6(3) ?
P2 C18 Fe . . 126.4(3) ?
C18 C19 C20 . . 107.1(5) ?
C18 C19 Fe . . 68.2(3) ?
C20 C19 Fe . . 70.0(3) ?
C18 C19 H19 . . 126.5 ?
C20 C19 H19 . . 126.5 ?
Fe C19 H19 . . 126.8 ?
C21 C20 C19 . . 109.1(5) ?
C21 C20 Fe . . 70.0(3) ?
C19 C20 Fe . . 69.3(3) ?
C21 C20 H20 . . 125.5 ?
C19 C20 H20 . . 125.5 ?
Fe C20 H20 . . 126.9 ?
C22 C21 C20 . . 107.8(5) ?
C22 C21 Fe . . 68.6(3) ?
C20 C21 Fe . . 69.9(3) ?
C22 C21 H21 . . 126.1 ?
C20 C21 H21 . . 126.1 ?
Fe C21 H21 . . 127.0 ?
C21 C22 C18 . . 108.4(5) ?
C21 C22 Fe . . 71.0(3) ?
C18 C22 Fe . . 68.7(3) ?
C21 C22 H22 . . 125.8 ?
C18 C22 H22 . . 125.8 ?
Fe C22 H22 . . 126.0 ?
C24 C23 C28 . . 119.5(5) ?
C24 C23 P2 . . 118.4(4) ?
C28 C23 P2 . . 122.1(4) ?
C25 C24 C23 . . 120.7(5) ?
C25 C24 H24 . . 119.7 ?
C23 C24 H24 . . 119.7 ?
C24 C25 C26 . . 120.0(6) ?
C24 C25 H25 . . 120.0 ?
C26 C25 H25 . . 120.0 ?
C27 C26 C25 . . 119.4(5) ?
C27 C26 H26 . . 120.3 ?
C25 C26 H26 . . 120.3 ?
C26 C27 C28 . . 121.1(5) ?
C26 C27 H27 . . 119.5 ?
C28 C27 H27 . . 119.5 ?
C27 C28 C23 . . 119.4(5) ?
C27 C28 H28 . . 120.3 ?
C23 C28 H28 . . 120.3 ?
C30 C29 C34 . . 119.9(5) ?
C30 C29 P2 . . 120.8(4) ?
C34 C29 P2 . . 119.3(4) ?
C29 C30 C31 . . 120.4(6) ?
C29 C30 H30 . . 119.8 ?
C31 C30 H30 . . 119.8 ?
C32 C31 C30 . . 119.3(6) ?
C32 C31 H31 . . 120.3 ?
C30 C31 H31 . . 120.3 ?
C33 C32 C31 . . 120.9(6) ?
C33 C32 H32 . . 119.6 ?
C31 C32 H32 . . 119.6 ?
C32 C33 C34 . . 119.8(6) ?
C32 C33 H33 . . 120.1 ?
C34 C33 H33 . . 120.1 ?
C33 C34 C29 . . 119.8(5) ?
C33 C34 H34 . . 120.1 ?
C29 C34 H34 . . 120.1 ?
Cl5 C35 Cl4 . . 111.4(4) ?
Cl5 C35 Cl3 . . 111.0(4) ?
Cl4 C35 Cl3 . . 110.2(4) ?
Cl5 C35 H35 . . 108.1 ?
Cl4 C35 H35 . . 108.1 ?
Cl3 C35 H35 . . 108.1 ?
C36 C36 C37 2_667 . 112.6(7) ?
C36 C36 H36A 2_667 . 109.1 ?
C37 C36 H36A . . 109.1 ?
C36 C36 H36B 2_667 . 109.1 ?
C37 C36 H36B . . 109.1 ?
H36A C36 H36B . . 107.8 ?
C38 C37 C36 . . 113.2(6) ?
C38 C37 H37A . . 108.9 ?
C36 C37 H37A . . 108.9 ?
C38 C37 H37B . . 108.9 ?
C36 C37 H37B . . 108.9 ?
