#------------------------------------------------------------------------------
#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/51/2225124.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/. The original data for this entry
# were provided by IUCr Journals, http://journals.iucr.org/.
#
# The file may be used within the scientific community so long as
# proper attribution is given to the journal article from which the
# data were obtained.
#
data_2225124
loop_
_publ_author_name
'bin Shawkataly, Omar'
'Khan, Imthyaz Ahmed'
'Yeap, Chin Sing'
'Fun, Hoong-Kun'
_publ_section_title
;[μ-Bis(diphenylarsino)methane-1:2κ²As:As'][bis(4-methoxyphenyl)phenylphosphine-3κP]-nonacarbonyl-1κ³C,2κ³C,3κ³C-triangulo-triruthenium(0)
 dichloromethane 0.15-solvate
;
_journal_coeditor_code           TK2608
_journal_issue                   2
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m225
_journal_page_last               m226
_journal_paper_doi               10.1107/S1600536810001194
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac
'[Ru3 (C25 H22 As2) (C20 H19 O2 P) (C O)9], 0.15C H2  Cl2'
_chemical_formula_moiety         'C54 H41 As2 O11 P Ru3, 0.15(C H2 Cl2)'
_chemical_formula_sum            'C54.15 H41.3 As2 Cl0.3 O11 P Ru3'
_chemical_formula_weight         1362.63
_chemical_name_systematic
;[μ-Bis(diphenylarsino)methane-1:2κ²As:As'][bis(4-
methoxyphenyl)phenylphosphine-3κP]nonacarbonyl-
1κ³C,2κ³C,3κ³C--triangulo-triruthenium(0)
dichloromethane
 0.15-solvate
;
_space_group_IT_number           14
_symmetry_cell_setting           monoclinic
_symmetry_space_group_name_Hall  '-P 2ybc'
_symmetry_space_group_name_H-M   'P 1 21/c 1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                90
_cell_angle_beta                 93.293(2)
_cell_angle_gamma                90
_cell_formula_units_Z            4
_cell_length_a                   13.3723(4)
_cell_length_b                   16.9461(6)
_cell_length_c                   25.0956(8)
_cell_measurement_reflns_used    9029
_cell_measurement_temperature    296(2)
_cell_measurement_theta_max      27.7
_cell_measurement_theta_min      2.5
_cell_volume                     5677.5(3)
_computing_cell_refinement       'SAINT (Bruker, 2005)'
_computing_data_collection       'APEX2 (Bruker, 2005)'
_computing_data_reduction        'SAINT (Bruker, 2005)'
_computing_molecular_graphics    'SHELXTL (Sheldrick, 2008)'
_computing_publication_material
;
SHELXTL (Sheldrick, 2008) and PLATON (Spek, 2009)
;
_computing_structure_refinement  'SHELXTL (Sheldrick, 2008)'
_computing_structure_solution    'SHELXTL (Sheldrick, 2008)'
_diffrn_ambient_temperature      296(2)
_diffrn_measured_fraction_theta_full 0.998
_diffrn_measured_fraction_theta_max 0.998
_diffrn_measurement_device_type
;
Bruker SMART APEXII CCD area-detector diffractometer
;
_diffrn_measurement_method       'φ and ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71073
_diffrn_reflns_av_R_equivalents  0.041
_diffrn_reflns_av_sigmaI/netI    0.054
_diffrn_reflns_limit_h_max       13
_diffrn_reflns_limit_h_min       -18
_diffrn_reflns_limit_k_max       23
_diffrn_reflns_limit_k_min       -23
_diffrn_reflns_limit_l_max       35
_diffrn_reflns_limit_l_min       -35
_diffrn_reflns_number            67215
_diffrn_reflns_theta_full        30.0
_diffrn_reflns_theta_max         30.0
_diffrn_reflns_theta_min         2.0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    2.042
_exptl_absorpt_correction_T_max  0.741
_exptl_absorpt_correction_T_min  0.571
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(SADABS; Bruker, 2005)'
_exptl_crystal_colour            purple
_exptl_crystal_density_diffrn    1.594
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       block
_exptl_crystal_F_000             2689
_exptl_crystal_size_max          0.31
_exptl_crystal_size_mid          0.21
_exptl_crystal_size_min          0.16
_refine_diff_density_max         1.00
_refine_diff_density_min         -0.38
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.02
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     654
_refine_ls_number_reflns         16557
_refine_ls_number_restraints     3
_refine_ls_restrained_S_all      1.02
_refine_ls_R_factor_all          0.081
_refine_ls_R_factor_gt           0.039
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0631P)²+0.2919P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.105
_refine_ls_wR_factor_ref         0.121
_reflns_number_gt                10503
_reflns_number_total             16557
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            tk2608.cif
_cod_data_source_block           I
_cod_depositor_comments
;
The following automatic conversions were performed:
'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to '/home/saulius/struct/CIF-dictionaries/cif_core.dic'
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_enum 1527 2010-12-29 10:47:43Z saulius 

The following automatic conversions were performed:

'_symmetry_cell_setting' value 'Monoclinic' changed to 'monoclinic'
according to /home/saulius/struct/CIF-dictionaries/cif_core.dic
dictionary named 'cif_core.dic' version 2.4.1 from 2010-06-29.

Automatic conversion script
Id: cif_fix_values 1715 2011-07-08 13:25:40Z adriana 
;
_cod_original_sg_symbol_H-M      'P 21/c'
_cod_original_formula_sum        'C54.15 H41.30 As2 Cl0.30 O11 P Ru3'
_cod_database_code               2225124
_cod_database_fobs_code          2225124
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, y+1/2, -z+1/2'
'-x, -y, -z'
'x, -y-1/2, z-1/2'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ru Ru1 0.23500(2) 0.681950(18) 0.163442(13) 0.03901(9) Uani d . 1 . .
Ru Ru2 0.04906(2) 0.755091(17) 0.183146(11) 0.03391(8) Uani d . 1 . .
Ru Ru3 0.19523(2) 0.842925(18) 0.130875(12) 0.03573(8) Uani d . 1 . .
As As1 0.16685(3) 0.55179(2) 0.182877(16) 0.03808(10) Uani d . 1 . .
As As2 -0.01950(3) 0.64684(2) 0.233294(14) 0.03357(9) Uani d . 1 . .
P P1 0.31142(7) 0.91113(6) 0.08118(4) 0.0403(2) Uani d . 1 . .
