#------------------------------------------------------------------------------
#$Date: 2016-02-14 16:26:36 +0200 (Sun, 14 Feb 2016) $
#$Revision: 176435 $
#$URL: svn://www.crystallography.net/cod/cif/2/22/79/2227916.cif $
#------------------------------------------------------------------------------
#
# This file is available in the Crystallography Open Database (COD),
# http://www.crystallography.net/
#
# All data on this site have been placed in the public domain by the
# contributors.
#
data_2227916
loop_
_publ_author_name
'Arman, Hadi D.'
'Miller, Tyler'
'Poplaukhin, Pavel'
'Tiekink, Edward R. T.'
_publ_section_title
;
 Poly[[bis[μ₂-N,N'-bis(2-pyridylmethyl)oxalamide-κ⁴N,O:N',O'][μ₂-N,N'-bis(2-pyridylmethyl)oxalamide-κ²N:N']disilver(I)]
 bis(trifluoromethanesulfonate)]
;
_journal_coeditor_code           PV2322
_journal_issue                   9
_journal_name_full               'Acta Crystallographica Section E'
_journal_page_first              m1167
_journal_page_last               m1168
_journal_paper_doi               10.1107/S1600536810033611
_journal_volume                  66
_journal_year                    2010
_chemical_formula_iupac          '[Ag (C14 H14 N4 O2)1.5] (C F3 S O3)'
_chemical_formula_moiety         'C21 H21 Ag N6 O3 +, C F3 O3 S -'
_chemical_formula_sum            'C22 H21 Ag F3 N6 O6 S'
_chemical_formula_weight         662.38
_chemical_name_systematic
;
Poly[[bis[μ₂-N,N'-bis(2-pyridylmethyl)oxalamide-
κ⁴N,O:N',O'][μ₂-N,N'-
bis(2-pyridylmethyl)oxalamide-κ²N:N']disilver(I)]
bis(trifluoromethanesulfonate)]
;
_space_group_IT_number           2
_symmetry_cell_setting           triclinic
_symmetry_space_group_name_Hall  '-P 1'
_symmetry_space_group_name_H-M   'P -1'
_atom_sites_solution_hydrogens   geom
_atom_sites_solution_primary     direct
_atom_sites_solution_secondary   difmap
_audit_creation_method           SHELXL-97
_cell_angle_alpha                95.9770(10)
_cell_angle_beta                 105.948(2)
_cell_angle_gamma                107.017(3)
_cell_formula_units_Z            2
_cell_length_a                   8.7242(14)
_cell_length_b                   11.1762(17)
_cell_length_c                   14.210(2)
_cell_measurement_reflns_used    5470
_cell_measurement_temperature    98(2)
_cell_measurement_theta_max      40.5
_cell_measurement_theta_min      2.7
_cell_volume                     1247.9(3)
_computing_cell_refinement
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_collection
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_data_reduction
'CrystalClear (Molecular Structure Corporation & Rigaku, 2005)'
_computing_molecular_graphics
'ORTEP-3 (Farrugia, 1997) and DIAMOND (Brandenburg, 2006)'
_computing_publication_material  'publCIF (Westrip, 2010)'
_computing_structure_refinement  'SHELXL97 (Sheldrick, 2008)'
_computing_structure_solution    'SHELXS97 (Sheldrick, 2008)'
_diffrn_ambient_temperature      98(2)
_diffrn_measured_fraction_theta_full 0.992
_diffrn_measured_fraction_theta_max 0.992
_diffrn_measurement_device_type  'Rigaku AFC12Κ/SATURN724'
_diffrn_measurement_method       'ω scans'
_diffrn_radiation_monochromator  graphite
_diffrn_radiation_source         'fine-focus sealed tube'
_diffrn_radiation_type           MoK\a
_diffrn_radiation_wavelength     0.71069
_diffrn_reflns_av_R_equivalents  0.029
_diffrn_reflns_av_sigmaI/netI    0.043
_diffrn_reflns_limit_h_max       11