H37A C37 H37B . . 107.8 ?
C37 C38 H38A . . 109.5 ?
C37 C38 H38B . . 109.5 ?
H38A C38 H38B . . 109.5 ?
C37 C38 H38C . . 109.5 ?
H38A C38 H38C . . 109.5 ?
H38B C38 H38C . . 109.5 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Au1 Cl1 . 2.3131(17) y
Au1 P1 . 2.2413(17) y
Au2 Cl2 . 2.2988(17) y
Au2 P2 . 2.2357(17) y
Fe C18 . 2.026(5) ?
Fe C22 . 2.039(5) ?
Fe C14 . 2.045(5) ?
Fe C13 . 2.046(5) ?
Fe C15 . 2.049(5) ?
Fe C19 . 2.059(5) ?
Fe C17 . 2.060(6) ?
Fe C16 . 2.060(6) ?
Fe C20 . 2.069(5) ?
Fe C21 . 2.071(5) ?
Cl3 C35 . 1.767(7) ?
Cl4 C35 . 1.764(7) ?
Cl5 C35 . 1.761(8) ?
P1 C13 . 1.795(6) ?
P1 C7 . 1.814(6) ?
P1 C1 . 1.817(5) ?
P2 C18 . 1.798(5) ?
P2 C29 . 1.819(6) ?
P2 C23 . 1.825(5) ?
C1 C6 . 1.396(8) ?
C1 C2 . 1.397(8) ?
C2 C3 . 1.396(8) ?
C2 H2 . 0.9500 ?
C3 C4 . 1.386(9) ?
C3 H3 . 0.9500 ?
C4 C5 . 1.392(9) ?
C4 H4 . 0.9500 ?
C5 C6 . 1.394(9) ?
C5 H5 . 0.9500 ?
C6 H6 . 0.9500 ?
C7 C8 . 1.401(8) ?
C7 C12 . 1.410(8) ?
C8 C9 . 1.385(9) ?
C8 H8 . 0.9500 ?
C9 C10 . 1.377(10) ?
C9 H9 . 0.9500 ?
C10 C11 . 1.383(10) ?
C10 H10 . 0.9500 ?
C11 C12 . 1.391(9) ?
C11 H11 . 0.9500 ?
C12 H12 . 0.9500 ?
C13 C14 . 1.432(8) ?
C13 C17 . 1.439(8) ?
C14 C15 . 1.428(8) ?
C14 H14 . 0.9500 ?
C15 C16 . 1.417(9) ?
C15 H15 . 0.9500 ?
C16 C17 . 1.415(8) ?
C16 H16 . 0.9500 ?
C17 H17 . 0.9500 ?
C18 C19 . 1.432(8) ?
C18 C22 . 1.446(7) ?
C19 C20 . 1.437(8) ?
C19 H19 . 0.9500 ?
C20 C21 . 1.420(8) ?
C20 H20 . 0.9500 ?
C21 C22 . 1.417(8) ?
C21 H21 . 0.9500 ?
C22 H22 . 0.9500 ?
C23 C24 . 1.396(8) ?
C23 C28 . 1.399(8) ?
C24 C25 . 1.379(8) ?
C24 H24 . 0.9500 ?
C25 C26 . 1.404(9) ?
C25 H25 . 0.9500 ?
C26 C27 . 1.378(9) ?
C26 H26 . 0.9500 ?
C27 C28 . 1.393(8) ?
C27 H27 . 0.9500 ?
C28 H28 . 0.9500 ?
C29 C30 . 1.369(8) ?
C29 C34 . 1.414(8) ?
C30 C31 . 1.404(9) ?
C30 H30 . 0.9500 ?
C31 C32 . 1.394(9) ?
C31 H31 . 0.9500 ?
C32 C33 . 1.376(9) ?
C32 H32 . 0.9500 ?
C33 C34 . 1.393(8) ?
C33 H33 . 0.9500 ?
C34 H34 . 0.9500 ?
C35 H35 . 1.0000 ?