O O1 0.2778(3) 0.6974(2) 0.28428(14) 0.0720(10) Uani d . 1 . .
O O2 0.4536(3) 0.6481(3) 0.1507(2) 0.130(2) Uani d . 1 . .
O O3 0.1941(3) 0.6619(2) 0.04285(14) 0.0723(10) Uani d . 1 . .
O O4 -0.0261(2) 0.6678(2) 0.08212(13) 0.0656(9) Uani d . 1 . .
O O5 -0.1248(3) 0.8700(2) 0.17369(18) 0.0905(13) Uani d . 1 . .
O O6 0.1308(3) 0.8404(2) 0.28432(14) 0.0721(10) Uani d . 1 . .
O O7 0.3531(2) 0.84785(18) 0.22408(14) 0.0652(9) Uani d . 1 . .
O O8 0.0740(2) 0.98639(19) 0.15749(14) 0.0685(9) Uani d . 1 . .
O O9 0.0639(3) 0.8144(2) 0.02844(14) 0.0824(11) Uani d . 1 . .
O O10 0.6764(3) 0.7311(2) 0.02742(18) 0.1004(14) Uani d . 1 . .
O O11 0.4740(3) 1.2156(2) 0.17242(16) 0.0889(12) Uani d . 1 . .
C C1 0.2580(3) 0.4723(2) 0.21440(17) 0.0481(10) Uani d . 1 . .
C C2 0.2382(4) 0.3932(3) 0.2083(2) 0.0716(15) Uani d . 1 . .
H H2A 0.1811 0.3768 0.1884 0.086 Uiso calc R 1 . .
C C3 0.3043(5) 0.3369(3) 0.2320(3) 0.0911(19) Uani d . 1 . .
H H3A 0.2912 0.2833 0.2277 0.109 Uiso calc R 1 . .
C C4 0.3878(4) 0.3614(4) 0.2614(3) 0.094(2) Uani d . 1 . .
H H4A 0.4324 0.3245 0.2765 0.112 Uiso calc R 1 . .
C C5 0.4054(4) 0.4390(4) 0.2683(3) 0.101(2) Uani d . 1 . .
H H5A 0.4611 0.4555 0.2893 0.121 Uiso calc R 1 . .
C C6 0.3409(4) 0.4949(3) 0.2445(2) 0.0832(17) Uani d . 1 . .
H H6A 0.3546 0.5483 0.2492 0.100 Uiso calc R 1 . .
C C7 0.1002(3) 0.4924(2) 0.12512(16) 0.0477(10) Uani d . 1 . .
C C8 0.0060(4) 0.4655(3) 0.1258(2) 0.0788(16) Uani d . 1 . .
H H8A -0.0306 0.4763 0.1554 0.095 Uiso calc R 1 . .
C C9 -0.0385(5) 0.4225(5) 0.0844(3) 0.113(3) Uani d . 1 . .
H H9A -0.1046 0.4060 0.0859 0.136 Uiso calc R 1 . .
C C10 0.0131(6) 0.4048(4) 0.0424(3) 0.105(2) Uani d . 1 . .
H H10A -0.0160 0.3736 0.0152 0.126 Uiso calc R 1 . .
C C11 0.1077(7) 0.4316(4) 0.0389(2) 0.106(2) Uani d . 1 . .
H H11A 0.1429 0.4208 0.0088 0.127 Uiso calc R 1 . .
C C12 0.1522(5) 0.4761(3) 0.0812(2) 0.0844(17) Uani d . 1 . .
H H12A 0.2174 0.4946 0.0792 0.101 Uiso calc R 1 . .
C C13 0.0702(3) 0.5543(2) 0.23829(14) 0.0378(8) Uani d . 1 . .
H H13A 0.1063 0.5544 0.2730 0.045 Uiso calc R 1 . .
H H13B 0.0300 0.5067 0.2358 0.045 Uiso calc R 1 . .
C C14 -0.1491(3) 0.6061(2) 0.20657(14) 0.0384(8) Uani d . 1 . .
C C15 -0.2116(3) 0.6561(3) 0.17702(19) 0.0597(12) Uani d . 1 . .
H H15A -0.1909 0.7071 0.1695 0.072 Uiso calc R 1 . .
C C16 -0.3055(4) 0.6301(3) 0.1586(2) 0.0799(17) Uani d . 1 . .
H H16A -0.3489 0.6643 0.1397 0.096 Uiso calc R 1 . .
C C17 -0.3347(3) 0.5534(3) 0.1682(2) 0.0675(14) Uani d . 1 . .
H H17A -0.3968 0.5355 0.1546 0.081 Uiso calc R 1 . .
C C18 -0.2734(3) 0.5047(3) 0.19719(19) 0.0577(11) Uani d . 1 . .
H H18A -0.2935 0.4533 0.2039 0.069 Uiso calc R 1 . .
C C19 -0.1803(3) 0.5312(2) 0.21701(17) 0.0479(10) Uani d . 1 . .
H H19A -0.1388 0.4976 0.2376 0.057 Uiso calc R 1 . .
C C20 -0.0419(3) 0.6665(2) 0.30814(15) 0.0383(8) Uani d . 1 . .
C C21 -0.1360(3) 0.6711(3) 0.32606(18) 0.0564(12) Uani d . 1 . .
H H21A -0.1911 0.6639 0.3022 0.068 Uiso calc R 1 . .
C C22 -0.1508(4) 0.6862(4) 0.3791(2) 0.0784(16) Uani d . 1 . .
H H22A -0.2154 0.6891 0.3909 0.094 Uiso calc R 1 . .
C C23 -0.0700(4) 0.6968(4) 0.4144(2) 0.0810(17) Uani d . 1 . .
H H23A -0.0796 0.7069 0.4501 0.097 Uiso calc R 1 . .
C C24 0.0267(4) 0.6923(4) 0.39655(19) 0.0748(16) Uani d . 1 . .
H H24A 0.0822 0.6998 0.4201 0.090 Uiso calc R 1 . .
C C25 0.0384(3) 0.6768(3) 0.34356(17) 0.0580(12) Uani d . 1 . .
H H25A 0.1028 0.6732 0.3315 0.070 Uiso calc R 1 . .
C C26 0.2623(3) 0.9403(3) 0.01425(16) 0.0484(10) Uani d . 1 . .
C C27 0.3035(4) 0.9174(3) -0.03199(19) 0.0682(13) Uani d . 1 . .