_diffrn_reflns_limit_h_min       -11
_diffrn_reflns_limit_k_max       14
_diffrn_reflns_limit_k_min       -14
_diffrn_reflns_limit_l_max       10
_diffrn_reflns_limit_l_min       -18
_diffrn_reflns_number            10177
_diffrn_reflns_theta_full        27.5
_diffrn_reflns_theta_max         27.5
_diffrn_reflns_theta_min         2.0
_diffrn_standards_decay_%        '< 1'
_diffrn_standards_interval_count 0
_diffrn_standards_number         0
_exptl_absorpt_coefficient_mu    0.966
_exptl_absorpt_correction_T_max  1.000
_exptl_absorpt_correction_T_min  0.868
_exptl_absorpt_correction_type   multi-scan
_exptl_absorpt_process_details   '(ABSCOR; Higashi, 1995)'
_exptl_crystal_colour            colourless
_exptl_crystal_density_diffrn    1.763
_exptl_crystal_density_method    'not measured'
_exptl_crystal_description       plate
_exptl_crystal_F_000             666
_exptl_crystal_size_max          0.36
_exptl_crystal_size_mid          0.32
_exptl_crystal_size_min          0.18
_refine_diff_density_max         0.67
_refine_diff_density_min         -1.05
_refine_ls_extinction_method     none
_refine_ls_goodness_of_fit_ref   1.05
_refine_ls_hydrogen_treatment    constr
_refine_ls_matrix_type           full
_refine_ls_number_parameters     352
_refine_ls_number_reflns         5688
_refine_ls_number_restraints     0
_refine_ls_restrained_S_all      1.05
_refine_ls_R_factor_all          0.036
_refine_ls_R_factor_gt           0.034
_refine_ls_shift/su_max          0.001
_refine_ls_shift/su_mean         0.000
_refine_ls_structure_factor_coef Fsqd
_refine_ls_weighting_details
'calc w=1/[σ²(Fo²)+(0.0295P)²+1.3977P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme      calc
_refine_ls_wR_factor_gt          0.077
_refine_ls_wR_factor_ref         0.079
_reflns_number_gt                5438
_reflns_number_total             5688
_reflns_threshold_expression     I>2σ(I)
_cod_data_source_file            pv2322.cif
_cod_data_source_block           I
_cod_original_formula_sum        'C22 H21 Ag F3 N6 O6 S '
_cod_database_code               2227916
_cod_database_fobs_code          2227916
loop_
_symmetry_equiv_pos_as_xyz
'x, y, z'
'-x, -y, -z'
loop_
_atom_site_type_symbol
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_U_iso_or_equiv
_atom_site_adp_type
_atom_site_calc_flag
_atom_site_refinement_flags
_atom_site_occupancy
_atom_site_disorder_assembly
_atom_site_disorder_group
Ag Ag 0.18992(2) 0.789941(17) 0.198313(13) 0.01680(6) Uani d . 1 . .
S S1 0.83484(8) 0.26442(7) 0.26813(5) 0.02348(14) Uani d . 1 . .
F F1 0.6446(3) 0.3310(3) 0.36252(17) 0.0586(6) Uani d . 1 . .
F F2 0.8906(4) 0.4736(2) 0.39309(18) 0.0663(7) Uani d . 1 . .
F F3 0.8647(3) 0.3038(2) 0.45763(14) 0.0527(6) Uani d . 1 . .
O O1 -0.1034(2) 0.56970(17) 0.06781(14) 0.0230(4) Uani d . 1 . .
O O2 0.4189(2) 0.89384(17) 0.38477(13) 0.0210(4) Uani d . 1 . .
O O3 0.5809(2) 0.65495(16) 0.47965(13) 0.0180(3) Uani d . 1 . .
O O4 0.7817(3) 0.3298(2) 0.18909(16) 0.0330(5) Uani d . 1 . .
O O5 0.7255(2) 0.1362(2) 0.25641(17) 0.0346(5) Uani d . 1 . .
O O6 1.0141(2) 0.28246(18) 0.29925(16) 0.0284(4) Uani d . 1 . .
N N1 0.2257(3) 0.8994(2) 0.06692(15) 0.0171(4) Uani d . 1 . .
N N2 0.0110(3) 0.63965(19) -0.05116(15) 0.0183(4) Uani d . 1 . .
H H2N 0.0695 0.6247 -0.0898 0.022 Uiso calc R 1 . .
N N3 0.0373(3) 0.8513(2) 0.28181(15) 0.0178(4) Uani d . 1 . .
N N4 0.3734(3) 1.07931(19) 0.42923(15) 0.0162(4) Uani d . 1 . .