C36 C36 2_667 1.521(13) ?
C36 C37 . 1.554(9) ?
C36 H36A . 0.9900 ?
C36 H36B . 0.9900 ?
C37 C38 . 1.511(10) ?
C37 H37A . 0.9900 ?
C37 H37B . 0.9900 ?
C38 H38A . 0.9800 ?
C38 H38B . 0.9800 ?
C38 H38C . 0.9800 ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
C35 H35 Cl2 1_565 1.00 2.72 3.634(8) 153
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
Cl1 Au1 P1 C13 . . . . 38.5(11) ?
Cl1 Au1 P1 C7 . . . . -81.1(11) ?
Cl1 Au1 P1 C1 . . . . 157.1(11) ?
Cl2 Au2 P2 C18 . . . . -16(5) ?
Cl2 Au2 P2 C29 . . . . -141(4) ?
Cl2 Au2 P2 C23 . . . . 101(4) ?
C13 P1 C1 C6 . . . . 162.1(5) ?
C7 P1 C1 C6 . . . . -86.4(5) ?
Au1 P1 C1 C6 . . . . 40.1(5) ?
C13 P1 C1 C2 . . . . -21.8(5) ?
C7 P1 C1 C2 . . . . 89.7(5) ?
Au1 P1 C1 C2 . . . . -143.8(4) ?
C6 C1 C2 C3 . . . . -0.5(9) ?
P1 C1 C2 C3 . . . . -176.6(5) ?
C1 C2 C3 C4 . . . . -1.3(10) ?
C2 C3 C4 C5 . . . . 2.3(11) ?
C3 C4 C5 C6 . . . . -1.6(11) ?
C4 C5 C6 C1 . . . . -0.2(11) ?
C2 C1 C6 C5 . . . . 1.3(9) ?
P1 C1 C6 C5 . . . . 177.5(5) ?
C13 P1 C7 C8 . . . . -113.5(5) ?
C1 P1 C7 C8 . . . . 136.3(5) ?
Au1 P1 C7 C8 . . . . 8.6(5) ?
C13 P1 C7 C12 . . . . 66.1(5) ?
C1 P1 C7 C12 . . . . -44.1(5) ?
Au1 P1 C7 C12 . . . . -171.7(4) ?
C12 C7 C8 C9 . . . . -0.3(9) ?
P1 C7 C8 C9 . . . . 179.4(5) ?
C7 C8 C9 C10 . . . . 1.6(10) ?
C8 C9 C10 C11 . . . . -2.3(10) ?
C9 C10 C11 C12 . . . . 1.9(11) ?
C10 C11 C12 C7 . . . . -0.6(10) ?
C8 C7 C12 C11 . . . . -0.2(9) ?
P1 C7 C12 C11 . . . . -179.9(5) ?
C7 P1 C13 C14 . . . . 155.6(4) ?
C1 P1 C13 C14 . . . . -93.8(5) ?
Au1 P1 C13 C14 . . . . 31.5(5) ?
C7 P1 C13 C17 . . . . -26.9(6) ?
C1 P1 C13 C17 . . . . 83.7(5) ?
Au1 P1 C13 C17 . . . . -151.1(4) ?
C7 P1 C13 Fe . . . . 67.4(4) ?
C1 P1 C13 Fe . . . . 178.1(3) ?
Au1 P1 C13 Fe . . . . -56.7(4) ?
C18 Fe C13 C14 . . . . 144.5(18) ?
C22 Fe C13 C14 . . . . -51.6(5) ?
C15 Fe C13 C14 . . . . 38.1(3) ?
C19 Fe C13 C14 . . . . -172.6(3) ?
C17 Fe C13 C14 . . . . 118.5(5) ?
C16 Fe C13 C14 . . . . 81.6(4) ?
C20 Fe C13 C14 . . . . -132.2(3) ?
C21 Fe C13 C14 . . . . -88.8(4) ?
C18 Fe C13 C17 . . . . 26(2) ?
C22 Fe C13 C17 . . . . -170.1(4) ?