H H27A 0.3594 0.8846 -0.0300 0.082 Uiso calc R 1 . .
C C28 0.2647(6) 0.9414(4) -0.0815(2) 0.0913(19) Uani d . 1 . .
H H28A 0.2957 0.9266 -0.1122 0.110 Uiso calc R 1 . .
C C29 0.1814(6) 0.9865(4) -0.0850(2) 0.096(2) Uani d . 1 . .
H H29A 0.1535 1.0009 -0.1184 0.115 Uiso calc R 1 . .
C C30 0.1369(4) 1.0116(4) -0.0392(3) 0.0881(19) Uani d . 1 . .
H H30A 0.0808 1.0442 -0.0419 0.106 Uiso calc R 1 . .
C C31 0.1770(4) 0.9876(3) 0.0106(2) 0.0669(13) Uani d . 1 . .
H H31A 0.1469 1.0031 0.0414 0.080 Uiso calc R 1 . .
C C32 0.4268(3) 0.8588(3) 0.06829(16) 0.0464(10) Uani d . 1 . .
C C33 0.5216(3) 0.8901(3) 0.07825(19) 0.0596(12) Uani d . 1 . .
H H33A 0.5285 0.9400 0.0934 0.072 Uiso calc R 1 . .
C C34 0.6064(3) 0.8484(3) 0.0661(2) 0.0695(14) Uani d . 1 . .
H H34A 0.6694 0.8702 0.0737 0.083 Uiso calc R 1 . .
C C35 0.5986(4) 0.7757(3) 0.0429(2) 0.0675(14) Uani d . 1 . .
C C36 0.5044(4) 0.7428(3) 0.0333(2) 0.0720(15) Uani d . 1 . .
H H36A 0.4984 0.6928 0.0182 0.086 Uiso calc R 1 . .
C C37 0.4195(4) 0.7835(3) 0.0458(2) 0.0640(13) Uani d . 1 . .
H H37A 0.3569 0.7605 0.0393 0.077 Uiso calc R 1 . .
C C38 0.3562(3) 1.0063(2) 0.10750(16) 0.0452(10) Uani d . 1 . .
C C39 0.3977(3) 1.0620(3) 0.07448(18) 0.0556(11) Uani d . 1 . .
H H39A 0.3988 1.0519 0.0381 0.067 Uiso calc R 1 . .
C C40 0.4374(4) 1.1319(3) 0.0945(2) 0.0633(13) Uani d . 1 . .
H H40A 0.4650 1.1679 0.0716 0.076 Uiso calc R 1 . .
C C41 0.4363(3) 1.1487(3) 0.1486(2) 0.0590(12) Uani d . 1 . .
C C42 0.3933(3) 1.0958(3) 0.18175(19) 0.0580(12) Uani d . 1 . .
H H42A 0.3904 1.1071 0.2179 0.070 Uiso calc R 1 . .
C C43 0.3542(3) 1.0254(3) 0.16138(17) 0.0530(11) Uani d . 1 . .
H H43A 0.3257 0.9900 0.1844 0.064 Uiso calc R 1 . .
C C44 0.2585(3) 0.6956(2) 0.2394(2) 0.0509(10) Uani d . 1 . .
C C45 0.3716(4) 0.6611(3) 0.1550(2) 0.0701(14) Uani d . 1 . .
C C46 0.2049(3) 0.6743(3) 0.0874(2) 0.0514(11) Uani d . 1 . .
C C47 0.0074(3) 0.7000(3) 0.11873(16) 0.0449(9) Uani d . 1 . .
C C48 -0.0595(3) 0.8263(3) 0.17773(19) 0.0528(11) Uani d . 1 . .
C C49 0.1048(3) 0.8074(3) 0.24627(17) 0.0478(10) Uani d . 1 . .
C C50 0.2913(3) 0.8388(2) 0.19054(17) 0.0446(9) Uani d . 1 . .
C C51 0.1216(3) 0.9336(3) 0.14699(16) 0.0457(10) Uani d . 1 . .
C C52 0.1119(3) 0.8218(3) 0.06718(18) 0.0513(10) Uani d . 1 . .
C C53 0.7717(5) 0.7646(5) 0.0315(3) 0.130(3) Uani d . 1 . .
H H53A 0.8198 0.7272 0.0198 0.195 Uiso calc R 1 . .
H H53B 0.7884 0.7788 0.0680 0.195 Uiso calc R 1 . .
H H53C 0.7727 0.8110 0.0095 0.195 Uiso calc R 1 . .
C C54 0.5152(6) 1.2734(4) 0.1412(3) 0.118(3) Uani d . 1 . .
H H54A 0.5435 1.3144 0.1638 0.177 Uiso calc R 1 . .
H H54B 0.4639 1.2952 0.1172 0.177 Uiso calc R 1 . .
H H54C 0.5667 1.2505 0.1210 0.177 Uiso calc R 1 . .
Cl Cl1 0.4479(13) 0.4905(11) 0.0404(6) 0.172(6) Uiso d PD 0.15 . .
Cl Cl2 0.3550(14) 0.5807(10) -0.0494(6) 0.174(7) Uiso d PD 0.15 . .
C C55 0.372(2) 0.4939(10) -0.0163(10) 0.083(11) Uiso d PD 0.15 . .
H H55A 0.3065 0.4752 -0.0073 0.100 Uiso calc PR 0.15 . .
H H55B 0.3977 0.4562 -0.0411 0.100 Uiso calc PR 0.15 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
P P 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Cl Cl 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
As As 0.0499 2.0058 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ru Ru -1.2594 0.8363 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
C45 Ru1 C44 . . 91.7(2) ?
C45 Ru1 C46 . . 91.4(2) ?
C44 Ru1 C46 . . 175.99(18) ?
C45 Ru1 As1 . . 103.17(16) ?
C44 Ru1 As1 . . 87.29(13) ?
C46 Ru1 As1 . . 94.46(13) ?
C45 Ru1 Ru2 . . 164.40(17) ?
C44 Ru1 Ru2 . . 82.56(13) ?
C46 Ru1 Ru2 . . 93.79(12) ?
As1 Ru1 Ru2 . . 91.080(14) ?
C45 Ru1 Ru3 . . 108.02(16) ?
C44 Ru1 Ru3 . . 100.56(13) ?
C46 Ru1 Ru3 . . 76.06(13) ?
As1 Ru1 Ru3 . . 147.496(16) ?