H H4N 0.4058 1.1475 0.4765 0.019 Uiso calc R 1 . .
N N5 0.3388(2) 0.65910(18) 0.18415(15) 0.0148(4) Uani d . 1 . .
N N6 0.3291(3) 0.49849(19) 0.39599(15) 0.0166(4) Uani d . 1 . .
H H6N 0.2627 0.4214 0.3942 0.020 Uiso calc R 1 . .
C C1 0.3585(3) 1.0079(2) 0.09336(19) 0.0203(5) Uani d . 1 . .
H H1 0.4419 1.0246 0.1568 0.024 Uiso calc R 1 . .
C C2 0.3804(3) 1.0972(2) 0.0328(2) 0.0229(5) Uani d . 1 . .
H H2 0.4757 1.1735 0.0545 0.028 Uiso calc R 1 . .
C C3 0.2598(4) 1.0721(3) -0.0599(2) 0.0257(6) Uani d . 1 . .
H H3 0.2707 1.1308 -0.1035 0.031 Uiso calc R 1 . .
C C4 0.1235(3) 0.9603(2) -0.08807(19) 0.0219(5) Uani d . 1 . .
H H4 0.0394 0.9414 -0.1516 0.026 Uiso calc R 1 . .
C C5 0.1091(3) 0.8756(2) -0.02376(18) 0.0177(5) Uani d . 1 . .
C C6 -0.0395(3) 0.7529(2) -0.0529(2) 0.0210(5) Uani d . 1 . .
H H6A -0.1056 0.7548 -0.0066 0.025 Uiso calc R 1 . .
H H6B -0.1140 0.7473 -0.1210 0.025 Uiso calc R 1 . .
C C7 -0.0292(3) 0.5578(2) 0.00759(18) 0.0168(5) Uani d . 1 . .
C C8 -0.1050(3) 0.7645(3) 0.2844(2) 0.0240(5) Uani d . 1 . .
H H8 -0.1325 0.6781 0.2532 0.029 Uiso calc R 1 . .
C C9 -0.2128(3) 0.7952(3) 0.3302(2) 0.0292(6) Uani d . 1 . .
H H9 -0.3111 0.7310 0.3314 0.035 Uiso calc R 1 . .
C C10 -0.1752(3) 0.9210(3) 0.3744(2) 0.0286(6) Uani d . 1 . .
H H10 -0.2494 0.9452 0.4042 0.034 Uiso calc R 1 . .
C C11 -0.0268(3) 1.0114(3) 0.37424(19) 0.0224(5) Uani d . 1 . .
H H11 0.0028 1.0983 0.4049 0.027 Uiso calc R 1 . .
C C12 0.0774(3) 0.9732(2) 0.32879(17) 0.0159(4) Uani d . 1 . .
C C13 0.2458(3) 1.0686(2) 0.33435(17) 0.0173(5) Uani d . 1 . .
H H13A 0.2820 1.0402 0.2783 0.021 Uiso calc R 1 . .
H H13B 0.2335 1.1531 0.3286 0.021 Uiso calc R 1 . .
C C14 0.4416(3) 0.9886(2) 0.44598(17) 0.0155(4) Uani d . 1 . .
C C15 0.4180(3) 0.6709(2) 0.11494(17) 0.0180(5) Uani d . 1 . .
H H15 0.4053 0.7318 0.0741 0.022 Uiso calc R 1 . .
C C16 0.5166(3) 0.5990(2) 0.10053(18) 0.0203(5) Uani d . 1 . .
H H16 0.5752 0.6132 0.0532 0.024 Uiso calc R 1 . .
C C17 0.5288(3) 0.5057(3) 0.15634(19) 0.0237(5) Uani d . 1 . .
H H17 0.5921 0.4522 0.1462 0.028 Uiso calc R 1 . .
C C18 0.4466(3) 0.4921(2) 0.22738(19) 0.0207(5) Uani d . 1 . .
H H18 0.4524 0.4284 0.2663 0.025 Uiso calc R 1 . .
C C19 0.3555(3) 0.5721(2) 0.24127(17) 0.0147(4) Uani d . 1 . .
C C20 0.2721(3) 0.5694(2) 0.32159(17) 0.0167(5) Uani d . 1 . .
H H20A 0.2964 0.6582 0.3552 0.020 Uiso calc R 1 . .