C14 Fe C13 C17 . . . . -118.5(5) ?
C15 Fe C13 C17 . . . . -80.4(4) ?
C19 Fe C13 C17 . . . . 68.9(4) ?
C16 Fe C13 C17 . . . . -36.9(4) ?
C20 Fe C13 C17 . . . . 109.3(4) ?
C21 Fe C13 C17 . . . . 152.8(3) ?
C18 Fe C13 P1 . . . . -99.3(18) ?
C22 Fe C13 P1 . . . . 64.6(6) ?
C14 Fe C13 P1 . . . . 116.2(5) ?
C15 Fe C13 P1 . . . . 154.3(4) ?
C19 Fe C13 P1 . . . . -56.4(5) ?
C17 Fe C13 P1 . . . . -125.3(5) ?
C16 Fe C13 P1 . . . . -162.2(4) ?
C20 Fe C13 P1 . . . . -16.0(4) ?
C21 Fe C13 P1 . . . . 27.4(5) ?
C17 C13 C14 C15 . . . . 0.3(6) ?
P1 C13 C14 C15 . . . . 178.2(4) ?
Fe C13 C14 C15 . . . . -59.7(4) ?
C17 C13 C14 Fe . . . . 60.0(4) ?
P1 C13 C14 Fe . . . . -122.1(4) ?
C18 Fe C14 C15 . . . . -55.0(5) ?
C22 Fe C14 C15 . . . . -90.8(4) ?
C13 Fe C14 C15 . . . . 118.5(5) ?
C19 Fe C14 C15 . . . . 168.8(18) ?
C17 Fe C14 C15 . . . . 80.3(4) ?
C16 Fe C14 C15 . . . . 37.0(4) ?
C20 Fe C14 C15 . . . . -170.7(3) ?
C21 Fe C14 C15 . . . . -133.6(4) ?
C18 Fe C14 C13 . . . . -173.5(3) ?
C22 Fe C14 C13 . . . . 150.7(3) ?
C15 Fe C14 C13 . . . . -118.5(5) ?
C19 Fe C14 C13 . . . . 50(2) ?
C17 Fe C14 C13 . . . . -38.3(3) ?
C16 Fe C14 C13 . . . . -81.5(4) ?
C20 Fe C14 C13 . . . . 70.8(4) ?
C21 Fe C14 C13 . . . . 107.9(3) ?
C13 C14 C15 C16 . . . . 0.2(6) ?
Fe C14 C15 C16 . . . . -59.4(4) ?
C13 C14 C15 Fe . . . . 59.6(4) ?
C18 Fe C15 C16 . . . . -91.3(4) ?
C22 Fe C15 C16 . . . . -135.5(3) ?
C14 Fe C15 C16 . . . . 120.1(5) ?
C13 Fe C15 C16 . . . . 81.8(4) ?
C19 Fe C15 C16 . . . . -57.6(5) ?
C17 Fe C15 C16 . . . . 37.4(3) ?
C20 Fe C15 C16 . . . . 169.2(13) ?
C21 Fe C15 C16 . . . . -173.2(3) ?
C18 Fe C15 C14 . . . . 148.6(3) ?
C22 Fe C15 C14 . . . . 104.5(4) ?
C13 Fe C15 C14 . . . . -38.3(3) ?
C19 Fe C15 C14 . . . . -177.6(4) ?
C17 Fe C15 C14 . . . . -82.6(4) ?
C16 Fe C15 C14 . . . . -120.1(5) ?
C20 Fe C15 C14 . . . . 49.2(16) ?
C21 Fe C15 C14 . . . . 66.7(4) ?
C14 C15 C16 C17 . . . . -0.6(6) ?
Fe C15 C16 C17 . . . . -59.5(4) ?
C14 C15 C16 Fe . . . . 58.9(4) ?
C18 Fe C16 C17 . . . . -136.2(3) ?
C22 Fe C16 C17 . . . . -176.8(3) ?
C14 Fe C16 C17 . . . . 81.8(4) ?