Ru2 Ru1 Ru3 . . 59.304(10) ?
C48 Ru2 C47 . . 93.72(19) ?
C48 Ru2 C49 . . 91.44(19) ?
C47 Ru2 C49 . . 174.09(17) ?
C48 Ru2 As2 . . 102.00(13) ?
C47 Ru2 As2 . . 88.23(12) ?
C49 Ru2 As2 . . 93.51(12) ?
C48 Ru2 Ru3 . . 100.32(13) ?
C47 Ru2 Ru3 . . 92.30(12) ?
C49 Ru2 Ru3 . . 83.93(12) ?
As2 Ru2 Ru3 . . 157.589(16) ?
C48 Ru2 Ru1 . . 160.42(13) ?
C47 Ru2 Ru1 . . 81.75(11) ?
C49 Ru2 Ru1 . . 92.43(12) ?
As2 Ru2 Ru1 . . 96.913(14) ?
Ru3 Ru2 Ru1 . . 61.075(11) ?
C51 Ru3 C50 . . 101.40(17) ?
C51 Ru3 C52 . . 92.56(18) ?
C50 Ru3 C52 . . 165.87(18) ?
C51 Ru3 P1 . . 94.76(12) ?
C50 Ru3 P1 . . 89.91(12) ?
C52 Ru3 P1 . . 91.12(13) ?
C51 Ru3 Ru2 . . 86.89(12) ?
C50 Ru3 Ru2 . . 93.93(12) ?
C52 Ru3 Ru2 . . 84.57(12) ?
P1 Ru3 Ru2 . . 175.45(3) ?
C51 Ru3 Ru1 . . 143.17(12) ?
C50 Ru3 Ru1 . . 68.93(12) ?
C52 Ru3 Ru1 . . 98.49(13) ?
P1 Ru3 Ru1 . . 119.86(3) ?
Ru2 Ru3 Ru1 . . 59.621(10) ?
C7 As1 C13 . . 104.42(17) ?
C7 As1 C1 . . 101.18(18) ?
C13 As1 C1 . . 98.61(16) ?
C7 As1 Ru1 . . 118.67(12) ?
C13 As1 Ru1 . . 113.06(11) ?
C1 As1 Ru1 . . 118.13(13) ?
C20 As2 C14 . . 102.10(15) ?
C20 As2 C13 . . 101.59(15) ?
C14 As2 C13 . . 105.44(16) ?
C20 As2 Ru2 . . 116.95(11) ?
C14 As2 Ru2 . . 116.29(11) ?
C13 As2 Ru2 . . 112.70(11) ?
C32 P1 C38 . . 103.28(19) ?
C32 P1 C26 . . 103.33(19) ?
C38 P1 C26 . . 100.68(19) ?
C32 P1 Ru3 . . 116.51(14) ?
C38 P1 Ru3 . . 117.01(13) ?
C26 P1 Ru3 . . 113.89(13) ?
C35 O10 C53 . . 117.6(5) ?
C41 O11 C54 . . 119.2(5) ?
C6 C1 C2 . . 118.8(4) ?
C6 C1 As1 . . 120.1(3) ?
C2 C1 As1 . . 121.1(3) ?
C1 C2 C3 . . 120.1(5) ?
C1 C2 H2A . . 119.9 ?
C3 C2 H2A . . 119.9 ?
C4 C3 C2 . . 119.7(5) ?
C4 C3 H3A . . 120.2 ?
C2 C3 H3A . . 120.2 ?
C5 C4 C3 . . 119.9(5) ?
C5 C4 H4A . . 120.1 ?
C3 C4 H4A . . 120.1 ?
C4 C5 C6 . . 120.6(6) ?
C4 C5 H5A . . 119.7 ?
C6 C5 H5A . . 119.7 ?
C1 C6 C5 . . 120.9(5) ?
C1 C6 H6A . . 119.6 ?
C5 C6 H6A . . 119.6 ?
C8 C7 C12 . . 117.7(5) ?
C8 C7 As1 . . 124.0(3) ?
C12 C7 As1 . . 118.3(4) ?
C7 C8 C9 . . 122.5(5) ?
C7 C8 H8A . . 118.8 ?
C9 C8 H8A . . 118.8 ?
C10 C9 C8 . . 119.8(7) ?
C10 C9 H9A . . 120.1 ?
C8 C9 H9A . . 120.1 ?
C9 C10 C11 . . 120.4(6) ?
C9 C10 H10A . . 119.8 ?
C11 C10 H10A . . 119.8 ?
C10 C11 C12 . . 119.3(6) ?
C10 C11 H11A . . 120.4 ?
C12 C11 H11A . . 120.4 ?
C7 C12 C11 . . 120.3(6) ?
C7 C12 H12A . . 119.9 ?
C11 C12 H12A . . 119.9 ?
As1 C13 As2 . . 113.38(17) ?
As1 C13 H13A . . 108.9 ?
As2 C13 H13A . . 108.9 ?
As1 C13 H13B . . 108.9 ?
As2 C13 H13B . . 108.9 ?
H13A C13 H13B . . 107.7 ?
C19 C14 C15 . . 119.5(4) ?
C19 C14 As2 . . 122.5(3) ?
C15 C14 As2 . . 117.9(3) ?
C14 C15 C16 . . 119.7(4) ?
C14 C15 H15A . . 120.1 ?
C16 C15 H15A . . 120.1 ?
C17 C16 C15 . . 120.0(5) ?
C17 C16 H16A . . 120.0 ?
C15 C16 H16A . . 120.0 ?
C18 C17 C16 . . 120.1(4) ?
C18 C17 H17A . . 120.0 ?
C16 C17 H17A . . 120.0 ?
C17 C18 C19 . . 120.1(4) ?
C17 C18 H18A . . 120.0 ?
C19 C18 H18A . . 120.0 ?
C14 C19 C18 . . 120.6(4) ?
C14 C19 H19A . . 119.7 ?
C18 C19 H19A . . 119.7 ?
C21 C20 C25 . . 119.0(4) ?
C21 C20 As2 . . 121.6(3) ?
C25 C20 As2 . . 119.4(3) ?
C20 C21 C22 . . 121.0(4) ?
C20 C21 H21A . . 119.5 ?
C22 C21 H21A . . 119.5 ?
C23 C22 C21 . . 119.7(5) ?
C23 C22 H22A . . 120.2 ?
C21 C22 H22A . . 120.2 ?