H H20B 0.1480 0.5304 0.2900 0.020 Uiso calc R 1 . .
C C21 0.4798(3) 0.5475(2) 0.46690(17) 0.0152(4) Uani d . 1 . .
C C22 0.8089(5) 0.3483(3) 0.3762(2) 0.0387(7) Uani d . 1 . .
loop_
_atom_type_symbol
_atom_type_description
_atom_type_scat_dispersion_real
_atom_type_scat_dispersion_imag
_atom_type_scat_source
C C 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
H H 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
Ag Ag -0.8971 1.1015 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
N N 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
O O 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
F F 0.0171 0.0103 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
S S 0.1246 0.1234 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
loop_
_geom_angle_atom_site_label_1
_geom_angle_atom_site_label_2
_geom_angle_atom_site_label_3
_geom_angle_site_symmetry_1
_geom_angle_site_symmetry_3
_geom_angle
_geom_angle_publ_flag
N3 Ag N5 . . 145.64(8) ?
N3 Ag N1 . . 114.52(7) ?
N5 Ag N1 . . 99.84(7) ?
N3 Ag O2 . . 77.39(7) ?
N5 Ag O2 . . 86.55(6) ?
N1 Ag O2 . . 117.91(6) ?
N3 Ag O1 . . 92.93(6) ?
N5 Ag O1 . . 84.19(6) ?
N1 Ag O1 . . 94.90(6) ?
O2 Ag O1 . . 146.99(5) ?
O5 S1 O4 . . 115.07(13) ?
O5 S1 O6 . . 115.22(12) ?
O4 S1 O6 . . 114.01(13) ?
O5 S1 C22 . . 102.86(16) ?
O4 S1 C22 . . 104.09(14) ?
O6 S1 C22 . . 103.39(15) ?
C7 O1 Ag . . 91.70(14) ?
C14 O2 Ag . . 131.58(16) ?
C1 N1 C5 . . 117.9(2) ?
C1 N1 Ag . . 115.41(16) ?
C5 N1 Ag . . 125.33(16) ?
C7 N2 C6 . . 121.8(2) ?
C7 N2 H2N . . 119.1 ?
C6 N2 H2N . . 119.1 ?
C8 N3 C12 . . 117.9(2) ?
C8 N3 Ag . . 118.87(18) ?
C12 N3 Ag . . 123.19(16) ?
C14 N4 C13 . . 121.6(2) ?
C14 N4 H4N . . 119.2 ?
C13 N4 H4N . . 119.2 ?
C19 N5 C15 . . 118.4(2) ?
C19 N5 Ag . . 124.21(15) ?
C15 N5 Ag . . 117.34(16) ?
C21 N6 C20 . . 121.6(2) ?
C21 N6 H6N . . 119.2 ?
C20 N6 H6N . . 119.2 ?
N1 C1 C2 . . 123.4(2) ?
N1 C1 H1 . . 118.3 ?
C2 C1 H1 . . 118.3 ?
C3 C2 C1 . . 118.2(2) ?
C3 C2 H2 . . 120.9 ?
C1 C2 H2 . . 120.9 ?
C4 C3 C2 . . 118.8(2) ?
C4 C3 H3 . . 120.6 ?
C2 C3 H3 . . 120.6 ?
C3 C4 C5 . . 120.0(2) ?
C3 C4 H4 . . 120.0 ?
C5 C4 H4 . . 120.0 ?
N1 C5 C4 . . 121.7(2) ?
N1 C5 C6 . . 117.5(2) ?
C4 C5 C6 . . 120.9(2) ?
N2 C6 C5 . . 113.0(2) ?
N2 C6 H6A . . 109.0 ?
C5 C6 H6A . . 109.0 ?
N2 C6 H6B . . 109.0 ?
C5 C6 H6B . . 109.0 ?
H6A C6 H6B . . 107.8 ?
O1 C7 N2 . . 125.9(2) ?
O1 C7 C7 . 2_565 121.7(3) ?
N2 C7 C7 . 2_565 112.3(3) ?
N3 C8 C9 . . 123.0(3) ?
N3 C8 H8 . . 118.5 ?
C9 C8 H8 . . 118.5 ?
C8 C9 C10 . . 118.9(3) ?
C8 C9 H9 . . 120.5 ?
C10 C9 H9 . . 120.5 ?