C13 Fe C16 C17 . . . . 37.6(3) ?
C15 Fe C16 C17 . . . . 119.2(5) ?
C19 Fe C16 C17 . . . . -92.5(4) ?
C20 Fe C16 C17 . . . . -57.6(6) ?
C21 Fe C16 C17 . . . . 151.5(12) ?
C18 Fe C16 C15 . . . . 104.6(3) ?
C22 Fe C16 C15 . . . . 64.0(4) ?
C14 Fe C16 C15 . . . . -37.4(3) ?
C13 Fe C16 C15 . . . . -81.6(3) ?
C19 Fe C16 C15 . . . . 148.3(3) ?
C17 Fe C16 C15 . . . . -119.2(5) ?
C20 Fe C16 C15 . . . . -176.8(4) ?
C21 Fe C16 C15 . . . . 32.3(15) ?
C15 C16 C17 C13 . . . . 0.7(6) ?
Fe C16 C17 C13 . . . . -58.4(4) ?
C15 C16 C17 Fe . . . . 59.2(4) ?
C14 C13 C17 C16 . . . . -0.6(6) ?
P1 C13 C17 C16 . . . . -178.4(4) ?
Fe C13 C17 C16 . . . . 59.0(4) ?
C14 C13 C17 Fe . . . . -59.6(4) ?
P1 C13 C17 Fe . . . . 122.6(5) ?
C18 Fe C17 C16 . . . . 64.0(5) ?
C22 Fe C17 C16 . . . . 16.7(18) ?
C14 Fe C17 C16 . . . . -81.7(4) ?
C13 Fe C17 C16 . . . . -120.0(5) ?
C15 Fe C17 C16 . . . . -37.6(4) ?
C19 Fe C17 C16 . . . . 105.6(4) ?
C20 Fe C17 C16 . . . . 150.0(4) ?
C21 Fe C17 C16 . . . . -171.4(4) ?
C18 Fe C17 C13 . . . . -176.1(3) ?
C22 Fe C17 C13 . . . . 136.6(15) ?
C14 Fe C17 C13 . . . . 38.2(3) ?
C15 Fe C17 C13 . . . . 82.4(4) ?
C19 Fe C17 C13 . . . . -134.4(3) ?
C16 Fe C17 C13 . . . . 120.0(5) ?
C20 Fe C17 C13 . . . . -90.0(4) ?
C21 Fe C17 C13 . . . . -51.5(6) ?
C29 P2 C18 C19 . . . . -21.3(5) ?
C23 P2 C18 C19 . . . . 89.1(5) ?
Au2 P2 C18 C19 . . . . -149.5(4) ?
C29 P2 C18 C22 . . . . 160.9(4) ?
C23 P2 C18 C22 . . . . -88.7(4) ?
Au2 P2 C18 C22 . . . . 32.6(5) ?
C29 P2 C18 Fe . . . . 73.3(4) ?
C23 P2 C18 Fe . . . . -176.4(3) ?
Au2 P2 C18 Fe . . . . -55.0(4) ?
C22 Fe C18 C19 . . . . -118.2(4) ?
C14 Fe C18 C19 . . . . -172.7(4) ?
C13 Fe C18 C19 . . . . 47.8(19) ?
C15 Fe C18 C19 . . . . 151.6(3) ?
C17 Fe C18 C19 . . . . 71.1(4) ?
C16 Fe C18 C19 . . . . 108.7(4) ?
C20 Fe C18 C19 . . . . -37.9(3) ?
C21 Fe C18 C19 . . . . -81.1(3) ?
C14 Fe C18 C22 . . . . -54.5(5) ?
C13 Fe C18 C22 . . . . 166.0(18) ?
C15 Fe C18 C22 . . . . -90.2(4) ?
C19 Fe C18 C22 . . . . 118.2(4) ?
C17 Fe C18 C22 . . . . -170.8(3) ?
C16 Fe C18 C22 . . . . -133.1(3) ?
C20 Fe C18 C22 . . . . 80.3(3) ?