C22 C23 C24 . . 119.9(5) ?
C22 C23 H23A . . 120.0 ?
C24 C23 H23A . . 120.0 ?
C25 C24 C23 . . 118.7(5) ?
C25 C24 H24A . . 120.7 ?
C23 C24 H24A . . 120.7 ?
C20 C25 C24 . . 121.7(4) ?
C20 C25 H25A . . 119.1 ?
C24 C25 H25A . . 119.1 ?
C27 C26 C31 . . 118.4(4) ?
C27 C26 P1 . . 123.9(4) ?
C31 C26 P1 . . 117.7(3) ?
C26 C27 C28 . . 122.0(5) ?
C26 C27 H27A . . 119.0 ?
C28 C27 H27A . . 119.0 ?
C29 C28 C27 . . 119.5(6) ?
C29 C28 H28A . . 120.3 ?
C27 C28 H28A . . 120.3 ?
C28 C29 C30 . . 120.7(6) ?
C28 C29 H29A . . 119.7 ?
C30 C29 H29A . . 119.7 ?
C29 C30 C31 . . 119.4(6) ?
C29 C30 H30A . . 120.3 ?
C31 C30 H30A . . 120.3 ?
C26 C31 C30 . . 120.0(5) ?
C26 C31 H31A . . 120.0 ?
C30 C31 H31A . . 120.0 ?
C33 C32 C37 . . 117.7(4) ?
C33 C32 P1 . . 123.9(4) ?
C37 C32 P1 . . 118.4(3) ?
C32 C33 C34 . . 121.2(5) ?
C32 C33 H33A . . 119.4 ?
C34 C33 H33A . . 119.4 ?
C35 C34 C33 . . 120.7(5) ?
C35 C34 H34A . . 119.6 ?
C33 C34 H34A . . 119.6 ?
O10 C35 C34 . . 125.6(5) ?
O10 C35 C36 . . 115.4(5) ?
C34 C35 C36 . . 119.0(4) ?
C37 C36 C35 . . 120.7(5) ?
C37 C36 H36A . . 119.7 ?
C35 C36 H36A . . 119.7 ?
C36 C37 C32 . . 120.7(5) ?
C36 C37 H37A . . 119.7 ?
C32 C37 H37A . . 119.7 ?
C43 C38 C39 . . 116.8(4) ?
C43 C38 P1 . . 122.1(3) ?
C39 C38 P1 . . 121.1(3) ?
C40 C39 C38 . . 121.5(4) ?
C40 C39 H39A . . 119.2 ?
C38 C39 H39A . . 119.2 ?
C39 C40 C41 . . 120.5(4) ?
C39 C40 H40A . . 119.8 ?
C41 C40 H40A . . 119.8 ?
O11 C41 C42 . . 115.8(5) ?
O11 C41 C40 . . 125.0(4) ?
C42 C41 C40 . . 119.2(4) ?
C41 C42 C43 . . 120.1(4) ?
C41 C42 H42A . . 120.0 ?
C43 C42 H42A . . 120.0 ?
C42 C43 C38 . . 122.0(4) ?
C42 C43 H43A . . 119.0 ?
C38 C43 H43A . . 119.0 ?
O1 C44 Ru1 . . 173.5(4) ?
O2 C45 Ru1 . . 178.9(5) ?
O3 C46 Ru1 . . 171.8(4) ?
O4 C47 Ru2 . . 173.7(4) ?
O5 C48 Ru2 . . 178.8(4) ?
O6 C49 Ru2 . . 174.8(4) ?
O7 C50 Ru3 . . 169.5(3) ?
O8 C51 Ru3 . . 177.2(4) ?
O9 C52 Ru3 . . 175.4(4) ?
O10 C53 H53A . . 109.5 ?
O10 C53 H53B . . 109.5 ?
H53A C53 H53B . . 109.5 ?
O10 C53 H53C . . 109.5 ?
H53A C53 H53C . . 109.5 ?
H53B C53 H53C . . 109.5 ?
O11 C54 H54A . . 109.5 ?
O11 C54 H54B . . 109.5 ?
H54A C54 H54B . . 109.5 ?
O11 C54 H54C . . 109.5 ?
H54A C54 H54C . . 109.5 ?
H54B C54 H54C . . 109.5 ?
Cl1 C55 Cl2 . . 119.77(11) ?
Cl1 C55 H55A . . 107.4 ?
Cl2 C55 H55A . . 107.4 ?
Cl1 C55 H55B . . 107.4 ?
Cl2 C55 H55B . . 107.4 ?
H55A C55 H55B . . 106.9 ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ru1 C45 . 1.884(5) ?
Ru1 C44 . 1.929(5) ?
Ru1 C46 . 1.931(5) ?
Ru1 As1 . 2.4463(5) ?
Ru1 Ru2 . 2.8469(4) ?
Ru1 Ru3 . 2.8883(4) ?
Ru2 C48 . 1.887(4) ?
Ru2 C47 . 1.921(4) ?
Ru2 C49 . 1.928(5) ?
Ru2 As2 . 2.4335(5) ?
Ru2 Ru3 . 2.8376(4) ?
Ru3 C51 . 1.881(5) ?
Ru3 C50 . 1.918(4) ?
Ru3 C52 . 1.929(5) ?
Ru3 P1 . 2.3511(10) ?
As1 C7 . 1.940(4) ?
As1 C13 . 1.952(3) ?
As1 C1 . 1.953(4) ?
As2 C20 . 1.948(4) ?
As2 C14 . 1.949(4) ?
As2 C13 . 1.974(4) ?
P1 C32 . 1.824(4) ?
P1 C38 . 1.830(4) ?
P1 C26 . 1.836(4) ?
O1 C44 . 1.140(5) ?
O2 C45 . 1.130(5) ?
O3 C46 . 1.140(5) ?
O4 C47 . 1.138(5) ?
O5 C48 . 1.145(5) ?
O6 C49 . 1.143(5) ?
O7 C50 . 1.155(5) ?
O8 C51 . 1.138(5) ?
O9 C52 . 1.140(5) ?
O10 C35 . 1.361(6) ?
O10 C53 . 1.394(8) ?
O11 C41 . 1.364(5) ?
O11 C54 . 1.388(7) ?
C1 C6 . 1.359(6) ?
C1 C2 . 1.373(6) ?
C2 C3 . 1.410(7) ?
C2 H2A . 0.9300 ?
C3 C4 . 1.366(8) ?