C9 C10 C11 . . 118.8(2) ?
C9 C10 H10 . . 120.6 ?
C11 C10 H10 . . 120.6 ?
C12 C11 C10 . . 119.1(3) ?
C12 C11 H11 . . 120.4 ?
C10 C11 H11 . . 120.4 ?
N3 C12 C11 . . 122.2(2) ?
N3 C12 C13 . . 118.0(2) ?
C11 C12 C13 . . 119.8(2) ?
N4 C13 C12 . . 109.80(19) ?
N4 C13 H13A . . 109.7 ?
C12 C13 H13A . . 109.7 ?
N4 C13 H13B . . 109.7 ?
C12 C13 H13B . . 109.7 ?
H13A C13 H13B . . 108.2 ?
O2 C14 N4 . . 126.2(2) ?
O2 C14 C14 . 2_676 120.5(3) ?
N4 C14 C14 . 2_676 113.3(3) ?
N5 C15 C16 . . 123.1(2) ?
N5 C15 H15 . . 118.5 ?
C16 C15 H15 . . 118.5 ?
C15 C16 C17 . . 118.8(2) ?
C15 C16 H16 . . 120.6 ?
C17 C16 H16 . . 120.6 ?
C16 C17 C18 . . 118.5(2) ?
C16 C17 H17 . . 120.7 ?
C18 C17 H17 . . 120.7 ?
C17 C18 C19 . . 119.6(2) ?
C17 C18 H18 . . 120.2 ?
C19 C18 H18 . . 120.2 ?
N5 C19 C18 . . 121.4(2) ?
N5 C19 C20 . . 115.7(2) ?
C18 C19 C20 . . 122.9(2) ?
N6 C20 C19 . . 113.0(2) ?
N6 C20 H20A . . 109.0 ?
C19 C20 H20A . . 109.0 ?
N6 C20 H20B . . 109.0 ?
C19 C20 H20B . . 109.0 ?
H20A C20 H20B . . 107.8 ?
O3 C21 N6 . . 125.6(2) ?
O3 C21 C21 . 2_666 121.4(3) ?
N6 C21 C21 . 2_666 113.0(2) ?
F3 C22 F2 . . 109.1(3) ?
F3 C22 F1 . . 106.6(3) ?
F2 C22 F1 . . 107.8(3) ?
F3 C22 S1 . . 111.0(2) ?
F2 C22 S1 . . 111.4(2) ?
F1 C22 S1 . . 110.8(2) ?
loop_
_geom_bond_atom_site_label_1
_geom_bond_atom_site_label_2
_geom_bond_site_symmetry_2
_geom_bond_distance
_geom_bond_publ_flag
Ag N1 . 2.378(2) y
Ag N3 . 2.210(2) y
Ag N5 . 2.250(2) y
Ag O1 . 2.9665(19) y
Ag O2 . 2.7299(17) y
S1 O5 . 1.433(2) ?
S1 O4 . 1.447(2) ?
S1 O6 . 1.4487(19) ?
S1 C22 . 1.818(3) ?
F1 C22 . 1.344(4) ?
F2 C22 . 1.333(4) ?
F3 C22 . 1.333(4) ?
O1 C7 . 1.225(3) ?
O2 C14 . 1.228(3) ?
O3 C21 . 1.225(3) ?
N1 C1 . 1.341(3) ?
N1 C5 . 1.347(3) ?
N2 C7 . 1.337(3) ?
N2 C6 . 1.457(3) ?
N2 H2N . 0.8800 ?
N3 C8 . 1.346(3) ?
N3 C12 . 1.352(3) ?
N4 C14 . 1.329(3) ?
N4 C13 . 1.461(3) ?
N4 H4N . 0.8800 ?
N5 C19 . 1.344(3) ?
N5 C15 . 1.345(3) ?
N6 C21 . 1.334(3) ?
N6 C20 . 1.452(3) ?
N6 H6N . 0.8800 ?
C1 C2 . 1.390(4) ?
C1 H1 . 0.9500 ?
C2 C3 . 1.382(4) ?
C2 H2 . 0.9500 ?
C3 C4 . 1.378(4) ?
C3 H3 . 0.9500 ?
C4 C5 . 1.386(3) ?
C4 H4 . 0.9500 ?
C5 C6 . 1.510(3) ?
C6 H6A . 0.9900 ?