C21 Fe C18 C22 . . . . 37.1(3) ?
C22 Fe C18 P2 . . . . 116.2(5) ?
C14 Fe C18 P2 . . . . 61.6(5) ?
C13 Fe C18 P2 . . . . -77.8(19) ?
C15 Fe C18 P2 . . . . 26.0(4) ?
C19 Fe C18 P2 . . . . -125.6(5) ?
C17 Fe C18 P2 . . . . -54.6(5) ?
C16 Fe C18 P2 . . . . -17.0(4) ?
C20 Fe C18 P2 . . . . -163.5(4) ?
C21 Fe C18 P2 . . . . 153.3(4) ?
C22 C18 C19 C20 . . . . -0.6(6) ?
P2 C18 C19 C20 . . . . -178.7(4) ?
Fe C18 C19 C20 . . . . 59.5(4) ?
C22 C18 C19 Fe . . . . -60.1(3) ?
P2 C18 C19 Fe . . . . 121.8(4) ?
C22 Fe C19 C18 . . . . 38.9(3) ?
C14 Fe C19 C18 . . . . 141.9(19) ?
C13 Fe C19 C18 . . . . -173.2(3) ?
C15 Fe C19 C18 . . . . -51.1(5) ?
C17 Fe C19 C18 . . . . -132.2(3) ?
C16 Fe C19 C18 . . . . -88.5(4) ?
C20 Fe C19 C18 . . . . 118.8(5) ?
C21 Fe C19 C18 . . . . 82.3(3) ?
C18 Fe C19 C20 . . . . -118.8(5) ?
C22 Fe C19 C20 . . . . -79.9(4) ?
C14 Fe C19 C20 . . . . 23(2) ?
C13 Fe C19 C20 . . . . 68.0(4) ?
C15 Fe C19 C20 . . . . -169.9(4) ?
C17 Fe C19 C20 . . . . 109.0(4) ?
C16 Fe C19 C20 . . . . 152.7(3) ?
C21 Fe C19 C20 . . . . -36.5(3) ?
C18 C19 C20 C21 . . . . 0.4(6) ?
Fe C19 C20 C21 . . . . 58.8(4) ?
C18 C19 C20 Fe . . . . -58.4(4) ?
C18 Fe C20 C21 . . . . -82.5(3) ?
C22 Fe C20 C21 . . . . -37.4(3) ?
C14 Fe C20 C21 . . . . 63.0(4) ?
C13 Fe C20 C21 . . . . 104.5(3) ?
C15 Fe C20 C21 . . . . 20.6(16) ?
C19 Fe C20 C21 . . . . -120.7(5) ?
C17 Fe C20 C21 . . . . 149.1(3) ?
C16 Fe C20 C21 . . . . -172.8(4) ?
C18 Fe C20 C19 . . . . 38.2(3) ?
C22 Fe C20 C19 . . . . 83.2(4) ?
C14 Fe C20 C19 . . . . -176.3(3) ?
C13 Fe C20 C19 . . . . -134.8(3) ?
C15 Fe C20 C19 . . . . 141.2(14) ?
C17 Fe C20 C19 . . . . -90.2(4) ?
C16 Fe C20 C19 . . . . -52.1(6) ?
C21 Fe C20 C19 . . . . 120.7(5) ?
C19 C20 C21 C22 . . . . 0.0(6) ?
Fe C20 C21 C22 . . . . 58.3(4) ?
C19 C20 C21 Fe . . . . -58.3(4) ?
C18 Fe C21 C22 . . . . -38.3(3) ?
C14 Fe C21 C22 . . . . 103.8(4) ?
C13 Fe C21 C22 . . . . 147.3(3) ?
C15 Fe C21 C22 . . . . 64.7(4) ?
C19 Fe C21 C22 . . . . -82.5(3) ?
C17 Fe C21 C22 . . . . -178.2(4) ?
C16 Fe C21 C22 . . . . 37.2(15) ?
C20 Fe C21 C22 . . . . -119.5(5) ?