C3 H3A . 0.9300 ?
C4 C5 . 1.346(8) ?
C4 H4A . 0.9300 ?
C5 C6 . 1.392(7) ?
C5 H5A . 0.9300 ?
C6 H6A . 0.9300 ?
C7 C8 . 1.340(6) ?
C7 C12 . 1.365(6) ?
C8 C9 . 1.375(7) ?
C8 H8A . 0.9300 ?
C9 C10 . 1.329(9) ?
C9 H9A . 0.9300 ?
C10 C11 . 1.351(10) ?
C10 H10A . 0.9300 ?
C11 C12 . 1.406(8) ?
C11 H11A . 0.9300 ?
C12 H12A . 0.9300 ?
C13 H13A . 0.9700 ?
C13 H13B . 0.9700 ?
C14 C19 . 1.367(5) ?
C14 C15 . 1.376(5) ?
C15 C16 . 1.385(6) ?
C15 H15A . 0.9300 ?
C16 C17 . 1.382(7) ?
C16 H16A . 0.9300 ?
C17 C18 . 1.347(6) ?
C17 H17A . 0.9300 ?
C18 C19 . 1.389(6) ?
C18 H18A . 0.9300 ?
C19 H19A . 0.9300 ?
C20 C21 . 1.363(5) ?
C20 C25 . 1.365(6) ?
C21 C22 . 1.382(6) ?
C21 H21A . 0.9300 ?
C22 C23 . 1.368(7) ?
C22 H22A . 0.9300 ?
C23 C24 . 1.395(7) ?
C23 H23A . 0.9300 ?
C24 C25 . 1.374(6) ?
C24 H24A . 0.9300 ?
C25 H25A . 0.9300 ?
C26 C27 . 1.369(6) ?
C26 C31 . 1.392(6) ?
C27 C28 . 1.380(7) ?
C27 H27A . 0.9300 ?
C28 C29 . 1.350(9) ?
C28 H28A . 0.9300 ?
C29 C30 . 1.390(8) ?
C29 H29A . 0.9300 ?
C30 C31 . 1.393(7) ?
C30 H30A . 0.9300 ?
C31 H31A . 0.9300 ?
C32 C33 . 1.383(6) ?
C32 C37 . 1.396(6) ?
C33 C34 . 1.386(6) ?
C33 H33A . 0.9300 ?
C34 C35 . 1.363(7) ?
C34 H34A . 0.9300 ?
C35 C36 . 1.386(8) ?
C36 C37 . 1.380(7) ?
C36 H36A . 0.9300 ?
C37 H37A . 0.9300 ?
C38 C43 . 1.392(6) ?
C38 C39 . 1.393(5) ?
C39 C40 . 1.381(6) ?
C39 H39A . 0.9300 ?
C40 C41 . 1.388(7) ?
C40 H40A . 0.9300 ?
C41 C42 . 1.370(6) ?
C42 C43 . 1.388(6) ?
C42 H42A . 0.9300 ?
C43 H43A . 0.9300 ?
C53 H53A . 0.9600 ?
C53 H53B . 0.9600 ?
C53 H53C . 0.9600 ?
C54 H54A . 0.9600 ?
C54 H54B . 0.9600 ?
C54 H54C . 0.9600 ?
Cl1 C55 . 1.6995(10) ?
Cl2 C55 . 1.6995(10) ?
C55 H55A . 0.9700 ?
C55 H55B . 0.9700 ?
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
C45 Ru1 Ru2 C48 . . . . 57.4(7) ?
C44 Ru1 Ru2 C48 . . . . 126.5(5) ?
C46 Ru1 Ru2 C48 . . . . -51.8(5) ?
As1 Ru1 Ru2 C48 . . . . -146.4(4) ?
Ru3 Ru1 Ru2 C48 . . . . 19.5(4) ?
C45 Ru1 Ru2 C47 . . . . 135.2(6) ?
C44 Ru1 Ru2 C47 . . . . -155.73(18) ?
C46 Ru1 Ru2 C47 . . . . 25.94(18) ?
As1 Ru1 Ru2 C47 . . . . -68.60(12) ?
Ru3 Ru1 Ru2 C47 . . . . 97.27(12) ?
C45 Ru1 Ru2 C49 . . . . -43.8(6) ?
C44 Ru1 Ru2 C49 . . . . 25.30(17) ?
C46 Ru1 Ru2 C49 . . . . -153.03(18) ?
As1 Ru1 Ru2 C49 . . . . 112.42(12) ?
Ru3 Ru1 Ru2 C49 . . . . -81.71(12) ?
C45 Ru1 Ru2 As2 . . . . -137.6(6) ?
C44 Ru1 Ru2 As2 . . . . -68.54(13) ?
C46 Ru1 Ru2 As2 . . . . 113.14(13) ?
As1 Ru1 Ru2 As2 . . . . 18.590(17) ?
Ru3 Ru1 Ru2 As2 . . . . -175.538(16) ?
C45 Ru1 Ru2 Ru3 . . . . 38.0(6) ?
C44 Ru1 Ru2 Ru3 . . . . 107.00(13) ?
C46 Ru1 Ru2 Ru3 . . . . -71.33(13) ?
As1 Ru1 Ru2 Ru3 . . . . -165.872(17) ?
C48 Ru2 Ru3 C51 . . . . 22.56(19) ?
C47 Ru2 Ru3 C51 . . . . 116.77(17) ?
C49 Ru2 Ru3 C51 . . . . -67.80(18) ?
As2 Ru2 Ru3 C51 . . . . -152.28(13) ?
Ru1 Ru2 Ru3 C51 . . . . -163.97(12) ?
C48 Ru2 Ru3 C50 . . . . 123.78(19) ?
C47 Ru2 Ru3 C50 . . . . -142.01(17) ?
C49 Ru2 Ru3 C50 . . . . 33.42(18) ?
As2 Ru2 Ru3 C50 . . . . -51.06(13) ?
Ru1 Ru2 Ru3 C50 . . . . -62.74(12) ?
C48 Ru2 Ru3 C52 . . . . -70.3(2) ?
C47 Ru2 Ru3 C52 . . . . 23.89(18) ?
C49 Ru2 Ru3 C52 . . . . -160.67(19) ?
As2 Ru2 Ru3 C52 . . . . 114.85(14) ?
Ru1 Ru2 Ru3 C52 . . . . 103.16(14) ?