C6 H6B . 0.9900 ?
C7 C7 2_565 1.537(5) ?
C8 C9 . 1.381(4) ?
C8 H8 . 0.9500 ?
C9 C10 . 1.382(4) ?
C9 H9 . 0.9500 ?
C10 C11 . 1.391(4) ?
C10 H10 . 0.9500 ?
C11 C12 . 1.385(3) ?
C11 H11 . 0.9500 ?
C12 C13 . 1.518(3) ?
C13 H13A . 0.9900 ?
C13 H13B . 0.9900 ?
C14 C14 2_676 1.538(5) ?
C15 C16 . 1.376(4) ?
C15 H15 . 0.9500 ?
C16 C17 . 1.386(4) ?
C16 H16 . 0.9500 ?
C17 C18 . 1.387(4) ?
C17 H17 . 0.9500 ?
C18 C19 . 1.392(3) ?
C18 H18 . 0.9500 ?
C19 C20 . 1.511(3) ?
C20 H20A . 0.9900 ?
C20 H20B . 0.9900 ?
C21 C21 2_666 1.543(4) ?
loop_
_geom_hbond_atom_site_label_D
_geom_hbond_atom_site_label_H
_geom_hbond_atom_site_label_A
_geom_hbond_site_symmetry_A
_geom_hbond_distance_DH
_geom_hbond_distance_HA
_geom_hbond_distance_DA
_geom_hbond_angle_DHA
N2 H2n O4 2_665 0.88 2.17 2.992(4) 156
N4 H4n O3 2_676 0.88 2.19 2.980(3) 149
N6 H6n O6 1_455 0.88 2.22 2.936(3) 139
C1 H1 O5 1_565 0.95 2.36 3.197(3) 146
C17 H17 O4 1_555 0.95 2.43 3.334(4) 158
C18 H18 F1 1_555 0.95 2.45 3.261(4) 144
N2 H2n O1 2_565 0.88 2.32 2.697(3) 106
N4 H4n O2 2_676 0.88 2.32 2.692(3) 105
N6 H6n O3 2_666 0.88 2.34 2.709(3) 106
loop_
_geom_torsion_atom_site_label_1
_geom_torsion_atom_site_label_2
_geom_torsion_atom_site_label_3
_geom_torsion_atom_site_label_4
_geom_torsion_site_symmetry_1
_geom_torsion_site_symmetry_2
_geom_torsion_site_symmetry_3
_geom_torsion_site_symmetry_4
_geom_torsion
_geom_torsion_publ_flag
N3 Ag O1 C7 . . . . 163.63(15) ?
N5 Ag O1 C7 . . . . -50.71(15) ?
N1 Ag O1 C7 . . . . 48.71(15) ?
O2 Ag O1 C7 . . . . -125.18(15) ?
N3 Ag O2 C14 . . . . -39.2(2) ?
N5 Ag O2 C14 . . . . 171.4(2) ?
N1 Ag O2 C14 . . . . 72.1(2) ?
O1 Ag O2 C14 . . . . -114.8(2) ?
N3 Ag N1 C1 . . . . 87.98(19) ?
N5 Ag N1 C1 . . . . -91.61(18) ?
O2 Ag N1 C1 . . . . -0.3(2) ?
O1 Ag N1 C1 . . . . -176.54(17) ?
N3 Ag N1 C5 . . . . -78.4(2) ?
N5 Ag N1 C5 . . . . 102.0(2) ?
O2 Ag N1 C5 . . . . -166.73(18) ?
O1 Ag N1 C5 . . . . 17.0(2) ?
N5 Ag N3 C8 . . . . -60.0(2) ?
N1 Ag N3 C8 . . . . 120.70(19) ?
O2 Ag N3 C8 . . . . -124.1(2) ?
O1 Ag N3 C8 . . . . 23.97(19) ?
N5 Ag N3 C12 . . . . 121.69(19) ?
N1 Ag N3 C12 . . . . -57.6(2) ?
O2 Ag N3 C12 . . . . 57.57(18) ?
O1 Ag N3 C12 . . . . -154.33(18) ?
N3 Ag N5 C19 . . . . 2.5(3) ?
N1 Ag N5 C19 . . . . -178.21(18) ?
O2 Ag N5 C19 . . . . 64.05(18) ?
O1 Ag N5 C19 . . . . -84.22(18) ?