C18 Fe C21 C20 . . . . 81.2(3) ?
C22 Fe C21 C20 . . . . 119.5(5) ?
C14 Fe C21 C20 . . . . -136.7(3) ?
C13 Fe C21 C20 . . . . -93.1(4) ?
C15 Fe C21 C20 . . . . -175.8(3) ?
C19 Fe C21 C20 . . . . 37.1(3) ?
C17 Fe C21 C20 . . . . -58.6(6) ?
C16 Fe C21 C20 . . . . 156.8(12) ?
C20 C21 C22 C18 . . . . -0.4(6) ?
Fe C21 C22 C18 . . . . 58.7(4) ?
C20 C21 C22 Fe . . . . -59.1(4) ?
C19 C18 C22 C21 . . . . 0.6(6) ?
P2 C18 C22 C21 . . . . 178.9(4) ?
Fe C18 C22 C21 . . . . -60.2(4) ?
C19 C18 C22 Fe . . . . 60.8(3) ?
P2 C18 C22 Fe . . . . -120.9(4) ?
C18 Fe C22 C21 . . . . 119.5(5) ?
C14 Fe C22 C21 . . . . -91.6(4) ?
C13 Fe C22 C21 . . . . -57.8(5) ?
C15 Fe C22 C21 . . . . -134.8(3) ?
C19 Fe C22 C21 . . . . 81.2(4) ?
C17 Fe C22 C21 . . . . 173.4(15) ?
C16 Fe C22 C21 . . . . -172.3(3) ?
C20 Fe C22 C21 . . . . 37.3(3) ?
C14 Fe C22 C18 . . . . 149.0(3) ?
C13 Fe C22 C18 . . . . -177.3(4) ?
C15 Fe C22 C18 . . . . 105.8(3) ?
C19 Fe C22 C18 . . . . -38.3(3) ?
C17 Fe C22 C18 . . . . 53.9(17) ?
C16 Fe C22 C18 . . . . 68.3(4) ?
C20 Fe C22 C18 . . . . -82.2(3) ?
C21 Fe C22 C18 . . . . -119.5(5) ?
C18 P2 C23 C24 . . . . 174.6(4) ?
C29 P2 C23 C24 . . . . -72.5(5) ?
Au2 P2 C23 C24 . . . . 52.6(5) ?
C18 P2 C23 C28 . . . . -2.1(5) ?
C29 P2 C23 C28 . . . . 110.9(5) ?
Au2 P2 C23 C28 . . . . -124.0(4) ?
C28 C23 C24 C25 . . . . -0.7(8) ?
P2 C23 C24 C25 . . . . -177.4(4) ?
C23 C24 C25 C26 . . . . -1.0(9) ?
C24 C25 C26 C27 . . . . 2.5(9) ?
C25 C26 C27 C28 . . . . -2.4(9) ?
C26 C27 C28 C23 . . . . 0.8(9) ?
C24 C23 C28 C27 . . . . 0.8(8) ?
P2 C23 C28 C27 . . . . 177.4(4) ?
C18 P2 C29 C30 . . . . 63.6(5) ?
C23 P2 C29 C30 . . . . -46.9(5) ?
Au2 P2 C29 C30 . . . . -169.7(4) ?
C18 P2 C29 C34 . . . . -118.7(4) ?
C23 P2 C29 C34 . . . . 130.8(4) ?
Au2 P2 C29 C34 . . . . 8.0(5) ?
C34 C29 C30 C31 . . . . 0.5(9) ?
P2 C29 C30 C31 . . . . 178.2(5) ?
C29 C30 C31 C32 . . . . -1.2(9) ?
C30 C31 C32 C33 . . . . 0.3(10) ?
C31 C32 C33 C34 . . . . 1.2(10) ?
C32 C33 C34 C29 . . . . -1.9(9) ?
C30 C29 C34 C33 . . . . 1.1(8) ?
P2 C29 C34 C33 . . . . -176.6(4) ?
C36 C36 C37 C38 2_667 . . . 178.6(7) ?