C48 Ru2 Ru3 Ru1 . . . . -173.47(15) ?
C47 Ru2 Ru3 Ru1 . . . . -79.27(12) ?
C49 Ru2 Ru3 Ru1 . . . . 96.17(13) ?
As2 Ru2 Ru3 Ru1 . . . . 11.69(4) ?
C45 Ru1 Ru3 C51 . . . . -142.6(3) ?
C44 Ru1 Ru3 C51 . . . . -47.3(2) ?
C46 Ru1 Ru3 C51 . . . . 130.5(2) ?
As1 Ru1 Ru3 C51 . . . . 54.4(2) ?
Ru2 Ru1 Ru3 C51 . . . . 27.4(2) ?
C45 Ru1 Ru3 C50 . . . . -61.9(2) ?
C44 Ru1 Ru3 C50 . . . . 33.41(18) ?
C46 Ru1 Ru3 C50 . . . . -148.79(19) ?
As1 Ru1 Ru3 C50 . . . . 135.12(13) ?
Ru2 Ru1 Ru3 C50 . . . . 108.11(13) ?
C45 Ru1 Ru3 C52 . . . . 111.5(2) ?
C44 Ru1 Ru3 C52 . . . . -153.26(19) ?
C46 Ru1 Ru3 C52 . . . . 24.54(19) ?
As1 Ru1 Ru3 C52 . . . . -51.54(14) ?
Ru2 Ru1 Ru3 C52 . . . . -78.55(13) ?
C45 Ru1 Ru3 P1 . . . . 15.24(18) ?
C44 Ru1 Ru3 P1 . . . . 110.52(13) ?
C46 Ru1 Ru3 P1 . . . . -71.68(13) ?
As1 Ru1 Ru3 P1 . . . . -147.77(4) ?
Ru2 Ru1 Ru3 P1 . . . . -174.78(3) ?
C45 Ru1 Ru3 Ru2 . . . . -169.99(18) ?
C44 Ru1 Ru3 Ru2 . . . . -74.71(13) ?
C46 Ru1 Ru3 Ru2 . . . . 103.10(13) ?
As1 Ru1 Ru3 Ru2 . . . . 27.01(3) ?
C45 Ru1 As1 C7 . . . . -97.8(2) ?
C44 Ru1 As1 C7 . . . . 171.09(19) ?
C46 Ru1 As1 C7 . . . . -5.30(19) ?
Ru2 Ru1 As1 C7 . . . . 88.58(14) ?
Ru3 Ru1 As1 C7 . . . . 65.59(15) ?
C45 Ru1 As1 C13 . . . . 139.4(2) ?
C44 Ru1 As1 C13 . . . . 48.32(17) ?
C46 Ru1 As1 C13 . . . . -128.08(17) ?
Ru2 Ru1 As1 C13 . . . . -34.19(12) ?
Ru3 Ru1 As1 C13 . . . . -57.18(12) ?
C45 Ru1 As1 C1 . . . . 25.1(2) ?
C44 Ru1 As1 C1 . . . . -66.02(19) ?
C46 Ru1 As1 C1 . . . . 117.59(19) ?
Ru2 Ru1 As1 C1 . . . . -148.53(14) ?
Ru3 Ru1 As1 C1 . . . . -171.52(14) ?
C48 Ru2 As2 C20 . . . . -70.3(2) ?
C47 Ru2 As2 C20 . . . . -163.71(17) ?
C49 Ru2 As2 C20 . . . . 21.94(18) ?
Ru3 Ru2 As2 C20 . . . . 104.53(13) ?
Ru1 Ru2 As2 C20 . . . . 114.82(13) ?
C48 Ru2 As2 C14 . . . . 50.62(19) ?
C47 Ru2 As2 C14 . . . . -42.82(17) ?
C49 Ru2 As2 C14 . . . . 142.84(18) ?
Ru3 Ru2 As2 C14 . . . . -134.58(13) ?
Ru1 Ru2 As2 C14 . . . . -124.29(12) ?
C48 Ru2 As2 C13 . . . . 172.52(19) ?
C47 Ru2 As2 C13 . . . . 79.09(16) ?
C49 Ru2 As2 C13 . . . . -95.26(17) ?
Ru3 Ru2 As2 C13 . . . . -12.67(13) ?
Ru1 Ru2 As2 C13 . . . . -2.38(12) ?
C51 Ru3 P1 C32 . . . . 163.9(2) ?
C50 Ru3 P1 C32 . . . . 62.4(2) ?
C52 Ru3 P1 C32 . . . . -103.5(2) ?
Ru1 Ru3 P1 C32 . . . . -3.02(17) ?
C51 Ru3 P1 C38 . . . . 41.01(19) ?
C50 Ru3 P1 C38 . . . . -60.42(19) ?
C52 Ru3 P1 C38 . . . . 133.7(2) ?
Ru1 Ru3 P1 C38 . . . . -125.87(15) ?
C51 Ru3 P1 C26 . . . . -75.9(2) ?
C50 Ru3 P1 C26 . . . . -177.4(2) ?
C52 Ru3 P1 C26 . . . . 16.7(2) ?
Ru1 Ru3 P1 C26 . . . . 117.18(16) ?
C7 As1 C1 C6 . . . . 158.3(4) ?
C13 As1 C1 C6 . . . . -95.0(4) ?
Ru1 As1 C1 C6 . . . . 27.0(5) ?
C7 As1 C1 C2 . . . . -23.9(4) ?
C13 As1 C1 C2 . . . . 82.7(4) ?
Ru1 As1 C1 C2 . . . . -155.3(4) ?
C6 C1 C2 C3 . . . . -1.3(8) ?
As1 C1 C2 C3 . . . . -179.1(4) ?
C1 C2 C3 C4 . . . . 0.3(10) ?
C2 C3 C4 C5 . . . . 1.4(11) ?
C3 C4 C5 C6 . . . . -2.0(11) ?
C2 C1 C6 C5 . . . . 0.7(9) ?
As1 C1 C6 C5 . . . . 178.5(5) ?
C4 C5 C6 C1 . . . . 1.0(11) ?
C13 As1 C7 C8 . . . . 3.4(5) ?
C1 As1 C7 C8 . . . . 105.5(4) ?
Ru1 As1 C7 C8 . . . . -123.5(4) ?
C13 As1 C7 C12 . . . . -176.0(4) ?
C1 As1 C7 C12 . . . . -73.9(4) ?