N3 Ag N5 C15 . . . . -176.41(15) ?
N1 Ag N5 C15 . . . . 2.93(18) ?
O2 Ag N5 C15 . . . . -114.81(17) ?
O1 Ag N5 C15 . . . . 96.91(17) ?
C5 N1 C1 C2 . . . . 0.9(4) ?
Ag N1 C1 C2 . . . . -166.6(2) ?
N1 C1 C2 C3 . . . . -0.7(4) ?
C1 C2 C3 C4 . . . . 0.2(4) ?
C2 C3 C4 C5 . . . . 0.1(4) ?
C1 N1 C5 C4 . . . . -0.6(4) ?
Ag N1 C5 C4 . . . . 165.49(18) ?
C1 N1 C5 C6 . . . . 179.8(2) ?
Ag N1 C5 C6 . . . . -14.1(3) ?
C3 C4 C5 N1 . . . . 0.2(4) ?
C3 C4 C5 C6 . . . . 179.8(2) ?
C7 N2 C6 C5 . . . . 120.3(2) ?
N1 C5 C6 N2 . . . . -58.2(3) ?
C4 C5 C6 N2 . . . . 122.2(3) ?
Ag O1 C7 N2 . . . . -68.5(2) ?
Ag O1 C7 C7 . . . 2_565 111.3(3) ?
C6 N2 C7 O1 . . . . -3.3(4) ?
C6 N2 C7 C7 . . . 2_565 176.9(2) ?
C12 N3 C8 C9 . . . . 1.8(4) ?
Ag N3 C8 C9 . . . . -176.6(2) ?
N3 C8 C9 C10 . . . . 1.0(4) ?
C8 C9 C10 C11 . . . . -2.4(4) ?
C9 C10 C11 C12 . . . . 0.9(4) ?
C8 N3 C12 C11 . . . . -3.3(3) ?
Ag N3 C12 C11 . . . . 175.01(18) ?
C8 N3 C12 C13 . . . . 174.4(2) ?
Ag N3 C12 C13 . . . . -7.3(3) ?
C10 C11 C12 N3 . . . . 2.0(4) ?
C10 C11 C12 C13 . . . . -175.7(2) ?
C14 N4 C13 C12 . . . . 74.8(3) ?
N3 C12 C13 N4 . . . . -95.2(2) ?
C11 C12 C13 N4 . . . . 82.5(3) ?
Ag O2 C14 N4 . . . . -11.8(4) ?
Ag O2 C14 C14 . . . 2_676 168.21(18) ?
C13 N4 C14 O2 . . . . 6.2(4) ?
C13 N4 C14 C14 . . . 2_676 -173.8(2) ?
C19 N5 C15 C16 . . . . -0.6(3) ?
Ag N5 C15 C16 . . . . 178.29(18) ?
N5 C15 C16 C17 . . . . 3.2(4) ?
C15 C16 C17 C18 . . . . -2.6(4) ?
C16 C17 C18 C19 . . . . -0.4(4) ?
C15 N5 C19 C18 . . . . -2.5(3) ?
Ag N5 C19 C18 . . . . 178.64(17) ?
C15 N5 C19 C20 . . . . 176.4(2) ?
Ag N5 C19 C20 . . . . -2.4(3) ?
C17 C18 C19 N5 . . . . 3.0(4) ?
C17 C18 C19 C20 . . . . -175.8(2) ?
C21 N6 C20 C19 . . . . 76.1(3) ?
N5 C19 C20 N6 . . . . -165.2(2) ?
C18 C19 C20 N6 . . . . 13.7(3) ?
C20 N6 C21 O3 . . . . 2.8(4) ?
C20 N6 C21 C21 . . . 2_666 -175.8(2) ?
O5 S1 C22 F3 . . . . 64.0(3) ?
O4 S1 C22 F3 . . . . -175.7(2) ?
O6 S1 C22 F3 . . . . -56.3(3) ?
O5 S1 C22 F2 . . . . -174.2(2) ?
O4 S1 C22 F2 . . . . -53.9(3) ?
O6 S1 C22 F2 . . . . 65.5(3) ?
O5 S1 C22 F1 . . . . -54.3(3) ?
O4 S1 C22 F1 . . . . 66.1(3) ?
O6 S1 C22 F1 . . . . -174.5(2) ?