Ru1 As1 C7 C12 . . . . 57.0(4) ?
C12 C7 C8 C9 . . . . 0.3(9) ?
As1 C7 C8 C9 . . . . -179.1(5) ?
C7 C8 C9 C10 . . . . 1.7(11) ?
C8 C9 C10 C11 . . . . -3.0(12) ?
C9 C10 C11 C12 . . . . 2.4(12) ?
C8 C7 C12 C11 . . . . -1.0(8) ?
As1 C7 C12 C11 . . . . 178.5(5) ?
C10 C11 C12 C7 . . . . -0.4(10) ?
C7 As1 C13 As2 . . . . -90.9(2) ?
C1 As1 C13 As2 . . . . 165.1(2) ?
Ru1 As1 C13 As2 . . . . 39.4(2) ?
C20 As2 C13 As1 . . . . -147.17(19) ?
C14 As2 C13 As1 . . . . 106.6(2) ?
Ru2 As2 C13 As1 . . . . -21.2(2) ?
C20 As2 C14 C19 . . . . -75.6(3) ?
C13 As2 C14 C19 . . . . 30.2(4) ?
Ru2 As2 C14 C19 . . . . 155.8(3) ?
C20 As2 C14 C15 . . . . 103.0(3) ?
C13 As2 C14 C15 . . . . -151.2(3) ?
Ru2 As2 C14 C15 . . . . -25.5(4) ?
C19 C14 C15 C16 . . . . 0.5(7) ?
As2 C14 C15 C16 . . . . -178.2(4) ?
C14 C15 C16 C17 . . . . -2.3(8) ?
C15 C16 C17 C18 . . . . 2.4(9) ?
C16 C17 C18 C19 . . . . -0.7(8) ?
C15 C14 C19 C18 . . . . 1.3(6) ?
As2 C14 C19 C18 . . . . 179.9(3) ?
C17 C18 C19 C14 . . . . -1.2(7) ?
C14 As2 C20 C21 . . . . -17.1(4) ?
C13 As2 C20 C21 . . . . -125.9(4) ?
Ru2 As2 C20 C21 . . . . 111.0(3) ?
C14 As2 C20 C25 . . . . 163.7(3) ?
C13 As2 C20 C25 . . . . 54.9(4) ?
Ru2 As2 C20 C25 . . . . -68.2(4) ?
C25 C20 C21 C22 . . . . 0.2(7) ?
As2 C20 C21 C22 . . . . -179.0(4) ?
C20 C21 C22 C23 . . . . 0.0(9) ?
C21 C22 C23 C24 . . . . 0.0(10) ?
C22 C23 C24 C25 . . . . -0.4(9) ?
C21 C20 C25 C24 . . . . -0.6(7) ?
As2 C20 C25 C24 . . . . 178.7(4) ?
C23 C24 C25 C20 . . . . 0.7(8) ?
C32 P1 C26 C27 . . . . 6.0(4) ?
C38 P1 C26 C27 . . . . 112.6(4) ?
Ru3 P1 C26 C27 . . . . -121.3(4) ?
C32 P1 C26 C31 . . . . -175.1(4) ?
C38 P1 C26 C31 . . . . -68.5(4) ?
Ru3 P1 C26 C31 . . . . 57.6(4) ?
C31 C26 C27 C28 . . . . 1.8(8) ?
P1 C26 C27 C28 . . . . -179.3(4) ?
C26 C27 C28 C29 . . . . -2.5(9) ?
C27 C28 C29 C30 . . . . 2.7(10) ?
C28 C29 C30 C31 . . . . -2.2(10) ?
C27 C26 C31 C30 . . . . -1.3(7) ?
P1 C26 C31 C30 . . . . 179.8(4) ?
C29 C30 C31 C26 . . . . 1.5(8) ?
C38 P1 C32 C33 . . . . 0.5(4) ?
C26 P1 C32 C33 . . . . 105.0(4) ?
Ru3 P1 C32 C33 . . . . -129.3(3) ?
C38 P1 C32 C37 . . . . -177.9(3) ?
C26 P1 C32 C37 . . . . -73.3(4) ?
Ru3 P1 C32 C37 . . . . 52.4(4) ?
C37 C32 C33 C34 . . . . 0.4(7) ?
P1 C32 C33 C34 . . . . -177.9(4) ?
C32 C33 C34 C35 . . . . 1.2(8) ?
C53 O10 C35 C34 . . . . -5.4(8) ?
C53 O10 C35 C36 . . . . 174.0(5) ?
C33 C34 C35 O10 . . . . 177.3(5) ?
C33 C34 C35 C36 . . . . -2.1(8) ?
O10 C35 C36 C37 . . . . -178.1(5) ?
C34 C35 C36 C37 . . . . 1.3(8) ?
C35 C36 C37 C32 . . . . 0.3(8) ?
C33 C32 C37 C36 . . . . -1.2(7) ?
P1 C32 C37 C36 . . . . 177.3(4) ?
C32 P1 C38 C43 . . . . -106.0(4) ?
C26 P1 C38 C43 . . . . 147.4(4) ?
Ru3 P1 C38 C43 . . . . 23.4(4) ?
C32 P1 C38 C39 . . . . 71.5(4) ?
C26 P1 C38 C39 . . . . -35.1(4) ?
Ru3 P1 C38 C39 . . . . -159.1(3) ?
C43 C38 C39 C40 . . . . 1.7(7) ?
P1 C38 C39 C40 . . . . -175.9(4) ?
C38 C39 C40 C41 . . . . -0.4(7) ?
C54 O11 C41 C42 . . . . -177.5(6) ?
C54 O11 C41 C40 . . . . 1.5(8) ?
C39 C40 C41 O11 . . . . 179.5(5) ?
C39 C40 C41 C42 . . . . -1.4(7) ?
O11 C41 C42 C43 . . . . -179.1(4) ?
C40 C41 C42 C43 . . . . 1.8(7) ?
C41 C42 C43 C38 . . . . -0.4(7) ?
C39 C38 C43 C42 . . . . -1.3(6) ?
P1 C38 C43 C42 . . . . 176.3(3) ?
C51 Ru3 C50 O7 . . . . -57(2) ?
C52 Ru3 C50 O7 . . . . 132.2(19) ?
P1 Ru3 C50 O7 . . . . 38(2) ?
Ru2 Ru3 C50 O7 . . . . -144(2) ?
Ru1 Ru3 C50 O7 . . . . 160(2) ?
